8341-14E
Spill Report - Field Response
01-10-011-07 W2M Battery
Prepared for: Harvest Operations Corp Prepared by: Vertex Professional Services Ltd. Date: January, 2014 General Information
Report Date: January 8, 2014 File Number: 8341-14E Client: Harvest Operations Corp Location: 01-10-011-07 W2M UWI: Battery Landowner: Ocean Man First Nation c/o Phone: Tenant: Hoffman and Associates Ltd. Phone: 306-621-7797
Spill Details Spill Date: May 22, 2014 Spill Type: Emulsion Facility Type: Battery % ON lease: 0% Spill Volume (m3): unknown Spill Area (m2): 4418 Recovered Volume (m3): 0 Fluid disposal: The only recovered product came from the purging of the emulsion line and was disposed of in a Harvest facility
Comments: The spill occurred west of the battery resulting from a ruptured flow line. There were three flow lines running parallel in a common corridor. The spill ran south towards a large water body.
Landscape Details Current Land Use: The spill occurred on Ocean Man First Nation crop land that was seeded to oats.
Adjacent Land Use: The adjacent land use is either cultivation or pasture owned by the Ocean Man First Nation Slope (%) and direction: <2% sloping towards the south Soils observed: Proximity to Residence: None within 500 m Proximity to Waterbody: Numerous pothole sloughs adjacent to the site Proximity to Livestock: None on 1/4 section Proximity to Other: Affected Receptors: The large water body at the southern boundary of the spill area did come in contact with the spill. Water samples indicated that there were no adverse affects to the water chemistry.
Applicable Spill Background Information
Landowner Conversation: Hoffman and Associates Ltd. (Dave Hoffman) represents the Ocean Man First Nation and they have been updated to the progress of the spill cleanup activities
Operator Comments: A historical spill occurred west of the current spill area. Spill cleanup activities on this site are coordinated by Summit.
Spill Cause Details: The spill was caused by a ruptured flow line.
Notification to Regulator: Harvest Operations personnel contacted the Ministry of Economy - Petroleum Development Branch to report the spill.
Vertex Professional Services Remedial Event Log
Date: July 8, 2014 Site activities: Vertex personnel responded to an emulsion spill communicated by Harvest Environmental Coordinator. The spill details were reviewed with operations representative Rolland Vienneau at the spill site. Meanwhile, current tenant, Dennis Smith, was removing livestock from the pasture adjacent to the south extent of the potentially affected wetland down gradient of the break point. A vac truck was utilized to purge flow line. The fluid was disposed of in a Harvest owned facility. Harvest operations personnel arranged a labour crew to monitor and deter any wildlife, birds, waterfowl from entering or occupying the potentially affected wetland areas. Operations also arranged deployment of a propane wildlife deterrent cannon to be placed at the edge of the large wetland. Date: July 9, 2014 Site activities: Two water samples were collected from the small slough, WS-5 near the entrance and WS-6 near the center. Field screening for chloride was below the detectable limit for each of 32 mg/L Vegetation along the spill pathway is visibly affected (brown and wilted) and appears to have nearly stopped at the shore of the large wetland area to the southwest An affected pathway approximately 0.3m wide and 0.6m long entered the wetland area and therefore water samples were collected. WS-1 is assumed to be from the most affected area (apparent by the vegetation stress) in the east half of the spill path with chloride readings of 1681 mg/L. The water samples taken from the west half of the spill path (WS-2) had chloride readings of 326 mg/L. Two water samples were taken from the south side of the large slough; WS-3 and WS-4 both had chloride concentrations of 146 mg/L. Vertex staff completed an EM38 and an EM31 survey of the spill area to background extents. The battery, spill area, and surface features around the site were mapped utilizing a Trimble GPS. Water samples were sent to ALS Laboratories for analysis.
Date: July 10, 2014 Site activities: A tracked excavator was used to scrape the southern portion of the spill area adjacent to the large wetland and a berm was constructed to protect the large wetland from any potential surface runoff. As the excavation continued, field screening was completed using an EC soil probe measuring relative soil conductivity. Excavated depth in the southern portion of the spill area ranged from 0.15 to 0.5 mbgs. Along the sloping portion of the spill pathway, ranged between 0.05 and 0.15 m.
Date: July 14 - 15, 2014 Site activities: Swamp matting was deployed as required for access and egress to the spill area due to adverse soil conditions and excessive traffic. Date: July 16, 2014 Site activities: An additional tracked excavator was used to assist in impacted soil excavation. The pipeline corridor was daylighted using hydrovacs. The contaminated hydrovac slurry was stored within the spill area and blended with impacted soil from the spill area.
Date: July 16, 17, 21, and 22, 2014 Site activities: An additional tracked excavator was used to assist in impacted soil excavation. The pipeline corridor was daylighted using hydrovacs. The contaminated hydrovac slurry was stored within the spill area and blended with impacted soil from the spill area. All areas were field screened with a handheld EC soil probe as the excavation progressed.
Date: July 29 - August 1, 2014 Site activities: A total of 1735.4 tonnes were hauled to Gibson's Heward, SK Landfill. Date: August 5, 2014 Site activities: Removed fluid from excavation and disposed of it in cell onsite. Date: August 6, 2014 Site activities: Sampled the excavation and spill area in a grid pattern and field screened. Areas of elevated EC and Cl were excavated and stockpiled on site. The total area and the sample locations were GPS'd utilizing a Trimble unit.
Vertex Professional Services Date: August 11, 2014 Site activities: Scouted potential dugout locations with Boyes Contracting's Kevin Dunham. Dave Hoffman gave 4 potential dugout locations to utilize for backfill material.
Date: September 15-24, 2014 Site activities: Re-sampled all previously elevated sample points at depth intervals of 0-0.15 m and 0.15-0.30 m. Field screened samples for EC and Chlorides, and further excavated areas of elevated EC levels and Chloride concentrations. A vacuum truck removed free liquid from excavation and hauled to Gibson's Midale, SK disposal facility. A hydrovac was implemented to expand excavation over the third line. All hydrovac mud was mixed in the cell for disposal
Date: October 7-8, 2014 A total of 691.9 tonnes of stockpiled impacted material was hauled to Gibson's Heward, SK Site activities: Landfill. Date: November 21, 2014 Site activities: A supplementary EM survey was completed over the spill area Date: December 1, 2014 Site activities: The spill area was sampled based on the results from the EM survey. Date: December 9-11, 2014 Site activities: Additional impacted soil with elevated EC and Chloride concentrations was excavated. A total of 399.7 tonnes were hauled to Gibson's Heward, SK Landfill. Date: January 29, 2015 Site activities: Met Dave Hoffman the representative for Ocean Man First Nation and spotted 4 dugout locations for backfill material. Dave took with him copies of the Harvest dugout placement forms to be signed by Ocean Man First Nation council. A tractor and blade combination was used to plow snow at these locations in preparation for excavation.
Date: February 25-March 6, 2015 Excavated exceedances on sample point #9. A total of 52.9 tonnes of soil was hauled to Gibson's Disposal. Completed the excavation of the four dugouts. Site activities: Date: March 9, 2015 Site activities: Started hauling topsoil from dugout locations to 01-10-011-07 W2M. Shut down early due to muddy site conditions. Tridem end dumps were implemented to haul topsoil adjacent to the spill area. Backfill activities started at south end moving north towards pipeline ROW using a dozer and excavator. A Hydro-vac was used to remove snow from the pipeline ROW and expose pipelines for sand cover.
Date: March 10, 2015 Site activities: Hauled clay and topsoil from the dugout locations to 01-10-011-07 W2M. Shut down early due to deteriorating site conditions. Shane & Ryan of Harvest Operations arrived on site to supervise sand padding of pipeline. Track-hoe began with sand padding. After sand padding, clay was spread on top of pipeline ROW with track-hoe - assisted by dozer operator. Shane left site after pipe was adequately covered. Date: March 11, 2014 Site activities: Hauled clay and topsoil from dugout locations to 01-10-011-07 W2M. Started earlier to run on the frost as long as possible. A tractor and blade combination was used to plow a new trail into the dugout location and level the ruts on the previous trail. Additional topsoil is required to restore adequate topsoil depth. No further shading of topsoil was done to avoid admixing. Future work is required once site conditions improve.
Vertex Professional Services Discussion As per SPIGEC criteria for Produced water spill assessment, soil samples were analyzed for 'Detailed Salinity,'. All confirmatory soil samples were within SPIGEC's Electrical Conductivity (EC) un conditional land use criteria excluding HA14- 001 with an EC of 24.5 dS/m at 0-15 cm and 13.8 dS/m at 30 -50 cm below surface, HA14-002 with an EC of 53.9 dS/m at 0- 15 cm and 22.5 dS/m at 30-50 cm below surface, and HA14-008 with an EC of 8.36 dS/m . All confirmatory soil samples were within SPIGEC's Sodium Adsorption Ratio (SAR) unconditional land use criteria excluding HA14-001 with an SAR of 31.7 at 0-15 cm and 17.8 at 30-50 cm below surface, HA14-002 with an EC of 51.7 at 0-15 cm and 31.9 at 30-50 cm below surface. HA14-001 and HA14-002 were in the flow line corridor and to excavate further would risk the structural integrity of flow line support.
