Bedrock Geology of Hardin County, Illinois F

Total Page:16

File Type:pdf, Size:1020Kb

Bedrock Geology of Hardin County, Illinois F STATEMAP Hardin Co-BG Bedrock Geology of Hardin County, Illinois F. Brett Denny and Mary J. Seid 2014 Prairie Research Institute ILLINOIS STATE GEOLOGICAL SURVEY 615 East Peabody Drive Champaign, Illinois 61820-6918 (217) 244-2414 http://www.isgs.illinois.edu © 2014 University of Illinois Board of Trustees. All rights reserved. For permission information, contact the Illinois State Geological Survey. 1. Introduction Oil and gas test holes, water well descriptions, mineral This report accompanies a 1:48,000 scale map of Hardin exploration borings, and stratigraphic core holes, core County, Illinois. Hardin County is situated in southeastern descriptions, sample studies, electric logs, and drillers’ logs Illinois, bordered on the west by Pope County, on the north supplemented outcrop data. Historical field notes from other by Saline and Gallatin Counties, and on the south and east ISGS geologists provided valuable information and aided by the Ohio River (Fig. 1). Fieldwork was conducted in geologic interpretations. The bedrock geology of Hardin 2013 and 2014. Outcrops were common along steep slopes County was previously studied by Worthen and Engelmann but were concealed by soil cover in the sinkhole plain in (1866), Weller et al. (1920), Baxter et al. (1963), Baxter the southeastern portion of the map area. Faults were rarely and Desborough (1965), and Baxter et al. (1967). Reports exposed and often inferred by interpolating the locations of on the igneous rocks were previously undertaken by Brad- fluorite mines. The oldest rocks of Devonian age are exposed bury and Baxter (1992) and Moorehead (2013). Reports on at Hicks Dome, in the northwestern part of the county. Mis- the Illinois-Kentucky Fluorite District and its mines and sissippian rocks crop out in an oval-shaped belt around the minerals were completed by Bastin (1931), Weller, Grogan central uplift. Pennsylvanian rocks occur in the northern and Tippie (1952), Heyl and Brock (1961), Brecke (1962), and eastern parts of the county, as well as in the Rock Creek Hutcheson (1973), Heyl et al. (1974), and Goldstein (1997). Graben. Permian igneous intrusions occur as dikes or narrow The new Hardin County geologic map utilizes data from sub-vertical “pipe-like” intrusions and in thin layered sills. these previous reports and incorporates newly acquired data These rocks are ultramafic lamprophyres, autolithic breccias, based on field work from 2007 to 2014 into an updated map and diatremes and are present throughout Hardin County. and accompanying report. The igneous rocks trend north-northwest and are also clus- tered around the periphery of Hicks Dome. All of the geologic data was compiled using ArcGIS. The geodatabase includes additional information not depicted on the geologic map, including brief details of the mineral prospects and mines. N 3. Stratigraphy The bedrock exposed in the quadrangle ranges from Lower and Middle Devonian cherty limestone to Middle Pennsylva- ILLINOIS nian sandstone and shale. A thin cap of Quaternary alluvium and loess covers parts of the quadrangle. Cahokia alluvium was mapped in well-developed stream valleys and terraces along the Ohio River terraces, but loess was not mapped. Lithologic descriptions of each mapping unit starting with Hardin the oldest Devonian formation is described in the following County section. Devonian The Clear Creek Chert, Grand Tower Limestone, and St. Figure 1 Project location map. Laurent Formations (Du) are combined together and are not differentiated since identification of individual forma- 2. Background and Methods tions is difficult in their outcrop area at the center of Hicks Dome. They all consist of cherty limestone and dolostone The Hardin County geologic map utilizes data from eight that have been silicified and weathered to a cherty white re- 7.5-minute quadrangle maps: Shetlerville, Herod, Rosiclare, siduum in a dark reddish brown clayey soil. Their combined Karbers Ridge, Cave-in-Rock, Saline Mines, Repton, and thickness is estimated to be over 400 feet thick. Dekoven. Recent 1:24,000 scale maps of each of these quad- rangles have been completed within the past decade through The Clear Creek Chert is composed of cherty limestone and a joint initiative between the ISGS and USGS (Denny et al. dolostone. The chert is light gray to white, and the limestone 2008a, 2010, 2011b, 2013; Denny and Counts 2009; Seid has been altered to a siliceous porous rock with clasts con- et al. 2013a, 2013b; Seid and Denny 2014). These 1:24,000 taining the brachiopods Amphigenia curta and Eodevonaria scale maps were combined, and the scale was reduced to arcuata. The underlying Grassy Knob Chert may be pres- 1:48,000. Outcrop studies were conducted along quadrangle ent since the Clear Creek and Grassy Knob are difficult to boundaries to rectify interpretations from different authors. separate, although the Grassy Knob does not contain many Thin map units were combined, and closely spaced faults brachiopod molds and contains very few bioclasts. The were omitted for clarity. 