Supercapacitor USER's MANUAL VOL.01 3

Sales & Marketing Division, Asia Chiyoda First Bldg., 8-1, Nishi-Kanda 3-chome, Chiyoda-ku, Tokyo 101-8362, Japan Phone: +81-3-3515-9224 Fax: +81-3-3515-9223 Vol. Sales & Marketing Division, Americas and Europe Chiyoda First Bldg., 8-1, Nishi-Kanda 3-chome, Chiyoda-ku, Tokyo 101-8362, Japan Phone: +81-3-3515-9222 Fax: +81-3-3515-9223 TOKIN Korea Co., Ltd. 518, Korea City AIR-Terminal B/D, 22, Teheran-ro 87 gil, Gangnam-gu, Seoul 06164, Korea Phone: +82-2-551-3651 Fax: +82-2-551-3650 TOKIN America Inc. (Headquarters & Western Area Sales) 2560 North First Street, Suite 100, San Jose, California 95131, U.S.A. 01 Phone: +1-408-324-1790 Fax: +1-408-324-1497 Chicago Branch (Northeast Sales Ofﬁce) 1600 Golf Road, Corporate Center-Suite 1228, Rolling Meadows, Illinois 60008, U.S.A. Phone: +1-847-981-5047 Fax: +1-847-981-5051 Austin Branch (Southeast Sales Ofﬁce) 11782 Jollyville Road, Suite 208, Austin, Texas 78759, U.S.A. Phone: +1-512-219-4040 Fax: +1-512-219-4007 TOKIN Hong Kong Ltd. SuperCapacitor Unit Nos. 1513-1515, Level 15, Tower Ⅱ, Grand Central Plaza, 138 Shatin Rural Committee Road, Shatin, New Territories, Hong Kong Phone: +852-2730-0028 Fax: +852-2375-2508 TOKIN Shanghai Co., Ltd. Room 301-303, Metro Plaza, No.555 Loushanguan Road, Changning District, Shanghai, China 200051 Phone: +86-21-6228-0606 Fax: +86-21-6228-6862 Shenzhen Branch Unit 2659-2660, 26/F, Dong Fang Plaza, No.1072 Jian She Road, Luohu, Shenzhen City, Guangdong, China, 518001 User's Manual Phone: +86-755-2295-4481 Fax: +86-755-2295-4486 TOKIN Singapore Pte Ltd. 150 Changi Road, #04-02 Guthrie Building, Singapore 419973 Phone: +65-6345-3181 Fax: +65-6345-6016 TOKIN Taiwan Co., Ltd. Room 411, 4F, No.9, Lane 3, Minsheng W.Road, Taipei 104, Taiwan Phone: +886-2-2521-3998 Fax: +886-2-2521-3993 TOKIN Europe GmbH Hellersbergstrasse 14, D-41460 Neuss, Germany Phone: +49-2131-1866-0 Fax: +49-2131-1866-18 France Branch Bâtiment FUJI YAMA, 1, avenue de l’Atlantique, 91940 LES ULIS, France Phone: +33-1-60-921137 Fax: +33-1-60-921146

©TOKIN Corporation 2017

For inquiry, Please call Sales & Marketing Department (Japan) SuperCapacitor Phone: 81-3-3515-9264 Fax: 81-3-3515-9261 http://www.tokin.com USER'S MANUAL

9565SCGVOL01E1705H1 Printed in Japan

●All specifications in this catalog and production status of products are subject to change without notice. Prior to the purchase, please contact TOKIN for updated product data. ●Please request for a specification sheet for detailed product data prior to the purchase. ●Before using the product in this catalog, please read "Precautions" and other safety precautions listed in the printed version catalog.

2017.05.17 9565SCGVOL01E1705H1 For Correct Use of SuperCapacitor

1. Please conﬁ rm the operating condition and the speciﬁ cations of the SuperCapacitors fefor using them. 2. The electrolyte of these SuperCapacitors is sealed with material such as rubber. When you use the capacitors for long time at high temperature, the moisture of the electrolyte evaporates and the equivalent series resistance (E.S.R.) increases. The fundamental failure mode is the open mode depending on E.S.R. increase. When using these capacitors, incorporate appropriate safety measures in your design, such as redundancy and measures to prevent misoperation. 3. Please read 'Notes on Using the SuperCapacitor' on page 30 when you design the circuits using the SuperCapacitors.

2017.05.17 9565SCGVOL01E1705H1 CONTENTS

1. SYSTEMATIC CHART OF SuperCapacitor ...... 4

2. STRUCTURE AND PRINCIPLE ...... 5

3. PRODUCT LINE-UP FOR SuperCapacitor ...... 7

4. FEATURES ...... 8

5. MANUFACTURING AND RELIABILITY & QUALITY CONTROL ...... 9

6. PERFORMANCE ...... 11

7. CHARACTERISTIC MEASURING METHOD ...... 19

8. SELECTION GUIDE ...... 21

9. OPERATING PRECAUTIONS ...... 30

10. FC-SERIES SuperCapacitor (Surface Mounting Type, Automatic Assembly) ...... 32

11. FM-SERIES SuperCapacitor (Resin Molded, Automatic Assembly) ...... 40

12. FG-SERIES SuperCapacitor ...... 53

13. FT-SERIES SuperCapacitor (Wide Operating Temperature Range, Low ESR) ...... 61

14. FY-SERIES SuperCapacitor ...... 67

15. FR-SERIES SuperCapacitor (Wide Operating Temperature Range) ...... 75

16. FS-SERIES SuperCapacitor (Miniaturized, Low ESR) ...... 80

17. FA-SERIES/FE-SERIES SuperCapacitor (Low ESR) ...... 87

18. APPLICATION OF SuperCapacitor ...... 95

SuperCapacitor USER'S MANUAL VOL.01 3

2017.05.17 9565SCGVOL01E1705H1 1 SYSTEMATIC CHART OF SuperCapacitor

－25 to 70℃ －40 to 85℃ guaranteed guaranteed

mA order μA order back-up back-up

For automatic mounting FC （SMD） series （embossad taping） 3.5 to 5.5V

For automatic mounting FME FM FMR （） Type series Type radial taping 5.5V 3.5 to 6.5V 3.5 to 5.5V

－40 to 85℃ guaranteed FT FG FGR Can Case type series series Type （） self-supporting Type 5.5V 3.5 to 5.5V 5.5V

FS FY FR series series series 5.5 to 12V 5.5V 5.5V

FE series 5.5V

FA series 5.5 to 11V

For A order current HV series 2.5 to 2.7V 10 to 100F

SuperCapacitor USER'S MANUAL VOL.01 4

2017.05.17 9565SCGVOL01E1705H1 2 STRUCTURE AND PRINCIPLE

An electrical double layer capacitor is different from a common Figure 2 shows a conceptual drawing of the basic structure of capacitor using dielectric substance. SuperCapacitor.

When two different phases of solid and liquid come into contact, positive and negative charges are distributed + – Liquid + – + – Liquid + – + + – + – confronting with each other in a very small distance on the – Application of + – + – + – + – Solid Solid a voltage Solid + – + – Solid boundary surface. A layer which spreads in the vicinity of this + – + – + – + – + – + – boundary surface is called the "electrical double layer." + + – + – – + – + – + – + – + – + – Electrical double layer + – + – The electrical double layer capacitor, "SuperCapacitor," uses φ 0+ φ 1 activated carbon as its solid part and aqueous solution of φ 0 φ 0– φ 1 dilute sulfuric acid as its liquid part. Figure 1(a) shows the state in which activated carbon and dilute sulfuric acid are Potential when no load is applied Potential when a voltage is applied brought into contact, and Figure 1(b) shows the modeled state (a) (b) in which two pairs of the solid and liquid parts in Figure 1(a)

are connected in series with both pairs sharing the same liquid Fig. 2 Basic Structure of SuperCapacitor part, and with an electrical ﬁ eld applied externally.

Suppose η is the amount of unitary charge of the solid part, Electrical double layer Electrical double layer δ Electrical double layer d is the dielectric constant of the medium (liquid part), is the + – + – ψ + – – Liquiddistance– from Solid the solid surface to the center of ions, and Solid + – – – + – – – – is– the potential+ of the– double layer, then η is represented by Liquid + + + + + + + + + – expression+ – (1). + – Solid + + + + + + + – + + + – – – – – + – – – + – – – d – η –= × ψ ( 1 ) + + – + – πδ – + + 4 According to Helmholtz's theory, there is a potential gradient (a) onlyExternal in the power electrical supply double layer, and their respective potential(b) curves are as shown in Figures 2 (a) and 2 (b). In

Figure 2(b), if ψ and η, when no load is applied, are φ0 and η0, Electrical double layer Electrical double layer Electrical double layer η + – + – respectively, then 0 is represented by expression (2). + – – Liquid – Solid Solid + – – – + – – – d – – + – η 0 = × ψ0 (2) Liquid + + + + + 4πδ + + + + – + – + – Solid Then, if an external electrical field is applied, charge is + + + + + + + – + + + – accumulated on the boundary surface as shown in Figure 2 (b). – – – – + – – – + – – – – – At this time, suppose ψ0 becomes ψ1 and η0 becomes η1, then + + – + – – + + η1 is represented by expression (3). d (a) External power supply η 1 = × (2ψ1 – ψ0) (3) 4πδ (b) From expressions (2) and (3) above, expression (4) is found.

ψ1 η 1 = 2η0 ( ) × (ψ1 > ψ0) (4) ψ Fig. 1 Model Showing Basic Principle 0 That is, the external electrical field allows charge

corresponding to η1 in expression (4) to accumulate in the

electrical double layer. Here, ψ0 is on the order of several mV. SuperCapacitor USER'S MANUAL VOL.01 5

2017.05.17 9565SCGVOL01E1705H1 According to an experiment using mercury for the electrode, electrolyte (dilute sulfuric acid). It also places a conductive an accumulated capacitance of 20 to 40 μF/cm2 per unit area current collecting electrode behind both electrodes (activated is obtained. Suppose the activated carbon electrode shows carbon powder) allowing a voltage to be applied to this the same action as that of mercury, then activated carbon with capacitor base cell. In addition, it provides sealing rubber a surface area of 1000 m2/g will produce a capacitance of 200 (mainly butyl rubber) at the electrode flank for sealing the to 400 F/g. However, such a high capacitance is not actually electrolyte and isolating the conductive material. The amount obtained. It is our proprietary technology that made it possible of the electrolyte to be sealed into the capacitor base cell is to obtain a value very close to the above value by improving equivalent to that needed for impregnation of the pores inside the quality of the activated carbon surface or increasing activated carbon and the porous organic ﬁ lm, and it is a very speciﬁ c surface area, etc. small amount.

On the other hand, it is not possible in principle to apply a The breakdown voltage of the capacitor base cell depends voltage higher than the decomposition voltage of an electrolyte on the electrolysis voltage of the electrolyte. The electrolysis based on the substance which makes up an electrical double voltage depends on the water content in the dilute sulfuric layer capacitor. Therefore, it is necessary to have a structure acid, and it is approximately 1.2 V. Design of the breakdown of connecting capacitor base cells in series in order to obtain voltage for the maximum operating voltage of 5.5 V is the desired breakdown voltage. determined by connecting 5 or more sheets of capacitor base cells in series. (See Figure 4.) Figure 3 shows the basic structure (capacitor base cell) of a SuperCapacitor. A certain pressure is applied inside the package to stabilize electrical connection between the capacitor base cells, The electrical double layer phenomenon appears on the between activated carbon powder particles and between boundary surface between activated porous carbon powder activated carbon powder and conductive current collecting (solid) and the electrolyte, dilute sulfuric acid (liquid). The electrodes. separator (porous organic film) has a structure which prevents short-circuit between the positive and negative Figures 5,6 and 7 show a cross section of a ﬁ nished product electrodes (activated carbon powder) and lets ions pass in the of a SuperCapacitor.

Conductive current collecting electrodeOuter case Pin

Mold material Polybutylene Terephthalate (PBT) Capacitor base cell Sealing synthetic rubber Capacitor Isolation casebase cell

Pin (iron + copper base plating + solder plating)

Sleeve Separator (porousPins (plate organic leads) film)

ActivatedNote carbon For cases + electrolyte where washing (dilute issulfuric required, acid) a washing-resistant product with resin sealing applied to the lead pin implantation is available. Fig. 3 Capacitor with Basic Structure (Base Cell) Fig. 6 SuperCapacitor Resin Mold Type Structure (FM Series)

Outer case

Mold material Polybutylene Terephthalate (PBT) Conductive current collecting electrode Pin Capacitor base cell

Isolation case Sealing synthetic rubber Capacitor base cell Outer case CapacitorPin (iron +base copper cell base plating + solder plating)

Sleeve Isolation case Pins (plate leads)

Note For cases where washing is required, a washing-resistant product with resin sealing applied to the lead pin implantation Pins(Plate leads) Separator (porous organic film) is available.

Activated carbon + electrolyte (dilute sulfuric acid) Plate Fig. 5 Cross Section SuperCapacitor Fig. 4 Assembly Schematic Standalone Type Can Case Fig. 7 SuperCapacitor FC Series Structure

SuperCapacitor USER'S MANUAL VOL.01 6

2017.05.17 9565SCGVOL01E1705H1 3 PRODUCT LINE-UP FOR SuperCapacitor

kA Low ESR

High power SuperCapacitor A BOX type

High power SuperCapacitor HV Series

mA Backup current Low impedance application use FA, FE, FS, FT, FM Series

High impedance application use

equivalent series resistance (ESR) FG, FY, FC, FM, FR Series µA Backup current depends on SuperCapacitor

2 3 4 5 6 7 8 High ESR 0.01 0.1 1 10 10 10 10 10 10 10 10 Backup time 1 minute 1 hour 1 day 1 week 1 month ( sec )

Backup time depends on capacitance

SuperCapacitor USER'S MANUAL VOL.01 7

2017.05.17 9565SCGVOL01E1705H1 4 FEATURES

A SuperCapacitor has internal resistance greater than an The table below shows the features of a SuperCapacitor in aluminum electrolytic capacitor (several hundreds of m Ω comparison with an aluminum electrolytic capacitor for power to 100 Ω), and cannot be used in an AC circuit for ripple supply backup and a secondary battery. absorption applications, etc. Therefore, it is mainly used in a secondary battery for power supply backup in a DC circuit, etc.

Capacitor Secondary Battery SuperCapacitor Aluminum Electrolytic Capacitor Ni-Cd Battery Lithium Secondary Battery Backup capacity ○ △ ◎ ◎ Pollutive characteristic – – Use of cadmium – Operating temperature –40 to 85 °C (FR.FT) –55 to 105 °C –20 to 60 °C –20 to 50 °C range Charging time A few seconds A few seconds A few hours A few hours Charging/discharging life Unlimited (Note 1) Unlimited (Note 1) Approx. 500 times Approx. 500 to1000 times Restrictions on charging/ No No Yes Yes discharging Flow soldering Applicable Applicable Not applicable Not applicable Automatic mounting Applicable (FC, FM Series) Applicable Not applicable Not applicable Failure mode Open Shorted Shorted Shorted Safety Gas emission (Note 2) Heating, explosion Leakage, explosion Leakage, ignition, explosion

Notes 1. Aluminum electrolytic capacitors and SuperCapacitors have a limited service life. However, within the lifetime of device set that SuperCapacitor has been built-in, these are designed to last long enough if used under appropriate conditions. 2. Water vapor generated from the water in the electrolyte, gradually leak out in a from of gas and are not dangerous. However, if unusual voltage such as greater than the maximum operating voltage is applied suddenly, a leakage of liquid or explosion may result.

SuperCapacitor USER'S MANUAL VOL.01 8

2017.05.17 9565SCGVOL01E1705H1 5 MANUFACTURING AND RELIABILITY & QUALITY CONTROL

5.1 Manufacturing Process Figure 7 shows an outline of the manufacturing process of a SuperCapacitor. The manufacturing process can be largely divided into the manufacturing process of capacitor base cells and the product assembly process.

(1) Manufacturing process of capacitor base cells A mixture of activated carbon and dilute sulfuric acid is formed on the conductive current collecting electrodes, which the electrolyte hardly penetrates, and this is used as an electrode. Two pairs of these electrodes are prepared, and a porous organic ﬁ lm separator and sealing material are inserted between these pairs, compacted in the periphery, and completely sealed. In this way, capacitor base cells are manufactured.

(2) Product assembly process The above capacitor base cells are placed one atop another. For the can case type, they are accommodated in a metal case and caulked. For the resin mold type, they are packaged in mold.

5.2 Process & Quality Control The SuperCapacitor is controlled and manufactured under a strict control and environmental protection system based on ISO9000 and ISO14000. Figure 7 shows the contents of the process & quality control of a SuperCapacitor.

SuperCapacitor USER'S MANUAL VOL.01 9

2017.05.17 9565SCGVOL01E1705H1 Manufacturing process and material Control item

Activated carbon Activated carbon Dilute sulfuric acid Activation level, purity, particle diameter

Dilute sulfuric acid Concentration, purity

Mixing Mixing ratio

Current collecting electrode Electrical conductivity, thickness, appearance

Sealing material Isolation resistance, thickness, appearance

Separator Mechanical strength, permeability, thickness, appearance

Electrode formation Weight, volume

Curing Temperature, pressure, time

Cell lamination Appearance

[SMD type] [Standalone type can case type] [Resin mold type]

Pins Plating thickness, Outer case, Outer case Plating thickness, Plating thickness, dimensions, electrode dimensions, dimensions, appearance appearance appearance

Mold Appearance, ESR Isolation case Dimensions, Isolation case Dimensions, appearance, appearance, isolation resistance isolation resistance Ageing Temperature, voltage, time

Caulking Appearance Caulking Appearance Inspection Electrical characteristics, Sleeve Thickness, appearance Ageing Temperature, dimensions, voltage, time appearance Finish test C, ESR, current, Marking Appearance self-discharge, Attachment Appearance appearance, of sleeve dimensions Finish test C, ESR, current, self-discharge, Ageing Voltage, Bottom board appearance, dimensions Appearance, temperature, time dimensions

Finish test C, ESR, current, Taping Appearance, Taping Appearance, dimensions self-discharge, dimensions appearance, dimensions

Shipment inspection C, ESR, current, self-discharge*, dimensions, appearance

Shipment *···· Self-discharge test is only applied to standardized series products.

Manufacturing Process and Process & Quality

SuperCapacitor USER'S MANUAL VOL.01 10

2017.05.17 9565SCGVOL01E1705H1 6 PERFORMANCE

6.1 Initial Performance (1) Capacitance (Cap) Table 1 shows typical capacitance values of each product.

Table 1. Initial Characteristics Values in this table are average values. Capacitance Equivalent Series DC Resistance Capacitance Equivalent Series DC Resistance Product Name Product Name C (F) Resistance ESR (Ω) R (Ω) C (F) Resistance ESR (Ω) R (Ω) FCS0H473ZF 0.047 15 25 FYD0H223ZF 0.026 80 168 104ZF 0.10 10 17 473ZF 0.047 55 113 224ZF 0.22 10 17 104ZF 0.095 24 45 FCS0V104ZF 0.10 15 25 224ZF 0.21 17 36 224ZF 0.22 10 17 474ZF 0.45 13 24 474ZF 0.47 10 17 105ZF 0.98 6.5 11 * FC0H473ZF 0.047 13 22 145ZF 1.3 8.2 18 * 104ZF 0.10 12 17 225ZF 2.3 4.2 9.2 * 224ZF 0.22 8 14 FYH0H223ZF 0.028 64 131 * 474ZF 0.47 5 8.2 * 105ZF 1.0 4 6 473ZF 0.047 35 66 * FC0V104ZF 0.1 18 21 104ZF 0.11 20 38 * 224ZF 0.22 11 12 224ZF 0.22 20 42 * 474ZF 0.47 11 15 474ZF 0.55 7.5 14 FM0H103ZF 0.012 30 65 105ZF 1.15 4.5 8 223ZF 0.022 18 33 FYL0H103ZF 0.012 80 155 473ZF 0.047 12 26 223ZF 0.022 25 48 104ZF 0.10 12 32 473ZF 0.047 20 38 * 224ZF 0.22 8 12 FE0H473ZF 0.052 10 16 FME0H223ZF 0.022 14 20 104ZF 0.12 5 8 473ZF 0.047 8.5 14 224ZF 0.28 2.5 4.4 FMR0H473ZF 0.047 11 19 474ZF 0.62 0.9 2.2 FMC0H473ZF 0.047 12 16 105ZF 0.98 0.7 1.2 104ZF 0.10 9 12 155ZF 1.68 0.3 0.6 * 334ZF 0.33 5 10 FA0H473ZF 0.052 10 17 FG0H103ZF 0.01 82 94 223ZF 0.022 23 31 104ZF 0.12 5 8 473ZF 0.047 23 29 224ZF 0.28 2.5 4.5 104ZF 0.10 12 16 474ZF 0.62 1 2.2 224ZF 0.22 10 15 105ZF 1.0 0.6 1.1 474ZF 0.47 14 26 FA1A223ZF 0.024 16 33 105ZF 1.0 7.6 14 104ZF 0.15 3.8 6.4 225ZF 2.2 3.2 7 224ZF 0.33 1.8 3.1 475ZF 4.7 1.2 3.2 474ZF 0.52 1 2.1 * FGH0H104ZF 0.1 12 20 * Capacitance values according to the constant current discharge method * 224ZF 0.22 18 36 * 474ZF 0.47 7 13 * 105ZF 1.0 3 6 Capacitance of the SuperCapacitor is measured according FT0H104ZF 0.10 13 23 224ZF 0.22 8.5 16 to the constant-resistance charge method or constant carrent 474ZF 0.46 3.6 5.4 105ZF 1.0 1.8 2.9 disoharge method. 225ZF 2.19 1.2 2.1 335ZF 3.3 0.8 1.3 565ZF 5.8 0.4 0.8 In Constant resistance charge method, Capacitance (F) of FS0H223ZF 0.028 24 51 473ZF 0.047 10 18 the capacitor is calculated by measuring the time constant (τ) 104ZF 0.10 7.5 11 which represents the charge characteristic when a resistor 224ZF 0.24 5.5 9 474ZF 0.54 2.5 4.2 is connected to the capacitor in series and a DC voltage is 105ZF 1.22 1.8 2.9 FS1A474ZF 0.47 1.7 3.4 applied. 105ZF 1.0 2.5 5.0 FS1B105ZF 1.0 2.7 (1.2) 5.0 505ZF 5.0 0.9 2.0 (To do this, it is necessary to short-circuit between the FR0H223ZF 0.022 38 72 473ZF 0.050 24 50 capacitor pins for 30 minutes or more to reduce the potential 104ZF 0.12 18 38 sufﬁ ciently. 224ZF 0.28 26 55 474ZF 0.6 18 38 105ZF 1.15 9 18

SuperCapacitor USER'S MANUAL VOL.01 11

2017.05.17 9565SCGVOL01E1705H1 τ The capacitance values measured using the fixed resistor Capacitance: Calculated from (F) = (5) RC charge method and the constant current discharge method

τ : Charge time until 0.632E0 (VC) (sec) are both shown in the standard ratings.