Summary An emulsion spill that occurred as a result of a fractured flow line west of Harvest's 01-10-011-07 W2M battery on July 8, 2014. Vertex staff coordinated recovery, excavation and disposal of impacted soil and water. Numerous spill area assessment and confirmatory soil samples were taken during and after the excavation process. The emulsion ran north, south, east and west of the break point following general site topography. A small volume of emulsion entered the large wetland south of the break point as well as the smaller wetland east of the break point. Initial soil sampling of the spill area was completed using a grid pattern. Confirmatory sampling was based off of an EM 38 derived figure. Sample points HA14- 001 and HA14-002 exceeded SPIGEC's EC and SAR criteria. Due to the position of these sample points within the flow line corridor to excavate further would risk the structural integrity of the flow lines. A total of 3126.1 tonnes of contaminated soil was excavated, hauled and disposed of at Gibson's Heward, SK landfill. Backfill material was obtained from 4 dugouts excavated by Vertex on Ocean Man First Nation land through Dave Hoffman - Ocean Man First Nation representative. Additional topsoil is required to cover the backfilled excavation in the spring of 2015.
Closure The following guidelines were used as references for the comparison and interpretation of analytical results: • Saskatchewan Petroleum Industry/Government Environmental Committee (SPIGEC) Guideline No. 4 – Saskatchewan Upstream Petroleum Sites Remediation Guidelines (SPIGEC – 2000, Revised 2009)
A copy of this report should be kept on file for evaluation upon pipeline abandonment. Vegetation monitoring is required for up to three years as per SPIGEC Guidelines. If you have any questions or concerns please contact Kristopher Boyes at 306.485-8117
Respectfully,
Kristopher Boyes Project Manager - Environmental Services
Reviewed and approved for transmittal by:
Brett Tuchscherer Project Manager - Environmental Services
Enclosed: Figure 1 - Site Location Map Figure 2 - Site Diagram Figure 3 - EM Diagram Figure 4A - Horizontal EM Diagram Figure 4B - Vertical EM Diagram Table 1 - Analytical Summary Appendix A - Site Photos Appendix B - Original ALS Laboratory Reports
Vertex Professional Services FIGURES
"Windthorst Kipling ³ Bredenbury " ² Southey Melville Langenburg 48 Balcarres Russell UV617Fort Qu'appelle 13-9-2 Lemberg 13-5-2 13-4-2 Moose Mountain Creek 13-8-2 Esterhazy 13-7-2 13-6-2 Qu'appelle Balgonie Sintaluta Regina WolseleyGrenfellBroadview Rocanville BroadviewWhitewood Wapella Moosomin Francis Kipling Fleming
Milestone Area of Wawota Detail 12-4-2 Yellow Grass 12-5-2 12-7-2 12-6-2 Stoughton12-8-2 12-9-2Weyburn ArcolaCarlyle Redvers
Radville Midale Lampman Alameda Oxbow UV711 Carnduff EstevanBienfait
11-4-2
11-6-2 11-5-2
³ Gooseberry Lake 11-8-2² 11-7-2 11-9-2 Moose Mountain Lake 47 Moose Mountain Creek 111/01-10-011-07 W2 jk
Ocean Man " 10-5-2 UV605 10-7-2 10-6-2 10-9-2 10-8-2
9-5-2
9-7-2 9-6-2
9-9-2 9-8-2 ³
33 ²
Stoughton 8-5-2 ³ 8-9-2 8-8-2 " 8-7-2 8-6-2² 13
" PREPARED FOR: FIGURE 1 LEGEND SITE LOCATION MAP Town / City 111/01-10-011-07 W2 Primary Highway
Secondary Highway PREPARED BY: Lakes DATE: 12/05/2015 DRAWN BY: PS SCALE: 1:250,000 CHECKED BY: KB DocumentPath: X:\CAD Files (Drafting Use Only)\Harvest Operations Corp\8341-14E\MXD\Loc Map.mxd N
W E
S
5490760
5490740
5490720
5490740
SMALL SLOUGH 1000 BBL 5490720 WATER LINE TANK TREATER
SPILL WS 5 3 PHASE 5490700 AREA 2885 Sq.m. POWER POLE TREATER BUILDING INDICATOR SIGN 5490680 WS 6
BREAK CONTROL
UTM NORTHING (m) 5490660 POINT BOX ACCESS ROAD CATHODIC 5490640 RISER WARNING WELL HEAD SIGN
CATHODIC 5490620 RISER UNAFFECTED AREA 537 Sq.m. 5528320 SK POWER CANISTER
WATER LINE 5528300 LARGE SLOUGH
5528280 652640 652660 652680 652700 652720 652740 652760 652780 652800 652820 652840 652860 652880 652900 652920 652940 652960 652980 653000 653020 UTM EASTING (m)
LEGEND: PREPARED FOR: FIGURE 2: LEASE BOUNDARY SITE DIAGRAM WELL CENTER 11/01-10-011-07 W2M PREPARED BY: DRAWN BY: BM 0 10 20 40 CHECKED BY: BT METERS DATE DRAWN: 10 JUL 14
U:\CAD\HARVEST N
W E
S
5490760
5490740
5490720
5490740
SMALL SLOUGH 1000 BBL 5490720 WATER LINE TANK TREATER
SPILL WS 5 3 PHASE 5490700 AREA 2885 Sq.m. POWER POLE TREATER BUILDING INDICATOR SIGN 5490680 WS 6
BREAK CONTROL
UTM NORTHING (m) 5490660 POINT BOX ACCESS ROAD CATHODIC 5490640 RISER WARNING WELL HEAD SIGN
CATHODIC 5490620 RISER UNAFFECTED AREA 537 Sq.m. 5528320 SK POWER CANISTER
WATER LINE 5528300 LARGE SLOUGH
5528280 652640 652660 652680 652700 652720 652740 652760 652780 652800 652820 652840 652860 652880 652900 652920 652940 652960 652980 653000 653020 UTM EASTING (m) mS/m
LEGEND: PREPARED FOR: FIGURE 3: LEASE BOUNDARY EM DIAGRAM WELL CENTER 11/01-10-011-07 W2M PREPARED BY: DRAWN BY: BM 0 10 20 40 CHECKED BY: BT METERS DATE DRAWN: 10 JUL 14
U:\CAD\HARVEST N
W E
S
5490760
5490740
5490720
5490740
SMALL SLOUGH 1000 BBL 5490720 WATER LINE TANK TREATER
WS 5 5490700 TREATER BREAK BUILDING POINT 5490680 AREA OFF LEASE WS 6 4418 Sq.m.
5490660 UTM NORTHING (m) ACCESS TOTAL SPILL ROAD AREA 4831 Sq.m.
5490640 AREA ON LEASE 413 Sq.m.
5490620 UNAFFECTED AREA 537 Sq.m. 5528320
WATER LINE 5528300 LARGE SLOUGH
5528280
5528260 652780 652800 652820 652840 652860 652880 652900 652920 652940 652960 652980 653000 653020 652660 652680 652700 652720 652740 652760 UTM EASTING (m)
LEGEND: PREPARED FOR: FIGURE 4: LEASE BOUNDARY AREA AFFECTED WELL CENTER 11/01-10-011-07 W2M PREPARED BY: DRAWN BY: BM 0 10 20 40 CHECKED BY: BT METERS DATE DRAWN: 26 AUG 14
8341-14E U:\CAD\HARVEST N
W E
S
5528570 5528560 5528550 5528540 5528530 5528520 5528510 5528500 5528490 5528480 5528470 5528460 SMALL 5528450 SLOUGH 1000 BBL WATER LINE TANK BREAK 5528440 TREATER POINT 5528430 AREA OFF LEASE WS 5 4418 Sq.m. 5528420 TREATER TOTAL SPILL BUILDING 5528410 AREA 4831 Sq.m. 5528400 WS 6 5528390
UTM NORTHING (m) 5528380 ACCESS ROAD 5528370 5528360 AREA ON LEASE 413 Sq.m. 5528350 5528340 UNAFFECTED 5528330 AREA 537 Sq.m. 5528320
5528310 WATER LINE LARGE SLOUGH 5528300 5528290 5528280 5528270 652690 652700 652710 652720 652730 652740 652750 652760 652770 652780 652790 652800 652810 652820 652830 652840 652850 652860 652870 652880 652890 652900 652910 652920 652930 652940 652950 652960 652970 652980 652990 653000 653010 653020 653030 UTM EASTING (m) mS/m 40 90 140 190 240 290 340 390 HORIZONTAL
LEGEND PREPARED FOR: SUSPENDED WELL FIGURE 4A CENTRE HORIZONTAL EM DIAGRAM SAMPLE POINT 111/01-10-011-07 W2M
POWER POLE PREPARED BY: LEASE BOUNDARY DRAWN BY: YMP 0 10 20 40 m CHECKED BY: NH DATE DRAWN: 21 NOV 14
8341-14E U:\CAD\8341-14E - HARVEST\MAPS N
W E
S
5528570 5528560 5528550 5528540 5528530 5528520 5528510 5528500 5528490 5528480 5528470 5528460 SMALL 5528450 SLOUGH 1000 BBL WATER LINE TANK BREAK 5528440 TREATER POINT 5528430 AREA OFF LEASE WS 5 4418 Sq.m. 5528420 TREATER TOTAL SPILL BUILDING 5528410 AREA 4831 Sq.m. 5528400 WS 6 5528390
UTM NORTHING (m) 5528380 ACCESS ROAD 5528370 5528360 AREA ON LEASE 413 Sq.m. 5528350 5528340 UNAFFECTED 5528330 AREA 537 Sq.m. 5528320
5528310 WATER LINE LARGE SLOUGH 5528300 5528290 5528280 5528270 652690 652700 652710 652720 652730 652740 652750 652760 652770 652780 652790 652800 652810 652820 652830 652840 652850 652860 652870 652880 652890 652900 652910 652920 652930 652940 652950 652960 652970 652980 652990 653000 653010 653020 653030 UTM EASTING (m) mS/m 20 70 120 170 220 270 320 370 VERTICAL
LEGEND PREPARED FOR: SUSPENDED WELL FIGURE 4B CENTRE VERTICAL EM DIAGRAM SAMPLE POINT 111/01-10-011-07 W2M
POWER POLE PREPARED BY: LEASE BOUNDARY DRAWN BY: YMP 0 10 20 40 m CHECKED BY: NH DATE DRAWN: 21 NOV 14
8341-14E U:\CAD\8341-14E - HARVEST\MAPS TABLES Table 1. Soil Characterization - Salinity and Petroleum Hydrocarbon Parameters Harvest Operations Corp. 01-10-011-07 W2M File #: 8341-14E Lab Reports: 14C891146, L1499888, L1499945, L1553971, L1557855 and L1582196
Sample Description Physical Properties and Salinity (Soluble Parameters) Petroleum Hydrocarbons Volatile Extractable
