Precious COMPOUNDS Metal and CATALYSTS

Precious COMPOUNDS Metal AND CATALYSTS

INCLUDES: • New Introduction to Catalysis and Catalysts by Martyn Twigg • Compounds and Homogeneous Catalysts • Supported Heterogeneous Catalysts • Unsupported Heterogeneous Catalysts • HiSpec™ Fuel Cell Products • FibreCat™ Anchored Homogeneous Catalysts • Smopex™ Precious Metal Scavenger Systems Improve Your Catalytic Processes with Johnson Matthey Products, Know-How & Service

When you order Johnson Matthey As a leading manufacturer and supplier precious metal chemicals or catalyst of PGM homogeneous and heteroge- products from Alfa Aesar, you can be neous catalysts, Johnson Matthey offers assured of Johnson Matthey quality toll and custom manufacturing, as and service through all stages of your well as refining and analytical services. project. Alfa Aesar carries a full range Johnson Matthey is developing new of Johnson Matthey catalysts in stock in catalytic materials for applications such smaller catalog pack sizes and semi-bulk as pharmaceuticals, fuel cells, sensors, quantities for immediate shipment. automobiles, batteries, photographic And our plants worldwide have the materials, specialized plating, and stock and manufacturing capability catalyst manufacture. to meet your needs when it is time to Many precious metal chemical and scale up. All products are lot-traceable catalyst products are produced at to ensure you get the specific material Johnson Matthey plants in the USA you need. (below left) and England (below right).

Gram to kilogram quantities are available from stock. For more information or to place an order call 1–800–343–0660 or 1–978–521–6300 or visit our website at www.alfa.com Table of Contents

How to Order/General Information 2 Abbreviations and Codes 3 Introduction to Catalysis and Catalysts by Martyn Twigg 5 Precious Metal Compounds & Homogeneous Catalysts 19 Homogeneous catalysis provides an excellent choice where highly specific reactions are desired including chiral transformations. Our homogeneous catalysts can be used in a wide range of chemical transformations. These compounds are available in gram to commercial scale quantities. – Asymmetric Hydrogenation Ligand/Catalyst Kit – Advanced Coupling Kit – Mini Advanced Coupling Kit

Supported Heterogeneous Catalysts 53 Supported (heterogeneous) precious metal catalysts are used in a variety of reactions including hydrogenation, oxidation, hydrogenolysis and isomerization. Our line of heterogeneous catalysts are available in a variety of supports such as carbon, alumina, silica, calcium carbonate and barium sulfate.

Unsupported Heterogeneous Catalysts 62 The range of Johnson Matthey unsupported catalysts includes platinum oxides, the oxides of the other platinum group metals, and a number of metal “blacks.”

Fuel Cell Products 64 The HiSPEC™ range consists of single and bimetal supported and unsupported catalysts, which have been used with success on both the anode and cathode sides of the fuel cell. HiSPEC™ catalysts are all made to a consistently high quality on a commercial scale, and are readily available in gram and kilogram quantities. – HiSPEC™ Fuel Cell Catalysts – HiFUEL™ Catalysts – Fuel Cell Components

FibreCat™ Anchored Homogeneous Catalysts 68 These newly designed polymer-anchored materials for homogeneous catalysis help maintain the accessibility of the catalytic sites for diffusion of the starting materials and products. The polyethylene fiber is extremely robust and is not degraded by stirring.

Smopex® Scavenger Systems 75 Smopex precious metal scavenger products for the purification of pharmaceutical process streams and other processes.

Terms and Conditions of Sale 78 How to Order/General Information

Telephone Technical Service Catalog Sales At your request, we will furnish technical (800) 343–0660 or (978) 521–6300 assistance and information with respect Monday-Friday, 8:00 am-7:00 pm EST to our products. Our Technical Service Specialty and Bulk Sales Representatives are trained in specific (888) 343–8025 or (978) 521–6401 product lines to answer your questions Monday-Friday, 8:00 AM-5:00 PM EST regarding applications, specifications, Technical Service product properties and handling. Call (800) 343–7276 or (978) 521–6405 (800) 343–7276. Monday-Friday, 8:00 AM-5:00 PM EST Material Safety Data Sheets Fax Each product is automatically accom- Catalog Sales panied by a Material Safety Data Sheet (800) 322–4757 or (978) 521–6350 (MSDS) in compliance with OSHA. If Specialty and Bulk Sales one is not immediately available, a (978) 521–6366 copy will be sent via mail as soon as possible. If an MSDS is needed prior Mail to shipment of a product please call Alfa Aesar, 26 Parkridge Road (800) 343–0660 or visit www.alfa.com. Ward Hill, MA 01835–8099 Certificates of Analysis Internet All Premion® brand products are www.alfa.com automatically accompanied by a Our web catalog features up-to-date batch-specific Certificate of Analysis. prices, stock availability, MSDS, Certificates of Analysis are also Certificates of Analysis and a available online at www.alfa.com. user-friendly e-commerce system. Return Shipments E–mail Some materials are not returnable. Please [email protected] refer to the Terms and Conditions of Ordering Sale at the end of this catalog. Returned There is no minimum order. All orders shipments cannot be accepted unless accepted...regardless of size. Orders prior arrangements have been made. under $100.00 will be subject to a Requests for return authorization must nominal handling fee. be made within 30 days of your receiving the materials. A 20% restocking fee is Pricing charged on authorized returns of Most current pricing may be found at standard catalog items, subject to a our web site: www.alfa.com. In cases minimum charge of $20.00 per order. where the selling price has changed significantly, we will contact you prior Terms of Sale to filling your order. Our payment Full details of Terms and Conditions terms are net 30 days of invoice. are listed at the end of this catalog. Shipping New Customers Whenever possible, we will ship products We welcome new customers and setting by the method specified on your up an account with Alfa Aesar is easy. order. Two-day delivery is standard Just call (800) 343–0660 and a customer within the contiguous United States service representative will assist you. (overnight in the Northeast). All orders are shipped FOB seller’s shipping point. Alfa Aesar is ISO 9001:2000 Certified Most catalog orders received by 6:00PM EST are shipped the same day. Abbreviations and Codes The following abbreviations are used throughout our listing of products.

AAS Atomic absorption spectrometry Mw/Mn Monodispersity value AES Atomic emission spectrometry N Normality of solution ACS Chemicals meeting the specifications outlined Refractive index for the sodium D line at by the American Chemical Society 20 ˚C (or temperature indicated) APS Average particle size nm Nanometer anhy Anhydrous New product Angstrom NMR Nuclear magnetic resonance Approximately OD Outer diameter approx. Approximately optical gr. Suitable for optical applications Atm Atmospheres pc(s) Piece(s) b.p. Boiling point in ˚C at 760mm pressure, unless pH Value taken to represent the acidity or otherwise specified alkalinity of an aqueous solution (c) Contained weight of active material POR Price on request ˚C Celsius ppb Parts per billion cc Cubic centimeter ppm Parts per million cm Centimeter prec. Precipitated cont. Contained Primary Analytical reagent of exceptional purity, cP Centipoise Standard for standardizing volumetric solutions and cS Centistoke preparing reference standards d. Density PTFE Poly(tetrafluoroethylene) dec. Decomposes Purified A grade of higher quality than technical, dia. Diameter often used where there are no official ea. Each standards eV Electron volt P.T. Passes test ˚F Fahrenheit P.V. Pore volume f.p. Flash point Reagent Reagent grade FSSS Fisher sub-sieve sizer REM Rare earth metal F.W. Formula weight (REO) Rare earth oxide base - content of specific g Gram rare earth element in comparison to total g/l Grams per liter (gas density) rare earths present GLC Suitable for use in gas liquid S.A. Surface area chromotography Sp.Gr. Specific gravity GC Gas chromotography Sp.Rot. Specific rotation HPLC High-performance liquid chromotography subl. Sublimes ICP Inductively Coupled Plasma Tc Critical temperature ID Inner diameter TLC Thin-layer chromotography in Inch TSCA Toxic Substance Control Act incl Includes UN Hazardous material transportation IR Infrared identification number J/mol.K Joule(s) per mole Kelvin Wavelength in nanometers kg Kilogram wt Weight KU Kilounit w/w Weight/weight L or l Liter w/v Weight/volume lb Pound XRD X-ray diffraction m Meter Air sensitive M Molarity of solution Moisture sensitive mg Milligram Hygroscopic Micro Light sensitive g Microgram > Greater than meq Milliequivalent Greater than or equal to Merck The Merck Index Less than m Micrometer (micron) Less than or equal to max Maximum [ ] Numbers in brackets after the chemical micron Micrometer description indicate the Chemical Abstract mm Millimeter Service Registry Number m.p. Melting point - mesh # 90% particles pass through screen having mol Mole a given mesh size mmol Millimole + mesh # 90% particles are retained by a screen M.W. Molecular weight having a given mesh size Mw Weighted averaged molecular weight Denotes substance is listed in Toxic Mn Number averaged molecular weight Substance Control Act (TSCA) inventory

3 4

1 IA 18 VIIIA 1.00794 1 4.002602 2 H www.alfa.com He

Hydrogen 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA Helium 6.941 3 9.012182 4 10.811 5 12.011 6 14.00674 7 15.9994 8 18.9984032 9 20.1797 10 Li Be B C N O F Ne

Lithium Beryllium PERIODIC TABLE Boron Carbon Nitrogen Oxygen Fluorine Neon 22.989768 11 24.3050 12 26.981539 13 28.0855 14 30.973762 15 32.066 16 35.4527 17 39.948 18 Na Mg OF THE ELEMENTS Al Si P S Cl Ar

Sodium Magnesium 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIIB 8 VIII 9 VIII 10 VIII 11 IB 12 IIB Aluminum Silicon Phosphorus Sulfur Chlorine Argon 39.0983 19 40.078 20 44.955910 21 47.88 22 50.9415 23 51.9961 24 54.93805 25 55.847 26 58.93320 27 58.6934 28 63.546 29 65.38 30 69.723 31 72.61 32 74.92159 33 78.96 34 79.904 35 83.80 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 85.4678 37 87.62 38 88.90585 39 91.224 40 92.9064 41 95.94 42 98 43 101.07 44 102.9055 45 106.42 46 107.868 47 112.411 48 114.818 49 118.710 50 121.75 51 127.60 52 126.9045 53 131.29 54 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe

Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 132.9054 55 137.327 56 57-71 178.49 72 180.9479 73 183.85 74 186.207 75 190.23 76 192.22 77 195.08 78 196.96654 79 200.59 80 204.3833 81 207.2 82 208.98037 83 208.9824 84 209.9871 85 222.0176 86 La- Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Cesium Barium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 223.0197 87 226.0254 88 89-103 261.1087 104 262.1138 105 263.1182 106 262.1229 107 265 108 266 109 269 110 272 111 277 112 Ac- Fr Ra Lr Rf Db Sg Bh Hs Mt Ds Uuu Uub Francium Radium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Unununium Ununbium

ATOMIC WEIGHT

24.3050 12 ATOMIC 138.9055 57 140.115 58 140.90765 59 144.24 60 146.9151 61 150.36 62 151.965 63 157.25 64 158.92534 65 162.50 66 164.93032 67 167.26 68 168.9342 69 173.04 70 174.967 71 NUMBER Mg SYMBOL La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

Magnesium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium ELEMENT 227.0278 89 232.0381 90 231.0359 91 238.03 92 237.0482 93 244.0642 94 243.0614 95 247.0703 96 247.0703 97 251.0796 98 252.0829 99 257.0951 100 258.0986 101 259.1009 102 262.11 103 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr

Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Catalysis and Catalysts rcosMtlCompounds Metal Precious Catalysts &

1-800-343-0660 5 Catalysis and Catalysts Compounds and Homogeneous Catalysts

6 www.alfa.com Catalysis and Catalysts ooeeu Catalysts Homogeneous opud and Compounds

1-800-343-0660 7 Catalysis and Catalysts Compounds and Homogeneous Catalysts

8 www.alfa.com Catalysis and Catalysts ooeeu Catalysts Homogeneous opud and Compounds

1-800-343-0660 9 Catalysis and Catalysts Compounds and Homogeneous Catalysts

10 www.alfa.com Catalysis and Catalysts ooeeu Catalysts Homogeneous opud and Compounds

1-800-343-0660 11 Catalysis and Catalysts Compounds and Homogeneous Catalysts

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1-800-343-0660 13 Catalysis and Catalysts Compounds and Homogeneous Catalysts

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1-800-343-0660 17 Catalysis and Catalysts Compounds and Homogeneous Catalysts

18 www.alfa.com Gold

Stock # Description Standard Selling Sizes 40434 Ammonium tetrachloroaurate(III) hydrate, Premion®, 99.99% (metals basis) 1g

[13874-04-9], (NH4)AuCl4ùxH2O, F.W. 356.82(anhy), Crystalline, m.p. 520ø, Solubility: Soluble 5g in water and alcohol, EINECS 250-476-0, MDL MFCD00011503, Ì bulk

R:36/37/38, S:26-37 41002 Bromo(triphenylphosphine)gold(I), Premion®, 99.99% (metals basis) 1g

[14243-65-3], AuBr[P(C6H5)3], F.W. 539.17, Powder, EINECS 238-118-1, MDL MFCD00049267 5g bulk R:36/37/38, S:26-37 41007 Chloro(triphenylphosphine)gold(I), Premion®, 99.99% (metals basis), Au 39.3% min 500mg [Triphenylphosphinegold(I) chloride] 1g

[14243-64-2], AuCl[P(C6H5)3], F.W. 494.71, Powder, EINECS 238-117-6, MDL MFCD00009588 5g bulk R:36/38, S:26-37 39742 Gold(III) acetate, 99.9% (metals basis) 500mg

[15804-32-7], Au(O2CCH3)3, F.W. 374.10, Powder, MDL MFCD00210614 1g

5g Catalysts Homogeneous bulk

12162 Gold(III) bromide, Premion®, 99.99% (metals basis), Au 44.6% min 1g and Compounds

[10294-28-7], AuBr3, F.W. 436.69, Granular, m.p. ca 160ø dec., UN3260, EINECS 233-654-2, 5g MDL MFCD00014171, Ì bulk

R:34, S:20-26-36/37/39-45 43365 Gold(I) chloride, 99.9% (metals basis) É 1g [10294-29-8], AuCl, F.W. 232.42, Powder, m.p. 289ø dec., d. 7.57, Merck 14,4515, UN3260, 5g MDL MFCD00046175, Note: Decomposes in water, Ì bulk

R:34, S:20-26-36/37/39-45 40432 Gold(I) chloride, Premion®, 99.99% (metals basis), Au 84.2% min É 250mg [10294-29-8], AuCl, F.W. 232.42, Powder, m.p. 289ø dec., d. 7.57, Merck 14,4515, UN3260, 1g MDL MFCD00046175, Note: Decomposes in water, Ì 5g bulk R:34, S:26-36/37/39 12163 Gold(III) chloride, Au 64.4% min Ê 250mg

[13453-07-1], AuCl3, F.W. 303.33, Crystalline, m.p. 160ø dec., Merck 14,4521, UN3260, 1g EINECS 236-623-1, MDL MFCD00014172, Ì 5g bulk R:34, S:26-36/37/39 43360 Gold(III) chloride, Premion®, 99.99% (metals basis), Au 64.4% min Ê 1g

[13453-07-1], AuCl3, F.W. 303.33, Crystalline, m.p. 160ø dec., Merck 14,4521, UN3260, 5g EINECS 236-623-1, MDL MFCD00014172, Ì bulk

R:34, S:26-36/37/39 32031 Gold(I) cyanide, Premion®, 99.99% (metals basis) É 250mg [506-65-0], AuCN, F.W. 222.98, Powder, m.p. dec., d. 7.14, Merck 14,4516, UN1588, 1g EINECS 208-049-1, MDL MFCD00003437, Ì 5g bulk R:26/27/28-32-50/53, S:7-28a-29-45-60-61 12159 Gold(III) hydroxide, Au 79% min ß 1g

[1303-52-2], Au(OH)3, F.W. 247.99, Powder, Merck 14,4523, Application(s): Gold plating 5g solutions, porcelain decoration, EINECS 215-120-0, MDL MFCD00046173, Note: Decomposed 10g by light to metallic gold, Ì bulk 16617 Gold(I) iodide, 99% É 1g [10294-31-2], AuI, F.W. 323.87, Crystalline, m.p. 120ø dec., d. 8.25, Solubility: Insoluble in 5g water. Soluble in alkali iodide, cyanide solutions. Decomposes in warm acids, UN3260, bulk EINECS 233-656-3, MDL MFCD00014175, Ì

R:34, S:20-26-36/37/39-45-60 12161 Gold(III) oxide, Premion®, 99.99% (metals basis), Au 88.6% min 250mg

[1303-58-8], Au2O3, F.W. 441.93, Powder, m.p. 150ø dec., Merck 14,4524, Solubility: Insoluble 1g in water. Soluble in HCl, HNO3, and in NaCN solution, EINECS 215-122-1, 5g MDL MFCD00014173, Ì bulk 12552 Gold(I) potassium cyanide, Premion®, 99.99% (metals basis), Au 67.8% min 1g [Potassium dicyanoaurate(I), Potassium gold cyanide] 5g

[13967-50-5], KAu(CN)2, F.W. 288.33, Powder, UN1588, MDL MFCD00011414, Ì 25g bulk R:26/27/28-32-50/53, S:7-28a-29-45-60-61

1-800-343-0660 19 Gold Stock # Description Standard Selling Sizes 39666 Gold(III) potassium thiocyanate, Premion®, 99.99% (metals basis) 250mg

KAu(SCN)4, F.W. 468.40, Powder, MDL MFCD00210615 1g bulk R:20/21/22-32, S:13 12637 Gold(I) sodium cyanide, 99.9% (metals basis), Au 72% min 250mg [Sodium gold cyanide] 1g

[15280-09-8], NaAu(CN)2, F.W. 271.99, Powder, UN1588, EINECS 239-320-3, 5g MDL MFCD00050423, Ì bulk

R:26/27/28-32-50/53, S:7-28a-29-45-60-61 39741 Gold(I) sodium thiosulfate hydrate, 99.9% (metals basis) 1g

Na3Au(S2O3)2ùxH2O, F.W. 490.19(anhy), Powder, m.p. 150-160ø -2H2O, d. 3.09, Merck 14,4519, 5g Solubility: Soluble in water. Insoluble in ethanol and most other organic solvents, 25g MDL MFCD00046176, Ì bulk 40433 Hydrogen tetrabromoaurate(III) hydrate, Premion®, 99.99% (metals basis), 1g Au 32% min Ê 5g [Bromoauric acid] bulk

HAuBr4ùxH2O (x÷5), F.W. 517.61(anhy), Crystalline, m.p. ca 27ø, Solubility: Soluble in water and alcohol, UN3260, MDL MFCD00054118, Ì

R:34, S:20-26-36/37/39-45-60 44744 Hydrogen tetrachloroaurate(III), solution, Au 40-44% w/w (cont. Au) (c)1g

HAuCl4, F.W. 517.61, Liquid, UN3264, MDL MFCD00011322, Ì (c)5g bulk R:34, S:9-26-36/37/39-45 12325 Hydrogen tetrachloroaurate(III) hydrate, 99.9% (metals basis), Au 49% min Ê 1g [Tetrachloroauric(III), Chloroauric acid] 5g

[27988-77-8], HAuCl4ùxH2O, F.W. 339.79(anhy), Crystalline, UN3260, MDL MFCD00149903, Ì 25g 100g R:34-43, S:26-36/37/39-45 bulk Compounds and 36400 Hydrogen tetrachloroaurate(III) trihydrate, ACS, 99.99% (metals basis), 1g Au 49.5% min Ê 5g

Homogeneous Catalysts [16961-25-4], HAuCl4ù3H2O, F.W. 393.83 (339.79anhy), Crystalline, UN3260, bulk MDL MFCD00149904, Ì Maximum level of impurities: Insoluble in ether 0.1%, Alkalies and other metals (as sulfates) 0.2%

R:34-43, S:26-36/37/39-45 42803 Hydrogen tetrachloroaurate(III) hydrate, Premion®, 99.999% (metals basis), 1g Au 49% min Ê 5g

[27988-77-8], HAuCl4ùxH2O, F.W. 339.79(anhy), Crystalline, UN3260, MDL MFCD00149903, Ì bulk

R:34-43, S:26-36/37/39-45 40431 Hydrogen tetranitratoaurate(III) hydrate, Premion®, 99.99% (metals basis), Au 38.9-40.1% 1g [Nitratoauric acid] 5g

HAu(NO3)4ùxH2O (x÷3), F.W. 445.99(anhy), Crystalline, m.p. ca 72ø dec., bulk Solubility: Decomposes in water. Soluble in HNO3, UN1477, MDL MFCD00046178

R:8-36/38, S:26 40429 Lithium tetrachloroaurate(III) hydrate, Premion®, 99.99% (metals basis) 250mg

LiAuCl4ùxH2O, F.W. 345.72(anhy), Crystalline to liquidous, MDL MFCD00798533 1g 5g R:36/37/38, S:26-37 bulk 12664 Potassium tetrabromoaurate(III) dihydrate, Premion®, 99.99% (metals basis), 1g Au 33%min 5g [Gold potassium bromide] bulk

[14323-32-1], KAuBr4ù2H2O, F.W. 591.72 (555.69anhy), Crystalline, Solubility: Soluble in water and alcohol, EINECS 238-268-8, MDL MFCD00049650, Ì

R:36/37/38, S:26 12150 Potassium tetrachloroaurate(III) hydrate, Premion®, 99.99% (metals basis), 1g Au 49% min 5g [Gold potassium chloride] bulk

[27988-75-6], KAuCl4ùxH2O, F.W. 377.88(anhy), Crystalline, m.p. 357ø dec., Merck 14,7681, Solubility: Soluble in water, EINECS 237-190-1, MDL MFCD00043088, Ì

R:36/37/38, S:26-37

20 www.alfa.com Gold/Iridium Stock # Description Standard Selling Sizes 39740 Sodium aurothiomalate(I), 99.9% (metals basis) 1g [Gold sodium thiomalate] 5g

[12244-57-4], C4H4AuNaO4S, F.W. 368.09, Powder, Merck 14,4518, bulk Solubility: Very soluble in water. Practically insoluble in alcohol, ether, EINECS 235-479-7, RTECS MD5435000, MDL MFCD00064304

R:20/22-43, S:9-24-37 40428 Sodium tetrabromoaurate(III) hydrate, Premion®, 99.99% (metals basis) 1g

[10378-49-1], NaAuBr4ùxH2O (x÷2), F.W. 539.59(anhy), Crystalline, Solubility: Soluble in 5g water, MDL MFCD00274624, Ì bulk

R:36/37/38, S:26-36 12148 Sodium tetrachloroaurate(III) dihydrate, Premion®, 99.99% (metals basis), Au 49-50% 1g [Sodium chloroaurate(III), Gold sodium chloride] 5g

[13874-02-7], NaAuCl4ù2H2O, F.W. 397.80 (361.77anhy), Crystalline, m.p. 100ø dec., bulk Merck 14,8688, Solubility: Soluble in water, alcohol, ether, EINECS 239-241-3, MDL MFCD00149162, Ì

R:36/37, S:26 Catalysts Homogeneous opud and Compounds

Stock # Description Standard Selling Sizes 12632 Ammonium hexachloroiridate(III) hydrate Ê 1g

(NH4)3IrCl6ùxH2O, F.W. 459.06(anhy), Powder, EINECS 239-842-0, MDL MFCD00003393, Ì 5g bulk R:36/37/38, S:26-37 10713 Ammonium hexachloroiridate(III) hydrate, Premion®, 99.9998% Ê 1g

(NH4)3IrCl6ùxH2O, F.W. 459.06(anhy), Powder, EINECS 239-842-0, MDL MFCD00003393, Ì 5g bulk R:36/37/38, S:26 12326 Ammonium hexachloroiridate(IV), 99% (metals basis), Ir 43% min Ê 1g

[16940-92-4], (NH4)2IrCl6, F.W. 441.02, Powder, m.p. dec., d. 2.86, EINECS 241-007-0, 5g MDL MFCD00010881, Ì bulk

R:22-36/37/38, S:26-36 10712 Ammonium hexachloroiridate(IV), Premion®, 99.994% (metals basis), Ir 43% min Ê 100mg

[16940-92-4], (NH4)2IrCl6, F.W. 441.02, Powder, m.p. dec., d. 2.86, EINECS 241-007-0, 1g MDL MFCD00010881, Ì 5g bulk R:22-36/37/38, S:26-36 39413 Carbonylchlorobis(triphenylphosphine)iridium(I) 250mg [Vaska's catalyst, Chlorocarbonylbis(triphenylphosphine)iridium(I)] 1g

[14871-41-1], IrCl(CO)[P(C6H5)3]2, F.W. 780.27, Crystalline, m.p. 215ø dec., Solubility: Soluble 5g in chloroform, toluene. Slightly soluble in acetone, alcohol, UN2811, EINECS 238-941-6, bulk MDL MFCD00009590, Ì

R:20/21/22, S:4-9-20-36/37/39-45-60 41005 Carbonylhydridotris(triphenylphosphine)iridium(I), Ir 18.6% min É 1g [Hydridocarbonyltris(triphenylphosphine)iridium(I), Carbonyltris(triphenylphosphine)iridium(I) hydride] 5g