Switch Figure 8 shows capacitance values when the discharge current is changed. When the discharge current is small, the RC + E0 C VC capacitance value is relatively large. –

In the method of measuring capacitance for normal backup applications, the discharge system is considered to reflect If measured according to competitors' constant current, more precisely the actual situation. However, in order to discharge and charge measurement methods, the speciﬁ ed simplify measurement, the charge system which discharges a current values are smaller than those specified by us and relatively large current is used. therefore they are apparently 1.3 to 1.5 times the capacitance values measured by our measurement method. Therefore, Figure 9 shows changes in capacitance due to temperature the backup capability of the same rated product as those of variations. The temperature changes in proportion to the competitors is 1.3 to 1.5 times that of competitors. capacitance, and the higher the temperature is, the greater the capacitance becomes. Refer to page 20 for capacitance values according to the constant current discharge method.

0.07 I (A) SW A FYH0H473ZF Constant current Capacitance according to E our charge system V C discharge 0.0439F (F)

0.06 Capacitance

0.05 0.01 0.1 1 10 Discharge current (mA)

Fig. 8 Capacitance Values vs. Discharge Current Values

0 Δ C/C (%)

–10

–20

–25 25 70 25 Temperature (˚C)

Fig. 9 Capacitance Change (Condition: –25 °C � 25 °C � 70 °C � 25 °C � , n = 10)

SuperCapacitor USER'S MANUAL VOL.01 12

2017.05.17 9565SCGVOL01E1705H1 (2) Equivalent series resistance (ESR) Figure 11 shows ESR changes due to temperature variation. Table 1 shows average typical values of equivalent series The lower the temperature is, the greater ESR becomes. resistance for each product.

The equivalent series resistance of a SuperCapacitor is 4 measured as follows: A sine wave oscillator of AC 1 kHz is used to pour an AC current of 10 mA into a capacitor (C) and 3

the voltage between both capacitor ends (VC) is measured, 2 then the equivalent series resistance of a SuperCapacitor is ESR ( Ω )

calculated from expression (6). 1

VC Equivalent series resistance = (6) 0 0.01 –25 25 70 25 (ESR) Temperature (˚C)

10mA Fig. 11 Temperature Dependency of ESR

1 kHZ C VC (3) Series resistance Normally, a SuperCapacitor is used for DC charge/discharge. Table 1 shows typical average values of DC resistance (internal resistance) of a SuperCapacitor actually measured using a Figure 10 shows ESR values when the frequency is changed. DC current. The lower the frequency is, the greater ESR becomes. Figure 12 shows voltage drops when the discharge current is changed. 20 2.0

15 1.5 FS0H473ZF FS0H473ZF 10

ESR ( Ω ) FA0H473ZF 1.0

5 Voltage drop (V) 0.5 FS0H474ZF 0 5 10 20 50 100 200 500 1,000 2,000 5,000 10,000 0 Frequency (Hz) 0.01 0.05 0.1 Current (A)

Fig. 10 Frequency Dependency of ESR Fig. 12 Voltage Drop

SuperCapacitor USER'S MANUAL VOL.01 13

2017.05.17 9565SCGVOL01E1705H1 (4) Current Figure 13 shows changes in the electrode when a voltage The current of a SuperCapacitor is calculated from expression is continuously applied to the capacitor. The main current (7) by applying a voltage to the capacitor [C] and measuring component after 30 minutes of voltage application is an the voltage between both DC resistor ends 30 minutes later. absorption current. It takes several tens to hundreds of hours (The voltage is applied after both ends of the capacitor for a leakage current to become the main component as the are shorted for 30 minutes or more to reduce the potential absorption current reduces. sufﬁ ciently.) Figure 14 shows the multi-hour current characteristic when the

VR ambient temperature is changed. The higher the temperature Current = × 103 (mA) (7) RC is, the greater the current becomes.

FY series - FYD type at 25˚C FYH0H104ZF

E1 V Measuring condition V E : 5.0V 30 R : 1kΩ 1 kΩ E R C 10 5 V C I : Leakage 20 current I = E 1 (A) R I = V (A) 1000 10

5.0 70˚C FYD0H225ZF

FYD0H145ZF 3.0

FYD0H105ZF µ 2.0 µ 1

1.0

FYD0H474ZF Current ( A) Current ( A)

FYD0H224ZF 40˚C 0.5

0.3 25˚C FYD0H104ZF 0.2

0.1 FYD0H473ZF 0.1 FYD0H223ZF

Number of samples : 5 each

0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Time (h) 100 200 300 400 500 600 700 Time (h)

Fig. 13 Multi-Hour Current Characteristic Fig. 14 Temperature Dependency of Multi-Hour Current

SuperCapacitor USER'S MANUAL VOL.01 14

2017.05.17 9565SCGVOL01E1705H1 (5) Self-discharge characteristic Figure 15 shows the self-discharge characteristic of a sample When applying a voltage to a SuperCapacitor and then which has been left at a normal temperature. releasing the voltage between both pins, the rate of decrease of the voltage between both pins is defined as the self- Figure 16 shows deterioration of the self-discharge discharge characteristic. characteristic of a SuperCapacitor which has been left at a high temperature of 50 °C. The self-discharge characteristic of a SuperCapacitor is * For backup applications, which may be affected by the obtained by charging 5.0 VDC (charge protection resistance: self-discharge characteristic for many hours on the order 0 Ω) into the capacitor for 24 hours, then releasing the voltage of μA, FG, FM, FC, FR and FY Series in which the between both pins, leaving the capacitor at an ambient self-discharge characteristic (residual voltage value) is temperature of 25 °C or below and relative humidity of 70%RH guaranteed, are most suitable. for 24 hours, and then measuring the voltage remaining between both pins.

FY Series • FYD Type Charge condition : 5V, 0Ω, 24h charge (25˚C) 5

3 FYD0H105ZF

FYD0H474ZF

Voltage (V) 2 FYD0H224ZF

FYD0H104ZF 1 FYD0H473ZF

0 0.1 1 10 100 1,000 Time (h)

Fig. 15 Self-Discharge Characteristic

10000

Charge condition : 5V, 1kΩ, 24h charge (25˚C) 5000 Temperature : 50˚C

2000 FYH0H473ZF

1000

500

200 Time required to change from 5 V 2 (h)

FS0H473ZF 100 Initial 10 20 30 40 50 60 Natural discharge time (H)

Fig. 16 Change of Self-Discharge Characteristic by Natural Discharge

SuperCapacitor USER'S MANUAL VOL.01 15

2017.05.17 9565SCGVOL01E1705H1 (6) Resistance discharge characteristic However, there is a difference in the backup characteristic ① Inﬂ uence of charge time on the discharge characteristic depending on charge time. Figures 17 and 18 show resistance discharge characteristics of the FS, FY (FYD type) Series 5.5 V/0.047F products. The longer the charge time is, the longer the possible There is no significant difference between the series. backup time is.

Discharge condition: 5MΩ FS0H473ZF (equivalent to 1µ A) Charge time (min.) 5.0 60 (min.) 30 10 5 4.0 1 )

V 3.0 (

Pin voltage 2.0

1.0

0 1 5 10 50 100 Discharge time (h)

Fig. 17 Constant-Resistance Discharge Characteristic (Charge Time Dependency)

Discharge condition: 5MΩ FYD0H473ZF (equivalent to 1 µ A) Charge time (min.) 5.0 60 (min.) 30 10 5 4.0 1 )

V 3.0 (

Pin voltage 2.0

1.0

0 1 5 10 50 100 Discharge time (h)

Fig. 18 Constant-Resistance Discharge Characteristic (Charge Time Dependency)

SuperCapacitor USER'S MANUAL VOL.01 16

2017.05.17 9565SCGVOL01E1705H1 ② Influence of ambient temperature on the resistance but the discharge time decreases drastically at a higher discharge characteristic temperature. Factors determining the discharge characteristic Figures 19 to 21 show the resistance discharge characteristics are storage dependency of capacitance and temperature when the ambient temperature is changed. There is no great dependency of leakage current. difference of the discharge time up to approximately 40 °C,

FYH0H223ZF Charge condition: 5 V, 0Ω, 1 h charge (25˚C)

5MΩ (1 µ A, 25˚C) 5 5MΩ (1 µ A, 40˚C) 250kΩ (20 µ A, 25˚C) 250kΩ (20 µ A, 40˚C) 4 ) V (

2 Pin-to-pin voltage

0 0.1 1 10 Discharge time (h)

Fig. 19 Resistance Discharge Characteristic (Temperature Dependency)

FYD0H224ZF Charge condition: 5 V, 0Ω, 24 h charge (25˚C) Discharge condition : 5 µ A (1MΩ) 5

4 ) V ( 3

2 70˚C 25˚C Pin-to-pin voltage

0 0.1 1 10 100 1,000 Discharge time (h)

Fig. 20 Resistance Discharge Characteristic (Temperature Dependency)

SuperCapacitor USER'S MANUAL VOL.01 17

2017.05.17 9565SCGVOL01E1705H1 Ω FYD0H225ZF Charge condition: 5 V, 0 , 24 h charge (25˚C) Discharge condition : 10 μ A (500 kΩ) 5.0

4.0 ) V ( 3.0

2.0 70˚C 60˚C 50˚C 25˚C Pin-to-pin voltage

1.0

0 0.1 1 10 100 1,000 Discharge time (h)

Fig. 21 Resistance Discharge Characteristic (Temperature Dependency)

(7) Rush current (maximum current during charging) The FS, FT, FME, FA and FE series are designed to have an A rush current occurs when a voltage of 5 V is applied and equivalent series resistance 1 digit smaller than other series. there is no series protection resistor. Its measurement circuit Care is required when designing peripheral circuits because is shown in Figure 22. application of a voltage causes a rush current to ﬂ ow that is greater than other series. Generally, the greater the capacitance and the greater the diameter of a product is, the smaller its DC resistance is and Especially, if a current exceeding the maximum supply current so the greater the rush current in the same series is. of the power supply ﬂ ows, the protection circuit of the power supply may malfunction or shut down. In such a case, it is necessary to insert a series resistor to protect the power Rush current I1 supply.

V0=5V SuperCapacitor The peak value of rush current I is calculated from expression (8). E I = [A] (8) Fig. 22 Test Conditions for Rush Current R E: Voltage applied (V) Figure 23 shows temporal changes in pin-to-pin voltage V and R: SuperCapacitor DC resistance (Ω) charge current I when a voltage is applied to the FA0H105ZF Note If there is a series protection resistor, add it to R. (5.5 V/1F).

Table 1 shows DC resistance R which is calculated from a V 5 5 voltage drop during discharging of a representative product. ) ) V

( DC resistance of a SuperCapacitor shows approximately 1.5 A ( times the actual ESR (at 1 kHz) value.

I Charge current Pin-to-pin voltage

0 0 0 5 10 Time (sec)

Fig. 23 Charge Characteristic SuperCapacitor USER'S MANUAL VOL.01 18

2017.05.17 9565SCGVOL01E1705H1 7 CHARACTERISTIC MEASURING METHOD

(1) Capacitance Switch 1. Measuring capacitance using the ﬁ xed resistor charge method RC + E0 C VC The capacitance of SuperCapacitors can not be measured – using the same methods used to measure ordinary capacitors because of their large capacitance and large equivalent series resistance.

E0 : 3.0 (V) ... Product with maximum operating voltage For this reason the capacitance is calculated by charging and 3.5 V discharging the capacitor with a direct current, in the same : 5.0 (V) ... Product with maximum operating voltage way that the capacity of batteries is measured. 5.5 V : 6.0 (V) ... Product with maximum operating voltage Capacitance is calculated from expression (9) by measuring 6.5 V the charge time constant (τ) of the capacitor (C). Prior to : 10.0 (V) ... Product with maximum operating voltage measurement, short between both pins of the capacitor for 11 V 30 minutes or more to let it discharge. In addition, follow the : 12.0 (V) ... Product with maximum operating voltage indication of the product when determining the polarity of the 12 V

capacitor during charging. τ : Time from start of charging until VC becomes

0.632E0 (V) (sec)

τ RC : See table below (Ω). Capacitance: C = (F) (9) RC

FY FM, FME FG FC FA FE FS FR FMC FGH FT FYD FYH FMR FGR FCS 0.010F – – – – – – 5000 Ω – 5000 Ω – – – 0.022F 1000 Ω – 1000 Ω 2000 Ω 2000 Ω 2000 Ω 2000 Ω – 2000 Ω – – Discharge 0.033F – – – – – – Discharge – – – – – 0.043F – – – – – – – – – – – Discharge 0.047F 1000 Ω 1000 Ω 1000 Ω 2000 Ω 1000 Ω 1000 Ω 2000 Ω 1000 Ω 2000 Ω – – – 0.068F – – – – – – – – – – – Discharge 0.10F 510 Ω 510 Ω 510 Ω 1000 Ω 510 Ω 1000 Ω 1000 Ω 1000 Ω 1000 Ω Discharge 510 Ω Discharge 0H: Discharge 0.22F 200 Ω 200 Ω 200 Ω 510 Ω 510 Ω 510 Ω – 1000 Ω Discharge 200 Ω Discharge 0V: 1000 Ω 0.33F – – – – – – – Discharge – – – – 0.47F 100 Ω 100 Ω 100 Ω 200 Ω 200 Ω 200 Ω – – 1000 Ω Discharge 100 Ω Discharge 1.0F 51 Ω 51 Ω 100 Ω 100 Ω 100 Ω 100 Ω – – 510 Ω Discharge 100 Ω Discharge 1.4F – – – 200 Ω – – – – – – – – 1.5F – 51 Ω – – – – – – 510 Ω – – – 2.2F – – – 100 Ω – – – – 200 Ω – 51 Ω – 3.3F – – – – – – – – – – 51 Ω – 4.7F – – – – – – – – 100 Ω – – – 5.0F – – 100 Ω – – – – – – – – – 5.6F – – – – – – – – – – 20 Ω – * Capacitance values according to the constant current discharge method.

SuperCapacitor USER'S MANUAL VOL.01 19

2017.05.17 9565SCGVOL01E1705H1 2. Measuring capacitance using the constant current (2) Equivalent series resistance (ESR) discharge method ESR is calculated from expression (10) by using a 1 kHz (0H: 5.5V products) oscillator, pouring an AC current of 10 mA and measuring the

Once the pin to pin voltage of the capacitor in the circuit voltage (VC) between both ends of the capacitor. below has reached 5.5V, charging is continued for another VC 30 minutes (Note 1). Equivalent series resistance : ESR = (Ω) (10) 0.01 Then, a constant current-load device is used to discharge 10 mA the capacitor at a current of 0.22 mA (Note 2), and the time for the terminal voltage to fall from 3.0V to 2.5V is measured. f : 1 kHZ C VC This value is used in the equation below to calculate the capacitance. Note 1: Products with 1.0F or more capacitance should be charged for 60 minutes. Note 2: The current value during discharge is 1 mA per 1F. (3) Current (30-minute value) The current value is calculated from expression (11) by I × (T2 – T1) Capacitance : C = (F) applying a voltage to the capacitor (C), and measuring the V 1 – V 2 voltage (VR) between both ends of the series resistor (RC) mA SW 30 minutes later. Prior to measurement, short between both A pins of the capacitor for 30 minutes or more to let it discharge. R 5.5V V C Follow the indication of the product when determining the polarity of the capacitor during charging.

VR 3 5.5V Current: I = × 10 (mA) (11) V1 : 3.0V ) RC V 1 ( V V2 : 2.5V

V2 VR voltage

0 T1 T2 Time (sec) RC Switch 30 minutes + C E0 – (0V: 3.5V products) Once the pin to pin voltage of the capacitor in the circuit E0: Conforms to E0 of capacitance measuring condition. below has reached 3.5V, charging is continued for another RC: 0.01 to 0.056F : 1 k Ω 30 minutes (Note 1). 0.1 to 0.47F : 100 Ω Then, a constant current-load device is used to discharge 1 to 2.2F : 10 Ω (Note 2) the capacitor at a current of 0.22 mA , and the time for FS Series 11 Vdc, 12 Vdc products the terminal voltage to fall from 1.8V to 1.5V is measured. 0.47F to 1.0F : 100 Ω This value is used in the equation below to calculate the 5.0F : 10 Ω capacitance. FG Series Note 1: Products with 1.0F or more capacitance should be charged 1.0F to 4.7F : 10 Ω for 60 minutes. Note 2: The current value during discharge is 1 mA per 1F. FT Series 1.0F to 5.6F : 10 Ω I × (T2 – T1) Capacitance : C = (F) (4) Self-discharge characteristic 1 – V 2 V (except FA, FE, FS, FT, FME, FML series, and 3.5 V and mA SW 6.5 V product) A

R The self-discharge characteristic is measured by charging 3.5V V C a voltage of 5.0 VDC (charge protection resistance: 0 Ω) according to the capacitor polarity for 24 hours, then releasing

3.5V between the pins for 24 hours and measuring the pin-to-pin V1 : 1.8V )

V 1 voltage. ( V V2 : 1.5V

voltage This test should be carried out in an environment with an

0 ambient temperature of 25 °C or below and relative humidity T1 T2 Time (sec) 30 minutes of 70%RH or below.

SuperCapacitor USER'S MANUAL VOL.01 20

2017.05.17 9565SCGVOL01E1705H1 8 SELECTION GUIDE

8.1 Calculating Backup Time (2) When backup current is 1 mA or below (1) When backup current is 1 mA or greater (FG, FM, FC, FR, FY series is most suitable.) (FS, FT, FME, FE, FA Series is most suitable.) There is no particularly great potential drop. The available An approximate backup time can be calculated from backup time is calculated from the constant-resistance expression (12). discharge characteristic obtained by converting the backup current to a constant-resistance load. C × (V0 – V1 – Vdrop) T = (sec) (12) I C : SuperCapacitor capacitance (F) For the constant-resistance discharge characteristic when the backup current value is converted to a constant-resistance V0 : Voltage charged in SuperCapacitor (V) load, see the each Series datasheet. Vdrop : Voltage drop by DC resistance in SuperCapacitor (V)

V1 : Minimum required voltage for backup circuit (V) I : Backup current (A)

The voltage drop is determined by the DC resistance and backup current of the SuperCapacitor.

Table 1 shows DC resistance values (typical values) of each product.

An approximate voltage drop Vdrop can be calculated from expression (13).

