Rule 1418. Halon Emissions from Fire Extinguishing Equipment
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Cylinder Valve Selection Quick Reference for Valve Abbreviations
SHERWOOD VALVE COMPRESSED GAS PRODUCTS Appendix Cylinder Valve Selection Quick Reference for Valve Abbreviations Use the Sherwood Cylinder Valve Series Abbreviation Chart on this page with the Sherwood Cylinder Valve Selection Charts found on pages 73–80. The Sherwood Cylinder Valve Selection Chart are for reference only and list: • The most commonly used gases • The Compressed Gas Association primary outlet to be used with each gas • The Sherwood valves designated for use with this gas • The Pressure Relief Device styles that are authorized by the DOT for use with these gases PLEASE NOTE: The Sherwood Cylinder Valve Selection Charts are partial lists extracted from the CGA V-1 and S-1.1 pamphlets. They can change without notice as the CGA V-1 and S-1.1 pamphlets are amended. Sherwood will issue periodic changes to the catalog. If there is any discrepancy or question between these lists and the CGA V-1 and S-1.1 pamphlets, the CGA V-1 and S-1.1 pamphlets take precedence. Sherwood Cylinder Valve Series Abbreviation Chart Abbreviation Sherwood Valve Series AVB Small Cylinder Acetylene Wrench-Operated Valves AVBHW Small Cylinder Acetylene Handwheel-Operated Valves AVMC Small Cylinder Acetylene Wrench-Operated Valves AVMCHW Small Cylinder Acetylene Handwheel-Operated Valves AVWB Small Cylinder Acetylene Wrench-Operated Valves — WB Style BV Hi/Lo Valves with Built-in Regulator DF* Alternative Energy Valves GRPV Residual Pressure Valves GV Large Cylinder Acetylene Valves GVT** Vertical Outlet Acetylene Valves KVAB Post Medical Valves KVMB Post Medical Valves NGV Industrial and Chrome-Plated Valves YVB† Vertical Outlet Oxygen Valves 1 * DF Valves can be used with all gases; however, the outlet will always be ⁄4"–18 NPT female. -
Status of Industry Efforts to Replace Halon Fire Extinguishing Agents
STATUS OF INDUSTRY EFFORTS TO REPLACE HALON FIRE EXTINGUISHING AGENTS Robert T. Wickham, P.E. March 16, 2002 WICKHAM ASSOCIATES NOTICE This document is disseminated under the sponsorship of the U.S. Environmental Protection Agency in the interest of information exchange. The views expressed in this report are those of the author and do not necessarily reflect those of the US Environmental Protection Agency. The US Environmental Protection Agency does not assume liability for the contents or use thereof and further the Agency does not endorse products or manufacturers. Trade or manufacturer's names appear herein solely because they are considered essential to the objective of this report. The following commercial products (requiring a trademark designation ® or ™) are mentioned in this report. Due to the frequency of usage, trademarks are not indicated. Mention of a product does not constitute endorsement or rejection of the product. Ansul FE-25 Argonite FE-36 Argotec FM-200 CEA-410 Halotron I CEA-614 Inergen CEA-308 NAF P-IV Envirogel NAF S-III FE-13 NN100 FE-227 Triodide FE-241 There are no restrictions on copying or distribution of this document. Additional copies of this report are available from ….. Wickham Associates 9 Winding Brook Drive Stratham, New Hampshire 03885 USA Tel: +603-772-3229 Fax: +603-772-7305 email: [email protected] The report is available at http://home.attbi.com/~wickham/downloads.htm for downloading in Adobe Acrobat portable document format (pdf). Preface This report is not intended to be a market study, but instead a snapshot of the progress industry and the government are making in employing non ozone depleting alternatives to halons in the fire protection sector. -
Liquefied Gas Conversion Chart