1 Backbone limestone is present between the Grassy Knob and Figure 2 Clear Creek Chert in the northern portions of Illinois which FORMATION Classification allows the Grassy Knob and Clear Creek to be differentiated. of the Devoni- SERIES Member or Bed The top of the Clear Creek Chert marks the top the Lower SYSTEM an and Lower Mississip- Devonian in this area of the state. The thickness of the Clear Fort Payne pian in Hardin Creek is estimated to be greater than 200 feet. The Grand County. Tower Limestone is dominated by light gray lithographic and siliceous limestone and dolostone. Workers in other Springville parts of the state have reported a basal sandstone which is almeyeran V Shale differentiated as the Dutch Creek Sandstone and a bentonite bed called the Tioga Bentonite which is at the top of the unit. Chouteau The Dutch Creek is less than 20 feet thick and the Tioga, if Mississippian Limestone present, is less than 6 inches thick (Willman et al. 1975). The base of the Grand Tower marks the base of the Middle Devo- Hannibal Shale nian in this region of Illinois. The grand Tower is estimated mbr. Kinderhookian to be 120 to 200 feet thick in this area. The St. Laurent Formation is composed of cherty and siliceous limestone, Saverton Shale dolostone, and shale. The unit was originally limestone but mbr. has been mostly silicified to a cherty or siliceous residuum Grassy Creek at the surface. Subsurface data indicate that the unit is a r Shale mbr. cherty argillaceous limestone. The St. Laurent is equivalent Albany Shale Uppe to the Lingle and Alto Formations, but due to stratigraphic Sweetland Creek complexities and miscorrelation Weller (1944) recom- New Shale mbr. mended combining the units into the St. Laurent Formation. Nelson et al. (1995) combined the Alto and Lingle into a Blocher Sh. mbr. single formation and adopted the St. Laurent nomenclature in southwestern Illinois. A diagnostic fossil for the lower St. St. Laurent Devonian Laurent is microcyclus discus which is a button coral (Nel- Formation son et al. 1995). Few exposures of this unit are available, but e Tioga Bentonite a two holes drilled by the ISGS on the Doug Deal property bed (0-0.6 ft.) (30-T11S-R8E) probably encountered this unit. The St. Lau- Middl Grand Tower rent is estimated to be 70 to 110 feet thick in this area. Limestone Dutch Creek SS. Devonian-Mississippian mbr. (0-30 ft.) The boundary between the Devonian-Mississippian is dif- r ficult to determine in this region but exists within the New Clear Creek Chert Albany Shale (Fig. 2). Collinson (1961) utilized conodonts Lowe to redefine the boundary to include the upper part of the New Albany Shale Group and stated that the boundary was gener- of the New Albany Shale and its contact with the Chouteau ally conformable except along the flanks of the Ozark uplift. Limestone can also be observed in Hicks Branch on the southwest side of Hicks Dome, although the Chouteau is The New Albany Shale and Chouteau Limestone (MDcn) only a few feet thick in this exposure. were combined and together attain a thickness of about 320 to 420 feet. The New Albany Shale was considered a group The New Albany Shale is divided into several members, by Willman et al. (1975) and there are probably marked from base to top: the Blocher Shale member, Sweetland contrasts between the individual formations that Willman Creek Shale member, Grassy Creek Shale member, Saver- cites. Regardless, these formations are very difficult to sepa- ton Shale member, and the Hannibal Shale member. The rate while mapping and given the similarities between these shales are black to greenish and bluish-gray, fissile, and may units, ranking them at group level is questionable. Nelson et be either silty or calcareous. Some of the more calcareous al. (1995) also concluded that group status was improper and layers may grade into argillaceous limestones, but these are lowered the group to formation status. We have followed the thin and rare. The unit is dominantly black fissile shale with nomenclature of Nelson et al. (1995), lowering the status of pyrite and few macrofossils. The Blocher is a black fissile the New Albany from group to formation. These units are shale that may include some gray silty shale at the top. The easily eroded, forming a valley of low topographic relief Blocher may be difficult to distinguish from the remaining encircling Hicks Dome. The New Albany Shale crops out in New Albany Shale. The Sweetland Creek Shale is com- active stream cuts along Goose Creek and is well exposed posed of gray and green fissile shale. Above the Sweetland along Hicks Branch Creek southeast of Hicks Dome. The top Creek is a dark gray to black fissile shale called the Grassy 2 Creek.