Vdrop = RiI (V) (13)

Ri : DC resistance of SuperCapacitor (Ω) I : Backup current (A)

Vdrop 0 V'0

Available backup voltage

V1 Minimum voltage required for backup Pin voltage of SuperCapacitor V'

Available backup time T Backup start Fig. 24 Voltage Waveform during Backup

SuperCapacitor USER'S MANUAL VOL.01 21

2017.05.17 9565SCGVOL01E1705H1 8.2 Leakage Current at 25˚C This indicates the charge current measured from the pin-to- V pin voltage of the charge resistor when the SuperCapacitor 1kΩ is charged for many hours. The charge current decreases 10 5V C as the time passes by. Continuing charging comes to a point Charge current I = V (A) where this charge current will not decrease any more but 1000 remains constant (Figures 25 to 34).

FG0H225ZF This is deﬁ ned as the leakage current.

μ FG0H105ZF 1 In addition, the leakage current generally changes in

proportion to capacitance. FG0H474ZF

FG0H224ZF Charge current ( A)

FG0H104ZF

0.1 FG0H473ZF FG0H223ZF

100 200 300 400 500 600 700 Charge Time (h)

Fig. 25 Charge Characteristic over Many Hours: FG Series

at 25˚C V

1kΩ 1 5V C

Charge current I = V (A) 1000 at 25˚C 1000 V

1kΩ 5V C FM0H104ZF V µ Charge current I = (A) 1000 0.1 100 FM0H473ZF

μ FM0H223ZF Charge current ( A) FM0H103ZF 10 FC0H105ZF-SS Charge current ( A)

0.01 1 FC0H474ZF-SS FC0H224ZF/FCS0H224ZF

FC0H104ZF/FCS0H104ZF FC0H473ZF/FCS0H473ZF 0.1 100 200 0 100 200 300 400 500 600 700 Charge Time (h) Charge Time (h)

Fig. 26 Charge Characteristic over Many Hours: FM Series Fig. 27 Charge Characteristic over Many Hours: FC Series

SuperCapacitor USER'S MANUAL VOL.01 22

2017.05.17 9565SCGVOL01E1705H1 at 25˚C V

1kΩ 100 5V C

V Charging current I= (A) 1000 at 25˚C 1000 V FS0H105ZF 1kΩ 5V C FS0H474ZF

Charge current I = V (A) 100 1000 10 FT0H565ZF µ FT0H335ZF µ FT0H225ZF FS0H224ZF FT0H105ZF FS0H104ZF 10 Charge current ( A) FT0H474ZF FT0H224ZF FS0H473ZF Charge current ( A) FT0H104ZF 1 1

0.1 100 200 300 400 500 600 700 0 100 200 300 400 500 600 700 Charge Time (h) Time (h)

Fig. 28 Charge Characteristic over Many Hours: Fig. 29 Charge Characteristic over Many Hours: FT Series FS Series (0H)

at 25˚C V

1kΩ 10 5V C at 25˚C 10000

V Charge current I = V (A) 1000

1kΩ 10V C 1000 V Charging current I= (A) 1000

µ 1 FR0H105ZF 100

µ FR0H474ZF Charge current ( A)

10 FR0H224ZF

Charge current ( A) FR0H104ZF FSIA474ZF FR0H473ZF FSIA105ZF 0.1 1 FR0H223ZF

0.1 0 50 100 150 200 100 200 300 400 500 600 700 Charge Time (h) Time (h) Fig. 31 Charge Characteristic over Many Hours: FR Series Fig. 30 Charge Characteristic over Many Hours: FS Series (1A)

SuperCapacitor USER'S MANUAL VOL.01 23

2017.05.17 9565SCGVOL01E1705H1 at 25˚C at 25˚C V V

1kΩ 1kΩ 10 5V C 10 5V C

V Charge current I = V (A) Charge current I = (A) 1000 1000

FYD0H225ZF FYH0H105ZF FYD0H145ZF

µ µ FYD0H105ZF 1 1 FYH0H474ZF FYD0H474ZF FYH0H224ZF FYD0H224ZF Charge current ( A) Charge current ( A) FYH0H104ZF

FYH0H473ZF FYD0H104ZF

0.1 0.1 FYD0H473ZF FYH0H223ZF FYD0H223ZF

100 200 300 400 500 600 700 100 200 300 400 500 600 700 Charge Time (h) Charge Time (h)

Fig. 32 Charge Characteristic over Many Hours: Fig. 33 Charge Characteristic over Many Hours: FY Series (FYD Type) FY Series(FYH Type)

at 25˚C at 25˚C

V V

1kΩ 1kΩ 1 5V C 100 5V C

V V Charge current I = (A) Charging current I= (A) 1000 1000

µ FE0H155ZF

0.1 FYL0H473ZF 10 FA0H105ZF, FE0H105ZF

FYL0H223ZF FA0H474ZF, FE0H474ZF

Charge current ( A) FA0H224ZF, FE0H224ZF

Charge current ( A) FYL0H103ZF

FA0H104ZF, FE0H104ZF

0.01 1 FA0H473ZF, FE0H473ZF

100 200 100 200 Charge Time (h) Charge Time (h)

Fig. 34 Charge Characteristic over Many Hours: Fig. 35 Charge Characteristic over Many Hours: FY Series (FYL Type) FA Series (0H), FE Series

SuperCapacitor USER'S MANUAL VOL.01 24

2017.05.17 9565SCGVOL01E1705H1 at 25˚C

1kΩ 100 10V C

V Charging current I= (A) 1000

FAIA474ZF

10 FAIA224ZF µ

FAIA104ZF Charge current ( A) FAIA223ZF

100 200 Time (h) Fig. 36 Charge Characteristic over Many Hours: FA Series (1A)

8.3 Estimation of Life 1000000

The external factor that must affects the life of a SuperCapacitor is the operating ambient temperature (average

temperature). 100000 10 years

If the life of a SuperCapacitor is deﬁ ned as the point at which 5 years capacitance is reduced to 70% of the initial value, then it is known through high temperature load life tests that the life is FYD0H145ZF 10000 reduced by half with an increase of 10°C temperature. FS0H473ZF

FYH0H223ZFSolid line: Actual value Dotted line: Estimated value

（t0ーt） Acceleration coeﬃcient =2 θ 1000 θ= 10 (25-70℃)

to: Temperature at which data has been obtained with high temperature load life test Time by whichcapacitance is reduced 30% from initial value ( h) t: Temperature at which life estimation is carried out

100 90 80 70 60 50 40 30 20 Temperature (℃)

Fig. 37 Life Estimation

SuperCapacitor USER'S MANUAL VOL.01 25

2017.05.17 9565SCGVOL01E1705H1 240 240 120 120

220 220

200 200 100 100

180 180

160 160 80 80

140 140

70˚C, 5.5V 70˚C, 5.5V 85˚C, 5.5V 85˚C, 5.5V 120 120 60 60

100 100 85˚C, 5.5V 85˚C, 5.5V 70˚C, 5.5V 70˚C, 5.5V 80 80 40 40

60 60

40 40 20 20 Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) 20 20

0 0 0 0 100 100 1,000 1,000 10,000 10,000 100 100 1,000 1,000 10,000 10,000 Initial value Initial value Initial value Initial value Time (h) Time (h) Time (h) Time (h)

20 20 20 20

10 10 10 10

0 0 0 0

–10 –10 –10 –10

70˚C, 5.5V 70˚C, 5.5V –20 –20 85˚C, 5.5V 85˚C, 5.5V70˚C, 5.5V 70˚C, 5.5V –20 –20 –30 –30 –30 –30 85˚C, 5.5V 85˚C, 5.5V –40 –40 –40 –40

–50 –50 –50 –50

–60 –60 –60 –60

–70 –70 –70 –70

–80 –80 –80 –80 Capacitance rate of change (%) Capacitance rate of change (%) Capacitance rate of change (%) Capacitance rate of change (%)

100 100 1,000 1,000 10,000 10,000 100 100 1,000 1,000 10,000 10,000 Initial value Initial value Initial value Initial value Time (h) Time (h) Time (h) Time (h)

Fig. 38 High Temperature Load Life Test: FYH0H223ZF Fig. 39 High Temperature Load Life Test: FM0H473ZF

240 240 60 60

220 220

200 200 50 50

180 180

160 160 40 40

140 140

120 120 30 30

100 100

70˚C, 5.5V 70˚C, 5.5V 80 80 20 20 85˚C, 5.5V 85˚C, 5.5V

60 60 85˚C, 5.5V 85˚C,70˚C, 5.5V 5.5V 70˚C, 5.5V 40 40 10 10 Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) 20 20

0 0 0 0 100 100 1,000 1,000 10,000 10,000 100 100 1,000 1,000 10,000 10,000 Initial valueInitial value Initial valueInitial value Time (h)Time (h) Time (h)Time (h)

20 20 20 20

10 10 10 10

0 0 0 0

–10 –10 –10 –10 70˚C, 5.5V70˚C, 5.5V 85˚C, 5.5V85˚C, 5.5V70˚C, 5.5V70˚C, 5.5V –20 –20 –20 –20 85˚C, 5.5V85˚C, 5.5V –30 –30 –30 –30

–40 –40 –40 –40

–50 –50 –50 –50

–60 –60 –60 –60

–70 –70 –70 –70

–80 –80 –80 –80 Capacitance rate of change (%) Capacitance rate of change (%) Capacitance rate of change (%) Capacitance rate of change (%)

100 100 1,000 1,000 10,000 10,000 100 100 1,000 1,000 10,000 10,000 Initial valueInitial value Initial valueInitial value Time (h)Time (h) Time (h)Time (h)

Fig. 40 FS0H473ZF Fig. 41 FYD0H145ZF

SuperCapacitor USER'S MANUAL VOL.01 26

2017.05.17 9565SCGVOL01E1705H1 2.4 2.4 20 20

2.2 2.2 10 10

2.0 2.0 0 0

1.8 1.8 –10 –10 70˚C, 5.5V70˚C, 5.5V 1.6 1.6 –20 –20

1.4 1.4 –30 –30

1.2 1.2 –40 –40

1.0 1.0 –50 –50

0.8 0.8 –60 –60

0.6 0.6 –70 –70

0.4 0.4 70˚C, 5.5V70˚C, 5.5V –80 –80 Equivalent series resistance ( Ω ) Equivalent series resistance ( Ω ) Capacitance rate of change (%) Capacitance rate of change (%) 0.2 0.2

0 0 100 100 1,000 1,000 10,000 10,000 100 100 1,000 1,000 10,000 10,000 Initial valueInitial value Initial valueInitial value Time (h)Time (h) Time (h)Time (h)

Fig. 42 FE0H105ZF

(2) Overvoltage life Failure rate The next external factor most affecting the life of a The failure rate of a SuperCapacitor is estimated to be 0.06 SuperCapacitor following the ambient temperature is Fit. The failure rate calculated based on market claim data the voltage applied. Applying overvoltage affects the life. is approximately 0.006 Fit. However, 0.06 Fit is assumed However, if the voltage applied is equal to or lower than the because it is estimated that there are ten times as many latent maximum operating voltage, there is almost no inﬂ uence. The are not directly connected to returning of products. results of overvoltage life tests for the FS0H473ZF (Figure 43) and FY series (Figure 44) are shown below.

(Ambient temperature 70˚C) (Ambient temperature 70˚C) 200 200

160 160

7.0V 120 120

80 6.5V 80 6.0V (5.5V) 40 40 6.0V

0 0 5.5V

–40 –40

Equivalent series resistance rate of change (%) 0 240 500 1,000 Equivalent series resistance rate of change (%) 0 250 500 1,000 Time (h) Time (h) (Ambient temperature 70˚C) (Ambient temperature 70˚C) 20 20

0 0 5.5V –20 (5.5V) –20 6.0V 6.0V –40 6.5V –40 7.0V

–60 –60

–80 –80 Capacitance rate of change (%) Capacitance rate of change (%)

–100 –100 0 240 500 1,000 0 250 500 1,000 Time (h) Time (h)

Note There are 10 samples for each voltage. Note There are 20 samples for each voltage. The above figure shows their average. The above figure shows their average.

Fig. 43 FS0H473ZF Overvoltage Life Test Fig. 44 FYH0H223ZF Overvoltage Life Test

SuperCapacitor USER'S MANUAL VOL.01 27

2017.05.17 9565SCGVOL01E1705H1 8.4 Washing Resistance Figure 45 shows a cross section of a washing-resistant Standard SuperCapacitor products except the FM series are product. Table 2 shows a list of washing-resistant products not designed to be washed. However, a washing-resistant and Table 3 shows their washing-resistant performance. product is available which has been resin-sealed to prevent washing liquid from permeating into the product.

Outer case

Capacitor base cell

Isolation case

Sealing resin Outer tube

+ Pins (lead plates) –

Fig. 45 Cross Seciton of SuperCapacitor(Washing-Resistant Product)

Table 2. Washing-Resistant Products

Series Name Name of Washing-Resistant Product Name of Non-Washing-Resistant Product Remarks FA FAW • • • • • • FA • • • • • • W : Denotes washing-resistant FE FEW • • • • • • FE • • • • • • product. FS FSW • • • • • • FS • • • • • • FSH FSH • • • • • • – W FSH • • • • • • FYD FYD • • • • • • – W FYD • • • • • • FYH FYH • • • • • • – W FYH • • • • • • FR FRW • • • • • • FR • • • • • • FG FGW • • • • • • FG • • • • • • FGH FGH • • • • • • – W FGH • • • • • • FT FTW • • • • • • FT • • • • • • FM FM • • • • • • None ＊ FC Series are not washable.

Table 3. Washing Resistance of Washing-Resistant (Resin-Sealed) Product

Series Name Product Name Washing Solution Washing Method Washing Times Remarks FA FAW • • • • • • Dipping at normal temperature Within 10 minutes When combining different Boiling, vapor Within 2 minutes washing methods, the total Alcohol Water Warm water (70 °C or below) Within 2 minutes washing time should not be Ultrasonic Within 1 minute exceed 10 minutes. FE FEW • • • • • • Ditto Ditto Ditto Ditto FS FSW • • • • • • Ditto Ditto Ditto Ditto FSH FSH • • • • • • – W Ditto Ditto Ditto Ditto FYD FYD • • • • • • – W Ditto Ditto Ditto Ditto FYH FYH • • • • • • – W Ditto Ditto Ditto Ditto FR FRW • • • • • • Ditto Ditto Ditto Ditto FG FGW • • • • • • Ditto Ditto Ditto Ditto FGH FGH • • • • • • – W Ditto Ditto Ditto Ditto FT FTW• • • • • • Ditto Ditto Ditto Ditto FM FM • • • • • • Ditto Ditto Ditto Ditto

SuperCapacitor USER'S MANUAL VOL.01 28

2017.05.17 9565SCGVOL01E1705H1 8.5 Inﬂ uence of Inverse Connection 8.6 Series and Parallel Connections (1) There is no influence on the long-term reliability of a (1) Series connection SuperCapacitor. Ensure that a voltage is distributed equally to all capacitors which are connected in series and that the voltage does not (2) In the manufacturing process, the SuperCapacitor is exceed the maximum operating voltage. processed with a voltage applied in the positive direction. For this reason, there may be cases where a small amount (2) Parallel connection of charge still remains. There is also a SuperCapacitor Any parallel connections are possible. speciﬁ c phenomenon in which a voltage which was previously applied returns. Special care is required to avoid damage to semiconductors, etc. which are vulnerable to an inverse voltage.

(3) Figure 46 shows the voltage retention characteristic for normal and inverse connections. It is seen from Figure 46 that the voltage retention characteristic deteriorates. However, even in the case of inverse connection, if the time of inverse charging exceeds 100 hours, it shows the same self-discharge characteristic as charging in the positive direction.

Time of Charging in Positive Direction - Self-Discharge Characteristic (Normal Temperature)

Sample : FS0H473ZF

Charge condition 5 Voltage : 5Vdc Time : 48h charge 3h charge 4 30minutes charge 3minutes charge

Note Average of each 10p

2 Pin-to-pin voltage (V) voltage Pin-to-pin

0 10 100 1,000 Time (h)

Time of Charging in Inverse Direction - Self-Discharge Characteristic (Normal Temperature)

Sample : FS0H473ZF

Charge condition 5 Voltage : 5Vdc (inverse direction) Time : 240h charge 24h charge 4 2.4h charge 0.24minutes charge 90sec charge 3

Pin-to-pin voltage (V) voltage Pin-to-pin Note Average of each 10p

0 10 100 1,000 Time (h)

Fig. 46 Voltage Retention Characteristic for Normal and Inverse Connections

SuperCapacitor USER'S MANUAL VOL.01 29

2017.05.17 9565SCGVOL01E1705H1 9 OPERATING PRECAUTIONS

1. Circuitry design between each capacitor will not vary. 1.1 Useful life The electrical double layered capacitor (SuperCapacitor) 1.6 Outer sleeve insulation uses electrolyte and is sealed with rubber etc. Water in the The outer sleeve wrapped around the SuperCapacitor electrolyte can evaporate in use over long periods at high indicates that it is sealed, however the outer sleeve is not temperatures, thus reducing electrostatic capacity which in guaranteed for insulation purposes. Therefore, it cannot be turn will create greater internal resistance. The characteristics used where insulation is necessary. of the SuperCapacitor can vary greatly depending on the environment it is used in. Therefore, controlling the usage 1.7 Polar characteristics environment will ensure prolonged life of the part. The SuperCapacitor is manufactured so that the terminal Basic breakdown mode is an open mode due to increased on the outer case is negative (-). Align the (-) symbol during internal resistance. use. Even though discharging has been carried out prior to shipping, any residual electrical charge may negatively affect 1.2 Fail rate in the ﬁ eld other parts. Based on field data, the fail rate is calculated at approx. 0.006Fit. We estimate that unreported failures are ten times 1.8 Use next to heat emitters this amount. Therefore, we assume that the fail rate is below Useful life of the SuperCapacitor will be signiﬁ cantly affected 0.06Fit. if used near heat emitting items (coils, power transistors, and posistors etc) where the SuperCapacitor itself may become 1.3 Voltage application when maximum usable voltage is heated. exceeded Performance may be compromised, and in some cases 1.9 Usage environment leakage or damage may occur if applied voltage exceeds This device cannot be used in any acidic, alkaline or similar maximum working voltage. type of environment.

1.4 Use of capacitor as a smoothing capacitor (ripple 2. Mounting absorption) in electrical circuits 2.1 Mounting onto a reﬂ ow furnace As SuperCapacitors contain a high level of internal resistance, Except for the FC series, it is not possible to mount this they are not recommended for use as electrical smoothing capacitor onto an IR / VPS reﬂ ow furnace. Do not immerse capacitors in electrical circuits. the capacitor into a soldering dip tank. Performance may be compromised, and in some cases leakage or damage may occur if a SuperCapacitor is used in 2.2 Flow soldering conditions ripple absorption. Keep solder under 260℃ and soldering time to within 10 seconds when using the flow automatic soldering method. 1.5 Series connections (Except for the FC series) As applied voltage balance to each SuperCapacitor is lost when used in series connection, excess voltage may 2.3 Installation using a soldering iron be applied to some SuperCapacitors, which will not only Care must be taken to prevent the soldering iron from touching negatively affect its performance but may also cause leakage other parts when soldering. Keep the tip of the soldering iron and/or damage. under 400℃ and soldering time to within 3 seconds. Always Allow ample margin for maximum voltage or attach a circuit make sure that the temperature of the tip is controlled. Internal for applying equal voltage to each SuperCapacitor (partial capacitor resistance is likely to increase if the terminals are pressure resistor/voltage divider) when using SuperCapacitors overheated. in series connection. Also, arrange SuperCapacitors so that the temperature

SuperCapacitor USER'S MANUAL VOL.01 30

2017.05.17 9565SCGVOL01E1705H1 2.4 Lead terminal processing Do not attempt to bend or polish the capacitor terminals with sand paper etc. Soldering may not be possible if the metallic plating is removed from the top of the terminals.

2.5 Cleaning, Coating, and Potting Except for the FM series, cleaning, coating, and potting must not be carried out. Consult us if this type of procedure is necessary. Terminals should be dried at less than the maximum operating temperature after cleaning.

3. Storage 3.1 Temperature and Humidity Make sure that the SuperCapacitor is stored according to the following conditions: Temp.: 5～35˚C (Standard 25), Humidity: 20～70% (Standard: 50%). Do not allow the build up of condensation through sudden temperature change.

3.2 Environment conditions Make sure that there are no corrosive gasses like sulfur dioxide as penetration of the lead terminals is possible. Always store this item in an area with low dust and dirt levels. Make sure that the packaging will not be deformed through heavy loading, movement and/or knocks. Keep out of direct sunlight, and away from radiation, static electricity, and magnetic ﬁ elds.

3.3 Maximum storage period This item may be stored up to one year from the date of delivery if stored at the conditions stated above. This product should be safe to use even after being stored for over a 1 year period. However, depending on the storage conditions, we recommend that the soldering is checked.