LIQUEFIED GAS CONVERSION CHART Cubic Feet / Pound Pounds / Gallon Product Name Column A Column B Acetylene UN/NA: 1001 14.70 4.90 CAS: 514-86-2 Air UN/NA: 1002 13.30 7.29 CAS: N/A Ammonia Anhydrous UN/NA: 1005 20.78 5.147 CAS: 7664-41-7 Argon UN/NA: 1006 9.71 11.63 CAS: 7440-37-1 Butane UN/NA: 1075 6.34 4.86 CAS: 106-97-8 Carbon Dioxide UN/NA: 2187 8.74 8.46 CAS: 124-38-9 Chlorine UN/NA: 1017 5.38 11.73 CAS: 7782-50-5 Ethane UN/NA: 1045 12.51 2.74 CAS: 74-84-0 Ethylene Oxide UN/NA: 1040 8.78 7.25 CAS: 75-21-8 Fluorine UN/NA: 1045 10.17 12.60 CAS: 7782-41-4 Helium UN/NA: 1046 97.09 1.043 CAS: 7440-59-7 Hydrogen UN/NA: 1049 192.00 0.592 CAS: 1333-74-0 1. Find the gas you want to convert. 2. If you know your quantity in cubic feet and want to convert to pounds, divide your amount by column A 3. If you know your quantity in gallons and want to convert to pounds, multiply your amount by column B 4. If you know your quantity in pounds and want to convert to gallons, divide your amount by column B If you have any questions, please call 1-800-433-2288 LIQUEFIED GAS CONVERSION CHART Cubic Feet / Pound Pounds / Gallon Product Name Column A Column B Hydrogen Chloride UN/NA: 1050 10.60 8.35 CAS: 7647-01-0 Krypton UN/NA: 1056 4.60 20.15 CAS: 7439-90-9 Methane UN/NA: 1971 23.61 3.55 CAS: 74-82-8 Methyl Bromide UN/NA: 1062 4.03 5.37 CAS: 74-83-9 Neon UN/NA: 1065 19.18 10.07 CAS: 7440-01-9 Mapp Gas UN/NA: 1060 9.20 4.80 CAS: N/A Nitrogen UN/NA: 1066 13.89 6.75 CAS: 7727-37-9 Nitrous Oxide UN/NA: 1070 8.73 6.45 CAS: 10024-97-2 Oxygen UN/NA: 1072 12.05 9.52 CAS: 7782-44-7 Propane UN/NA: 1075 8.45 4.22 CAS: 74-98-6 Sulfur Dioxide UN/NA: 1079 5.94 12.0 CAS: 7446-09-5 Xenon UN/NA: 2036 2.93 25.51 CAS: 7440-63-3 1. -
Ozone Depleting Substances
Ozone Depleting Substances What are they? Ozone depleting substances are chemicals that destroy the earth’s protective ozone layer. They include: • chlorofluorocarbons (CFCs) • halons • carbon tetrachloride (CCl4) • methyl chloroform (CH3CCl3) • hydrobromofluorocarbons (HBFCs) • hydrochlorofluorocarbons (HCFCs) • methyl bromide (CH3Br) • bromochloromethane (CH2BrCl) The use of these chemicals is controlled by the Montreal Protocol on Substances that Deplete the Ozone Layer (the Montreal Protocol). There are other ozone depleting substances, but their ozone depleting effects are very small, so they are not controlled by the Montreal Protocol. One kilogram of halon 1211 can destroy 50 tonnes of ozone What is ozone depleting potential? Ozone depleting potential is a measure of how much damage a chemical can cause to the ozone layer compared with a similar mass What did we use ozone depleting of trichlorofluoromethane (CFC-11). CFC-11, with an ozone depleting potential of 1.0, is substances for? used as the base figure for measuring ozone depletion potential. The higher the number, The main uses of ozone depleting substances the more damage a chemical can cause to include; CFCs and HCFCs in refrigerators and the ozone layer. Bromotrifluoromethane air conditioners, HCFCs and halons in fire (halon -1301) has an ozone depleting potential extinguishers, CFCs and HCFCs in foam, CFCs of 10.0. Carbon dioxide (CO2) is a naturally and HCFCs as aerosol propellants and methyl occurring greenhouse gas, but has an ozone bromide for fumigation of soil, structures and depleting potential of 0. goods to be imported or exported. Have we stopped using ozone Why do we still use some ozone depleting substances? depleting substances? Production of most ozone depleting Some substances with a high ozone depleting substances has been phased out under the potential are still used in quarantine and Montreal Protocol. -
Gas Conversion Factor for 300 Series