[17250-25-8], IrH(CO)[P(C6H5)3]3, F.W. 1008.09, Powder, Solubility: Soluble in chloroform bulk and toluene, UN2813, EINECS 241-282-7, MDL MFCD00015525, Ì

R:15-22, S:7/8-33-36-43h 12749 Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2% 250mg [Bis(1,5-cyclooctadiene)diiridium(I) dichloride] 1g

[12112-67-3], C16H24Cl2Ir2, F.W. 671.71, Solid, m.p. 190ø dec., 5g Solubility: Soluble in chloroform, toluene. Slightly soluble in acetone, bulk alcohol., EINECS 235-170-7, MDL MFCD00012414 41006 Chloropentaammineiridium(III) chloride, 99.9% (metals basis), Ir 49.6% min 250mg

[IrCl(NH3)5]Cl2, F.W. 383.714, Powder, MDL MFCD00798542 1g 5g R:6-37/38, S:37 bulk 18809 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) 500mg hexafluorophosphate È É 2g

[38465-86-0], C34H38F6IrP3, F.W. 845.79, Crystalline, m.p. 224ø dec., bulk Solubility: Soluble in acetone, Application(s): Hydrogenation, MDL MFCD00064800

R:36/38, S:26-37

1-800-343-0660 21 Iridium Stock # Description Standard Selling Sizes 42057 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) 50mg hexafluorophosphate, 99% É 250mg [Crabtree's catalyst] bulk

[64536-78-3], C31H50F6IrNP2, F.W. 804.89, Crystalline, m.p. 175ø dec., Fieser 12,151 13,88, Solubility: Slightly soluble in acetone, dichloromethane, ethanol, diethyl ether, MDL MFCD00075097

R:36/38, S:26-37 44966 Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9% 1g [Di-æ-chlorobis(cyclooctene)iridium(I)] 5g

[12246-51-4], C32H56Cl2Ir2, F.W. 896.00 bulk

39411 Dicarbonyl(2,4-pentanedionato)iridium(I) 500mg [(Acetylacetonato)dicarbonyliridium(I)] bulk

[14023-80-4], C7H7IrO4, F.W. 347.35, Crystalline, UN3466, MDL MFCD00049135

R:25-36/37/38, S:20-26-36/37-45-60 41009 Dihydrogen hexabromoiridate(IV) hexahydrate, 99.9% (metals basis), Ir 24.1% min 1g [Bromoiridic Acid, Hydrogen hexabromoiridate(IV)] 5g

H2IrBr6ù6H2O, F.W. 781.76 (673.67anhy), Powder, UN3260, MDL MFCD00798543 bulk

R:34, S:7/8-20-26-36/37/39-45-60 11031 Dihydrogen hexachloroiridate(IV) hydrate, 99.9% (metals basis), Ir 38-42% 1g [Hydrogen hexachloroiridate(IV), Chloroiridic acid] 5g

H2IrCl6ùxH2O, F.W. 406.93(anhy), Lump, Solubility: Soluble in alcohol and water, UN3260, 25g EINECS 241-012-8, MDL MFCD00011328, Ì bulk

R:22-36/37/38, S:26-36/37-60 10505 Dodecacarbonyltetrairidium, 98% È 1g Compounds and [Tetrairidium dodecacarbonyl, Iridium carbonyl] 5g

[11065-24-0], Ir4(CO)12, F.W. 1105.01, Powder, m.p. 195ø dec., UN3466, MDL MFCD00011064 bulk Homogeneous Catalysts R:23/25, S:4-9-20-36-45-60 12212 Iridium(III) bromide hydrate, Ir 35.9% min 1g

IrBr3ùxH2O, F.W. 431.91(anhy), Crystalline, m.p. 100ø -3H2O, EINECS 233-174-3, 5g MDL MFCD00049466, Ì bulk 39493 Iridium(IV) bromide, Premion®, 99.99% (metals basis), Ir 37.1% min 500mg

[7789-64-2], IrBr4, F.W. 511.84, Crystalline, m.p. dec., Solubility: Soluble in water, 2g EINECS 232-180-3, MDL MFCD00049467, Ì bulk

R:36/37/38, S:26-37 11030 Iridium(III) chloride hydrate, 99.9% (metals basis) 1g

[14996-61-3], IrCl3ùxH2O, F.W. 298.56(anhy), Crystalline, Merck 14,5088, Solubility: Soluble 5g in water and alcohol, EINECS 233-044-6, MDL MFCD00149750, Ì 25g 50g R:36/37/38, S:26-37 bulk 12158 Iridium(III) chloride, anhydrous, Ir 62% min Ê 1g

[10025-83-9], IrCl3, F.W. 298.56, Powder, m.p. 763ø dec., Merck 14,5088, Solubility: Insoluble 5g in water, acids, alkalies, EINECS 233-044-6, MDL MFCD00011063, Ì bulk

R:36/37/38, S:26-37 43380 Iridium(III) chloride, anhydrous, Premion®, 99.99% (metals basis), Ir 63.9% min 1g

[10025-83-9], IrCl3, F.W. 298.56, Powder, m.p. 763ø dec., Merck 14,5088, EINECS 233-044-6, 5g MDL MFCD00011063, Ì bulk

R:36/37/38, S:26-37 12184 Iridium(IV) chloride, Premion®, 99.95% (metals basis), Ir 56.5% min 250mg

[10025-97-5], IrCl4, F.W. 334.01(anhy), Glassy amorphous pieces/powder, m.p. dec., 1g EINECS 233-048-8, MDL MFCD00016155, Ì 5g bulk R:22-36/37/38, S:26-36 40424 Iridium(IV) iodide, Premion®, 99.95% (metals basis), Ir 27.0% min 1g

[7790-45-6], IrI4, F.W. 699.82, Powder, Solubility: Insoluble in water and alcohol. Soluble in 5g aqueous KI, EINECS 232-206-3, MDL MFCD00049960, Ì bulk

R:36/37/38, S:26-37 43051 Iridium(IV) oxide dihydrate, Premion®, 99.99% (metals basis), Ir 73% min 1g

[30980-84-8], IrO2ù2H2O, F.W. 260.23 (224.20anhy), Powder, EINECS 234-743-9, 5g MDL MFCD00011065, Ì bulk

22 www.alfa.com Iridium/Osmium Stock # Description Standard Selling Sizes 43396 Iridium(IV) oxide, Premion®, 99.99% (metals basis), Ir 84.5% min 1g

[12030-49-8], IrO2, F.W. 224.20, Powder, d. 11.7, EINECS 234-743-9, MDL MFCD00011065, Ì 5g bulk 10514 Iridium(III) 2,4-pentanedionate, Ir 37.5% min 250mg [Iridium(III) acetylacetonate] 1g

[15635-87-7], C15H21IrO6, F.W. 489.53, Crystalline, m.p. 269-271ø, 5g EINECS 239-711-8, MDL MFCD00015353 bulk

44967 Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58% 1g [Bis(1,5-cyclooctadiene)di-æ-methoxydiiridium(I)] 5g

[12148-71-9], C18H30Ir2O2, F.W. 662.88, Lump bulk

R:36/37/38, S:26-37 12651 Potassium hexabromoiridate(IV), Ir 25.5% min Ê 1g

[19121-78-9], K2IrBr6, F.W. 749.86, Crystalline, EINECS 242-827-1, MDL MFCD00054221 5g bulk R:36/37/38, S:26

41012 Potassium hexabromoiridate(IV), 99.9% (metals basis), Ir 25.2% min 1g Catalysts Homogeneous

[19121-78-9], K2IrBr6, F.W. 749.86, Powder, EINECS 242-827-1, MDL MFCD00054221, Ì 5g bulk opud and Compounds R:36/37/38, S:26 11887 Potassium hexachloroiridate(III) hydrate, Ir 33.4% min 1g

K3IrCl6ùxH2O, F.W. 522.22(anhy), Crystalline, EINECS 237-854-0, MDL MFCD00038699, Ì 5g 25g bulk 11888 Potassium hexachloroiridate(IV), Ir 39% min Ê 1g

[16920-56-2], K2IrCl6, F.W. 483.12, Crystalline, m.p. dec., EINECS 240-976-7, 5g MDL MFCD00011369, Ì 25g bulk 39183 Potassium hexacyanoiridate (III) hydrate, Premion®, 99.99% (metals basis), Ir 35% min 500mg

K3Ir(CN)6ùxH2O, F.W. 465.61(anhy), Crystalline, MDL MFCD00798517, Ì 1g 5g R:20/22-36/37/38, S:9-26-36 bulk 10528 Potassium hexanitroiridate(III), Ir 32.3% min 1g

[38930-18-6], K3Ir(NO2)6, F.W. 585.54, Micro Crystals, EINECS 254-191-2, 5g MDL MFCD00049672 bulk

R:36/37/38, S:26 12649 Sodium hexabromoiridate(IV), Ir 24.1% min Ê 1g

[28529-99-9], Na2IrBr6, F.W. 717.63, Crystalline, m.p. >350ø, EINECS 249-069-0, 5g MDL MFCD00064675 bulk

R:36/37/38, S:26 11889 Sodium hexachloroiridate(III) hydrate, Ir 31.5% min É 1g

Na3IrCl6ùxH2O, F.W. 473.89(anhy), Crystalline, EINECS 239-795-6, MDL MFCD00003508, Ì 5g bulk R:36/37/38, S:26 11890 Sodium hexachloroiridate(IV) hexahydrate, Ir 33.9% min 1g

[19567-78-3], Na2IrCl6ù6H2O, F.W. 558.99 (450.92anhy), Crystalline, m.p. 600ø dec., 5g MDL MFCD00149169, Ì bulk

R:36/37/38, S:26

Stock # Description Standard Selling Sizes 12648 Ammonium hexabromoosmiate(IV), 99.9% (metals basis), Os 26.5% min Ê 1g

[24598-62-7], (NH4)2OsBr6, F.W. 705.73, Powder, EINECS 246-340-5, MDL MFCD00049389, Ì 5g bulk R:22-36/37/38, S:26-36/37 42874 Ammonium hexachloroosmiate(IV), 99.9% (metals basis), Os 42.5% min Ê 1g

[12125-08-5], (NH4)2OsCl6, F.W. 438.99, Crystalline, m.p. 170ø subl., d. 2.9, Merck 14,536, 5g Solubility: Soluble in water and in alcohol, EINECS 235-188-5, MDL MFCD00010883, Ì bulk

R:22-36/38, S:26

1-800-343-0660 23 Osmium Stock # Description Standard Selling Sizes 10823 Ammonium hexachloroosmiate(IV), Premion®, 99.99% (metals basis), 500mg Os 42.8% min Ê 1g

[12125-08-5], (NH4)2OsCl6, F.W. 438.99, Powder, m.p. 170ø subl., d. 2.9, Merck 14,536, 5g EINECS 235-188-5, MDL MFCD00010883, Ì bulk

R:22-36/38, S:26 39235 Bis(cyclopentadienyl)osmium È É 250mg [Osmocene, Cyclopentadienylosmium] 1g

[1273-81-0], C10H10Os, F.W. 320.39, Crystalline, Packaged under argon, m.p. 226-228ø, bulk EINECS 215-055-8, MDL MFCD00058734

R:36/37/38, S:26-37-60 39239 Bis(pentamethylcyclopentadienyl)osmium, 99% È É 500mg [Decamethylosmocene] bulk

[100603-32-5], C20H30Os, F.W. 462.64, Powder, Packaged in ampoules, EINECS 202-873-5, MDL MFCD00058711

R:36/37/38, S:26-37

42527 Dihydrogen hexabromoosmiate(IV) hydrate, 99.9% (metals basis) 250mg [Bromoosmic Acid, Hydrogen hexabromoosmiate(IV)] 1g

H2OsBr6ùxH2O, F.W. 352.02(anhy), Crystalline, UN3260, MDL MFCD01863474 5g bulk R:34, S:20-26-36/37/39-45-60 12178 Dihydrogen hexachloroosmiate(IV) hydrate, Premion®, 99.95% (metals basis), 500mg Os 37% min 1g [Hydrogen hexachloroosmiate(IV), Chloroosmic acid] 5g

H2OsCl6ùxH2O, F.W. 404.93(anhy), Crystalline, UN3260, EINECS 235-188-5, bulk MDL MFCD00011329 Compounds and R:34, S:20-26-36/37/39-45-60 13038 Dodecacarbonyltriosmium, 99% 500mg Homogeneous Catalysts [Triosmium dodecacarbonyl, Osmium carbonyl] 2g

[15696-40-9], Os3(CO)12, F.W. 906.73, Crystalline, m.p. 224ø, UN3466, EINECS 239-789-3, bulk MDL MFCD00011149

R:23/25, S:37-45 33480 Osmium(III) chloride trihydrate, Premion®, 99.99% (metals basis), Os 52-56% 250mg

[135296-80-9], OsCl3ù3H2O, F.W. 350.60 (296.56anhy), Crystalline, m.p. dec., UN3260, 1g EINECS 236-587-7, MDL MFCD00011148, Ì 5g bulk R:20/21/22-34, S:9-20-26-36/37/39-45 39497 Osmium(IV) oxide, Os 83% min 250mg

[12036-02-1], OsO2, F.W. 222.20, Crystalline, d. 11.4, MDL MFCD00011150 1g 5g R:22, S:36 bulk 45384 Osmium(VIII) oxide, 2% aq. soln. 2ml

OsO4, F.W. 254.10, Merck 14,6893, EINECS 244-058-7, MDL MFCD00011150 10ml bulk 45385 Osmium(VIII) oxide, 4% aq. soln. 2ml

[20816-12-0], OsO4, F.W. 254.10, Merck 14,6893, EINECS 244-058-7, MDL MFCD00011150, Ì 10ml bulk 12103 Osmium(VIII) oxide, 99.8% (metals basis), Os 74.4% min 500mg [Osmic acid, Osmium tetroxide] 1g

[20816-12-0], OsO4, F.W. 254.10, Crystalline, m.p. 40.6ø, b.p. 130ø, Merck 14,6893, 10x1g Solubility: Soluble in chloroform, alcohol and ethers, Application(s): Oxidation, catalyst in bulk Sharpless dihydroxylations, UN2471, EINECS 244-058-7, MDL MFCD00011150, Note: Special handling precautions required. View MSDS prior to purchase. MSDS are available online at www.alfa.com, Ì

R:26/27/28-34, S:7/9-26-45 39507 Potassium hexabromoosmiate, Premion®, 99.99% (metals basis) 500mg

K2OsBr6, F.W. 747.86, Powder, MDL MFCD00049658 2g bulk R:36/37/38, S:26-37 12177 Potassium hexachloroosmiate(IV), Os 38.7% min Ê 250mg

[16871-60-6], K2OsCl6, F.W. 481.12, Powder, m.p. dec., Merck 14,7635, Solubility: Soluble 1g in water. Sparingly soluble in alcohol, EINECS 240-893-6, MDL MFCD00011371, Ì 5g bulk R:22-36/37/38, S:26-36

24 www.alfa.com Osmium/Palladium Stock # Description Standard Selling Sizes 12647 Potassium osmium(VI) oxide dihydrate, 99+% Ê 250mg [Potassium osmate dihydrate] 1g

[10022-66-9], K2OsO4ù2H2O, F.W. 368.43 (332.40anhy), Powder, Fieser 4,412, bulk Solubility: Soluble in water. Slowly decomposes in aqueous solution forming the tetroxide. Insoluble in alcohol, ether, UN3288, EINECS 243-247-1, MDL MFCD00149919, Ì

R:23/25-36/37/38, S:4-9-20-26-36/37-45 40412 Sodium hexabromoosmiate(IV), Premion®, 99.95% (metals basis), Os 26.1% min 1g

Na2OsBr6, F.W. 715.64, Crystalline Powder, MDL MFCD00798532 5g bulk R:36/37/38, S:26-37 12176 Sodium hexachloroosmiate(IV) dihydrate, Os 38.7% min È É 250mg

[1307-81-9], Na2OsCl6ù2H2O, F.W. 484.93 (448.90anhy), Crystalline, EINECS 215-152-5, 1g MDL MFCD00014234 5g bulk R:22-36/37/38, S:26-36 41020 Tetraamminedioxoosmium(VI) chloride, Os 52.2% min 1g

[OsO2(NH3)4]Cl2, F.W. 361.23, Powder, MDL MFCD00798548 bulk ooeeu Catalysts Homogeneous

R:36/37/38, S:26 opud and Compounds

Stock # Description Standard Selling Sizes 10005 Allylpalladium(II) chloride dimer, Pd 56.5% min È 250mg

[12012-95-2], C6H10Cl2Pd2, F.W. 365.85, Powder, m.p. 120ø dec., 1g EINECS 234-579-8, MDL MFCD00044874 5g bulk R:20/21-38, S:9-36/37 44046 Allylpalladium(II) trifluoroacetate, dimer bulk

[32699-43-7], [Pd(C3H5)(O2CCF3)]2, F.W. 521.02, Powder, MDL MFCD03788257 43475 Ammonium bis(oxalato)palladium(II) dihydrate, Premion®, 99.99% (metals basis) 1g

(NH4)2Pd(C2O4)2ù2H2O, F.W. 354.57 (318.54anhy), Crystalline, UN3288, MDL MFCD02684521 5g bulk R:21/22, S:24/25 11042 Ammonium hexachloropalladate(IV), 99.9% (metals basis), Pd 29% Ê 2g

[19168-23-1], (NH4)2PdCl6, F.W. 355.20, Crystalline, EINECS 242-854-9, 10g MDL MFCD00015959, Ì bulk

R:36/37/38, S:26-37 11882 Ammonium tetrachloropalladate(II), Pd 36% min Ê 1g [Ammonium chloropalladite] 5g

[13820-40-1], (NH4)2PdCl4, F.W. 284.29, Powder, m.p. dec., EINECS 237-498-6, bulk MDL MFCD00010884, Ì

R:36/37/38, S:26-37 10824 Ammonium tetrachloropalladate(II), Premion®, 99.998% (metals basis), Pd 37% Ê 1g

[13820-40-1], (NH4)2PdCl4, F.W. 284.29, Powder, m.p. dec., EINECS 237-498-6, 5g MDL MFCD00010884, Ì 25g bulk R:36/37/38, S:26-37 10002 Bis(acetonitrile)dichloropalladium(II), Pd 40.5% 1g

[14592-56-4], PdCl2(CH3CN)2, F.W. 259.41, Powder, Solubility: Soluble in acetonitrile, acetone, 5g chloroform, Application(s): Olefin isomerization, preparation of acetals and hemiacetal esters, bulk UN3439, EINECS 238-637-3, MDL MFCD00013122

R:20/21/22-36/37/38, S:9-26-36/37 10006 trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.7% 500mg

[14220-64-5], PdCl2[(C6H5)(CN)]2, F.W. 383.55, Powder, Solubility: Soluble in acetone, 1g chloroform, UN3439, EINECS 238-085-3, MDL MFCD00013123 bulk

R:23/24/25, S:4-9-20-27-36/37-45 39233 Bis[1,2-bis(diphenylphosphino)ethane]palladium (0) È 500mg

[31277-98-2], Pd[(C6H5)2PCH2CH2P(C6H5)2]2, F.W. 903.25, Powder, MDL MFCD00009880 1g bulk R:36/37/38, S:26-37

1-800-343-0660 25 Palladium Stock # Description Standard Selling Sizes 12764 Bis(dibenzylideneacetone)palladium(0) È É 250mg

[32005-36-0], C34H28O2Pd, F.W. 575.00, Powder, Packaged under 1g argon, m.p. 135ø dec., Solubility: Slightly soluble in CH2Cl2, CHCl3 and 5g benzene, Application(s): Hydrogenation, isomerization, carbonylation, bulk oxidation, C-C bond formation, MDL MFCD00051942 44829 1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride, 100mg Pd 16.3% 1g [95408-45-0], C26H44Cl2FeP2Pd, F.W. 651.77, Crystalline, packaged under bulk Argon, Application(s): Coupling reactions, Suzuki couplings, MDL MFCD08064219

R:36/37/38, S:26-37 44980 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) bromide, Pd 12.9% 1g

[124268-93-5], C34H28Br2FeP2Pd, F.W. 820.62, Solid 5g bulk

44972 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, 1g complex with acetone, Pd 13.7% 5g

[851232-71-8], C34H28Cl2FeP2Pdù(CH3)2CO, F.W. 787.81, 25g Application(s): Coupling reactions, carbonylation, MDL MFCD00792899 bulk 41225 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, 1g complex with dichloromethane (1:1), Pd 13% 5g

[95464-05-4], C34H28Cl2FeP2PdùCH2Cl2, F.W. 816.64, Powder, 25g m.p. 275-280ø, MDL MFCD00792899 bulk 44845 Bis(tri-tert-butylphosphine)palladium(0), Pd 20.9% ß È É 250mg

[53199-31-8], Pd[P(C(CH3)3)3]2, F.W. 510.00, Powder, ampouled under argon, 1g Application(s): Coupling reactions, Heck couplings, MDL MFCD03094580, Note: Decomposes bulk in water Compounds and R:36/37/38, S:26-37

Homogeneous Catalysts L16948 trans-Di-mu-acetatobis[2-(di-o-tolylphosphino)benzyl]- 250mg dipalladium(II), 94% 1g [Herrmann's Catalyst] bulk

[172418-32-5], C46H46O4P2Pd2, F.W. 937.66, m.p. ca 230ø, Fieser 21,310, MDL MFCD01075746

R:36/37/38, S:26-37 44032 Diacetatobis(triphenylphosphine)palladium(II), Pd 14.2% bulk

[14588-08-0], Pd(OOCCH3)2[P(C6H5)3]2, F.W. 749.09, Powder, MDL MFCD00010013 39249 trans-Diamminedibromopalladium(II), Premion®, 99.99% (metals basis), Pd 34.7% min 1g

[14591-90-3], Pd(NH3)2Br2, F.W. 300.28, Powder, m.p. 290ø dec., d. 2.5, MDL MFCD00058860 bulk

R:36/37/38, S:26-37 11037 trans-Diamminedichloropalladium(II), Premion®, 99.95% (metal basis), Pd 49.9% min 500mg [Dichlorodiamminepalladium(II)] 2g

[14323-43-4], Pd(NH3)2Cl2, F.W. 211.37, Powder, d. 2.5, Solubility: Slightly soluble in water. 10g Soluble in NH4OH. Insoluble in chloroform, acetone, MDL MFCD00011621, Ì bulk

R:36/37/38, S:26 11038 Diamminepalladium(II) nitrite solution, Pd 8-10% w/w (cont. Pd) (c)0.5g [Diamminedinitritopalladate(II)] (c)2g

[28068-05-5], (NH3)2Pd(NO2)2, F.W. 232.47(anhy), Liquid, UN2672, MDL MFCD00038712, Ì bulk

R:34, S:20-26-36/37/39-45-60 13704 trans-Dibromobis(triphenylphosphine)palladium(II), Pd 13.4% Ê 2g

[22180-53-6], Br2Pd[P(C6H5)3]2, F.W. 790.80, Powder, Solubility: Soluble in chloroform, toluene 10g and benzene, Application(s): Hydrogenation, MDL MFCD00134175 bulk 44979 Dibromobis(tri-o-tolylphosphine)palladium(II), Pd 12% È É 1g

[24554-43-6], C42H42Br2P2Pd, F.W. 874.98, Solid, Note: Slowly 5g decomposes in air and moisture bulk

26 www.alfa.com Palladium Stock # Description Standard Selling Sizes 44971 Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6% 1g

[29964-62-3], C28H28Cl2P2Pd, F.W. 603.80, Lump 5g bulk

18779 Dichloro[bis(1,2-diphenylphosphino)ethane]palladium(II), Pd 18.5% 2g

[19978-61-1], C26H24Cl2P2Pd, F.W. 575.73, Powder, m.p. >360ø, MDL MFCD00015702 10g bulk R:36/37/38, S:26-37 44977 Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II), Pd 14.8% 1g

[205319-06-8], C36H28Cl2OP2Pd, F.W. 715.88 5g bulk R:36/37/38, S:26-37

44844 Dichlorobis(tricyclohexylphosphine)palladium(II), Pd 14.4% 1g Catalysts Homogeneous

[29934-17-6], PdCl2[P(C6H12)3]2, F.W. 744.24, Powder, MDL MFCD00191830 bulk opud and Compounds R:36/37/38, S:26-37 39823 trans-Dichlorobis(triethylphosphine)palladium(II) Ê 250mg

[28425-04-9], PdCl2[P(C2H5)3]2, F.W. 413.63, Solubility: Soluble in chloroform, toluene and 1g benzene, Application(s): Coupling of C-C bonds, UN3464, MDL MFCD00191831 5g bulk R:20-24/25-36, S:4-9-20-26-27-36/37/39-45-60 10491 trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min Ê 1g [Bis(triphenylphosphine)dichloropalladium(II), Dichlorobis(triphenylphosphine)palladium(II)] 5g

[13965-03-2], PdCl2[P(C6H5)3]2, F.W. 701.89, Crystalline, m.p. 308-310ø, Solubility: Soluble 25g in toluene and benzene. Slightly soluble in acetone, chloroform, Application(s): Hydrogenation, bulk hydrosilation, carbonylation, oxidation, and C-C bond formation, EINECS 237-744-2, MDL MFCD00009593 41245 trans-Dichlorobis(triphenylphosphine)palladium(II), Premion®, 99.95% (metals 1g basis), Pd 14.7% min 5g

