46Th RMS Program Notes
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Pezzottaite from Ambatovita, Madagascar: a New Gem Mineral
PEZZOTTAITE FROM AMBATOVITA, MADAGASCAR: A NEW GEM MINERAL Brendan M. Laurs, William B. (Skip) Simmons, George R. Rossman, Elizabeth P. Quinn, Shane F. McClure, Adi Peretti, Thomas Armbruster, Frank C. Hawthorne, Alexander U. Falster, Detlef Günther, Mark A. Cooper, and Bernard Grobéty Pezzottaite, ideally Cs(Be2Li)Al2Si6O18, is a new gem mineral that is the Cs,Li–rich member of the beryl group. It was discovered in November 2002 in a granitic pegmatite near Ambatovita in cen- tral Madagascar. Only a few dozen kilograms of gem rough were mined, and the deposit appears nearly exhausted. The limited number of transparent faceted stones and cat’s-eye cabochons that have been cut usually show a deep purplish pink color. Pezzottaite is distinguished from beryl by its higher refractive indices (typically no=1.615–1.619 and ne=1.607–1.610) and specific gravity values (typically 3.09–3.11). In addition, the new mineral’s infrared and Raman spectra, as well as its X-ray diffraction pattern, are distinctive, while the visible spectrum recorded with the spec- trophotometer is similar to that of morganite. The color is probably caused by radiation-induced color centers involving Mn3+. eginning with the 2003 Tucson gem shows, (Be3Sc2Si6O18; Armbruster et al., 1995), and stoppaniite cesium-rich “beryl” from Ambatovita, (Be3Fe2Si6O18; Ferraris et al., 1998; Della Ventura et Madagascar, created excitement among gem al., 2000). Pezzottaite, which is rhombohedral, is Bcollectors and connoisseurs due to its deep purplish not a Cs-rich beryl but rather a new mineral species pink color (figure 1) and the attractive chatoyancy that is closely related to beryl. -
Phase Equilibria and Thermodynamic Properties of Minerals in the Beo
American Mineralogist, Volwne 71, pages 277-300, 1986 Phaseequilibria and thermodynamic properties of mineralsin the BeO-AlrO3-SiO2-H2O(BASH) system,with petrologicapplications Mlnx D. B.qnroN Department of Earth and SpaceSciences, University of California, Los Angeles,Los Angeles,California 90024 Ansrru,cr The phase relations and thermodynamic properties of behoite (Be(OH)r), bertrandite (BeoSirOr(OH)J, beryl (BerAlrSiuO,r),bromellite (BeO), chrysoberyl (BeAl,Oo), euclase (BeAlSiOo(OH)),and phenakite (BerSiOo)have been quantitatively evaluatedfrom a com- bination of new phase-equilibrium, solubility, calorimetric, and volumetric measurements and with data from the literature. The resulting thermodynamic model is consistentwith natural low-variance assemblagesand can be used to interpret many beryllium-mineral occurTences. Reversedhigh-pressure solid-media experimentslocated the positions of four reactions: BerAlrSiuO,,: BeAlrOo * BerSiOo+ 5SiO, (dry) 20BeAlSiOo(OH): 3BerAlrsi6or8+ TBeAlrOo+ 2BerSiOn+ l0HrO 4BeAlSiOo(OH)+ 2SiOr: BerAlrSiuO,,+ BeAlrOo+ 2H2O BerAlrSiuO,,+ 2AlrSiOs : 3BeAlrOa + 8SiO, (water saturated). Aqueous silica concentrationswere determined by reversedexperiments at I kbar for the following sevenreactions: 2BeO + H4SiO4: BerSiOo+ 2H2O 4BeO + 2HoSiOo: BeoSirO'(OH),+ 3HrO BeAlrOo* BerSiOo+ 5H4Sio4: Be3AlrSiuOr8+ loHro 3BeAlrOo+ 8H4SiO4: BerAlrSiuOrs+ 2AlrSiO5+ l6HrO 3BerSiOo+ 2AlrSiO5+ 7H4SiO4: 2BerAlrSiuOr8+ l4H2o aBeAlsioloH) + Bersio4 + 7H4sio4:2BerAlrsiuors + 14Hro 2BeAlrOo+ BerSiOo+ 3H4SiOo: 4BeAlSiOr(OH)+ 4HrO. -
L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}. -
Alteration of Spodumene, Montebrasite and Lithiophilite In
