DOCSLIB.ORG

Chemical Name

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Chemical Name List of substances banned for use in cosmetic products as from 1 December 2010 (updated July 2015) The following substances are classified as CMR substances of category 1A, 1B or 2 under Commission Regulation (EC) No 790/2009 and successive amendments of the Regulation 1272/2008.1 Therefore, these substances are banned for use in cosmetic products as from 1 December 2010 (which is the starting date of application of their classification), in accordance with Article 15 of the Cosmetics Regulation (EC) 1223/2009. Please note that some of the substances classified as CMR substances under Commission Regulation (EC) No 790/2009 and the successive amending regulations had already been regulated in Annex II to the Cosmetics Regulation through previous adaptations to technical progress of the Annexes to the Cosmetics Directive (which had been taken over by the Cosmetics Regulation at the time of its adoption in November 2009). They continue therefore to be listed in this Annex and to be banned for use in cosmetics, and are thus not included in the list below. In addition, some substances classified as CMR substances under Commission Regulation (EC) No 790/2009 and the successive amending regulations are considered to be covered by existing entries in Annex II to the Cosmetics Regulation and are not included in the list below. Chemical name EC No CAS No O-isobutyl-N-ethoxy carbonylthiocarbamate 434-350-4 103122-66-3 chlorpropham (ISO); 202-925-7 101-21-3 isopropyl 3-chlorocarbanilate hydroxylammonium nitrate 236-691-2 13465-08-2 reaction mass of: 4,7-bis(mercaptomethyl)-3,6,9-trithia- 427-050-1 - 1,11-undecanedithiol-; 4,8-bis(mercaptomethyl)-3,6,9-trithia-1,11- undecanedithiol; 5,7-bis(mercaptomethyl)-3,6,9-trithia-1,11- undecanedithiol cobalt acetate 200-755-8 71-48-7 1 This list does not contain the substance Musk Ketone (CAS 81-14-1), even though it has been classified as a CMR 2 substance by Commission Regulation 790/2009. Indeed, Musk Ketone is already listed under Annex III, entry 97 of the Cosmetics Regulation and the data as published in the RAR on Musk Ketone, which was the basis for the official CMR2 classification of the material, was also taken into consideration in the second review of the material by the SCCNFP in 2004, which led to the transfer of the material from a preliminary regulation (Annex III, part 2 of the Cosmetics Directive) to a permanent regulation (Annex III, part 1 of the Cosmetics Directive) in the same year. Therefore, it can be considered that this substance has been subject to "evaluation and approval" of the SCCS and that it remains regulated in Annex III to the Cosmetics Regulation, entry 97. 1 Chemical name EC No CAS No cobalt nitrate 233-402-1 10141-05-6 cobalt carbonate 208-169-4 513-79-1 nickel dichloride 231-743-0 7718-54-9 nickel dinitrate; [1] 236-068-5 [1] 13138-45-9 [1] nitric acid, nickel salt [2] 238-076-4 [2] 14216-75-2 [2] dibutyltin dichloride; 211-670-0 683-18-1 (DBTC) 4,4'-bis(N-carbamoyl-4- 418-770-5 151882-81-4 methylbenzenesulfonamide)diphenylmethane 6-glycidyloxynapht-1-yl oxymethyloxirane 429-960-2 27610-48-6 2-(2-aminoethylamino)ethanol 203-867-5 111-41-1 (AEEA) 1,2-diethoxyethane 211-076-1 629-14-1 (E)-3-[1-[4-[2-(dimethylamino)ethoxy]phenyl]-2- 428-010-4 82413-20-5 phenylbut-1-enyl]phenol 2-butyryl-3-hydroxy-5-thiocyclohexan-3-yl-cyclohex-2- 425-150-8 94723-86-1 en-1-one profoxydim (ISO); - 139001-49-3 2-{(EZ)-1-[(2RS)-2-(4- chlorophenoxy)propoxyimino]butyl}-3-hydroxy-5- (thian-3-yl)cyclohex-2-en-1-one tepraloxydim (ISO); - 149979-41-9 (RS)-(EZ)-2-{1-[(2E)-3-chloroallyloxyimino]propyl}-3- hydroxy-5-perhydropyran-4-ylcyclohex-2-en-1-one 1,2-benzenedicarboxylic acid; 276-158-1 71888-89-6 di-C6-8-branched alkylesters, C7-rich reaction mass of: diester of 4,4'-methylenebis[2-(2- 427-140-9 - hydroxy-5-methylbenzyl)-3,6-dimethylphenol] and 6- diazo-5,6-dihydro-5-oxonaphthalene-1-sulfonic acid (1:2); triester of 4,4'-methylenebis[2-(2-hydroxy-5- methylbenzyl)-3,6-dimethylphenol] and 6-diazo-5,6- dihydro-5-oxonaphthalene-1-sulfonic acid (1:3) diammonium 1-hydroxy-2-(4-(4-carboxyphenylazo)- 422-670-7 - 2,5-dimethoxyphenylazo)-7-amino-3- naphthalenesulfonate 3-oxoandrost-4-ene-17-β-carboxylic acid 414-990-0 302-97-6 (Z)-2-methoxymino-2-[2-(tritylamino)thiazol-4-yl]acetic 431-520-1 64485-90-1 acid 2 Chemical name EC No CAS No reaction mass of: succinic acid; 432-790-1 - monopersuccinic acid; dipersuccinic acid; monomethyl ester of succinic acid; monomethyl ester of persuccinic acid; dimethyl succinate; glutaric acid; monoperglutaric acid; diperglutaric acid; monomethyl ester of glutaric acid; monomethyl ester of perglutaric acid; dimethyl glutarate; adipic acid; monoperadipic acid; diperadipic acid; monomethyl ester of adipic acid; monomethyl ester of peradipic acid; dimethyl adipate; hydrogen peroxide; methanol; water 4-mesyl-2-nitrotoluene 430-550-0 1671-49-4 *chrysoidine; 207-803-7 495-54-5 4-(phenylazo)benzene-1,3-diamine *chrysoidine monohydrochloride; 208-545-8 [1] 532-82-1 [1] 4-phenylazophenylene-1,3-diamine monohydrochloride; 278-290-5 [2] 75660-25-2 [2] [1] 279-116-0 [3] 79234-33-6 [3] chrysoidine monoacetate; 264-409-8 [4] 63681-54-9 [4] 4-(phenylazo)benzene-1,3-diamine monoacetate; [2] 281-549-5 [5] 83968-67-6 [5] chrysoidine acetate; 282-432-1 [6] 84196-22-5 [6] 4-(phenylazo)benzene-1,3-diamine acetate; [3] chrysoidine-p-dodecylbenzenesulfonate; dodecylbenzenesulfonic acid, compound with 4- (phenylazo)benzene-1,3-diamine (1:1); [4] chrysoidine dihydrochloride; 4-(phenylazo)benzene-1,3-diamine dihydrochloride; [5] chrysoidine sulfate; bis[4-(phenylazo)benzene-1,3-diamine] sulfate [6] * chrysoidine C10-14-alkyl derivatives and; 286-946-7 [1] 85407-90-5 [1] benzenesulfonic acid, mono-C10-14-alkyl derivatives, 304-236-8 [2] 94247-67-3 [2] compounds with 4-(phenylazo)-1,3-benzenediamine; [1] chrysoidine compound with dibutylnaphthalene sulfonic acid; dibutylnaphthalenesulfonic acid, compound with 4- (phenylazo)benzene-1,3-diamine (1:1) [2] piperazine; 203-808-3 110-85-0 [liquid] hydroxylamine ...% 232-259-2 7803-49-8 [≤ 55% in aqueous solution] * These substances are prohibited when used as a substance in hair dye products, under entry 1293 of Annex II to Regulation 1223/2009. However, as from 1 December 2010, they are banned for use in all cosmetic products. * * 3 Chemical name EC No CAS No mepanipyrim; - 110235-47-7 4-methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine hydroxylammonium hydrogensulfate; 233-154-4 10046-00-1 hydroxylamine sulfate (1:1) (6R-trans)-1-((7-ammonio-2-carboxylato-8-oxo-5-thia- 423-260-0 100988-63-4 1-azabicyclo-[4.2.0]oct-2-en-3-yl)methyl)pyridinium iodide forchlorfenuron (ISO); - 68157-60-8 1-(2-chloro-4-pyridyl)-3-phenylurea cinidon ethyl (ISO); - 142891-20-1 ethyl (Z)-2-chloro-3-[2-chloro-5-(cyclohex-1-ene-1,2- dicarboximido)phenyl]acrylate N-[6,9-dihydro-9-[[2-hydroxy-1- 424-550-1 84245-12-5 (hydroxymethyl)ethoxy]methyl]-6-oxo-1H-purin-2- yl]acetamide molybdenum trioxide 215-204-7 1313-27-5 2,2'-((3,3',5,5'-tetramethyl-(1,1'-biphenyl)-4,4'-diyl)- 413-900-7 85954-11-6 bis(oxymethylene))-bis-oxirane trifluralin (ISO) (containing < 0.5 ppm NPDA); 216-428-8 1582-09-8 α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine (containing < 0.5 ppm NPDA); 2,6-dinitro-N,N-dipropyl-4-trifluoromethylaniline (containing < 0.5 ppm NPDA); N,N-dipropyl-2,6-dinitro-4-trifluoromethylaniline (containing < 0.5 ppm NPDA) piperazine; 203-808-3 110-85-0 [solid] hydroxylamine ....