[13965-03-2], PdCl2[P(C6H5)3]2, F.W. 701.89, Powder, m.p. 308-310ø, EINECS 237-744-2, 25g MDL MFCD00009593 bulk 44976 Dichlorobis(tri-ortho-tolylphosphine)palladium(II), Pd 17.6% 1g

[40691-33-6], C42H42Cl2P2Pd, F.W. 786.08 5g bulk

10493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% Ê 1g

[12107-56-1], C8H12Cl2Pd, F.W. 285.49, Crystalline, Solubility: Soluble in 5g dichloromethane, EINECS 235-161-8, MDL MFCD00012412, Ì bulk 10496 Dichloro(ethylenediamine)palladium(II), Pd 44.8% Ê 1g

[15020-99-2], PdCl2(H2NCH2CH2NH2), F.W. 237.41, Crystalline, MDL MFCD00044991 5g bulk R:36/37/38, S:26 44865 Dihydrogen dinitrosulfatopalladate(II) solution, Pd 3.9-4.1% w/v (cont. Pd) (c)0.5g [Palladium DNS solution, Dinitrosulfatopalladium(II)] (c)2g

H2Pd(NO2)2SO4, F.W. 296.51(anhy), Liquid, UN3264, MDL MFCD08064221 (c)10g bulk R:34, S:20-26-36/37/39-45 17316 Lithium tetrachloropalladate(II) É 1g

[15525-45-8], Li2PdCl4, F.W. 262.09, Crystalline, EINECS 239-567-6, MDL MFCD00011082 5g bulk R:36/37/38, S:26-37-60 10516 Palladium(II) acetate, trimer, Pd 45.9-48.4% Ê 1g [Acetic acid palladium(II) salt, Palladium diacetate] 5g

[3375-31-3], [Pd(C2H3O2)2]3, F.W. 673.46, Needles, m.p. 205ø dec., Merck 14,6991, 25g Solubility: Soluble as monomer in glacial acetic acid or as trimer in benzene, bulk Application(s): Carbonylation, oxidation and C-C bond formation, EINECS 222-164-4, MDL MFCD00012453, Ì 43086 Palladium(II) acetate, trimer, 99.98% (metals basis), Pd 47% min 1g

[3375-31-3], [Pd(C2H3O2)2]3, F.W. 673.46, Powder, m.p. 205ø dec., Merck 14,6991, 5g EINECS 222-164-4, MDL MFCD00012453, Ì bulk

1-800-343-0660 27 Palladium Stock # Description Standard Selling Sizes 11878 Palladium(II) bromide, Premion®, 99.99% (metals basis), Pd 39.5% min Ê 2g

[13444-94-5], PdBr2, F.W. 266.22, Powder, m.p. dec., EINECS 236-588-2, 10g MDL MFCD00011170, Ì bulk

R:36/37/38, S:26-37 43697 Palladium(II) bromide, Premion®, 99.999% (metals basis), Pd 39.5% min 1g

[13444-94-5], PdBr2, F.W. 266.22, Powder, m.p. dec., EINECS 236-588-2, 5g MDL MFCD00011170, Ì bulk

R:36/37/38, S:26-37 12623 Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd) (c)1g

[7647-10-1], PdCl2, F.W. 177.31, Liquid, UN3264, EINECS 231-596-2, MDL MFCD00003558, Ì (c)5g bulk R:21/22-36/38, S:26-36 40019 Palladium(II) chloride, solution, Pd 20-25% w/w (cont. Pd) (c)1g

[7647-10-1], PdCl2, F.W. 177.31, Liquid, UN3264, EINECS 231-596-2, MDL MFCD00003558, Ì (c)5g bulk R:21/22-36/38, S:26-36 11034 Palladium(II) chloride, 99.9% (metals basis), Pd 59.5% min 500mg

[7647-10-1], PdCl2, F.W. 177.31, Crystalline, m.p. 675ø dec., Merck 14,6990, Solubility: Soluble 2g in dilute mineral acids, aqueous metal halides, Application(s): Catalyst precursor, 10g EINECS 231-596-2, MDL MFCD00003558, Ì 50g bulk R:20/21/22-36/37/38, S:26-36 43085 Palladium(II) chloride, Premion®, 99.999% (metals basis), Pd 59.5% min 1g

[7647-10-1], PdCl2, F.W. 177.31, Powder, m.p. 675ø dec., Merck 14,6990, EINECS 231-596-2, 5g MDL MFCD00003558, Ì 25g bulk R:20/21/22-36/37/38, S:26-36 11879 Palladium(II) cyanide, Pd 67% 1g Compounds and [2035-66-7], Pd(CN)2, F.W. 158.74, Powder, m.p. dec., UN1588, EINECS 217-999-6, 5g MDL MFCD00016282, Ì bulk Homogeneous Catalysts R:5-26/27/28-32-50/53, S:7-28b-29-45-60-61 39496 Palladium hydroxide, 99% 250mg

[12135-22-7], Pd(OH)2, F.W. 140.42, Powder, EINECS 235-219-2, MDL MFCD00064599, Ì 1g 5g bulk 42578 Palladium hydroxide, Pd 20% on carbon, nominally 50% water, Pearlman's Catalyst 2g [Pearlman's Catalyst] 10g [12135-22-7], Application(s): Hydrogenolysis of benzyl-nitrogen bonds, EINECS 235-219-2, 50g MDL MFCD00064599, Note: Sold on a dry weight basis. Unit weight excludes water weight, Ì bulk 11881 Palladium(II) iodide, 99.9% (metals basis), Pd 28% min 2g

[7790-38-7], PdI2, F.W. 360.23, Powder, m.p. 350ø dec., EINECS 232-203-7, 10g MDL MFCD00011171, Ì bulk

R:36/37/38, S:26 43084 Palladium(II) iodide, Premion®, 99.998% (metals basis), Pd 29% min 2g

[7790-38-7], PdI2, F.W. 360.23, Powder, m.p. 350ø dec., EINECS 232-203-7, 10g MDL MFCD00011171, Ì bulk

R:36/37/38, S:26 12621 Palladium(II) nitrate, solution, Pd 8.5% w/w (cont. Pd) (c)1g

[10102-05-3], Pd(NO3)2, F.W. 230.43, Liquid, UN3098, EINECS 233-265-8, (c)5g MDL MFCD00011169, Ì (c)25g bulk R:8-34, S:23b-26-36/37/39-45 41647 Palladium(II) nitrate, solution, 99.95% (metals basis), Pd 12-16% w/w (cont. Pd) (c)1g

[10102-05-3], Pd(NO3)2, F.W. 230.43, Liquid, UN3098, EINECS 233-265-8, (c)5g MDL MFCD00011169, Ì (c)25g bulk R:8-34, S:23b-26-36/37/39-45 11035 Palladium(II) nitrate hydrate, 99.9% (metals basis), Pd 39% min Ê 2g

Pd(NO3)2ùxH2O, F.W. 230.43(anhy), Crystalline, m.p. dec., Merck 14,6992, Solubility: Soluble 10g in water with turbidity, precipitating a brown basic salt. Completely soluble in dilute HNO3, 50g UN1477, EINECS 233-265-8, MDL MFCD00011169, Ì bulk

R:8-36/38, S:17-26 39495 Palladium oxalate 500mg

[57592-57-1], PdC2O4, F.W. 194.42, Powder, UN3288, MDL MFCD00050801 2g bulk R:21/22, S:24/25

28 www.alfa.com Palladium Stock # Description Standard Selling Sizes 11041 Palladium(II) oxide monohydrate, 99.9% (metals basis), Pd 73% min 2g

[14024-61-4], C10H14O4Pd, F.W. 304.92, Needles, m.p. 210ø dec., bulk Solubility: Soluble in benzene and chloroform, Application(s): Carbonylation, oligomerization, EINECS 237-859-8, MDL MFCD00000025, Ì 43699 Palladium(II) potassium thiosulfate monohydrate 1g

K2Pd(S2O3)2ùH2O, F.W. 426.87 (408.85anhy), Crystalline, MDL MFCD02684525 5g bulk 12622 Palladium(II) sulfate, solution, Pd 6% w/w (cont. Pd) (c)1g

[13566-03-5], PdSO4, F.W. 202.46(anhy), Liquid, EINECS 236-957-8, MDL MFCD00011173, Ì (c)5g

bulk Catalysts Homogeneous 42529 Palladium(II) sulfate dihydrate, 99% (metals basis) Ê 1g

[13566-03-5], PdSO4ù2H2O, F.W. 238.50 (202.46anhy), Crystalline, b.p. dec., Solubility: Soluble 5g in cold water; decomposes in hot water, EINECS 236-957-8, MDL MFCD00011173, Ì bulk and Compounds 12165 Palladium(II) sulfate dihydrate, Premion®, 99.95% (metals basis), Pd 44.1% min Ê 250mg

[13566-03-5], PdSO4ù2H2O, F.W. 238.50 (202.46anhy), Crystalline, b.p. dec., 1g EINECS 236-957-8, MDL MFCD00011173, Ì 5g bulk R:36/37/38, S:26-37 43698 Palladium(II) sulfate dihydrate, Premion®, 99.999% (metals basis) 1g

[13566-03-5], PdSO4ù2H2O, F.W. 238.50 (202.46anhy), Powder, EINECS 236-957-8, 5g MDL MFCD00011173, Ì bulk

R:36/37/38, S:26-37 12674 Palladium(II) sulfide, 99% (metals basis), Pd 72% min 1g [12125-22-3], PdS, F.W. 138.46, Crystalline, m.p. 950ø dec., d. 6.60, EINECS 235-190-6, 5g MDL MFCD00016285, Ì bulk

R:36/37/38, S:26-37-60 44446 Palladium(I) tri-tert-butylphosphine bromide, dimer È 100mg

[185812-86-6], [Pd(C4H9)3PBr]2, F.W. 777.29, Powder, Application(s): Coupling reactions. 500mg Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and 2g iodides. Especially active in difficult aminations, MDL MFCD04114019 bulk

R:20/22, S:9-36 39448 Palladium(II) trifluoroacetate, 97% Ê 1g

[42196-31-6], Pd(O2CCF3)2, F.W. 332.44, Powder, m.p. 210ø dec., MDL MFCD00013204 5g bulk R:36/37/38, S:26 43473 Potassium bis(oxalato)palladate(II) dihydrate, Premion®, 99.99% (metals basis) 1g

K2Pd(C2O4)2ù2H2O, F.W. 396.69 (360.66anhy), Crystalline, UN3288, MDL MFCD00061538 5g bulk R:21/22, S:24/25 12629 Potassium dinitrosulfatopalladate(II), solution, Pd 5% (cont. Pd) (c)1g

K2Pd(NO2)2SO4, F.W. 372.68, Liquid, MDL MFCD00064669, Ì (c)5g bulk 41011 Potassium disulfitopalladate(II), Premion®, 99.95% (metals basis), Pd 30.4% min 1g [Potassium palladium sulfite] 5g

K2Pd(SO3)2, F.W. 344.75, Powder, MDL MFCD00792331 bulk

R:36/37/38, S:26-37 43947 Potassium hexabromopalladate(IV), Premion®, 99.999% (metals basis), Pd 15.5% min 1g

K2PdBr6, F.W. 664.04, Crystalline, MDL MFCD03093651 5g bulk R:36/37/38, S:26-37 11884 Potassium hexachloropalladate(IV), Pd 26.3% min Ê 1g

[16919-73-6], K2PdCl6, F.W. 397.32, Crystalline, m.p. dec., EINECS 240-974-6, 5g MDL MFCD00043081, Ì 25g bulk R:36/37/38 11883 Potassium tetrabromopalladate(II), Pd 21.1% Ê 1g

[13826-93-2], K2PdBr4, F.W. 504.21, Crystalline, EINECS 237-535-6, MDL MFCD00049659, Ì 5g bulk R:36/37/38, S:26-37

1-800-343-0660 29 Palladium Stock # Description Standard Selling Sizes 11885 Potassium tetrachloropalladate(II), Premion®, 99.99% (metals basis), Pd 32.2% min Ê 2g

[10025-98-6], K2PdCl4, F.W. 326.42, Crystalline, EINECS 233-049-3, MDL MFCD00011373, Ì 10g bulk R:36/37, S:26 10535 Potassium tetracyanopalladate(II) hydrate 1g

[14516-46-2], K2[Pd(CN)4]ùxH2O, F.W. 288.68(anhy), Crystalline, MDL MFCD00150431, Ì bulk

R:20/22, S:9-36 10537 Potassium tetranitropalladate(II), Pd 28.3% min 1g

[13844-89-8], K2Pd(NO2)4, F.W. 368.63, Crystalline, m.p. 310ø dec., EINECS 237-568-6, 5g MDL MFCD00049788, Ì bulk

R:36/37/38, S:26 11039 Sodium hexachloropalladate(IV) hydrate, 99.9% (metals basis) 1g

Na2PdCl6ùxH2O, F.W. 365.10(anhy), Crystalline, EINECS 258-809-1, MDL MFCD00014235 5g 25g R:36/37/38, S:26 bulk 40407 Sodium tetrabromopalladate(II), Premion®, 99.95% (metals basis), Pd 22.0% min 1g

[50495-13-1], Na2PdBr4, F.W. 472.02, Powder, EINECS 256-605-7, MDL MFCD00046199, Ì 5g 10g R:36/37/38, S:26-37 bulk 11886 Sodium tetrachloropalladate(II) hydrate, 99.95% (metals basis), Pd 30% 2g [Sodium chloropalladate(II), Palladium sodium chloride] 10g

[13820-53-6], Na2PdCl4ùxH2O (x÷3), F.W. 294.20(anhy), Crystalline, EINECS 237-502-6, 50g MDL MFCD00003487, Ì bulk 43945 Sodium tetrachloropalladate(II) hydrate, Premion®, 99.999% (metals basis), 1g Pd 30% min 5g

[13820-53-6], Na2PdCl4ùxH2O (x÷3), F.W. 294.20(anhy), Crystalline, EINECS 237-502-6, bulk MDL MFCD00003487, Ì

Compounds and 41021 Tetraamminepalladium(II) bromide, Premion®, 99.95% (metals basis), Pd 31.3% min 1g

[44463-62-9], (NH3)4PdBr2, F.W. 334.34, Powder, m.p. >150ø dec., MDL MFCD00797352 5g bulk Homogeneous Catalysts R:36/37/38, S:26 11036 Tetraamminepalladium(II) chloride monohydrate, 99.9% (metals basis), 2g Pd 39% min Ê 10g

[13933-31-8], Pd(NH3)4Cl2ùH2O, F.W. 263.45 (245.43anhy), Crystalline, MDL MFCD00151033, Ì bulk

R:36/37/38, S:26 35749 Tetraamminepalladium(II) nitrate solution, 99.9% (metals basis), (c)2g Pd 5.0% max (cont.Pd) (c)10g [13601-08-6], (NH3)4Pd(NO3)2, F.W. 298.63, Liquid, UN3218, EINECS 237-078-2, bulk MDL MFCD00011591, Ì

R:1-8-36/37/38, S:26 44956 Tetraamminepalladium(II) sulfate, 99.9% (metals basis), Pd 37.4% min 1g

[13601-06-4], (NH3)4PdSO4, F.W. 270.61, Crystalline 5g 25g bulk 39447 Tetraamminepalladium(II) tetrachloropalladate(II) 1g

[13820-44-5], [Pd(NH3)4][PdCl4], F.W. 422.80, Powder, m.p. 192ø dec., d. 2.489, 5g EINECS 237-500-5, MDL MFCD00049783, Ì bulk

R:36/37/38, S:26 39446 Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9% È 250mg

[21797-13-7], [Pd(CH3CN)4](BF4)2, F.W. 444.22, Powder, m.p. 230ø dec., Solubility: Soluble 1g in water, UN2811, MDL MFCD00043297 bulk

R:20/21/22, S:9-36/37-60 10548 Tetrakis(triphenylphosphine)palladium(0), 99.8% (metals basis), Pd 9% min È 500mg [Palladium(0) tetrakis(triphenylphosphine)] 2g

[14221-01-3], Pd[P(C6H5)3]4, F.W. 1155.57, Crystalline, m.p. 100-105ø, Solubility: Soluble in 10g benzene, ethanol and chloroform, Application(s): Hydrosilation, isomerization, carbonylation, bulk oxidation, and C-C bond formation, EINECS 238-086-9, BRN 6704828, MDL MFCD00010012, Note: Heat sensitive, Ì

R:22, S:36 12760 Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min È É 1g

[Bis(dibenzylideneacetone)palladium(0), Pd2(dba)3] 5g

[51364-51-3], C51H42O3Pd2, F.W. 915.74, Powder, m.p. 152-155ø, bulk Fieser 9,46 12,56 14,38 15,33 17,394 18,389 19,388 20,417 21,469, Solubility: Soluble in chlorinated solvents, MDL MFCD00013310

30 www.alfa.com Palladium/Platinum Stock # Description Standard Selling Sizes 44969 Tris(dibenzylideneacetone)dipalladium(0), complex with 1g chloroform, Pd 20.6% È É 5g

[52522-40-4], Pd2(C17H14O)3ùCHCl3, F.W. 1035.12, Powder, bulk m.p. 131-135ø, Fieser 11,508 13,9 14,339 15,353 16,372 17,394 19,390 20,420 21,474, MDL MFCD00075479

R:38-40-48/20/22, S:22-36/37

Stock # Description Standard Selling Sizes 12619 Ammonium hexabromoplatinate(IV), 99.9% (metals basis), Pt 28% Ê 1g

[17363-02-9], (NH4)2PtBr6, F.W. 710.62, Powder, m.p. 145ø dec., EINECS 241-394-6, 5g MDL MFCD00044261, Ì bulk

R:22-36/37/38, S:26-36/37 12882 Ammonium hexachloroplatinate(IV), Pt 43.4% min Ê 1g [Ammonium platinic chloride] 5g Catalysts Homogeneous

[16919-58-7], (NH4)2PtCl6, F.W. 443.89, Powder, d. 3.06, Merck 14,548, Solubility: Slightly bulk

soluble in water. Insoluble in alcohol, Application(s): Electroplating of platinum, manufacturing and Compounds of platinum sponge, UN3288, EINECS 240-973-0, MDL MFCD00010886, Ì

R:25-41-42/43-68, S:20-22-26-28a-36/37/39-45 40406 Ammonium hexathiocyanoplatinate(IV), Premion®, 99.95% (metals basis), 1g Pt 33.2%min 5g

(NH4)2Pt(SCN)6, F.W. 579.66, Powder, EINECS 243-002-9, MDL MFCD00798530, Ì bulk

R:20/21/22-32, S:13 11046 Ammonium tetrachloroplatinate(II), 99.9% (metals basis), Pt 51% min Ê 1g [Ammonium chloroplatinate] 5g

[13820-41-2], (NH4)2PtCl4, F.W. 372.98, Crystalline, m.p. 145ø dec., EINECS 237-499-1, bulk MDL MFCD00010885, Ì

R:25-38-41-42/43, S:22-26-36/37/39-45 12679 Barium tetracyanoplatinate(II) tetrahydrate, Pt 38% 1g [Barium platinocyanide, Barium cyanoplatinate(II)] 5g

[13755-32-3], BaPt(CN)4ù4H2O, F.W. 508.56 (436.50anhy), Powder, m.p. 100ø dec., d. 3.05, bulk Merck 14,991, Application(s): Radiography (making x-ray screens), UN1564, EINECS 209-238-1, MDL MFCD00014183

R:25-36/37/38, S:20-26-36/37-45 39463 Barium tetracyanoplatinate(II) tetrahydrate, Premion®, 99.99% (metals basis) 1g

[13755-32-3], BaPt(CN)4ù4H2O, F.W. 508.56 (436.50anhy), Powder, m.p. 100ø dec., d. 3.05, 5g Merck 14,991, UN1564, EINECS 209-238-1, MDL MFCD00014183, Ì bulk

R:25-36/37/38, S:20-26-36/37-45 10004 Bis(benzonitrile)dichloroplatinum(II), Pt 40% min 500mg

[14873-63-3], PtCl2[(C6H5)(CN)]2, F.W. 472.25, Powder, Solubility: Slightly soluble in acetone, 1g chloroform, UN3439, EINECS 238-943-7, MDL MFCD00013125 5g bulk R:23/24/25-42/43, S:4-9-20-23-27-36/37/39-45 44041 (1,5-Cyclooctadiene)diiodoplatinum(II) 1g

[12266-72-7], PtI2(C8H12), F.W. 557.07, Powder, MDL MFCD00050491 bulk

R:36/37/38, S:26-37 13735 (1,5-Cyclooctadiene)dimethylplatinum(II), Pt 58.5% 1g

[12266-92-1], C10H18Pt, F.W. 333.30, Powder, m.p. 103-105ø, 5g MDL MFCD00064719, Ì bulk

R:36/37/38-42, S:22-26-36/37-45 10471 cis-Diamminedichloroplatinum(II), Pt 64.5% min 250mg [Cisplatin] 1g

[15663-27-1], PtCl2(NH3)2, F.W. 300.06, Micro Crystals, m.p. 270ø dec., Merck 14,2317, 5g Solubility: Soluble in DMF. Insoluble in most common solvents, EINECS 239-733-8, bulk RTECS TP2450000, MDL MFCD00011623, Note: Special handling precautions required. View MSDS prior to purchase. MSDS are available online at www.alfa.com, Ì

R:45-46-60-25-36/37/38-42/43, S:53-20-23-24-26-27/28a-37/39-45

1-800-343-0660 31 Platinum Stock # Description Standard Selling Sizes 10472 trans-Diamminedichloroplatinum(II), Pt 64.5% min 250mg [Dichlorodiammineplatinum(II), Transplatin] 1g

[14913-33-8], PtCl2(NH3)2, F.W. 300.06, Crystalline, m.p. 340ø dec., EINECS 238-980-9, 5g RTECS TP2455000, MDL MFCD00011623 bulk

R:36/37/38-42/43, S:23-24-26-37 11054 Diammineplatinum(II) nitrite solution, Pt 1.7% w/w (cont. Pt) (c)0.5g [P salt] (c)2g

[14286-02-3], (NH3)2Pt(NO2)2, F.W. 321.16(anhy), Liquid, UN2672, MDL MFCD00011622, Ì bulk

R:34, S:20-23-26-36/37/39-45 10475 trans-Diamminetetrachloroplatinum(IV), Pt 52.6% Ê 1g

[16893-06-4], PtCl4(NH3)2, F.W. 370.96, Crystalline, MDL MFCD00050045 bulk

R:36/37/38-42/43-68, S:22-26-36/37-45 39282 Dibromo(1,5-cyclooctadiene)platinum(II), Pt 41.6% min Ê 1g

[12145-48-1], C8H12Br2Pt, F.W. 463.09, Powder, MDL MFCD00058724 5g bulk R:36/37/38, S:26-37 10482 cis-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7% 500mg

[15442-57-6], Pt[(C2H5)2S]2Cl2, F.W. 446.37, Crystalline, Solubility: Soluble in acetone, alcohol 1g and benzene, Application(s): Hydrogenation, EINECS 239-454-1, MDL MFCD00050943 bulk

R:36/37/38, S:26 10484 trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7% 1g

[15337-84-5], Pt[(C2H5)2S]2Cl2, F.W. 446.37, Crystalline, Solubility: Soluble in acetone, alcohol 5g and benzene, Application(s): Hydrosilation, EINECS 239-373-1, MDL MFCD00050943 bulk

R:36/37/38, S:26 39667 cis-Dichlorobis(ethylenediamine)platinum(II), 99.9% (metals basis) Ê 1g Compounds and Pt(C2H8N2)2Cl2, F.W. 386.19, Crystalline, MDL MFCD00009881 5g bulk R:36/37/38, S:26 Homogeneous Catalysts 39284 cis-Dichlorobis(triethylphosphine)platinum(II) Ê 500mg

[15692-07-6], PtCl2[P(C2H5)3]2, F.W. 502.32, Powder, m.p. 139-142ø, MDL MFCD00058821 bulk

R:36/37/38-42/43, S:22-24-26-37-45-60 10492 cis-Dichlorobis(triphenylphosphine)platinum(II), Pt 24.2% min Ê 250mg

[15604-36-1], PtCl2[P(C6H5)3]2, F.W. 790.58, Crystalline, m.p. 310ø dec., Solubility: Slightly 1g soluble in chloroform, hexane toluene, MDL MFCD00010825 bulk

R:36/37/38, S:26 41008 cis-Dichlorobis(triphenylphosphine)platinum(II), Premion®, 99.95% (metals basis), 1g Pt 24.2% min Ê 5g

[15604-36-1], PtCl2[P(C6H5)3]2, F.W. 790.58, Powder, m.p. 310ø dec., MDL MFCD00010825 bulk

R:36/37/38, S:26 44038 cis-Dichlorobis(triphenylphosphite)platinum(II) 500mg

[30053-58-8], Pt[P(OC6H5)3]2Cl2, F.W. 886.56, Powder, MDL MFCD00010825 1g 5g R:36/37/38-42, S:22-26-36/37-45 bulk 12739 Dichloro(1,5-cyclooctadiene)platinum(II), Pt 52.1% Ê 250mg

