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Annex V Major Chemical Formulae and Nomenclature This annex presents the formulae and nomenclature for halogen-containing species and other species that are referred to in this report (Annex V.1). The nomenclature for refrigerants and refrigerant blends is given in Annex V.2. V.1 Substances by Groupings V.1.1 Halogen-Containing Species V.1.1.1 Inorganic Halogen-Containing Species Atomic chlorine Cl Atomic bromine Br Molecular chlorine Cl2 Molecular bromine Br2 Chlorine monoxide ClO Bromine monoxide BrO Chlorine radicals ClOx Bromine radicals BrOx Chloroperoxy radical ClOO Bromine nitrate BrONO2, BrNO3 Dichlorine peroxide (ClO dimer) (ClO)2, Cl2O2 Potassium bromide KBr Hydrogen chloride (Hydrochloric acid) HCl Inorganic chlorine Cly Antimony pentachloride SbCl5 Atomic fluorine F Molecular fluorine F2 Atomic iodine I Hydrogen fluoride (Hydrofluoric acid) HF Molecular iodine I2 Sulphur hexafluoride SF6 Nitrogen trifluoride NF3 IPCC Boek (dik).indb 467 15-08-2005 10:57:13 468 IPCC/TEAP Special Report: Safeguarding the Ozone Layer and the Global Climate System V.1.1.2 Halocarbons For each halocarbon the following information is given in columns: • Chemical compound [Number of isomers]1 (or common name) • Chemical formula • CAS number2 • Chemical name (or alternative name) V.1.1.2.1 Chlorofluorocarbons (CFCs) CFC-11 CCl3F 75-69-4 Trichlorofluoromethane CFC-12 CCl2F2 75-71-8 Dichlorodifluoromethane CFC-13 CClF3 75-72-9 Chlorotrifluoromethane CFC-113 [2] C2Cl3F3 Trichlorotrifluoroethane CCl FCClF 76-13-1 CFC-113 2 2 1,1,2-Trichloro-1,2,2-trifluoroethane CFC-113a CCl3CF3 354-58-5 1,1,1-Trichloro-2,2,2-trifluoroethane CFC-114 [2] C2Cl2F4 Dichlorotetrafluoroethane CClF CClF 76-14-2 CFC-114 2 2 1,2-Dichloro-1,1,2,2-tetrafluoroethane CFC-114a CCl2FCF3 374-07-2 1,1-Dichloro-1,2,2,2-tetrafluoroethane CFC-115 CClF2CF3 Chloropentafluoroethane V.1.1.2.2 Hydrochlorofluorocarbons (HCFCs) HCFC-21 CHCl2F 75-43-4 Dichlorofluoromethane HCFC-22 CHClF2 75-45-6 Chlorodifluoromethane HCFC-123 [3] C2HCl2F3 Dichlorotrifluoroethane HCFC-123 CHCl2CF3 306-83-2 2,2-Dichloro-1,1,1-trifluoroethane HCFC-123a C2HCl2F3 354-23-4 1,2-Dichloro-1,1,2-trifluoroethane HCFC-123b C2HCl2F3 812-04-4 1,1-Dichloro-1,2,2-trifluoroethane HCFC-124 [2] Chlorotetrafluoroethane HCFC-124 CHClFCF3 2837-89-0 2-Chloro-1,1,1,2-tetrafluoroethane HCFC-124a C2HClF4 354-25-6 1-Chloro-1,1,2,2-tetrafluoroethane HCFC-141b CH3CCl2F 1717-00-6 1,1-Dichloro-1-fluoroethane HCFC-142b CH3CClF2 75-68-3 1-Chloro-1,1-difluoroethane HCFC-225ca CHCl2CF2CF3 422-56-0 3,3-Dichloro-1,1,1,2,2-pentafluoropropane HCFC-225cb CHClFCF2CClF2 507-55-1 1,3-Dichloro-1,1,2,2,3-pentafluoropropane 1 The number of isomers is shown between brackets for figures larger than unity. 