American Mineralogist, Volume 67, pages 97-113, 1982 Alteration of spodumene,montebrasite and lithiophilite in pegmatites of the White PicachoDistrict, Arizona Davrp Lor.rooxrnNo DoNer-uM. Bunr Department of Geology Arizona State University Tempe, Arizona 85281 Abstract The crystallization sequence and metasomatic alteration of spodumene (LiAlSizOe), montebrasite(LiAIPO4(OH,F)), and lithiophilite (Li(Mn,Fe)PO+)are describedfor nine zoned lithium pegmatitesin the White Picacho district, Arizona. The observedcrystalliza- tion trends suggesta progressiveincrease in the activities of lithium species(spodumene follows microcline as the principal alkali aluminosilicate), as well as an increase in the activities of the acidic volatiles phosphorus and fluorine (montebrasite succeedsspodu- mene as the stableprimary lithium phase).Much of the lithiophilite occurs with columbite, apatite, beryl, zircon, and tourmaline in cleavelanditecomplexes that formed in part at the expenseof quartz-spodumenepegmatite. Fracture-controlledpseudomorphic alteration of the primary lithium minerals is widespread and apparently is the result of subsolidus reactionswith residualpegmatitic fluids. Spodumenehas been replacedby eucryptite, albite, and micas. Alteration products of montebrasite include low-fluorine secondary montebrasite,crandallite (tentative), hydroxylapatite, muscovite, brazilianite, augelite (tentative),scorzalite, kulanite, wyllieite, and carbonate-apatite.Secondary phases identi- fied in altered lithiophilite include hureaulite, triploidite, eosphorite, -
Mineralogy and Chemistry of Rare Earth Elements in Alkaline Ultramafic Rocks and Fluorite in the Western Kentucky Fluorspar District Warren H
University of Kentucky UKnowledge Kentucky Geological Survey Report of Kentucky Geological Survey Investigations 6-2019 Mineralogy and Chemistry of Rare Earth Elements in Alkaline Ultramafic Rocks and Fluorite in the Western Kentucky Fluorspar District Warren H. Anderson University of Kentucky, [email protected] Right click to open a feedback form in a new tab to let us know how this document benefits oy u. Follow this and additional works at: https://uknowledge.uky.edu/kgs_ri Part of the Geology Commons Repository Citation Anderson, Warren H., "Mineralogy and Chemistry of Rare Earth Elements in Alkaline Ultramafic Rocks and Fluorite in the Western Kentucky Fluorspar District" (2019). Kentucky Geological Survey Report of Investigations. 55. https://uknowledge.uky.edu/kgs_ri/55 This Report is brought to you for free and open access by the Kentucky Geological Survey at UKnowledge. It has been accepted for inclusion in Kentucky Geological Survey Report of Investigations by an authorized administrator of UKnowledge. For more information, please contact [email protected]. Mineralogy and Chemistry of Rare Earth Elements in Alkaline Ultramafic Rocks and Fluorite in the Western Kentucky Fluorspar District Warren H. Anderson Report of Investigations 8 doi.org/10.13023/kgs.ri08.13 Series XIII, 2019 Cover Photo: Various alkaline ultramafic rocks showing porphyritic, brecciated, and aphanitic textures, in contact with host limestone and altered dike texture. From left to right: • Davidson North dike, Davidson core, YH-04, 800 ft depth. Lamprophyre with calcite veins, containing abundant rutile. • Coefield area, Billiton Minner core BMN 3. Intrusive breccia with lamprophyric (al- nöite) matrix. • Maple Lake area, core ML-1, 416 ft depth. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Shear Zone Initiation in the Marcy Anorthosite Massif, Adirondacks, New York, USA James Hodge University of Maine, [email protected]