[12080-32-9], C8H12Cl2Pt, F.W. 374.18, Solid, m.p. 250ø dec., Solubility: Soluble 1g in dichloromethane, EINECS 235-144-5, MDL MFCD00012413, Ì 5g bulk R:36/37/38, S:26-37 44033 Di-æ-chlorodichlorobis(cyclohexene)diplatinum(II) bulk

[60134-75-0], [PtCl2(C6H10)]2, F.W. 692.26, Powder, MDL MFCD00050944 39285 Di-æ-chlorodichlorobis(ethylene)diplatinum(II), 97% 250mg

[12073-36-8], C4H8Cl4Pt, F.W. 588.10, Crystalline, EINECS 235-135-6, 1g MDL MFCD00058713 bulk

R:36/37/38-42/43, S:22-24-26-37-45 10497 Dichloro(ethylenediamine)platinum(II), Pt 59.7% min Ê 250mg

[14096-51-6], PtCl2(H2NCH2CH2NH2), F.W. 326.10, Crystalline/Powder, EINECS 237-943-4, 1g MDL MFCD00000011 bulk

R:36/37/38, S:26 44035 Dichloro(norbornadiene)platinum(II) bulk

[12152-26-0], PtCl2(C7H8), F.W. 358.13, Crystalline, MDL MFCD00213423

32 www.alfa.com Platinum Stock # Description Standard Selling Sizes 12627 Dihydrogen dinitrosulfatoplatinate(II) solution, Pt 4-6% (cont. Pt) (c)0.5g [Dinitrosulfatoplatinum(II), Hydrogen dinitrosulfatoplatinate(II)] (c)2g

[12033-81-7], H2Pt(NO2)2SO4, F.W. 384.17(anhy), Liquid, UN3264, MDL MFCD00064668, (c)10g Note: Pt DNS Solution, Ì bulk

R:34, S:20-26-36/37/39-45 12617 Dihydrogen hexabromoplatinate(IV) nonahydrate, 99.9% (metals basis), Pt 23.7% min 1g [Bromoplatinic acid, Platinic bromide] 5g

[20596-34-3], H2Br6Ptù9H2O, F.W. 838.67 (676.56anhy), Crystalline, UN3260, bulk EINECS 243-903-7, MDL MFCD00049645, Ì

R:34-42/43, S:20-22-26-36/37/39-45-60 40177 Dihydrogen hexachloroplatinate(IV) solution, Pt 20% (cont. Pt) (c)0.5g

[16941-12-1], H2PtCl6, F.W. 409.82(anhy), Liquid, Merck 14,7526, UN2507, (c)2g EINECS 241-010-7, MDL MFCD00011330, Ì (c)10g bulk R:25-34-42/43, S:26-36/37/39-45 11051 Dihydrogen hexachloroplatinate(IV) hexahydrate, 99.9% (metals basis) Ê 1g [CPA, Chloroplatinic acid] 5g Catalysts Homogeneous

[26023-84-7], H2PtCl6ù6H2O, F.W. 517.91 (409.82anhy), Crystalline, m.p. 60ø dec., d. 2.430, 25g

Merck 14,7526, Fieser 1,890 4,87 13,145 15,135, Solubility: Soluble in water, alcohol, acetone, bulk and Compounds ethyl acetate and ether, Application(s): Catalysis, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink, microscopy, UN2507, EINECS 241-010-7, RTECS TP1500000, MDL MFCD00149910, Ì

R:25-34-42/43, S:22-26-36/37/39-45 36259 Dihydrogen hexachloroplatinate(IV) hexahydrate, ACS, Premion®, 1g 99.95% (metals basis), Pt 37.5% min Ê 5g

[26023-84-7], H2PtCl6ù6H2O, F.W. 517.91 (409.82anhy), Lump, m.p. 60ø dec., d. 2.430, 25g Merck 14,7526, Fieser 1,890 4,87 13,145 15,135, UN2507, EINECS 241-010-7, bulk RTECS TP1500000, MDL MFCD00149910, Ì Maximum level of impurities: Solubility in alcohol P.T., Alkali and other salts (as sulfates) 0.05%, Suitability for potassium determinations P.T.

R:25-34-42/43, S:22-26-36/37/39-45 42815 Dihydrogen hexachloroplatinate(IV) hexahydrate, low nitrate, Premion®, 1g 99.95% (metals basis), Pt 37.5% min Ê 5g

R:25-34-42/43, S:22-26-36/37/39-45 43696 Dihydrogen hexachloroplatinate(IV) hydrate, Premion®, 99.999% (metals basis) Ê 1g

[26023-84-7], H2PtCl6ùxH2O, F.W. 409.82(anhy), Crystalline, m.p. 60ø dec., d. 2.430, 5g Merck 14,7526, Fieser 1,890 4,87 13,145 15,135, UN2507, EINECS 241-010-7, bulk RTECS TP1500000, MDL MFCD00149909, Ì

R:25-34-42/43, S:22-26-36/37/39-45 11052 Dihydrogen hexahydroxyplatinate(IV), 99.9% (metals basis), Pt 61.0% min É 500mg [Hexahydroxyplatinic acid] 1g

[51850-20-5], H2Pt(OH)6, F.W. 299.17, Crystalline, EINECS 257-471-2, MDL MFCD00058744 5g bulk R:36/37/38, S:26 44039 Diphenyl(1,5-cyclooctadiene)platinum(II) 1g

[12277-88-2], Pt(C8H12)(C6H5)2b, F.W. 457.47, Powder, MDL MFCD03788255 5g bulk R:36/37/38, S:26-37 39286 Iodotrimethylplatinum(IV) ß È 500mg

[14364-93-3], (CH3)3PtI, F.W. 367.09, Crystalline, MDL MFCD00013702 1g bulk R:36/38, S:26-37 40404 Lithium tetracyanoplatinate(II) hydrate, Premion®, 99.95% (metals basis) 1g [Lithium platinocyanide] 5g

Li2Pt(CN)4ùxH2O (x÷5), F.W. 313.04(anhy), Crystalline, Merck 14,5542, Solubility: Slightly bulk soluble in water, Application(s): X-ray photography, MDL MFCD00798528 12172 Platinum(II) bromide, 99.9% (metals basis), Pt 54.5% min 1g

[13455-12-4], PtBr2, F.W. 354.91, Crystalline, m.p. 250ø dec., EINECS 236-648-8, 5g MDL MFCD00011180, Ì bulk

R:36/37/38, S:26-37

1-800-343-0660 33 Platinum Stock # Description Standard Selling Sizes 12171 Platinum(IV) bromide, 99.99% (metals basis), Pt 37.2% min 1g

[68938-92-1], PtBr4, F.W. 514.73, Crystalline, m.p. 180ø dec., UN3260, EINECS 273-151-5, 5g MDL MFCD00016289, Ì bulk

R:34, S:20-26-36/37/39-45-60 11044 Platinum(II) chloride, 99.9% (metals basis), Pt 73% min 1g

[10025-65-7], PtCl2, F.W. 266.00, Crystalline, m.p. 581ø dec., d. 5.87, Merck 14,7528, 5g Solubility: Insoluble in water, alcohol, ether. Soluble in HCl, NH4OH, EINECS 233-034-1, bulk MDL MFCD00011181, Ì

R:36/37/38, S:26-36/37 43090 Platinum(II) chloride, Premion®, 99.99+% (metals basis), Pt 73% min 1g

[10025-65-7], PtCl2, F.W. 266.00, Powder, m.p. 581ø dec., d. 5.87, Merck 14,7528, 5g EINECS 233-034-1, MDL MFCD00011181, Ì bulk

R:36/37/38, S:26-36/37 11045 Platinum(IV) chloride, 99.9% (metals basis), Pt 57% min Ê 1g

[13454-96-1], PtCl4, F.W. 336.90, Crystalline, m.p. 370ø dec., UN3260, EINECS 236-645-1, 5g MDL MFCD00011182, Ì bulk

R:22-34-42/43-68, S:20-22-26-36/37/39-45-60 43703 Platinum(IV) chloride, Premion®, 99.99+% (metals basis), Pt 57% min Ê 1g

[13454-96-1], PtCl4, F.W. 336.90, Crystalline, m.p. 370ø dec., UN3260, EINECS 236-645-1, 5g MDL MFCD00011182, Ì bulk

R:22-34-42/43-68, S:20-22-26-36/37/39-45-60 44503 Platinum(IV) chloride, Premion®, 99.99+% (metals basis), Pt 57% min Ê 1g

[13454-96-1], PtCl4, F.W. 336.90, Crystalline Soluble, m.p. 370ø dec., UN1759, 5g EINECS 236-645-1, MDL MFCD00011182, Ì bulk

Compounds and R:22-34-42/43-68, S:20-22-26-36/37/39-45-60 41508 Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated 1g

Homogeneous Catalysts polydimethylsiloxane É 5g

[68478-92-2], O[Si(CH3)2CH=CH2]2Pt, F.W. 381.00, Liquid, d. 0.984, Application(s): Catalyst 25g for Si-H addition to olefins silicone vinyl addition room temperature cure catalyst, bulk MDL MFCD00151662, Ì

R:36/37/38, S:26-37 12170 Platinum(II) iodide, Premion®, 99.99% (metals basis), Pt 43.0% min 250mg

[7790-39-8], PtI2, F.W. 448.90, Powder, m.p. 325ø dec., Solubility: Insoluble in water, alkali 1g iodides, EINECS 232-204-2, MDL MFCD00011183, Ì 5g bulk R:36/37/38-43, S:24-26-37 40401 Platinum(IV) iodide, Premion®, 99.95% (metals basis), Pt 27.3% min 250mg

[7790-46-7], PtI4, F.W. 702.70, Powder, m.p. 130ø dec., d. 6.06, Solubility: Decomposes in 1g water. Soluble in alcohol, acetone, alkali, HI, KI, liquid NH3, UN3260, MDL MFCD00016292 5g bulk R:34, S:20-26-36/37/39-43h-45-60 12278 Platinum(IV) oxide monohydrate, Adams Catalyst, Pt 75% min 1g 2 [1314-15-4], PtO2ùH2O, F.W. 245.10 (227.09 anhy), Powder, S.A. >85m /g, m.p. 450ø, 5g Merck 14,7527, Solubility: Insoluble in water, acid, aqua regia, Application(s): Hydrogenation bulk catalyst. Suitable for the reduction of double and triple bonds, aromatics, carbonyls, nitriles, and nitro groups, UN1479, EINECS 215-223-0, MDL MFCD00066964, Note: Electrochemically prepared for catalyst use, Ì

R:8-43, S:17-24-37-60 11049 Platinum(IV) oxide hydrate, 99.9% (metals basis), Pt 71-75% 250mg

[1314-15-4], PtO2, F.W. 227.09, Powder, m.p. 450ø, d. 10.2, Merck 14,7527, UN1479, 1g EINECS 215-223-0, MDL MFCD00011184, Ì 5g bulk R:8-43, S:17-24-37-60 10526 Platinum(II) 2,4-pentanedionate, Pt 48.0% min 1g [Platinum(II) acetylacetonate] 5g

[15170-57-7], C10H14O4Pt, F.W. 393.31, Needles, m.p. 250-252ø, Solubility: Very bulk soluble in chloroform, EINECS 239-223-5, MDL MFCD00000028, Ì

34 www.alfa.com Platinum Stock # Description Standard Selling Sizes 13992 Platinum(IV) sulfide, Pt 74.8% min 1g

[12038-21-0], PtS2, F.W. 259.22, Powder, m.p. 225-250ø dec., EINECS 234-876-2, 5g MDL MFCD00016293, Ì bulk 12169 Potassium hexachloroplatinate(IV), Pt 40.1% Ê 250mg

[16921-30-5], K2PtCl6, F.W. 486.01, Powder, m.p. 250ø, d. 3.50, Ë ÷1.825, Merck 14,7636, 1g Solubility: Soluble in hot water. Slightly soluble in cold water. Practically insoluble in alcohol, 5g EINECS 240-979-3, MDL MFCD00011389, Ì bulk

R:25-41-42/43, S:22-26-36/37/39-45 12678 Potassium hexacyanoplatinate(IV) 1g

[16920-94-8], K2Pt(CN)6, F.W. 429.40, Powder, EINECS 240-978-8, MDL MFCD00058745 5g bulk R:20/22-36/37/38, S:7/9-26-28a-36/37-45 41014 Potassium hexahydroxyplatinate(IV), Premion®, 99.95% (metals basis), Pt 51.5% min 1g

[12285-90-4], K2Pt(OH)6, F.W. 375.34, Powder, MDL MFCD00064671, Ì 5g bulk R:36/38, S:26 12642 Potassium hexaiodoplatinate(IV), Pt 18.2% min 1g ooeeu Catalysts Homogeneous [16905-14-9], K2PtI6, F.W. 1034.72, Crystalline, EINECS 240-954-7, MDL MFCD00049660 5g bulk

R:36/37/38, S:26 and Compounds 11048 Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min Ê 1g

[10025-99-7], K2PtCl4, F.W. 415.11, Crystalline, Merck 14,7682, Solubility: Soluble in water, 5g EINECS 240-979-3, MDL MFCD00011378, Ì 25g bulk R:25-38-41-42/43, S:22-26-36/37/39-45 43946 Potassium tetrachloroplatinate(II), Premion®, 99.99% (metals basis), Pt 46.4% min 1g

[10025-99-7], K2PtCl4, F.W. 415.11, Crystalline, Merck 14,7682, EINECS 240-979-3, 5g MDL MFCD00011378, Ì 25g bulk R:25-38-41-42/43, S:22-26-36/37/39-45 10536 Potassium tetracyanoplatinate(II) trihydrate, 99.9% (metals basis), Pt 45.2% 1g

[14323-36-5], K2[Pt(CN)4]ù3H2O, F.W. 431.42 (377.37anhy), Crystalline, Merck 14,7685, 5g Solubility: Soluble in hot water, EINECS 209-236-0, MDL MFCD00149921, Ì bulk

R:20/22, S:9-36 10538 Potassium tetranitroplatinate(II), Pt 42.6% min 1g

[13815-39-9], K2Pt(NO2)4, F.W. 457.32, Crystalline, EINECS 237-491-8, 5g MDL MFCD00011375, Ì bulk 39433 Potassium trichloroammineplatinate(II) 500mg [Potassium amminetrichloroplatinate(II)] bulk

[13820-91-2], K(PtCl3NH3), F.W. 357.56, Crystalline, MDL MFCD00145154

R:36/37/38, S:26-37 44028 Potassium trichloro(ethylene)platinate(II) Ê bulk

[12012-50-9], K[PtCl3(C2H4)]ùxH2O, F.W. 368.61(anhy), Powder, m.p. 220ø dec., MDL MFCD00150524, Note: Zeise's salt 88966 Sodium hexabromoplatinate(IV) hexahydrate 1g

[39277-13-9], Na2PtBr6ù6H2O, F.W. 828.49 (720.49anhy), Crystalline, EINECS 254-398-8, 5g MDL MFCD00014237, Ì bulk

R:36/37/38-42/43, S:22-24-26-37-45 11047 Sodium hexachloroplatinate(IV) hexahydrate 1g [Sodium chloroplatinate] 5g

[16923-58-3], Na2PtCl6ù6H2O, F.W. 561.88 (453.79anhy), Crystalline, m.p. 110ø -6H2O, d. 2.50, bulk Merck 14,8623, Solubility: Soluble in water, alcohol. Insoluble in ether, Application(s): Catalyst, EINECS 240-983-5, MDL MFCD00003488, Ì

R:25-41-42/43, S:22-26-36/37/39-45 44043 Sodium hexahydroxyplatinate(IV) solution, Pt 7-10% w/v (cont. Pt) bulk

[12325-31-4], Na2[Pt(OH)6], F.W. 343.10(anhy), Liquid, MDL MFCD00014236 12620 Sodium hexahydroxyplatinate(IV), 99.9% (metals basis) 1g

[12325-31-4], Na2Pt(OH)6, F.W. 343.11, Crystalline, m.p. 150ø dec., EINECS 235-590-0, 5g MDL MFCD00014236, Note: Pt 57%, Ì bulk

R:36/38, S:26 41018 Sodium hexaiodoplatinate(IV) hexahydrate, Premion®, 99.95% (metals basis), 1g Pt 17.1% min 5g

Na2PtI6ù6H2O, F.W. 1110.58 (1002.50anhy), Powder, MDL MFCD00798546 bulk

R:36/37/38-43, S:24-26-37

1-800-343-0660 35 Platinum Stock # Description Standard Selling Sizes 12168 Sodium tetrachloroplatinate(II) hydrate, Premion®, 99.95% (metals basis), 1g Pt 42.4% min 5g [Sodium platinum chloride, Sodium chloroplatinate(II)] bulk

Na2PtCl4ùxH2O (x÷3), F.W. 382.88(anhy), Crystalline, m.p. 100ø, EINECS 233-051-4, MDL MFCD00150188, Ì

R:25-38-41-42/43, S:22-26-36/37/39-45 40400 Sodium tetracyanoplatinate(II) hydrate, Premion®, 99.95% (metals basis), Pt 48.4% min 1g

Na2Pt(CN)4ùxH2O (x÷3), F.W. 345.14(anhy), Crystalline Powder, MDL MFCD00798527 5g bulk R:20/22, S:9-36 44045 Tetraammineplatinum(II) chloride solution, Pt 8-10% w/w (cont. Pt) (c)1g

[13933-32-9], [Pt(NH3)4]Cl2, F.W. 334.11(anhy), Liquid, MDL MFCD00011475, Ì (c)5g bulk R:36/37/38, S:26-37 10544 Tetraammineplatinum(II) chloride monohydrate Ê 1g

[13933-33-0], Pt(NH3)4Cl2ùH2O, F.W. 352.13 (334.11anhy), Crystalline, m.p. 250ø, d. 2.7, 5g EINECS 237-706-5, MDL MFCD00149947, Ì 25g bulk R:36/37/38-43, S:24-26-37 10836 Tetraammineplatinum(II) chloride monohydrate, Premion®, 99.998% (metals basis) Ê 1g

[13933-33-0], Pt(NH3)4Cl2ùH2O, F.W. 352.13 (334.11anhy), Crystalline, m.p. 250ø, d. 2.7, 5g EINECS 237-706-5, MDL MFCD00149947, Ì bulk

R:36/37/38-43, S:24-26-37 44042 Tetraammineplatinum(II) hydrogen carbonate 1g

[123439-82-7], [Pt(NH3)4](HCO3)2, F.W. 385.24, Crystalline, MDL MFCD03788256 5g bulk 44076 Tetraammineplatinum(II) hydrogen phosphate solution, Pt 0.5% w/w (cont. Pt) (c)1g [5Q Salt] (c)5g Compounds and [127733-98-6], [Pt(NH3)4]HPO4, F.W. 359.18(anhy), Liquid, MDL MFCD03788258 bulk 44047 Tetraammineplatinum(II) hydrogen phosphate solution, Pt 2% w/w (cont. Pt) (c)1g Homogeneous Catalysts [20Q Salt] (c)5g

[127733-98-6], [Pt(NH3)4]HPO4, F.W. 359.18(anhy), Liquid, MDL MFCD03788258 bulk

R:42/43, S:23-25-37 42918 Tetraammineplatinum(II) hydroxide solution, Pt 8-11% w/w (cont. Pt) (c)1g

[38201-97-7], (NH3)4Pt(OH)2, F.W. 297.23, Liquid, EINECS 253-823-4, MDL MFCD00050044, Ì (c)5g (c)25g R:43, S:23-24-37 bulk 12167 Tetraammineplatinum(II) nitrate solution, Pt 3-4% w/w (cont. Pt) (c)0.5g

[20634-12-2], (NH3)4Pt(NO3)2, F.W. 387.00, Liquid, UN3218, EINECS 243-929-9, (c)2g MDL MFCD00011624 bulk

R:8-34-43, S:17-20-23-26-36/37/39-45 88960 Tetraammineplatinum(II) nitrate 1g

[20634-12-2], (NH3)4Pt(NO3)2, F.W. 387.00, Powder, m.p. 262ø dec., UN1477, 5g EINECS 243-929-9, MDL MFCD00011624 bulk

R:5-8-36/37-43, S:17-24-26-37 39444 Tetraammineplatinum(II) tetrachloroplatinate(II) 1g [Magnus Green salt] bulk

[13820-46-7], [Pt(NH3)4][PtCl4], F.W. 600.12, Powder, m.p. 320ø dec., d. 4.000, EINECS 237-501-0, MDL MFCD01459899, Ì

R:25-41-42/43, S:22-26-36/37/39-45 10549 Tetrakis(triphenylphosphine)platinum(0), Pt 15.2% min È 1g

[14221-02-4], Pt[P(C6H5)3]4, F.W. 1244.21, Crystalline Powder, Solubility: Soluble in benzene, 5g Application(s): Hydrosilation and oxidation, EINECS 238-087-4, MDL MFCD00010014, Ì bulk

R:22, S:36 43474 Trimethylbenzylammoniumhexachloroplatinate(IV), Premion®, 99.99% (metals basis) 1g

[C6H5CH2N(CH3)3]2PtCl6, F.W. 708.28, Powder, MDL MFCD00054403 5g bulk R:25-41-42/43, S:22-26-36/37/39-45 98158 Trimethyl(methylcyclopentadienyl)platinum(IV) 500mg

[94442-22-5], C9H16Pt, F.W. 319.32, Powder/Pieces, m.p. 28-31ø, bulk b.p. 23ø/0.053mm subl., MDL MFCD00079665, Ì

36 www.alfa.com Rhodium

Stock # Description Standard Selling Sizes 12645 Ammonium aquopentachlororhodate(III), Rh 30% min 1g [Ammonium pentachlororhodate] 5g

[63771-33-5], (NH4)2[RhCl5(H2O)], F.W. 334.26, Powder, m.p. 210-230ø dec., bulk EINECS 264-455-9, MDL MFCD00064673, Ì

R:22-36/37/38, S:26-36/37-60 11812 Ammonium hexachlororhodate(III) hydrate, Premion®, 99.99% (metals basis) Ê 250mg

(NH4)3RhCl6ùxH2O (x÷1) (formula not proven), F.W. 369.74(anhy), Powder, EINECS 239-364-2, 1g MDL MFCD00003394, Ì 5g bulk 10849 Ammonium hexachlororhodate(III) hydrate, Premion®, 99.995% (metals basis) Ê 500mg

(NH4)3RhCl6ùxH2O (x÷1) (formula not proven), F.W. 369.74(anhy), Powder, EINECS 239-364-2, 1g MDL MFCD00003394, Ì 5g bulk 44031 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1g Catalysts Homogeneous

[35138-22-8], [Rh(C8H12)2]BF4, F.W. 406.08, Powder, MDL MFCD00075045 5g

bulk and Compounds 39289 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate È 500mg [Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate] 2g

[99326-34-8], C17H24F3O3RhS, F.W. 468.34, Crystalline, Packaged under bulk argon, Solubility: Soluble in chloroform, MDL MFCD00143752

R:36/37/38, S:26-37 44546 (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)- 50mg rhodium(I) trifluoromethanesulfonate È É 250mg

[142184-30-3], Rh(C8H12)(C22H36P2)CF3SO3, F.W. 722.63, Crystalline, Packaged bulk under argon, Application(s): Catalytic asymmetric cycloisomerization and enantio selections hydrogenation reactions, MDL MFCD00269861, Note: Store cold 39288 Bis(ethylene)(2,4-pentanedionato)rhodium(I), Rh 39.9% min È 250mg [(Acetylacetonato)bis(ethylene)rhodium(I)] 1g

[12082-47-2], C9H15O2Rh, F.W. 258.13, Crystalline, Solubility: Soluble in bulk dichloromethane, chloroform, EINECS 235-147-1, MDL MFCD00015354

44036 Bis(norbornadiene)rhodium(I) tetrafluoroborate È É 1g

[36620-11-8], [Rh(C7H8)2]BF4, F.W. 373.99, Powder, MDL MFCD00671775 5g bulk R:22-36/37/38, S:26-36/37 39821 Bromotris(triphenylphosphine)rhodium(I), 99.95% (metals basis), Rh 10.1% min 250mg

[14973-89-8], RhBr[(C6H5)3P]3, F.W. 969.69, Crystalline, Solubility: Soluble in chlorinated 1g solvents, Application(s): Hydrogenation, EINECS 239-050-5, MDL MFCD00009828 5g bulk 41004 Carbonylbromobis(triphenylphosphine)rhodium(I), Premion®, 99.95% (metals basis), 1g Rh 13.5% min 5g [Bromocarbonylbistriphenylphosphinerhodium(I)] bulk

[14056-79-2], RhBr(CO)[P(C6H5)3]2, F.W. 735.41, Powder, Solubility: Soluble in chloroform, MDL MFCD00064608

R:36/37/38, S:26-37 39822 Carbonylchlorobis(triphenylphosphine)rhodium(I), Rh 14.9% min 250mg [Carbonylbis(triphenylphosphine)rhodium(I) chloride] 1g

[13938-94-8], RhCl(CO)[P(C6H5)3]2, F.W. 690.71, Crystalline, Fieser 5,46 6,105 15,69, 5g Solubility: Soluble in acetone, chloroform, ethanol, EINECS 237-712-8, MDL MFCD00044273 bulk