2 The Chemical Abstracts Service (CAS) Registry Number for this substance. The CAS number is an internationally-recognised unique numeric identifier that designates only one chemical substance. The CAS is a division of the American Chemical Society. IPCC Boek (dik).indb 468 15-08-2005 10:57:13 Annex V: Major Chemical Formulae and Nomenclature 469 V.1.1.2.3 Hydrofluorocarbons (HFCs) HFC-23 CHF3 75-46-7 Trifluoromethane HFC-32 CH2F2 75-10-5 Difluoromethane (Methylene fluoride) HFC-41 CH3F 593-53-3 Fluoromethane (Methyl fluoride) HFC-125 CHF2CF3 354-33-6 Pentafluoroethane HFC-134 [2] C2H2F4 Tetrafluoroethane HFC-134 CHF2CHF2 359-35-3 1,1,2,2-Tetrafluoroethane HFC-134a CH2FCF3 811-97-2 1,1,1,2-Tetrafluoroethane HFC-143 [2] C2H3F3 Trifluoroethane HFC-143 CH2FCHF2 430-66-0 1,1,2-Trifluoroethane HFC-143a CH3CF3 420-46-2 1,1,1-Trifluoroethane HFC-152 [2] C2H4F2 Difluoroethane HFC-152 CH2FCH2F 624-72-6 1,2-Difluoroethane HFC-152a CHF2CH3 75-37-6 1,1-Difluoroethane HFC-161 CH3CH2F 353-36-6 Monofluoroethane (Ethyl fluoride) HFC-227 [2] C3HF7 Heptafluoropropane HFC-227ca CF3CF2CHF2 2252-84-8 1,1,1,2,2,3,3-Heptafluoropropane HFC-227ca CF3CHFCF3 431-89-0 1,1,1,2,3,3,3-Heptafluoropropane HFC-236 [4] C3H2F6 Hexafluoropropane HFC-236ca CHF2CF2CHF2 27070-61-7 1,1,2,2,3,3-Hexafluoropropane HFC-236cb CH2FCF2CF3 677-56-5 1,1,1,2,2,3-Hexafluoropropane HFC-236ea CHF2CHFCF3 431-63-0 1,1,1,2,3,3-Hexafluoropropane HFC-236fa CF3CH2CF3 690-39-1 1,1,1,3,3,3-Hexafluoropropane HFC-245 [5] C3H3F5 Pentafluoropropane e.g. HFC-245ce CH2FCF2CHF2 679-86-7 1,1,2,2,3-Pentafluoropropane HFC-245fa CHF2CH2CF3 460-73-1 1,1,1,3,3-Pentafluoropropane HFC-365mfc CH3CF2CH2CF3 406-58-6 1,1,1,3,3-Pentafluorobutane HFC-c-447ef c-C5H3F7 15290-77-4 Heptafluorocyclopentane V.1.1.2.4 Halons Halon-1202 CBr2F2 75-61-6 Dibromodifluoromethane Halon-1211 CBrClF2 353-59-3 Bromochlorodifluoromethane (Chlorodifluorobromomethane), R-12B1 Halon-1301 CBrF3 75-63-8 Bromotrifluoromethane, R-13B1 Halon-2402 CBrF2CBrF2 124-73-2 1,2-Dibromotetrafluoroethane (1,1,2,2-Tetrafluoro-1,2- dibromoethane, 1,2-Dibromo-1,1,2,2-tetrafluoroethane) V.1.1.2.5 Perfluorocarbons (PFCs) PFC-14 CF4 75-73-0 Tetrafluoromethane (Carbon tetrafluoride) PFC-116 C2F6 (CF3CF3) 76-16-4 Perfluoroethane (Hexafluoroethane) PFC-218 C3F8 (CF3CF2CF3) 76-19-7 Perfluoropropane (Octafluoropropane) PFC-318 or PFC-c318 c-C4F8 ( -(CF2)4- ) 115-25-3 Perfluorocyclobutane (Octafluorocyclobutane) PFC-3-1-10 C4F10 355-25-9 Perfluorobutane PFC-5-1-14 C6F14 355-42-0 Perfluorohexane PFC-6-1-16 C7F16 335-57-9 Perfluoroheptane PFC-7-1-18 C8F18 307-34-6 Perfluorooctane IPCC Boek (dik).indb 469 15-08-2005 10:57:14 470 IPCC/TEAP Special Report: Safeguarding the Ozone Layer and the Global Climate System V.1.1.2.6 Fluorinated Ethers HFE-449s1 C5H3F9O CF (CF ) OCH 163702-07-6 Methyl nonafluorobutyl ether 3 2 3 3 Perfluoroisobutyl methyl ether (CF3)2CFCF2OCH3 163702-08-7 HFE-569sf2 C6H5F9O CF3(CF2)3OCH2CH3 163702-05-4 Ethyl perfluorobutyl ether (CF3)2CFCF2OCH2CH3 163702-06-5 Ethyl perfluoroisobutyl ether HFE-347pcf2 C4H3F7O (CF3CH2OCF2CHF2) 1,1,2,2-Tetrafluoroethyl 