Location Depth (m) Date ) 2 Moisture pH (in 0.01 M CaCl Electrical Conductivity Sodium Adsorption Ratio Saturation Chloride Calcium Potassium Magnesium Sodium Particle Size (> 75 µm) 75 (> Size Particle Sulphate Benzene Toluene Ethylbenzene Xylenes (o,m & p) Total Extractable Hydrocarbons - (C11 C22) Total Extractable Hydrocarbons - (C23 C60) (%) (%) (units) (dS/m) (units) (%) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) A A A A Agricultural Land Use - - 6 - 8 2 5 ------0.5, 5 3, 30 5, 50 5, 50 1,000 4,000 Residential Land Use - - 6 - 8 2 5 ------0.5 3 5 5 1,000 1,000 SPIGEC Forest Land Use - - 4 - 7 2 5 ------5 30 50 50 1,000 4,000 Subsoil - - 6 - 8 8 2 ------5 30 50 50 1,000 4,000 Background B1 0.0 - 0.15 August 6, 2014 - - 6.79 0.89 0.80 54.0 73 62.2 18.3 22 28.7 91.2 ------0.15 - 0.30 August 6, 2014 - - 6.94 1.02 0.76 51.3 41 78.8 10.7 56.9 36.3 273 ------0.30 - 0.50 August 6, 2014 - - 7.50 0.843 1.55 46.7 51 36.4 5.3 25.8 50 106 ------0.50 - 1.0 August 6, 2014 - - 7.73 0.924 3.70 54.7 36 26.4 6 24.8 110 247 ------B2 0.0 - 0.15 August 6, 2014 - - 6.95 0.929 0.49 58.7 <20 101 14 40.7 22.9 247 ------0.15 - 0.30 August 6, 2014 - - 6.71 0.78 0.60 48.7 <20 65.7 5.8 25.4 22.5 147 ------0.30 - 0.50 August 6, 2014 - - 6.74 0.85 0.83 43.3 <20 60.7 6.7 26.1 30.7 149 ------0.50 - 1.0 August 6, 2014 - - 7.09 0.54 0.67 37.3 <20 38.3 <5.0 25.2 21.8 158 ------Sampling After Initial Scrape #1 0.5 August 6, 2014 - - 8.12 2.80 14.2 60.7 662 29.2 10.3 18.8 401 290 ------#4 0.4 August 6, 2014 - - 7.88 1.50 1.66 50.0 253 23.6 <5.0 97.5 82 255 ------#6 0.4 August 6, 2014 - - 7.65 5.76 5.09 48.7 1,970 298 18.7 277 508 172 ------#11 0.15 August 6, 2014 - - 7.98 13.6 30.9 47.3 5,320 187 13.9 204 2,560 512 ------#13 0.3 August 6, 2014 - - 8.10 5.20 32.6 55.3 1,430 63.9 19.6 34.6 1,300 261 ------#16 0.15 August 6, 2014 - - 8.01 30.4 44.5 59.3 13,900 445 40 905 7,120 1,420 ------#18 0.15 August 6, 2014 - - 7.54 3.84 4.48 44.7 1,280 239 7.4 128 346 218 ------#22 0.15 August 6, 2014 - - 7.69 14.0 6.35 47.3 2,870 298 <10 614 834 535 ------#25 0.2 August 6, 2014 - - 7.66 9.63 17.9 27.3 3,360 286 13.1 167 1,540 318 ------#26 0.15 August 6, 2014 - - 7.63 4.57 7.29 54.0 1,330 84.5 <5.0 179 516 442 ------#28 0.15 August 6, 2014 - - 7.75 8.92 9.90 35.3 3,280 199 8.9 456 1,110 450 ------#32 0.15 August 6, 2014 - - 7.75 7.66 19.1 45.3 2,290 168 5.6 107 1,290 370 ------#36 0.3 August 6, 2014 - - 7.92 8.16 11.9 54.7 2,590 136 7.8 311 1,100 292 ------#40 0.15 August 6, 2014 - - 7.92 8.10 5.03 48.0 3,060 101 14 708 651 208 ------#48 0.3 August 6, 2014 - - 8.05 1.23 2.18 56.7 185 26.8 9.8 47.1 81 37 ------#49 0.15 August 6, 2014 - - 8.00 3.20 5.35 60.7 1,070 53.7 13.5 146 333 90 ------#50 0.15 August 6, 2014 - - 7.59 10.2 14.8 50.7 3,250 375 14.7 231 1,480 303 ------#52 0.15 August 6, 2014 - - 7.76 17.2 42.8 48.7 6,550 290 35 190 3,820 616 ------#54 0.15 August 6, 2014 - - 8.03 11.1 14.3 112 4,480 136 24.2 477 1,570 288 ------#55 0.15 August 6, 2014 - - 7.89 17.9 20.5 105 8,020 222 59 988 3,210 569 ------#57 0.2 August 6, 2014 - - 7.33 19.9 38.9 49.3 7,720 474 15 266 4,270 669 ------#59 0.15 August 6, 2014 - - 8.07 28.8 85.2 61.3 11,700 407 132 151 7,920 1,390 ------#60 0.15 August 6, 2014 - - 7.72 41.4 77.3 55.3 15,600 1,030 199 347 11,200 1,470 ------Sampling After Initial Excavation in Flowline Corridor E1 1.2 August 6, 2014 - - 7.84 6.46 6.71 50.0 2,280 152 34.1 356 663 103 ------E3 1.5 August 6, 2014 - - 8.05 17.6 24.7 56.7 7,310 266 32 723 3,430 676 ------E5 1.5 August 6, 2014 - - 7.68 18.6 23.7 44.7 7,850 598 21 618 3,450 571 ------E6 1.5 August 6, 2014 - - 8.00 13.6 15.9 53.3 5,280 164 17 633 2,010 348 ------E7 1.5 August 6, 2014 - - 7.95 11.6 13.1 52.7 3,240 151 17 568 1,570 264 ------E8 1.5 August 6, 2014 - - 7.86 18.0 24.6 54.7 7,310 327 42 638 3,320 549 ------E12 1.0 August 6, 2014 - - 7.85 18.5 18.9 55.3 8,000 345 17 977 3,030 468 ------E13 1.0 August 6, 2014 - - 7.97 18.9 26.0 58.7 8,090 337 26 729 3,710 596 ------E15 1.0 August 6, 2014 - - 7.71 11.4 8.62 36.7 3,940 477 24.6 708 1,270 303 ------1.2 August 6, 2014 - - 7.84 18.0 14.1 33.3 8,150 475 33 1,150 2,500 443 ------Confirmatory Samples Highlighted in Red. Sample Points were determined using the data obtained from the EM 38. Table 1. Soil Characterization - Salinity and Petroleum Hydrocarbon Parameters Harvest Operations Corp. 01-10-011-07 W2M File #: 8341-14E Lab Reports: 14C891146, L1499888, L1499945, L1553971, L1557855 and L1582196
Sample Description Physical Properties and Salinity (Soluble Parameters) Petroleum Hydrocarbons Volatile Extractable
Location Depth (m) Date ) 2 Moisture pH (in 0.01 M CaCl Electrical Conductivity Sodium Adsorption Ratio Saturation Chloride Calcium Potassium Magnesium Sodium Particle Size (> 75 µm) 75 (> Size Particle Sulphate Benzene Toluene Ethylbenzene Xylenes (o,m & p) Total Extractable Hydrocarbons - (C11 C22) Total Extractable Hydrocarbons - (C23 C60) (%) (%) (units) (dS/m) (units) (%) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) A A A A Agricultural Land Use - - 6 - 8 2 5 ------0.5, 5 3, 30 5, 50 5, 50 1,000 4,000 Residential Land Use - - 6 - 8 2 5 ------0.5 3 5 5 1,000 1,000 SPIGEC Forest Land Use - - 4 - 7 2 5 ------5 30 50 50 1,000 4,000 Subsoil - - 6 - 8 8 2 ------5 30 50 50 1,000 4,000 HA14-001 0.0 - 0.15 December 1, 2014 - - 7.85 24.5 31.7 53.0 9,160 346 42 638 4,300 900 ------Sampled in Pipeline 0.15 - 0.30 December 1, 2014 - - 7.87 15.1 20.0 48.0 5,240 273 24 447 2,300 849 ------Corridor 0.30 - 0.50 December 1, 2014 - - 7.76 13.8 17.8 53.0 4,640 228 17 428 1,970 635 ------HA14-002 0.0 - 0.15 December 1, 2014 - - 7.67 53.9 51.7 52.0 20,900 1,050 165 1,070 9,980 2,470 ------Sampled in Pipeline 0.15 - 0.30 December 1, 2014 - - 7.83 25.2 33.9 62.0 9,410 352 71 529 4,310 910 ------Corridor 0.30 - 0.50 December 1, 2014 - - 7.85 22.5 31.9 57.0 8,290 273 59 450 3,700 650 ------HA14-003 0.0 - 0.15 December 1, 2014 - - 8.04 9.24 13.6 52.0 2,970 134 43 299 1,240 557 ------0.0 - 0.30 December 12, 2014 - - 7.73 7.91 7.94 48.7 3,200 321 34.2 603 1,050 1,200 ------HA14-004 0.0 - 0.15 December 1, 2014 - - 7.69 28.2 21.1 48.0 10,300 344 36 1,240 3,750 510 ------0.15 - 0.30 December 1, 2014 - - 7.65 23.2 14.7 57.0 9,090 373 32 1,280 2,650 491 ------0.30 - 0.50 December 1, 2014 - - 7.72 13.1 7.40 66.0 4,820 262 18 824 1,080 177 ------0.0 - 0.30 December 12, 2014 - - 7.83 3.78 2.42 52.0 1,580 60 15.5 402 237 130 ------HA14-005 0.0 - 0.15 December 1, 2014 - - 8.24 6.69 12.3 54.0 2,090 56.0 <5.0 239 950 298 ------0.0 - 0.30 December 12, 2014 - - 7.79 4.55 14.2 44.0 1,760 83.8 14.3 115 855 178 ------HA14-006 0.0 - 0.15 December 1, 2014 - - 7.71 12.3 17.0 41.0 4,350 276 40 400 1,890 501 ------0.15 - 0.30 December 1, 2014 - - 7.78 8.12 14.2 41.0 2,610 154 30 212 1,160 324 ------0.0 - 0.30 December 12, 2014 - - 7.61 2.08 4.09 41.3 590 84.9 18.2 67.3 208 108 ------HA14-007 0.0 - 0.15 December 1, 2014 - - 8.10 5.94 2.91 45.0 1,860 64.0 <5.0 541 327 314 ------HA14-008 0.0 - 0.15 December 1, 2014 - - 7.76 8.36 7.78 27.0 2,650 251 <10 481 914 710 ------HA14-009 0.0 - 0.15 December 1, 2014 - - 7.41 37.9 23.8 49.0 15,300 842 22 1,730 5,240 1,280 ------0.15 - 0.30 December 1, 2014 - - 7.39 30.2 19.5 41.0 11,500 728 <20 1,480 3,990 1,170 ------0.30 - 0.50 December 1, 2014 - - 7.32 13.0 8.18 27.0 4,600 370 <10 718 1,170 436 ------February 25, 2015 - - 7.63 3.6 7.73 77.0 1,070 92 9.2 99 448 162 ------
SPIGEC - Saskatchewan Upstream Petroleum Site Remediation Guidelines (Saskatchewan Petroleum Industry/Government Environmental Committee, 2009) Salt remediation guidelines applied for EC and SAR are based on tolerant crops for EC and conditional use for SAR AMust monitor crop growth and yield for a minimum of 3 years " - " - No standard/not analyzed Particle size (>75 µm) <50% indicates fine-grained soil; >50% indicates coarse-grained soil Shading indicates values (excluding those in background samples) exceeding/outside of comparative guidelines Table 4. Soil Characterization - Landfill Suitability Harvest Operations Corp. 01-10-011-07 W2M File #: 8341-14E Lab Reports: L1488873 and 14C887923
Physical Sample Description Chemical Properties BTEX Leachable Metals Properties
Location Date Free Liquid Test Extraction) (1:1 pH Flashpoint Leachable Benzene Toluene Ethylbenzene Xylenes (Total) (Inorganic) Arsenic Barium Boron (Non-metal, Hot Water Soluble) Cadmium Chromium Lead (Inorganic) Mercury Selenium Uranium Pass/Fail (units) (°C) (mg/L) (mg/kg) (mg/kg) (mg/kg) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) Landfill Suitability Spill Area Comp July 16, 2014 Pass 8.02 >75 <0.0050 <0.050 <0.015 0.1 <0.20 <5.0 <5.0 <0.050 <0.50 <0.50 - <0.20 <1.0 Landfill 05-05-008-09 W2 September 11, 2014 Pass 7.61 >100 0.005 4.57 2.31 12.6 <0.5 1 <0.5 <0.5 <0.5 <0.5 <0.1 <0.5 <0.5
" - " - Not analyzed APPENDIX A Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 1. Viewing indicator sign and entrance off grid
Photo 2. View of where emulsion came to surface
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 8, 2014 Page 1 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 3. Viewing spill pathway running east towards small wet slough
Photo 4. Viewing spill pathway running south towards large wet slough
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 8, 2014 Page 2 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 5. Viewing spill pathway heading south towards large wet slough
