DOCSLIB.ORG

Aldrich Hydrocarbons

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Aldrich Hydrocarbons Aldrich Hydrocarbons Library Listing – 1,199 spectra Subset of Aldrich FT-IR Library related to hydrocarbons. The Aldrich Material-Specific FT-IR Library collection represents a wide variety of the Aldrich Handbook of Fine Chemicals' most common chemicals divided by similar functional groups. These spectra were assembled from the Aldrich Collection of FT-IR Spectra and the data has been carefully examined and processed by Thermo. The molecular formula, CAS (Chemical Abstracts Services) registry number, when known, and the location number of the printed spectrum in The Aldrich Library of FT-IR Spectra are available. Aldrich Hydrocarbons Index Compound Name Index Compound Name 304 (+)-BETA-PINENE, 98% 483 1,1,2,2-TETRABROMOETHANE, 98% 306 (+)-CAMPHENE, TECH., 80% 481 1,1,2,2-TETRACHLOROETHANE, 235 (+)-CYCLOSATIVENE, 99% 97% 308 (+)-LONGIFOLENE, 98+% 591 1,1,2-TRICHLORO-2,3,3- 289 (-)-ALPHA-CUBEBENE, 97% TRIFLUOROCYCLOBUTANE, 97% 307 (-)-CAMPHENE, 95% 464 1,1,2-TRICHLOROETHANE, 98% 314 (-)-ISOCARYOPHYLLENE, 98% 494 1,1,2- 597 (-)-MENTHYL CHLORIDE, 99+% TRICHLOROTRIFLUOROETHANE, 843 (1,2-DIBROMOETHYL)BENZENE, 99% 99% 566 1,1,3-TRICHLOROPROPENE, 95% 840 (1-BROMOETHYL)BENZENE, 97% 744 1,1,4,4-TETRAPHENYL-1,3- 291 (1R)-(+)-ALPHA-PINENE, 98% (91+% BUTADIENE, SCINTIL-LATION EE/GLC) GRADE, 99+% 287 (1S)-(+)-3-CARENE, 99% 675 1,1-BIS(3,4- 292 (1S)-(-)-ALPHA-PINENE, 98% (81+% DIMETHYLPHENYL)ETHANE, EE/GLC) TECH., 90+% 305 (1S)-(-)-BETA-PINENE, 99% 1156 1,1-BIS(4-CHLOROPHENYL)-2,2,2- 850 (2,2-DICHLORO-1- TRICHLOROETHANE, 99+% METHYLCYCLOPROPYL)BENZENE 1154 1,1-BIS(4-FLUOROPHENYL)-2,2- , 97% DICHLOROETHANE 849 (2,2-DICHLOROCYCLOPROPYL)- 436 1,1-DICHLOROETHANE BENZENE, 97% 437 1,1-DICHLOROPROPANE, 97% 632 (2,2-DIMETHYLPROPYL)BENZENE, 280 1,1-DICYCLOPROPYLETHYLENE 98% 451 1,1-DIIODO-2,2- 842 (2-BROMOETHYL)BENZENE, 98% DIMETHYLPROPANE, 98% 841 (2-CHLOROETHYL)BENZENE, 99% 215 1,1-DIMETHYLCYCLOHEXANE, 667 (2.2)PARACYCLOPHANE, 97% 99% 832 (BIS(TRIFLUOROACETOXY)IODO) 140 1,1-DINEOPENTYLETHYLENE BENZENE, 97% 1147 1,1-DIPHENYL-2,2,2- 614 (BROMOMETHYL)CYCLOBUTANE, TRICHLOROETHANE, 98% 97% 739 1,1-DIPHENYLETHYLENE, 97% 592 (BROMOMETHYL)CYCLOHEXANE, 431 1,10-DIBROMODECANE, 97% 99% 430 1,10-DICHLORODECANE, 99% 590 (BROMOMETHYL)CYCLOPROPAN 432 1,10-DIIODODECANE, 95% E, 97% 433 1,11-DIBROMOUNDECANE, 98+% 589 (CHLOROMETHYL)CYCLOPROPAN 435 