2,2,2-trifluoroethyl ether V.1.1.2.7 Chlorocarbons Carbon tetrachloride CCl4 56-23-5 R-10, (Halon 104) Chloroform CHCl3 67-66-3 Trichloromethane, R-20 Methylene chloride CH2Cl2 75-09-2 Dichloromethane, R-30, freon 30 Methyl chloride CH3Cl 74-87-3 Chloromethane, R-40, freon 40 Trichloroethene C2HCl3 79-01-6 1,1,2-Trichloroethylene, TCE (CHCl=CCl2) Perchloroethene C2Cl4 (CCl2=CCl2) 127-18-4 Perchloroethylene, tetrachloroethene Ethyl chloride CH3CH2Cl 75-00-3 Chloroethane Methyl chloroform CH3CCl3 71-55-6 1,1,1-Trichloroethane Isopropyl chloride CH3CHClCH3 75-29-6 2-Chloropropane V.1.1.2.8 Bromocarbons Methyl bromide CH3Br 74-83-9 Bromomethane (Halon-1001) Bromoform CHBr3 75-25-2 Tribromomethane n-Propyl bromide CH3CH2CH2Br 106-94-5 1-Bromopropane, n-PB (n-C3H7Br) IPCC Boek (dik).indb 470 15-08-2005 10:57:14 Annex V: Major Chemical Formulae and Nomenclature 471 V.1.1.2.9 Other Halocarbons FK-5-1-12 C6F12O 756-13-8 Nonafluoro-4- (trifluoromethyl)-3- pentanone (CF3CF2C(O)CF(CF3)2) CH2BrCl 74-97-5 Bromochloromethane (Halon-1011) C2HF3O2 76-05-1 Trifluoroacetic acid (TFA), Perfluoric acid (CF3COOH) COF2 353-50-4 Carbonyl fluoride, Carbonic difluoride C2F4O (CF3COF) 354-34-7 Trifluoroacetyl fluoride C8HF15O2 335-67-1 Perfluorooctanoic acid (FOA), Pentadecafluorooctanoic acid CH2ClI 593-71-5 Chloroiodomethane CH2BrI 557-68-6 Bromoiodomethane CF3I 2314-97-8 Trifluoromethyl iodide, trifluoroiodomethane CF3CF2I 354-64-3 Iodopentafluoroethane COClF 353-49-1 Chlorofluorocarbonyl CF3COCl 354-32-5 Trifluoroacetyl chloride SF5CF3 373-80-8 Trifluoromethylsulphur pentafluoride V.1.2 Other Species V.1.2.1 Inorganic Species Carbon atom C Carbon monoxide CO Carbon dioxide (R-744) CO2 Atomic oxygen O Sodium bicarbonate NaHCO3 Atomic oxygen (first excited state) O(1D) Molecular oxygen (R-732) O2 Ozone O3 1 Odd oxygen (O, O( D), O3) Ox Atomic nitrogen N or oxidant (O3 + NO2) Molecular nitrogen (R-728) N2 Nitrous oxide (R-744A) N2O Nitric oxide NO Nitrogen dioxide NO2 Atomic hydrogen H Nitrogen trioxide, nitrate radical NO3 Molecular hydrogen (R-702) H2 Dinitrogen pentoxide N2O5 Hydroxyl radical OH Nitrogen oxides (NO + NO2) NOx Hydroperoxyl radical HO2 Total reactive nitrogen (usually includes NOy Water (R-718) H2O NO, NO2, NO3, N2O5, ClONO2, HNO4, Hydrogen peroxide H2O2 HNO3) Odd hydrogen (H, OH, HO2, H2O2) HOx Amidogen radical NH2 Ammonia (R-717) NH3 Ammonium NH4 Ammonium sulfate (NH4)2SO4 Atomic sulphur S Ammonium nitrate NH4NO3 Sulphur dioxide (R-764) SO2 Ammonium phosphate (NH4)H2PO4 Sulfate SO4 Nitric acid HNO3 Sulphuric acid H2SO4 Hydrogen cyanide HCN Hydrogen sulfide H2S Sulphur oxides (SO + SO2 + SO3) SOx Helium (R-704) He Argon (R-740) Ar Radon Rn IPCC Boek (dik).indb 471 15-08-2005 10:57:15 472 IPCC/TEAP Special Report: Safeguarding the Ozone Layer and the Global Climate System V.1.2.2 Non-Halogenated Hydrocarbons and Other Organic Species Common or Industrial Designation Formula CAS-number Other Names Methane CH4 