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Dichlorodifluoromethane Dcf
DICHLORODIFLUOROMETHANE DCF CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION 4.1 Flash Point: 7.1 Grades of Purity: 99.5% (vol.) Common Synonyms Gas Colorless Faint odor Not flammable 7.2 Storage Temperature: Ambient Arcton 6 4.2 Flammable Limits in Air: Not flammable Eskimon 12 7.3 Inert Atmosphere: No requirement 4.3 Fire Extinguishing Agents: Not F-12 Visible vapor cloud is produced. 7.4 Venting: Safety relief flammable Freon 12 7.5 IMO Pollution Category: Currently not available Frigen 12 4.4 Fire Extinguishing Agents Not to Be Genetron 12 Used: Not flammable 7.6 Ship Type: Currently not available Halon 122 4.5 Special Hazards of Combustion 7.7 Barge Hull Type: 3 Isotron 12 Products: Although nonflammable, Ucon 12 dissociation products generated in a fire may be irritating or toxic. 8. HAZARD CLASSIFICATIONS Notify local health and pollution control agencies. 4.6 Behavior in Fire: Helps extinguish fire. 8.1 49 CFR Category: Nonflammable gas Avoid inhalation. 4.7 Auto Ignition Temperature: Not 8.2 49 CFR Class: 2.2 flammable 8.3 49 CFR Package Group: Not pertinent. Not flammable. 4.8 Electrical Hazards: Not pertinent Fire Cool exposed containers with water. 8.4 Marine Pollutant: No 4.9 Burning Rate: Not flammable 8.5 NFPA Hazard Classification: Not listed 4.10 Adiabatic Flame Temperature: Currently 8.6 EPA Reportable Quantity: 5000 pounds CALL FOR MEDICAL AID. not available Exposure 8.7 EPA Pollution Category: D 4.11 Stoichometric Air to Fuel Ratio: Not VAPOR 8.8 RCRA Waste Number: U075 Not irritating to eyes, nose or throat. -
Elemental Fluorine Product Information (Pdf)
Elemental Fluorine Contents 1 Introduction ............................................................................................................... 4 2.1 Technical Application of Fluorine ............................................................................. 5 2.2 Electronic Application of Fluorine ........................................................................... 7 2.3 Fluorine On-Site Plant ............................................................................................ 8 3 Specifications ............................................................................................................ 9 4 Safety ...................................................................................................................... 10 4.1 Maintenance of the F2 system .............................................................................. 12 4.2 First Aid ................................................................................................................ 13 5.1 Chemical Properties ............................................................................................. 14 5.2 Physical Data ....................................................................................................... 15 6 Toxicity .................................................................................................................... 18 7 Shipping and Transport ........................................................................................... 20 8 Environment ........................................................................................................... -
SAFETY DATA SHEET Halocarbon R-503
SAFETY DATA SHEET Halocarbon R-503 Section 1. Identification GHS product identifier : Halocarbon R-503 Other means of : Not available. identification Product type : Liquefied gas Product use : Synthetic/Analytical chemistry. SDS # : 007306 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : GASES UNDER PRESSURE - Liquefied gas substance or mixture HAZARDOUS TO THE OZONE LAYER - Category 1 GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : Contains gas under pressure; may explode if heated. May cause frostbite. May displace oxygen and cause rapid suffocation. Harms public health and the environment by destroying ozone in the upper atmosphere. Precautionary statements General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Always keep container in upright position. Prevention : Not applicable. Response : Not applicable. Storage : Protect from sunlight. Store in a well-ventilated place. Disposal : Refer to manufacturer or supplier for information on recovery or recycling. Hazards not otherwise : Liquid can cause burns similar to frostbite. -
Ethylene Dichloride (Edc) Handbook