% 232-259-2 7803-49-8 [> 55% in aqueous solution] hydroxylammonium chloride; 226-798-2 [1] 5470-11-1 [1] hydroxylamine hydrochloride; [1] 233-118-8 [2] 10039-54-0 [2] bis(hydroxylammonium) sulfate; hydroxylamine sulfate (2:1) [2] 4,4'-methylenediphenyl diisocyanate; 202-966-0 [1] 101-68-8 [1] diphenylmethane-4,4'-diisocyanate; [1] 219-799-4 [2] 2536-05-2 [2] 2,2'-methylenediphenyl diisocyanate; 227-534-9 [3] 5873-54-1 [3] diphenylmethane-2,2'-diisocyanate; [2] 247-714-0 [4] 26447-40-5 [4] o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'-diisocyanate; [3] methylenediphenyl diisocyanate [4] mancozeb (ISO); - 8018-01-7 manganese ethylenebis(dithiocarbamate) (polymeric) complex with zinc salt maneb (ISO); 235-654-8 12427-38-2 manganese ethylenebis(dithiocarbamate) (polymeric) benfuracarb (ISO); - 82560-54-1 ethyl N-[2,3-dihydro-2,2-dimethylbenzofuran-7- yloxycarbonyl(methyl)aminothio]-N-isopropyl- β- alaninate phoxim (ISO); 238-887-3 14816-18-3 α-(diethoxyphosphinothioylimino) phenylacetonitrile 4 Chemical name EC No CAS No glufosinate ammonium (ISO); 278-636-5 77182-82-2 ammonium 2-amino-4- (hydroxymethylphosphinyl)butyrate furfuryl alcohol 202-626-1 98-00-0 1,2-epoxy-4-epoxyethylcyclohexane; 203-437-7 106-87-6 4-vinylcyclohexene diepoxide reaction mass of: Ca salicylates (branched C10-14 and C18- 415-930-6 - 30 alkylated); Ca phenates (branched C10-14 and C18-30 alkylated); Ca sulfurised phenates (branched C10-14 and C18-30 alkylated) N,N'-diacetylbenzidine 210-338-2 613-35-4 cyclohexylamine 203-629-0 108-91-8 hydroxylammonium hydrogensulfate; 233-154-4 [1] 10046-00-1 [1] hydroxylamine sulfate(1:1); [1] 244-077-0 [2] 20845-01-6 [2] hydroxylamine phosphate; [2] 242-818-2 [3] 19098-16-9 [3] hydroxylamine dihydrogenphosphate; [3] 258-872-5 [4] 53933-48-5 [4] hydroxylamine 4-methylbenzenesulfonate [4] Refractory Ceramic Fibres, Special Purpose Fibres, with - - the exception of those specified elsewhere in this Annex; [Man-made vitreous (silicate) fibres with random orientation with alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+ MgO+BaO) content less or equal to 18 % by weight] O-hexyl-N-ethoxycarbonylthiocarbamate
Load more

Recommended publications
  • Aniline and Aniline Hydrochloride
    SOME AROMATIC AMINES AND RELATED COMPOUNDS VOLUME 127 This publication represents the views and expert opinions of an IARC Working Group on the Identification of Carcinogenic Hazards to Humans, which met remotely, 25 May–12 June 2020 LYON, FRANCE - 2021 IARC MONOGRAPHS ON THE IDENTIFICATION OF CARCINOGENIC HAZARDS TO HUMANS ANILINE AND ANILINE HYDROCHLORIDE 1. Exposure Characterization 1.1.2 Structural and molecular formulae, and relative molecular mass 1.1 Identification of the agent (a) Aniline 1.1.1 Nomenclature NH2 (a) Aniline Chem. Abstr. Serv. Reg. No.: 62-53-3 EC No.: 200-539-3 Molecular formula: C H N IUPAC systematic name: aniline 6 7 Relative molecular mass: 93.13 (NCBI, 2020a). Synonyms and abbreviations: benzenamine; phenylamine; aminobenzene; aminophen; (b) Aniline hydrochloride aniline oil. NH2 (b) Aniline hydrochloride Chem. Abstr. Serv. Reg. No.: 142-04-1 EC No.: 205-519-8 HCl IUPAC systematic name: aniline hydro - Molecular formula: C6H8ClN chloride Relative molecular mass: 129.59 (NCBI, Synonyms: aniline chloride; anilinium chlo- 2020b). ride; benzenamine hydrochloride; aniline. HCl; phenylamine hydrochloride; phenylam- monium chloride. 1.1.3 Chemical and physical properties of the pure substance Aniline is a basic compound and will undergo acid–base reactions. Aniline and its hydrochlo- ride salt will achieve a pH-dependent acid–base equilibrium in the body. 109 IARC MONOGRAPHS – 127 (a) Aniline Octanol/water partition coefficient (P): log Kow, 0.936, predicted median (US EPA, 2020b) Description: aniline appears as a yellowish Conversion factor: 1 ppm = 5.3 mg/m3 [calcu- to brownish oily liquid with a musty fishy lated from: mg/m3 = (relative molecular odour (NCBI, 2020a), detectable at 1 ppm 3 mass/24.45) × ppm, assuming temperature [3.81 mg/m ] (European Commission, 2016; (25 °C) and pressure (101 kPa)].
    [Show full text]