Recommended publications
  • Barite (Barium)
    Barite (Barium) Chapter D of Critical Mineral Resources of the United States—Economic and Environmental Geology and Prospects for Future Supply Professional Paper 1802–D U.S. Department of the Interior U.S. Geological Survey Periodic Table of Elements 1A 8A 1 2 hydrogen helium 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 lithium beryllium boron carbon nitrogen oxygen fluorine neon 6.94 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 13 14 15 16 17 18 sodium magnesium aluminum silicon phosphorus sulfur chlorine argon 22.99 24.31 3B 4B 5B 6B 7B 8B 11B 12B 26.98 28.09 30.97 32.06 35.45 39.95 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.64 74.92 78.96 79.90 83.79 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon 85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 cesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon 132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.5 204.4 207.2 209.0 (209) (210)(222) 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116
    [Show full text]
  • Infrare D Transmission Spectra of Carbonate Minerals
    Infrare d Transmission Spectra of Carbonate Mineral s THE NATURAL HISTORY MUSEUM Infrare d Transmission Spectra of Carbonate Mineral s G. C. Jones Department of Mineralogy The Natural History Museum London, UK and B. Jackson Department of Geology Royal Museum of Scotland Edinburgh, UK A collaborative project of The Natural History Museum and National Museums of Scotland E3 SPRINGER-SCIENCE+BUSINESS MEDIA, B.V. Firs t editio n 1 993 © 1993 Springer Science+Business Media Dordrecht Originally published by Chapman & Hall in 1993 Softcover reprint of the hardcover 1st edition 1993 Typese t at the Natura l Histor y Museu m ISBN 978-94-010-4940-5 ISBN 978-94-011-2120-0 (eBook) DOI 10.1007/978-94-011-2120-0 Apar t fro m any fair dealin g for the purpose s of researc h or privat e study , or criticis m or review , as permitte d unde r the UK Copyrigh t Design s and Patent s Act , 1988, thi s publicatio n may not be reproduced , stored , or transmitted , in any for m or by any means , withou t the prio r permissio n in writin g of the publishers , or in the case of reprographi c reproductio n onl y in accordanc e wit h the term s of the licence s issue d by the Copyrigh t Licensin g Agenc y in the UK, or in accordanc e wit h the term s of licence s issue d by the appropriat e Reproductio n Right s Organizatio n outsid e the UK. Enquirie s concernin g reproductio n outsid e the term s state d here shoul d be sent to the publisher s at the Londo n addres s printe d on thi s page.
    [Show full text]
  • Thirty-Fourth List of New Mineral Names
    MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given.