ETHYLENE DICHLORIDE (EDC) HANDBOOK OXYCHEM TECHNICAL INFORMATION 11/2014 Dallas-based Occidental Chemical Corporation is a leading North American manufacturer of basic chemicals, vinyls and performance chemicals directly and through various affiliates (collectively, OxyChem). OxyChem is also North America's largest producer of sodium chlorite. As a Responsible Care® company, OxyChem's global commitment to safety and the environment goes well beyond compliance. OxyChem's Health, Environment and Safety philosophy is a positive motivational force for our employees, and helps create a strong culture for protecting human health and the environment. Our risk management programs and methods have been, and continue to be, recognized as some of the industry's best. OxyChem offers an effective combination of industry expertise, experience, on line business tools, quality products and exceptional customer service. As a member of the Occidental Petroleum Corporation family, OxyChem represents a rich history of experience, top-notch business acumen, and sound, ethical business practices. 1 Table of Contents Page Introduction to Ethylene Dichloride ............................................................................................................ 3 Manufacturing .................................................................................................................................................. 3 Ethylene Dichloride (EDC) — Uses ................................................................................................................ -
2018 Annual Survey of Biological and Chemical Agents Regulated by Homeland Security (And Carcinogens Regulated by OSHA)
Name: Dept: Date: 2018 Annual Survey of Biological and Chemical Agents regulated by Homeland Security (and carcinogens regulated by OSHA) Due (date) All labs that do not have a current chemical inventory in Chematix MUST complete this survey. The University is required to make an annual report of all chemicals on the Chemical Facility Anti-Terrorism Standards (CFATS) lists. Additional information regarding the regulations is available on the EH&S website at http://www.safety.rochester.edu/restricted/occsafe/chemicalagent.html and https://www.selectagents.gov. 1. Please review the lists on the following pages and indicate if any are possessed by your lab. The CAS# has been added to the list for ease of searching databases. The CAS# is a Chemical Abstract Service numbering system which assigns a unique number to every chemical substance based on structure; this helps avoid confusion by use of synonyms or different naming conventions. a. If yes for possession, place an X in the applicable box and if requested, include the quantity held in your lab. b. If no, leave blank. 2. After reviewing the list, please complete the information box below (or on last page for possession), then sign, date and return to EH&S. 3. Please call Donna Douglass at 275-2402 if you have any questions. Thank you for your cooperation in collecting data required by the Department of Homeland Security! Possession: 1) Fill in applicable boxes, 2) have PI sign last page, 3) return all pages to Donna Douglass OR Non-possession: 1) Check only one box on the left, 2) sign, 3) return just this page to Donna Douglass I do not have a lab, do not work in a lab, nor do I possess any of the agents in this survey. -
Refrigerant Safety Refrigerant History
Refrigerant Safety The risks associated with the use of refrigerants in refrigeration and airconditioning equipment can include toxicity, flammability, asphyxiation, and physical hazards. Although refrigerants can pose one or more of these risks, system design, engineering controls, and other techniques mitigate this risk for the use of refrigerant in various types of equipment. Refrigerant History Nearly all of the historically used refrigerants were flammable, toxic, or both. Some were also highly reactive, resulting in accidents (e. g., leak, explosion) due to equipment failure, poor maintenance, or human error. The task of finding a nonflammable refrigerant with good stability was given to Thomas Midgley in 1926. With his associates Albert Leon Henne and Robert Reed McNary, Dr. Midgley observed that the refrigerants then in use comprised relatively few chemical elements, many of which were clustered in an intersecting row and column of the periodic table of elements. The element at the intersection was fluorine, known to be toxic by itself. Midgley and his collaborators felt, however, that compounds containing fluorine could be both nontoxic and nonflammable. The attention of Midgley and his associates was drawn to organic fluorides by an error in the literature that showed the boiling point for tetrafluoromethane (carbon tetrafluoride) to be high compared to those for other fluorinated compounds. The correct boiling temperature later was found to be much lower. Nevertheless, the incorrect value was in the range sought and led to evaluation of organic fluorides as candidates. The shorthand convention, later introduced to simplify identification of the organic fluorides for a systematic search, is used today as the numbering system for refrigerants. -