  • Cheminformatics Tools for Enabling Metabolomics by Yannick Djoumbou Feunang
    Cheminformatics Tools for Enabling Metabolomics by Yannick Djoumbou Feunang A thesis submitted in partial fulfillment of requirements for the degree of Doctor of Philosophy in Microbiology and Biotechnology Department of Biological Sciences University of Alberta ©Yannick Djoumbou Feunang, 2017 ii Abstract Metabolites are small molecules (<1500 Da) that are used in or produced during chemical reactions in cells, tissues, or organs. Upon absorption or biosynthesis in humans (or other organisms), they can either be excreted back into the environment in their original form, or as a pool of degradation products. The outcome and effects of such interactions is function of many variables, including the structure of the starting metabolite, and the genetic disposition of the host organism. For this reasons, it is usually very difficult to identify the transformation products as well as their long-term effect in humans and the environment. This can be explained by many factors: (1) the relevant knowledge and data are for the most part unavailable in a publicly available electronic format; (2) when available, they are often represented using formats, vocabularies, or schemes that vary from one source (or repository) to another. Assuming these issues were solved, detecting patterns that link the metabolome to a specific phenotype (e.g. a disease state), would still require that the metabolites from a biological sample be identified and quantified, using metabolomic approaches. Unfortunately, the amount of compounds with publicly available experimental data (~20,000) is still very small, compared to the total number of expected compounds (up to a few million compounds). For all these reasons, the development of cheminformatics tools for data organization and mapping, as well as for the prediction of biotransformation and spectra, is more crucial than ever.
    [Show full text]
  • Evaluating Analytical Methods for Detecting Unknown Chemicals in Recycled Water
    PROJECT NO. 4992 Evaluating Analytical Methods for Detecting Unknown Chemicals in Recycled Water Evaluating Analytical Methods for Detecting Unknown Chemicals in Recycled Water Prepared by: Keith A. Maruya Charles S. Wong Southern California Coastal Water Research Project Authority 2020 The Water Research Foundation (WRF) is a nonprofit (501c3) organization which provides a unified source for One Water research and a strong presence in relationships with partner organizations, government and regulatory agencies, and Congress. The foundation conducts research in all areas of drinking water, wastewater, stormwater, and water reuse. The Water Research Foundation’s research portfolio is valued at over $700 million. The Foundation plays an important role in the translation and dissemination of applied research, technology demonstration, and education, through creation of research‐based educational tools and technology exchange opportunities. WRF serves as a leader and model for collaboration across the water industry and its materials are used to inform policymakers and the public on the science, economic value, and environmental benefits of using and recovering resources found in water, as well as the feasibility of implementing new technologies. For more information, contact: The Water Research Foundation Alexandria, VA Office Denver, CO Office 1199 North Fairfax Street, Suite 900 6666 West Quincy Avenue Alexandria, VA 22314‐1445 Denver, Colorado 80235‐3098 Tel: 571.384.2100 Tel: 303.347.6100 www.waterrf.org [email protected] ©Copyright 2020 by The Water Research Foundation. All rights reserved. Permission to copy must be obtained from The Water Research Foundation. WRF ISBN: 978‐1‐60573‐503‐0 WRF Project Number: 4992 This report was prepared by the organization(s) named below as an account of work sponsored by The Water Research Foundation.