The University of Maine DigitalCommons@UMaine Electronic Theses and Dissertations Fogler Library Summer 8-23-2019 Fractures, Fluids, and Metamorphism: Shear Zone Initiation in the Marcy Anorthosite Massif, Adirondacks, New York, USA James Hodge University of Maine, [email protected] Follow this and additional works at: https://digitalcommons.library.umaine.edu/etd Part of the Geochemistry Commons, Geology Commons, and the Tectonics and Structure Commons Recommended Citation Hodge, James, "Fractures, Fluids, and Metamorphism: Shear Zone Initiation in the Marcy Anorthosite Massif, Adirondacks, New York, USA" (2019). Electronic Theses and Dissertations. 3050. https://digitalcommons.library.umaine.edu/etd/3050 This Open-Access Thesis is brought to you for free and open access by DigitalCommons@UMaine. It has been accepted for inclusion in Electronic Theses and Dissertations by an authorized administrator of DigitalCommons@UMaine. For more information, please contact [email protected]. FRACTURES, FLUIDS, AND METAMORPHISM: SHEAR ZONE INITIATION IN THE MARCY ANORTHOSITE MASSIF, ADIRONDACKS, NEW YORK, USA By James Hodge B.S. College of Saint Rose, 2017 A Thesis Submitted in Partial Fulfillment of the Requirements for the Degree of Master of Science (in Earth and Climate Sciences) The Graduate School The University of Maine August 2019 Advisory Committee: Scott Johnson, Professor and Director School of Earth and Climate Sciences, Advisor Chris Gerbi, Professor School of Earth and Climate Sciences, Advisor Alicia Cruz-Uribe, Professor School of Earth and Climate Sciences Martin Yates, Professor School of Earth and Climate Sciences FRACTURES, FLUIDS, AND METAMORPHISM: SHEAR ZONE INITIATION IN THE MARCY ANORTHOSITE MASSIF, ADIRONDACKS, NEW YORK, USA By James Hodge Thesis Advisors: Dr. -
Heat Capacities and Thermodynamic Functions for Beryl, Beralrsiuotr
American Mineralogist, Volume 7I, pages 557-568, 1986 Heat capacitiesand thermodynamicfunctions for beryl, BerAlrSiuOtr, phenakite, BerSiOn,euclase, BeAlSiOo(OH)' bertranditeo BeoSirOt(OH)r,and chrysoberyl' BeAl2Oa B. S. HnluNcw.q,Y U.S. GeologicalSurvey, Reston, Y irgrnia22092 M. D. B.nnroN Departmentof Earthand SpaceSciences, University of California,Los Angeles,Los Angeles,California 90024 R. A. Ronrn, H. T. HLsnr.roN, Jn. U.S. GeologicalSurvey, Reston, Y irginia22092 Ansrru,cr The heat capacities of beryl, phenakite, euclase,and bertrandite have been measured betweenabout 5 and 800 K by combined quasi-adiabaticcryogenic calorimetry and dif- ferential scanningcalorimetry. The heat capacitiesof chrysoberylhave beenmeasured from 340 to 800 K. The resulting data have been combined with solution and phase-equilibrium experimentaldata and simultaneouslyfit using the program pHAS2oto provide an internally consistent set of thermodynamic properties for several important beryllium phases.The experimentalheat capacitiesand tablesof derived thermodynamic propertiesare presented in this report. The derived thermodynamic properties at I bar and 298.15 K for the stoichiometric beryllium phasesberyl, phenakite, euclase,and bertrandite are entropies of 346.7 + 4.7, 63.37+0.27,89.09+0.40, andl72.l+0.77 J/(mol'K),respectively,andGibbsfree energiesof formation(elements) of -8500.36 + 6.39, -2028.39 + 3.78, -2370.17 + 3.04, and -4300.62 + 5.45 kJlmol, respectively,and, -2176.16 + 3.18kJ/mol for chrysoberyl. The coefficientscr to c, of the heat-capacityfunctions are as follows: valid phase ct c2 c, x 105 c4 c, x 10-6 range beryl 1625.842 -0.425206 12.0318 -20 180.94 6.82544 200-1800K phenakite 428.492 -0.099 582 1.9886 -5 670.47 2.0826 200-1800K euclase 532.920 -0.150729 4.1223 -6726.30 2.1976 200-1800K bertrandite 825.336 -0.099 651 -10 570.31 3.662r7200-1400 K chrysoberyl 362.701 -0.083 527 2.2482 -4033.69 -6.7976 200-1800K whereC!: cr * ctT + crT2 * coT-os* crT-2and Zisinkelvins. -