Summary of Gas Cylinder and Permeation Tube Standard Reference Materials Issued by the National Bureau of Standards
A111D3 TTbS?? o z C/J NBS SPECIAL PUBLICATION 260-108 o ^EAU U.S. DEPARTMENT OF COMMERCE/National Bureau of Standards Standard Reference Materials: Summary of Gas Cylinder and Permeation Tube Standard Reference Materials Issued by the National Bureau of Standards QC 100 U57 R. Mavrodineanu and T. E. Gills 260-108 1987 m he National Bureau of Standards' was established by an act of Congress on March 3, 1901. The Bureau's overall goal i s t0 strengthen and advance the nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research to assure international competitiveness and leadership of U.S. industry, science arid technology. NBS work involves development and transfer of measurements, standards and related science and technology, in support of continually improving U.S. productivity, product quality and reliability, innovation and underlying science and engineering. The Bureau's technical work is performed by the National Measurement Laboratory, the National Engineering Laboratory, the Institute for Computer Sciences and Technology, and the Institute for Materials Science and Engineering. The National Measurement Laboratory Provides the national system of physical and chemical measurement; • Basic Standards 2 coordinates the system with measurement systems of other nations and • Radiation Research furnishes essential services leading to accurate and uniform physical and • Chemical Physics chemical measurement throughout the Nation's scientific community, • Analytical Chemistry industry, and commerce; provides advisory and research services to other Government agencies; conducts physical and chemical research; develops, produces, and distributes Standard Reference Materials; provides calibration services; and manages the National Standard Reference Data System. -
Toxicological Profile for Ethylbenzene
ETHYLBENZENE 151 5. PRODUCTION, IMPORT/EXPORT, USE, AND DISPOSAL 5.1 PRODUCTION Ethylbenzene is primarily produced by the alkylation of benzene with ethylene in liquid-phase slurry reactors promoted with aluminum chloride catalysts or by vapor-phase reaction of benzene with dilute ethylene-containing feedstock with a boron trifluoride catalyst supported on alumina (Cannella 2007; Clayton and Clayton 1981; HSDB 2009; Welch et al. 2005; Ransley 1984). Newer versions of the method employ synthetic zeolites in fixed-bed reactors as catalysts for alkylation in the liquid phase or narrow pore synthetic zeolites in fixed-bed reactors in the vapor phase (Welch et al. 2005). Other methods of manufacturing ethylbenzene include preparation from acetophenone, dehydrogenation of naphthenes, catalytic cyclization and aromatization, separation from mixed xylenes via fractionation, reaction of ethylmagnesium bromide and chlorobenzene, extraction from coal oil, and recovery from benzene-toluene-xylene (BTX) processing(Clayton and Clayton 1981; HSDB 2009; Ransley 1984; Welch et al. 2005). Commercial grades of ethylbenzene may contain small amounts of m-xylene, p-xylene, cumene, and toluene (HSDB 2009). Ethylbenzene is traditionally ranked as one of the top 50 chemicals produced in the United States. Table 5-1 shows the historical production volumes of ethylbenzene from 1983 to 2005 (C&EN 1994a, 1994b, 1995, 2006; Kirschner 1995). Table 5-2 lists the facilities in each state that manufacture or process ethylbenzene, the intended use, and the range of maximum amounts of ethylbenzene that are stored on site. There are currently 3,755 facilities that produce, process, or use ethylbenzene in the United States. The data listed in Table 5-2 are derived from the Toxics Release Inventory (TRI06 2008). -
Flammable Refrigerants Firefighter Training