1,12-DIBROMODODECANE E, 98% 434 1,12-DICHLORODODECANE, 98% 620 (R)-(+)-3-CHLOROSTYRENE OXIDE, 195 1,13-TETRADECADIENE, 90% 98% 687 1,2,3,4,5,6,7,8- 283 (R)-(+)-LIMONENE, 97% (98% OCTAHYDROANTHRACENE EE/GLC) 295 1,2,3,4,5,6,7,8- 284 (S)-(-)-LIMONENE, 96% OCTAHYDRONAPHTHALENE, 99% 784 1,1'-BI(ACENAPHTHENYLIDENE) 583 1,2,3,4,5,6- 508 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8- HEXACHLOROCYCLOHEXANE, HEPTADECA-FLUOROOCTANE, ALPHA-ISOMER, 99% 99% 584 1,2,3,4,5,6- 499 1,1,1,2,2,3,3- HEXACHLOROCYCLOHEXANE, HEPTACHLOROPROPANE, 99% GAMMA-ISOMER, 97% 482 1,1,1,2-TETRABROMOETHANE, 98% 258 1,2,3,4,5- 480 1,1,1,2-TETRACHLOROETHANE, PENTAMETHYLCYCLOPENTADIEN 99% E, 95% 463 1,1,1-TRICHLOROETHANE, 99% 747 1,2,3,4,5-PENTAPHENYL-1,3- 493 1,1,1- CYCLOPENTADIENE, 99% TRICHLOROTRIFLUOROETHANE, 1009 1,2,3,4-TETRACHLOROBENZENE, 99% 98% 467 1,1,1- 1199 1,2,3,4- TRIS(CHLOROMETHYL)PROPANE, TETRACHLORONAPHTHALENE- 99% BIS(HEXA- 492 1,1,2,2,3-PENTAFLUOROPROPANE, CHLOROCYCLOPENTADIENE) 99% ADDUC (c) 2007 Thermo Fisher Scientific Inc. All rights reserved. Page 1 of 15 Aldrich Hydrocarbons Index Compound Name Index Compound Name 1007 1,2,3,4-TETRAFLUOROBENZENE, 457 1,2-DIBROMO-3,3- 99% DIMETHYLBUTANE, 97% 652 1,2,3,4- 856 1,2-DIBROMOBENZENE, 98% TETRAHYDRONAPHTHALENE, 445 1,2-DIBROMOBUTANE, 97% 97+% 402 1,2-DIBROMOETHANE, 99+% 257 1,2,3,4-TETRAMETHYL-1,3- 554 1,2-DIBROMOETHYLENE, 98%, CYCLOPENTADIENE, CA. 85% MIXTURE OF CIS AND TRANS 682 1,2,3,4-TETRAMETHYLBENZENE, 502 1,2- 95% DIBROMOHEXAFLUOROPROPANE, 746 1,2,3,4-TETRAPHENYL-1,3- 95% CYCLOPENTADIENE, 97% 454 1,2-DIBROMOHEXANE, 98% 777 1,2,3,4- 441 1,2-DIBROMOPROPANE, 97% TETRAPHENYLNAPHTHALENE, 497 1,2- 97% DIBROMOTETRACHLOROETHANE, 1016 1,2,3,5-TETRACHLOROBENZENE, 97% 99% 449 1,2-DICHLORO-2- 1011 1,2,3,5-TETRAFLUOROBENZENE, METHYLPROPANE, 98% 99+% 951 1,2-DICHLORO-3-IODOBENZENE, 683 1,2,3,5-TETRAMETHYLBENZENE, 97% 80% 973 1,2-DICHLORO-4- 773 1,2,3,6,7,8-HEXAHYDROPYRENE, FLUOROBENZENE, 99% 98% 853 1,2-DICHLOROBENZENE, 99%, 466 1,2,3-TRIBROMOPROPANE, 97% SPECTROPHOTOMETRIC GRADE 949 1,2,3-TRICHLOROBENZENE, 99% 400 1,2-DICHLOROETHANE, 99+%, 465 1,2,3-TRICHLOROPROPANE, 99% SPECTROPHOTOMETRIC GRADE 568 1,2,3-TRICHLOROPROPENE 551 1,2-DICHLOROETHYLENE, 98%, 941 1,2,3-TRIFLUOROBENZENE, 99% MIXTURE OF CIS AND TRANS 670 1,2,3-TRIMETHYLBENZENE, TECH., 438 1,2-DICHLOROPROPANE, 99% 90% 650 1,2-DIETHYLBENZENE, TECH., 92% 1026 1,2,4,5-TETRACHLOROBENZENE, 972 1,2-DIFLUORO-4-IODOBENZENE, 98% 98% 1023 