    [Show full text]
  • UNITED STATES PATENT Office 2,377,193 PROCESS for the PRODUCTION of by DROXYAMMONUM, CLOB OE Philip F
    EPaRenees: Ray 29, 1945 2,377,193 UNITED STATES PATENT office 2,377,193 PROCESS FOR THE PRODUCTION OF BY DROXYAMMONUM, CLOB OE Philip F. Tryon, Terre Baute, nd, assignor to Commercial Solvents Corporation, Terre Haute, Ind., a corporation of Maryland No Drawing. Application October 9, 1943, Serial No. 505,664 10 Claims. (c. 23-87) My invention relates to a process for the pro and used as the source, of solvent for another duction of hydroxylammonium chloride. More reaction solution. The crystals obtained from particularly, it relates to a process for the pro this process are preferably dried for approxi duction of hydroxylammonium chloride by there- . mately two hours at 70-80 C. action of hydroxylammonium sulfate with hydro The reaction is effected with satisfactory re chloric acid. sults without the presence of a lower alcohol sol Prior methods of preparing hydroxylammoni went. However, slightly better yields are obtained um chloride have generally been unsatisfactory and the separation of the reaction product is in view of the relatively long and involved pro more easily accomplished when utilizing a lower cedures utilized, and the comparatively low yields O alcohol solvent, such as methanol. Also, it is obtained thereby, Typical of the former methods sometimes advantageous to heat the reaction employed in the synthesis of hydroxylammonium mixture to an elevated temperature of approx chloride, is the procedure involving the use of so imately 70° C. In such instances, however, little dium nitrite, sodium bisulfite and sulfur dioxide if any advantage is obtained by keeping the lower . to produce sodium hydroxylamine disulfonate, 15 alcohol reaction mixture at an elevated tempera which is in turn treated with acetone to form ac ture for an extended length of time.
    [Show full text]
  • Safety Data Sheet - Version 5.0 Preparation Date 2/5/2016 Latest Revision Date (If Revised) SDS Expiry Date 2/3/2019
    Safety Data Sheet - Version 5.0 Preparation Date 2/5/2016 Latest Revision Date (If Revised) SDS Expiry Date 2/3/2019 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier Chemical Name Hydroxylamine Sulfate Catalogue # H943830 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against Product Uses To be used only for scientific research and development. Not for use in humans or animals. 1.3 Details of the Supplier of the Safety Data Sheet Company Toronto Research Chemicals 2 Brisbane Road Toronto, ON M3J 2J8 CANADA Telephone +14166659696 FAX +14166654439 Email [email protected] 1.4 Emergency Telephone Number Emergency# +14166659696 between 0800-1700 (GMT-5) 2. HAZARDS IDENTIFICATION WHMIS Classification (Canada) WHMIS Symbols (Canada) D2A Very Toxic Material Causing Other Toxic Effects Chronic Toxicity D2B Toxic Material Causing Other Toxic Effects Carcinogen E Corrosive Material 2.1/2.2 Classification of the Substance or Mixture and Label Elements GHS Hazards Classification (According to EU Regulation 1272/2008 and US OSHA 1910.1200) Corrosive to Metals (Category 1) Acute Toxicity, Oral (Category 4) Acute Toxicity, Dermal (Category 4) Skin Irritation (Category 2) Serious Eye Irritation (Category 2A) Sensitisation, Skin (Category 1) Carcinogenicity (Category 2) Specific Target Organ Toxicity, Repeated Exposure (Category 2) Hazardous to the Aquatic Environment, Acute Hazard (Category 1) Hazardous to the Aquatic Environment, Long-Term Hazard (Category 3) EU Classification (According to EU Regulation 67/548/EEC) Harmful in contact with skin and if swallowed. Irritating to eyes and skin. May cause sensitization by skin contact.