74-82-8 R-50 Ethane C2H6 (CH3CH3) 74-84-0 R-170 Propane C3H8 (CH3CH2CH3) 74-98-6 R-290 Butane C4H10 (CH3CH2CH2CH3) 106-97-8 R-600, n-Butane Isobutane C4H10 ((CH3)2CHCH3) 75-28-5 R-600a, i-Butane, 2-Methylpropane Pentane C5H12 (CH3(CH2)3CH3) 109-66-0 R-601, n-Pentane Isopentane C5H12 ((CH3)2CHCH2CH3) 78-78-4 R-601a, i-Pentane, 2-Methylbutane Methyl ether C2H6O (CH3OCH3) 115-10-6 R-E170, Dimethyl ether Cyclopropane c-C3H6 ( -(CH2)3- ) 75-19-4 C-270 Cyclopentane c-C5H10 ( -(CH2)5- ) 287-92-3 Ethene C2H4 (CH2=CH2) 74-85-1 R-1150, Ethylene Propene C3H6 (CH3CH=CH2) 115-07-1 R-1270, Propylene Benzene C6H6 71-43-2 Toluene C7H8 108-88-3 Methylbenzine Xylene C8H10 several isomers Dimethylbenzene Trimethylbenzene C9H12 several isomers Isoprene C5H8 78-79-5 2-Methyl-1,3-butadiene Ethyl ether C4H10O 60-29-7 R-610, Diethyl ether (CH3CH2OCH2CH3) n-Octanol C8H18O (CH3(CH2)7OH) 111-87-5 1-Octanol, 1-Octyl alcohol Methyl formate C2H4O2
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    1 SYNTHESIS OF BROMOCHLOROMETHANE USING PHASE TRANSFER CATALYSIS By LANCELOT LUCRETIUS BROOKS Baccalaureus Scientiae Honores-Chemistry, Nelson Mandela Metropolitan University A dissertation submitted in fulfillment of the requirements for the Masters Degree in Chemistry In the Faculty of Science at the NELSON MANDELA METROPOLITAN UNIVERSITY Nov. 2011 Promoter : Dr G. Dugmore Co-Promoter : Prof B. Zeelie 2 DECLARATION I, Lancelot Brooks, hereby declare that the above-mentioned treatise is my own work and that it has not previously been submitted for assessment to another University, or for another qualification. ……………………………….. ……………………….. Mr. L.L. Brooks Date 3 ACKNOWLEDGEMENTS To my promoters Dr. Gary Dugmore, and Prof. Ben Zeelie for their invaluable input, help and guidance. To NRF and NMMU for financial assistance To my parents and brothers for their love and support To Peter, Batsho, Unati, and friends in NMMU chemistry research laboratory, thank you guys. To my dearest fiancée, Natasha, a very special thank you for always being there and supporting me. Love you angel. “And we know that all things work together for good to those who love God, to those who are called according to His purpose” -Romans 8:28. 4 TABLE OF CONTENTS DECLARATION……………………………………………………………………. 2 ACKNOWLEDGEMENTS……………………………………………………………. 3 TABLE OF CONTENTS………………………………………………………………. 4 LIST OF FIGURES…………………………………………………………………….. 8 LIST OF TABLES……………………………………………………………………… 9 LIST OF EQUATIONS………………………………………………………………… 11 SUMMARY……………………………………………………………………………… 12 CHAPTER 1…………………………………………………………………………….. 14 INTRODUCTION………………………………………………………………………. 14 1.1. Technology of leather production……………………………………………….. 14 1.2. Synthesis of TCMTB……………………………………………………………… 17 1.3. Bromine……………………………………………………………………………. 20 1.3.1. Overview……………………………………………………………. 20 1.3.2. Applications of bromine compounds…………..…………………. 22 1.3.2.1. Photography……………………………………………… 22 1.3.2.2.