Alphab Etical Index
ALPHAB ETICAL INDEX Names of authors are printed in SMALLCAPITALS, subjects in lower-case roman, and localities in italics; book reviews are placed at the end. ABDUL-SAMAD, F. A., THOMAS, J. H., WILLIAMS, P. A., BLASI, A., tetrahedral A1 in alkali feldspar, 465 and SYMES, R. F., lanarkite, 499 BORTNIKOV, N. S., see BRESKOVSKA, V. V., 357 AEGEAN SEA, Santorini I., iron oxide mineralogy, 89 Boulangerite, 360 Aegirine, Scotland, in trachyte, 399 BRAITHWAITE, R. S. W., and COOPER, B. V., childrenite, /~kKERBLOM, G. V., see WILSON, M. R., 233 119 ALDERTON, D. H. M., see RANKIN, A. H., 179 Braunite, mineralogy and genesis, 506 Allanite, Scotland, 445 BRESKOVSKA, V. V., MOZGOVA, N. N., BORTNIKOV, N. S., Aluminosilicate-sodalites, X-ray study, 459 GORSHKOV, A. I., and TSEPIN, A. I., ardaite, 357 Amphibole, microstructures and phase transformations, BROOKS, R. R., see WATTERS, W. A., 510 395; Greenland, 283 BULGARIA, Madjarovo deposit, ardaite, 357 Andradite, in banded iron-formation assemblage, 127 ANGUS, N. S., AND KANARIS-SOTIRIOU, R., autometa- Calcite, atomic arrangement on twin boundaries, 265 somatic gneisses, 411 CANADA, SASKATCHEWAN, uranium occurrences in Cree Anthophyllite, asbestiform, morphology and alteration, Lake Zone, 163 77 CANTERFORD, J. H., see HILL, R. J., 453 Aragonite, atomic arrangements on twin boundaries, Carbonatite, evolution and nomenclature, 13 265 CARPENTER, M. A., amphibole microstructures, 395 Ardaite, Bulgaria, new mineral, 357 Cassiterite, SW England, U content, 211 Arfvedsonite, Scotland, in trachyte, 399 Cebollite, in kimberlite, correction, 274 ARVlN, M., pumpellyite in basic igneous rocks, 427 CHANNEL ISLANDS, Guernsey, meladiorite layers, 301; ASCENSION ISLAND, RE-rich eudialyte, 421 Jersey, wollastonite and epistilbite, 504; mineralization A TKINS, F. -
Scandiobabingtonite, a New Mineral from the Baveno Pegmatite
American Mineralogist, Volume 83, pages 1330-1334, 1998 Scandiobabingtonite,a new mineral from the Bavenopegmatite, Piedmont, Italy Ploro ORl.tNnIrr'* Ma,nco PasERorr and GrovlNNa Vn,zzllrNr2 rDipartimento di Scienzedella Terra, Universitd di Pisa, Via S. Maria 53,1-56126 Pisa, Italy '?Dipartimento di Scienzedella Terra, Universitd di Modena, Via S Eufemia 19, I-41 100 Modena, Italy Ansrntcr Scandiobabingtonite,ideally Ca,(Fe,*,Mn)ScSi,O,o(OH) is the scandium analogue of babingtonite; it was found in a pegmatitic cavity of the Baveno granite associatedwith orthoclase, albite, muscovite, stilbite, and fluorite. Its optics are biaxial (+) with 2V : : ^v: 64(2)",ct 1.686(2),P: 1.694(3), 1.709(2).D-"." : 3.24(5)slcm3, D.",.:3.24 sl cm3, and Z : 2. Scandiobabingtoniteis colorless or pale gray-green, transparent,with vitreous luster. It occurs as submillimeter sized, short, tabular crystals, slightly elongated on [001],and characterizedby the associationof forms {010}, {001}, {110}, {110}, and {101}. It occurs also as a thin rim encrustingsmall crystals of babingtonite.The strongest lines in the X-ray powder pauern are at2.969 (S), 2.895 (S), 3.14 (mS), and 2.755 (mS) 4. fn" mineralis triclinic, ipu.. g.oup PT, with a : 7.536(2),b : 1L734(2),c : 6.t48(Z) A, : 91.10(2), : 93.86(2), : lO+.S:(2)'. Scandiobabingtoniteis isostructural " B r with babingtonite, with Sc replacing Fe3* in sixfold coordination, but no substitution of Fer* by Sc takes place. Due to the lack of a suitably large crystal of the new species, such a replacementhas been confirmed by refining the crystal structure of a Sc-rich babingtonite (final R : O.O47)using single-crystal X-ray diffraction (XRD) data. -
