Kit Components 07.07.2014 Product Code Description 102034 Kit
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07.07.2014 Kit Components Product code Description 102034 Kit COLORTEC E-6 3-Bath Kit for 5L for rotary development Components: 102034 COLORTEC E-6 3-Bad 102034 Part 1 COLORTEC E-6 Dreibad Farbentwickler CD Part 1 102034 Part 2 COLORTEC E-6 3-Bad Colour Developer CD- Part 2 102034 BX-P1 COLORTEC C-41/ E-6 Negativ Kit Rapid BX-Part 1 102034 BX-P2 COLORTEC C-41/E-6 Negativ Kit Bleichfixierbad BX Part 2 102034 Stab COLORTEC E-6 3-BAD KIT STAB Stabilizer; Stabi + Netzmittelbad Page 1/7 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 07.07.2014 version no: 1 Revision: 07.07.2014 * SECTION 1: Identification of the substance/mixture and of the company/undertaking . 1.1 Product identifier . Trade name: COLORTEC E-6 3-Bath Firstdeveloper . Article number: 102034, Erstentwickler, 102031 . 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Developer for photographic use . 1.3 Details of the supplier of the safety data sheet . Manufacturer/Supplier: TETENAL Europe GmbH Schützenwall 31-35 D-22844 Norderstedt / Germany Phone: ++49 (0) 40 521 45-0; Fax: +49 (0) 40-52145-296 www.tetenal.com; E-Mail: [email protected] TETENAL Ltd., 2 Meridian West, Meridian Business Park, Leicester LE19 1WX Phone: 0116 - 289 3644; E-Mail: [email protected]; www.tetenaluk.com . Further information obtainable from: Department environment and safety. E-Mail: [email protected] . 1.4 Emergency telephone number: Poison Information Centre Berlin (Germany): +49 (0) 30 - 30686 790 * SECTION 2: Hazards identification . 2.1 Classification of the substance or mixture . Classification according to Regulation (EC) No 1272/2008 ~ GHS07 Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1B H317 May cause an allergic skin reaction. Classification according to Directive 67/548/EEC or Directive 1999/45/EC ?@G Xi; Sensitising R43: May cause sensitisation by skin contact. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 2.2 Label elements . Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: ?@G Xi Irritant (Contd. on page 2) EN 38.0.12 Page 2/7 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 07.07.2014 version no: 1 Revision: 07.07.2014 Trade name: COLORTEC E-6 3-Bath Firstdeveloper (Contd. of page 1) . Hazard-determining components of labelling: potassium 2,5-dihydroxybenzenesulphonate . Risk phrases: 43 May cause sensitisation by skin contact. Safety phrases: 2 Keep out of the reach of children. 24 Avoid contact with skin. 37 Wear suitable gloves. 46 If swallowed, seek medical advice immediately and show this container or label. 56 Dispose of this material and its container to hazardous or special waste collection point. 2.3 Other hazards . Results of PBT and vPvB assessment . PBT: Not applicable. vPvB: Not applicable. SECTION 3: Composition/information on ingredients . 3.2 Chemical characterization: Mixtures . Description: Mixture of substances listed below and with nonhazardous additions. Dangerous components: CAS: 21799-87-1 potassium 2,5-dihydroxybenzenesulphonate 5-10% EINECS: 244-584-7 ?@G Xi R36/37/38 ~ Eye Irrit. 2, H319; Skin Sens. 1B, H317 CAS: 584-08-7 potassium carbonate 5-10% EINECS: 209-529-3 ?@G Xi R36/38 Reg.nr.: 01-2119532646-36 ~ Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335 CAS: 111-46-6 diethylene glycol 5-10% EINECS: 203-872-2 ?@G Xn R22 Index number: 603-140-00-6 ~ Acute Tox. 4, H302 CAS: 13047-13-7 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one (HMP) <1% EINECS: 235-920-3 ?@G Xn R22; ?@G Xi R43; ?@D N R51/53 ~ Aquatic Chronic 2, H411; ~ Acute Tox. 4, H302; Skin Sens. 1, H317 . Additional information: For the wording of the listed risk phrases refer to section 16. * SECTION 4: First aid measures . 4.1 Description of first aid measures . After inhalation: Supply fresh air and to be sure call for a doctor. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: If symptoms persist consult doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. EN (Contd. on page 3) 38.0.12 Page 3/7 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 07.07.2014 version no: 1 Revision: 07.07.2014 Trade name: COLORTEC E-6 3-Bath Firstdeveloper (Contd. of page 2) SECTION 5: Firefighting measures . 5.1 Extinguishing media . Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 5.2 Special hazards arising from the substance or mixture No further relevant information available. 5.3 Advice for firefighters . Protective equipment: No special measures required. SECTION 6: Accidental release measures . 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation . 6.2 Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * SECTION 7: Handling and storage . 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities . Storage: . Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Store away from foodstuffs. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Store under lock and key and out of the reach of children. Recommended storage temperature: 5-25 °C Protect from exposure to the light. 7.3 Specific end use(s) No further relevant information available. * SECTION 8: Exposure controls/personal protection . Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters . Ingredients with limit values that require monitoring at the workplace: 111-46-6 diethylene glycol (5-10%) WEL Long-term value: 101 mg/m³, 23 ppm . Additional information: The lists valid during the making were used as basis. (Contd. on page 4) EN 38.0.12 Page 4/7 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 07.07.2014 version no: 1 Revision: 07.07.2014 Trade name: COLORTEC E-6 3-Bath Firstdeveloper (Contd. of page 3) . 8.2 Exposure controls . Personal protective equipment: . General protective and hygienic measures: Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Respiratory protection: Not required. Protection of hands: `S Protective gloves Impervious gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation . Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Butyl rubber, BR Nitrile rubber, NBR Neoprene gloves . Penetration time of glove material Gove material breakthroug-time layer thickness Butyl rubber: >480 min ≥0,4mm Nitrile rubber: >480 min ≥0,38mm Neoprene: >240 min ≥0,65mm The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses . Body protection: Protective work clothing * SECTION 9: Physical and chemical properties . 9.1 Information on basic physical and chemical properties . General Information . Appearance: Form: Fluid Colour: Light yellow . Odour: Recognizable . pH-value at 20 °C: 9.9 . Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: > 100 °C . Flash point: Not applicable. Ignition temperature: 230 °C . Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. (Contd. on page 5) EN 38.0.12 Page 5/7 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 07.07.2014 version no: 1 Revision: 07.07.2014 Trade name: COLORTEC E-6 3-Bath Firstdeveloper (Contd. of page 4) . Vapour pressure at 20 °C: 23 hPa . Density at 20 °C: 1.278 g/cm³ . Solubility in / Miscibility with water: Fully miscible. Solvent content: Organic solvents: 5.2 % Water: >61 % . 9.2 Other information No further relevant information available. SECTION 10: Stability and reactivity . 10.1 Reactivity . 10.2 Chemical stability . Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.