R:20/21/22, S:9-36/37-60 10016 Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2% min É 100mg [Tris(triphenylphosphine)rhodium carbonyl hydride] 1g

[17185-29-4], RhH(CO)[P(C6H5)3]3, F.W. 918.19, Crystals, Solubility: Soluble in hydrocarbons 5g (e.g. benzene and toluene) with dissociation of phosphine ligands, bulk Application(s): Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation, UN2813, EINECS 241-230-3, MDL MFCD00151644, Ì

R:15-22, S:7/8-33-36-43h

1-800-343-0660 37 Rhodium Stock # Description Standard Selling Sizes 10458 Carbonyl-2,4-pentanedionato(triphenylphosphine)rhodium(I), Rh 21% 250mg

[25470-96-6], C24H22O3PRh, F.W. 492.32, Crystals, Merck 14,356, 1g Solubility: Soluble in acetone and chlorinated solvents, 5g Application(s): Hydroformylation, EINECS 247-015-0, MDL MFCD00064611, Ì bulk

R:36/37/38, S:26-37 39291 Chlorobis(ethylene)rhodium(I) dimer, 99% È 1g

[12081-16-2], [RhCl(C2H4)2]2, F.W. 388.93, Powder, EINECS 235-145-0, MDL MFCD00013206 bulk S:22 10466 Chloro(1,5-cyclooctadiene)rhodium(I) dimer È Ê 250mg [Bis(1,5-cyclooctadiene)dirhodium(I) dichloride] 1g

[12092-47-6], C16H24Cl2Rh2, F.W. 493.08, Crystalline, m.p. 243ø dec., bulk Solubility: Sparingly soluble in most common solvents, EINECS 235-157-6, MDL MFCD00012415, Note: Slowly decomposes in air, Ì

R:36/37/38, S:26-37 10468 Chlorotris(triphenylphosphine)rhodium(I), 97% 1g [Wilkinson's catalyst, Tris(triphenylphosphine)rhodium(I) chloride] 5g

[14694-95-2], RhCl[(C6H5)3P]3, F.W. 925.23, Micro Crystals, m.p. 245-250ø, Merck 14,10047, bulk Solubility: Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but

with phosphine dissociation. Reacts with O2 in solution, EINECS 238-744-5, MDL MFCD00010016, Note: Slowly decomposes in air, Ì

R:36/37/38, S:26-37 39295 Dicarbonyl(2,4-pentanedionato)rhodium(I), 99% 250mg [(Acetylacetonato)dicarbonylrhodium(I)] 1g

[14874-82-9], C7H7RhO4, F.W. 258.04, Crystalline, m.p. 144-147ø subl., 5g Fieser 19,119 20,134 21,1, Solubility: Soluble in acetone, UN3466, bulk EINECS 238-947-9, MDL MFCD00009884, Ì

Compounds and R:25-36/37/38, S:20-26-36/37-45-60 10467 Di-æ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min 500mg

Homogeneous Catalysts [Chloro(norbornadiene)rhodium(I) dimer] 1g

[12257-42-0], C14H16Cl2Rh2, F.W. 461.01, Powder, EINECS 235-510-4, bulk MDL MFCD00198060

R:36/37/38, S:26-37 33657 Dichloropentamethylcyclopentadienylrhodium(III) dimer, 99% 250mg

[12354-85-7], C10H15Cl4Rh2, F.W. 618.08, Powder, m.p. >300ø, 1g MDL MFCD00061552 bulk

R:36/37/38-42, S:22-26-36/37-45

44686 Dirhodium(II) tetrakis(caprolactam) 25mg

[138984-26-6], C24H40N4O4Rh2, F.W. 654.43, Powder, 100mg MDL MFCD00467690, Note: Nominal rhodium content=31.54% 500mg bulk

44552 Dirhodium(II) tetrakis(methyl 100mg 2-oxazolidone-4(S)-carboxylate), acetonitrile (1:2) bulk complex É

[Doyle dirhodium catalyst, Rh2(4S-MEOX)4]

[167693-36-9], C24H32N4O16Rhù2CH3CN, F.W. 920.45, Powder, Packaged under argon, m.p. 293ø dec., UN2811, MDL MFCD00467689, Note: Rh 23.81%

R:25-36/37/38, S:20-26-36/37-45-60

38 www.alfa.com Rhodium Stock # Description Standard Selling Sizes 44707 Dirhodium(II) tetrakis(methyl 100mg 2-pyrrolidinone-5(R)-carboxylate)acetonitrile/2-propanol 500mg complex bulk

[Rh2(5R-MEPY)4]

[131796-58-2], C24H28N4O12Rh2ùCH3CN/CH3CH(OH)CH3, F.W. 871.46, Powder, Packaged under argon, UN2811, MDL MFCD00192122, Note: Rh nominally 26.58%

R:20/21/22, S:9-36/37-60 44638 Dirhodium(II) tetrakis(methyl 100mg 2-pyrrolidinone-5(S)-carboxylate)acetonitrile/2-propanol 500mg complex, Rh nominally 25.5% bulk

[Rh2(5S-MEPY)4]

[132435-65-5], C24H28N4O12Rh2ùCH3CN/CH3CH(OH)CH3, F.W. 871.46, Powder, Packaged under argon, MDL MFCD00192123

R:22-36/37/38, S:26-36/37 43004 Hexa(acetato)-æ-oxotris(aqua)trirhodium(III) acetate 1g Catalysts Homogeneous [Rhodium(III) acetate] 5g

[42204-14-8], [Rh3(OOCCH3)6-æ-O(H2O)3]OAc, F.W. 792.07, Powder, Solubility: Soluble in bulk and Compounds water, acetic acid, MDL MFCD01074923

R:36/37, S:26-60 10512 Hexadecacarbonylhexarhodium, 98+% È 250mg [Rhodium hexacarbonyl, Rhodium carbonyl] 1g

[28407-51-4], Rh6(CO)16, F.W. 1065.61, Crystalline, Solubility: Very sparingly soluble in bulk chloroform, carbon tetrachloride and dichloromethane, Application(s): Hydrogenation, UN3466, EINECS 249-009-3, MDL MFCD00011206, Ì

R:23/24/25, S:4-9-20-27-36/37-45-60 44030 Hydridotetrakis(triphenylphosphine)rhodium(I), Rh 8.9% min È 1g

[18284-36-1], RhH[P(C6H5)3]4, F.W. 1153.09, Powder, m.p. 145-147ø dec., Solubility: Soluble 5g in chloroform, toluene, MDL MFCD00015867 bulk

R:36/37/38, S:26-37

44801 [(S)-Paraphos Rhodium (NBD)]BF4 100mg

C47H42P2RhBF4, F.W. 858.51, Powder, MDL MFCD08064215 bulk

44805 [(R)-Paraphos Rhodium (NBD)]BF4 bulk

C47H42P2RhBF4, F.W. 858.51, Powder, MDL MFCD08064215 10519 Pentaamminechlororhodium(III) chloride, Rh 34.5% min Ê 500mg

[13820-95-6], [RhCl(NH3)5]Cl2, F.W. 294.42, Micro Crystals, m.p. dec., EINECS 237-505-2, 1g MDL MFCD00135665, Ì 5g bulk R:36/37/38, S:26-37 41013 Potassium hexachlororhodate(III), Premion®, 99.99% (metals basis), Rh 23.3% min Ê 250mg

[13845-07-3], K3RhCl6, F.W. 432.93, Powder, EINECS 237-569-1, MDL MFCD00192414, Ì 1g 5g R:36/37/38, S:26-37 bulk 40410 Potassium hexanitrorhodate(III), Premion®, 99.99% (metals basis), Rh 20.2% min 1g

[17712-66-2], K3Rh(NO2)6, F.W. 496.24, Powder, EINECS 241-716-5, MDL MFCD00049776 5g bulk R:36/37/38, S:26-37-60 11053 Potassium pentachlororhodate(III) hydrate, 99.9% (metals basis), Rh 29% 1g

K2RhCl5ùxH2O, F.W. 358.37(anhy), Powder, MDL MFCD00049661, Ì 5g R:22/36/38, S:22/26 bulk 40409 Potassium pentachlororhodate(III), Premion®, 99.99% (metals basis), Rh 28.2% min 1g

K2RhCl5, F.W. 358.37, Powder, Solubility: Slightly soluble in cold water. Insoluble in alcohol, 5g MDL MFCD00049661 bulk R:22/36/38, S:22/26 L15152 Rhodium(II) acetate, dimer, 98+% 100mg [Dirhodium tetraacetate] 500mg

[15956-28-2], [Rh(CO2CH3)2]2, F.W. 441.99, m.p. 205ø, Fieser 5,571 8,434 13,266 15,278 2g 16,289 17,298 18,306 20,318 21,367, EINECS 240-084-8, RTECS VI9361000, bulk MDL MFCD00003538 S:22-24/25

1-800-343-0660 39 Rhodium Stock # Description Standard Selling Sizes 10560 Rhodium(II) acetate, dimer, Premion®, 99.99% (metals basis), Rh 46.2% min 250mg [Tetrakis(aceto)dirhodium(II)] 1g

[15956-28-2], [Rh(CO2CH3)2]2, F.W. 441.99, Powder, m.p. 205ø, Fieser 5,571 8,434 13,266 5g 15,278 16,289 17,298 18,306 20,318 21,367, Solubility: Slightly soluble in ethanol, bulk Application(s): Cyclopropanation of alkenes, EINECS 226-843-6, RTECS VI9361000, MDL MFCD00003538 S:22-24/25 11816 Rhodium(III) bromide hydrate Ê 1g

[123333-87-9], RhBr3ùxH2O, F.W. 342.62(anhy), Crystalline, EINECS 239-687-9, 5g MDL MFCD00149837, Ì bulk

R:36/37/38, S:26-37

Rh2(capy)4, see Dirhodium(II) tetrakis(caprolactam), 44686, p. 38 11032 Rhodium(III) chloride hydrate, Rh 38.5-45.5% Ê 250mg

[20765-98-4], RhCl3ùxH2O, F.W. 209.26(anhy), Crystalline, m.p. 100ø dec., Merck 14,8188, 1g Solubility: Soluble in alcohol, water. Slightly soluble in acetone, MDL MFCD00149839, Ì 5g bulk R:22-36, S:26-36 43702 Rhodium(III) chloride hydrate, Premion®, 99.99% (metals basis) 1g

[20765-98-4], RhCl3ùxH2O, F.W. 209.26(anhy), Crystalline, m.p. 100ø dec., Merck 14,8188, 5g MDL MFCD00149839, Ì bulk

R:22-36, S:26-36 11815 Rhodium(III) chloride, anhydrous, 99.9% (metals basis), Rh 48.7% min Ê 250mg

[10049-07-7], RhCl3, F.W. 209.26, Powder, Merck 14,8188, EINECS 233-165-4, 1g MDL MFCD00011204, Ì 5g bulk R:22-36/37/38, S:26-36/37 11029 Rhodium(III) iodide, 99.9% (metals basis), Rh 20.8% min Ê 250mg [15492-38-3], RhI , F.W. 483.62, Crystalline, EINECS 239-521-5, MDL MFCD00016311, Ì 1g Compounds and 3 5g bulk Homogeneous Catalysts Rh2(5R-MEPY)4, see Dirhodium(II) tetrakis(methyl 2-pyrrolidinone-5(R)-carboxylate)- acetonitrile/2-pr, 44707, p. 39 12633 Rhodium(III) nitrate solution, Rh 10% w/w (cont. Rh) (c)0.5g

[13465-43-5], Rh(NO3)3, F.W. 288.92(anhy), Liquid, UN3218, MDL MFCD00011202, Ì (c)2g bulk R:8-34, S:17-23b-26-36/37/39-45 39825 Rhodium octanoate dimer 1g

[73482-96-9], [Rh[CH3(CH2)6CO2]2]2, F.W. 778.62, Powder, Solubility: Soluble in hot alcohol, 5g dichloromethane, toluene and acetic acid, slightly soluble in alcohol, MDL MFCD00064724 bulk 12667 Rhodium(III) oxide pentahydrate, Premion®, 99.99% (metals basis), Rh 59% min 250mg

[39373-27-8], Rh2O3ù5H2O, F.W. 343.88 (253.81anhy), Powder, m.p. dec., EINECS 234-846-9, 1g MDL MFCD00149843, Ì 5g bulk 11814 Rhodium(III) oxide, anhydrous, 99.9% (metals basis), Rh 80.6% min Ê 500mg

[12036-35-0], Rh2O3, F.W. 253.81, Powder, m.p. 1100ø dec., EINECS 234-846-9, 2g MDL MFCD00011205, Ì bulk 10561 Rhodium(III) 2,4-pentanedionate, Premion®, 99.99% (metals basis), 500mg Rh 25.2% min 1g [Rhodium(III) acetylacetonate] 5g

[14284-92-5], C15H21O6Rh, F.W. 400.23, Crystalline, m.p. 263-264ø, bulk Solubility: Very soluble in chloroform. Soluble in alcohol, EINECS 238-192-5, MDL MFCD00083144, Ì

R:36/37/38, S:26-37 12635 Rhodium(III) sulfate, bright plating solution, Rh 5% (cont. Rh) (c)0.5g

[10489-46-0], Rh2(SO4)3, F.W. 493.99, Liquid, UN3264, EINECS 234-014-5, (c)2g MDL MFCD00016309, Ì (c)5g bulk R:34, S:20-26-36/37/39-45 41016 Rhodium(III) sulfate tetrahydrate, Premion®, 99.99% (metals basis), Rh 35.9% min 250mg

Rh2(SO4)3ù4H2O, F.W. 566.05 (493.99anhy), Crystalline, EINECS 234-014-5, 1g MDL MFCD00798544, Ì 5g bulk R:36/37/38, S:26 44029 Rhodium(II) trifluoroacetate, dimer bulk

[31126-95-1], [Rh(CF3CO2)2]2, F.W. 657.88, Powder, MDL MFCD00209611

40 www.alfa.com Rhodium/Ruthenium Stock # Description Standard Selling Sizes 40408 Sodium hexabromorhodate(III) hydrate, Premion®, 99.99% (metals basis), 1g Rh 11.4%min 5g

Na3RhBr6ùxH2O (x÷12), F.W. 384.59(anhy), Crystalline Powder, MDL MFCD00798531 bulk

R:36/37/38, S:26 11809 Sodium hexachlororhodate(III) dodecahydrate, Rh 17.1% 1g

[14972-70-4], Na3RhCl6ù12H2O, F.W. 600.77 (384.59anhy), Crystalline, m.p. 900ø dec., 5g EINECS 236-047-9, MDL MFCD00003509, Ì bulk 10547 Tetracarbonyldi-æ-chlorodirhodium(I), Rh 50.1-52.9% È É 250mg [Rhodium carbonyl chloride] 1g

[14523-22-9], [RhCl(CO)2]2, F.W. 388.76, Crystalline, m.p. 121ø, Merck 14,8187, UN3466, bulk EINECS 238-540-6, MDL MFCD00135610

R:23/25, S:9-28a-36/37/39-45 10553 Tris(ethylenediamine)rhodium(III) chloride trihydrate, Rh 23.2% 500mg [Trichlorotris(ethylenediamine)rhodium(III)] 1g

[15004-86-1], Rh(H2NCH2CH2NH2)3Cl3ù3H2O, F.W. 443.61 (389.56anhy), Crystalline, m.p. 280ø 5g dec., EINECS 237-846-7, MDL MFCD00149661 bulk ooeeu Catalysts Homogeneous

R:36/37/38, S:26-37 opud and Compounds

Stock # Description Standard Selling Sizes 11874 Ammonium hexachlororuthenate(IV), Ru 28.4% min Ê 1g

[18746-63-9], (NH4)2RuCl6, F.W. 349.87, Powder, EINECS 242-552-7, MDL MFCD00015962, Ì 5g bulk R:36/37/38, S:26-37 12778 cis-Bis-(2,2'-bipyridine)dichlororuthenium(II) dihydrate 1g [cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate] 5g

[15746-57-3], RuCl2(C10H8N2)2ù2H2O, F.W. 520.38 (484.35anhy), Crystalline, bulk MDL MFCD00012040

12781 Bis(cyclopentadienyl)ruthenium, Ru 43.2% min È É 1g [Ruthenocene] 5g

[1287-13-4], C10H10Ru, F.W. 231.26, Crystalline, Packaged under argon, m.p. 194-198ø, bulk EINECS 215-065-2, MDL MFCD00001442

R:36/37/38, S:26-37-60 39297 Bis(pentamethylcyclopentadienyl)ruthenium È É 500mg [Decamethylruthenocene] bulk

[84821-53-4], C20H30Ru, F.W. 371.53, Crystalline, Packaged in ampoules, MDL MFCD00058889

R:36/37/38, S:26/36

40524 Carbonyldihydridotris(triphenylphosphine)ruthenium(II), 99% É 500mg

[25360-32-1], Ru(CO)(H2)[P(C6H5)3]3, F.W. 917.98, Crystalline, m.p. 161-163ø, UN2813, 2g MDL MFCD00015870 10g bulk R:15-22, S:7/8-33-36-43h 10494 Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer Ê 1g

[50982-13-3], [RuCl2(C8H12)]¡, Powder, MDL MFCD00171304 5g bulk L19126 Dichloro(p-cymene)ruthenium(II) dimer, 98% 500mg [Bis(p-cymene)diruthenium(II) tetrachloride, 2g Di-æ-chlorobis[(p-cymene)chlororuthenium(II)]] 10g

[52462-29-0], C20H28Cl4Ru2, F.W. 612.40, Fieser 19,120 21,52, bulk EINECS 435-530-5, MDL MFCD00064793 S:22-24/25

1-800-343-0660 41 Ruthenium Stock # Description Standard Selling Sizes 10504 Dichlorotris(triphenylphosphine)ruthenium(II), Premion®, 99.95% (metals basis), 1g Ru 10.2% min ÈÉ 5g [Tris(triphenylphosphine)ruthenium(II) chloride] bulk

[15529-49-4], RuCl2[P(C6H5)3]3, F.W. 958.86, Crystalline, m.p. 132-134ø, Fieser 4,564 14,130 15,128 16,126 18,309 19,123 20,136 21,164, Solubility: Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene, EINECS 239-569-7, MDL MFCD00013077 10507 Dodecacarbonyltriruthenium, 99% 1g [Ruthenium carbonyl, Triruthenium dodecacarbonyl] 5g

[15243-33-1], Ru3(CO)12, F.W. 639.33, Crystalline, m.p. ca 150ø dec., Solubility: Sparingly bulk soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating, Application(s): Carbonylation, UN3466, EINECS 239-287-4, MDL MFCD00011209, Ì

R:23/25, S:37-45 10511 Hexaammineruthenium(III) chloride, Ru 32.1% min 250mg

[14282-91-8], Ru(NH3)6Cl3, F.W. 309.61, Powder, EINECS 238-176-8, RTECS VM2651530, 1g MDL MFCD00011478 5g bulk R:22-36/37/38, S:26-36

44803 (S)-Paraphos RutheniumCl2 (R,R)-DPEN 100mg

C74H66Cl2N2OP2Ru, F.W. 1233.27, Powder, MDL MFCD08064217 bulk

44800 (R)-P-Phos Ruthenium (acac)2 100mg

C56H64N2O8P2Ru, F.W. 1056.15, Powder, MDL MFCD08064214 bulk 10520 Pentaamminechlororuthenium(III) chloride Ê 1g

[18532-87-1], [RuCl(NH3)5]Cl2, F.W. 292.58, Micro Crystals, EINECS 242-408-3, 5g MDL MFCD00011529 bulk

R:36/37/38, S:26

Compounds and 41716 Potassium aquapentachlororuthenate(III), Premion®, 99.99% (metals basis), 1g Ru 26.4% min 5g

[14404-33-2], K2RuCl5(H2O), F.W. 374.49 (356.54anhy), Crystalline, MDL MFCD00058747, Ì bulk Homogeneous Catalysts 44547 Potassium hexachlororuthenate(III), Premion®, 99.99% (metals basis), Ru 23% min 1g

[25443-63-4], K3RuCl6, F.W. 431.09, Crystalline, MDL MFCD00011390, Ì 5g bulk R:36/37/38, S:26-37 40399 Potassium hexachlororuthenate(IV), Premion®, 99.95% (metal basis), Ru 25.3% min 1g

[23013-82-3], K2RuCl6, F.W. 391.99, Cystalline Powder, EINECS 245-381-6, 5g MDL MFCD00050159, Ì bulk

R:36/37/38, S:26-37 11876 Potassium hexacyanoruthenate(II) hydrate, Ru 23.0% min 200mg

[15002-31-0], K4Ru(CN)6ùxH2O, F.W. 413.59(anhy), Crystalline, EINECS 239-097-1, 2g MDL MFCD00168064 10g bulk R:20/22-36/37/38, S:9-26-36 10530 Potassium hydroxytetranitronitrosylruthenate(II) bulk

[14167-09-0], K2Ru(OH)(NO2)4(NO), F.W. 410.31, Crystalline, EINECS 238-010-4, MDL MFCD00050034

R:36/37/38, S:26-37-60 10534 Potassium pentachloronitrosylruthenate(II), Ru 25.8% 250mg

[14854-54-7], K2RuCl5(NO), F.W. 386.55, Crystalline, m.p. 220ø dec., EINECS 238-919-6, 1g MDL MFCD00049789, Ì bulk

R:36/37/38, S:26-37-60 12173 Potassium pentachlororuthenate(III) hydrate, 99.95% (metals basis), Ru 25.4% min 1g

K2RuCl5ùxH2O, F.W. 356.54(anhy), Crystalline, MDL MFCD00058747, Ì 5g bulk 11877 Potassium perruthenate(VII), 98% 1g

[10378-50-4], KRuO4, F.W. 204.17, Crystalline, m.p. 440ø dec., UN1479, EINECS 233-835-6, 5g MDL MFCD00061333, Ì bulk

R:8-36/37/38, S:17-26 12628 Ruthenium(III) bromide hydrate, Ru 25% min Ê 1g

[14014-88-1], RuBr3ùxH2O (x÷3), F.W. 340.78(anhy), Crystalline, Solubility: Soluble in alcohol, 5g Application(s): Oxidation, UN3260, EINECS 237-829-4, MDL MFCD00016314, Ì bulk

R:34, S:20-26-36/37/39-45-60

42 www.alfa.com Ruthenium Stock # Description Standard Selling Sizes 11807 Ruthenium(III) bromide, Ru 29% min Ê 1g

[14014-88-1], RuBr3, F.W. 340.78, Powder, d. 5.30, UN3260, EINECS 237-829-4, 5g MDL MFCD00016314, Ì bulk

R:34, S:20-26-36/37/39-45-60 11043 Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min Ê 2g

[14898-67-0], RuCl3ùxH2O, F.W. 207.43(anhy), Crystalline Soluble, Merck 14,8302, 10g Solubility: Very soluble in water. Soluble in alcohol, acetone, Application(s): Oxidation, 50g UN3260, EINECS 233-167-5, MDL MFCD00149844, Ì bulk

R:20/21/22-34, S:26-27/28a-36/37/39 43364 Ruthenium(III) chloride hydrate, Premion®, 99.99% (metals basis) Ê 2g

[14898-67-0], RuCl3ùxH2O, F.W. 207.43(anhy), Crystalline, Merck 14,8302, UN3260, 10g EINECS 233-167-5, MDL MFCD00149844, Ì bulk

R:20/21/22-34, S:26-27/28a-36/37/39 11808 Ruthenium(III) chloride, anhydrous, Premion®, 99.99% (metals basis), 2g Ru 48.2% min Ê 10g ooeeu Catalysts Homogeneous [10049-08-8], RuCl3, F.W. 207.43, Powder, m.p. >500ø dec., d. 3.110, Merck 14,8302, bulk Solubility: Insoluble in cold water. Decomposes in hot water, UN3260, EINECS 233-167-5,

MDL MFCD00011208, Ì and Compounds

R:34, S:20-26-36/37/39-45-60 11806 Ruthenium(III) chloride oxide, ammoniated, Ru 35.3% min 1g [Tetraamminechlorohydroxoruthenium(III) chloride, Ruthenium Red] 5g

[11103-72-3], [(NH3)5RuORu(NH3)4ORu(NH3)5]Cl6, F.W. 786.35, Crystalline, m.p. >500ø dec., bulk d. 3.110, Merck 14,8300, Solubility: Soluble in water, ammonia, Application(s): Microscopic stain, MDL MFCD00011479 11805 Ruthenium(III) iodide, anhydrous, Ru 20.5% min Ê 1g

[13896-65-6], RuI3, F.W. 481.78, Powder, m.p. 590ø dec., EINECS 237-664-8, 5g MDL MFCD00016316, Ì bulk

R:36/37/38, S:26-37 43435 Ruthenium(III) nitrosylacetate, Premion®, 99.99% (metals basis) 1g

Ru(NO)(OOCCH3)3, F.W. 308.18, Powder, MDL MFCD02684507 5g bulk R:36/37/38, S:26-37 43089 Ruthenium(III) nitrosylchloride hydrate 1g

[32535-76-5], Ru(NO)Cl3ùxH2O, F.W. 237.44(anhy), Crystalline, m.p. 180ø dec., 5g MDL MFCD00049765, Ì bulk