300GasTable Rec # Gas Symbol GCF Density (g/L) Density (g/L) 25° C / 1 atm 0° C / 1 atm 1 Acetic Acid C2H4F2 0.4155 2.7 2.947 2 Acetic Anhydride C4H6O3 0.258 4.173 4.555 3 Acetone C3H6O 0.3556 2.374 2.591 4 Acetonitryl C2H3N 0.5178 1.678 1.832 5 Acetylene C2H2 0.6255 1.064 1.162 6 Air Air 1.0015 1.185 1.293 7 Allene C3H4 0.4514 1.638 1.787 8 Ammonia NH3 0.7807 0.696 0.76 9 Argon Ar 1.4047 1.633 1.782 10 Arsine AsH3 0.7592 3.186 3.478 11 Benzene C6H6 0.3057 3.193 3.485 12 Boron Trichloride BCl3 0.4421 4.789 5.228 13 Boron Triflouride BF3 0.5431 2.772 3.025 14 Bromine Br2 0.8007 6.532 7.13 15 Bromochlorodifluoromethane CBrClF2 0.3684 6.759 7.378 16 Bromodifluoromethane CHBrF2 0.4644 5.351 5.841 17 Bromotrifluormethane CBrF3 0.3943 6.087 6.644 18 Butane C4H10 0.2622 2.376 2.593 19 Butanol C4H10O 0.2406 3.03 3.307 20 Butene C4H8 0.3056 2.293 2.503 21 Carbon Dioxide CO2 0.7526 1.799 1.964 22 Carbon Disulfide CS2 0.616 3.112 3.397 23 Carbon Monoxide CO 1.0012 1.145 1.25 24 Carbon Tetrachloride CCl4 0.3333 6.287 6.863 25 Carbonyl Sulfide COS 0.668 2.456 2.68 26 Chlorine Cl2 0.8451 2.898 3.163 27 Chlorine Trifluoride ClF3 0.4496 3.779 4.125 28 Chlorobenzene C6H5Cl 0.2614 4.601 5.022 29 Chlorodifluoroethane C2H3ClF2 0.3216 4.108 4.484 30 Chloroform CHCl3 0.4192 4.879 5.326 31 Chloropentafluoroethane C2ClF5 0.2437 6.314 6.892 32 Chloropropane C3H7Cl 0.308 3.21 3.504 33 Cisbutene C4H8 0.3004 2.293 2.503 34 Cyanogen C2N2 0.4924 2.127 2.322 35 Cyanogen Chloride ClCN 0.6486 2.513 2.743 36 Cyclobutane C4H8 0.3562 2.293 2.503 37 Cyclopropane C3H6 0.4562 -
Halons Technical Options Committee 2018 AssessMent Report
Halons Technical Options Committee 2018 Assess ment Report Volume 1 Montreal Protocol on Substances that Deplete the Ozone Layer Ozone Secretariat MONTREAL PROTOCOL ON SUBSTANCES THAT DEPLETE THE OZONE LAYER REPORT OF THE HALONS TECHNICAL OPTIONS COMMITTEE DECEMBER 2018 VOLUME 1 2018 ASSESSMENT REPORT i Montreal Protocol on Substances that Deplete the Ozone Layer Report of the Halons Technical Options Committee December 2018 Volume 1 2018 ASSESSMENT REPORT The text of this report is composed in Times New Roman Co-ordination: Halons Technical Options Committee Composition of the report: Halons Technical Options Committee Reproduction: Ozone Secretariat Date: December 2018 Under certain conditions, printed copies of this report are available from: UNITED NATIONS ENVIRONMENT PROGRAMME Ozone Secretariat, P.O. Box 30552, Nairobi, Kenya This document is also available in portable document format from the Ozone Secretariat's website: https://ozone.unep.org/sites/default/files/Assessment_Panel/Assessment_Panels/TEAP/R eports/HTOC/HTOC_assessment_2018.pdf No copyright involved. This publication may be freely copied, abstracted and cited, with acknowledgement of the source of the material. ISBN: 978-9966-076-48-9 iii Disclaimer The United Nations Environment Programme (UNEP), the Technology and Economic Assessment Panel (TEAP) Co-chairs and members, the Technical Options Committees Co-chairs and members, the TEAP Task Forces Co-chairs and members, and the companies and organisations that employ them do not endorse the performance, worker safety, or environmental acceptability of any of the technical options discussed. Every industrial operation requires consideration of worker safety and proper disposal of contaminants and waste products. Moreover, as work continues - including additional toxicity evaluation - more information on health, environmental and safety effects of alternatives and replacements will become available for use in selecting among the options discussed in this document. -
ACE Tips for Filing EPA ODS
Automated Commercial Environment ACE Tips for Filing EPA ODS June, 2018 Ozone-depleting substances (ODS) deplete the stratospheric ozone layer when the chlorine and bromine atoms that they contain come into contact with ozone molecules. One chlorine atom can destroy over 100,000 ozone molecules before it is removed from the stratosphere. ODS that release chlorine include chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), carbon tetrachloride, and methyl chloroform. ODS that release bromine include halons and methyl bromide. HTS code Ozone-Depleting Substance 2903.14.0000 Carbon tetrachloride What