    [Show full text]
  • Topics in Safety Topic 13: Allergic Responses Within School Science
    Topics in Safety ASE Health & Safety Group Topic 13: Allergic responses within school science This Topic has been updated to reflect that, as incidences of allergies of all sorts have increased, dealing with them has become a whole-school issue rather than just of concern to the science department. The incidence of allergies, and its reporting, have become increasingly common. Some research suggests this is because we live in increasingly clean environments and so children do not build up immunity at a young age. Allergy results initially from exposure to a sensitiser. Respiratory sensitisers cause asthma. Once sensitisation has occurred, individuals will respond to much lower exposures in the future. There is no way of determining the threshold concentration for sensitisation or for subsequent triggering of an allergic reaction in sensitised individuals. Sensitisation usually takes months, or even years, of exposure to the sensitiser. Allergy symptoms may occur immediately after exposure, or may be delayed for several hours. There is some evidence to suggest that individuals with one significant allergic reaction may be more likely to develop allergy to other substances. A school should have an agreed policy and set of procedures to know about and deal with allergic responses in both children and staff. 13.1 Advice for science departments Science, departments should ensure that they: have a mechanism for receiving, and recording, whole school information about individuals (students, teachers, technicians) who are allergic to particular
    [Show full text]
  • Preparation from Hydroxylammonium Sulfate of Alcoholic Hydroxylamine
    ratentamt JcuropaiscnesEuropean Patent Office ® Publication number: 0108 294 vsrriceOffice europeeneuroDeen aesdes Drevetsbrevets B1 ® EUROPEAN PATENT SPECIFICATION (45) Date of publication of patent specification: 06.02.91 (g) int. CI.5: C 01 B 21/14, C 07 C 51/41, C 07 C 249/04< C 07 C 259/04 ® Application number: 83110342.9 (22) Date of filing: 17.10.83 w> preparation trom nyaroxyiammomum suirate ot alcoholic hydroxylamine solutions and of oximes, hydroxamic acids and other hydroxylammonium salts via alcoholic hydroxylamine solutions. & rriorixy: ui.il.tsz US 437920 (73) Proprietor: ALLIED-SIGNAL INC. (a Delaware 23.09.83 US 534292 corporation) 23.09.83 US 534291 Columbia Road and Park Avenue P.O. Box 2245R Morristown New Jersey 07960 (US) g) Date of publication of application: 16.05.84 Bulletin 84/20 ® I nventor: Mathew, Chempolil Thomas 9 Openaki Road tandolph New Jersey 07869 (US) ruDiication ot the grant of the patent: nventor: Ulmer, Harry Edwards 06.02.91 Bulletin 91/06 !6 Ellsworth Avenue /lorristown. New Jersey 07960 (US) HJ Designated Contracting States: BE CH DE FR GB IT LI NL SE J5) Representative: Brock, Peter William et al URQUHART-DYKES & LORD 91 Wimpole Street London W1M8AH (GB) nererences citea: DE-B-1247284 JS-A-2483252 JS-A-3420 621 JOURNAL OF ORGANIC CHEMISTRY, vol. H,May 1946, pages 207-214, Washington, US; ID. HURD et al.: "Hydroxamic acids from iliphatic dicarboxylic acids" wie. vviuiim nine monms rrom Tne puDiication or the mention of the grant of the European patent, any person may jive notice to the European Patent Office of opposition to the European patent granted.
    [Show full text]
  • Chemical Name
    Ref. Ares(2015)2892676 - 09/07/2015 List of substances banned for use in cosmetic products as from 1 December 2010 (updated July 2015) The following substances are classified as CMR substances of category 1A, 1B or 2 under Commission Regulation (EC) No 790/2009 and successive amendments of the Regulation 1272/2008.1 Therefore, these substances are banned for use in cosmetic products as from 1 December 2010 (which is the starting date of application of their classification), in accordance with Article 15 of the Cosmetics Regulation (EC) 1223/2009. Please note that some of the substances classified as CMR substances under Commission Regulation (EC) No 790/2009 and the successive amending regulations had already been regulated in Annex II to the Cosmetics Regulation through previous adaptations to technical progress of the Annexes to the Cosmetics Directive (which had been taken over by the Cosmetics Regulation at the time of its adoption in November 2009). They continue therefore to be listed in this Annex and to be banned for use in cosmetics, and are thus not included in the list below. In addition, some substances classified as CMR substances under Commission Regulation (EC) No 790/2009 and the successive amending regulations are considered to be covered by existing entries in Annex II to the Cosmetics Regulation and are not included in the list below. Chemical name EC No CAS No O-isobutyl-N-ethoxy carbonylthiocarbamate 434-350-4 103122-66-3 chlorpropham (ISO); 202-925-7 101-21-3 isopropyl 3-chlorocarbanilate hydroxylammonium nitrate 236-691-2 13465-08-2 reaction mass of: 4,7-bis(mercaptomethyl)-3,6,9-trithia- 427-050-1 - 1,11-undecanedithiol-; 4,8-bis(mercaptomethyl)-3,6,9-trithia-1,11- undecanedithiol; 5,7-bis(mercaptomethyl)-3,6,9-trithia-1,11- undecanedithiol cobalt acetate 200-755-8 71-48-7 1 This list does not contain the substance Musk Ketone (CAS 81-14-1), even though it has been classified as a CMR 2 substance by Commission Regulation 790/2009.