  • Supplement to the Role of Internal Standards and Their Interaction With

    Supplement to the Role of Internal Standards and Their Interaction With

    Supplement to: Hiatt, M., “The Role of Internal Standards and their Interaction with Soils Impact Accuracy of Volatile Organics Determinations,” Int. J. of Environ. Anal. Chem., 2010 90:8 591-604. Please note that this is a non-copyrighted web version of supplemental information belonging to the above-cited journal article. There are formatting and page-numbering differences between this web version and the actual published version. There are also minor content differences. This version can be accessed at: http://www.epa.gov/nerlesd1/chemistry/vacuum/reference/pubs.htm This publication is also available from Informaworld: http://www.informaworld.com/smpp/content~db=all~content=a921288588 Web version, 27 April 2010 1 Supplement to: The Role of Internal Standards and their Interaction with Soils Impact Accuracy of Volatile Organics Determinations Michael H. Hiatt U.S. Environmental Protection Agency, National Exposure Research Laboratory Environmental Sciences Division. P.O. Box 93478, Las Vegas, Nevada 89193-3478 Phone: 702 798 2381. Fax: 702 798 2142. E-mail: [email protected]. Supplementary Information Data that was too detailed for “The Role of Internal Standards and their Interaction with Soils Impact Accuracy of Volatile Organics Determinations” is presented as supplemental information. This information includes each analyte by matrix and includes the accuracy evaluation, analyte results impacted by criteria, and results from varying spike equilibration times. The list of internal standards and their chemical properties are presented in Table S1 while the surrogates are listed in Table S2. Tables of results by analyte are included as Tables S3-8. These tables include the data by matrix and combined.
  • Finding Refrigerant Leaks with the Chempro100i

    Finding Refrigerant Leaks with the Chempro100i

    Application Note: 108 Finding Refrigerant Leaks with the ChemPro100i The ChemPro100i is a great sniffer for halocarbon refrigerants, often generically referred to as “Freon” because of its multiple sensors and broad sniffing capability. As refrigerant sniffers are only carried by a small subset of first responders, the ChemPro100i can fill the role for those that don’t have a refrigerant sniffer. As a bonus, if someone suspects that it may be a refrigerant leak, and it turns out to be something else, the wide range of detectable gases and vapors seen by the ChemPro100i means that it will most likely find the unexpected gas/vapor too. The ChemPro100i’s Sensors The ChemPro100i uses a suite of seven sensors including an aspirated Ion Mobility Spectroscopy (IMS), five metal oxide sensors and a field effect sensor to detect, characterize, and even identify, some gases and vapors. Using this suite of sensors, the ChemPro100i can find halocarbon refrigerant leaks using its “Trend” or “sniffer” screen. As one gets closer to the refrigerant leak, the trend line will Using other Sniffers for increase. This is a non-quantifiable reading Refrigerants that does not directly correlate with parts per Most dedicated refrigerant detectors use a million (ppm), but the fast response of the Metal Oxide Sensor (MOS) that is doped to ChemPro100i to refrigerants provides one with be relatively specific to the halogenated the means of quickly finding a refrigerant leak. hydrocarbons (halogens) that are the hallmark of most refrigerants. MOS sensors Increase in the Trend line leads you to the leak are non-linear and not suitable for quantification of refrigerants, but they provide sensitive and fast response to halocarbon refrigerants.
  • UV Spectroscopic Determination of the Chlorine Monoxide (Clo)/Chlorine Peroxide (Cloocl) Thermal Equilibrium Constant

    UV Spectroscopic Determination of the Chlorine Monoxide (Clo)/Chlorine Peroxide (Cloocl) Thermal Equilibrium Constant

    Atmos. Chem. Phys., 19, 6205–6215, 2019 https://doi.org/10.5194/acp-19-6205-2019 © Author(s) 2019. This work is distributed under the Creative Commons Attribution 4.0 License. UV spectroscopic determination of the chlorine monoxide (ClO) = chlorine peroxide (ClOOCl) thermal equilibrium constant J. Eric Klobas1,2 and David M. Wilmouth1,2 1Harvard John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA 2Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA Correspondence: J. Eric Klobas ([email protected]) Received: 22 October 2018 – Discussion started: 29 October 2018 Revised: 19 April 2019 – Accepted: 24 April 2019 – Published: 10 May 2019 Abstract. The thermal equilibrium constant between the net V 2O3 ! 3O2 (R5) chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was determined as a function of tem- Within this cycle, the equilibrium governing the partitioning perature between 228 and 301 K in a discharge flow ap- of ClO and ClOOCl in Reaction (R1) is defined as follows. paratus using broadband UV absorption spectroscopy. A [ClOOCl] third-law fit of the equilibrium values determined from Keq D (1) [ClO]2 the experimental data provides the expression Keq D 2:16 × 10−27e.8527±35 K=T / cm3 molecule−1 (1σ uncertainty). A This thermal equilibrium is a key parameter that deter- second-law analysis of the data is in good agreement. From mines the nighttime partitioning of active chlorine in the the slope of the van’t Hoff plot in the third-law analy- winter–spring polar vortex.