Photo 6. Viewing spill pathway heading south towards large wet slough
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 8, 2014 Page 3 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 7. Viewing edge of large wet slough facing west.
Photo 8. Viewing spill pathway heading towards small wet slough
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 8, 2014 Page 4 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 9. Viewing small wet slough facing east
Photo 10. Viewing hydrocarbons on the water in the small wet slough
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 8, 2014 Page 5 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 11. Viewing spill area facing north from south side of large wet slough
Photo 12. Viewing south at water sampling activities
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 9, 2014 Page 6 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 13. Viewing east at intial scrape of spill area by waters edge north of large wet slough
Photo 14. Viewing south east at intial scrape of contaminated soil north of large wet slough
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 10, 2014 Page 7 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 15. Viewing west after intial scrape of contaminated soil north of large wet slough
Photo 16 Viewing north west at intitial scraping of soil from north of large wet slough
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 10, 2014 Page 8 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 17. Viewing south after intial scrape of spill area down the west spill pathway
Photo 18. Viewing south after intial scrape of spill area down the east spill pathway
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 10, 2014 Page 9 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 19. Viewing east from well site at matting being delivered
Photo 20. Viewing west at hydrovacs exposing the flowline corridor on matted access
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 16, 2014 Page 10 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 21. Viewing south west at excavators completing intial scrape north of large wet slough
Photo 22. Viewing south east at hydrovacs dumping into temporary berm on matted access
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 16, 2014 Page 11 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 23. Viewing east at the north line of three (ruptured line).
Photo 24. Viewing east towards small wet slough after intital scrape
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 16, 2014 Page 12 of 13 Harvest Operations 01-10-011-07 W2M 2014 Initial Spill Response
Photo 25. Viewing south east at hydrovacs dumping into temporary berm
Photo 26. Viewing north at western most point of daylighted flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: July 16, 2014 Page 13 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 1. Viewing south at excvation from north of the flowline corridor
Photo 2. Viewing south west at excavation from north east of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 22, 2014 Page 1 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 3. Viewing south at excavation from south of flowline corridor
Photo 4. Viewing west at sampling grid within the excavation
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 22, 2014 Page 2 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 5. Viewing west at flowline corridor as the southern most flowline is being uncovered
Photo 6. Viewing east at flowline corridor as southern most flowline is being uncovered
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 23, 2014 Page 3 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 7. Viewing south east at southern most flowline being uncovered
Photo 8. Viewing west at excavation of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 23, 2014 Page 4 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 9. Viewing west at flowline corridor
Photo 10. Viewing south at flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 23, 2014 Page 5 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 11. Viewing south east at excavation of flowline corridor
Photo 12. Viewing west at excavation of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 23, 2014 Page 6 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 13. Viewing west at excavation from south of flowline corridor
Photo 14. Viewing east at excavation from south of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 24, 2014 Page 7 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 15. Viewing south at excavation from south of flowline corridor
Photo 16. Viewing north east at excavation from south of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 24, 2014 Page 8 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 17. Viewing north at excavation from south of flowline corridor
Photo 18. Viewing west from north of flowline corridor at excavation of "hotspots"
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Sept. 24 and Dec. 9, 2014 Page 9 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 19. Viewing south west at excavation of "hotspots"
Photo 20. Viewing east from south of flowline corridor at excavation of "hotspots"
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date:Dec. 9, 2014 Page 10 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 21. Viewing north west at excavation of "hotspots" south of flowline corridor
Photo 22. Viewing south west at excavation of "hotspots" south of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Dec. 9, 2014 Page 11 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 19. Viewing south south at excavation of "hotspots" south of flowline corridor
Photo 20. Viewing south west at excavation of "hotspots" south of flowline corridor
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Dec. 10, 2014 Page 12 of 13 Harvest Operations 01-10-011-07 W2M 2014 Excavation
Photo 19. Viewing south at excavation of "hotspots" from north of large wet slough
Photo 20. Viewing south west at finished excavation from north eastern boundary of spill area
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Dec. 10, 2014 Page 13 of 13 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 1. Viewing snow removal from with the excavations
Photo 2. Viewing snow removal from with the excvations
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Feb. 25, 2015 Page 1 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 3. Viewing south excavation after the snow has been removed.
Photo 4. Viewing west at flowline corridor after the snow has been removed
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 9 & 10, 2015 Page 2 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 5. Viewing west at flowline corridor after the snow has been removed
Photo 6. Viewing south west at flowline corridor during sand padding of lines
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 10, 2015 Page 3 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 7. View of sand padding of lines
Photo 8. Viewing west at completed sand padding of lines
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 10, 2015 Page 4 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 9. Viewing south at excavation being backfilled
Photo 10. Viewing south at backfilled excavation
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 10, 2015 Page 5 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 11. Viewing excavation being backfilled
Photo 12. Viewing south at backfilling of excavation
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 10 & 11, 2015 Page 6 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 13. Viewing south at backfilled excavation
Photo 14. Viewing south at backfilled excavation
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 11, 2015 Page 7 of 8 Harvest Operations 01-10-011-07 W2M 2015 Backfill
Photo 15. Viewing south at backfilled excavation
Photo 16. Viewing south at backfilled excavation
Client:
2014 Spill Response HARVEST OPERATIONS Consultant: 01-10-011-07 W2M Vertex Professional Services Ltd.
Photo Date: Mar. 11, 2015 Page 8 of 8 APPENDIX B VERTEX PROFESSIONAL SERVICES Date Received: 11-AUG-14 GROUP Report Date: 17-AUG-14 19:15 (MT) ATTN: KRISTOPHER BOYES Version: FINAL 418B McDONALD STREET REGINA SK . Client Phone: 306-485-8117
Certificate of Analysis Lab Work Order #: L1499888 Project P.O. #: NOT SUBMITTED Job Reference: 8341-14E C of C Numbers: Legal Site Desc: 01-10-011-07 W2M
______Nelson Kwan Account Manager [This report shall not be reproduced except in full without the written authority of the Laboratory.]