    [Show full text]
  • Adiabatic Calorimetric Studies of Hydroxylamine
    ADIABATIC CALORIMETRIC STUDIES OF HYDROXYLAMINE COMPOUNDS A Dissertation by LIZBETH OLIVIA CISNEROS TREVIÑO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY August 2002 Major Subject: Chemical Engineering iii ABSTRACT Adiabatic Calorimetric Studies of Hydroxylamine Compounds. (August 2002) Lizbeth Olivia Cisneros Treviño, B.S., ITESM, Monterrey, Mexico Chair of Advisory Committee: Dr. M. Sam Mannan In the present work, the thermal decomposition reaction of HA and some of its derivatives (aqueous solutions of hydroxylamine, hydroxylamine hydrochloride, hydroxylamine sulfate, and hydroxylamine o-sulfonic acid) were studied using adiabatic calorimetry. The effect of some metal contaminants such as Ti, stainless steel, carbon steel, ferric ion, and ferrous ion was also analyzed. Useful information was generated such as safe storage temperatures (onset temperature), maximum temperature, maximum pressure, pressure of noncondensables, heat and pressure generation rates as functions of temperature, temperature vs. pressure and time to maximum rate. To get an insight about the possible decomposition mechanisms, HA decomposition reactions were carried out with and without air above the sample. The thermokinetics of the respective systems was modeled using the heat generation rates. From such kinetic models, reaction order, activation energies, and frequency factors for the overall decomposition reactions were obtained. The kinetic parameters were used in computer simulations to obtain models for the temperature vs. time curves. Since several members of the hydroxylamine family were studied, a comparison of their thermal behavior is presented. iv To my husband Javier, my brothers Rodolfo, Francisco Javier and José Juan, and my parents Rodolfo and Olivia… v ACKNOWLEDGMENTS I thank Dr.
    [Show full text]
  • ~Ward Period: ~Rom I Lj+'Ljf;J. to 3)30/Y::{ (Performance) ------(Reporut Lponsor Amount: Total Estimated: S L;;J., Yt? Funded: S__ I,....;J.=T-1
    _lJRGIA INSTITUTE OF TECHNOLOGY OFFICE Of l,;UN I 1'11-\\.. I "'LIIYIII•I"" 1 ''~ • ,...,. •• '· PROJECT Al>MINISTRATION LlATA SHEET 00 ORIGINAt D REVISION NO. --- roject No. A '34 3 0 GTRIK*=f DATE _....1...101.J..~J J-'-4+-/ ~Yk=--- Seheei/Lab _- __;t_~-~M..;...;s~· =~;.._ ______ roject Director: ·1ft· -~n9 /.... Wt.t. ponsor: Get _11 (Qr_o. Ve I cLo:sf a, 6-11- 'yr,e Agreement: na l\()e111 en I= d zd~d Jl/2 rjf;J.. ~ward Period: ~rom I lj+'ljf;J. To 3)30/Y::{ (Performance) ------- (Reporut lponsor Amount: Total Estimated: S l;;J., yt? Funded: s__ I,....;J.=t-1 ......Y __ i_3 ______ _ I ,~-----~~~-2V~~--~--- ~[)MINISTRATIVE DATA OCA Contact z;tn d a If. I$()(.J&l 411 ;( ff).(J I) Sponsor Technical Contact: 2) Sponsor Admin/Contractual Matters: M.s, LJ',d7L t:l//ot . , Defense Priority Rating: __fJ~l .... 11,..7...,£ ____ _ Military Security Classification: /] ()0 ( (or) Company/Industrial Proprietary: RESTRICTIONS See Attached __.,1)+-+-/ .. zu..::;... _____ Supplemental Information Sheet for Additional Requirements. I l'ravel: Foreign travel must have prior approval - Contact OCA in each case. Domestic travel requires sponsor approval where total will excee~ greater of $500 or 125% of approved proposal budget category. Equipment: Title vests with 0 QO e 0(0 r;?p~cf_ ~ I COPIES TO: Research Administrative Network Research Security Services Research Communications (2) Research Property Management "'Aepnrb Coordinator (OCAL-­ Project F ile Accounting GTRI Other P•D Procurement/EES Supply Services · Library Other ------------------------------- GEORGIA INSTITUTE Of ·.TECHNOLOGY OFFICE OF CONTRACT ADMINISTRATION SPONSORED PROJECT TERMINATION SHEET .