R:36/37/38, S:26-37 16622 Ruthenium(III) nitrosylchloride, Ru 42.1% min Ê 1g

[18902-42-6], Ru(NO)Cl3, F.W. 237.44, Crystalline, EINECS 242-651-5, 5g MDL MFCD00049765, Ì bulk

R:36/37/38, S:26-37-60 12630 Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v 50ml

[34513-98-9], Ru(NO)(NO3)3, F.W. 317.09(anhy), Liquid, d. ÷1.1, UN3218, 250ml MDL MFCD00016313, Note: »1.1, Ì 1L bulk R:8-36/37/38, S:26 12175 Ruthenium(III) nitrosylnitrate, Ru 31.3% min 1g

[34513-98-9], Ru(NO)(NO3)3, F.W. 317.09, Crystalline, UN1477, EINECS 252-068-8, 5g MDL MFCD00016313, Ì 25g bulk R:8-36/37/38, S:26 43436 Ruthenium(III) nitrosylsulfate, Premion®, 99.99% (metals basis) 1g

[Ru(NO)]2(SO4)3, F.W. 550.34, Powder, Solubility: Soluble in water, 5g Application(s): Electroplating, coating, MDL MFCD02684508 bulk

R:36/37/38, S:26-37 11803 Ruthenium(IV) oxide hydrate, Ru 54% min 1g

[32740-79-7], RuO2ùxH2O, F.W. 133.07(anhy), Powder, m.p. 1200ø subl., Solubility: Insoluble 5g in water. Soluble in HCl, Application(s): Oxidation, EINECS 234-840-6, MDL MFCD00149846, Ì 25g bulk R:36, S:26 43403 Ruthenium(IV) oxide hydrate, Premion®, 99.99% (metals basis), Ru 54-58% 1g

[32740-79-7], RuO2ùxH2O, F.W. 133.07(anhy), Powder, m.p. 1200ø subl., EINECS 234-840-6, 5g MDL MFCD00149846, Ì 25g bulk R:36, S:26

1-800-343-0660 43 Ruthenium/Silver Stock # Description Standard Selling Sizes 11804 Ruthenium(IV) oxide, anhydrous, Premion®, 99.95% (metals basis), Ru 75.2% min Ê 500mg

[12036-10-1], RuO2, F.W. 133.07, Powder, m.p. 1200ø subl., d. 6.97, Solubility: Insoluble in 2g water, acids. Soluble in fused alkalis, EINECS 234-840-6, MDL MFCD00011210, Ì 10g bulk R:36/37/38, S:26-37 40336 Ruthenium(IV) oxide, Electronic Grade, Premion®, 99.95% (metals basis), 500mg Ru typically 74% 2g 2 [12036-10-1], RuO2, F.W. 133.07, Sub-micron Powder, Surface Area 45-65m /g, m.p. 1200ø 10g subl., d. 6.97, Application(s): Semiconductor industry for the manufacture of resistor pastes, bulk EINECS 234-840-6, MDL MFCD00011210, Ì

R:33-36/37/38, S:26-37 10568 Ruthenium(III) 2,4-pentanedionate 1g [Ruthenium(III) acetylacetonate] 5g

[14284-93-6], C15H21O6Ru, F.W. 398.40, Crystalline, m.p. 260ø dec., bulk Solubility: Soluble in acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene, Application(s): Hydrogenation, EINECS 238-193-0, MDL MFCD00000030, Ì 43098 Ruthenium(IV) sulfide, 99.9% (metals basis) 1g

RuS2, F.W. 165.19, Powder, UN3178, EINECS 235-318-0, MDL MFCD00799846, Ì 5g bulk R:11-29-31-36/37/38, S:7/8-26-33-37-43h-60 B24511 Tetra-n-propylammonium perruthenate(VII), 98% Ê 100mg [TPAP] 500mg

[114615-82-6], (CH3(CH2)2)4NRuO4, F.W. 351.43, m.p. 160ø dec., Fieser 14,302 16,325 18,351 bulk 20,370 21,1610, UN1479, MDL MFCD00074914

R:8-36/37/38, S:17-26-37-60 10503 Tricarbonyldichlororuthenium(II) dimer 1g

[22594-69-0], [RuCl2(CO)3]2, F.W. 512.02, Crystalline, UN3466, MDL MFCD00011528 bulk Compounds and R:20/21/22-36/37/38, S:9-26-36/37/39-60

Homogeneous Catalysts 12783 Tris(2,2'-bipyridine)ruthenium(II) chloride hexahydrate 500mg [Tris(2,2'-bipyridyl)dichlororuthenium(II)] 2g

[50525-27-4], C30H24Cl2N6Ruù6H2O, F.W. 748.63 (640.54anhy), Crystalline, bulk m.p. 63-66ø, EINECS 238-266-7, RTECS VM2730000, MDL MFCD00149670, Ì

R:36/38, S:26

44006 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium(III), 99% Ê 500mg [Ruthenium(III)tris(2,2,6,6-tetramethyl-3,5-heptanedionate, Ruthenium(III)-DPM] 2g

[38625-54-6], C33H57O6Ru, F.W. 650.88, Powder, m.p. 200-203ø, b.p. 250ø bulk dec., MDL MFCD00269841, Note: Sublimes at 120ø/0.5mm

R:36/37/38, S:26-37

44802 (R)-Xyl-P-Phos RutheniumCl2 (R,R)-DPEN 100mg

C60H66Cl2N4O4P2Ru, F.W. 1141.13, Powder, MDL MFCD08064216 bulk

Stock # Description Standard Selling Sizes 39306 Mercury(II) silver iodide 5g

[7784-03-4], Ag2HgI4, F.W. 923.95, Powder, UN2025, EINECS 232-045-9, 25g MDL MFCD00046160 100g bulk R:26/27/28-33-50/53, S:13-28a-45-60-61 11660 Silver acetate, anhydrous, 99% 25g

[563-63-3], AgOOCCH3, F.W. 166.92, Crystalline, m.p. dec., d. 3.26, Merck 14,8505, 100g Solubility: Soluble in dilute HNO3. Water solubility increases with temperature, bulk EINECS 209-254-9, MDL MFCD00012446, Ì

R:36/37/38, S:26-37 44228 Silver arsenate, 99.99% (metals basis) 5g

[13510-44-6], Ag3AsO4, F.W. 462.53, Powder, UN1557, MDL MFCD00046163, Ì 25g 100g R:45-23/25-50/53, S:53-45-60-61 bulk 11896 Silver benzoate hydrate 5g

[532-31-0], C6H5CO2AgùxH2O, F.W. 228.89(anhy), Powder, EINECS 208-533-2, 25g MDL MFCD00013030, Ì 100g bulk

44 www.alfa.com Silver Stock # Description Standard Selling Sizes 11425 Silver bromide, 99.9% 5g [7785-23-1], AgBr, F.W. 187.78, Powder, m.p. 432ø, d. 6.47, Merck 14,8506, 25g Solubility: Practically insoluble in water. Insoluble in alcohol and acids. Partially soluble in 100g ammonia, EINECS 232-076-8, MDL MFCD00003398, Ì bulk 12110 Silver bromide, Premion®, 99.998% (metals basis) 5g [7785-23-1], AgBr, F.W. 187.78, Crystalline, m.p. 432ø, d. 6.47, Merck 14,8506, 25g EINECS 232-076-8, MDL MFCD00003398, Ì 100g bulk

18202 Silver carbonate on Celite®, ÷0.7 mmole Ag2CO3/g reagent 15mmo

[534-16-7], Ag2CO3/celite, Powder, EINECS 208-590-3, MDL MFCD00003403, Ì 75mmo bulk R:36, S:26 11420 Silver carbonate, 99.5% (metals basis) 25g

[534-16-7], Ag2CO3, F.W. 275.75, Powder, m.p. 218ø dec., d. 6.08, Merck 14,8507, 100g Solubility: Insoluble in water. Freely soluble in dilute HNO3, ammonia, EINECS 208-590-3, bulk MDL MFCD00003403, Ì

R:36, S:26 ooeeu Catalysts Homogeneous 87342 Silver(I) chloride, 95% 25g [7783-90-6], AgCl, F.W. 143.32, Coarse Powder, m.p. 455ø, b.p. 1550ø, d. 5.56, Ë 2.071, 100g Merck 14,8509, Solubility: Practically insoluble in water. Soluble in ammonia, solutions of 500g and Compounds alkali cyanides, thiosulfates, ammonium carbonates. Insoluble in alcohol, dilute acids, bulk Application(s): Silver plating, EINECS 232-033-3, MDL MFCD00003399, Ì 11421 Silver(I) chloride, 99.9% (metals basis) 25g [7783-90-6], AgCl, F.W. 143.32, Crystalline, m.p. 455ø, b.p. 1550ø, d. 5.56, Ë 2.071, 100g Merck 14,8509, EINECS 232-033-3, MDL MFCD00003399, Ì 500g 3x500g bulk 10857 Silver(I) chloride, Premion®, 99.998% (metals basis) 5g [7783-90-6], AgCl, F.W. 143.32, Coarse Powder, m.p. 455ø, b.p. 1550ø, d. 5.56, Ë 2.071, 25g Merck 14,8509, EINECS 232-033-3, MDL MFCD00003399, Ì 100g bulk 35715 Silver(I) chloride, ultra dry, 99.997% (metals basis) 1g [7783-90-6], AgCl, F.W. 143.32, -10 Mesh Beads, Ampouled under argon, m.p. 455ø, 5g b.p. 1550ø, d. 5.56, Ë 2.071, Merck 14,8509, EINECS 232-033-3, MDL MFCD00003399, Ì 25g 100g bulk 40107 Silver(I) chromate, 99% min 25g

[7784-01-2], Ag2CrO4, F.W. 331.73, Powder, d. 5.63, Merck 14,8510, Solubility: Slightly 100g soluble in water. Soluble in HNO3 and ammonia, UN3087, EINECS 232-043-8, bulk MDL MFCD00003402, Ì

R:49-8-34-43-50/53, S:53-45-60-61 11424 Silver cyanide, 99% 25g [506-64-9], AgCN, F.W. 133.84, Powder, m.p. 320ø dec., d. 3.95, Ë 1.685, Merck 14,8512, 100g Solubility: Insoluble in water, dilute acids, and alcohol. Soluble in alkali cyanides and boiling bulk

concentrated HNO3, Application(s): Silver plating, UN1684, EINECS 208-048-6, MDL MFCD00003409, Ì

R:26/27/28-32-50/53, S:7-28a-29-45-60-61 43708 Silver cyclohexanebutyrate 1g

[62638-04-4], C10H17AgO2, F.W. 277.11, Powder, m.p. ca 255ø dec., 5g EINECS 263-667-9, MDL MFCD00036396, Note: Ag 38-40%, Ì 25g bulk R:36/37/38, S:26-37 11898 Silver diethyldithiocarbamate, ACS 10g

[1470-61-7], C5H10AgNS2, F.W. 256.14, Powder, m.p. 172-175ø, 50g EINECS 216-003-7, MDL MFCD00004929, Ì bulk Specifications: Solubility in pyridine P.T., Suitability for determination of arsenic P.T.

R:36/37/38, S:26 11609 Silver(I) fluoride, 98% É Ê 5g [7775-41-9], AgF, F.W. 126.87, Crystalline, m.p. 435ø, b.p. ca 1150ø, d. 5.852, Merck 14,8514, 25g

Solubility: Soluble in HF, ammonia, CH3CN, EINECS 231-895-8, MDL MFCD00003410, Ì bulk

R:36/37/38, S:26

1-800-343-0660 45 Silver Stock # Description Standard Selling Sizes 11610 Silver(II) fluoride, 98% min É Ê 2g [Silver difluoride] 10g

[7783-95-1], AgF2, F.W. 145.87, Crystalline, m.p. 690ø, d. 4.7, Merck 14,8513, UN1479, 50g EINECS 232-037-5, MDL MFCD00003411, Ì bulk

R:8-14-36/37/38, S:8-26-30 11538 Silver hexafluoroantimonate(V), 99% É 1g

[26042-64-8], AgSbF6, F.W. 343.41, Powder, Fieser 5,577 7,320 11,467, UN3260, 5g EINECS 247-429-1, MDL MFCD00003401, Ì 25g bulk R:20/22-34-51/53, S:22-26-36/37/39-45-61 11608 Silver hexafluoroarsenate(V), 98.5% É 2g

[12005-82-2], AgAsF6, F.W. 296.78, Powder, UN1557, MDL MFCD00014142 10g bulk R:23/25-50/53, S:20/21-28a-45-60-61 11873 Silver hexafluorophosphate(V), 98% É 1g

[26042-63-7], AgPF6, F.W. 252.83, Powder, m.p. 102ø dec., UN3260, EINECS 247-428-6, 5g MDL MFCD00003415, Ì 25g bulk R:34, S:26-36/37/39-45 40129 Silver hydrogen fluoride, 99% min 10g [Silver bifluoride] 50g

[12249-52-4], AgHF2, F.W. 146.87, Crystalline, m.p. dec., UN3288, MDL MFCD00042145 bulk

R:23/24/25-31, S:4-9-20-27-36/37-45-60 40109 Silver iodate, 99% 25g

[7783-97-3], AgIO3, F.W. 282.77, Powder, m.p. >200ø, d. 5.53, Merck 14,8515, 100g Solubility: Practically insoluble in water. Soluble in aqueous ammonia, UN1479, bulk EINECS 232-039-6, MDL MFCD00014150, Ì

Compounds and R:8-36/37/38, S:17-26-36/37/39-60 11419 Silver iodide, 99.9% (metals basis) 25g

Homogeneous Catalysts [7783-96-2], AgI, F.W. 234.77, Crystalline, m.p. 558ø, d. 5.67, Merck 14,8516, 100g Solubility: Insoluble in water, acids, ammonium carbonate. Freely soluble in alkali cyanides bulk and iodides, EINECS 232-038-0, MDL MFCD00003412, Ì 12111 Silver iodide, Premion®, 99.999% (metals basis) 5g [7783-96-2], AgI, F.W. 234.77, Powder, m.p. 558ø, d. 5.67, Merck 14,8516, EINECS 232-038-0, 25g MDL MFCD00003412, Ì 100g bulk 44858 Silver lactate solution, Ag 4-5% w/w (cont. Ag) (c)1g

[128-00-7], CH3CH(OH)CO2Ag, F.W. 196.94, Liquid, MDL MFCD00043279 (c)5g (c)25g bulk 20835 Silver lactate 10g

[128-00-7], CH3CH(OH)CO2Ag, F.W. 196.94, Powder, m.p. 120-122ø, Merck 14,8517, 50g MDL MFCD00043279 bulk

R:36/38, S:26 44828 Silver metavanadate ß 5g [Silver vanadium trioxide] 25g

[13497-94-4], AgVO3, F.W. 206.81, Powder, UN3285, EINECS 236-820-2, bulk MDL MFCD00041760, Ì

R:22-36/37/38, S:26-36/37-60 18641 Silver methanesulfonate 10g

[2386-52-9], Ag(SO3CH3), F.W. 202.97, Powder, EINECS 219-199-2, MDL MFCD00064795, Ì 50g bulk 39650 Silver molybdenum oxide, 99% 250mg [Silver molybdate] 1g

[13765-74-7], Ag2MoO4, F.W. 375.68, Powder, m.p. 483ø, d. 6.18, EINECS 237-374-1, bulk MDL MFCD00053384, Ì S:26-37

46 www.alfa.com Silver Stock # Description Standard Selling Sizes 11414 Silver nitrate, ACS, 99.9+% (metals basis) ß 5g

[7761-88-8], AgNO3, F.W. 169.87, Crystalline, m.p. 212ø, d. 4.352, Merck 14,8518, 25g Solubility: Freely soluble in water, alcohol, ammonia water. Slightly soluble in ether, 100g Application(s): Silver plating, photography, manufacturing of other silver compounds, mirrors, 500g as an analytical lab reagent, in coloring porcelain, UN1493, EINECS 231-853-9, 6x500g RTECS VW4725000, MDL MFCD00003414, Ì bulk Maximum level of impurities: Clarity of solution P.T., Cl 5ppm, Free acid P.T., Substances

not precipitated by hydrochloric acid 0.01%, SO4 0.002%, Cu 2ppm, Fe 2ppm, Pb 0.001%

R:8-34-50/53, S:26-45-60-61 43087 Silver nitrate, Premion®, 99.995% (metals basis), Ag 63% min ß 5g

[7761-88-8], AgNO3, F.W. 169.87, Crystalline, m.p. 212ø, d. 4.352, Merck 14,8518, UN1493, 25g EINECS 231-853-9, RTECS VW4725000, MDL MFCD00003414, Ì 100g bulk R:8-34-50/53, S:26-45-60-61 10858 Silver nitrate, Premion®, 99.9995% (metals basis) ß 5g

[7761-88-8], AgNO3, F.W. 169.87, Powder, m.p. 212ø, d. 4.352, Merck 14,8518, UN1493, 25g EINECS 231-853-9, RTECS VW4725000, MDL MFCD00003414, Ì 100g

bulk Catalysts Homogeneous R:8-34-50/53, S:26-45-60-61

11418 Silver nitrite, 99% (metals basis) ß 10g and Compounds

[7783-99-5], AgNO2, F.W. 153.88, Crystalline, m.p. 140ø dec., d. 4.45, Merck 14,8519, 50g UN1479, EINECS 232-041-7, MDL MFCD00003413, Ì bulk

R:8 43268 Silver(I) oxide, Electrical Grade 250g

[20667-12-3], Ag2O, F.W. 231.74, -325 Mesh Powder, m.p. 230ø dec., d. 7.2, Merck 14,8521, 1kg Solubility: Soluble in dilute HNO3 and ammonia. Practically insoluble in water. Insoluble in bulk alcohol, Application(s): For battery plates, pollution control filters, UN1479, EINECS 243-957-1, MDL MFCD00003404, Ì

R:8-36/38, S:26 11407 Silver(I) oxide, 99+% (metals basis) 25g

[20667-12-3], Ag2O, F.W. 231.74, Powder, m.p. 230ø dec., d. 7.2, Merck 14,8521, 100g Application(s): Polishing glass, coloring glass yellow, catalyst, purifying drinking water, lab 500g reagent, UN1479, EINECS 243-957-1, MDL MFCD00003404, Ì bulk

R:8-36/38, S:26 42577 Silver(I) oxide, 99.99% (metals basis) 1g

[20667-12-3], Ag2O, F.W. 231.74, Powder, m.p. 230ø dec., d. 7.2, Merck 14,8521, UN1479, 5g EINECS 243-957-1, MDL MFCD00003404, Ì 25g 4x25g R:8-36/38, S:26 bulk 22695 Silver(II) oxide, 98% 5g [Silver peroxide, Silver suboxide] 25g [1301-96-8], AgO, F.W. 123.87, Powder, m.p. >100ø dec., d. 7.44, Merck 14,8522, 100g Solubility: Insoluble in water. Soluble in alkalies, ammonium hydroxide with decomposition bulk

and N2 formation, Application(s): Manufacturing of silver oxide-zinc alkali batteries, UN1479, EINECS 215-098-2, MDL MFCD00044285, Ì

R:8-36/38, S:26 40187 Silver(II) oxide, 99.9% (metals basis), Ag 86.6% min 5g [1301-96-8], AgO, F.W. 123.87, -100 Mesh Powder, m.p. >100ø dec., d. 7.44, Merck 14,8522, 25g UN1479, EINECS 215-098-2, MDL MFCD00044285, Ì 100g bulk R:8-36/38, S:26 11624 Silver(I) perchlorate monohydrate, 99.9% (metals basis) ß Ê 2g

[14242-05-8], AgClO4ùH2O, F.W. 225.34 (207.32anhy), Crystalline, m.p. 485ø dec., d. 2.800, 10g Merck 14,8523, Fieser 2,369 7,142 9,413 10,354 11,469 15,121 16,300 18,321 20,341, 50g UN1481, EINECS 232-035-4, MDL MFCD00149128, Ì 250g bulk R:8-36/37/38, S:26 42209 Silver(I) perchlorate, anhydrous Ê 5g

[7783-93-9], AgClO4, F.W. 207.32, Crystalline, m.p. 486ø dec., d. 2.806, Merck 14,8523, 25g Solubility: Soluble in water and many organic solvents (benzene, toluene, pyridine), UN1481, 100g EINECS 232-035-4, MDL MFCD00003400, Ì bulk

R:8-36/37/38, S:26

1-800-343-0660 47 Silver Stock # Description Standard Selling Sizes 44480 Silver(I) perrhenate, 99.99% (metals basis) 1g

[20654-56-2], AgReO4, F.W. 358.10, Powder, m.p. 430ø, d. 7.05, UN1479, 5g MDL MFCD00014144 25g bulk R:8-36/37/38, S:17-26-37 11415 Silver phosphate (ortho), 99% 5g [Silver orthophosphate] 25g

[7784-09-0], Ag3PO4, F.W. 418.58, Powder, m.p. 849ø, d. 6.37, Merck 14,8525, bulk Solubility: Practically insoluble in water. Slightly soluble in dilute acetic acid. Freely soluble

in dilute HNO3, ammonia, ammonium carbonate, alkali cyanides and thiosulfates, Application(s): In photography, EINECS 232-049-0, MDL MFCD00014148, Ì 12551 Silver potassium cyanide, 99.9% (metals basis), Ag 54.2% 25g [Potassium silver cyanide, Potassium dicyanoargentate] 100g

[506-61-6], KAg(CN)2, F.W. 199.01, Powder, Merck 14,7669, Solubility: Soluble in water, 500g Application(s): Silver plating, UN1588, EINECS 208-047-0, MDL MFCD00036297, Ì bulk

R:26/27/28-32-50/53, S:7-28a-29-45-60-61 41880 Silver potassium iodide 1g [Potassium silver iodide] 5g

[12041-40-6], KAg4I5, F.W. 1105.09, Pieces, MDL MFCD00467907 bulk 18585 Silver salicylate hydrate 5g

[528-93-8], C7H5AgO3ùxH2O, F.W. 244.99(anhy), Powder, 25g MDL MFCD00013976 bulk

R:36/37/38, S:26-37-60 11417 Silver sulfate, ACS, 98% 25g

[10294-26-5], Ag2SO4, F.W. 311.80, Powder, m.p. 657ø, b.p. 1085ø dec., d. 5.45, 100g Merck 14,8529, Solubility: Partially soluble in water. Water solubility increases with bulk

temperature. Soluble in HNO3, ammonia, conc. H2SO4, EINECS 233-653-7, MDL MFCD00003407, Ì Compounds and Maximum level of impurities: Insoluble matter and silver chloride 0.02%, NO3 0.001%, Substances not precipitated by hydrochloric acid 0.03%, Fe 0.001% Homogeneous Catalysts R:36/37/38, S:26-36 41443 Silver sulfate, Premion®, 99.99% (metals basis), Ag 68.9% min 25g

[10294-26-5], Ag2SO4, F.W. 311.80, Powder, m.p. 657ø, b.p. 1085ø dec., d. 5.45, 100g Merck 14,8529, EINECS 233-653-7, MDL MFCD00003407, Ì bulk

R:36/37/38, S:26-36 12112 Silver sulfate, Premion®, 99.999% (metals basis) 5g

[10294-26-5], Ag2SO4, F.W. 311.80, Powder, m.p. 657ø, b.p. 1085ø dec., d. 5.45, 25g Merck 14,8529, EINECS 233-653-7, MDL MFCD00003407, Ì 100g bulk R:36/37/38, S:26-36 11416 Silver(I) sulfide, 99% 5g

[21548-73-2], Ag2S, F.W. 247.80, Powder, m.p. 825ø, d. 7.317, Merck 14,8530, 25g Solubility: Soluble in HNO3, alkali cyanide solutions. Insoluble in water, EINECS 244-438-2, 100g MDL MFCD00003406, Ì bulk 89473 Silver(I) sulfide, 99.9+% (metals basis) 5g

[21548-73-2], Ag2S, F.W. 247.80, Crystalline Powder, m.p. 825ø, d. 7.317, Merck 14,8530, 25g EINECS 244-438-2, MDL MFCD00003406, Ì bulk 12113 Silver(I) sulfide, Premion®, 99.998% (metals basis) 5g

[21548-73-2], Ag2S, F.W. 247.80, Powder, m.p. 825ø, d. 7.317, Merck 14,8530, 25g EINECS 244-438-2, MDL MFCD00003406, Ì bulk 11539 Silver tetrafluoroborate, 99% Ê 10g

[14104-20-2], AgBF4, F.W. 194.67, Crystalline, m.p. 200ø dec., Fieser 1,1015 4,428 5,587 50g 6,519 8,443 9,414 11,471 18,322 21,394, UN3288, EINECS 237-956-5, RTECS ED2875000, bulk MDL MFCD00003408, Ì

R:25-36/37/38, S:20-26-36/37-45-60 11897 Silver thiocyanate 10g [1701-93-5], AgSCN, F.W. 165.95, Crystalline, m.p. dec., Solubility: Very slightly soluble in 50g

water. Insoluble in ethanol, acetone, acid. Soluble in NH4OH, Application(s): Preparation of bulk nonmetallic thiocyanates, analytical reagent, in photographic emulsions, as an organic intermediate, EINECS 216-934-9, MDL MFCD00003416, Ì