ADDRESS: 2559 29 Street NE, Calgary, AB T1Y 7B5 Canada | Phone: +1 403 291 9897 | Fax: +1 403 291 0298 ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company 8341-14E L1499888 CONTD.... PAGE 2 of 3 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1499888-1 #6 0.4M Sampled By: KRIS BOYES on 06-AUG-14 @ 12:00 Matrix: SOIL
Detailed Salinity % Saturation % Saturation 48.7 1.0 % 15-AUG-14 R2920586 Ca,K,Mg,Na in Soil (Paste) by ICPOES Calcium (Ca) 298 5.0 mg/L 15-AUG-14 R2920327 Magnesium (Mg) 277 5.0 mg/L 15-AUG-14 R2920327 Potassium (K) 18.7 5.0 mg/L 15-AUG-14 R2920327 Sodium (Na) 508 5.0 mg/L 15-AUG-14 R2920327 Chloride in Soil (Paste) by Colorimetry Chloride (Cl) 1970 20 mg/L 15-AUG-14 R2920922 Conductivity in Soil (Paste) by Meter Conductivity Sat. Paste 5.76 0.030 dS/m 15-AUG-14 R2920586 Salinity in mg/kg Chloride (Cl) 959 9.7 mg/kg 17-AUG-14 Calcium (Ca) 145 2.4 mg/kg 17-AUG-14 Magnesium (Mg) 135 2.4 mg/kg 17-AUG-14 Potassium (K) 9.1 2.4 mg/kg 17-AUG-14 Sodium (Na) 247 2.4 mg/kg 17-AUG-14 Sulfur (as SO4) 83.8 2.9 mg/kg 17-AUG-14 Sodium Adsorption Ratio SAR 5.09 0.10 SAR 15-AUG-14 Sulphate (SO4) Sulfur (as SO4) 172 6.0 mg/L 15-AUG-14 R2920327 pH (1:2 CaCl2) pH (1:2 CaCl2) 7.65 0.10 pH 14-AUG-14 R2918466
* Refer to Referenced Information for Qualifiers (if any) and Methodology. 8341-14E L1499888 CONTD.... PAGE 3 of 3 Reference Information Version: FINAL
Qualifiers for Sample Submission Listed: Qualifier Description
EXTEMP 19C - Samples Received with temperature >15 Degrees C
Test Method References: ALS Test Code Matrix Test Description Method Reference**
CL-PASTE-COL-CL Soil Chloride in Soil (Paste) by Colorimetry CSSS, APHA 4500-Cl E A soil extract produced by the saturated paste extraction procedure is analyzed for Chloride by Colourimetry.
EC-PASTE-CL Soil Conductivity in Soil (Paste) by Meter CSSS 18.3.1 This analysis is adapted from the methods outlined in "Soil Sampling and Methods of Analysis" by M. Carter. In summary, 200 to 500 grams of sample is extracted for a minimum of 4 hours with an amount of deionized water as required to create a saturated paste. The sample is then filtered or centrifuged and decanted to produce an extract that is ready for analysis. This analysis is carried out using procedures adapted from APHA Method 2510 "Conductivity". Conductivity is determined using a conductivity electrode. MET-PASTE-ICP-CL Soil Ca,K,Mg,Na in Soil (Paste) by ICPOES CSSS CH15/EPA 6010B A soil extract produced by the saturated paste extraction procedure is analyzed for Calcium, Magnesium, Potassium, Sodium by ICPOES.
PH-1:2 CACL2-CL Soil pH (1:2 CaCl2) CSSS 16.3 - 1:2 Extraction w/0.01M CaCl2 SAL-MG/KG-CALC-CL Soil Salinity in mg/kg Manual Calculation SALINITY-INTCHECK-CL Soil CSSS 18.4-Calculation SAR-PASTE-CALC-CL Soil Sodium Adsorption Ratio CSSS 15.4.4-Calculation Sodium Adsorption Ratio (SAR) is calculated as per "Soil Sampling and Methods of Analysis" by M. Carter.
SAT-PCNT-CL Soil % Saturation CSSS 18.2-Calculation SO4-PASTE-ICP-CL Soil Sulphate (SO4) Carter-CSSS / EPA 300.1 (modified) A soil extract produced by the saturated extraction procedure is analyzed for sulfate by ICPOES.
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location CL ALS ENVIRONMENTAL - CALGARY, ALBERTA, CANADA
Chain of Custody Numbers:
GLOSSARY OF REPORT TERMS Surrogates are compounds that are similar in behaviour to target analyte(s), but that do not normally occur in environmental samples. For applicable tests, surrogates are added to samples prior to analysis as a check on recovery. In reports that display the D.L. column, laboratory objectives for surrogates are listed there. mg/kg - milligrams per kilogram based on dry weight of sample mg/kg wwt - milligrams per kilogram based on wet weight of sample mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight mg/L - unit of concentration based on volume, parts per million. < - Less than. D.L. - The reporting limit. N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory. UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION. Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review. Quality Control Report
Workorder: L1499888 Report Date: 17-AUG-14 Page 1 of 3
Client: VERTEX PROFESSIONAL SERVICES GROUP 418B McDONALD STREET REGINA SK . Contact: KRISTOPHER BOYES Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
CL-PASTE-COL-CL Soil Batch R2920922 WG1932425-11 IRM ED-SAL_NAT1 Chloride (Cl) 96.9 % 70-130 15-AUG-14 WG1932425-15 IRM ED-SAL_NAT1 Chloride (Cl) 93.6 % 70-130 15-AUG-14 WG1932425-19 IRM ED-SAL_NAT1 Chloride (Cl) 98.6 % 70-130 15-AUG-14 WG1932425-7 IRM ED-SAL_NAT1 Chloride (Cl) 98.6 % 70-130 15-AUG-14 WG1932425-13 LCS Chloride (Cl) 99.5 % 70-130 15-AUG-14 WG1932425-17 LCS Chloride (Cl) 98.2 % 70-130 15-AUG-14 WG1932425-5 LCS Chloride (Cl) 103.9 % 70-130 15-AUG-14 WG1932425-9 LCS Chloride (Cl) 103.8 % 70-130 15-AUG-14 WG1932425-1 MB Chloride (Cl) <20 mg/L 20 15-AUG-14 WG1932425-2 MB Chloride (Cl) <20 mg/L 20 15-AUG-14 WG1932425-3 MB Chloride (Cl) <20 mg/L 20 15-AUG-14 WG1932425-4 MB Chloride (Cl) <20 mg/L 20 15-AUG-14 WG1932425-12 MS L1499945-6 Chloride (Cl) 123.0 % 60-140 15-AUG-14 WG1932425-16 MS L1500685-5 Chloride (Cl) 118.7 % 60-140 15-AUG-14 WG1932425-20 MS L1502891-1 Chloride (Cl) 117.9 % 60-140 16-AUG-14 WG1932425-8 MS L1499945-5 Chloride (Cl) 98.1 % 60-140 15-AUG-14
EC-PASTE-CL Soil Batch R2920586 WG1932153-3 IRM ED-SAL_NAT1 Conductivity Sat. Paste 93.8 % 70-130 15-AUG-14 WG1932153-1 MB Conductivity Sat. Paste <0.030 dS/m 0.03 15-AUG-14 Quality Control Report
Workorder: L1499888 Report Date: 17-AUG-14 Page 2 of 3
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-PASTE-ICP-CL Soil Batch R2920327 WG1931933-2 IRM ED-SAL_NAT1 Calcium (Ca) 91.0 % 70-130 15-AUG-14 Magnesium (Mg) 88.3 % 70-130 15-AUG-14 Potassium (K) 95.1 % 70-130 15-AUG-14 Sodium (Na) 95.9 % 70-130 15-AUG-14 WG1931933-1 MB Calcium (Ca) <5.0 mg/L 5 15-AUG-14 Magnesium (Mg) <5.0 mg/L 5 15-AUG-14 Potassium (K) <5.0 mg/L 5 15-AUG-14 Sodium (Na) <5.0 mg/L 5 15-AUG-14
PH-1:2 CACL2-CL Soil Batch R2918466 WG1931072-1 IRM ED-SAL_NAT1 pH (1:2 CaCl2) 6.57 pH 6.36-6.96 14-AUG-14
SAT-PCNT-CL Soil Batch R2920586 WG1932153-3 IRM ED-SAL_NAT1 % Saturation 101.6 % 80-120 15-AUG-14
SO4-PASTE-ICP-CL Soil Batch R2920327 WG1931933-1 MB Sulfur (as SO4) <6.0 mg/L 6 15-AUG-14 Quality Control Report
Workorder: L1499888 Report Date: 17-AUG-14 Page 3 of 3
Legend: Limit ALS Control Limit (Data Quality Objectives) DUP Duplicate RPD Relative Percent Difference N/A Not Available LCS Laboratory Control Sample SRM Standard Reference Material MS Matrix Spike MSD Matrix Spike Duplicate ADE Average Desorption Efficiency MB Method Blank IRM Internal Reference Material CRM Certified Reference Material CCV Continuing Calibration Verification CVS Calibration Verification Standard LCSD Laboratory Control Sample Duplicate
Sample Parameter Qualifier Definitions: Qualifier Description J Duplicate results and limits are expressed in terms of absolute difference. RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.