    [Show full text]
  • United States Patent (19) 11 Patent Number: 4,645,579 Weiss Et Al
    United States Patent (19) 11 Patent Number: 4,645,579 Weiss et al. 45) Date of Patent: Feb. 24, 1987 (54 PREPARATION OF AOUEOUS 4,521,285 6/1985 De Witt et al............... 204/182.4 X HYDROXYLAMINE SOLUTIONS OTHER PUBLICATIONS 75 Inventors: Franz-Josef Weiss, Neuhofen; Chemical Abstracts, vol. 102, 1985, abstract No. 134403s, Wolfgang Habermann, Mainz; Peter Stamicarbon, B. V., "Circulating Process for Preparing Hammes, Ruppertsberg; Elmar and Working Up a Hydroxylammonium Salt Solution'. Frommer, Ludwigshafen; Erwin Chemical Abstracts, vol. 94, 1981, abstract No. 141,98ly, Thomas, Freinsheim; Peter Thoma, Chang, Y. et al., "Conversion of Hydroxylamine Hydro Frankenthal, all of Fed. Rep. of chloride to Hydroxylamine Nitrate by Electrodialysis Germany and Water Splitting". 73) Assignee: BASF Aktiengsellschaft, Fed. Rep. of Chemical Abstracts, vol. 83, 1975, abstract No. 181595e, Germany Maurel, A., "Continuous Transformation of a Hydroxy lamine Salt into Another Hydroxylamine Salt'. 21 Appl. No.: 685,254 Y. Chang et al., "Chemical Abstracts', Band 94, (1981), 22 Filed: Dec. 24, 1984 p. 134. 30 Foreign Application Priority Data Primary Examiner-John F. Niebling Dec. 28, 1983 DE Fed. Rep. of Germany ....... 3347259 Attorney, Agent, or Firm-Keil & Weinkauf 51) Int. Cl. .............................................. B01D 13/02 57 ABSTRACT 52 U.S.C. ................................. 204/1824; 204/101; Aqueous solutions of hydroxylamine are prepared from 204/102; 204/182.5 aqueous hydroxylammonium salt solutions by electrodi 58) Field of Search .................... 204/101, 102, 180 P, alysis by a method in which the aqueous hydroxylam 204/1824, 182.5, 72 monium salt solution is fed into the middle zone of an electrolysis cell, which is divided into a cathode zone, 56) References Cited an anode zone and a middle zone by means of semiper U.S.
    [Show full text]
  • Material Safety Data Sheet Hydroxylamine Sulfate ACC# 11270 Section 1 - Chemical Product and Company Identification
    Material Safety Data Sheet Hydroxylamine sulfate ACC# 11270 Section 1 - Chemical Product and Company Identification MSDS Name: Hydroxylamine sulfate Catalog Numbers: AC198530000, AC198530010, AC198530050, AC198531000, AC198532500, H331-100, H331-500 Synonyms: Hydroxylammonium sulfate; Oxammonium sulfate; Bis(hydroxylammonium) sulphate. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECS/ELINCS 10039-54-0 Hydroxylamine sulfate >99 233-118-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: white crystals. Warning! Strong reducing agent. Fire and explosion risk in contact with oxidizing agents. Causes eye, skin, and respiratory tract irritation. Harmful if swallowed. May cause allergic skin reaction. May cause blood abnormalities. May cause methemoglobinemia. Corrosive to metal. Heat sensitive. Target Organs: Blood, respiratory system, cardiovascular system, eyes, skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause skin burns. Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. Inhalation: May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, tachycardia, dyspnea (labored breathing), and death. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.
    [Show full text]