4. Dismantling There is a small amount of electrolyte stored within the capacitor. Do not attempt to dismantle as direct skin contact with the electrolyte will cause burning. This product should be treated as industrial waste and not is not to be disposed of by ﬁ re.

5. Applicable Laws and Regulations This product satisﬁ es the requirements of the RoHS Directive (2002/95/EC) (related to the speciﬁ ed hazardous substances contained in electrical and electronic equipment).

SuperCapacitor USER'S MANUAL VOL.01 31

2017.05.17 9565SCGVOL01E1705H1 FC-SERIES SuperCapacitor 10 (Surface Mounting Type)

FC Series SuperCapacitors are surface mounting type Part Number System products. Generally, conventional electrically-double-layered capacitors have been mounted on surface mount PWBs by FC 0H 105 Z F TB R 44 -SS soldering with solder iron, or by being mounted on the holders Tape width soldered by the reflow soldering process in advance. FC Anode terminal Series SuperCapacitors have been developed for mounting position for tape directly by reﬂ ow soldering. forwarding direction

Supplied with chips mounted Features on intended square-hole • Surface mounting possible plastic tape • Wide range of temperature from –25°C to +70°C Environmental impact • Maintenance free reduced products • High rated voltage of 5.5V guaranteed Capacitance tolerance • High reliability for prevention of liquid leakage Maintenance Z : +80 %; –20 % free. Nominal capacitance : 1.0F • Lead-free type. RoHS Compliant. First 2 digits represent significant figures. Third digit specifies Application number of zeros to follow μ F code. Sub-power supply Maximum Rated voltage Backup of power supply 0H: 5.5 Vdc,0V: 3.5 Vdc Backup of memory at battery exchange SuperCapacitor: FC : FC Series FCS : FCS Type

SuperCapacitor USER'S MANUAL VOL.01 32

2017.05.17 9565SCGVOL01E1705H1 Precautions for use • This series is exclusively for refl ow soldering. It is designed • Applying refl ow soldering is limited to 2 times. After the fi rst for thermal conduction system such as combination use refl ow, cool down the capacitor thoroughly to 5-35℃ before of infrared ray and heat blow. Consult with TOKIN before the second refl ow. applying other methods. • The reflow condition must be kept within reflow profile Always consult with TOKIN when applying refl ow soldering in graphs shown below. a more severe condition than the condition described here.

・FCS Type ・FC Type

Reflow profile Reflow profile Temperature on the Peak temperature Peak temperature : capacitor top 235℃，within 10sec. 300 250 260℃ 250 ) 200 217℃ 160 ℃ 200 200℃ 150 70sec ℃ 150 150 120 sec 150sec 100 100 c a p i t o r ( ℃ ) e m p r a t u ( ℃ T e m p r a t u o n h T 50 50 Tp Time exceeding 200℃ 0 0 0 50 100 150 200 250 300 350 400 Time ( sec) Time (sec)

Tp Time exceeding 200℃ ・Above "Reﬂ ow Proﬁ le" graph indicates temperature at the terminals 250

and capacitor top. 240

230

220 Peak temperature Below 260℃ 210 ℃ Over 255 Within 10sec. P e a k t m p r u ( ℃ ) 200 ℃ Over 230 Within 45sec. 0 10 20 30 40 50 60 Over 220℃ Within 60sec. Tp (sec) Over 217℃ Within 70sec. Time between 150℃ to 200℃ 150sec. ・Above "Reﬂ ow Proﬁ le" graph indicates temperature at the terminals (temperature zone over 170℃＝ within 50sec.) and capacitor top.

SuperCapacitor USER'S MANUAL VOL.01 33

2017.05.17 9565SCGVOL01E1705H1 Markings Dimensions

Nominal capacitance, maximum operating voltage, serial B±0.2 number, and polarity are marked. D±0.5 A±0.2 H max. Negative W±0.1 L terminal Conversion table for manufacture date code K Positive Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 terminal I P I Indication A B C D E F H J K L M N Month 1 2 3 4 5 6 7 8 9 10 11 12 Indication 1 2 3 4 5 6 7 8 9 O N D

Polarity Nominal Polarity Nominal (negative) capacitance Series name MAX (negative) capacitance operating voltage MAX N T MAX Polarity 473 operating voltage 473 operating voltage (negative) FC 5.5V 5.5V 474 5.5V A1 S FCS Type A1-001 Nominal A1 capacitance Date code Serial number Date code Date code FCS0H473ZFTBR24 FC0H474ZFTBR32-SS FC0H473ZFTBR24 FCS0H104ZFTBR24 FC0H105ZFTBR44-SS FC0H104ZFTBR24 FCS0H224ZFTBR24 FC0H224ZFTBR24 FCS0V104ZFTBR24 FC0V104ZFTBR24 FCS0V224ZFTBR24 FC0V224ZFTBR24 FCS0V474ZFTBR24 FC0V474ZFTBR24

Standard Ratings

FCS Type

Max. Nominal Max. ESR Max. Voltage Dimension (Unit:mm) Operating Capacitance current at Holding Weight Part Number (at 1kHz) (g) Voltage Discharge (Ω) 30 minutes Characteristic (Vdc) system (F) (mA) Min. (V) D H A B I W P K L +0.3 FCS0H473ZFTBR24 5.5 0.047 100 0.071 4.2 10.7 5.5 10.8 10.8 3.9±0.5 1.2 5.0 0.9±0.3 0 −0.1 1.0 +0.3 FCS0H104ZFTBR24 5.5 0.10 50 0.15 4.2 10.7 5.5 10.8 10.8 3.9±0.5 1.2 5.0 0.9±0.3 0 −0.1 1.0 +0.3 FCS0H224ZFTBR24 5.5 0.22 50 0.33 4.2 10.7 8.5 10.8 10.8 3.9±0.5 1.2 5.0 0.9±0.3 0 −0.1 1.4 +0.3 FCS0V104ZFTBR24 3.5 0.10 100 0.09 — 10.7 5.5 10.8 10.8 3.9±0.5 1.2 5.0 0.9±0.3 0 −0.1 1.0 +0.3 FCS0V224ZFTBR24 3.5 0.22 50 0.20 — 10.7 5.5 10.8 10.8 3.9±0.5 1.2 5.0 0.9±0.3 0 −0.1 1.0 +0.3 FCS0V474ZFTBR24 3.5 0.47 50 0.42 — 10.7 8.5 10.8 10.8 3.9±0.5 1.2 5.0 0.9±0.3 0 −0.1 1.4

FC Type

Max. Nominal Max. ESR Max. Voltage Dimension (Unit:mm) Operating Capacitance current at Holding Weight Part Number (at 1kHz) (g) Voltage Discharge (Ω) 30 minutes Characteristic (Vdc) system (F) (mA) Min. (V) D H A B I W P K L +0.3 FC0H473ZFTBR24 5.5 0.047 50 0.071 4.2 10.5 5.5 10.8 10.8 3.6±0.5 1.2 5.0 0.7±0.3 0 −0.1 1.0 +0.3 FC0H104ZFTBR24 5.5 0.10 25 0.15 4.2 10.5 5.5 10.8 10.8 3.6±0.5 1.2 5.0 0.7±0.3 0 −0.1 1.0 +0.3 FC0H224ZFTBR24 5.5 0.22 25 0.33 4.2 10.5 8.5 10.8 10.8 3.6±0.5 1.2 5.0 0.7±0.3 0 −0.1 1.4 +0.5 FC0H474ZFTBR32-SS 5.5 0.47 13 0.71 4.2 16.0 9.5 16.3 16.3 6.8±1.0 1.2 5.0 1.2±0.5 0 −0.1 4.0 +0.5 FC0H105ZFTBR44-SS 5.5 1.0 7 1.50 4.2 21.0 10.5 21.6 21.6 7.0±1.0 1.4 10.0 1.2±0.5 0 −0.1 6.7 +0.3 FC0V104ZFTBR24 3.5 0.10 50 0.09 — 10.5 5.5 10.8 10.8 3.6±0.5 1.2 5.0 0.7±0.3 0 −0.1 1.0 +0.3 FC0V224ZFTBR24 3.5 0.22 25 0.20 — 10.5 5.5 10.8 10.8 3.6±0.5 1.2 5.0 0.7±0.3 0 −0.1 1.0 +0.3 FC0V474ZFTBR24 3.5 0.47 25 0.42 — 10.5 8.5 10.8 10.8 3.6±0.5 1.2 5.0 0.7±0.3 0 −0.1 1.4

SuperCapacitor USER'S MANUAL VOL.01 34

2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics

Series name FC, FCS Test conditions (conforming to JIS C 5160-1) Item 5.5V type, 3.5V type Category temperature range −25℃ to +70℃ MAX operating voltage 5.5Vdc, 3.5Vdc Capacitance Refer to standard ratings Refer to “Measurement Conditions” Capacitance allowance +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also “Measurement ESR Refer to standard ratings Conditions” Current (30-minutes value) Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：4.0V (3.5V type, 3.6V type) ：6.3V (5.5V type) ESR Less than 120% of initial specifi ed value Charge：30 sec. Current (30 minutes value) Less than 120% of initial specifi ed value Discharge：9min 30sec. Number of cycles：1000 Series resistance ：0.043F, 0.047F 300Ω * ： Ω Surge 0.068F 240 ：0.10F 150Ω Appearance No obvious abnormality ：0.22F 56Ω ：0.47F 30Ω ：1.0F 15Ω Discharge resistance：0Ω Temperature：70±2℃ More than 50% of initial Capacitance measured value Phase 2 Less than 400% of initial ESR measured value Capacitance Phase 3 ESR Conforms to 4.17 Phase1：+25±2℃ * Less than 200% of initial ： ℃ Characteristics in Capacitance Phase2 −25±2 measured value ：+ ℃ different temperature Phase4 25±2 ESR Phase 5 Satisfy initial specifi ed value Phase5：+70±2℃ Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below Within ±20% of initial Capacitance measured value ESR Phase 6 Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Capacitance ESR Satisfy initial specifi ed value Conforms to 4.13 * ： Vibration resistance Frequency 10 to 55 Hz Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality Capacitance Cooled down to ambient temperature after refl ow * ESR Satisfy initial specifi ed value Solder heat resistance soldering, then the product must fulfi ll the condition Current (30 minutes value) stated left. (See page 10 for refl ow condition) Appearance No obvious abnormality Capacitance Conforms to 4.12 * ESR Satisfy initial specifi ed value Temperature condition：−25℃→ Room temperature → Temperature cycle Current (30 minutes value) +70℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality Capacitance Within ±20% of initial measured value Conforms to 4.14 * ESR Less than 120% of initial specifi ed value ： ℃ High temp. and high Temperature 40±2 ：％ humidity resistance Current (30 minutes value) Less than 120% of initial specifi ed value Relative humidity 90 to 95 RH Testing time：240±8 hours Appearance No obvious abnormality Capacitance Within ±30% of initial measured value Conforms to 4.15 ESR Less than 200% of initial specifi ed value Voltage applied：MAX operating voltage * ： ℃ High temperature load Temperature 70±2 Current (30 minutes value) Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality Testing time：1000 0 Hours Voltage applied：5.0Vdc (Terminal Charging at the case's side be negative) condition Series resistance：0Ω ： * 5.5V type: Voltage between terminal leads Charging time 24 hours Self discharge characteristics higher than 4.2V Let stand for 24 hours in condition (voltage holding characteristics) 3.5V type: Not specifi ed described below with terminals Storage opened. Ambient temperature：Lower than 25℃ Relative humidity：Lower than 70%RH * The characteristics above must be satisfi ed for asterisked items after the end of refl ow soldering (according to the refl ow condition shown on page 32).

SuperCapacitor USER'S MANUAL VOL.01 35

2017.05.17 9565SCGVOL01E1705H1 Tape and Reel Dimensions [Reel Dimensions] (mm) Mark TBR24 TBR32 TBR44 E A 380±2 330±2 380±2 C Product height 5.5mm 80±1 B 100±1 100±1 Product height 8.5mm 100±1 B C 13±0.5 13±0.5 13±0.5 R:10 D D 21±0.8 21±0.8 21±0.8 E 2±0.5 2±0.5 2±0.5 Product height 5.5mm 25.5±0.5 t W 33.5±1.0 45.5±1.0 A Product height 8.5mm 25.5±1.0 W t 2.0 2.0 2.0

Dimensions of indented [square-hole plastic tape] TBR16/24 (mm) Sprocket hole φD0 t1 Mark TBR24 TBR32 TBR44 P2 P0

E W 24.0 32.0 44.0 A F A 11.4 18.0 23.0 W

B B 13.0 20.0 25.0

P0 4.0 4.0 4.0 Indented square-hole P1 Forward direction for fitting SuperCapacitors P1 16.0 24.0 32.0 t2 Supercapacitors fitting on square-hole P2 2.0 2.0 2.0 F 11.5 14.2 20.2 TBR32/44 φD0 φD0 1.55 1.55 1.55 t1 P2 P0 E t1 0.4 0.5 0.5

A F E 1.75 1.75 1.75 B G

W Product height 5.5mm 6.0 t2 10.0 12.0 Product height 8.5mm 8.4

G – 28.4 40.4 t2 SuperCapacitors fitting P1 on square-hole R0.75 0.2

Recommended land pattern Land pattern Lead terminal

(mm) (mm) Part Number A B C Part Number A B C FCS0H473ZFTBR24 5.0 4.9 2.5 FCS0H473ZFTBR24 5.0 3.9 1.2 FCS0H104ZFTBR24 5.0 4.9 2.5 FCS0H104ZFTBR24 5.0 3.9 1.2 FCS0H224ZFTBR24 5.0 4.9 2.5 FCS0H224ZFTBR24 5.0 3.9 1.2 FCS0V104ZFTBR24 5.0 4.9 2.5 FCS0V104ZFTBR24 5.0 3.9 1.2 FCS0V224ZFTBR24 5.0 4.9 2.5 FCS0V224ZFTBR24 5.0 3.9 1.2 C FCS0V474ZFTBR24 5.0 4.9 2.5 FCS0V474ZFTBR24 5.0 3.9 1.2 FC0H473ZFTBR24 5.0 4.9 2.5 FC0H473ZFTBR24 5.0 3.6 1.2 FC0H104ZFTBR24 5.0 4.9 2.5 FC0H104ZFTBR24 5.0 3.6 1.2 FC0H224ZFTBR24 5.0 4.9 2.5 FC0H224ZFTBR24 5.0 3.6 1.2 FC0H474ZFTBR32-SS 5.0 10.0 2.5 FC0H474ZFTBR32-SS 5.0 6.8 1.2 Logo FC0H105ZFTBR44-SS 10.0 10.5 3.5 FC0H105ZFTBR44-SS 10.0 7.0 1.4 B A B FC0V104ZFTBR24 5.0 4.9 2.5 FC0V104ZFTBR24 5.0 3.6 1.2 FC0V224ZFTBR24 5.0 4.9 2.5 FC0V224ZFTBR24 5.0 3.6 1.2 FC0V474ZFTBR24 5.0 4.9 2.5 FC0V474ZFTBR24 5.0 3.6 1.2

SuperCapacitor USER'S MANUAL VOL.01 36

2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistance discharge characteristic (Backup time capability)

FC0H473ZF/FCS0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 500 kΩ 1 MΩ 5 MΩ

Terminal voltage (Vdc) (100 μ A) (50 μ A) (10 μ A) (5 μ A) (1 μ A)

1.0

0 0.01 0.1 1 10 100 Discharge time (h)

FC0H104ZF/FCS0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 500 kΩ 1 MΩ 5 MΩ

Terminal voltage (Vdc) (100 μ A) (50 μ A) (10 μ A) (5 μ A) (1 μ A)

1.0

0 0.01 0.1 1 10 100 Discharge time (h)

FC0H224ZF/FCS0H224ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 500 kΩ 1 MΩ 5 MΩ

Terminal voltage (Vdc) (100 μ A) (50 μ A) (10 μ A) (5 μ A) (1 μ A)

1.0

0 0.1 1 10 100 1000 Discharge time (h)

SuperCapacitor USER'S MANUAL VOL.01 37

2017.05.17 9565SCGVOL01E1705H1 Resistance discharge characteristic (Backup time capability)

FC0H474ZF-SS at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 500 kΩ 5 MΩ

Terminal voltage (Vdc) (100 µ A) (10 µ A) (1 µ A)

1.0

0 0.1 1 10 100 1000 Discharge time (h)

FC0H105ZF-SS at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5

50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ

Voltage (Vdc) 2 （100 µA（）50 µA（）20 µA（）10 µA（）5 µA）

0 0.01 0.1 1 10 100 1000 Time (h)

FC0V104ZF/FCS0V104ZF at 25 ˚C [Charging: 3 V, 0 Ω, 24 h] 3.0

2.0

Terminal voltage (Vdc) 1.0 100 kΩ 300 kΩ 500 kΩ 1 MΩ 3 MΩ (30 μ A) (10 μ A) (6 μ A) (3 μ A) (1 μ A)

0 0.01 0.1 1 10 100 1000 Discharge time (h)

SuperCapacitor USER'S MANUAL VOL.01 38

2017.05.17 9565SCGVOL01E1705H1 Resistance discharge characteristic (Backup time capability)

FC0V224ZF/FCS0V224ZF at 25 ˚C [Charging: 3 V, 0 Ω, 24 h] 3.0

2.0

Terminal voltage (Vdc) 1.0 100 kΩ 300 kΩ 500 kΩ 1 MΩ 3 MΩ (30 μ A) (10 μ A) (6 μ A) (3 μ A) (1 μ A)

0 0.01 0.1 1 10 100 1000 Discharge time (h)

FC0V474ZF/FCS0V474ZF at 25 ˚C [Charging: 3 V, 0 Ω, 24 h] 3.0

2.5

2.0

1.5

1.0 Terminal Voltage (Vdc) 100 kΩ 300 kΩ 500 kΩ 1 MΩ 3 MΩ （30 μ A）（10 μ A）（6 μ A）（3 μ A）（1μ A）

0.5

0 0.01 0.1 1 10 100 1000 Time (h)

SuperCapacitor USER'S MANUAL VOL.01 39

2017.05.17 9565SCGVOL01E1705H1 FM-SERIES SuperCapacitor 11 (Resin Molded, Automatic Assembly)

The FM-Series SuperCapacitors have been developed for (2) Folded tape packaging (Ammo Pack) automatic assembly; thus, tape packaging is available in all FM0H223ZF TP 18 product lines. Height of component from tape center. They are particularly suited for applications requiring a long 18 : 18 mm backup time capability and small backup current such as Tape packaging microprocessor and memory backup. (FME type are backup devices adaptable to current consumption mA level.)

Part number of bulk packaging Features • High adaptability of automatic assembly • Cleanable • Excellent voltage holding characteristics. (Except 3.5 V, 6.5 V type FME type) • Wide operating range: –25 to +70 °C (–40 to +85°C for FMR type) • Easily chargeable (fast charge time) • Maintenance-free • Small installation area • Lead-free type. RoHS Compliant.

Application Backup of CMOS Microprocesser, SRAM, DTS, ICs, etc.

Part Number System (1) Bulk

FM 0H 473 Z F Environmental impact reduced products Capacitance tolerance Z : +80 %; –20 % Nominal capacitance First two digits represent significant figures. Third digit specifies number of zeros to follow μ F code. 473 : 47,000 μ F=0.047F

Maximum operating voltage 0H : 5.5 Vdc 0V : 3.5 Vdc 0J : 6.5 Vdc SuperCapacitor : FM：FM Series FME ：FME Type FMR ：FMR Type FMC ：FMC Type

SuperCapacitor USER'S MANUAL VOL.01 40

2017.05.17 9565SCGVOL01E1705H1 Dimensions

10.5±0.5 T±0.5 11.5 ± 0.5 0.4 ± 0.1 5 ± 1

0.5±0.1 0.4±0.1

5±0.5

(Unit�mm)

Markings

Negative polarity identification Conversion table for manufacture date code Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 N T Indication A B C D E F H J K L M N MAX operating Nominal capacitance Month 1 2 3 4 5 6 7 8 9 10 11 12 Indication 1 2 3 4 5 6 7 8 9 O N D voltage 5.5V 473 E E ：FME type marking – A1 + R ：FMR type marking

Date code Polarity

Lead Terminal Forming Example

Lead length designation For transverse mounting ＜L1＞

Ask us about dimensions.

