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Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation SAFETY DATA SHEET Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation Version Revision Date: SDS Number: Date of last issue: 2020/10/10 3.7 2021/04/09 935013-00010 Date of first issue: 2016/10/12 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation Manufacturer or supplier's details Company : MSD Address : JL Raya Pandaan KM. 48 Pandaan, Jawa Timur - Indonesia Telephone : 908-740-4000 Emergency telephone number : 1-908-423-6000 E-mail address : [email protected] Recommended use of the chemical and restrictions on use Recommended use : Veterinary product 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 3 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 1 tation Germ cell mutagenicity : Category 1B Carcinogenicity : Category 1B Reproductive toxicity : Category 1B Specific target organ toxicity - : Category 1 (Central nervous system) single exposure Specific target organ toxicity - : Category 3 single exposure Specific target organ toxicity - : Category 1 (Central nervous system) repeated exposure 1 / 30 SAFETY DATA SHEET Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation Version Revision Date: SDS Number: Date of last issue: 2020/10/10 3.7 2021/04/09 935013-00010 Date of first issue: 2016/10/12 Aspiration hazard : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H226 Flammable liquid and vapour. H301 + H311 Toxic if swallowed or in contact with skin. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H360FD May damage fertility. May damage the unborn child. H370 Causes damage to organs (Central nervous system). H372 Causes damage to organs (Central nervous system) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting equip- ment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe mist or vapours. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection. Response: P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. 2 / 30 SAFETY DATA SHEET Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation Version Revision Date: SDS Number: Date of last issue: 2020/10/10 3.7 2021/04/09 935013-00010 Date of first issue: 2016/10/12 P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate- ly all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P308 + P311 IF exposed or concerned: Call a POISON CENTER/ doctor. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. P361 + P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification Vapours may form explosive mixture with air. 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Components Chemical name CAS-No. Concentration (% w/w) Solvent naphtha (petroleum), light aromatic 64742-95-6 >= 30 - < 60 Ethion 563-12-2 >= 10 - < 25 Chlorpyrifos 2921-88-2 >= 2.5 - < 10 2-Methyl-1-propanol 78-83-1 >= 3 - < 10 (S)-α-Cyano-3-phenoxybenzyl (1R, 3R)-3-(2,2- 67375-30-8 >= 2.5 - < 10 dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate Hydrocarbons, C10, aromatics, <1% naphtha- 64742-94-5 >= 0.25 - < 2.5 lene 2,6-Di-tert-butyl-p-cresol 128-37-0 >= 0.25 - < 2.5 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical ad- vice immediately. 3 / 30 SAFETY DATA SHEET Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation Version Revision Date: SDS Number: Date of last issue: 2020/10/10 3.7 2021/04/09 935013-00010 Date of first issue: 2016/10/12 When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately. If swallowed : If swallowed, DO NOT induce vomiting. If vomiting occurs have person lean forward. Call a physician or poison control centre immediately. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person. Most important symptoms : Toxic if swallowed or in contact with skin. and effects, both acute and May be fatal if swallowed and enters airways. delayed Causes skin irritation. Causes serious eye damage. Harmful if inhaled. May cause drowsiness or dizziness. May cause genetic defects. May cause cancer. May damage fertility. May damage the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8). Notes to physician : Treat symptomatically and supportively. 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing : High volume water jet media Specific hazards during fire- : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapours may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- : Carbon oxides 4 / 30 SAFETY DATA SHEET Ethion / Chlorpyrifos / Alpha-Cypermethrin Formulation Version Revision Date: SDS Number: Date of last issue: 2020/10/10 3.7 2021/04/09 935013-00010 Date of first issue: 2016/10/12 ucts Sulphur oxides Oxides of phosphorus Chlorine compounds Nitrogen oxides (NOx) Specific extinguishing meth- : Use extinguishing measures that are appropriate to local cir- ods cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for firefighters Use personal protective equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- : Remove all sources of ignition. tive equipment and emer- Use personal protective equipment. gency procedures Follow safe handling advice (see section 7) and personal pro- tective equipment recommendations (see section 8). Environmental precautions : Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for : Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapours/mists with a water spray jet. For large spills, provide dyking or other appropriate contain- ment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor- bent. Local or national regulations may apply to releases and dis- posal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter- mine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation
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