R:20/21/22-32, S:13

48 www.alfa.com Silver Stock # Description Standard Selling Sizes 13933 Silver(I) trifluoroacetate, 98% 5g

[2966-50-9], AgOOCCF3, F.W. 220.88, Powder, m.p. 257-260ø dec., EINECS 221-004-0, 25g MDL MFCD00013199, Ì bulk

R:22-36/37/38, S:26-36/37 88722 Silver trifluoromethanesulfonate, 98% 2g [Silver triflate] 10g

[2923-28-6], AgOSO2CF3, F.W. 256.94, Crystalline, m.p. 286ø, EINECS 220-882-2, 50g MDL MFCD00013226, Ì bulk

R:36/37/38, S:26 39661 Silver tungsten oxide, 99% 10g [Silver tungstate] 50g

[13465-93-5], Ag2WO4, F.W. 463.58, Powder, Solubility: Insoluble in water. Soluble in bulk potassium cyanide, ammonium hydroxide and nitric acid, EINECS 236-708-3, MDL MFCD00014147 ooeeu Catalysts Homogeneous opud and Compounds

1-800-343-0660 49 Asymmetric Ligand/Catalyst Kits talyst Kits

Stock # Description Standard Selling Sizes Ligand/Ca 44780 Asymmetric Hydrogenation Ligand/Catalyst Kit POR

Stock # Description Standard Selling Sizes 44610 (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenyl- 100mg phosphino)-3,3'-bipyridine 500mg [(R)-P-Phos] bulk

[221012-82-4], C38H34N2O4P2, F.W. 644.64, Powder, packaged under argon, m.p. 261-265ø, Application(s): Asymmetric hydrogenation, MDL MFCD04038734

44609 (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine 100mg [(S)-P-Phos] 500mg

[362524-23-0], C38H34N2O4P2, F.W. 644.64, Powder, packaged under argon, bulk m.p. 261-265ø, Application(s): Asymmetric hydrogenation, MDL MFCD04038734

44613 (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)- 100mg phosphino)-3,3'-bipyridine 500mg [(R)-Xylyl-P-Phos] bulk

[442905-33-1], C46H50N2O4P2, F.W. 756.86, Powder, packaged under argon, m.p. 190-194ø, Application(s): Asymmetric hydrogenation, MDL MFCD04974235

50 www.alfa.com Individual Ligands and Catalysts Stock # Description Standard Selling Sizes 44614 (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)- 100mg phosphino)-3,3'-bipyridine 500mg [(S)-Xylyl-P-Phos] bulk

[443347-10-2], C46H50N2O4P2, F.W. 756.86, Powder, packaged under argon, m.p. 158-162ø, Application(s): Asymmetric hydrogenation, MDL MFCD04974235

R:36/37/38, S:26-37

44615 (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane, 100mg CTH-(R)-3,5-xylyl-PHANEPHOS 500mg

[325168-89-6], C48H50P2, F.W. 688.87, Powder, packaged under bulk argon, ¾ -160ø(c=0.5 in benzene), Application(s): Asymmetric hydrogenation, MDL MFCD03840578

44616 (S)-(+)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane, 100mg Li CTH-(S)-3,5-xylyl-PHANEPHOS 500mg g and/Catalyst [325168-88-5], C48H50P2, F.W. 688.87, Powder, packaged under bulk argon, Application(s): Asymmetric hydrogenation, MDL MFCD03840578 Kits 44684 (R)-N-Diphenylphosphino-N-methyl-[(S)-2-(diphenylphosphino)- 100mg ferrocenyl]ethylamine, (R)-Methyl BoPhozÑ 500mg [(R)-Methyl BoPhoz] bulk

[406680-94-2], C37H35FeNP2, F.W. 611.50, m.p. 80-82ø, Application(s): Asymmetric hydrogenation, MDL MFCD05865220, Note: Sold in collaboration with JM Catalysts for research purposes only. US patent US 6,590,115 and patents arising therefrom. Patent: Boaz, Neil W.; Debenham, Sheryl D. US Patent No. 6,590,115, July 8, 2003 44685 (S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)- 100mg ferrocenyl]ethylamine, (S)-Methyl BoPhozÑ 500mg [(S)-Methyl BoPhoz] bulk

[406681-09-2], C37H35FeNP2, F.W. 611.50, m.p. 80-82ø, Application(s): Asymmetric hydrogenation, MDL MFCD05865220, Note: Sold in collaboration with JM Catalysts for research purposes only. US patent US 6,590,115 and patents arising therefrom. Patent: Boaz, Neil W.; Debenham, Sheryl D. US Patent No. 6,590,115, July 8, 2003

44803 (S)-Paraphos RutheniumCl2 (R,R)-DPEN 100mg

C74H66Cl2N2OP2Ru, F.W. 1233.27, Powder, MDL MFCD08064217 bulk

44802 (R)-Xyl-P-Phos RutheniumCl2 (R,R)-DPEN 100mg

C60H66Cl2N4O4P2Ru, F.W. 1141.13, Powder, MDL MFCD08064216 bulk

44801 [(S)-Paraphos Rhodium (NBD)]BF4 100mg

C47H42P2RhBF4, F.W. 858.51, Powder, MDL MFCD08064215 bulk

44800 (R)-P-Phos Ruthenium (acac)2 100mg

C56H64N2O8P2Ru, F.W. 1056.15, Powder, MDL MFCD08064214 bulk

1-800-343-0660 51 Advanced Coupling Kit talyst Kits Ligand/Ca

52 www.alfa.com Iridium/Palladium Heterogeneous Catalysts

Stock # Description Standard Selling Sizes 38327 Iridium, 0.5% on activated carbon powder, reduced, nominally 50% water wet 5g MDL MFCD00011062, Note: Sold on a dry weight basis. Unit weight excludes water weight, Ì 25g 100g bulk 11735 Iridium, 1% on high purity 4mm alumina spheres, reduced, anhydrous 10g MDL MFCD00011062, Ì 50g 250g R:37, S:22-36-38 bulk 38330 Iridium, 1% on activated carbon powder, reduced, nominally 50% water wet 5g MDL MFCD00011062, Note: Sold on a dry weight basis. Unit weight excludes water weight, Ì 25g 100g bulk 41305 Iridium, 5% on calcium carbonate powder 5g H et Ir/CaCO3, Powder, Application(s): Selective hydrogenation of olefins to alkanes, carbonyls 25g e

to alcohols, MDL MFCD00011062, Ì 100g Catalysts rogeneous bulk R:36/37/38, S:26-37

Stock # Description Standard Selling Sizes 42206 Palladium, 0.12%, Ruthenium, 0.12%; on 3mm alumina tablets 10g

Application(s): Reduction of nitrogen oxides to N2 with H2 in the presence of CO and CO2, 50g MDL MFCD03613602, Ì 250g bulk R:40, S:36/37 38786 Palladium, 0.5% on 1/8in alumina pellets, reduced 25g MDL MFCD03613602, Ì 100g bulk R:40, S:36/37 89114 Palladium, 0.5% on 1/8in alumina pellets, unreduced 25g MDL MFCD03613602, Ì 100g 500g R:40, S:36/37 bulk 41383 Palladium, 0.5% on 2-4 mm alumina spheres 25g

Spherical powder, Application(s): Gas purification (O2, O3), MDL MFCD03613602, Ì 100g bulk R:40, S:36/37 38289 Palladium, 0.5% on granular carbon, reduced 25g 4x8 Mesh, 900-1100m2/g, Application(s): Hydrogenation of olefins, UN1325, 100g MDL MFCD03457879, Ì bulk

R:11-36/37/38, S:26-37-60 11711 Palladium, 1% on alumina powder, reduced 25g 300m2/g, MDL MFCD03613602, Ì 100g bulk R:40, S:22-36/37 44820 Palladium, 1% on 1-2 mm alumina spheres, reduced 100g Spherical powder, MDL MFCD03613602, Ì 500g bulk R:40, S:36/37 38290 Palladium, 1% on granular carbon, reduced 5g 4x8 Mesh, 900-1100m2/g, Application(s): Vapor phase hydrogenation, UN1325, 25g MDL MFCD03457879, Ì 100g bulk R:11-36/37/38, S:26-37-60 38527 Palladium, 1% on activated carbon powder, eggshell, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38292 Palladium, 1% on activated carbon powder, standard, reduced, 10g nominally 50% water wet 50g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes bulk water weight, Ì

1-800-343-0660 53 Palladium Stock # Description Standard Selling Sizes 38293 Palladium, 1% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 11691 Palladium, 3% on activated carbon powder, eggshell, reduced 5g 900-1100m2/g, UN1325, MDL MFCD03457879, Ì 25g 100g R:11-36/37/38, S:26-37-60 bulk 38295 Palladium, 3% on activated carbon powder, eggshell, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38296 Palladium, 3% on activated carbon powder, standard, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38297 Palladium, 3% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 41825 Palladium, 5% on 3mm alumina pellets 5g Application(s): Hydrogen removal "getter", MDL MFCD03613602, Ì 25g 100g R:40, S:36/37 bulk 11721 Palladium, 5% on barium carbonate powder, reduced 5g UN1564, MDL MFCD03427451, Ì 25g 100g R:22-62, S:22-36/37-60 bulk 11722 Palladium, 5% on barium sulfate powder, reduced 2.5g MDL MFCD03613605, Ì 25g 100g bulk Heterogeneous Catalysts 21162 Palladium, 5% on barium sulfate powder, unreduced 10g Application(s): Hydrodehalogenation, Rosenmund reduction, asymetric hydrogenation, 50g MDL MFCD03613605, Ì bulk 11723 Palladium, 5% on calcium carbonate powder, reduced 5g MDL MFCD03427452, Ì 25g 100g R:37/38-41, S:26-37/39 bulk 43172 Palladium, 5% on calcium carbonate, lead poisoned 5g [Lindlar catalyst] 25g [53092-86-7], Application(s): Selective hydrogenation, MDL MFCD03427452, Ì 100g bulk R:61-62-20/22-33-51/53, S:25-33-45-60-61 11713 Palladium, 5% on alumina powder, reduced 5g MDL MFCD03613602, Ì 25g 100g R:40, S:22-36/37 bulk 11694 Palladium, 5% on activated carbon powder, eggshell, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, Application(s): Debenzylation, MDL MFCD03457879, Note: Sold on a dry 100g weight basis. Unit weight excludes water weight, Ì bulk 38299 Palladium, 5% on activated carbon powder, eggshell, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, Application(s): Aromatic nitro group hydrogenation, MDL MFCD03457879, 100g Note: Sold on a dry weight basis. Unit weight excludes water weight, Ì bulk 38300 Palladium, 5% on activated carbon powder, standard, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 44142 Palladium, 5% on activated carbon powder, standard, reduced, acidic catalyst, 10g nominally 50% water wet 50g 900-1100m2/g, Application(s): Hydrogenation of aromatic and aliphatic nitro groups, reductive 250g alkylation/amination, hydrogenation of aromatic carbonyls, olefins, nitriles, bulk MDL MFCD03457879, Ì 38301 Palladium, 5% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk

54 www.alfa.com Palladium/Platinum Stock # Description Standard Selling Sizes 45051 Palladium, 5% on activated carbon powder, Type A405023-5, nominally 50% water wet 5g Notes: Sold on a dry weight basis, MDL MFCD00011167, Ì 25g 100g bulk 44337 Palladium, 5% on charcoal paste, 50-65% water wet 5g Type 39, 900-1100m2/g, Application(s): Debenzylation, C-N and C-O cleavage, alkene 25g hydrogenation, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 45132 Palladium, 5% on charcoal paste, nominally 50% water wet 5g Type 58, Ì 25g 100g bulk 39819 Palladium, 5% on strontium carbonate powder, reduced 2g MDL MFCD00192595, Ì 10g 50g bulk 42208 Palladium, 8%, Platinum, 2%; on activated carbon powder, nominally 50% water wet 2g

Application(s): Selective hydrogenation of nitrates to hydroxylamines, reduction of nitrogen 10g H

oxides to N2 with H2 in the presence of CO and CO2, MDL MFCD01074898, Note: Sold on 50g et

dry weight basis. Unit weight excludes water weight, Ì bulk e oeeu Catalysts rogeneous R:40, S:36/37 38303 Palladium, 10% on activated carbon powder, eggshell, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 50g water weight, Ì bulk 38304 Palladium, 10% on activated carbon powder, standard, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 44350 Palladium, 10% on activated carbon powder, standard, reduced, 5g nominally 50% water wet 25g Type 58, Application(s): Hydrogenation of aromatic and aliphatic nitro groups, reductive 100g alkylation/amination, hydrogenation of aromatic nitrites to 1ø amines, MDL MFCD03457879, Ì bulk 38305 Palladium, 10% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38306 Palladium, 20% on activated carbon powder, eggshell, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38307 Palladium, 20% on activated carbon powder, eggshell, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, Application(s): Debenzylation, MDL MFCD03457879, Note: Sold on a dry 100g weight basis. Unit weight excludes water weight, Ì bulk 38308 Palladium, 20% on activated carbon powder, standard, reduced, 250mg nominally 50% water wet 2g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 10g water weight, Ì 50g bulk 38309 Palladium, 20% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD03457879, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk

Stock # Description Standard Selling Sizes 42205 Platinum, 0.1% on 2-4mm alumina spheres 5g

Spheres, Application(s): VOC removal from vent streams by combination with O2, 25g MDL MFCD00011179, Ì 100g bulk 39826 Platinum, 0.3% on 1/8in alumina pellets, reduced 25g Application(s): Selective hydrogenation, gas purifications: e.g. Oxidation of carbon monoxide 100g to carbon dioxide, hydrogen removal from oxygen or carbon dioxide, EINECS 215-691-6, bulk MDL MFCD00011179, Ì

1-800-343-0660 55 Platinum Stock # Description Standard Selling Sizes 44796 Platinum, 0.5% on 1/16in alumina spheres, reduced 50g Sphere, MDL MFCD03458043, Ì 250g 1kg bulk 89106 Platinum, 0.5% on 1/8in alumina pellets, reduced 25g Application(s): Selective hydrogenations; gas purifications: e.g. Oxidation of carbon monoxide 100g to carbon dioxide, hydrogen removal from oxygen or carbon dioxide, EINECS 215-691-6, 500g MDL MFCD00011179, Ì bulk 38344 Platinum, 0.5% on granular carbon, reduced 5g 2-5mm granules, UN1325, MDL MFCD00011179, Ì 25g 100g R:11, S:7-33-43h bulk

43407 Platinum, 1% on polyethyleneimine/SiO2 5g [7440-06-4], 20-40 Mesh Bead, Application(s): Reduction reactions, MDL MFCD00011179, Ì 25g bulk R:20-37, S:9-36

43408 Platinum, 1% on polyethyleneimine/SiO2 powder 5g [7440-06-4], 40-200 Mesh Powder, Application(s): Reduction reactions, 25g MDL MFCD00011179, Ì bulk

R:20-37, S:9-36 11797 Platinum, 1% on alumina powder, reduced 5g 300m2/g, MDL MFCD00011179, Ì 25g 100g bulk 38343 Platinum, 1% on granular carbon, reduced, nominally 50% water wet 25g 4x8 Mesh, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38312 Platinum, 1% on activated carbon powder, standard, reduced, 25g nominally 50% water wet 100g 900-1100m2/g, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes bulk

Heterogeneous Catalysts water weight, Ì 38313 Platinum, 1% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, Application(s): Schiff's base and nitrohydrogenation, hydrosilation, 100g MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes water weight, Ì bulk 38316 Platinum, 3% on activated carbon powder, standard, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 38317 Platinum, 3% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 44222 Platinum, 5% on alumina powder, reduced, 25g MDL MFCD03458043, Note: Low surface area, Ì 100g bulk 38318 Platinum, 5% on alumina powder, reduced, <20% water wet 5g 150m2/g, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes water 25g weight, Ì 100g bulk 38321 Platinum, 5% on activated carbon powder, standard, reduced, 25g nominally 50% water wet 100g 900-1100m2/g, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes bulk water weight, Ì 43905 Platinum, 5% on activated carbon powder, sulfided, 0.5% S (as sulfide) 10g Powder, UN1325, MDL MFCD00011179 50g bulk R:11-36/37/38, S:26-37 44365 Platinum, 5% on graphite 5g Application(s): Material for gas sensors, UN1325, MDL MFCD00011179, Ì 25g 100g R:11-36/37/38, S:26-37 bulk 38325 Platinum, 10% on activated carbon powder, standard, reduced, 5g nominally 50% water wet 25g 900-1100m2/g, Application(s): Aromatic ring hydrogenation, aliphatic aldehydes and ketones 100g

to alcohols, conversion of -CH=CH- to -CH2-CH2-, MDL MFCD00011179, Note: Sold on a bulk dry weight basis. Unit weight excludes water weight, Ì

56 www.alfa.com Heterogeneous Catalysts

Platinum/Rhodium Stock # Description Standard Selling Sizes 38326 Platinum, 10% on activated carbon powder, standard, unreduced, 5g nominally 50% water wet 25g 900-1100m2/g, MDL MFCD00011179, Note: Sold on a dry weight basis. Unit weight excludes 100g water weight, Ì bulk 43876 Platinum, nominally 10% on carbon black 500mg HiSPECÑ 2000, UN1325, MDL MFCD00011179, Ì 2g 10g R:11-36/37/38, S:26 50g bulk 35849 Platinum, nominally 20% on carbon black 1g HiSPECÑ 3000, UN1325, MDL MFCD00011179, Ì 5g 25g R:11-36/37/38, S:26 bulk 40473 Platinum, nominally 20%, Ruthenium, nominally 10% on carbon black 250mg HiSPECÑ 5000, UN1325, MDL MFCD00798552, Ì 1g 5g R:11-36/37/38, S:26 25g bulk H

43990 Platinum, nominally 30%, Ruthenium, nominally 15% on carbon black 1g et

HiSPECÑ 7000, UN1325, MDL MFCD00798552, Ì 5g e

25g Catalysts rogeneous R:11-36/37/38, S:26 bulk 44172 Platinum, nominally 40%, Ruthenium, nominally 20% on carbon black 2g HiSPECÑ 10000, UN1325, MDL MFCD00798552, Ì 10g bulk R:11-36/37/38, S:26 42204 Platinum, nominally 40% on carbon black 1g HiSPECÑ 4000, UN1325, MDL MFCD00011179, Ì 5g 25g R:11-36/37/38, S:26 bulk 43989 Platinum, nominally 50%, on carbon black 1g HiSPECÑ 8000, UN1325, MDL MFCD00011179, Ì 5g 25g R:11-36/37/38, S:26 bulk 44171 Platinum, nominally 60%, on carbon black 2g HiSPECÑ 9000, UN1325, MDL MFCD00011179, Ì 10g bulk R:11-36/37/38, S:26

Stock # Description Standard Selling Sizes 42507 Rhodium, 0.5% on 3mm alumina pellets 10g [7440-16-6], Application(s): Hydrogenation of aromatics, EINECS 231-125-0, 50g MDL MFCD00011201, Ì bulk

43410 Rhodium, 1% on Polyethyleneimine/SiO2 5g [7440-16-6], Bead, EINECS 231-125-0, MDL MFCD00011201, Note: 20-40 mesh, Ì 25g bulk R:20-37, S:9-36

43409 Rhodium, 1% on Polyethyleneimine/SiO2 powder 5g [7440-16-6], Powder, 40-200 mesh, EINECS 231-125-0, MDL MFCD00011201, Ì 25g bulk R:20-37, S:9-36 11769 Rhodium, 1% on alumina powder, reduced 10g [7440-16-6], EINECS 231-125-0, MDL MFCD00011201, Ì 50g bulk R:37, S:22-38 11770 Rhodium, 5% on alumina powder, reduced 2g [7440-16-6], EINECS 231-125-0, MDL MFCD00011201, Ì 10g 50g R:37, S:22-38 bulk 11761 Rhodium, 5% on activated carbon powder, reduced, nominally 50% water wet 1g [7440-16-6], EINECS 231-125-0, MDL MFCD00011201, Note: Sold on a dry weight basis. 10g Unit weight excludes water weight, Ì 50g bulk 44124 Rhodium 10%, Palladium 1% on activated carbon powder 5g UN1325, MDL MFCD03792580, Ì 25g 100g R:11-36/37/38, S:26-37-60 bulk

1-800-343-0660 57 ogeneous Catalysts Ruthenium

Stock # Description Standard Selling Sizes 42206 Palladium, 0.12%, Ruthenium, 0.12%; on 3mm alumina tablets 10g

Application(s): Reduction of nitrogen oxides to N2 with H2 in the presence of CO and CO2, 50g MDL MFCD03613602, Ì 250g bulk R:40, S:36/37 38332 Ruthenium, 0.5% on granular carbon 25g [7440-18-8], 4-12 Mesh, 900-1100m2/g, UN1325, EINECS 231-127-1, MDL MFCD00011207, Ì 100g bulk R:11 44575 Ruthenium, 2% on 1/8in alumina pellets 25g [7440-18-8], S.A. nominally 200m2/g, EINECS 231-127-1, MDL MFCD00011207, Ì 100g 500g bulk 43048 Ruthenium, 0.5% on 3 mm alumina tablets 25g

[7440-18-8], Tablets, Application(s): CO or CO2 from H2 by methanation to CH4, 100g EINECS 231-127-1, MDL MFCD00011207, Ì bulk

R:37, S:22-36-38 44272 Ruthenium, 3% on 2mm carbon extrudate 25g [7440-18-8], Application(s): Hydrogenetion of aliphatic carbonyls, Aromatic ring hydrogenetion, 100g UN1325, EINECS 231-127-1, MDL MFCD03458417, Ì 500g bulk R:11 44593 Ruthenium, 4% on 1/4in alumina rings 500g [7440-18-8], EINECS 231-127-1, MDL MFCD00011207, Ì bulk 11749 Ruthenium, typically 5% on alumina powder, reduced 5g [7440-18-8], Application(s): Hydrogenation of aliphatic carbonyls and aromatic rings, especially 25g bulky molecules, EINECS 231-127-1, MDL MFCD00011207, Ì 100g Heterogeneous Catalysts bulk R:37, S:22-36-38 11748 Ruthenium, 5% on activated carbon powder, reduced 5g [7440-18-8], Application(s): Aromatic ring hydrogenation, UN1362, EINECS 231-127-1, 25g MDL MFCD00011207, Ì 100g bulk R:11-36/37/38, S:26 44338 Ruthenium, 5% on activated carbon powder, reduced, nominally 50% water wet 5g [7440-18-8], EINECS 231-127-1, MDL MFCD03458417, Note: Sold on dry weight basis. Unit 25g weight excludes water weight, Ì 100g bulk 11757 Ruthenium, 10% on activated carbon powder, reduced 5g [7440-18-8], Fieser 1,983 5,574, UN1362, EINECS 231-127-1, MDL MFCD00011207, Ì 25g 100g R:11-36/37/38, S:26 bulk

58 www.alfa.com Heterogeneous Catalyst Screening Kit H trgnosCatalysts eterogeneous

1-800-343-0660 59 Heterogeneous Catalyst Screening Kit Heterogeneous Catalysts

60 www.alfa.com Heterogeneous Catalyst Screening Kit H et e oeeu Catalysts rogeneous

1-800-343-0660 61 Iridium/Palladium/Platinum

Stock # Description Standard Selling Sizes 12071 Iridium black, 99.8% (metals basis) 500mg S.A. >20m2/g, UN3089, EINECS 231-095-9, MDL MFCD00011062, Ì 2g 10g R:11 bulk 43051 Iridium(IV) oxide dihydrate, Premion®, 99.99% (metals basis), Ir 73% min 1g

[30980-84-8], IrO2ù2H2O, F.W. 260.23 (224.20anhy), Powder, EINECS 234-743-9, 5g MDL MFCD00011065, Ì bulk

Stock # Description Standard Selling Sizes 00659 Palladium black, 99.9% (metals basis) 1g S.A. typically 20m2/g, UN3089, EINECS 231-115-6, MDL MFCD00011167, Ì 5g bulk R:11 11041 Palladium(II) oxide monohydrate, 99.9% (metals basis), Pd 73% min 2g

[64109-12-2], PdOùH2O, F.W. 140.41 (122.40anhy), Powder, m.p. dec., Merck 14,6993, 10g EINECS 215-218-3, MDL MFCD00011172, Ì bulk 11040 Palladium(II) oxide, anhydrous, 99.9% (metals basis), Pd 85% min 1g [1314-08-5], PdO, F.W. 122.40, -22 Mesh Powder, m.p. 750ø dec., d. 8.3, Merck 14,6993, 5g Solubility: Insoluble in water, acids. Slightly soluble in aqua regia, Application(s): Catalytic bulk reduction, in organic synthesis, EINECS 215-218-3, MDL MFCD00011172, Ì Unsupported Catalysts Stock # Description Standard Selling Sizes 12076 Platinum black 100mg S.A. 10m2/g, UN3089, EINECS 231-116-1, MDL MFCD00011179, Ì 1g 5g R:11, S:7-33-43h-60 bulk 12755 Platinum black 250mg HiSPECÑ 1000, S.A. nominally 27m2/g, UN3089, EINECS 231-116-1, MDL MFCD00011179, Ì 1g 5g R:11, S:7-33-43h-60 25g bulk 43838 Platinum black, high surface area 250mg S.A. 24-29m2/g, UN3089, EINECS 231-116-1, MDL MFCD00011179, Ì 1g 5g R:11, S:7/8-16-33 25g bulk 41171 Platinum Ruthenium black, nominally Pt 50%, Ru 50% (Atomic wt%) 250mg Pt:Ru; 50:50 atomic %, HiSPECÑ 6000, UN3089, MDL MFCD00798552, Ì 1g 5g R:11, S:7/8-16-33 25g bulk 11049 Platinum(IV) oxide hydrate, 99.9% (metals basis), Pt 71-75% 250mg