Ｌ＝2.2 to 5mm

SuperCapacitor USER'S MANUAL VOL.01 41

2017.05.17 9565SCGVOL01E1705H1 Standard Ratings

5.5V Type

Nominal Part Number MAX operating MAX ESR MAX current at Voltage holding capacitance T Weight voltage (at 1 kHz) 30 min. characteristics Charge Discharge (mm) (g) Bulk Ammo pack (Vdc) (Ω) (mA) (V) system(F) system(F) FM0H103ZF FM0H103ZFTP18 5.5 0.01 0.014 300 0.015 4.2 5.0 1.3 FM0H223ZF FM0H223ZFTP18 5.5 0.022 0.028 200 0.033 4.2 5.0 1.3 FM0H473ZF FM0H473ZFTP18� 5.5 0.047 0.06 200 0.071 4.2 5.0 1.3 FM0H104ZF FM0H104ZFTP18 5.5 0.10 0.13 100 0.15 4.2 6.5 1.6 FM0H224ZF FM0H224ZFTP18 5.5 − 0.22 100 0.33 4.2 6.5 1.6

3.5V Type

Nominal Part Number MAX operating MAX ESR MAX current at capacitance T Weight voltage (at 1 kHz) 30 min. Charge Discharge (mm) (g) Bulk Ammo pack (Vdc) (Ω) (mA) system(F) system(F) FM0V473ZF FM0V473ZFTP18 3.5 0.047 0.06 200 0.042 5.0 1.3 FM0V104ZF FM0V104ZFTP18 3.5 0.10 0.13 100 0.090 5.0 1.3 FM0V224ZF FM0V224ZFTP18 3.5 0.22 0.30 100 0.20 6.5 1.6

6.5V Type

FME Type (Buckup Large Current, mA Order)

Nominal Part Number MAX operating MAX ESR MAX current at capacitance T Weight voltage (at 1 kHz) 30 min. Charge Discharge (mm) (g) Bulk Ammo pack (Vdc) (Ω) (mA) system(F) system(F) FME0H223ZF FME0H223ZFTP18 5.5 0.022 0.028 40 0.033 5.0 1.3 FME0H473ZF FME0H473ZFTP18 5.5 0.047 0.06 20 0.071 5.0 1.3

FMR Type (MAX Operating Temperature 85℃ Type)

Nominal Part Number MAX operating MAX ESR MAX current at Voltage holding capacitance T Weight voltage (at 1 kHz) 30 min. characteristics Charge Discharge (mm) (g) Bulk Ammo pack (Vdc) (Ω) (mA) (V) system(F) system(F) FMR0H473ZF FMR0H473ZFTP18 5.5 0.047 0.062 200 0.071 4.2 6.5 1.6 FMR0H104ZF FMR0H104ZFTP18 5.5 0.10 50 0.15 4.2 6.5 1.6 FMR0V104ZF FMR0V104ZFTP18 3.5 0.10 50 0.090 － 6.5 1.6

SuperCapacitor USER'S MANUAL VOL.01 42

2017.05.17 9565SCGVOL01E1705H1 FMC Type

Chip parts applicable to treatment in bond hardening furnace (160±5℃ for 120±10 seonds)

Dimensions

b ±0.5 T±0.5 a ± 0.5 0.4 ± 0.1 5 ± 1

d1 ±0.1 d2 ±0.1

5±0.5 (Unit：mm)

Markings

Negative polarity identification

N T MAX operating Nominal capacitance voltage 5.5V 473 C C：FMC type marking – K1 +

Date code Polarity

Standard Ratings

Nominal Part Number MAX MAX MAX ESR Voltage holding a b T d1 d2 Weight operating capacitance current at (at 1 kHz) characteristics voltage Charge Discharge 30 min. Bulk Ammo pack (Ω) (V) (mm) (mm) (mm) (mm) (mm) (g) (Vdc) system(F) system(F) (mA) FMC0H473ZF FMC0H473ZFTP18 5.5 0.047 0.06 100 0.071 4.2 11.5 10.5 5.0 0.5 0.4 1.3

FMC0H104ZF FMC0H104ZFTP18 5.5 0.10 0.13 50 0.15 4.2 11.5 10.5 6.5 0.5 0.4 1.6

FMC0H334ZF FMC0H334ZFTP18 5.5 – 0.33 25 0.50 4.2 15.0 14.0 9.0 0.6 0.6 3.5

SuperCapacitor USER'S MANUAL VOL.01 43

2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name 5.5V type, 3.5V type, 6.5V type Test conditions FME type Item FMC type (conforming to JIS C 5160-1) Category temperature range −25℃ to +70℃ −25℃ to +70℃ MAX operating voltage 5.5Vdc, 3.5Vdc, 6.5Vdc 5.5Vdc 5.5V：0.010F to 0.33F Capacitance 3.5V：0.047F to 0.22F 0.022F, 0.033F, 0.047F Refer to “Measurement Conditions” 6.5V：0.047 Capacitance allowance +80％ , −20％ +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also ESR Refer to standard ratings Refer to standard ratings “Measurement Conditions” Current (30-minutes value) Refer to standard ratings Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value More than 90% of initial specifi ed value Surge voltage ：4.0V (3.5V type) ： ESR Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value 6.3V (5.5V type) ：7.4V (6.5V type) Current (30 minutes value) Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value Charge：30 sec. Discharge：9min 30sec. Number of cycles ：1000 Series resistance ：0.010F 1500Ω ：0.022F 560Ω Surge ：0.033F 510Ω ： 0.047F 300Ω Appearance No obvious abnormality No obvious abnormality ：0.068F 240Ω ：0.10F 150Ω ：0.22F 56Ω ：0.33F 51Ω Discharge resistance：0Ω Temperature：70±2℃ More than 50% of initial More than 50% of initial Capacitance measured value measured value Phase 2 Phase 2 Less than 400% of initial Less than 300% of initial ESR measured value measured value Capacitance Phase 3 Phase 3 Conforms to 4.17 ESR Phase1：+25±2℃ Characteristics Less than 200% of initial Less than 150% of initial Phase2：−25±2℃ in different Capacitance measured value measured value Phase4：+25±2℃ temperature Phase 5 Phase 5 ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Phase5：+70±2℃ ：+ ℃ Current (30 minutes value) 1.5CV (mA) or below 1.5CV (mA) or below Phase6 25±2 Within ±20% of initial Within ±20% of initial Capacitance measured value measured value Phase 6 Phase 6 ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Satisfy initial specifi ed value Lead strength (tensile) No terminal damage No terminal damage Conforms to 4.9 Capacitance Conforms to 4.13 Vibration ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Frequency：10 to 55 Hz resistance Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should Over 3/4 of the terminal should Solder temp：245±5℃ Solderability be covered by the new solder be covered by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 Solder heat ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Solder temp：260±10℃ resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality No obvious abnormality Capacitance Conforms to 4.12 Temperature ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Temperature condition：−25℃→ Room temperature → cycle Current (30 minutes value) +70℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality No obvious abnormality Capacitance Within ±20% of initial measured value Within ±20% of initial measured value High temp. Conforms to 4.14 and high ESR Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value Temperature：40±2℃ humidity Current (30 minutes value) Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value Relative humidity：90 to 95％ RH resistance Testing time：240±8 hours Appearance No obvious abnormality No obvious abnormality Capacitance Within ±30% of initial measured value Within ±30% of initial measured value Conforms to 4.15 ： ℃ High ESR Less than 200% of initial specifi ed value Less than 200% of initial specifi ed value Temperature 70±2 temperature Voltage applied：MAX operating voltage load Current (30 minutes value) Less than 200% of initial specifi ed value Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality No obvious abnormality Testing time：1000 0 Hours Voltage applied：5.0Vdc (Terminal at Charging the case's side be negative) 5.5V type: Voltage between condition Series resistance：0Ω terminal leads Self discharge characteristics Charging time：24 hours higher than 4.2V (voltage holding characteristics) 3.5V type: Not specifi ed Let stand for 24 hours in condition described below with terminals opened. 6.5V type: Not specifi ed Storage Ambient temperature：Lower than 25℃ Relative humidity：Lower than 70%RH

SuperCapacitor USER'S MANUAL VOL.01 44

2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name FMR type Test conditions (conforming to JIS C 5160-1) Item Category temperature range −40℃ to +85℃ MAX operating voltage 5.5Vdc, 3.5Vdc Capacitance 0.047F, 0.10F Refer to “Measurement Conditions” Capacitance allowance +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also “Measurement ESR Refer to standard ratings Conditions” Current (30-minutes value) Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：4.0V (3.5V type) ： ESR Less than 120% of initial specifi ed value 6.3V (5.5V type) Charge：30 sec. Current (30 minutes value) Less than 120% of initial specifi ed value Discharge：9min 30sec. Surge Number of cycles：1000 Series resistance ：0.047F 300Ω Appearance No obvious abnormality ：0.10F 150Ω Discharge resistance：0Ω Temperature：85±2℃ More than 50% of initial Capacitance measured value Phase 2 Less than 400% of initial ESR measured value More than 30% of initial Capacitance measured value Phase 3 Conforms to 4.17 Less than 700% of initial ：+ ℃ ESR Phase1 25±2 measured value Phase2：−25±2℃ Characteristics in Less than 200% of initial Phase3：−40±2℃ different temperature Capacitance measured value Phase4：+25±2℃ Phase 5 Phase5：+85±2℃ ESR Satisfy initial specifi ed value Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below Within ±20% of initial Capacitance measured value Phase 6 ESR Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Lead strength (tensile) No terminal damage Conforms to 4.9 Capacitance ESR Satisfy initial specifi ed value Conforms to 4.13 Vibration resistance Frequency：10 to 55 Hz Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should be Solder temp：245±5℃ Solderability covered by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 ESR Satisfy initial specifi ed value Solder temp：260±10℃ Solder heat resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality Capacitance Conforms to 4.12 ESR Satisfy initial specifi ed value Temperature condition：−40℃→ Room temperature → Temperature cycle Current (30 minutes value) +85℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality Capacitance Within ±20% of initial measured value Conforms to 4.14 High temp. and high ESR Less than 120% of initial specifi ed value Temperature：40±2℃ humidity resistance Current (30 minutes value) Less than 120% of initial specifi ed value Relative humidity：90 to 95％ RH Testing time：240±8 hours Appearance No obvious abnormality Capacitance Within ±30% of initial measured value Conforms to 4.15 ： ℃ ESR Less than 200% of initial specifi ed value Temperature 85±2 High temperature load Voltage applied：MAX operating voltage Current (30 minutes value) Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality Testing time：1000 0 Hours Voltage applied：5.0Vdc (Terminal Charging at the case's side be negative) condition Series resistance：0Ω 5.5V type: Voltage between terminal leads Charging time：24 hours Self discharge characteristics higher than 4.2V (voltage holding characteristics) Let stand for 24 hours in condition 3.5V type: Not specifi ed described below with terminals Storage opened. Ambient temperature：Lower than 25℃ Relative humidity：Lower than 70%RH

SuperCapacitor USER'S MANUAL VOL.01 45

2017.05.17 9565SCGVOL01E1705H1 Taping Speciﬁ cations [except FMC0H334ZFTP18]

P2 P ∆h

b c a

– + – + 2 P1 F W4 W 3

H t L 1 W 0

W t2 W

P0 D0 t1

Unit : (mm)

Item Symbol Value Tolerance Remarks Component Height a 11.5 ±0.5 Component Width b 10.5 ±0.5 5.5 V type : 5.0/0.010F to 0.047F, 6.5/0.047F 3.5 V type : 5.0/0.047F to 0.10F, 6.5/0.22F FME type : 5.0/0.022F to 0.047F Component Thickness c － ±0.5 6.5 V type : 6.5/0.047F, 0.10F FMR type : 6.5/0.047F FMC type : 5.0/0.047F, 6.5/0.10F

Lead-wire Width W4 0.5 ±0.1

Lead-wire Thickness t3 0.4 ±0.1 Pitch between Component P 12.7 ±1.0

Sprocket Hole Pitch P0 12.7 ±0.3

Sprocket Hole to Lead P1 3.85 ±0.7

〃 P2 6.35 ±1.3 Lead Spacing F 5.0 ±0.5 Component Alignment Δh 2.0 Max. － Including tilting caused by bending lead wire. +1.0 Tape Width W 18.0 −0.5

Hold-down tape Width W0 12.5 Min. －

Sprocket Hole Position W1 9.0 ±0.5

Hold-down Tape Position W2 3.0 Max. － No protrusion of tape. Component's Bottom Line Position H 18.0 ±0.5

Sprocket Hole Diameter D0 φ4.0 ±0.2

Total tape Thickness t1 0.7 ±0.2

〃 t2 1.5 Max. － Defect Component Cut-off Position L 11.0 Max. －

SuperCapacitor USER'S MANUAL VOL.01 46

2017.05.17 9565SCGVOL01E1705H1 Taping Speciﬁ cations [FMC0H334ZFTP 18]

P2 P Δh

b c a

– + – + 2 P1 F W4 3 W t H L 1 W 0

W t2 W

P0 D0 t1

Unit : (mm)

Item Symbol Value Tolerance Remarks

Component Height a 15.0 ±0.5

Component Width b 14.0 ±0.5

Component Thickness c 9.0 ±0.5

Lead-wire Width W4 0.6 ±0.1

Lead-wire Thickness t3 0.6 ±0.1

Pitch between Component P 25.4 ±1.0

Sprocket Hole Pitch P0 12.7 ±0.3

Sprocket Hole to Lead P1 3.85 ±0.7

〃 P2 6.35 ±1.3

Lead Spacing F 5.0 ±0.5

Component Alignment Δh 2.0 Max. － Including tilting caused by bending lead wire +1.0 Tape Width W 18.0 −0.5

Hold-down tape Width W0 12.5 Min. －

Sprocket Hole Position W1 9.0 ±0.5

Hold-down Tape Position W2 3.0 Max. － No protrusion of tape

Component's Bottom Line Position H 18.0 ±0.5

Sprocket Hole Diameter D0 φ4.0 ±0.2

Total tape Thickness t1 0.67 ±0.2

〃 t2 1.7 Max. －

Defect Component Cut-off Position L 11.0 Max. －

SuperCapacitor USER'S MANUAL VOL.01 47

2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistive discharge characteristic (Backup time capability) 5.5V Type

FM0H103ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0

Terminal voltage (Vdc) 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ 1.0 (100 mµ A) (50 mµ A) (20 mµ A) (10 mµ A) (5 mµ A) (2 mµ A) (1 mµ A)

0 0.1 1 10 100

Discharge time (h)

FM0H223ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 mµ A) (50 mµ A) (20 mµ A) (10 mµ A) (5 mµ A) (2 mµ A) (1 mµ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100

Discharge time (h)

SuperCapacitor USER'S MANUAL VOL.01 48

2017.05.17 9565SCGVOL01E1705H1 Resistance discharge characteristic (Backup time capability) 5.5V Type

FM0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 mµ A) (50 mµ A) (20 mµ A) (10 µmA) (5 mµ A) (2 mµ A) (1 mµ A) Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 Discharge time (h)

FM0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100µ A) (50 µ A) (20 µ A) (10µ A) (5µ A) (2µ A) (1µ A) Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 1000 Discharge time (h)

FM0H224ZF at 25 ℃〔Charging : 5 V, 0Ω, 24 h〕 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 500 kΩ 1 MΩ 5 MΩ （100 mµ A）（50 mµ A）（10 µmA）（5 mµ A）（1 mµ A） Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 1000 Discharge time (h)

SuperCapacitor USER'S MANUAL VOL.01 49

2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) 3.5 V Type, 6.5V Type

FM0V473ZF at 25 ˚C [Charging: 3 V, 0 Ω, 24 h] 3.0

2.0 voltage (Vdc)

1.0 100 kΩ 300 kΩ 500 kΩ 1 MΩ 3 MΩ (30 µ A) (10 µ A) (6 µ A) (3 µ A) (1 µ A) Terminal

0 0.1 1 10 100 Discharge time (h)

FM0V104ZF at 25 ˚C [Charging: 3 V, 0 Ω, 24 h] 3.0

2.0 voltage (Vdc)

1.0 100 kΩ 300 kΩ 500 kΩ 1 MΩ 3 MΩ (30 µ A) (10 µ A) (6 µ A) (3 µ A) (1 µ A) Terminal

0 1 10 100 Discharge time (h)

FM0V224ZF at 25 ˚C [Charging: 3 V, 0 Ω, 24 h] 3.0

2.0 voltage (Vdc)

1.0 100 kΩ 300 kΩ 500 kΩ 1 MΩ 3 MΩ (30 µ A) (10 µ A) (6 µ A) (3 µ A) (1 µ A) Terminal

0 1 10 100 1000 Discharge time (h)

FM0J473ZF at 25 ˚C [Charging: 6 V, 0 Ω, 24 h] 6

3 voltage (Vdc) 2 6 kΩ 12 kΩ 20 kΩ 1 （1mA）（500μA）（300μA） Terminal

0 1 10 100 1000 10000 Discharge time (sec)

SuperCapacitor USER'S MANUAL VOL.01 50

2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FME Type

FME0H223ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ 25 kΩ 50 kΩ (5 mA) (2 mA) (1 mA) (500 µ A) (200 µ A) (100 µ A) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FME0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 500 Ω 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ 25 kΩ (10 mA) (5 mA) (2 mA) (1 mA) (500 µ A) (200 µ A) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

SuperCapacitor USER'S MANUAL VOL.01 51

2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FMC Type

FMC0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 mµ A) (50 mµ A) (20 mµ A) (10 µmA) (5 mµ A) (2 mµ A) (1 mµ A) Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 Discharge time (h)

FMC0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100µ A) (50 µ A) (20 µ A) (10µ A) (5µ A) (2µ A) (1µ A) Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 1000 Discharge time (h)

FMC0H334ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5

2 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ

Terminal Voltage (Vdc) （100µ A）（50µ A）（20µ A）（10µ A）（5µ A）（2µ A）（1µ A）

0 0.01 0.1 1 10 100 1000 Discharge Time (h)

SuperCapacitor USER'S MANUAL VOL.01 52

2017.05.17 9565SCGVOL01E1705H1 FG-SERIES SuperCapacitor 12 (Miniaturized, Large Capacitance) (For cleanable products, see page 28.)

The FG Series SuperCapacitor is a range of compact, large Features capacitance double-layer capacitors with excellent voltage • The same capacitance at approximately half the size, holding characteristics. compared with the FY Series. • Excellent voltage holding characteristics ideal for backup of The FG-Series capacitors were designed to provide more 1 μA to several hundred μA compact versions of the FY-Series of capacitors. • Easily chargeable Compared with the conventional FY Series, these capacitors • Wide operating range: –25 to +70°C provide the same capacitance at approximately half the size. • Maintenance free. • Lead-free, PVC-free type. RoHS Compliant. These capacitors are ideal as long-time backup devices for minute-current loads in small and lightweight systems. Application Backup of CMOS microcomputers, static RAMs, DTSs (digital tuning systems)

Part Number System

FG 0H 473 Z F Environmental impact reduced products Capacitance tolerance Z : +80 %; –20 % Nominal capacitance : 0.047F First two digits represent significant figures. Third digit specifies number of zeros to follow μ F code.

Maximum operating voltage 0H : 5.5 Vdc, 0V : 3.5 Vdc SuperCapacitor : FG：FG Series FGH：FGH Type FGR：FGR Type

Markings

Name of manufacturer, maximum operating voltage, Conversion table for manufacture date code capacitance, manufacture date code, serial no., and series Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 name are marked on the external tube. The negative lead Indication A B C D E F H J K L M N Month 1 2 3 4 5 6 7 8 9 10 11 12 terminal is marked with black bands. Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Maximum operating voltage External tube M6 Production 001 FG 5.5 V FG 5.5 V lot number 0.047F 0.047F Nominal Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative lead terminal Negative terminal marker (terminal on the case)

SuperCapacitor USER'S MANUAL VOL.01 53

2017.05.17 9565SCGVOL01E1705H1 Dimensions

Negative terminal marker φ D ± 0.5 ℓ MIN. H MAX. Sleeve 0.3 MIN.