    [Show full text]
  • Daqingshanite-(Ce) (Sr, Ca, Ba)3(Ce, La)(PO4)(CO3)3−X(OH, F)X C 2001-2005 Mineral Data Publishing, Version 1
    Daqingshanite-(Ce) (Sr, Ca, Ba)3(Ce, La)(PO4)(CO3)3−x(OH, F)x c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal. Point Group: 3m (probable). As subhedral to rounded platy crystals, may be crudely rhombohedral, to 3 mm, in aggregates. Twinning: Complex polysynthetic twinning observed in some material. Physical Properties: Cleavage: Perfect on {1011}. Fracture: Conchoidal. Hardness = n.d. VHN = 335 (20 g load). D(meas.) = 3.81 D(calc.) = 3.71 Optical Properties: Semitransparent. Color: Pale yellow to nearly white; colorless in thin section. Streak: White. Luster: Vitreous to greasy. Optical Class: Uniaxial (–). ω = 1.708 = 1.609 Cell Data: Space Group: R3m, R3m, or R32. a = 10.058–10.073 c = 9.225–9.234 Z = 3 X-ray Powder Pattern: Bayan Obo deposit, China. 3.16 (10), 2.52 (7), 3.95 (6), 2.040 (6), 1.941 (6), 2.110 (5), 1.895 (4) Chemistry: (1) (2) (1) (2) (1) (2) P2O5 11.73 10.50 Fe2O3 0.21 K2O 0.03 CO2 16.19 n.d. MnO 0.02 F 0.80 0.29 ThO2 0.04 < 0.22 MgO 0.72 < 0.12 Cl 0.10 + Al2O3 0.18 < 0.12 CaO 6.17 0.94 H2O 0.68 n.d. La2O3 7.88 10.22 SrO 26.10 41.82 −O=F2 0.34 Ce2O3 10.16 12.24 BaO 15.98 4.57 Total [99.376] RE2O3 2.696 < 3.36 Na2O 0.13 < 0.16 (1) Bayan Obo deposit, China; CO2 and H2O by gas chromatography, original total given as 99.20%; RE2O3 =Pr6O11 0.70%, Nd2O3 1.59%, Sm2O3 0.106%, Eu2O3 0.02%, Gd2O3 0.12%, Tb4O7 0.05%, Dy2O3 0.03%, Ho2O3 0.03%, Er2O3 0.01%, Tm2O3 0.01%, Yb2O3 0.02%, Lu2O3 0.01%; corresponds to (Sr1.52Ca0.67Ba0.63Mg0.11Na0.03)Σ=2.96(Ce0.37La0.29RE0.10Al0.02 3+ Fe0.02)Σ=0.80(PO4)1.00(CO3)2.23[(OH)0.46F0.26]Σ=0.72.
    [Show full text]
  • NOTICE New Mineratr Names Has Been Prepared by Michael
    NOTICE New Mineratr Names has been prepared by Michael Fleischer for many years with extraordinary coverage and critical evaluation, and remains one of the most important sections ol The Americon Mineral,ogist. Dr. Fleischer con- tinues to find the task enjoyable but increasingly burdensome. This is a call for volunteers to assist him in combing and reviewing the literature for clescrip- tions of new minerals and new mineral data Mineralogists interested, please contact Dr. M. Fleischer, U, S. Geological Survey, Washington 25, D. C., and specify the language(s) and journals you can ancl are willing to cover. Es- pecially helpful would be the services of three good mineralogists to cover Minerologicol Magazine, Bulletin Soci.6t6 Franqaise Minlralogie, and Neues Jahrbuch J* Minerologie etc., Monatshefte NEW MINERAL NAMES Farringtonite E. R' DurnnsNa aNo s. K. Rov. A new phosphate mineral from the springwater pallasite: Geocltim.et Cosmocltim.Acta,24, 198 205 (1961). The mineral was found in the springn'ater pallasite, from near Springwater, Sas- katchewan. rt occurs as colorless to wax-white to yellon' material peripheral to olivine nodules. The meteorite also contains metallic iron (kamacite) ancl troilite. Spectrographic analyses were made on two 25 mg. samples; the first rn'ascleaned magnetically, the second by gravity separation in a centrifuge as we1l. These gave: pror 37.6+0.6,49.7 + 1.0;MgO 49.2+O.2,4t.6I1.3; SiO, 11.1+0.2,2.9 +0.1; Fe 5.4+0.1,3.7 ,,quite +0.2ok. The final content of metallic iron in the samples was negligible,,; the Fe reported must be present as FeO or FezO: or both.