Hold Time Exceedances: All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre- determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
VERTEX PROFESSIONAL SERVICES Date Received: 03-DEC-14 GROUP Report Date: 04-DEC-14 14:51 (MT) ATTN: KAYLEE MATISHO Version: FINAL #24-12TH STREET WEYBURN SK S4H 1K2 Client Phone: 306-861-7498
Certificate of Analysis Lab Work Order #: L1553971 Project P.O. #: NOT SUBMITTED Job Reference: HARVEST 01-10-011-07W2M C of C Numbers: Legal Site Desc: 111/01-10-011-07W2M
______Brian Morgan Account Manager [This report shall not be reproduced except in full without the written authority of the Laboratory.]
ADDRESS: #819-58th St E., Saskatoon, SK S7K 6X5 Canada | Phone: +1 306 668 8370 | Fax: +1 306 668 8383 ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 2 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-1 HA14-001, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 9160 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 4860 DLA 53 mg/kg 04-DEC-14 Calcium (Ca) 183 DLA 21 mg/kg 04-DEC-14 Magnesium (Mg) 338 DLA 21 mg/kg 04-DEC-14 Potassium (K) 22 DLA 11 mg/kg 04-DEC-14 Sodium (Na) 2280 DLA 42 mg/kg 04-DEC-14 Sulfur (as SO4) 479 DLA 53 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 346 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 42 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 638 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 4300 DLA 80 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 31.7 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 900 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 11.1 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 53.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.85 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 24.5 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-2 HA14-001, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 5240 DLA 60 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 2520 DLA 29 mg/kg 04-DEC-14 Calcium (Ca) 131 DLA 9.6 mg/kg 04-DEC-14 Magnesium (Mg) 215 DLA 9.6 mg/kg 04-DEC-14 Potassium (K) 11.6 DLA 4.8 mg/kg 04-DEC-14 Sodium (Na) 1110 DLA 19 mg/kg 04-DEC-14 Sulfur (as SO4) 407 DLA 24 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 273 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 24 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 447 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 2300 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 20.0 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 849 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 28.9 0.10 t/ha 04-DEC-14 TGR(sodic) 6.06 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 48.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.87 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 15.1 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 3 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-2 HA14-001, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL L1553971-3 HA14-001, 0.30-0.50M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 4640 DLA 60 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 2460 DLA 32 mg/kg 04-DEC-14 Calcium (Ca) 121 DLA 11 mg/kg 04-DEC-14 Magnesium (Mg) 227 DLA 11 mg/kg 04-DEC-14 Potassium (K) 9.1 DLA 5.3 mg/kg 04-DEC-14 Sodium (Na) 1040 DLA 21 mg/kg 04-DEC-14 Sulfur (as SO4) 336 DLA 27 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 228 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 17 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 428 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 1970 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 17.8 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 635 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 22.5 0.10 t/ha 04-DEC-14 TGR(sodic) 5.72 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 53.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.76 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 13.8 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-4 HA14-002, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 20900 DLA 400 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 10900 DLA 210 mg/kg 04-DEC-14 Calcium (Ca) 547 DLA 52 mg/kg 04-DEC-14 Magnesium (Mg) 558 DLA 52 mg/kg 04-DEC-14 Potassium (K) 86 DLA 26 mg/kg 04-DEC-14 Sodium (Na) 5190 DLA 100 mg/kg 04-DEC-14 Sulfur (as SO4) 1290 DLA 130 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 1050 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 165 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 1070 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 9980 DLA 200 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 51.7 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 2470 DLA 250 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 16.4 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) * Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 4 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-4 HA14-002, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL pH and EC (Saturated Paste) % Saturation 52.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.67 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 53.9 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-5 HA14-002, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 9410 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 5830 DLA 62 mg/kg 04-DEC-14 Calcium (Ca) 218 DLA 25 mg/kg 04-DEC-14 Magnesium (Mg) 328 DLA 25 mg/kg 04-DEC-14 Potassium (K) 44 DLA 12 mg/kg 04-DEC-14 Sodium (Na) 2670 DLA 50 mg/kg 04-DEC-14 Sulfur (as SO4) 564 DLA 62 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 352 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 71 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 529 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 4310 DLA 80 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 33.9 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 910 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 13.9 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 62.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.83 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 25.2 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-6 HA14-002, 0-0.30-0.50M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 8290 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 4730 DLA 57 mg/kg 04-DEC-14 Calcium (Ca) 156 DLA 23 mg/kg 04-DEC-14 Magnesium (Mg) 256 DLA 23 mg/kg 04-DEC-14 Potassium (K) 34 DLA 11 mg/kg 04-DEC-14 Sodium (Na) 2110 DLA 46 mg/kg 04-DEC-14 Sulfur (as SO4) 372 DLA 57 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 273 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 59 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 450 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 3700 DLA 80 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 31.9 0.10 SAR 04-DEC-14 04-DEC-14 R3115126
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 5 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-6 HA14-002, 0-0.30-0.50M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL SAR, Cations and SO4 in saturated soil Sulfur (as SO4) 650 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 12.1 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 57.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.85 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 22.5 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-7 HA14-003, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 2970 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 1540 DLA 21 mg/kg 04-DEC-14 Calcium (Ca) 70 DLA 10 mg/kg 04-DEC-14 Magnesium (Mg) 155 DLA 10 mg/kg 04-DEC-14 Potassium (K) 22.4 DLA 5.2 mg/kg 04-DEC-14 Sodium (Na) 645 DLA 21 mg/kg 04-DEC-14 Sulfur (as SO4) 290 DLA 26 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 134 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 43 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 299 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 1240 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 13.6 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 557 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 7.61 0.10 t/ha 04-DEC-14 TGR(sodic) 3.69 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 52.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 8.04 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 9.24 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-8 HA14-004, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 10300 DLA 500 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 4950 DLA 240 mg/kg 04-DEC-14 Calcium (Ca) 165 DLA 19 mg/kg 04-DEC-14 Magnesium (Mg) 597 DLA 19 mg/kg 04-DEC-14 Potassium (K) 17.1 DLA 9.6 mg/kg 04-DEC-14 Sodium (Na) 1800 DLA 38 mg/kg 04-DEC-14 Sulfur (as SO4) 244 DLA 48 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 6 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-8 HA14-004, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL SAR, Cations and SO4 in saturated soil Calcium (Ca) 344 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 36 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 1240 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 3750 DLA 80 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 21.1 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 510 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 6.50 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 48.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.69 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 28.2 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-9 HA14-004, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 9090 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 5180 DLA 57 mg/kg 04-DEC-14 Calcium (Ca) 213 DLA 11 mg/kg 04-DEC-14 Magnesium (Mg) 728 DLA 11 mg/kg 04-DEC-14 Potassium (K) 18.3 DLA 5.7 mg/kg 04-DEC-14 Sodium (Na) 1510 DLA 23 mg/kg 04-DEC-14 Sulfur (as SO4) 280 DLA 29 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 373 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 32 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 1280 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 2650 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 14.7 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 491 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 40.0 0.10 t/ha 04-DEC-14 TGR(sodic) 4.59 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 57.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.65 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 23.2 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-10 HA14-004, 0.30-0.50M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 4820 DLA 60 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 3180 DLA 40 mg/kg 04-DEC-14 Calcium (Ca) 173 DLA 13 mg/kg 04-DEC-14
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 7 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-10 HA14-004, 0.30-0.50M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL Detail Salinity in mg/kg Magnesium (Mg) 544 DLA 13 mg/kg 04-DEC-14 Potassium (K) 11.8 DLA 6.6 mg/kg 04-DEC-14 Sodium (Na) 714 DLA 26 mg/kg 04-DEC-14 Sulfur (as SO4) 117 DLA 33 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 262 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 18 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 824 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 1080 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 7.40 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 177 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 1.06 0.10 t/ha 04-DEC-14 TGR(sodic) 0.48 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 66.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.72 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 13.1 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-11 HA14-005, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 2090 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 1130 DLA 54 mg/kg 04-DEC-14 Calcium (Ca) 30.3 DLA 5.4 mg/kg 04-DEC-14 Magnesium (Mg) 129 DLA 5.4 mg/kg 04-DEC-14 Potassium (K) <2.7 DLA 2.7 mg/kg 04-DEC-14 Sodium (Na) 513 DLA 11 mg/kg 04-DEC-14 Sulfur (as SO4) 161 DLA 14 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 56 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) <5.0 DLA 5.0 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 239 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 950 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 12.3 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 298 DLA 25 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 4.27 0.10 t/ha 04-DEC-14 TGR(sodic) 3.16 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 54.