○－ ○＋

P ± 0.5 d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

FG Type

MAX Nominal capacitance MAX Dimension (unit:mm) MAX ESR Voltage holding Weight operating current at Part Number (at 1 kHz) characteristics voltage Charge Discharge 30 min. (Ω) (V) φD H P ℓ d1 d2 (g) (Vdc) system (F) system (F) (mA) FG0H103ZF 5.5 0.010 0.013 300 0.015 4.2 11.0 5.5 5.08 2.7 0.2 1.2 0.9 FG0H223ZF 5.5 0.022 0.028 200 0.033 4.2 11.0 5.5 5.08 2.7 0.2 1.2 1.0 FG0H473ZF 5.5 0.047 0.060 200 0.071 4.2 11.0 5.5 5.08 2.7 0.2 1.2 1.0 FG0H104ZF 5.5 0.10 0.13 100 0.15 4.2 11.0 6.5 5.08 2.7 0.2 1.2 1.3 FG0H224ZF 5.5 0.22 0.28 100 0.33 4.2 13.0 9.0 5.08 2.2 0.4 1.2 2.5 FG0H474ZF 5.5 0.47 0.60 120 0.71 4.2 14.5 18.0 5.08 2.4 0.4 1.2 5.1 FG0H105ZF 5.5 1.0 1.3 65 1.5 4.2 16.5 19.0 5.08 2.7 0.4 1.2 7.0 FG0H225ZF 5.5 2.2 2.8 35 3.3 4.2 21.5 19.0 7.62 3.0 0.6 1.2 12.1 FG0H475ZF 5.5 4.7 6.0 35 7.1 4.2 28.5 22.0 10.16 6.1 0.6 1.4 27.3 FG0V155ZF 3.5 1.5 2.2 65 1.5 − 16.5 14.0 5.08 2.7 0.4 1.2 5.2

FGH Type

MAX MAX Dimension (unit:mm) MAX ESR Voltage holding Weight operating Nominal capacitance current at Part Number (at 1 kHz) characteristics voltage (F) 30 min. (Ω) (V) φD H P ℓ d1 d2 (g) (Vdc) (mA) FGH0H104ZF 5.5 0.10 100 0.15 4.2 11.0 5.5 5.08 2.7 0.2 1.2 1.0 FGH0H224ZF 5.5 0.22 100 0.33 4.2 11.0 7.0 5.08 2.7 0.2 1.2 1.3 FGH0H474ZF 5.5 0.47 65 0.71 4.2 16.5 8.0 5.08 2.7 0.4 1.2 4.1 FGH0H105ZF 5.5 1.0 35 1.5 4.2 21.5 9.5 7.62 3.0 0.6 1.2 7.2

FGR Type

SuperCapacitor USER'S MANUAL VOL.01 54

2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name Test conditions FG, FGH type FGR type Item (conforming to JIS C 5160-1) Category temperature range −25℃ to +70℃ −40℃ to +85℃ MAX operating voltage 5.5Vdc, 3.5Vdc 5.5Vdc FG：0.010F to 4.7F Capacitance 0.47F to 2.2F Refer to “Measurement Conditions” FGH：0.10F to 1.0F Capacitance allowance +80％ , −20％ +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also ESR Refer to standard ratings Refer to standard ratings “Measurement Conditions” Current (30-minutes value) Refer to standard ratings Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value More than 90% of initial specifi ed value Surge voltage ：6.3V (5.5V type) ： ESR Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value 4.0V(3.5V type) Charge：30 sec. Current (30 minutes value) Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value Discharge：9min 30sec. Number of cycles：1000 Series resistance ：0.010F 1500Ω ：0.022F 560Ω ：0.047F 300Ω Surge ：0.10F 150Ω ：0.22F 56Ω Appearance No obvious abnormality No obvious abnormality ：0.47F 30Ω ：1.0F, 1.5F 15Ω ：2.2F, 4.7F 10Ω Discharge resistance：0Ω Temperature： 85±2℃ (FGR) ：70±2℃ (FG, FGH) More than 50% of More than 50% of Capacitance initial measured value initial measured value Phase 2 Phase 2 Less than 400% of Less than 400% of ESR initial measured value initial measured value More than 30% of Capacitance initial measured value Conforms to 4.17 Phase 3 Phase 3 Phase1 ：+25±2℃ Less than 700% of ESR Phase2 ：−25±2℃ Characteristics initial measured value Phase3 ：−40±2℃ (FGR) in different Less than 200% of Less than 200% of Phase4 ：+25±2℃ temperature Capacitance initial measured value initial measured value Phase5 ：+70±2℃ (FG, FGH) Phase 5 Phase 5 ESR Satisfy initial specifi ed value Satisfy initial specifi ed value ：+85±2℃ (FGR) ：+ ℃ Current (30 minutes value) 1.5CV (mA) or below 1.5CV (mA) or below Phase6 25±2 Within ±20% of initial Within ±20% of initial Capacitance measured value measured value Phase 6 Phase 6 ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Satisfy initial specifi ed value Lead strength (tensile) No terminal damage No terminal damage Conforms to 4.9 Capacitance Conforms to 4.13 Vibration ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Frequency：10 to 55 Hz resistance Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should Over 3/4 of the terminal should Solder temp：245±5℃ Solderability be covered by the new solder be covered by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 Solder heat ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Solder temp：260±10℃ resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality No obvious abnormality Capacitance Conforms to 4.12 Temperature ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Temperature condition：Category MIN temp → Room temp → cycle Current (30 minutes value) Category MAX temp → Room temp Number of cycles：5 Cycles Appearance No obvious abnormality No obvious abnormality Capacitance Within ±20% of initial measured value Within ±20% of initial measured value High temp. Conforms to 4.14 and high ESR Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value Temperature：40±2℃ humidity Current (30 minutes value) Less than 120% of initial specifi ed value Less than 120% of initial specifi ed value Relative humidity：90 to 95％ RH resistance Testing time：240±8 hours Appearance No obvious abnormality No obvious abnormality Capacitance Within ±30% of initial measured value Within ±30% of initial measured value Conforms to 4.15 ： ℃ High ESR Less than 200% of initial specifi ed value Less than 200% of initial specifi ed value Temp Category MAX temp ±2 temperature Voltage applied：MAX operating voltage load Current (30 minutes value) Less than 200% of initial specifi ed value Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality No obvious abnormality Testing time：1000 0 Hours Voltage applied：5.0Vdc (Terminal at Charging the case's side be negative) ： Ω 5.5V type: Voltage between condition Series resistance 0 ： Self discharge characteristics terminal leads Voltage between terminal Charging time 24 hours (voltage holding characteristics) higher than 4.2V leads higher than 4.2V Let stand for 24 hours in condition 3.5V type: Not specifi ed described below with terminals opened. Storage Ambient temperature：Lower than 25℃ Relative humidity：Lower than 70%RH

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2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistive discharge characteristics (Backup time capability)

FG0H103ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0

50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ

Terminal voltage (Vdc) 1.0 (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A)

0 0.1 1 10 100 Discharge time (h)

FG0H223ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0

50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ

Terminal voltage (Vdc) 1.0 (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A)

0 0.1 1 10 100 Discharge time (h)

FG0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability)

FG0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FG0H224ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 6.0

5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ

Terminal voltage (Vdc) (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FG0H474ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 6.0

5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ

Terminal voltage (Vdc) (50 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (5 µ A) (1 µ A) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability)

FG0H105ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 6.0

5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ

Terminal voltage (Vdc) (100 µ A) (50 µ A)(20 µ A)(10 µ A) (5 µ A) (2 µ A) (1 µ A) 1.0

0 1 10 100 1000 10000 Discharge time (h)

FG0H225ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 6.0

5.0

4.0

3.0

50 kΩ 5 MΩ 2.0 10 k (100 µ A) 100 k 1 M Ω Ω Ω (1 µ A) Terminal voltage (Vdc) (500 µ A) (50 µ A) 500 kΩ (5 µ A) (10 µ A) 1.0

0 1 10 100 1000 10000 Discharge time (h)

FG0H475ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 6.0

5.0

4.0

3.0

50 kΩ 2.0 (100 µ A) 5 MΩ 10 kΩ 100 kΩ 1 MΩ (1 µ A) Terminal voltage (Vdc) (500 µ A) (50 µ A) 500 kΩ (5 µ A) (10 µ A) 1.0

0 1 10 100 1000 10000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FGH Type

FGH0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 500 kΩ 1 MΩ 5 MΩ (100 µ A) (50 µ A) (10 µ A) (5 µ A) (1 µ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FGH0H224ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) Terminal voltage (Vdc) 1.0

0 0.01 0.1 1 10 100 1000 Discharge time (h)

FGH0H474ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A)

Terminal voltage (Vdc) 1.0

0 0.01 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FGH Type

FGH0H105ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

250 kΩ 500 kΩ 1 MΩ 100 kΩ 2.0 50 kΩ (20 µ A) (10 µ A) (5 µ A) (100 µ A)(50 µ A)

Terminal voltage (Vdc) 1.0

0 0.01 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 FT-SERIES SuperCapacitor 13 (Miniaturized, Low ESR)

FT Series SuperCapacitors are backup devices adaptable to Part Number System current consumption levels ranging from several hundred μA to several hundred mA. These products are developed for the FT 0H 473 Z F purpose of miniaturizing conventional FS Series capacitors with ESR equal to the size half of the FS Series. Environmental impact reduced products

Features Capacitance tolerance • Half the size of the FS Series, and ESR and capacitance Z : +80 %; –20 % equal to the FS Series Nominal capacitance : 0.047F • Surface mounting possible First two digits represent • Wide range of temperature from –40°C to +85°C significant figures. • Maintenance free Third digit specifies number • Lead-free, PVC-free type. RoHS Compliant. of zeros to follow μ F code.

Maximum operating voltage Application 0H : 5.5 V Designed to be used for products such as personal SuperCapacitor computers, PBXs, telephone sets, and HDDs with circuits that FT：FT Series need backup of mA level current.

Markings Name of manufacturer, maximum operating voltage, nominal capacitance, manufacturing date code, serial number, and series name are marked on the external tube. The negative lead terminal is marked with a black band.

Conversion table for manufacture date code Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 Indication A B C D E F H J K L M N Month 1 2 3 4 5 6 7 8 9 10 11 12 Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Maximum operating voltage External tube M6 Production 001 FT 5.5 V FT 5.5 V lot number 85˚C 0.047F 85˚C 0.047F Nominal Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative lead terminal Negative terminal marker (terminal on the case)

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2017.05.17 9565SCGVOL01E1705H1 Dimensions

φ D ± 0.5 Negative terminal marker ℓ MIN. H MAX. Sleeve 0.3 MIN.

○－ ○＋

P ± 0.5

d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

MAX Nominal capacitance Dimension (unit:mm) MAX ESR MAX current Weight operating Part Number (at 1 kHz) at 30 min. voltage Charge Discharge (Ω) (mA) φD H P d1 d2 ℓ (g) (Vdc) system (F) system (F) FT0H104ZF 5.5 0.10 0.14 16 0.15 11.5 8.5 5.08 0.4 1.2 2.7 1.6

FT0H224ZF 5.5 0.22 0.28 10 0.33 14.5 12.0 5.08 0.4 1.2 2.2 4.1

FT0H474ZF 5.5 0.47 0.60 6.5 0.71 16.5 13.0 5.08 0.4 1.2 2.7 5.3

FT0H105ZF 5.5 1.0 1.3 3.5 1.5 21.5 13.0 7.62 0.6 1.2 3.0 10.0

FT0H225ZF 5.5 2.2 2.8 1.8 3.3 28.5 14.0 10.16 0.6 1.4 6.1 18.0

FT0H335ZF 5.5 3.3 4.2 1.0 5.0 36.5 15.0 15.00 0.6 1.7 6.1 38.0

FT0H565ZF 5.5 5.6 7.2 0.6 8.4 44.5 17.0 20.00 1.0 1.4 6.1 72.0

SuperCapacitor USER'S MANUAL VOL.01 62

2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name FT type Test conditions (conforming to JIS C 5160-1) Item Category temperature range −40℃ to +85℃ MAX operating voltage 5.5Vdc Capacitance 0.1F to 5.6F Refer to “Measurement Conditions” Capacitance allowance +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also “Measurement ESR Refer to standard ratings Conditions” Current (30-minutes value) Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：6.3V Charge：30 sec. ESR Less than 120% of initial specifi ed value Discharge：9min 30sec. Current (30 minutes value) Less than 120% of initial specifi ed value Number of cycles：1000 Series resistance ：0.10F 150Ω ：0.22F 56Ω Surge ：0.47F 30Ω ：1.0F 15Ω Appearance No obvious abnormality ：2.2F 10Ω ：3.3F 10Ω ：5.6F 10Ω Discharge resistance：0Ω Temperature：85±2℃ More than 50% of initial Capacitance measured value Phase 2 Less than 300% of initial ESR measured value More than 30% of initial Capacitance measured value Phase 3 Conforms to 4.17 Less than 700% of initial ESR Phase1：+25±2℃ measured value Phase2：−25±2℃ Characteristics in Less than 150% of initial Phase3：−40±2℃ different temperature Capacitance measured value Phase4：+25±2℃ ：+ ℃ ESR Phase 5 Satisfy initial specifi ed value Phase5 85±2 Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below Within ±20% of initial Capacitance measured value ESR Phase 6 Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Lead strength (tensile) No terminal damage Conforms to 4.9 Capacitance ESR Satisfy initial specifi ed value Conforms to 4.13 Vibration resistance Frequency：10 to 55 Hz Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should be Solder temp：245±5℃ Solderability covered by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 ESR Satisfy initial specifi ed value Solder temp：260±10℃ Solder heat resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality Capacitance Conforms to 4.12 ESR Satisfy initial specifi ed value Temperature condition：−40℃→ Room temperature → Temperature cycle Current (30 minutes value) +85℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality Capacitance Within ±20% of initial measured value Conforms to 4.14 High temp. and high ESR Less than 120% of initial specifi ed value Temperature：40±2℃ humidity resistance Current (30 minutes value) Less than 120% of initial specifi ed value Relative humidity：90 to 95％ RH Testing time：240±8 hours Appearance No obvious abnormality Capacitance Within ±30% of initial measured value Conforms to 4.15 ESR Less than 200% of initial specifi ed value Temperature：85±2℃ High temperature load Voltage applied：MAX operating voltage Current (30 minutes value) Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality Testing time：1000 0 Hours

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2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistance discharge characteristic (Backup time capability)

FT0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 250 Ω 500 Ω 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ (20 mA) (10 mA) (5 mA) (2 mA) (1 mA) (500 µ A) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FT0H224ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 50 Ω 100 Ω 250 Ω 500 Ω 1 kΩ 2.5 kΩ (100 mA) (50 mA) (20 mA) (10 mA) (5 mA) (2 mA) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FT0H474ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 10 Ω 25 Ω 50 Ω 100 Ω 250 Ω 500 Ω (500 mA) (200 mA) (100 mA) (50 mA) (20 mA) (10 mA) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

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2017.05.17 9565SCGVOL01E1705H1 Resistance discharge characteristic (Backup time capability)

FT0H105ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 10 Ω 25 Ω 50 Ω 100 Ω 250 Ω (500 mA) (200 mA) (100 mA) (50 mA) (20 mA) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FT0H225ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 10 Ω 25 Ω 50Ω 100 Ω 250 Ω (500 mA) (200 mA) (100 mA) (50 mA) (20 mA) Terminal

1.0

0 0.1 1 10 100 1000

Discharge time (sec)

FT0H335ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 5 Ω 10 Ω 25Ω 50 Ω 100 Ω (1000 mA) (500 mA) (200 mA) (100 mA) (50 mA) Terminal

1.0

0 0.1 1 10 100 1000

Discharge time (sec)

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2017.05.17 9565SCGVOL01E1705H1 Resistance discharge characteristic (Backup time capability)

FT0H565ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 5 Ω 10 Ω 25Ω 50 Ω 100 Ω (1000 mA) (500 mA) (200 mA) (100 mA) (50 mA) Terminal

1.0

0 0.1 1 10 100 1000

Discharge time (sec)

SuperCapacitor USER'S MANUAL VOL.01 66

2017.05.17 9565SCGVOL01E1705H1 FY-SERIES SuperCapacitor 14 (Miniaturized, Large Capacitance) (For cleanable products, see page 28.)

The FY Series includes small-sized electric double-layer Features capacitors with excellent voltage holding characteristics. The • Product variety makes the FYD, and FYH types suitable for FYD type occupies only a small area on a printed circuit use in many types of application systems board, and the FYH types feature a low proﬁ le in height, so • Excellent voltage holding characteristics ideal for backup of that they can be used in various systems. 1 μA to several hundred μA These capacitors are ideal as long-time backup devices for • Easily chargeable minute-current loads in small and lightweight systems. • Wide operating range: –25 to +70°C • Maintenance free. • Lead-free, PVC-free type. RoHS Compliant.

Application Backup of CMOS microcomputers, static RAMs, DTSs (digital tuning systems)

Part Number System

FYD 0H 473 Z F Environmental impact reduced products Capacitance tolerance Z : +80 %; –20 %

Nominal capacitance : 0.047F First two digits represent significant figures. Third digit specifies number of zeros to follow μ F code.

Maximum operating voltage 0H : 5.5 Vdc

SuperCapacitor FY：FY Series FYD ： FYD Type FYH ： FYH Type

Markings Name of manufacturer, maximum operating voltage, Conversion table for manufacture date code capacitance, manufacture date code, serial no., and series Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 Indication A B C D E F H J K L M N name are marked on the external tube. The negative lead Month 1 2 3 4 5 6 7 8 9 10 11 12 terminal is marked with black bands. Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Maximum operating voltage External tube M6 Production 001 FYD 5.5 V FYD 5.5 V lot number 0.047F 0.047F Nominal Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative lead terminal Negative terminal marker (terminal on the case)

SuperCapacitor USER'S MANUAL VOL.01 67

2017.05.17 9565SCGVOL01E1705H1 Dimensions

Negative terminal marker φ D ± 0.5 ℓ MIN. H MAX. Sleeve 0.3 MIN.

○－ ○＋

P ± 0.5 d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

FYD Type

MAX Nominal capacitance MAX Dimension (unit:mm) MAX ESR Voltage holding Weight operating current at Part Number (at 1 kHz) characteristics voltage Charge Discharge 30 min. (Ω) (V) φD H P ℓ d1 d2 (g) (Vdc) system (F) system (F) (mA) FYD0H223ZF 5.5 0.022 0.033 220 0.033 4.2 11.5 8.5 5.08 2.7 0.4 1.2 1.6 FYD0H473ZF 5.5 0.047 0.070 220 0.071 4.2 11.5 8.5 5.08 2.7 0.4 1.2 1.7 FYD0H104ZF 5.5 0.10 0.14 100 0.15 4.2 13.0 8.5 5.08 2.2 0.4 1.2 2.4 FYD0H224ZF 5.5 0.22 0.35 120 0.33 4.2 14.5 15.0 5.08 2.4 0.4 1.2 4.3 FYD0H474ZF 5.5 0.47 0.75 65 0.71 4.2 16.5 15.0 5.08 2.7 0.4 1.2 6.0 FYD0H105ZF 5.5 1.0 1.6 35 1.5 4.2 21.5 16.0 7.62 3.0 0.6 1.2 11.0 FYD0H145ZF 5.5 1.4 2.1 45 2.1 4.2 21.5 19.0 7.62 3.0 0.6 1.2 12.0 FYD0H225ZF 5.5 2.2 3.3 35 3.3 4.2 28.5 22.0 10.16 6.1 0.6 1.4 22.9

FYH Type

MAX Nominal capacitance MAX Dimension (unit:mm) MAX ESR Voltage holding Weight operating current at Part Number (at 1 kHz) characteristics voltage Charge Discharge 30 min. (Ω) (V) φD H P ℓ d1 d2 (g) (Vdc) system (F) system (F) (mA) FYH0H223ZF 5.5 0.022 0.033 200 0.033 4.2 11.5 7.0 5.08 2.7 0.4 1.2 1.5 FYH0H473ZF 5.5 0.047 0.075 100 0.071 4.2 13.0 7.0 5.08 2.2 0.4 1.2 2.2 FYH0H104ZF 5.5 0.10 0.16 50 0.15 4.2 16.5 7.5 5.08 2.7 0.4 1.2 3.4 FYH0H224ZF 5.5 0.22 0.30 60 0.33 4.2 16.5 9.5 5.08 2.7 0.4 1.2 3.6 FYH0H474ZF 5.5 0.47 0.70 35 0.71 4.2 21.5 10.0 7.62 3.0 0.6 1.2 7.2 FYH0H105ZF 5.5 1.0 1.5 20 1.5 4.2 28.5 11.0 10.16 6.1 0.6 1.4 13.9

SuperCapacitor USER'S MANUAL VOL.01 68

2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name FY type Test conditions (conforming to JIS C 5160-1) Item Category temperature range −25℃ to +70℃ MAX operating voltage 5.5Vdc FYD： 0.022F to 2.2F Capacitance Refer to “Measurement Conditions” FYH： 0.022F to 1.0F Capacitance allowance +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also “Measurement ESR Refer to standard ratings Conditions” Current (30-minutes value) Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：6.3V Charge：30 sec. ESR Less than 120% of initial specifi ed value Discharge：9min 30sec. Current (30 minutes value) Less than 120% of initial specifi ed value Number of cycles：1000 Series resistance ：0.022F 560Ω ：0.047F 300Ω ：0.068F 240Ω Surge ：0.10F 150Ω ：0.22F 56Ω Appearance No obvious abnormality ：0.47F 30Ω ：1.0F, 1.4F 15Ω ：2.2F 10Ω Discharge resistance：0Ω Temperature：70±2℃ More than 50% of initial Capacitance measured value Phase 2 Less than 400% of initial ESR measured value Capacitance Phase 3 Conforms to 4.17 ESR Phase1：+25±2℃ Characteristics in Less than 200% of initial Phase2：−25±2℃ Capacitance different temperature measured value Phase4：+25±2℃ ：+ ℃ ESR Phase 5 Satisfy initial specifi ed value Phase5 70±2 Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below Capacitance Within ±20% of initial measured value ESR Phase 6 Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Lead strength (tensile) No terminal damage Conforms to 4.9 Capacitance ESR Satisfy initial specifi ed value Conforms to 4.13 Vibration resistance Frequency：10 to 55 Hz Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should be covered Solder temp：245±5℃ Solderability by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 ESR Satisfy initial specifi ed value Solder temp：260±10℃ Solder heat resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality Capacitance Conforms to 4.12 ESR Satisfy initial specifi ed value Temperature condition：−25℃→ Room temperature → Temperature cycle Current (30 minutes value) +70℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality Capacitance Within ±20% of initial measured value Conforms to 4.14 High temp. and high ESR Less than 120% of initial specifi ed value Temperature：40±2℃ humidity resistance Current (30 minutes value) Less than 120% of initial specifi ed value Relative humidity：90 to 95％ RH Testing time：240±8 hours Appearance No obvious abnormality Capacitance Within ±30% of initial measured value Conforms to 4.15 ESR Less than 200% of initial specifi ed value Temperature：70±2℃ High temperature load Voltage applied：MAX operating voltage Current (30 minutes value) Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality Testing time：1000 0 Hours Voltage applied：5.0Vdc (Terminal Charging at the case's side be negative) condition Series resistance：0Ω Self discharge characteristics Charging time：24 hours Voltage between terminal leads higher than 4.2V (voltage holding characteristics) Let stand for 24 hours in condition described below with terminals opened. Storage Ambient temperature：Lower than 25℃ Relative humidity：Lower than 70%RH

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2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistive discharge characteristics (Backup time capability) FYD Type

FYD0H223ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYD0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYD0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FYD Type

FYD0H224ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A)(10 µ A)(5 µ A) (2 µ A) (1 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYD0H474ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYD0H105ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A)(20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FYD Type

FYD0H145ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0 5 MΩ (1 µ A) 3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A) (5 µ A) (2.5 µ A) Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYD0H225ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 10 kΩ 50 kΩ 100 kΩ 500 kΩ 1 MΩ 5 MΩ (500 µ A) (100 µ A)(50 µ A) (10 µ A) (5 µ A) (1 µ A) Terminal 1.0

0 1.0 10 100 1000 10000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FYH Type

FYH0H223ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYH0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A)(10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYH0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability) FYH Type

FYH0H224ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A)(50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYH0H474ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FYH0H105ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc) 2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A)(20 µ A)(10 µ A)(5 µ A) (2 µ A) (1 µ A)

Terminal 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 FR-SERIES SuperCapacitor 15 (Wide Operating Temperature Range) (For cleanable products, see page 28.)