Examples from NYF Pegmatites of the Třebíč Pluton, Czech Republic
Journal of Geosciences, 65 (2020), 153–172 DOI: 10.3190/jgeosci.307 Original paper Beryllium minerals as monitors of geochemical evolution from magmatic to hydrothermal stage; examples from NYF pegmatites of the Třebíč Pluton, Czech Republic Adam ZACHAŘ*, Milan NOVÁK, Radek ŠKODA Department of Geological Sciences, Faculty of Sciences, Masaryk University, Kotlářská 2, Brno 611 37, Czech Republic; [email protected] * Corresponding author Mineral assemblages of primary and secondary Be-minerals were examined in intraplutonic euxenite-type NYF peg- matites of the Třebíč Pluton, Moldanubian Zone occurring between Třebíč and Vladislav south of the Třebíč fault. Primary magmatic Be-minerals crystallized mainly in massive pegmatite (paragenetic type I) including common beryl I, helvite-danalite I, and a rare phenakite I. Rare primary hydrothermal beryl II and phenakite II occur in miarolitic pockets (paragenetic type II). Secondary hydrothermal Be-minerals replaced primary precursors or filled fractures and secondary cavities, or they are associated with ,,adularia” and quartz (paragenetic type III). They include minerals of bohseite-ba- venite series, less abundant beryl III, bazzite III, helvite-danalite III, milarite-agakhanovite-(Y) III, phenakite III, and datolite-hingganite-(Y) III. Chemical composition of the individual minerals is characterized by elevated contents of Na, Cs, Mg, Fe, Sc in beryl I and II; Na, Ca, Mg, Fe, Al in bazzite III; REE in milarite-agakhanovite-(Y) III; variations in Fe/Mn in helvite-danalite and high variation of Al in bohseite-bavenite series. Replacement reactions of primary Be- -minerals are commonly complex and the sequence of crystallization of secondary Be-minerals is not defined; minerals of bohseite-bavenite series are mostly the latest. -
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T Hn AMERICax M INERALoGIST JOURNAL OF THE MINERALOGICAL SOCIETY OF AMERICA Vol. 25 JUNE, 1940 No.6 DEPOSITS OF RADIOACTIVE CERITE NEAR JAMESTOWN, COLORADO* Elwnr N. Gonoann aNn Jnwnu J. Gr-ass, IL S. GeologicalSuraey, Washington, D.C. CONTENTS Abstract 381 Introduction 382 Geological occurrence 383 Mineralogy 385 Occurrence.. 385 Northern group 386 Southern group, 391 List of minerals. 393 Cerite... 393 Allanite. 397 Brown epidote 399 Tijrnebohmite 400 Fluorite 4.00 Bastniisite 401 Monazite 401 Uraninite 4Ol Sulphides 402 Comparisons with other deposits of cerite 402 Radioactivity 403 Age determination 404 Assrnecr Cerite, a rare silicate of the cerium metals, occurs in small deposits in the pre-Cambrian rocks of the Front Range near Jamestolvn, colorado. They are near the north border of a stock of Silver Plume granite, to which they are genetically related. Numerous lenticular schist masses in the granite suggest proximity to the roof. The cerite rock containing about 75 per cent of cerite occurs as irregular lenses,one- fourth of an inch to 15 inches wide, in narrow aplite-pegmatite zones along the borders of small schist areas. Narrow veinlets of black allanite border the cerite rock and minute grains of uraninite (pitchblende) and pyrite are localiy present. Microscopic examination of the cerite rock shows it to be finely intergrown with * Published by permission of the Director, Geological Survey, United States Depart- ment of the Interior, the Colorado Geological Survey Board, and the Colorado Metal Mining Fund. 381 E. N, GODDARD AND T. I. GLASS varying amounts of allanite, brown epidote, tdrnebohmite, fluorite, bastniisite, monazite, uraninite, and quartz.