    [Show full text]
  • Fluid Inclusions in Fibrous and Octahedrally-Grown Diamonds
    FLUID INCLUSIONS IN FIBROUS AND OCTAHEDRALLY-GROWN DIAMONDS by Evan Mathew Smith A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY in The Faculty of Graduate and Postdoctoral Studies (Geological Sciences) THE UNIVERSITY OF BRITISH COLUMBIA (Vancouver) March 2014 © Evan Mathew Smith, 2014 Abstract My thesis puts forth new models for diamond formation that explain the difference between octahedral and fibrous diamond growth, as well as the difference between octahedral diamond growth in the lithospheric and the sublithospheric mantle. Diamond growth in the mantle involves reactions between carbon-bearing fluid and the host rocks it infiltrates. This fluid is sometimes included in diamond. Fluids in dendritically-grown, fibrous diamonds from Wawa, Superior craton, were analysed in a novel way, using transmission X-ray diffraction. The technique allows bulk analysis of daughter minerals within fluid inclusions. The mineralogy, major and trace elements, Sr isotopes, volatiles, and nitrogen characteristics of the hydrous saline–high-Mg carbonatitic fluid in these Archean diamonds strongly resemble those of Phanerozoic fibrous diamonds. This implies that some mantle processes, including the formation of fibrous diamonds, can be extended unvaryingly back to 2.7 Ga. Fluid equilibrated with octahedrally-grown diamonds from the Siberian, Kaapvaal, and Congo cratons is trapped in healed fractures in the diamonds. They contain anhydrous CO2–N2 fluid inclusions with 40±4 mol% N2 and inclusions of former silicate melt that had an original N2 content of ~0.1 wt%, as shown by Raman, electron microprobe, and microthermometry analyses. The liberation of N2 from the convecting mantle is proposed to be controlled by increasing oxygen fugacity that destabilizes host phases.
    [Show full text]
  • New Mineral Names
    NEW MINERAL NAMES Mrcrrlrr Flrrscsnn Sibirskite N. N. V.rsrr,rovA, A new calcium borate, sibirskite. Zapishi Vses. Mineral'og. Obshch,9l, 4554& (1962) (in Russian). Analysis of a mixture of the mineral with calcite, a chlorite, and a little pyrite gave 5iO27.72, TiO, 0.03, L12O82.43,FeO 1.01, MgO 10.06, MnO 0.29, CaO 41.78, NarO 0.04' K2O none, CO216.72,B2O3 13.51, C 0.12,HrO- 0.36,H2O+ 6.38,S 0.48:100.93-(0: S) 0.24:100.697o. Separate analyses were made of the material soluble in acetic acid (calcite *sibirskite) and the insoluble. Recalculation indicates CaO:BzOa:HzO:2.07:1:1.02 or CauBzOr(OH)z or CaHBOa. The mineral is insoluble in boiling HzO, soluble in cold acetic or hydrochloric acid. DTA curves showed strong endothermic peaks at 870" (due to calcite) and at 430o, and a weak endothermic peak at 670" (due to chlorite). X-ray powder data by G. A. Sidorenko (19 lines) are givenl the strongest lines are 2.93 (5),2.58 (5), 1.878 (3). (The data are inadequate for comparison with the r-ray clata of Lehmann etr ol'., Zeits. onorg. allgem. Ckem. 2968, 202-203 (1958) on synthetic CaHBOa.MF). Sibirskite occurs as diamond-shaped forms of size 1.0-1.5 mm or as aggregates of irregular grains colored dark gray by chlorite. The rhombs show angles of 110" and 70". Measurements on the Federov stage show that the symmetry approximates orthorhombic. Biaxial (-); indices measured by Yu.
    [Show full text]
  • (1Eso). the Barite Rock Is Fine-Grained and Has a Gray Color Owing to Varying Amounts of Interspersedshaly Matter
    THE AMERICAN MINERALOGIST, VOL.47, MAY_JUNE, 1962 BENSTONITE, CazBa6(COr)tr,A NEW MINERAL FROM THE BARITE DEPOSIT IN HOT SPRING COUNTY, ARKANSAS Fnrrrnrcs Lrrruenw,l Mineralogische Anstohen der Uniaersildl, Gdttingen,Germany. Ansrnlcr Benstonite, (Ca,Mg,Mn)r(Ba,Sr)6(CO)s, was found at the barite mine in Hot Spring County, Arkansas, where it occurs in veins within the barite body associated with milky quartz, barite and calcite. It forms white cleavable masses which show cleavage faces up to 1 cm across.H:3-4; G 3.596 (meas.), 3.648 (calc.); good rhombohedral cleavagewith about the same angles as calcite. Uniaxial negative with o:1.690s and e:1.527. Single crystal r-ray studies revealed a rhombohedral lattice with the following characteristics: possible space groups RB or R3, the most probable being R3 because of -the symmetry of the CO3-groupand the available equipoints; hexagonal, o:18.28*0.01 A, c:8.67IO.02; rhombohedral, a,t:10.944, a:113.3o; volume 2509 Aa ftex.;, cell contents:3 [CazBao (COa)ul in the hexagonal unit. The index of the cleavageface is [3142] or [4132]. The hexagonal indices of the strongest r-ray reflections satisfy the relation Trzaftzlhk :13n, and they may be transformed to the indices of calcite reflections. The resulting "calcite-ceil" of benstonite has o!:a/t4i3:5.0? A, C':2c:17.34 A; volume 386.0 A3; calcite: a:4.990 A; c:17.06 A; volume 367.80 A3. Benstonite therefore has a structure which may be described as a superstructure derived from the calcite configuration.