1,2,4,5-TETRAFLUOROBENZENE, 851 1,2-DIFLUOROBENZENE, 98% 99+% 700 1,2-DIHYDRONAPHTHALENE, 98% 686 1,2,4,5- 860 1,2-DIIODOBENZENE, 98% TETRAISOPROPYLBENZENE, 96% 403 1,2-DIIODOETHANE, 99% 1022 1,2,4,5- 1054 1,2- TETRAKIS(BROMOMETHYL)BENZ DIIODOTETRAFLUOROBENZENE, ENE, 95% 99% 685 1,2,4,5-TETRAMETHYLBENZENE, 216 1,2-DIMETHYLCYCLOHEXANE, ZONE REFINED, 99.9+% 98%, MIXTURE OF CIS AND TRANS 996 1,2,4-TRIBROMOBENZENE, 97% 760 1,2-DIMETHYLNAPHTHALENE, 987 1,2,4-TRICHLOROBENZENE, 99% 98% 674 1,2,4-TRIETHYLBENZENE, 97% 816 1,2:3,4-DIBENZANTHRACENE, 97% 968 1,2,4-TRIFLUOROBENZENE, 98% 815 1,2:5,6-DIBENZANTHRACENE, 97% 671 1,2,4-TRIMETHYLBENZENE, 98% 270 1,3,5,7-CYCLOOCTATETRAENE, 223 1,2,4-TRIMETHYLCYCLOHEXANE, 98% 99% 177 1,3,5-HEXATRIENE, 97%, MIXTURE 278 1,2,4-TRIVINYLCYCLOHEXANE, OF ISOMERS 98%, MIXTURE OF ISOMERS 681 1,3,5-TRI-TERT-BUTYLBENZENE, 588 1,2,5,6,9,10- 97% HEXABROMOCYCLODODECANE, 1005 1,3,5-TRIBROMOBENZENE, 98% 95% 1048 1,3,5-TRICHLORO-2,4,6- 804 1,2-BENZANTHRACENE, 99% TRIFLUOROBENZENE, 98% 750 1,2-BIS(3-INDENYL)ETHANE, 99% 1001 1,3,5-TRICHLOROBENZENE, 99% 479 1,2-DIBROMO-1,1- 677 1,3,5-TRIETHYLBENZENE, 98% DIFLUOROETHANE, 99% 998 1,3,5-TRIFLUOROBENZENE, 97% 484 1,2-DIBROMO-2,3- 678 1,3,5-TRIISOPROPYLBENZENE, 97% DICHLOROPROPANE 224 1,3,5- 450 1,2-DIBROMO-2- TRIISOPROPYLCYCLOHEXANE, METHYLPROPANE, 98% 98%, MIXTURE OF ISOMERS (c) 2007 Thermo Fisher Scientific Inc. All rights reserved. Page 2 of 15 Aldrich Hydrocarbons Index Compound Name Index Compound Name 250 1,3,5-TRIMETHYL-1- 1106 1,4- CYCLOHEXENE, 98%, MIXTURE OF BIS(TRICHLOROMETHYL)BENZEN CIS AND TRANS E, 99% 717 1,3,5-TRIPHENYLBENZENE, 97% 1105 1,4- 1113 1,3,5- BIS(TRIFLUOROMETHYL)BENZEN TRIS(TRIFLUOROMETHYL)BENZE E, 98% NE, 99% 253 1,4-CYCLOHEXADIENE, 97% 809 1,3,6,8-TETRAPHENYLPYRENE 665 1,4-DI-TERT-BUTYLBENZENE, 98% 1097 1,3- 498 1,4-DIBROMO-1,1,2,2- BIS(TRIFLUOROMETHYL)BENZEN TETRAFLUOROBUTANE, 96% E, 99% 563 1,4-DIBROMO-2-BUTENE, 99%, 254 1,3-CYCLOHEPTADIENE, 97% PREDOMINANTLY TRANS 252 1,3-CYCLOHEXADIENE, 97% 977 1,4-DIBROMO-2-FLUOROBENZENE, 607 1,3-DIBROMOADAMANTANE, 99% 98% 883 1,3-DIBROMOBENZENE, 97% 608 1,4-DIBROMOADAMANTANE, 98%, 446 1,3-DIBROMOBUTANE, 98% MIXTURE OF CIS AND TRANS 408 1,3-DIBROMOPROPANE, 99% 908 1,4-DIBROMOBENZENE, 98% 1051 1,3- 413 1,4-DIBROMOBUTANE, 99% DIBROMOTETRAFLUOROBENZEN 453 1,4-DIBROMOPENTANE, 97% E 1052 1,4- 1035 1,3-DICHLORO-2,4,6- DIBROMOTETRAFLUOROBENZEN TRIFLUOROBENZENE, 98% E, 99+% 559 1,3-DICHLORO-2-BUTENE, 95%, 1056 