commodities 2903.19.6010 Methylchloroform (1,1,1-Trichloroethane) are ODS used in? 2903.39.1520 Methyl bromide 2903.71.0000 Chlorodifluoromethane (HCFC-22) ODS have been used 2903.72.0020 Dichlorotrifluoroethane (HCFC-123) for refrigeration, air 2903.73.0000 Dichlorofluoroethanes (HCFC-141, 141b) conditioning, insulation, 2903.74.0000 Chlorodifluoroethanes (HCFC-142, 142b) solvents, aerosol 2903.75.0000 Dichloropentafluoropropanes propellants, and in other (HCFC-225, 225ca, 225cb) sectors. Currently, the United 2903.76.0010 Bromotrifluoromethane (Halon 1301) States is in the 2903.76.0050 Bromochlorodifluoromethane (Halon 1211), process of phasing bromotrifluoromethane (Halon 1301), and out HCFCs, but in the dibromotetrafluoroethanes (Halon 2402), Other interim limited imports are 2903.77.0010 Trichlorofluoromethane (CFC-11) allowed. CFCs, 2903.77.0020 Trichlorotrifluoroethanes (CFC-113, CFC-113a) methyl bromide, halon, 2903.77.0030 -
Fluorinated Butatrienes
Fluorinated Butatrienes Dissertation zur Erlangung des akademischen Grades des Doktors der Naturwissenschaften (Dr. rer. nat.) eingereicht im Fachbereich Biologie, Chemie, Pharmazie der Freien Universität Berlin vorgelegt von Dipl.-Chem. Christian Ehm aus Berlin Berlin, April 2010 1. Gutachter: Prof. Dr. Dieter Lentz 2. Gutachter: Prof. Dr. Beate Paulus Disputation am 28.6.2010 I Acknowledgements It would not have been possible to write this doctoral thesis without the help and support of the kind people around me, to only some of whom it is possible to give particular mention here. First and foremost I would like to thank my principal supervisor, Professor Dieter Lentz, for the opportunity of doing research in his group. Without his continuous support and encouragement this thesis would not be in the present state. I highly appreciate that Professor Beate Paulus has agreed to be co-referee of my thesis. I would like to cordially thank Lada for her love and patience as well as her interest in my research. Special thanks to my family for their continuous support and love. I would like to thank Mike Roland, Sten Dathe and Sven Wünsche for their friendship and the fun we have had every Sunday evening. Special thanks to Sebastian Freitag, Boris Bolsinger and Frederic Heinrich for their friendship. They deserve much gratefulness for keeping me on the right way. I would like to thank all my colleagues at the Institut für Chemie und Biochemie, Abteilung Anorganische Chemie. In particular I want to thank all members of the Lentz group, Thomas Hügle, Moritz Kühnel, Dr. Floris Akkerman, Dr. -
List of Lists
United States Office of Solid Waste EPA 550-B-10-001 Environmental Protection and Emergency Response May 2010 Agency www.epa.gov/emergencies LIST OF LISTS Consolidated List of Chemicals Subject to the Emergency Planning and Community Right- To-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act • EPCRA Section 302 Extremely Hazardous Substances • CERCLA Hazardous Substances • EPCRA Section 313 Toxic Chemicals • CAA 112(r) Regulated Chemicals For Accidental Release Prevention Office of Emergency Management This page intentionally left blank. TABLE OF CONTENTS Page Introduction................................................................................................................................................ i List of Lists – Conslidated List of Chemicals (by CAS #) Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA), Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and Section 112(r) of the Clean Air Act ................................................. 1 Appendix A: Alphabetical Listing of Consolidated List ..................................................................... A-1 Appendix B: Radionuclides Listed Under CERCLA .......................................................................... B-1 Appendix C: RCRA Waste Streams and Unlisted Hazardous Wastes................................................ C-1 This page intentionally left blank. LIST OF LISTS Consolidated List of Chemicals -