Flammable refrigerants firefighter training: Hazard assessment and demonstrative testing FINAL REPORT BY: Noah L. Ryder, P. E. Stephen J. Jordan Fire & Risk Alliance, LLC. Rockville, Maryland, USA. Peter B. Sunderland, Ph.D. University of Maryland Department of Fire Protection Engineering College Park, Maryland, USA. May 2019 © 2019 Fire Protection Research Foundation 1 Batterymarch Park, Quincy, MA 02169-7417, USA Email: [email protected] | Web: nfpa.org/foundation ---page intentionally left blank--- —— Page ii —— FOREWORD The ongoing push toward sustainability of refrigeration systems will require the adoption of low global warming potential (GWP) refrigerants to meet the shift in environmental regulations. Fire safety is a lingering issue with the new age of flammable refrigerants being adopted and first responders may not be familiar with the change in material hazards or the appropriate response procedures required to safely handle these fire scenarios. This project is part of the overall two-year project with a goal to enhance firefighter safety and reduce potential injury by providing training on the hazards from appliances with flammable refrigerants. It will document the information about flammable refrigerants technologies and the hazards to emergency responders and develop interactive training modules to transfer the knowledge to the fire service. This report is focused to develop material documenting the hazards associated with flammable refrigerant technologies and the risks posed to the first responders. The material documentation included a literature review, Task 1, identifying baseline information on flammable refrigerants, their existing usage and implementation into products, potential integration into future technologies, and finally any existing guidance and best practices on response and tactics. -
Chemical Chemical Hazard and Compatibility Information
Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine -
"Fluorine Compounds, Organic," In: Ullmann's Encyclopedia Of
Article No : a11_349 Fluorine Compounds, Organic GU¨ NTER SIEGEMUND, Hoechst Aktiengesellschaft, Frankfurt, Federal Republic of Germany WERNER SCHWERTFEGER, Hoechst Aktiengesellschaft, Frankfurt, Federal Republic of Germany ANDREW FEIRING, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States BRUCE SMART, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States FRED BEHR, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, United States HERWARD VOGEL, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, United States BLAINE MCKUSICK, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States 1. Introduction....................... 444 8. Fluorinated Carboxylic Acids and 2. Production Processes ................ 445 Fluorinated Alkanesulfonic Acids ...... 470 2.1. Substitution of Hydrogen............. 445 8.1. Fluorinated Carboxylic Acids ......... 470 2.2. Halogen – Fluorine Exchange ......... 446 8.1.1. Fluorinated Acetic Acids .............. 470 2.3. Synthesis from Fluorinated Synthons ... 447 8.1.2. Long-Chain Perfluorocarboxylic Acids .... 470 2.4. Addition of Hydrogen Fluoride to 8.1.3. Fluorinated Dicarboxylic Acids ......... 472 Unsaturated Bonds ................. 447 8.1.4. Tetrafluoroethylene – Perfluorovinyl Ether 2.5. Miscellaneous Methods .............. 447 Copolymers with Carboxylic Acid Groups . 472 2.6. Purification and Analysis ............. 447 8.2. Fluorinated Alkanesulfonic Acids ...... 472 3. Fluorinated Alkanes................. 448 8.2.1. Perfluoroalkanesulfonic Acids -
Liquefied Gas Conversion Chart
LIQUEFIED GAS CONVERSION CHART Cubic Feet / Pound Pounds / Gallon Product Name Column A Column B Acetylene UN/NA: 1001 14.70 4.90 CAS: 514-86-2 Air UN/NA: 1002 13.30 7.29 CAS: N/A Ammonia Anhydrous UN/NA: 1005 20.78 5.147 CAS: 7664-41-7 Argon UN/NA: 1006 9.71 11.63 CAS: 7440-37-1 Butane UN/NA: 1075 6.34 4.86 CAS: 106-97-8 Carbon Dioxide UN/NA: 2187 8.74 8.46 CAS: 124-38-9 Chlorine UN/NA: 1017 5.38 11.73 CAS: 7782-50-5 Ethane UN/NA: 1045 12.51 2.74 CAS: 74-84-0 Ethylene Oxide UN/NA: 1040 8.78 7.25 CAS: 75-21-8 Fluorine UN/NA: 1045 10.17 12.60 CAS: 7782-41-4 Helium UN/NA: 1046 97.09 1.043 CAS: 7440-59-7 Hydrogen UN/NA: 1049 192.00 0.592 CAS: 1333-74-0 1. Find the gas you want to convert. 2. If you know your quantity in cubic feet and want to convert to pounds, divide your amount by column A 3. If you know your quantity in gallons and want to convert to pounds, multiply your amount by column B 4. If you know your quantity in pounds and want to convert to gallons, divide your amount by column B If you have any questions, please call 1-800-433-2288 LIQUEFIED GAS CONVERSION CHART Cubic Feet / Pound Pounds / Gallon Product Name Column A Column B Hydrogen Chloride UN/NA: 1050 10.60 8.35 CAS: 7647-01-0 Krypton UN/NA: 1056 4.60 20.15 CAS: 7439-90-9 Methane UN/NA: 1971 23.61 3.55 CAS: 74-82-8 Methyl Bromide UN/NA: 1062 4.03 5.37 CAS: 74-83-9 Neon UN/NA: 1065 19.18 10.07 CAS: 7440-01-9 Mapp Gas UN/NA: 1060 9.20 4.80 CAS: N/A Nitrogen UN/NA: 1066 13.89 6.75 CAS: 7727-37-9 Nitrous Oxide UN/NA: 1070 8.73 6.45 CAS: 10024-97-2 Oxygen UN/NA: 1072 12.05 9.52 CAS: 7782-44-7 Propane UN/NA: 1075 8.45 4.22 CAS: 74-98-6 Sulfur Dioxide UN/NA: 1079 5.94 12.0 CAS: 7446-09-5 Xenon UN/NA: 2036 2.93 25.51 CAS: 7440-63-3 1.