1,4-DICHLORO-2,3,5,6- MIXTURE OF CIS AND TRANS TETRAMETHYLBENZENE, 99% 943 1,3-DICHLORO-2- 560 1,4-DICHLORO-2-BUTENE, TECH., FLUOROBENZENE, 98% 90%, MIXTURE OF CIS AND TRANS 456 1,3-DICHLORO-3-METHYLBUTANE 990 1,4-DICHLORO-2-IODOBENZENE, 974 1,3-DICHLORO-4- 98% FLUOROBENZENE, 99% 905 1,4-DICHLOROBENZENE, 99+% 989 1,3-DICHLORO-4-IODOBENZENE, 410 1,4-DICHLOROBUTANE, 97% 98% 666 1,4-DICYCLOHEXYLBENZENE, 99% 1002 1,3-DICHLORO-5-IODOBENZENE, 662 1,4-DIETHYLBENZENE, 96% 99% 903 1,4-DIFLUOROBENZENE, 99+% 880 1,3-DICHLOROBENZENE, 98% 762 1,4-DIHYDRO-9-ISOPROPYLIDENE- 443 1,3-DICHLOROBUTANE, 99% 1,4-METHANO- NAPHTHALENE, 404 1,3-DICHLOROPROPANE, 99% 99% 555 1,3-DICHLOROPROPENE, 95%, 912 1,4-DIIODOBENZENE, 99% MIXTURE OF ISOMERS 415 1,4-DIIODOBUTANE, 99+% 1047 1,3- 1055 1,4- DICHLOROTETRAFLUOROBENZEN DIIODOTETRAFLUOROBENZENE, E, 85% 98% 658 1,3-DIETHYLBENZENE, 98% 710 1,4-DIISOPROPENYLBENZENE, 97% 878 1,3-DIFLUOROBENZENE, 99+% 249 1,4-DIISOPROPYL-1- 409 1,3-DIIODOPROPANE, 99% CYCLOHEXENE, 96% 704 1,3-DIISOPROPENYLBENZENE, 97% 664 1,4-DIISOPROPYLBENZENE, 97% 659 1,3-DIISOPROPYLBENZENE, 96% 221 1,4-DIMETHYLCYCLOHEXANE, 234 1,3-DIMETHYLADAMANTANE, 99%, MIXTURE OF CIS AND TRANS 99+% 763 1,4-DIMETHYLNAPHTHALENE, 219 1,3-DIMETHYLCYCLOHEXANE, 95% 99%, MIXTURE OF CIS AND TRANS 182 1,4-HEXADIENE, 99%, MIXTURE OF 761 1,3-DIMETHYLNAPHTHALENE, CIS AND TRANS 96% 189 1,4-OCTADIENE 172 1,3-HEXADIENE, 98%, 179 1,4-PENTADIENE, 99% PREDOMINANTLY TRANS 197 1,5,9-DECATRIENE, 97%, MIXTURE 303 1,4,5,8,9,10- OF CIS AND TRANS HEXAHYDROANTHRACENE, 97% 269 1,5,9-TRIMETHYL-1,5,9- 745 1,4-BIS(2- CYCLODODECATRIENE, 98% , METHYLSTYRYL)BENZENE, 99% (MIXTURE OF ISOMERS) (c) 2007 Thermo Fisher Scientific Inc. All rights reserved. Page 3 of 15 Aldrich Hydrocarbons Index Compound Name Index Compound Name 256 1,5-CYCLODECADIENE, TECH., 1032 1-BROMO-2,3,4,5- 90+% MIXTURE OF CIS AND TETRAFLUOROBENZENE, 98% TRANS 1033 1-BROMO-2,3,4,6- 255 1,5-CYCLOOCTADIENE, TETRAFLUOROBENZENE, 99% REDISTILLED, 99+% 1008 1-BROMO-2,3,4- 418 1,5-DIBROMOPENTANE, 97% TRIFLUOROBENZENE, 99% 416 1,5-DICHLOROPENTANE, 99% 1125 1-BROMO-2,3,5,6-TETRAFLUORO-4- 419 1,5-DIIODOPENTANE, 97% (TRIFLUORO- METHYL)BENZENE, 264 1,5-DIMETHYL-1,5- 99% CYCLOOCTADIENE, 75% 1034 1-BROMO-2,3,5,6- 764 1,5-DIMETHYLNAPHTHALENE, TETRAFLUOROBENZENE, 99% 98% 1037 1-BROMO-2,3,5,6- 187 1,5-HEPTADIENE,
Load more

Recommended publications
  • Transport of Dangerous Goods
    ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions.