The FR Series SuperCapacitors are small-sized electric • No drawbacks of overcharge and overdischarge. No double-layer capacitors that can operate in a temperature protection circuit required. Quick charge and discharge. range as wide as –40 ˚C to +85 ˚C. • The capacitors can satisfactorily function during the design These capacitors are ideal as long-time backup devices for life of a set and no maintenance is required, provided the minute current loads in industrial equipment such as measuring capacitors are used under the prescribed conditions. instruments, control equipment, and communications equipment. • Flow-solderable. Superior mountability. • Environmentally-friendly end-product design can be achieved Features using these capacitors free from heavy metals such as cadmium. • Wide operating temperature range (–40 ˚C to +85 ˚C) • Lead-free, PVC-free type. RoHS Compliant. • High reliability (Load life of 85 ˚C, 5.5 V : 1000 H guaranteed) • Excellent voltage holding characteristics ideal for long-time Applications current supply of 1 μA to several hundred μA Memory back-up for C-MOS microcomputers, static RAMs, • Wide capacitance range (0.022 F to 1.0 F) DTSs (Digital tuning systems) and so forth.

Part Number System

FR 0H 223 Z F

Environmental impact reduced products Capacitance tolerance Z : +80 %; –20 %

Nominal capacitance : 0.022F First two digits represent significant figures. Third digit specifies number of zeros to follow μ F code.

Maximum operating voltage 0H : 5.5 Vdc

SuperCapacitor FR : FR Series

Markings

Name of manufacturer, maximum operating voltage, Conversion table for manufacture date code capacitance, manufacture date code, serial no., and series Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 Indication A B C D E F H J K L M N name are marked on the external tube. The negative lead Month 1 2 3 4 5 6 7 8 9 10 11 12 terminal is marked with black bands. Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Maximum operating voltage External tube M6 Production 001 FR 5.5 V FR 5.5 V lot number 85˚C 0.022F 85˚C 0.022F Nominal Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative terminal marker

Negative lead terminal (terminal on the case) SuperCapacitor USER'S MANUAL VOL.01 75

2017.05.17 9565SCGVOL01E1705H1 Dimensions

φ D ± 0.5 Negative terminal marker ℓ MIN. H MAX. Sleeve 0.3 MIN.

○－ ○＋

P ± 0.5

d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

FR0H473ZF 5.5 0.047 0.060 110 0.071 4.2 14.5 14.0 5.08 2.4 0.4 1.2 3.9

FR0H104ZF 5.5 0.10 0.15 150 0.15 4.2 14.5 15.5 5.08 2.4 0.4 1.2 4.3

FR0H224ZF 5.5 0.22 0.33 180 0.33 4.2 14.5 21.0 5.08 2.4 0.4 1.2 5.3

FR0H474ZF 5.5 0.47 0.75 100 0.71 4.2 16.5 21.5 5.08 2.7 0.4 1.2 7.5

FR0H105ZF 5.5 1.0 1.6 60 1.5 4.2 21.5 22.0 7.62 3.0 0.6 1.2 13.3

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2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name FR type Test conditions (conforming to JIS C 5160-1) Item Category temperature range −40℃ to +85℃ MAX operating voltage 5.5Vdc Capacitance 0.022F to 1.0F Refer to “Measurement Conditions” Capacitance allowance +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also “Measurement ESR Refer to standard ratings Conditions” Current (30-minutes value) Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：6.3V (5.5V type) Charge：30 sec. ESR Less than 120% of initial specifi ed value Discharge：9min 30sec. Current (30 minutes value) Less than 120% of initial specifi ed value Number of cycles：1000 Series resistance ：0.022F 560Ω ：0.047F 300Ω Surge ：0.068F 240Ω ：0.10F 150Ω Appearance No obvious abnormality ：0.22F 56Ω ：0.47F 30Ω ：1.0F 15Ω Discharge resistance：0Ω Temperature：85±2℃ More than 50% of initial Capacitance measured value Phase 2 Less than 400% of initial ESR measured value More than 30% of initial Capacitance measured value Conforms to 4.17 Phase 3 Less than 700% of initial Phase1：+25±2℃ ESR measured value Phase2：−25±2℃ Characteristics in ： ℃ Less than 200% of initial Phase3 −40±2 different temperature Capacitance ：+ ℃ measured value Phase4 25±2 ：+ ℃ Phase 5 Phase5 85±2 ESR Satisfy initial specifi ed value Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below Capacitance Within ±20% of initial measured value ESR Phase 6 Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Lead strength (tensile) No terminal damage Conforms to 4.9 Capacitance ESR Satisfy initial specifi ed value Conforms to 4.13 Vibration resistance Frequency：10 to 55 Hz Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should be covered Solder temp：245±5℃ Solderability by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 ESR Satisfy initial specifi ed value Solder temp：260±10℃ Solder heat resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality Capacitance Conforms to 4.12 ESR Satisfy initial specifi ed value Temperature condition：−40℃→ Room temperature → Temperature cycle Current (30 minutes value) +85℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality Capacitance Within ±20% of initial measured value Conforms to 4.14 High temp. and high ESR Less than 120% of initial specifi ed value Temperature：40±2℃ humidity resistance Current (30 minutes value) Less than 120% of initial specifi ed value Relative humidity：90 to 95％ RH Testing time：240±8 hours Appearance No obvious abnormality Capacitance Within ±30% of initial measured value Conforms to 4.15 ESR Less than 200% of initial specifi ed value Temperature：85±2℃ High temperature load Voltage applied：MAX operating voltage Current (30 minutes value) Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Appearance No obvious abnormality Testing time：1000 0 Hours Voltage applied：5.0Vdc (Terminal Charging at the case's side be negative) condition Series resistance：0Ω Self discharge characteristics Charging time：24 hours Voltage between terminal leads higher than 4.2V (voltage holding characteristics) Let stand for 24 hours in condition described below with terminals opened. Storage Ambient temperature：Lower than 25℃ Relative humidity：Lower than 70%RH

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2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistive discharge characteristics (Backup time capability)

FR0H223ZF at 25˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 m A) (1 µ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

FR0H473ZF at 25˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h) FR0H104ZF 5.0 at 25˚C [Charging: 5 V, 0 Ω, 24 h]

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability)

FR0H224ZF at 25˚C [Charging: 5 V, 0 , 24 h] 5.0 Ω

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal voltage (Vdc) 1.0

0 0.1 1 10 100 1000 Discharge time (h) FR0H474ZF 5.0 at 25˚C [Charging: 5 V, 0 Ω, 24 h]

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 1000 Discharge time (h) FR0H105ZF 5.0 at 25˚C [Charging: 5 V, 0 Ω, 24 h]

4.0

3.0

2.0 50 kΩ 100 kΩ 250 kΩ 500 kΩ 1 MΩ 2.5 MΩ 5 MΩ (100 µ A) (50 µ A) (20 µ A) (10 µ A) (5 µ A) (2 µ A) (1 µ A) Terminal voltage (Vdc)

1.0

0 0.1 1 10 100 1000 Discharge time (h)

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2017.05.17 9565SCGVOL01E1705H1 FS-SERIES SuperCapacitor 16 (Miniaturized, Large Capacitance) (For cleanable products, see page 28.)

The miniaturized FS-Series SuperCapacitors with large [Characteristics of FS-Series] capacitance are backup devices adaptable to current • The volume of the products is approx. 1/3 that of the FA-/FE- consumption levels ranging from several hundred μA to Series products. several hundred mA. Choices can be made between 2 levels • The ESR is approx. 1/3 that of FY-/FM-Series. Adaptable to of maximum operating voltage to best correspond to backup current consumption levels ranging from several hundred μA operations: 5.5 V. DC (0.022 to 1.0 F), 11 V. DC (0.47 F and 1.0 to several hundred mA. F only) and 12 V. DC (1.0 F and 5.0 F only). Applications Features • Memory backup for microcomputers, SRAMs, DRAMs, and [Comparison with batteries] system boards in the event of a momentary power failure. • Environmentally-friendly end-product design can be • Auxiliary power source for mechanical devices (motors, achieved using these capacitors free from heavy metals such relays, solenoid valves, actuators, buzzers, and so on). as cadmium. • Wide operating range: –25 to +70°C. • No drawbacks of overcharge and overdischarge. No protection circuit required. Quick charge and discharge. • Full life duration that matches that of end-products if used properly. • Flow-solderable. Superior mountability. • Lead-free, PVC-free type. RoHS Compliant.

Part Number System

FS 0H 473 Z F Environmental impact reduced products Capacitance tolerance Z : +80 %; –20 % Nominal capacitance : 0.047F First two digits represent significant figures. Third digit specifies number of zeros to follow μ F code.

Maximum operating voltage 0 H : 5.5 Vdc 1A : 11 Vdc 1B : 12 Vdc SuperCapacitor FS：FS Series

SuperCapacitor USER'S MANUAL VOL.01 80

2017.05.17 9565SCGVOL01E1705H1 Markings Name of manufacturer, maximum operating voltage, Conversion table for manufacture date code capacitance, manufacture date code, serial no., and series Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 Indication A B C D E F H J K L M N name are marked on the external tube. The negative lead Month 1 2 3 4 5 6 7 8 9 10 11 12 terminal is marked with black bands. Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Maximum operating voltage External tube M6 Production 001 FS 5.5 V FS 5.5 V lot number 0.047F 0.047F Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative lead terminal Negative terminal marker (terminal on the case)

Dimensions

φ D ± 0.5 Negative terminal marker ℓ MIN. H MAX. Sleeve 0.3 MIN.

○－ ○＋

P ± 0.5

d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

MAX Nominal capacitance Dimension (unit:mm) MAX ESR MAX current Weight operating Part Number (at 1 kHz) at 30 min. voltage Charge Discharge (Ω) (mA) φD H P ℓ d1 d2 (g) (Vdc) system (F) system (F) FS0H223ZF 5.5 0.022 0.033 60.0 0.033 11.5 8.5 5.08 2.7 0.4 1.2 1.6

FS0H473ZF 5.5 0.047 0.072 40.0 0.071 13.0 8.5 5.08 2.2 0.4 1.2 2.6

FS0H104ZF 5.5 0.10 0.15 25.0 0.15 16.5 8.5 5.08 2.7 0.4 1.2 4.1

FS0H224ZF 5.5 0.22 0.33 25.0 0.33 16.5 13.0 5.08 2.7 0.4 1.2 5.3

FS0H474ZF 5.5 0.47 0.75 13.0 0.71 21.5 13.0 7.62 3.0 0.6 1.2 10

FS0H105ZF 5.5 1.0 1.3 7.0 1.5 28.5 14.0 10.16 6.1 0.6 1.4 18

FS1A474ZF 11.0 0.47 0.60 7.0 1.41 28.5 25.5 10.16 6.1 0.6 1.4 32

FS1A105ZF 11.0 1.0 1.3 7.0 3.0 28.5 31.5 10.16 6.1 0.6 1.4 35

FS1B105ZF 12.0 1.0 1.3 7.5 3.6 28.5 38.0 10.16 6.1 0.6 1.4 40

FS1B505ZF 12.0 5.0 6.5 4.0 18.0 44.8 60.0 20.00 9.5 1.0 1.4 160

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2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name FS type Test conditions (conforming to JIS C 5160-1) Item Category temperature range −25℃ to +70℃ MAX operating voltage 5.5Vdc, 11Vdc, 12Vdc 5.5V：0.022F to 1.0F Capacitance 11V：0.47, 1.0 Refer to “Measurement Conditions” 12V：1.0F, 5.0F Capacitance allowance +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also “Measurement ESR Refer to standard ratings Conditions” Current (30-minutes value) Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：6.3V (5.5V type) ：12.6V (11V type) ESR Less than 120% of initial specifi ed value ：13.6V (12V type) Current (30 minutes value) Less than 120% of initial specifi ed value Charge：30 sec. Discharge：9min 30sec. Number of cycles：1000 Series resistance ：0.022F 560Ω Surge ：0.047F 300Ω ：0.10F 150Ω Appearance No obvious abnormality ：0.22F 56Ω ：0.47F 30Ω ：1.0F 15Ω ：5.0F 10Ω Discharge resistance：0Ω Temperature：70±2℃ More than 50% of initial Capacitance measured value Phase 2 Less than 300% of initial ESR measured value Capacitance Phase 3 Conforms to 4.17 ESR Phase1：+25±2℃ Characteristics in Less than 150% of initial Phase2：−25±2℃ Capacitance different temperature measured value Phase4：+25±2℃ ：+ ℃ ESR Phase 5 Satisfy initial specifi ed value Phase5 70±2 Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below Capacitance Within ±20% of initial measured value ESR Phase 6 Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Lead strength (tensile) No terminal damage Conforms to 4.9 Capacitance ESR Satisfy initial specifi ed value Conforms to 4.13 Vibration resistance Frequency：10 to 55 Hz Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should be covered Solder temp：245±5℃ Solderability by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 ESR Satisfy initial specifi ed value Solder temp：260±10℃ Solder heat resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality Capacitance Conforms to 4.12 ESR Satisfy initial specifi ed value Temperature condition：−25℃→ Room temperature → Temperature cycle Current (30 minutes value) +70℃→ Room temperature Number of cycles：5 Cycles Appearance No obvious abnormality More than 90% of initial specifi ed value (5.5V type) Capacitance Within ±20% of initial measured value (11V type, 12V type) Conforms to 4.14 High temp. and high ESR Less than 120% of initial specifi ed value Temperature：40±2℃ humidity resistance Relative humidity：90 to 95％ RH Current (30 minutes value) Less than 120% of initial specifi ed value Testing time：240±8 hours Appearance No obvious abnormality More than 85% of initial specifi ed value (5.5V type) Capacitance Within ±30% of initial measured value (11V type, 12V type) Conforms to 4.15 Temperature：70±2℃ High temperature load ESR Less than 200% of initial specifi ed value Voltage applied：MAX operating voltage Current (30 minutes value) Less than 200% of initial specifi ed value Series protection resistance：0Ω +48 Testing time：1000 0 Hours Appearance No obvious abnormality

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FS0H223ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ 25 kΩ 50 kΩ (5 mA) (2 mA) (1 mA) (500 µ A) (200 µ A) (100 µ A) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FS0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 500 Ω 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ 25 kΩ (10 mA) (5 mA) (2 mA) (1 mA) (500 µ A) (200 µ A) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FS0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 250 Ω 500 Ω 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ (20 mA) (10 mA) (5 mA) (2 mA) (1 mA) (500 µ A) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

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FS0H224ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 50 Ω 100 Ω 250 Ω 500 Ω 1 kΩ 2.5 kΩ (100 mA) (50 mA) (20 mA) (10 mA) (5 mA) (2 mA) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FS0H474ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 25 Ω 50 Ω 100 Ω 250 Ω 500 Ω (200 mA) (100 mA) (50 mA) (20 mA) (10 mA) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

FS0H105ZF

at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 10 Ω 25 Ω 50 Ω 100 Ω 250 Ω (500 mA) (200 mA) (100 mA) (50 mA) (20 mA) Terminal

1.0

0 1 10 100 1000

Discharge time (sec)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability)

FS1A474ZF at 25 ˚C [Charging: 10 V, 0 Ω, 24 h] 10.0

8.0

6.0 voltage (Vdc)

4.0 50 100 200 500 1 k 2 k Terminal Ω Ω Ω Ω Ω Ω (200 mA) (100 mA) (50 mA) (20 mA) (10 mA) (5 mA)

2.0

0 1 10 100 1000 10000 Discharge time (sec)

FS1A105ZF at 25 ˚C [Charging: 10 V, 0 Ω, 24 h] 10.0

8.0

6.0 voltage (Vdc)

4.0 50 100 200 500 1 k 2 k Terminal Ω Ω Ω Ω Ω Ω (200 mA) (100 mA) (50 mA) (20 mA) (10 mA) (5mA)

2.0

0 1 10 100 1000 10000 Discharge time (sec)

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FS1B105ZF

at 25 ˚C [Charging: 12 V, 0 Ω, 24 h] 12.0

10.0

8.0

6.0 voltage (Vdc)

4.0 Terminal

2.0 10 Ω 20 Ω 51 Ω 100 Ω 200 Ω 510 Ω 1 kΩ (1.2 A) (600 mA) (240 mA) (120 mA) (60 mA) (24 mA) (12 mA)

0 1 10 100 1000 Discharge time (sec)

FS1B505ZF

at 25 ˚C [Charging: 12 V, 0 Ω, 24 h]

14.0

12.0

10.0

8.0 voltage (Vdc)

6.0

Terminal 4.0

2.0 10 Ω 20 Ω 51 Ω 100 Ω (1.2 A) (600 mA) (235 mA) (120 mA) 0 10 100 1000 10000 Discharge time (sec)

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2017.05.17 9565SCGVOL01E1705H1 FA-SERIES/FE-SERIES SuperCapacitor 17 (For Heavy Current) (For cleanable products, see page 28.)

The miniaturized FA-Series/FE-Series SuperCapacitors with [Characteristics of FA-/FE-Series] large capacitance and low internal resistance (Equivalent • Electric double-layer capacitors capable of carrying out Series Resistance) are capable of carrying out charges and charges and discharges ranging in the order of milliamperes discharges ranging in the order of milliamperes to amperes. to amperes with an ESR (Equivalent Series Resistance) approx. 1/4 that of the FS-Series and approx. 1/10 that of These products offer excellent performance in instantaneous FY-/FM-Series. backup (countermeasure against momentary power failure) of electric load of the same range in electronic devices. [Differences between FA-Series and FE-Series] • The FE-Series products have lower ESR speciﬁ cations than those of FA-Series featuring equivalent capacitance. And as Features for dimensions, the FE-Series products are one size smaller [Comparison with batteries] than the FA-Series. Due to the differences in guaranteed • Environmentally-friendly end-product design can be performance and lead terminal pitches, however, the achieved using these capacitors free from heavy metals such customer is requested to choose the proper series for each as cadmium. end-product. • Wide operating range: –25 to +70°C (–40 to +70°C for FE- • The FA-Series offers a model which guarantees a maximum Series). operating voltage of 11V. (5.5V maximum for the FE-Series.) • No drawbacks of overcharge and overdischarge. No protection circuit or limiting circuit required. Quick charge and Applications discharge. • Memory backup for microcomputers, SRAMs, DRAMs, and • Full life duration that matches that of end-products if used system boards in the event of a momentary power failure. properly. • Auxiliary power source for mechanical devices (motors, • Flow-solderable. Superior mountability. relays, solenoid valves, actuators, buzzers, and so on). • Lead-free, PVC-free type. RoHS Compliant.