1 HUMAN HEALTH SAFETY EVALUATION of HALON REPLACEMENT CANDIDATES Darol E. Dodd1, Gary W. Jepson1, and Joseph A. Macko, Jr.2 1Air
HUMAN HEALTH SAFETY EVALUATION OF HALON REPLACEMENT CANDIDATES Darol E. Dodd1, Gary W. Jepson1, and Joseph A. Macko, Jr.2 1Air Force Research Laboratory/Operational Toxicology Branch (AFRL/HEST) – ManTech Environmental Technology, Inc. Wright-Patterson Air Force Base, Ohio 2Toxicology Directorate (MCHB-TS-T)/U.S. Army Center for Health Promotion & Preventive Medicine Aberdeen Proving Ground, Maryland Next-Generation Fire Suppression Technology Program (NGP) Project 3B/1/89 Final Report – Section II of II This research is part of the Department of Defense’s Next-Generation Fire Suppression Technology Program, funded by the DoD Strategic Environmental Research and Development Program (SERDP) 1 TABLE OF CONTENTS Page INTRODUCTION……………………………...………………………………………………….4 PHASE 1 – TOXICITY SCREENING METHODS……………………...……………………….5 Chemical/physical properties……………………………………………….…………….6 Existing toxicity literature…………………………………………………..…………….6 Preliminary “specific use” scenarios………………………………………..…………….7 Qualitative/quantitative structure activity relationships……………………..……………7 In vitro screens……………………………………………………………...…………….8 Acute irritation tests………………………………………………………………………9 Acute toxicity tests…………………………………………………………..…………..10 The “limit test”…………………………………………………………………..11 The “specific use” scenario test……………………………………..…………..12 Genotoxicity tests (Phase 1)………………………………………………..……………13 DECISION POINT 1……………………………………………………………………14 Concentration x time (C x T) relationships……………………….……………18 Stop or continue testing…………………………………………..…………….18 PHASE 2 – TOXICITY -
Federal Register/Vol. 84, No. 230/Friday, November 29, 2019
Federal Register / Vol. 84, No. 230 / Friday, November 29, 2019 / Proposed Rules 65739 are operated by a government LIBRARY OF CONGRESS 49966 (Sept. 24, 2019). The Office overseeing a population below 50,000. solicited public comments on a broad Of the impacts we estimate accruing U.S. Copyright Office range of subjects concerning the to grantees or eligible entities, all are administration of the new blanket voluntary and related mostly to an 37 CFR Part 210 compulsory license for digital uses of increase in the number of applications [Docket No. 2019–5] musical works that was created by the prepared and submitted annually for MMA, including regulations regarding competitive grant competitions. Music Modernization Act Implementing notices of license, notices of nonblanket Therefore, we do not believe that the Regulations for the Blanket License for activity, usage reports and adjustments, proposed priorities would significantly Digital Uses and Mechanical Licensing information to be included in the impact small entities beyond the Collective: Extension of Comment mechanical licensing collective’s potential for increasing the likelihood of Period database, database usability, their applying for, and receiving, interoperability, and usage restrictions, competitive grants from the Department. AGENCY: U.S. Copyright Office, Library and the handling of confidential of Congress. information. Paperwork Reduction Act ACTION: Notification of inquiry; To ensure that members of the public The proposed priorities do not extension of comment period. have sufficient time to respond, and to contain any information collection ensure that the Office has the benefit of SUMMARY: The U.S. Copyright Office is requirements. a complete record, the Office is extending the deadline for the extending the deadline for the Intergovernmental Review: This submission of written reply comments program is subject to Executive Order submission of written reply comments in response to its September 24, 2019 to no later than 5:00 p.m.