    [Show full text]
  • Halogenated Ether, Alcohol, and Alkane Anesthetics Activate TASK-3 Tandem Pore Potassium Channels Likely Through a Common Mechanism S
    Supplemental material to this article can be found at: http://molpharm.aspetjournals.org/content/suppl/2017/03/21/mol.117.108290.DC1 1521-0111/91/6/620–629$25.00 https://doi.org/10.1124/mol.117.108290 MOLECULAR PHARMACOLOGY Mol Pharmacol 91:620–629, June 2017 Copyright ª 2017 by The American Society for Pharmacology and Experimental Therapeutics Halogenated Ether, Alcohol, and Alkane Anesthetics Activate TASK-3 Tandem Pore Potassium Channels Likely through a Common Mechanism s Anita Luethy, James D. Boghosian, Rithu Srikantha, and Joseph F. Cotten Department of Anesthesia, Critical Care, and Pain Medicine, Massachusetts General Hospital, Boston, Massachusetts (A.L., J.D.B., and J.F.C.); Department of Anesthesia, Kantonsspital Aarau, Aarau, Switzerland (A.L.); Carver College of Medicine, University of Iowa, Iowa City, Iowa (R.S.) Received January 7, 2017; accepted March 20, 2017 Downloaded from ABSTRACT The TWIK-related acid-sensitive potassium channel 3 (TASK-3; hydrate (165% [161–176]) . 2,2-dichloro- . 2-chloro 2,2,2- KCNK9) tandem pore potassium channel function is activated by trifluoroethanol . ethanol. Similarly, carbon tetrabromide (296% halogenated anesthetics through binding at a putative anesthetic- [245–346]), carbon tetrachloride (180% [163–196]), and 1,1,1,3,3,3- binding cavity. To understand the pharmacologic requirements for hexafluoropropanol (200% [194–206]) activate TASK-3, whereas molpharm.aspetjournals.org TASK-3 activation, we studied the concentration–response of the larger carbon tetraiodide and a-chloralose inhibit. Clinical TASK-3 to several anesthetics (isoflurane, desflurane, sevoflurane, agents activate TASK-3 with the following rank order efficacy: halothane, a-chloralose, 2,2,2-trichloroethanol [TCE], and chloral halothane (207% [202–212]) .
    [Show full text]
  • Chemical Chemical Hazard and Compatibility Information
    Chemical Chemical Hazard and Compatibility Information Acetic Acid HAZARDS & STORAGE: Corrosive and combustible liquid. Serious health hazard. Reacts with oxidizing and alkali materials. Keep above freezing point (62 degrees F) to avoid rupture of carboys and glass containers.. INCOMPATIBILITIES: 2-amino-ethanol, Acetaldehyde, Acetic anhydride, Acids, Alcohol, Amines, 2-Amino-ethanol, Ammonia, Ammonium nitrate, 5-Azidotetrazole, Bases, Bromine pentafluoride, Caustics (strong), Chlorosulfonic acid, Chromic Acid, Chromium trioxide, Chlorine trifluoride, Ethylene imine, Ethylene glycol, Ethylene diamine, Hydrogen cyanide, Hydrogen peroxide, Hydrogen sulfide, Hydroxyl compounds, Ketones, Nitric Acid, Oleum, Oxidizers (strong), P(OCN)3, Perchloric acid, Permanganates, Peroxides, Phenols, Phosphorus isocyanate, Phosphorus trichloride, Potassium hydroxide, Potassium permanganate, Potassium-tert-butoxide, Sodium hydroxide, Sodium peroxide, Sulfuric acid, n-Xylene. Acetone HAZARDS & STORAGE: Store in a cool, dry, well ventilated place. INCOMPATIBILITIES: Acids, Bromine trifluoride, Bromine, Bromoform, Carbon, Chloroform, Chromium oxide, Chromium trioxide, Chromyl chloride, Dioxygen difluoride, Fluorine oxide, Hydrogen peroxide, 2-Methyl-1,2-butadiene, NaOBr, Nitric acid, Nitrosyl chloride, Nitrosyl perchlorate, Nitryl perchlorate, NOCl, Oxidizing materials, Permonosulfuric acid, Peroxomonosulfuric acid, Potassium-tert-butoxide, Sulfur dichloride, Sulfuric acid, thio-Diglycol, Thiotrithiazyl perchlorate, Trichloromelamine, 2,4,6-Trichloro-1,3,5-triazine
    [Show full text]
  • An Automated Purge and Trap Gas Chromatography- Mass Spectrometry System for the Sensitive Shipboard Analysis of Volatile Organi
    J. Sep. Sci. 2001, 24, 97–103 Hashimoto, Tanaka, Yamashita, Maeda97 Shinya Hashimotoa), An automated purge and trap gas chromatography- Toshiyuki Tanakab), mass spectrometry system for the sensitive Nobuyoshi Yamashitab), Tsuneaki Maedac) shipboard analysis of volatile organic compounds in seawater a) Department of Ocean Sciences, Tokyo University of We developed an automated purge and trap unit connected to a gas chromatograph- Fisheries, 4-5-7 Konan, Minato- mass spectrometer for shipboard determination of unstable volatile organic com- ku, Tokyo 108±8477, Japan pounds in seawater. The device used a small column for the rapid desorption of ad- b) National Institute for sorbed compounds, thus eliminating the need for post-desorption cryofocusing. The Resources and Environment, a 16-3 Onogawa, Tsukuba, repeatability (relative standard deviation, RSD; n = 7) was typically 5%. The detection Ibaraki 305±8569, Japan limits were 0.1–4.3 pM for chloromethane, bromomethane, dichloromethane, iodo- c) DKK Corporation, 4-13-14 methane, dimethyl sulfide, iodoethane, isoprene, bromochloromethane, chloroform, Kichijoji Kitamachi, Musashino- tetrachloromethane, dibromomethane, bromodichloromethane, iodopropane, chlor- shi, Tokyo 108-0001, Japan oiodomethane, dimethyl disulfide, dibromochloromethane, bromoform, and diiodo- methane. To investigate the stability of seawater samples, we obtained a concentra- tion-time profile of volatile organic compounds using this method during the incubation of a seawater sample with and without the addition of HgCl2 in the dark at 48C. We found shipboard determination to be suitable and essential for the determination of un- stable compounds such as dimethyl sulfide in seawater, as the concentration of di- methyl sulfide increased considerably during the incubation of a seawater sample both with and without the addition of HgCl2.
