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Sealed Lead Acid Battery #5375422 5375438 5375444 5375450 Sealed Lead Acid Battery #5375422 5375438 5375444 5375450 RS Components Pty Ltd Chemwatch Hazard Alert Code: 3 Chemwatch: 22-9187 Issue Date: 01/01/2013 Version No: 2.1.1.1 Print Date: 17/02/2015 Material Safety Data Sheet according to NOHSC and ADG requirements Initial Date: Not Available L.Local.AUS.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Sealed Lead Acid Battery #5375422 5375438 5375444 5375450 Synonyms 5375422, 5375438, 5375444, 5375450, 5375472, 5375488, 5375494, 5375501, 5377305 Proper shipping name BATTERIES, WET, NON-SPILLABLE, electric storage Other means of Not Available identification Relevant identified uses of the substance or mixture and uses advised against Relevant identified Use according to manufacturer's directions. uses Details of the manufacturer/importer Registered company RS Components Pty Ltd name Address 25 Pavesi Street NSW 2164 Australia Telephone 1300 656 636 Fax 1300 656 696 Website Not Available Email Not Available Emergency telephone number Association / Not Available Organisation Emergency telephone 1800 039 008 numbers Other emergency 03 95733112 telephone numbers SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. CHEMWATCH HAZARD RATINGS Min Max Flammability 1 Toxicity 2 0 = Minimum Body Contact 3 1 = Low Reactivity 2 2 = Moderate 3 = High Chronic 3 4 = Extreme Poisons Schedule Not Applicable Continued... Chemwatch: 22-9187 Page 2 of 12 Issue Date: 01/01/2013 Version No: 2.1.1.1 Sealed Lead Acid Battery #5375422 5375438 5375444 5375450 Print Date: 17/02/2015 R20/22 Harmful by inhalation and if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R61(1) May cause harm to the unborn child. Risk Phrases [1] R33 Danger of cumulative effects. R62(3) Possible risk of impaired fertility. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with /21/22 skin and if swallowed. 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex Legend: VI Relevant risk statements are found in section 2 Indication(s) of T, Xn, N danger SAFETY ADVICE S01 Keep locked up. S07 Keep container tightly closed. S09 Keep container in a well ventilated place. S13 Keep away from food, drink and animal feeding stuffs. S20 When using do not eat or drink. S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse with plenty of water and contact Doctor or Poisons Information Centre. S28 After contact with skin, wash immediately with plenty of water S29 Do not empty into drains. S35 This material and its container must be disposed of in a safe way. S36 Wear suitable protective clothing. S37 Wear suitable gloves. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S39 Wear eye/face protection. S40 To clean the floor and all objects contaminated by this material, use water and detergent. In case of accident or if you feel unwell IMMEDIATELY contact Doctor or Poisons Information Centre (show label if S45 possible). S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well ventilated areas. S53 Avoid exposure - obtain special instructions before use. S56 Dispose of this material and its container at hazardous or special waste collection point. S57 Use appropriate container to avoid environmental contamination. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets. S64 If swallowed, rinse mouth with water (only if the person is conscious). Other hazards Limited evidence of a carcinogenic effect*. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Continued... Chemwatch: 22-9187 Page 3 of 12 Issue Date: 01/01/2013 Version No: 2.1.1.1 Sealed Lead Acid Battery #5375422 5375438 5375444 5375450 Print Date: 17/02/2015 Mixtures CAS No %[weight] Name 7439-92-1 57 lead 1309-60-0 22 lead dioxide 7631-86-9 7 silica amorphous 7664-93-9 14 sulfuric acid SECTION 4 FIRST AID MEASURES Description of first aid measures Eye Contact Generally not applicable. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. Inhalation Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorised by him/her. (ICSC13719) IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY. For advice, contact a Poisons Information Centre or a doctor. Urgent hospital treatment is likely to be needed. In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive measures as indicated by the patient's condition. If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a copy of the MSDS should be provided. Further action will be the responsibility of the medical specialist. If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of Ingestion the MSDS. Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or unless instructed otherwise: INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. NOTE: Wear a protective glove when inducing vomiting by mechanical means. Indication of any immediate medical attention and special treatment needed For acute or short term repeated exposures to strong acids: Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues. INGESTION: Immediate dilution (milk or water) within 30 minutes post ingestion is recommended. DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult. Charcoal has no place in acid management. Some authors suggest the use of lavage within 1 hour of ingestion. SKIN: Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine. EYE: Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. Continued... Chemwatch: 22-9187 Page 4 of 12 Issue Date: 01/01/2013 Version No: 2.1.1.1 Sealed Lead Acid Battery #5375422 5375438 5375444 5375450 Print Date: 17/02/2015 DO NOT use neutralising agents or any other additives. Several litres of saline are required. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist). [Ellenhorn and Barceloux: Medical Toxicology] Gastric acids solubilise lead and its salts and lead absorption occurs in the small bowel. Particles of less than 1 um diameter are substantially absorbed by the alveoli following inhalation. Lead is distributed to the red blood cells and has a half-life of 35 days. It is subsequently redistributed to soft tissue & bone-stores or eliminated. The kidney accounts for 75% of daily lead loss; integumentary and alimentary losses account for the remainder. Neurasthenic symptoms are the most common symptoms of intoxication. Lead toxicity produces a classic motor neuropathy. Acute encephalopathy appears infrequently in adults. Diazepam is the best drug for seizures. Whole-blood lead is the best measure of recent exposure; free erythrocyte protoporphyrin (FEP) provides the best screening for chronic exposure. Obvious clinical symptoms occur in adults when whole-blood lead exceeds 80 ug/dL. British Anti-Lewisite is an effective antidote and enhances faecal and urinary excretion of lead. The onset of action of BAL is about 30 minutes and most of the chelated metal complex is excreted in 4-6 hours, primarily in the bile. Adverse reaction appears in up to 50% of patients given BAL in doses exceeding 5 mg/kg.
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