Part Number System

FE 0H 473 Z F Environmental impact reduced products

Capacitance tolerance Z : +80 %; –20 %

Nominal capacitance : 0.047F First two digits represent significant figures. Third digit specifies number of zeros to follow μ F code.

Maximum operating voltage 0 H : 5.5 Vdc 1 A : 11 Vdc (FA Series only)

SuperCapacitor FA : FA Series FE : FE Series

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2017.05.17 9565SCGVOL01E1705H1 FA Series

Marking Name of manufacturer, rated voltage, capacitance, Conversion table for manufacture date code manufacture date code, serial no., and series name are Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 Indication A B C D E F H J K L M N marked on the external tube. The negative lead terminal is Month 1 2 3 4 5 6 7 8 9 10 11 12 marked with black bands. Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Rated voltage External tube M6 Production 001 FA 5 V FA 5 V lot number 1.0F 1.0F Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative lead terminal Negative terminal marker (terminal on the case)

Dimensions

φ ± Negative terminal marker D 0.5 ℓ MAX. H MAX. 2.0 MAX.

Sleeve ○－ ○＋ P ± 0.5 d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

MAX Nominal capacitance MAX Dimension (unit:mm) Rated MAX ESR operating current at Weight Part Number voltage (at 1 kHz) voltage Charge Discharge 30 min. (g) (Vdc) (Ω) φD H P ℓ d1 d2 (Vdc) system (F) system (F) (mA) FA0H473ZF 5.5 5 0.047 0.075 20.0 0.071 16.0 15.5 5.1 5.0 0.4 1.2 6.2 FA0H104ZF 5.5 5 0.10 0.16 8.0 0.15 21.5 15.5 7.6 5.5 0.6 1.2 12 FA0H224ZF 5.5 5 0.22 0.35 5.0 0.33 28.5 16.5 10.2 9.5 0.6 1.4 25 FA0H474ZF 5.5 5 0.47 0.75 3.5 0.71 36.5 16.5 15.0 9.5 0.6 1.7 42 FA0H105ZF 5.5 5 1.0 1.6 2.5 1.5 44.5 18.5 20.0 9.5 1.0 1.4 65 FA1A223ZF 11.0 10 0.022 0.035 20.0 0.066 16.0 25.0 5.1 5.0 0.4 1.2 7.5 FA1A104ZF 11.0 10 0.10 0.16 8.0 0.30 28.5 25.5 10.2 9.5 0.6 1.4 32 FA1A224ZF 11.0 10 0.22 0.35 6.0 0.66 36.5 27.5 15.0 9.5 1.0 1.4 55 FA1A474ZF 11.0 10 0.47 0.75 4.0 1.41 44.5 28.5 20.0 9.5 1.0 1.4 83

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2017.05.17 9565SCGVOL01E1705H1 FE Series

Marking Name of manufacturer, maximum operating voltage, Conversion table for manufacture date code capacitance, manufacture date code, serial no., and series Year 2010 ’11 ’12 ’13 ’14 ’15 ’16 ’17 ’18 ’19 ’20 ’21 Indication A B C D E F H J K L M N name are marked on the external tube. The negative lead Month 1 2 3 4 5 6 7 8 9 10 11 12 terminal is marked with black bands. Indication 1 2 3 4 5 6 7 8 9 O N D

Manufacture Development diagram of external tube date code SuperCapacitor SuperCapacitor Maximum operating voltage External tube M6 Production 001 FE 5.5V FE 5.5 V lot number 0.047F 0.047F Capacitance M6 SuperCapacitor SuperCapacitor

Series name Negative lead terminal Negative terminal marker (terminal on the case)

Dimensions

Negative terminal marker φ D ± 0.5 ℓ MIN. H MAX. Sleeve 0.3 MIN.

○－ ○＋

P ± 0.5 d1 ± 0.1

d2 ± 0.1 （Terminal）

Standard Ratings

MAX Nominal capacitance Dimension (unit:mm) MAX ESR MAX current operating Weight Part Number (at 1 kHz) at 30 min. voltage Charge Discharge (g) (Ω) (mA) φD H P ℓ d1 d2 (Vdc) system (F) system (F) FE0H473ZF 5.5 0.047 0.075 14.0 0.071 14.5 14.0 5.1 2.2 0.4 1.2 3.9 FE0H104ZF 5.5 0.10 0.16 6.5 0.15 16.5 14.0 5.1 2.7 0.4 1.2 5 FE0H224ZF 5.5 0.22 0.35 3.5 0.33 21.5 15.5 7.6 3.0 0.6 1.2 9.5 FE0H474ZF 5.5 0.47 0.75 1.8 0.71 28.5 16.5 10.2 6.1 0.6 1.4 16 FE0H105ZF 5.5 1.0 1.4 1.0 1.5 36.5 18.5 15.0 6.1 0.6 1.7 38 FE0H155ZF 5.5 1.5 2.1 0.6 2.3 44.5 18.5 20.0 6.1 1.0 1.4 72

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2017.05.17 9565SCGVOL01E1705H1 Performance Characteristics Series name Test conditions FA FE Item (conforming to JIS C 5160-1) Category temperature range −25℃ to +70℃ −40℃ to +70℃ MAX operating voltage 5.5Vdc, 11Vdc 5.5Vdc 5.5V：0.047F to 1.0F Capacitance 0.047F to 1.5F Refer to “Measurement Conditions” 11V：0.022F to 0.47F Capacitance allowance +80％ , −20％ +80％ , −20％ Refer to “Measurement Conditions” Measured at 1kHz, 10mA ; See also ESR Refer to standard ratings Refer to standard ratings “Measurement Conditions” Current (30-minutes value) Refer to standard ratings Refer to standard ratings Refer to “Measurement Conditions” Capacitance More than 90% of initial specifi ed value Surge voltage ：6.3V (5.5V type) ：12.6V (11V type) ESR Less than 120% of initial specifi ed value Charge：30 sec. Current (30 minutes value) Less than 120% of initial specifi ed value Discharge：9min 30sec. Number of cycles：1000 Series resistance ：0.047F 300Ω Surge ：0.10F 150Ω ：0.22F 56Ω Appearance No obvious abnormality ：0.47F 30Ω ：1.0F, 1.5F 15Ω Discharge resistance：0Ω Temperature：70±2℃ More than 70% of Capacitance Phase initial measured value Phase 2 Less than 300% of 2 ESR initial measured value More than 40% of Capacitance initial measured value Phase Phase Conforms to 4.17 3 3 Less than 400% of ESR Phase1：+25±2℃ Characteristics initial measured value Phase2：−25±2℃ in different Less than 150% of Less than 200% of Phase3：−40±2℃ (FE type) Capacitance temperature initial measured value initial measured value Phase4：+25±2℃ Phase Phase ：+ ℃ ESR 5 Satisfy initial specifi ed value 5 Satisfy initial specifi ed value Phase5 70±2 Phase6：+25±2℃ Current (30 minutes value) 1.5CV (mA) or below 1.5CV (mA) or below Within ±20% of initial Within ±20% of initial Capacitance Phase measured value Phase measured value ESR 6 Satisfy initial specifi ed value 6 Satisfy initial specifi ed value Current (30 minutes value) Satisfy initial specifi ed value Satisfy initial specifi ed value Lead strength (tensile) No terminal damage No terminal damage Conforms to 4.9 Capacitance Conforms to 4.13 Vibration ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Frequency：10 to 55 Hz resistance Current (30 minutes value) Testing time：6 hours Appearance No obvious abnormality No obvious abnormality Conforms to 4.11 Over 3/4 of the terminal should Over 3/4 of the terminal should Solder temp：245±5℃ Solderability be covered by the new solder be covered by the new solder Dipping time：5±0.5 sec. 1.6mm from the bottom should be dipped. Capacitance Conforms to 4.10 Solder heat ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Solder temp：260±10℃ resistance Current (30 minutes value) Dipping time：10±1 sec. 1.6mm from the bottom should be dipped. Appearance No obvious abnormality No obvious abnormality Capacitance Conforms to 4.12 Temperature condition：−25℃ (−40℃ for FE type) → Temperature ESR Satisfy initial specifi ed value Satisfy initial specifi ed value Room temperature → cycle Current (30 minutes value) +70℃→ Room temperature Appearance No obvious abnormality No obvious abnormality Number of cycles：5 Cycles More than 90% of initial Within ±20% of initial Capacitance specifi ed value measured value Conforms to 4.14 High temp. and Less than 120% of initial Less than 120% of initial ESR Temperature：40±2℃ high humidity specifi ed value specifi ed value Relative humidity：90 to 95％ RH resistance Less than 120% of initial Less than 120% of initial Current (30 minutes value) Testing time：240±8 hours specifi ed value specifi ed value Appearance No obvious abnormality No obvious abnormality More than 85% of initial Within ±30% of initial Capacitance specifi ed value measured value Conforms to 4.15 Less than 120% of initial Less than 300% of initial High ESR Temperature：70±2℃ temperature specifi ed value specifi ed value Voltage applied：MAX operating voltage load Less than 200% of initial Less than 200% of initial Series protection resistance：0Ω Current (30 minutes value) +48 specifi ed value specifi ed value Testing time：1000 0 Hours Appearance No obvious abnormality No obvious abnormality

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2017.05.17 9565SCGVOL01E1705H1 Typical Performance Data Resistive discharge characteristics (Backup time capability)

FA0H473ZF, FE0H473ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 500 Ω 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ (10 mA) (5 mA) (2 mA) (1 mA) (500 µ A) Terminal

1.0

0 1 10 100 1000 Discharge time (sec)

FA0H104ZF, FE0H104ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 250 Ω 500 Ω 1 kΩ 2.5 kΩ 5 Ω (20 mA) (10 mA) (5 mA) (2 mA) (1 mA) Terminal

1.0

0 1 10 100 1000 Discharge time (sec)

FA0H224ZF, FE0H224ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 50 Ω 100 Ω 250 Ω 500 Ω 1 kΩ (100 mA) (50 mA) (20 mA) (10 mA) (5 mA) Terminal

1.0

0 1 10 100 1000 Discharge time (sec)

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FA0H474ZF, FE0H474ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 10 Ω 25 Ω 50 Ω 100 Ω 250 Ω (500 mA) (200 mA) (100 mA) (50 mA) (20 mA) Terminal

1.0

0 1 10 100 1000 Discharge time (sec)

FA0H105ZF, FE0H105ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 5 Ω 10 Ω 25 Ω 50 Ω 100 Ω (1A) (500 mA) (200 mA)(100 mA) (50 mA) Terminal

1.0

0 1 10 100 1000 Discharge time (sec)

FE0H155ZF at 25 ˚C [Charging: 5 V, 0 Ω, 24 h] 5.0

4.0

3.0 voltage (Vdc)

2.0 5 Ω 10 Ω 25 Ω 50 Ω 100 Ω (1A) (500 mA) (200 mA) (100 mA) (50 mA) Terminal

1.0

0 1 10 100 1000 Discharge time (sec)

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FA1A223ZF at 25 ˚C [Charging: 10 V, 0 Ω, 24 h] 10.0

8.0

6.0 voltage (Vdc)

4.0 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ 25 kΩ (10 mA) (4 mA) (2 mA) (1 mA) (400 µA) Terminal

2.0

0 1 10 100 1000 Discharge time (sec)

FA1A104ZF at 25 ˚C [Charging: 10 V, 0 Ω, 24 h] 10.0

8.0

6.0 voltage (Vdc)

4.0 500 Ω 1 kΩ 2.5 kΩ 5 kΩ 10 kΩ (20 mA) (10 mA) (4 mA) (2 mA)(1 mA) Terminal

2.0

0 1 10 100 1000 Discharge time (sec)

FA1A224ZF at 25 ˚C [Charging: 10 V, 0 Ω, 24 h] 10.0

8.0

6.0 voltage (Vdc)

4.0 100 Ω 250 Ω 500 Ω 1 kΩ 2.5 kΩ (10 mA) (40 mA) (20 mA) (10 mA) (4 mA) Terminal

2.0

0 1 10 100 1000 Discharge time (sec)

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2017.05.17 9565SCGVOL01E1705H1 Resistive discharge characteristics (Backup time capability)

FA1A474ZF at 25 ˚C [Charging: 10 V, 0 Ω, 24 h] 10.0

8.0

6.0 voltage (Vdc)

4.0 25 Ω 50 Ω 100 Ω 250 Ω 500 Ω (400 mA) (200 mA) (100 mA) (40 mA) (20 mA) Terminal

2.0

0 1 10 100 1000 Discharge time (sec)

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2017.05.17 9565SCGVOL01E1705H1 18 APPLICATION OF SuperCapacitor

1. Master Circuit A master circuit using a SuperCapacitor is shown in the ﬁ gure below. Application examples of backup power source circuits for electric circuit operations and data preservation of microcomputers and memory devices during the power source interruption of products, of which examples are shown in the table, Example of power source interruption.

(1) Master circuit

Rc : Power source protective resistance (To be inserted depending on power source current capacity)

Rectifier diode

Power source C SuperCapacitor Load

(2) Example of power source interruption

Category Speciﬁ c Example Unanticipated power source • Power failure, unplugging, operation error interruption • Dislocation of batteries in battery box due to impact Unstable connection (2-(2) ex.) • Lack of sunlight on solar battery Anticipated power source • Turning off of power switch • Changing of battery interruption

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2017.05.17 9565SCGVOL01E1705H1 2. Backup Power Source During Source Interruption

(1) Backup during power source interruption of alternating current power source Even in the event of power source interruption due to power failure, Rectification operation error, etc., the power source of the memory component circuit is backed up for a certain period of time so that data preserved in memory is not lost. Alternating Microcomputer, SuperCapacitor Load Example of products employing backup circuits: current Memory power source • VTR • Measurement, control • Telephone set • Audio equipment • Radio equipment • (DTS) • Ofﬁ ce automation equipment • Others

(2) Backup when power source is off Even where memory and clock functions are preserved and operate for a certain time after the power source is off, the power source for such functions is backed up. Battery or Direct Load Example of products employing backup circuits: Current Power Source Microcomputer, SuperCapacitor • VTR camera Memory • Rice cooker with time display function • On-vehicle (DTS)

(3) Electronic circuit auxiliary power source

Operation of electronic circuit for certain time after power source is off. Example of products employing backup circuits: • Radio with timed listening function Battery or Direct SuperCapacitor Electronic Current Power Source circuit

(4) Lighting of lamps or LEDs

Lighting of lamp or LED during power failure or when power source is off, gradually darkening after a certain time. Example of products employing backup circuits: Battery, direct current SuperCapacitor Lamp power source or direct LED • Lights for bicycles, etc. current generator. • Power failure display lamp

(5) Motor drive

Discharge from SuperCapacitor, for low power source capacity and initiating initial torque. Example of products employing backup circuits: Charging terminal SuperCapacitor Motor • FDD, HDD

(6) Backup for solar batteries

When the solar battery is not operating (when not subject to sunlight), back up of power source of memory component. Example of products employing backup circuits: Load • Calculator • Electronic wristwatch SuperCapacitor Microcomputer, Solar Battery Memory • Electronic stopwatch

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2017.05.17 9565SCGVOL01E1705H1 3. Backup Power Source During Source Power Source Voltage Drop Dueto Heavy Loading

In the event of heavy loading (respective of motors, relays, etc.), as a large current becomes necessary instantaneously, if power source capacity is low, voltage declines and memory and electronic circuits

Motor, sharing a power source may experience malfunction. Thus, memory Battery or Direct etc. Current Power Source Microcomputer, and electronic circuit power sources are backed up instantaneously. SuperCapacitor Memory Example of products employing backup circuits: • Single lens reﬂ ex camera • Printer

4. Backup Power Source for Products Using Batteries Regarding a product using a battery, as there are many cases where a battery is used as a backup power source, it is thought that a SuperCapacitor is unnecessary. However, in a case as in Figure 27, a SuperCapacitor is used.

(1) Backup when changing battery

Temporary backup of power source of memory component, when changing a battery due to battery exhaustion, etc., in devices that normally operate by battery. Battery Load Microcomputer, Example of products employing backup circuits: SuperCapacitor Memory • Portable word processor • Handheld computer • Camera • Electronic taxi meter • On-vehicle (DTS)

(2) Backup for instantaneous disconnection due to unstable battery connection

As the connection of batteries inserted into a battery box may undergo disconnection (instantaneous separation) due to vibration, impact, etc., power source backup for memory component is necessary. Battery Load Microcomputer, SuperCapacitor Example of products employing backup circuits: Memory • Portable Terminal

(3) Backup for microcomputers and memories while shifting from normal operation to standby mode When shifting to standby during power failure, there are cases where it may be necessary to operate the microcomputers. Microcomputers with operation-guaranteed voltage of 5 +/-0.5 V cannot be operated

Battery or Direct Load with backup-use batteries. Because a voltage of backup-use batteries Current Power Source Microcomputer, SuperCapacitor is usually 3.0 to 3.6 V, and is insufﬁ cient to operate microcomputers. Backup use Memory battery In such case, with a SuperCapacitor, backup is possible while shifting to standby. Example of products employing backup circuits: • Portable Terminal

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2017.05.17 9565SCGVOL01E1705H1 5. Use of Discharge Characteristics of Capacitors In the event of designing a power source in which voltage is gradually reduced, an extremely simple means of design may be realized by using discharge characteristics of a capacitor. In such case, where using TOKIN’S SuperCapacitors, the products become compact. Moreover, with SuperCapacitors, problems do not arise when charging and discharging is executed without protective resistance. Where current capacity of the power source is small, it is necessary to have protective resistance in order to preserve the power source. Figure 28 shows an application example of the use of discharge characteristics of a capacitor.

(1) Operation of solenoid valve

Use of discharge characteristics of a capacitor to operate a solenoid valve for a certain time. Battery Solenoid Example of products employing backup circuits: valve coil: SuperCapacitor • Gas water heater • Gas range

(2) Gradual stopping of motor

Gradual suspension of motor revolution during power failure or when power source is off Battery or Direct SuperCapacitor Motor Example of products employing backup circuits: Current Power Source • Mechanized Music Box

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2017.05.17 9565SCGVOL01E1705H1 SuperCapacitor USER'S MANUAL VOL.01 99

2017.05.17 9565SCGVOL01E1705H1 SuperCapacitor USER'S MANUAL VOL.01 100

2017.05.17 9565SCGVOL01E1705H1 Precautions

(1) Request for safety design of equipment and system, taking into account electronic component failures during operation Generally, there is a certain probability of failures with electronic components. Despite the fact that we are striving to improve the quality and reliability of electronic components, it is impossible to reduce the probability of failure to 0. Therefore, when using our electronic component products, you are requested to perform safety design such as redundant design with respect to accidents resulting in injury or death, fi re accidents, social damage, or fi re prevention design or design preventing malfunction, etc. (For details of failure mode, see "Operating Precautions.") (2) Quality grade of components and applicable equipment The product falls under the category of standard grade unless specifi ed otherwise. Our electronic component products are classifi ed into three categories in low to high order of quality grade, [standard grade], [special grade], and [specifi c grade] in which case the customer specifi es a quality assurance program separately. Each quality grade indicates that the product is intended for the following applications: If you are planning to use the product for applications other than those specifi ed for the [standard grade], be sure to contact our sales representative in advance. Standard grade :Computers, OA equipment, communications equipment, measurement equipment, AV equipment, domestic appliances, machine tools,personal equipment, industrial robots Special grade :Transportation equipment (automobile, train, vessel, etc.), traffic signal equipment, anti-disaster/anti-crime devices, safety devices, medical equipment which is not directly intended for life support systems Specifi c grade :Aircraft equipment, aerospace equipment, marine relay equipment, atomic power control systems, medical equipment for life support, devices or systems, etc. When there is no indication of quality grade in documents of our electronic component products such as catalogs, data sheets, data books, etc., this means that the relevant product conforms to the standard grade. (3) This document is subject to change without notice. The contents of this document are based on documents as of May 2017, and are subject to change without notice in the future. For volume production design, contact our sales representative by way of precaution. (4) No part of this document may be reprinted or copied without our written consent. (5) Industrial property We will assume no responsibility for any infringement of third party's industrial property, etc. in relation to the use of this product except for cases involving the structure or manufacturing method of our products. (6) Export Control For customers outside Japan TOKIN products should not be used or sold for use in the development, production, stockpiling or utilization of any conventional weapons or mass-destructive weapons (nuclear weapons, chemical or biological weapons, or missiles), or any other weapons. For customers in Japan For products which are controlled items subject to the "Foreign Exchange and Foreign Trade Law" of Japan, the export license specifi ed by the law is required for export.

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