    [Show full text]
  • 13C NMR Study of Co-Contamination of Clays with Carbon Tetrachloride
    Environ. Sci. Technol. 1998, 32, 350-357 13 sometimes make it the equal of solid acids like zeolites or C NMR Study of Co-Contamination silica-aluminas. Benesi (7-9) measured the Hammett acidity of Clays with Carbon Tetrachloride function H0 for a number of clays; these H0 values range from +1.5 to -8.2 (in comparison to H0 )-12 for 100% ) and Benzene sulfuric acid and H0 5 for pure acetic acid). Therefore, one can expect that certain chemical transformations might occur in/on clays that are similar to what are observed in zeolite TING TAO AND GARY E. MACIEL* systems. Thus, it is of interest to examine what happens Department of Chemistry, Colorado State University, when carbon tetrachloride and benzene are ªco-contami- Fort Collins, Colorado 80523 nantsº in a clay. This kind of information would be useful in a long-term view for understanding chemical transforma- tions of contaminants in soil at contaminated sites. Data on 13 these phenomena could also be useful for designing predic- Both solid-sample and liquid-sample C NMR experiments tive models and/or effective pollution remediation strategies. have been carried out to identify the species produced by Solid-state NMR results, based on 13C detection and line the reaction between carbon tetrachloride and benzene narrowing by magic angle spinning (MAS) and high-power when adsorbed on clays, kaolinite, and montmorillonite. Liquid- 1H decoupling (10), have been reported on a variety of organic sample 13C and 1H NMR spectra of perdeuteriobenzene soil components such as humic samples (11-13). Appar- extracts confirm the identities determined by solid-sample ently, there have been few NMR studies concerned directly 13C NMR and provide quantitative measures of the amounts with elucidating the interactions of organic compounds with of the products identifiedsbenzoic acid, benzophenone, and soil or its major components.
    [Show full text]
  • Used at Rocky Flats
    . TASK 1 REPORT (Rl) IDENTIFICATION OF CHEMICALS AND RADIONUCLIDES USED AT ROCKY FLATS I PROJECT BACKGROUND ChemRisk is conducting a Rocky Flats Toxicologic Review and Dose Reconstruction study for The Colorado Department of Health. The two year study will be completed by the fall of 1992. The ChemRisk study is composed of twelve tasks that represent the first phase of an independent investigation of off-site health risks associated with the operation of the Rocky Flats nuclear weapons plant northwest of Denver. The first eight tasks address the collection of historic information on operations and releases and a detailed dose reconstruction analysis. Tasks 9 through 12 address the compilation of information and communication of the results of the study. Task 1 will involve the creation of an inventory of chemicals and radionuclides that have been present at Rocky Flats. Using this inventory, chemicals and radionuclides of concern will be selected under Task 2, based on such factors as the relative toxicity of the materials, quantities used, how the materials might have been released into the environment, and the likelihood for transport of the materials off-site. An historical activities profile of the plant will be constructed under Task 3. Tasks 4, 5, and 6 will address the identification of where in the facility activities took place, how much of the materials of concern were released to the environment, and where these materials went after the releases. Task 7 addresses historic land-use in the vicinity of the plant and the location of off-site populations potentially affected by releases from Rocky Flats.