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 8.24 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 6.69 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-12 HA14-006, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 8 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-12 HA14-006, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL Chloride (Cl) (Saturated Paste) Chloride (Cl) 4350 DLA 60 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 1780 DLA 25 mg/kg 04-DEC-14 Calcium (Ca) 113 DLA 8.2 mg/kg 04-DEC-14 Magnesium (Mg) 164 DLA 8.2 mg/kg 04-DEC-14 Potassium (K) 16.4 DLA 4.1 mg/kg 04-DEC-14 Sodium (Na) 774 DLA 16 mg/kg 04-DEC-14 Sulfur (as SO4) 205 DLA 21 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 276 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 40 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 400 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 1890 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 17.0 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 501 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 15.7 0.10 t/ha 04-DEC-14 TGR(sodic) 4.16 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 41.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.71 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 12.3 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-13 HA14-006, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 2610 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 1070 DLA 16 mg/kg 04-DEC-14 Calcium (Ca) 63.0 DLA 8.2 mg/kg 04-DEC-14 Magnesium (Mg) 86.9 DLA 8.2 mg/kg 04-DEC-14 Potassium (K) 12.5 DLA 4.1 mg/kg 04-DEC-14 Sodium (Na) 475 DLA 16 mg/kg 04-DEC-14 Sulfur (as SO4) 133 DLA 21 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 154 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 30 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 212 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 1160 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 14.2 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 324 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 5.41 0.10 t/ha 04-DEC-14 TGR(sodic) 3.14 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 41.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.78 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 8.12 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 9 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-14 HA14-007, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 1860 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 837 DLA 9.0 mg/kg 04-DEC-14 Calcium (Ca) 28.8 DLA 4.5 mg/kg 04-DEC-14 Magnesium (Mg) 243 DLA 4.5 mg/kg 04-DEC-14 Potassium (K) <2.3 DLA 2.3 mg/kg 04-DEC-14 Sodium (Na) 147 DLA 9.0 mg/kg 04-DEC-14 Sulfur (as SO4) 141 DLA 11 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 64 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) <5.0 DLA 5.0 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 541 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 327 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 2.91 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 314 DLA 25 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) <0.10 0.10 t/ha 04-DEC-14 TGR(sodic) <0.10 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 45.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 8.10 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 5.94 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-15 HA14-008, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 2650 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 716 DLA 11 mg/kg 04-DEC-14 Calcium (Ca) 67.9 DLA 5.4 mg/kg 04-DEC-14 Magnesium (Mg) 130 DLA 5.4 mg/kg 04-DEC-14 Potassium (K) <2.7 DLA 2.7 mg/kg 04-DEC-14 Sodium (Na) 247 DLA 11 mg/kg 04-DEC-14 Sulfur (as SO4) 192 DLA 14 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 251 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) <10 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 481 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 914 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 7.78 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 710 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 0.56 0.10 t/ha 04-DEC-14 TGR(sodic) 0.31 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 27.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.76 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 8.36 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 10 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-15 HA14-008, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL L1553971-16 HA14-009, 0-0.15M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 15300 DLA 200 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 7500 DLA 98 mg/kg 04-DEC-14 Calcium (Ca) 413 DLA 20 mg/kg 04-DEC-14 Magnesium (Mg) 847 DLA 20 mg/kg 04-DEC-14 Potassium (K) 10.9 DLA 9.8 mg/kg 04-DEC-14 Sodium (Na) 2570 DLA 39 mg/kg 04-DEC-14 Sulfur (as SO4) 629 DLA 49 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 842 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) 22 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 1730 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 5240 DLA 80 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 23.8 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 1280 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 7.63 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 49.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.41 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 37.9 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-17 HA14-009, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 11500 DLA 200 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 4710 DLA 82 mg/kg 04-DEC-14 Calcium (Ca) 298 DLA 16 mg/kg 04-DEC-14 Magnesium (Mg) 608 DLA 16 mg/kg 04-DEC-14 Potassium (K) <8.2 DLA 8.2 mg/kg 04-DEC-14 Sodium (Na) 1630 DLA 33 mg/kg 04-DEC-14 Sulfur (as SO4) 480 DLA 41 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 728 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) <20 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 1480 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 3990 DLA 80 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 19.5 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 1170 DLA 100 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) >50 0.10 t/ha 04-DEC-14 TGR(sodic) 5.02 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) * Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 11 of 12 Version: FINAL ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1553971-17 HA14-009, 0.15-0.30M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL pH and EC (Saturated Paste) % Saturation 41.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.39 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 30.2 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945 L1553971-18 HA14-009, 0.30-0.50M Sampled By: KAYLEE MATISHO on 01-DEC-14 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 4600 DLA 60 mg/L 04-DEC-14 04-DEC-14 R3115071 Detail Salinity in mg/kg Chloride (Cl) 1240 DLA 16 mg/kg 04-DEC-14 Calcium (Ca) 99.9 DLA 5.4 mg/kg 04-DEC-14 Magnesium (Mg) 194 DLA 5.4 mg/kg 04-DEC-14 Potassium (K) <2.7 DLA 2.7 mg/kg 04-DEC-14 Sodium (Na) 316 DLA 11 mg/kg 04-DEC-14 Sulfur (as SO4) 118 DLA 14 mg/kg 04-DEC-14 SAR, Cations and SO4 in saturated soil Calcium (Ca) 370 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Potassium (K) <10 DLA 10 mg/L 04-DEC-14 04-DEC-14 R3115126 Magnesium (Mg) 718 DLA 20 mg/L 04-DEC-14 04-DEC-14 R3115126 Sodium (Na) 1170 DLA 40 mg/L 04-DEC-14 04-DEC-14 R3115126 SAR 8.18 0.10 SAR 04-DEC-14 04-DEC-14 R3115126 Sulfur (as SO4) 436 DLA 50 mg/L 04-DEC-14 04-DEC-14 R3115126 Theoretical Gypsum Requirement TGR(brine) 1.28 0.10 t/ha 04-DEC-14 TGR(sodic) 0.43 0.10 t/ha 04-DEC-14 pH and EC (Saturated Paste) % Saturation 27.0 1.0 % 03-DEC-14 04-DEC-14 R3114945 pH in Saturated Paste 7.32 0.10 pH 03-DEC-14 04-DEC-14 R3114945 Conductivity Sat. Paste 13.0 0.10 dS m-1 03-DEC-14 04-DEC-14 R3114945
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1553971 CONTD.... PAGE 12 of 12 Reference Information Version: FINAL
Sample Parameter Qualifier Key: Qualifier Description
DLA Detection Limit adjusted for required dilution
Test Method References: ALS Test Code Matrix Test Description Method Reference**
CL-PASTE-COL-SK Soil Chloride (Cl) (Saturated Paste) CSSS(1993) 18.2.2/APHA 4500-CL E Chloride in a saturated soil extract is determined colorimetrically by auto-analyzer.
SAL-MG/KG-CALC-SK Soil Detail Salinity in mg/kg Manual Calculation SALINITY-INTCHECK-SK Soil CSSS 18.4-Calculation SAR-CALC-SO4-SK Soil SAR, Cations and SO4 in saturated soil APHA 3120B Ca, Mg, Na, K and SO4 in a saturated soil extract are determined by ICP-OES.
SAT/PH/EC-SK Soil pH and EC (Saturated Paste) CSSS 18.2.2/CSSC 3.14/CSSS 18.3.1 pH of a saturated soil paste is measured using a pH meter. After equilibration, an extract is obtained by vacuum filtration with conductivity of the extract measured by a conductivity meter. TGR2-CALC-SK Soil Theoretical Gypsum Requirement J. Ashworth et al (1999) Theoretical Gypsum Requirement is an estimate of the gypsum amendment required to remediate brine-contaminated or sodic soils, and is provided in units of tonnes per hectare (t/ha) for a treatment depth of 15cm. TGR(brine), intended for brine-contaminated soils, is calculated using Method A from "A Comparison of Methods for Gypsum Requirement of Brine-Contaminated Soils", by J. Ashworth (Cdn J. of Soil Science, 1999), available at www.alsglobal.com. TGR(sodic), intended for naturally sodic soils, uses the Oster and Frenkel method (Method B) from the same paper. Reported TGR values are capped at 50 t/ha, considered the maximum practical gypsum amendment. To convert TGR from t/ha to tons/acre, multiply by 0.446. To determine a TGR value for an alternate treatment depth, multiply by [desired treatment depth (cm) / 15 cm].
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location SK ALS ENVIRONMENTAL - SASKATOON, SASKATCHEWAN, CANADA
Chain of Custody Numbers:
GLOSSARY OF REPORT TERMS Surrogates are compounds that are similar in behaviour to target analyte(s), but that do not normally occur in environmental samples. For applicable tests, surrogates are added to samples prior to analysis as a check on recovery. In reports that display the D.L. column, laboratory objectives for surrogates are listed there. mg/kg - milligrams per kilogram based on dry weight of sample mg/kg wwt - milligrams per kilogram based on wet weight of sample mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight mg/L - unit of concentration based on volume, parts per million. < - Less than. D.L. - The reporting limit. N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory. UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION. Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review. Quality Control Report
Workorder: L1553971 Report Date: 04-DEC-14 Page 1 of 2
Client: VERTEX PROFESSIONAL SERVICES GROUP #24-12TH STREET WEYBURN SK S4H 1K2 Contact: KAYLEE MATISHO Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
CL-PASTE-COL-SK Soil Batch R3115071 WG2007655-2 IRM SAL814 Chloride (Cl) 101.7 % 70-130 04-DEC-14 WG2007655-1 MB Chloride (Cl) <5.0 mg/L 5 04-DEC-14
SAR-CALC-SO4-SK Soil Batch R3115126 WG2007655-2 IRM SAL814 Calcium (Ca) 106.2 % 70-130 04-DEC-14 Potassium (K) 98.9 % 70-130 04-DEC-14 Magnesium (Mg) 110.7 % 70-130 04-DEC-14 Sodium (Na) 101.3 % 70-130 04-DEC-14 Sulfur (as SO4) 107.4 % 70-130 04-DEC-14 WG2007655-1 MB Calcium (Ca) <2.0 mg/L 2 04-DEC-14 Potassium (K) <1.0 mg/L 1 04-DEC-14 Magnesium (Mg) <2.0 mg/L 2 04-DEC-14 Sodium (Na) <4.0 mg/L 4 04-DEC-14 Sulfur (as SO4) <5.0 mg/L 5 04-DEC-14
SAT/PH/EC-SK Soil Batch R3114945 WG2007655-2 IRM SAL814 % Saturation 46.0 % 37-47 04-DEC-14 pH in Saturated Paste 7.82 pH 7.4-8 04-DEC-14 Conductivity Sat. Paste 111.7 % 80-120 04-DEC-14 WG2007655-1 MB Conductivity Sat. Paste <0.10 dS m-1 0.1 04-DEC-14 Quality Control Report
Workorder: L1553971 Report Date: 04-DEC-14 Page 2 of 2
Legend: Limit ALS Control Limit (Data Quality Objectives) DUP Duplicate RPD Relative Percent Difference N/A Not Available LCS Laboratory Control Sample SRM Standard Reference Material MS Matrix Spike MSD Matrix Spike Duplicate ADE Average Desorption Efficiency MB Method Blank IRM Internal Reference Material CRM Certified Reference Material CCV Continuing Calibration Verification CVS Calibration Verification Standard LCSD Laboratory Control Sample Duplicate
Sample Parameter Qualifier Definitions: Qualifier Description DLA Detection Limit adjusted for required dilution
Hold Time Exceedances: All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre- determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
VERTEX PROFESSIONAL SERVICES Date Received: 27-FEB-15 GROUP Report Date: 04-MAY-15 14:04 (MT) ATTN: Kristopher Boyes Version: FINAL REV. 2 418B McDONALD STREET REGINA SK . Client Phone: 306-485-8117
Certificate of Analysis Lab Work Order #: L1582196 Project P.O. #: AFE: Job Reference: HARVEST 01-10-011-07W2M C of C Numbers: Legal Site Desc: 01-10-011-07W2M
Other INV COMMENTS: Harvest Coding: Information:
Comments: 4-MAY-2015 Revised Client ID
______Brian Morgan Account Manager [This report shall not be reproduced except in full without the written authority of the Laboratory.]