[52785-06-5], PtO2ùxH2O, F.W. 227.09(anhy), Powder, m.p. 450ø, d. 10.2, Merck 14,7527, 1g Fieser 1,890 2,332 15,268 21,353, UN1479, EINECS 215-223-0, MDL MFCD00066964, Ì 5g 25g R:8-43, S:17-24-37-60 bulk 12278 Platinum(IV) oxide monohydrate, Adams Catalyst, Pt 75% min 1g 2 [1314-15-4], PtO2ùH2O, F.W. 245.10 (227.09 anhy), Powder, S.A. >85m /g, m.p. 450ø, 5g Merck 14,7527, Solubility: Insoluble in water, acid, aqua regia, Application(s): Hydrogenation bulk catalyst. Suitable for the reduction of double and triple bonds, aromatics, carbonyls, nitriles, and nitro groups, UN1479, EINECS 215-223-0, MDL MFCD00066964, Note: Electrochemically prepared for catalyst use, Ì

R:8-43, S:17-24-37-60

62 www.alfa.com Rhodium/Ruthenium

Stock # Description Standard Selling Sizes 12353 Rhodium black, 99.9% (metals basis) 500mg UN3089, EINECS 231-125-0, MDL MFCD00011201, Ì 2g 10g R:11 bulk 12667 Rhodium(III) oxide pentahydrate, Premion®, 99.99% (metals basis), Rh 59% min 250mg

[12036-35-0], Rh2O3, F.W. 253.81, Powder, m.p. 1100ø dec., EINECS 234-846-9, 2g MDL MFCD00011205, Ì bulk U

Stock # Description Standard Selling Sizes ns

12354 Ruthenium black, 99.9% (metals basis) 2g upp UN3089, EINECS 231-127-1, MDL MFCD00011207, Ì 10g

bulk orte R:11, S:7-16-33-43h-60 11803 Ruthenium(IV) oxide hydrate, Ru 54% min 1g d [32740-79-7], RuO2ùxH2O, F.W. 133.07(anhy), Powder, m.p. 1200ø subl., Solubility: Insoluble 5g in water. Soluble in HCl, Application(s): Oxidation, EINECS 234-840-6, MDL MFCD00149846, Ì 25g Catalysts bulk R:36, S:26 43403 Ruthenium(IV) oxide hydrate, Premion®, 99.99% (metals basis), Ru 54-58% 1g

[32740-79-7], RuO2ùxH2O, F.W. 133.07(anhy), Powder, m.p. 1200ø subl., EINECS 234-840-6, 5g MDL MFCD00149846, Ì 25g bulk R:36, S:26 11804 Ruthenium(IV) oxide, anhydrous, Premion®, 99.95% (metals basis), Ru 75.2% min Ê 500mg

1-800-343-0660 63 HiSPEC TM Fuel Cell Catalysts

Stock # Description Standard Selling Sizes 12755 Platinum black 250mg HiSPECÑ 1000, S.A. nominally 27m2/g, UN3089, EINECS 231-116-1, MDL MFCD00011179, Ì 1g 5g R:11, S:7-33-43h-60 25g bulk 41171 Platinum Ruthenium black, nominally Pt 50%, Ru 50% (Atomic wt%) 250mg Pt:Ru; 50:50 atomic %, HiSPECÑ 6000, UN3089, MDL MFCD00798552, Ì 1g 5g R:11, S:7/8-16-33 25g bulk 43876 Platinum, nominally 10% on carbon black 500mg HiSPECÑ 2000, UN1325, MDL MFCD00011179, Ì 2g 10g R:11-36/37/38, S:26 50g bulk 35849 Platinum, nominally 20% on carbon black 1g HiSPECÑ 3000, UN1325, MDL MFCD00011179, Ì 5g 25g Cell Products R:11-36/37/38, S:26 bulk 42204 Platinum, nominally 40% on carbon black 1g

Fuel HiSPECÑ 4000, UN1325, MDL MFCD00011179, Ì 5g 25g R:11-36/37/38, S:26 bulk 43989 Platinum, nominally 50%, on carbon black 1g HiSPECÑ 8000, UN1325, MDL MFCD00011179, Ì 5g 25g R:11-36/37/38, S:26 bulk 44171 Platinum, nominally 60%, on carbon black 2g HiSPECÑ 9000, UN1325, MDL MFCD00011179, Ì 10g bulk R:11-36/37/38, S:26 44728 Platinum, nominally 60% on high surface area advanced carbon support 1g HiSPECÑ 9100, UN1325, MDL MFCD00011179, Ì 5g bulk R:11-33-36/37/38, S:7-26-33-37-60 45041 Platinum, nominally 70% on high surface area advanced carbon support 1g HiSPECÑ 13100, UN1325, MDL MFCD00011179, Ì 5g bulk 40473 Platinum, nominally 20%, Ruthenium, nominally 10% on carbon black 250mg HiSPECÑ 5000, UN1325, MDL MFCD00798552, Ì 1g 5g R:11-36/37/38, S:26 25g bulk 43990 Platinum, nominally 30%, Ruthenium, nominally 15% on carbon black 1g HiSPECÑ 7000, UN1325, MDL MFCD00798552, Ì 5g 25g R:11-36/37/38, S:26 bulk 44172 Platinum, nominally 40%, Ruthenium, nominally 20% on carbon black 2g HiSPECÑ 10000, UN1325, MDL MFCD00798552, Ì 10g bulk R:11-36/37/38, S:26 45039 Platinum, nominally 40%, Ruthenium nominally 20% on 50% compressed carbon black 1g HiSPECÑ 10300, MDL MFCD00798552 5g bulk 45040 Platinum, nominally 50%, Ruthenium nominally 25% on high surface area advanced 1g carbon support 5g HiSPECÑ 12100, UN1325, Ì bulk

64 www.alfa.com HiFUEL Catalysts

Stock # Description Standard Selling Sizes 45466 Copper based low temperature water gas shift catalyst, HiFUELÑ W220 500g Pellets, 3.1mm x 3.1mm 1kg

2.5kg Fuel bulk 45470 Copper based medium temperature water gas shift catalyst, HiFUELÑ W230 500g

Pellets, 5.2mm x 3.0mm 1kg Cell 2.5kg bulk P

45468 Copper based methanol reforming catalyst, HiFUELÑ R120 500g roducts Pellets, 5.2mm x 3.0mm 1kg 2.5kg bulk 45467 Iron-chrome based high temperature gas shift catalyst, HiFUELÑ W210 500g Pellets, 5.4mm x 3.6mm 1kg 2.5kg bulk 45465 Nickel based steam reforming catalyst, HiFUELÑ R110 500g 4-hole, 4-flute domed cylinders 1kg 2.5kg bulk 45469 Zinc oxide based sulfur removal material, HiFUELÑ A310 500g Spheres, 2-5mm dia 1kg 2.5kg bulk

1-800-343-0660 65 Fuel Cell Components

Stock # Description Standard Selling Sizes 45036 NafionÑ membrane, 0.05mm thick 15x15cm [31175-20-9], NRE-212, Note: NafionÑ NRE-212 perfluorosulfonic acid-PTFE copolymer, 30x30cm nominally 50 microns thick, standard exchange capacity 0.92meq/g. Membrane is positioned 60x60cm between a backing film and a cover sheet. bulk 42181 NafionÑ membrane, 0.09mm thick; high exchange capacity Ê 15x15cm [66796-30-3], Note: NafionÑ NE-1035 perfluorosulfonic acid-PTFE copolymer, nominally 90 30x30cm microns thick, standard exchange capacity 1.0meq/g bulk 42179 NafionÑ membrane, 0.125mm thick Ê 15x15cm [66796-30-3], Note: NafionÑ N-115 perfluorosulfonic acid-PTFE copolymer, nominally 125 30x30cm microns thick, standard exchange capacity 0.9meq/g 60x60cm s bulk 42180 NafionÑ membrane, 0.180mm thick Ê 15x15cm [31175-20-9], Note: NafionÑ N-117 perfluorosulfonic acid-PTFE copolymer, nominally 180 30x30cm microns thick, standard exchange capacity 0.9meq/g 60x60cm

Product bulk 45356 Toray Carbon Paper, TGP-60, 19x19cm each bulk Cell 45365 Toray Carbon Paper, Teflonated, TGP-60, 19x19cm each bulk Fuel 45360 Toray Carbon Paper, Baselayered, TGP-60, 12x12cm each bulk

45359 Direct Methanol Fuel Cell (DMFC) Anode, 25cm2 each bulk

45367 Direct Methanol Fuel Cell (DMFC) Anode, 50cm2 each bulk

45374 Direct Methanol Fuel Cell (DMFC) Anode, 100cm2 each bulk

45361 Direct Methanol Fuel Cell (DMFC) Cathode, 25cm2 each bulk

45368 Direct Methanol Fuel Cell (DMFC) Cathode, 50cm2 each bulk

45375 Direct Methanol Fuel Cell (DMFC) Cathode, 100cm2 each bulk

45357 Hydrogen Electrode/Reformate Cathode, 25cm2 each bulk

45452 Hydrogen Electrode/Reformate Cathode, 50cm2 each bulk

45372 Hydrogen Electrode/Reformate Cathode, 100cm2 each bulk

45358 Reformate Anode, 25cm2 each bulk

45366 Reformate Anode, 50cm2 each bulk

45373 Reformate Anode, 100cm2 each bulk 45364 Direct Methanol Fuel Cell (DMFC) Screener Membrane Electrode Assembly (MEA-5 each layer), Active Area 25cm2, plus membrane bulk 45371 Direct Methanol Fuel Cell (DMFC) Screener Membrane Electrode Assembly (MEA-5 each layer), Active Area 50cm2, plus membrane bulk 45378 Direct Methanol Fuel Cell (DMFC) Screener Membrane Electrode Assembly (MEA-5 each layer), Active Area 100cm2, plus membrane bulk

66 www.alfa.com Fuel Cell Components Stock # Description Standard Selling Sizes 45362 Hydrogen Screener Membrane Electrode Assembly (MEA-5 layer), Active Area 25cm2, each plus membrane border bulk 45369 Hydrogen Screener Membrane Electrode Assembly (MEA-5 layer), Active Area 50cm2, each plus membrane border bulk 45376 Hydrogen Screener Membrane Electrode Assembly (MEA-5 layer), Active Area 100cm2, each plus membrane border bulk 45363 Reformate Screener Membrane Electrode Assembly (MEA-5 layer), Active area 25cm2, each plus membrane border bulk 45370 Reformate Screener Membrane Electrode Assembly (MEA-5 layer), Active Area 50cm2, each plus membrane border bulk 45377 Reformate Screener Membrane Electrode Assembly (MEA-5 layer), Active Area 100cm2, each plus membrane border bulk Fuel Cell Pro ducts

1-800-343-0660 67 FibreCat Anchored Homogeneous Catalysts Anchored Homogeneous Catalysts

68 www.alfa.com FibreCat Anchored Homogeneous Catalysts ooeeu Catalysts Homogeneous Anc h ored

1-800-343-0660 69 FibreCat Anchored Homogeneous Catalysts Anchored Homogeneous Catalysts

70 www.alfa.com FibreCat Anchored Homogeneous Catalysts ooeeu Catalysts Homogeneous An c h ored

1-800-343-0660 71 FibreCat Anchored Homogeneous Catalysts Anchored Homogeneous Catalysts

72 www.alfa.com FibreCat Anchored Homogeneous Catalysts ooeeu Catalysts Homogeneous Anc h ored

Stock # Description Standard Selling Sizes 44111 Palladium anchored homogeneous catalyst, FibreCatÑ 1001 5g Application(s): Bromo/Iodo coupling, MDL MFCD04040828 25g 100g bulk 44110 Palladium anchored homogeneous catalyst, FibreCatÑ 1007 5g Application(s): Chloro coupling, MDL MFCD04040827 25g 100g bulk 44981 Palladium anchored homogeneous catalyst, FibreCatÑ 1026 5g 25g bulk 44983 Palladium anchored homogeneous catalyst, FibreCatÑ 1030 5g 25g 100g bulk 44982 Palladium anchored homogeneous catalyst, FibreCatÑ 1031 5g 25g 100g bulk 44730 Palladium anchored homogeneous catalyst, FibreCatÑ 1032 È 5g MDL MFCD08064489 bulk 44113 Rhodium anchored homogeneous catalyst, FibreCatÑ 2003 È 5g Application(s): Hydrogenation, MDL MFCD04040829 25g 100g bulk 44114 Rhodium anchored homogeneous catalyst, FibreCatÑ 2006 È 5g Application(s): Hydrogenation, MDL MFCD04040830 25g 100g bulk

1-800-343-0660 73 FibreCat Anchored Homogeneous Catalysts Stock # Description Standard Selling Sizes 44116 Ruthenium anchored homogeneous catalyst, FibreCatÑ 3002 È 5g Application(s): Selective Oxidation, MDL MFCD04040831 25g 100g bulk 44117 Osmium anchored homogeneous catalyst, FibreCatÑ 3003 È 5g Application(s): Dihydroxylation, MDL MFCD04040832 25g 100g R:36/37, S:26 bulk Anchored Homogeneous Catalysts

74 www.alfa.com Smopex PGM Scavengers Scav enger Produc ts

Stock # Description Standard Selling Sizes 44568 Smopex®-101 5g Powder, Application(s): Recovery of precious metals from catalyst process streams, 25g MDL MFCD06202258, Note: Chopped fibers. Strong cation action exchanger. Exchange 100g capacity 2.5mmol/g bulk S:22 44705 Smopex®-102 5g Powder, Application(s): Recovery of precious metals, MDL MFCD06202259, Note: Chopped 25g fibers-Weak acid cation exchanger. Exchange capacity 7-10 mmol/g 100g bulk 44706 Smopex®-103 5g Powder, Application(s): Recovery of precious metal complexes, MDL MFCD06202260, 25g Note: Strong base (trimethylammonium functional group) anion exchanger. Exchange capacity 100g 2-3.5 mmol/g bulk 44710 Smopex®-105 5g Powder, Application(s): Recovery of negatively charged precious metals complexes used in 25g complex reactions (Suzuki, Heck, Sonagashira), MDL MFCD06202261, Note: Weak base 100g (pyridine functional group) anion exchanger. Exchange capacity 4-6 mmol/g bulk S:22 45027 Smopex®-111 5g 25g bulk 44984 Smopex®-234 1g 5g 25g bulk 45043 Smopex® kit 1 1each Powder bulk

1-800-343-0660 75 Smopex Scavenger Kit Products Scavenger

76 www.alfa.com Alfa Aesar A Johnson Matthey Company, Inc. General Terms and Conditions of Sale

By ordering any product or material, Buyer hereby agrees to the following terms and conditions of sale:

Acceptance ALL ORDERS ARE ACCEPTED AND SHIPPED STRICTLY SUBJECT TO THESE GENERAL TERMS AND CONDITIONS AND NO OTHER TERMS AND CONDITIONS PRINTED ON BUYER'S PURCHASE ORDER OR OTHERWISE, SHALL BE APPLICABLE TO ANY ORDER.

Method of Shipment Whenever possible, Seller will ship products by the method specified on Buyer's order. Seller works closely with selected carriers and service is better achieved when using these carriers. Additional expenses and delays in shipment may be experienced when deviating from Seller's list of selected carriers. Seller will be happy to utilize other carriers based on Buyer's require- ments; however, Seller reserves the right to change the method of shipping for any reason. In such cases, Seller will select the most appropriate and cost effective method. Certain poison- ous, reactive, corrosive or other chemicals may require a barrier bag, steel can, and/or other special packaging for shipment. There will be additional charges for these packages. Seller's Customer Service Representatives will advise Buyer of the charges at the time the order is placed. Seller strives to minimize these costs through efficient packaging.

Terms and Prices All orders are shipped FOB seller's shipping point. Current standard published shipping charges will be added to the invoice when Buyer order indicates the freight terms are prepay and add. A current copy of these standard published shipping charges is available upon request. Buyer's order may be subject to handling charges. Buyer may request shipment by freight collect, if desired. All prices are listed in US dollars. PRICES AND PRODUCT DESCRIPTIONS ARE SUBJECT TO CHANGE WITHOUT NOTICE. In cases where the selling prices have changed significantly, Seller will contact Buyer for approval prior to shipping your mailed, faxed, or elec- tronically-transferred order. SELLER'S PAYMENT TERMS ARE NET 30 DAYS OF INVOICE, UNLESS OTHERWISE STATED.

Order Changes/Cancellations No change or addition by Buyer of any term or condition of this contract or any of Seller's rights or remedies hereunder shall be binding on Seller, nor shall the order hereby acknowledged be changed or cancelled by Buyer unless approved in writing by authorized officer of Johnson Matthey Catalog Company, Inc. There are no representations, agreements, promises, or under- standings between Buyer and Seller that are not expressed herein.

Claims for Lost or Damaged Shipments Seller urges Buyer to inspect all packages immediately upon receipt and report any damage, shortage or defect to Seller's Customer Service Department as soon as possible. CLAIMS FOR ANY DISCREPANCIES MUST BE MADE WITHIN 30 DAYS OF BUYER RECEIVING THE MATERIALS. All products are sold FOB seller's shipping point unless otherwise noted. Delivery of goods to the carrier at Seller's location or to other loading point, shall constitute delivery to Buyer, and regardless of shipping terms, all risks of loss or damage in transit shall be borne by Buyer. At Buyer's expense, each precious metal shipment valued at over $1,000.00 is fully insured and shipped Federal Express Priority I by Seller for Buyer's protection against loss or damage. Should Buyer need assistance in filing a claim, please call Seller's Customer Service Department.

Return Shipments Some materials are not returnable to Johnson Matthey Catalog Company, Inc., including, but not limited to, custom or special order materials, leaking or damaged chemicals, reagents past expiration date, items with missing or obliterated labels, parts or instructions, refrigerated or frozen materials and opened materials. Returned shipments will not be accepted by Seller unless prior arrangements have been made. If it is necessary to return any materials, contact Seller's Customer Service Department to obtain a return authorization number. REQUESTS FOR RETURN AUTHORIZATION NUMBERS MUST BE MADE WITHIN 30 DAYS OF BUYER RECEIVING THE MATERIALS. Only items authorized by Seller for return will be accepted. Final disposition of returned goods will be made only after receipt and inspection of goods. Collect shipments will not be accepted unless previously authorized. Hazardous goods must be shipped in compliance with all applicable Department of Transportation regulations. Material must be received on or before the Return Authorization expiration date. Material returned

1-800-343-0660 77 requiring disposal may incur additional charges. A 20% restocking fee is charged on catalog items returned, subject to a minimum charge of $20.00 and a maximum charge of $150.00.

Taxes Buyer shall be responsible for any use, tax, sales tax, excise tax, duty, custom, inspection or testing fee, or any other tax, fee or charge of any nature whatsoever imposed by any govern- mental authority, on or measure by the transaction between Seller and Buyer, in addition to the prices quoted or invoiced, unless Buyer shall provide Seller at the time the order is submitted an exemption certificate or other document acceptable to the taxing authority. In the event Seller is required to pay any such tax, fee or charge, Buyer shall reimburse Seller therefore.

Uses and Patents SELLER'S PRODUCTS ARE OFFERED FOR RESEARCH AND DEVELOPMENT USE ONLY. They are NOT intended for use as drugs, food additives, cosmetic, household chemicals, or other inappropriate applications. Seller does not warrant that Buyer's use of a product sold will not infringe any United States or other patents. The listing of a material in this catalog does not constitute a license to, or a recommendation for, its use in infringement of any patent. Seller reserves the right, in its sole discretion, to limit sales of products or not to sell products to any customers.

Limited Warranties The information included in this catalog has been obtained from normally reliable and depend- able sources and is correct to the best of Seller's knowledge; however, Seller does not make any guarantee of such information. Seller warrants title as provided in the Uniform Commercial Code. SELLER MAKES NO OTHER REPRESENTATIONS OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, AS TO MERCHANTABILITY, FITNESS FOR PARTICULAR PUR- POSE, OR ANY OTHER MATTER WITH RESPECT TO SELLER'S PRODUCTS, WHETHER USED ALONE OR IN CONNECTION WITH ANY OTHER SUBSTANCE.

Limited Liability/Purchaser's Indemnity Claims for rejected, nonconforming product, or any other claim against Seller, must be made in writing and must be received and acknowledged by Seller in writing within thirty (30) days of Buyer's receipt of the product in question. Any claims not satisfying this condition shall be deemed waived. Upon the approved return of any such product, Seller shall have the option, at its sole discretion, to replace such product with conforming product or to return the purchase price to Buyer. BUYER'S EXCLUSIVE REMEDY, FOR ANY CAUSE OR CLAIM WHATSOEV- ER, INCLUDING BUT NOT LIMITED TO ALLEGED BREACH OF WARRANTY, PRODUCT LIABILITY, NEGLIGENCE, OR OTHERWISE, SHALL BE FOR MONEY DAMAGES IN AN AMOUNT NOT TO EXCEED THE PURCHASE PRICE PAID BY BUYER FOR THE PRODUCT IN RESPECT TO WHICH THE CLAIM IS MADE. IN NO EVENT SHALL SELLER BE LIABLE FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES, WHETHER BUYER'S CLAIM IS IN CONTRACT, NEGLIGENCE, STRICT LIABILITY OR OTHERWISE EVEN IF SELLER HAS BEEN ADVISED OF THE POSSIBILITY OF SUCH DAMAGE.

Buyer represents and warrants that it's use products ordered will not violate any law or regula- tion. IN CONSIDERATION OF THE SALE OF PRODUCT TO BUYER, WHICH SALES SELL- ER WOULD NOT OTHERWISE MAKE, BUYER AGREES TO INDEMNIFY AND HOLD SELL- ER HARMLESS FROM ALL CLAIMS, EXPENSES, LOSSES AND LIABILITY OF ANY NATURE WHATSOEVER ARISING OUT OF BUYER'S HANDLING AND/OR USE OF PROD- UCT, WHETHER USED ALONE OR IN COMBINATION WITH ANY OTHER SUBSTANCE.

Applicable Law All orders shall be governed by the law of the Commonwealth of Massachusetts without regard to its choice of law principles. Any litigation concerning an order shall be brought in the United States District Courts and/or State courts located in the Commonwealth of Massachusetts and the parties hereby agree to submit to the jurisdiction of these courts for such purposes. The parties further agree that the Convention on Contracts for the International Sale of Goods shall have no application with respect to this order.

Material Safety Data Sheets Each product is accompanied by a Material Safety Data Sheet in compliance with the OSHA Hazard Communication Standard. If one is not immediately available, a copy will be sent via mail as soon as possible. Seller strongly recommends that Buyer reviews all relevant information available to ensure safe use of products. If an MSDS is needed prior to shipment of a product, or in case of an emergency, please contact Seller's Customer Service Department. Seller furnishes the information on each Material Safety Data Sheet without warranty.

78 www.alfa.com Technical Service At Buyer's request, Seller may furnish technical assistance and information with respect to products sold. Unless otherwise agreed, all such technical assistance and information will be provided without any representation or warranty and Buyer, as the user, assumes sole respon- sibility for results obtained in relying on this information. Seller makes no warranties of any kind or nature with respect to technical assistance or information provided. Any suggestions by Seller regarding use, application, or suitability of the products shall not be construed as an express or implied warranty. Seller strives to keep all technical discussions confidential, however, Seller makes NO guarantee that such discussion or information will remain confidential.

Hazards, Buyer's Use All of Seller's products should be handled only by qualified and trained individuals. In purchas- ing these products, the Buyer acknowledges that there are hazards associated with their use. Buyer represents and warrants to Seller that from Buyer's own independent review and study it is fully aware and knowledgeable about (a) the health and safety hazards associated with the handling of the products purchased; (b) industrial hygiene controls necessary to protect its workers from such health and safety hazards; (c) the need to adequately warn of health and safety hazards associated with products; and (d) government regulations regarding the use of and exposure to such products.

Toxic Substance Control Act (TSCA) Seller does not warrant that its products are listed in the chemical substances inventory under the Toxic Substances Control Act (TSCA). The Buyer represents and warrants that the use of products purchased from Seller will be in full compliance with the act and its regulations.

1-800-343-0660 79 Specialty & Bulk Products

Alfa Aesar’s Specialty Chemicals, Metals and Materials Group offers expertise in producing and sourcing a substantial range of products for your research, pilot-scale or production application. Backed by the global manufacturing network of Johnson Matthey, a world leader in advanced materials technology, Alfa Aesar offers prompt delivery of many thousands of chemicals and materials directly from stock.

Call for a Free Brochure or Contact our Product Specialists for an immediate response to your quote request.

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