    [Show full text]
  • Cycloalkanes, Cycloalkenes, and Cycloalkynes
    CYCLOALKANES, CYCLOALKENES, AND CYCLOALKYNES any important hydrocarbons, known as cycloalkanes, contain rings of carbon atoms linked together by single bonds. The simple cycloalkanes of formula (CH,), make up a particularly important homologous series in which the chemical properties change in a much more dramatic way with increasing n than do those of the acyclic hydrocarbons CH,(CH,),,-,H. The cyclo- alkanes with small rings (n = 3-6) are of special interest in exhibiting chemical properties intermediate between those of alkanes and alkenes. In this chapter we will show how this behavior can be explained in terms of angle strain and steric hindrance, concepts that have been introduced previously and will be used with increasing frequency as we proceed further. We also discuss the conformations of cycloalkanes, especially cyclo- hexane, in detail because of their importance to the chemistry of many kinds of naturally occurring organic compounds. Some attention also will be paid to polycyclic compounds, substances with more than one ring, and to cyclo- alkenes and cycloalkynes. 12-1 NOMENCLATURE AND PHYSICAL PROPERTIES OF CYCLOALKANES The IUPAC system for naming cycloalkanes and cycloalkenes was presented in some detail in Sections 3-2 and 3-3, and you may wish to review that ma- terial before proceeding further. Additional procedures are required for naming 446 12 Cycloalkanes, Cycloalkenes, and Cycloalkynes Table 12-1 Physical Properties of Alkanes and Cycloalkanes Density, Compounds Bp, "C Mp, "C diO,g ml-' propane cyclopropane butane cyclobutane pentane cyclopentane hexane cyclohexane heptane cycloheptane octane cyclooctane nonane cyclononane "At -40". bUnder pressure. polycyclic compounds, which have rings with common carbons, and these will be discussed later in this chapter.
    [Show full text]
  • WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
    (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK).
    [Show full text]
  • IIIHIIII US005202462A United States Patent (19) (11) Patent Number: 5,202,462 Yazawa Et Al
    IIIHIIII US005202462A United States Patent (19) (11) Patent Number: 5,202,462 Yazawa et al. 45) Date of Patent: Apr. 13, 1993 (54) PROCESS FOR PRODUCING A HALOMETHYL PVALATE FOREIGN PATENT DOCUMENTS 75) Inventors: Naoto Yazawa, Shizuoka; Keinosuke 224.5457 3/1973 Fed. Rep. of Germany . Ishikame, Tokyo, both of Japan 3152341 6/1988 Japan ................................... 560/236 73) Assignee: hara Chemical Industry Co., Ltd., OTHER PUBLICATIONS Tokyo, Japan Chemical Abstracts, vol. 107, No. 17, Oct. 26, 1987, Andreev et al: "Chloromethyl pivalate." p. 664, Ab (21) Appl. No.: 920,529 stract No. 153938q. (22 Filed: Jul. 28, 1992 Chemical Abstracts, vol. 101, No. 23, Dec. 3, 1984, Binderup et al: "Chlorosulfates as reagents in the syn Related U.S. Application Data thesis of carboxylic acid esters . ', p. 563, Abstract 63 Continuation of Ser. No. 686,921, Apr. 18, 1991, aban No. 210 048b. doned. Primary Examiner-Arthur C. Prescott (30) Foreign Application Priority Data Attorney, Agent, or Firm-Oblon, Spivak, McClelland, Maier & Neustadt Apr. 20, 1990 JP Japan .................................. 2-104544 (51) Int. Cl* ... co7C 69/62 57 ABSTRACT 52) U.S. C. ............... A process for producing a halomethyl pivalate which 58) Field of Search ......................................... S60/236 comprises reacting an aqueous solution of a metal salt of pivalic acid with a dihalomethane selected from the (56) References Cited group consisting of bromochloromethane, chloroi U.S. PATENT DOCUMENTS odomethane and bromoiodomethane in the presence of 3,992,432 11/1976 Napier ................................. 560/236 a phase transfer catalyst. 4,421,675 12/1983 Sawicki. ... 560/236 4,699,991 0/1987 Arkles ................................. 560/236 14 Claims, No Drawings 5,202,462 1 2 According to the present invention, it is essential to PROCESS FOR PRODUCING A HALOMETHYL have a phase transfer catalyst present during the reac PVALATE tion of the aqueous solution of metal salt of pivalic acid with the dihalomethane.