    [Show full text]
  • Barytocalcite Baca(CO3)2 C 2001-2005 Mineral Data Publishing, Version 1
    Barytocalcite BaCa(CO3)2 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as elongated crystals, short to long prismatic and striated parallel [101], to 5 cm, or equant, showing large {100}, {111}, {131}, {210}, minor {001},{110}, {101}; may be massive, cleavable. Physical Properties: Cleavage: On {210}, perfect; on {001}, imperfect. Fracture: Uneven to subconchoidal. Hardness = 3.5–4 D(meas.) = 3.66–3.71 D(calc.) = 3.72 Pale yellowish to red fluorescence under SW and LW UV. Optical Properties: Transparent to translucent. Color: Colorless to white, pale gray, bright to pale green, pale yellow; colorless in transmitted light. Luster: Vitreous to resinous. Optical Class: Biaxial (–). Orientation: Z = b; X ∧ c =64◦; Y ∧ c = –26◦. Dispersion: r> v, weak. α = 1.525 β = 1.684 γ = 1.686 2V(meas.) = 15◦ Cell Data: Space Group: P 21/m. a = 8.092(1) b = 5.2344(6) c = 6.544(1) β = 106.05(1)◦ Z=2 X-ray Powder Pattern: Alston, England. (ICDD 15-285). 3.125 (100), 3.140 (90), 4.018 (40), 4.345 (25), 2.157 (25), 2.512 (20), 2.379 (20) Chemistry: (1) (2) CO2 29.95 29.59 MgO 0.50 CaO 18.75 18.85 SrO 1.81 BaO 48.92 51.56 Total 99.93 100.00 (1) Vuoriyarvi massif, Russia; corresponds to Ba0.92Ca1.03Sr0.08Mg0.03(CO3)2.00. (2) BaCa(CO3)2. Polymorphism & Series: Trimorphous with alstonite and paralstonite. Occurrence: A relatively uncommon accessory mineral in metallic veins, formed by reaction of hydrothermal fluids with limestone; however it may be the dominant barium-bearing species; rarely in carbonatites and Alpine veins.
    [Show full text]
  • EPR, UV-Visible, and Near-Infrared Spectroscopic Characterization of Dolomite
    Hindawi Publishing Corporation Advances in Condensed Matter Physics Volume 2008, Article ID 175862, 8 pages doi:10.1155/2008/175862 Research Article EPR, UV-Visible, and Near-Infrared Spectroscopic Characterization of Dolomite S. Lakshmi Reddy,1 R. L. Frost,2 G. Sowjanya,1 N. C. G. Reddy,3 G. Siva Reddy,3 andB.J.Reddy2 1 Department of Physics, S.V.D. College, Kadapa 516003, India 2 Inorganic Materials Research Program, Queensland University of Technology, 2 George Street, Brisbane, GPO Box 2434, Queensland 4001, Australia 3 Department of Chemistry, Yogi Vemana University, Kadapa 516003, India Correspondence should be addressed to R. L. Frost, [email protected] Received 17 June 2008; Accepted 21 October 2008 Recommended by David Huber Dolomite mineral samples having white and light green colors of Indian origin have been characterized by EPR, optical, and NIR spectroscopy. The optical spectrum exhibits a number of electronic bands due to presence of Fe(III) ions in the mineral. From EPR studies, the parameters of g for Fe(III) and g, A,andD for Mn(II) are evaluated and the data confirm that the ions are in distorted octahedron. Optical absorption studies reveal that Fe(III) is in distorted octahedron. The bands in NIR spectra are due to the overtones and combinations of water molecules. Thus EPR and optical absorption spectral studies have proven useful for the study of the solid state chemistry of dolomite. Copyright © 2008 S. Lakshmi Reddy et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
    [Show full text]
  • Alstonite Baca(CO3)2 C 2001-2005 Mineral Data Publishing, Version 1