ADDRESS: #819-58th St E., Saskatoon, SK S7K 6X5 Canada | Phone: +1 306 668 8370 | Fax: +1 306 668 8383 ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company HARVEST 01-10-011-07W2M L1582196 CONTD.... PAGE 2 of 3 Version: FINAL REV. ALS ENVIRONMENTAL ANALYTICAL REPORT
Sample Details/Parameters Result Qualifier* D.L. Units Extracted Analyzed Batch
L1582196-1 HA14-009 Sampled By: BRENT KIRKUP on 25-FEB-15 Matrix: SOIL
Detailed Salinity Chloride (Cl) (Saturated Paste) Chloride (Cl) 1070 DLA 50 mg/L 27-FEB-15 27-FEB-15 R3153164 Detail Salinity in mg/kg Chloride (Cl) 823 DLA 39 mg/kg 27-FEB-15 Calcium (Ca) 70.8 DLA 7.7 mg/kg 27-FEB-15 Magnesium (Mg) 76.4 DLA 7.7 mg/kg 27-FEB-15 Potassium (K) 7.1 DLA 3.9 mg/kg 27-FEB-15 Sodium (Na) 345 DLA 15 mg/kg 27-FEB-15 Sulfur (as SO4) 124 DLA 19 mg/kg 27-FEB-15 SAR, Cations and SO4 in saturated soil Calcium (Ca) 92 DLA 10 mg/L 27-FEB-15 27-FEB-15 R3153191 Potassium (K) 9.2 DLA 5.0 mg/L 27-FEB-15 27-FEB-15 R3153191 Magnesium (Mg) 99 DLA 10 mg/L 27-FEB-15 27-FEB-15 R3153191 Sodium (Na) 448 DLA 20 mg/L 27-FEB-15 27-FEB-15 R3153191 SAR 7.73 0.10 SAR 27-FEB-15 27-FEB-15 R3153191 Sulfur (as SO4) 162 DLA 25 mg/L 27-FEB-15 27-FEB-15 R3153191 Theoretical Gypsum Requirement TGR(brine) 0.36 0.10 t/ha 27-FEB-15 TGR(sodic) 0.84 0.10 t/ha 27-FEB-15 pH and EC (Saturated Paste) % Saturation 77.0 1.0 % 27-FEB-15 27-FEB-15 R3153137 pH in Saturated Paste 7.63 0.10 pH 27-FEB-15 27-FEB-15 R3153137 Conductivity Sat. Paste 3.60 0.10 dS m-1 27-FEB-15 27-FEB-15 R3153137
* Refer to Referenced Information for Qualifiers (if any) and Methodology. HARVEST 01-10-011-07W2M L1582196 CONTD.... PAGE 3 of 3 Reference Information Version: FINAL REV
Sample Parameter Qualifier Key: Qualifier Description
DLA Detection Limit adjusted for required dilution
Test Method References: ALS Test Code Matrix Test Description Method Reference**
CL-PASTE-COL-SK Soil Chloride (Cl) (Saturated Paste) CSSS(1993) 18.2.2/APHA 4500-CL E Chloride in a saturated soil extract is determined colorimetrically by auto-analyzer.
SAL-MG/KG-CALC-SK Soil Detail Salinity in mg/kg Manual Calculation SALINITY-INTCHECK-SK Soil CSSS 18.4-Calculation SAR-CALC-SO4-SK Soil SAR, Cations and SO4 in saturated soil APHA 3120B Ca, Mg, Na, K and SO4 in a saturated soil extract are determined by ICP-OES.
SAT/PH/EC-SK Soil pH and EC (Saturated Paste) CSSS 18.2.2/CSSC 3.14/CSSS 18.3.1 pH of a saturated soil paste is measured using a pH meter. After equilibration, an extract is obtained by vacuum filtration with conductivity of the extract measured by a conductivity meter. TGR2-CALC-SK Soil Theoretical Gypsum Requirement J. Ashworth et al (1999) Theoretical Gypsum Requirement is an estimate of the gypsum amendment required to remediate brine-contaminated or sodic soils, and is provided in units of tonnes per hectare (t/ha) for a treatment depth of 15cm. TGR(brine), intended for brine-contaminated soils, is calculated using Method A from "A Comparison of Methods for Gypsum Requirement of Brine-Contaminated Soils", by J. Ashworth (Cdn J. of Soil Science, 1999), available at www.alsglobal.com. TGR(sodic), intended for naturally sodic soils, uses the Oster and Frenkel method (Method B) from the same paper. Reported TGR values are capped at 50 t/ha, considered the maximum practical gypsum amendment. To convert TGR from t/ha to tons/acre, multiply by 0.446. To determine a TGR value for an alternate treatment depth, multiply by [desired treatment depth (cm) / 15 cm].
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location SK ALS ENVIRONMENTAL - SASKATOON, SASKATCHEWAN, CANADA
Chain of Custody Numbers:
Additional Information:
INV COMMENTS Harvest Coding:
GLOSSARY OF REPORT TERMS Surrogates are compounds that are similar in behaviour to target analyte(s), but that do not normally occur in environmental samples. For applicable tests, surrogates are added to samples prior to analysis as a check on recovery. In reports that display the D.L. column, laboratory objectives for surrogates are listed there. mg/kg - milligrams per kilogram based on dry weight of sample mg/kg wwt - milligrams per kilogram based on wet weight of sample mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight mg/L - unit of concentration based on volume, parts per million. < - Less than. D.L. - The reporting limit. N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory. UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION. Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review. Quality Control Report
Workorder: L1582196 Report Date: 04-MAY-15 Page 1 of 2
Client: VERTEX PROFESSIONAL SERVICES GROUP 418B McDONALD STREET REGINA SK . Contact: Kristopher Boyes Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
CL-PASTE-COL-SK Soil Batch R3153164 WG2047166-3 IRM SAL814 Chloride (Cl) 102.1 % 70-130 27-FEB-15 WG2047166-2 MB Chloride (Cl) <5.0 mg/L 5 27-FEB-15
SAR-CALC-SO4-SK Soil Batch R3153191 WG2047166-3 IRM SAL814 Calcium (Ca) 106.3 % 70-130 27-FEB-15 Potassium (K) 123.4 % 70-130 27-FEB-15 Magnesium (Mg) 110.0 % 70-130 27-FEB-15 Sodium (Na) 93.7 % 70-130 27-FEB-15 Sulfur (as SO4) 108.9 % 70-130 27-FEB-15 WG2047166-2 MB Calcium (Ca) <2.0 mg/L 2 27-FEB-15 Potassium (K) <1.0 mg/L 1 27-FEB-15 Magnesium (Mg) <2.0 mg/L 2 27-FEB-15 Sodium (Na) <4.0 mg/L 4 27-FEB-15 Sulfur (as SO4) <5.0 mg/L 5 27-FEB-15
SAT/PH/EC-SK Soil Batch R3153137 WG2047166-3 IRM SAL814 % Saturation 45.0 % 37-47 27-FEB-15 pH in Saturated Paste 7.74 pH 7.4-8 27-FEB-15 Conductivity Sat. Paste 108.3 % 80-120 27-FEB-15 WG2047166-2 MB Conductivity Sat. Paste <0.10 dS m-1 0.1 27-FEB-15 Quality Control Report
Workorder: L1582196 Report Date: 04-MAY-15 Page 2 of 2
Legend: Limit ALS Control Limit (Data Quality Objectives) DUP Duplicate RPD Relative Percent Difference N/A Not Available LCS Laboratory Control Sample SRM Standard Reference Material MS Matrix Spike MSD Matrix Spike Duplicate ADE Average Desorption Efficiency MB Method Blank IRM Internal Reference Material CRM Certified Reference Material CCV Continuing Calibration Verification CVS Calibration Verification Standard LCSD Laboratory Control Sample Duplicate
Sample Parameter Qualifier Definitions: Qualifier Description DLA Detection Limit adjusted for required dilution
Hold Time Exceedances: All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre- determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.