    [Show full text]
  • Efficient Synthesis of Chelators for Nuclear
    (19) TZZ Z_T (11) EP 2 079 486 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: A61K 49/00 (2006.01) A61K 51/04 (2006.01) 04.04.2018 Bulletin 2018/14 A61P 9/00 (2006.01) A61P 9/10 (2006.01) A61P 9/06 (2006.01) A61P 35/00 (2006.01) (2006.01) (21) Application number: 07799253.5 A61P 35/02 (22) Date of filing: 02.07.2007 (86) International application number: PCT/US2007/072669 (87) International publication number: WO 2008/045604 (17.04.2008 Gazette 2008/16) (54) EFFICIENT SYNTHESIS OF CHELATORS FOR NUCLEAR IMAGING AND RADIOTHERAPY: COMPOSITIONS AND APPLICATIONS EFFIZIENTE SYNTHESE VON CHELATOREN FÜR NUKLEARBILDGEBUNG UND RADIOTHERAPIE: ZUSAMMENSETZUNGEN UND ANWENDUNGEN SYNTHÈSE EFFICACE DE CHÉLATEURS DESTINÉS À L’IMAGERIE NUCLÉAIRE ET À LA RADIOTHÉRAPIE : COMPOSITIONS ET APPLICATIONS (84) Designated Contracting States: (74) Representative: Dehmel, Albrecht AT BE BG CH CY CZ DE DK EE ES FI FR GB GR Dehmel & Bettenhausen HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE Patentanwälte PartmbB SI SK TR Herzogspitalstraße 11 Designated Extension States: 80331 München (DE) AL BA HR MK RS (56) References cited: (30) Priority: 05.10.2006 US 828347 P US-A1- 2005 079 133 US-A1- 2006 182 687 28.06.2007 US 770395 • G. BORMANS, B. CLEYNHENS, T. J. DE GROOT, (43) Date of publication of application: L. MORTELMANS, J.-L. MORETTI, A. 22.07.2009 Bulletin 2009/30 VERBRUGGEN: "Synthesis, radio-LC-MS analysis and biodistribution in mice of (73) Proprietors: 99mTc-NIM-BAT" JOURNAL OF LABELLED • The Board of Regents of The University of Texas COMPOUNDS AND RADIOPHARMACEUTICALS, System vol.
    [Show full text]
  • SROC Annex V
    Annex V Major Chemical Formulae and Nomenclature This annex presents the formulae and nomenclature for halogen-containing species and other species that are referred to in this report (Annex V.1). The nomenclature for refrigerants and refrigerant blends is given in Annex V.2. V.1 Substances by Groupings V.1.1 Halogen-Containing Species V.1.1.1 Inorganic Halogen-Containing Species Atomic chlorine Cl Atomic bromine Br Molecular chlorine Cl2 Molecular bromine Br2 Chlorine monoxide ClO Bromine monoxide BrO Chlorine radicals ClOx Bromine radicals BrOx Chloroperoxy radical ClOO Bromine nitrate BrONO2, BrNO3 Dichlorine peroxide (ClO dimer) (ClO)2, Cl2O2 Potassium bromide KBr Hydrogen chloride (Hydrochloric acid) HCl Inorganic chlorine Cly Antimony pentachloride SbCl5 Atomic fluorine F Molecular fluorine F2 Atomic iodine I Hydrogen fluoride (Hydrofluoric acid) HF Molecular iodine I2 Sulphur hexafluoride SF6 Nitrogen trifluoride NF3 IPCC Boek (dik).indb 467 15-08-2005 10:57:13 468 IPCC/TEAP Special Report: Safeguarding the Ozone Layer and the Global Climate System V.1.1.2 Halocarbons For each halocarbon the following information is given in columns: • Chemical compound [Number of isomers]1 (or common name) • Chemical formula • CAS number2 • Chemical name (or alternative name) V.1.1.2.1 Chlorofluorocarbons (CFCs) CFC-11 CCl3F 75-69-4 Trichlorofluoromethane CFC-12 CCl2F2 75-71-8 Dichlorodifluoromethane CFC-13 CClF3 75-72-9 Chlorotrifluoromethane CFC-113 [2] C2Cl3F3 Trichlorotrifluoroethane CCl FCClF 76-13-1 CFC-113 2 2 1,1,2-Trichloro-1,2,2-trifluoroethane
    [Show full text]
  • Addition Reactions and Photoisomerization of Cis,Trans-1,5-Cyclodecadiene
    Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1970 Addition Reactions and Photoisomerization of Cis,trans-1,5-Cyclodecadiene. Hsin-hsiong Hsieh Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Hsieh, Hsin-hsiong, "Addition Reactions and Photoisomerization of Cis,trans-1,5-Cyclodecadiene." (1970). LSU Historical Dissertations and Theses. 1859. https://digitalcommons.lsu.edu/gradschool_disstheses/1859 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. 71-6579 HSIEH, Hsin-Hsiong, 1936- ADDITION REACTIONS AND PHOTOISOMERIZATION OF CIS,TRANS-1,5-CYCLODECADIENE. The Louisiana State University and Agricultural and Mechanical College, Ph.D., 1970 Chemistry, organic University Microfilms, Inc., Ann Arbor, Michigan ADDITION REACTIONS AND PHOTOISOMERIZATION OF CIS,TRANS-1,5“CYCLODECADIENE A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy in The Department of Chemistry by Hsin-Hsiong Hsieh B.S., Taiwan Provincial Chung-Hsing University, i960 M.S., Louisiana State University,
    [Show full text]