    Alstonite BaCa(CO3)2 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Triclinic, pseudo-orthorhombic. Point Group: 1or1. Steep pseudohexagonal dipyramids bounded by pseudohexagonal prisms, to 6 mm, striated strongly ⊥ pseudohexagonal [0001] and commonly exhibiting a medial re-entrant k pseudohexagonal [0001]. Twinning: Common on pseudo-orthorhombic {110} and {310}, forming pseudohexagonal groups. Physical Properties: Cleavage: On pseudo-orthorhombic {110}, imperfect. Fracture: Uneven. Hardness = 4–4.5 D(meas.) = 3.707(4) D(calc.) = 3.69 Fluoresces yellow under SW and LW UV. Optical Properties: Transparent to translucent. Color: Colorless to snow-white; also pale gray, pale cream, pink to pale rose-red, which may fade on exposure to light; colorless in transmitted light, showing six or twelve domains. Streak: White. Luster: Vitreous. Optical Class: Biaxial (–). Orientation: X = c; Y = a; Z = b. Dispersion: r> v,weak. α = 1.526 β = 1.671 γ = 1.672 2V(meas.) = 6◦ Cell Data: Space Group: C1orC1. a = 30.14 b = 17.40 c = 6.12 α =90◦ β =90◦ γ =90◦ Z=24 X-ray Powder Pattern: Alston, England; essentially identical to paralstonite. 3.55 (100), 2.507 (35), 2.050 (23), 1.941 (19), 1.846 (15), 2.835 (10), 1.589 (8) Chemistry: (1) (2) CO2 29.41 29.59 CaO 17.60 18.85 SrO 4.25 BaO 48.54 51.56 Total 99.80 100.00 (1) Alston, England. (2) CaBa(CO3)2. Polymorphism & Series: Trimorphous with barytocalcite and paralstonite. Occurrence: Typically in low-temperature hydrothermal Pb–Zn deposits; rare in carbonatites. Association: Calcite, barite, ankerite, siderite, benstonite, galena, sphalerite, pyrite, quartz.
    [Show full text]
  • Subsolidus Phase Relations in Aragonite-Type Carbonates. Lll. The
    American Mineralogist, Volume 58, pages 979-985, 1973 SubsolidusPhase Relations in Aragonite-typeCarbonates. lll. The SystemsMgCO'-CaCO,-BaCOB, MgOO,-CaGO,-SrCO,, and MgCO,-SrCO,-BaCO, Wrtr,reu R. BnrcE Department ol Earth and Planeta:rySciences, Uniuersity of Pittsburgh at lohttstown, Iohnstown, Pennsylaania 15901 Lurn L. Y. CnaNc Department ol Geology, Miqmi Uniuersity, Oxford, Ohio 45056 Abstract Subsolidus phase relations in the three ternary systems were studied at 650"C and at both 5 and 15 kbar using high-pressure, opposed-anvil apparatus. Phases found in the systems, in addition to the end members, are dolomite (MgCa(COa),), norsethite (MgBa(COo),), MgSr(CO")a and two forms of CaBa(COs),, a monoclinic barytocalcite and a rhombohedral form with disordered calcite structure. In the system MgCOrCaCOrBaCO", both norsethite and disordered calcite have detectable ranges of solid solution at 650'C and 5 kbar, and six two-phase areas and four three-phase triangles are observed. In the system MgCO-CaCO-SrCOI, a complete series of solid solution along the join MgCa(CO")-MgSr(COg)z and a significantregion of calcite-typesolid solution exist at 650"C and 5 kbar, whereas at 650'C and 15 kbar, aragonite is the stable form of CaCO" and forms a complete series of solid solution with SrCO". Two complete solid solution series, SrCO-BaCO* and MgSr(CO")-MgBa(COo)a were found in the system MgCO- SrCO-BaCOa, and the system is represented by two large immiscibility gaps between the two solid solution series and between the dolomite seriesand MgCOa. Introduction Experimental Procedures As the third part of a study on the subsolidus Starting materials used were Baker analyzedrea- phase relations in aragonite-type carbonates, the gent grade CaCO3,SrCO3, BaCOs, and basic mag- systems MgCO3-CaCO3-BaCO3,MgCO3-CaCO3- nesium carbonate.The MgCO3 was prepared by SrCOs, and MgCOB-SrCOs-BaCOswere investi- hydrothermallytreating the basic magnesiumcar- gated at 650"C and two pressures,5 and 15 kbar.
    [Show full text]