Physical Units, Constants and Conversion Factors
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Depletion Forces Due to Image Charges Near Dielectric Discontinuities
Depletion forces due to image charges near dielectric discontinuities Robin A. Curtisa, Leo Lueb,∗ a School of Chemical Engineering and Analytical Science, The University of Manchester Oxford Road, Manchester M13 9PL, United Kingdom b Department of Chemical and Process Engineering, University of Strathclyde James Weir Building, 75 Montrose Street, Glasgow G1 1XJ, United Kingdom Abstract The depletion force is an effective inter-particle attractive interaction that is en- tropically driven by the exclusion of co-solvent molecules. For large co-solvents, such as polymers, the exclusion is primarily driven by excluded volume interac- tions. However, the exclusion of co-solvents, such as electrolytes, can be caused by other mechanisms. In this review, we summarize the literature on inter- particle depletion forces that arise from repulsive image-charge forces between low-dielectric particles and electrolytes. In particular, we emphasize the results from a variational perturbation theory for describing the salting-out behavior observed in moderately concentrated salt solutions. The theory predicts an unscreened force with a range given by the Bjerrum length and a magnitude proportional to the osmotic pressure of the salt solution. The force becomes sig- nificant at the same salt concentration where salting-out behavior is typically observed. Keywords: depletion force, dielectric, electrolyte, colloids 1. Introduction The depletion force was originally used to describe the attraction between colloidal particles induced by the addition of small polymer molecules [1]. In ∗Corresponding author Email address: [email protected] ( Leo Lue ) Preprint submitted to Curr. Opin. Colloid Interface Sci. December 1, 2014 this case, the force is driven by polymer exclusion from the colloidal particles. -
Operating Instructions Ac Snap-Around Volt-Ohm
4.5) HOW TO USE POINTER LOCK & RANGE FINDER LIFETIME LIMITED WARRANTY 05/06 From #174-1 SYMBOLS The attention to detail of this fine snap-around instrument is further enhanced by OPERATING INSTRUCTIONS (1) Slide the pointer lock button to the left. This allows easy readings in dimly lit the application of Sperry's unmatched service and concern for detail and or crowded cable areas (Fig.8). reliability. AC SNAP-AROUND VOLT-OHM-AMMETER (2) For quick and easy identification the dial drum is marked with the symbols as These Sperry snap-arounds are internationally accepted by craftsman and illustrated below (Fig.9). servicemen for their unmatched performance. All Sperry's snap-around MODEL SPR-300 PLUS & SPR-300 PLUS A instruments are unconditionally warranted against defects in material and Pointer Ampere Higher workmanship under normal conditions of use and service; our obligations under Lock range range to the to the this warranty being limited to repairing or replacing, free of charge, at Sperry's right. right. sole option, any such Sperry snap-around instrument that malfunctions under normal operating conditions at rated use. 1 Lower Lower range range to the to the left. left. REPLACEMENT PROCEDURE Fig.8 Fig.9 Securely wrap the instrument and its accessories in a box or mailing bag and ship prepaid to the address below. Be sure to include your name and address, as 5) BATTERY & FUSE REPLACEMENT well as the name of the distributor, with a copy of your invoice from whom the (1) Remove the screw on the back of the case for battery and fuse replacement unit was purchased, clearly identifying the model number and date of purchase. -
Modern Physics Unit 15: Nuclear Structure and Decay Lecture 15.1: Nuclear Characteristics
Modern Physics Unit 15: Nuclear Structure and Decay Lecture 15.1: Nuclear Characteristics Ron Reifenberger Professor of Physics Purdue University 1 Nucleons - the basic building blocks of the nucleus Also written as: 7 3 Li ~10-15 m Examples: A X=Chemical Element Z X Z = number of protons = atomic number 12 A = atomic mass number = Z+N 6 C N= A-Z = number of neutrons 35 17 Cl 2 What is the size of a nucleus? Three possibilities • Range of nuclear force? • Mass radius? • Charge radius? It turns out that for nuclear matter Nuclear force radius ≈ mass radius ≈ charge radius defines nuclear force range defines nuclear surface 3 Nuclear Charge Density The size of the lighter nuclei can be approximated by modeling the nuclear charge density ρ (C/m3): t ≈ 4.4a; a=0.54 fm 90% 10% Usually infer the best values for ρo, R and a for a given nucleus from scattering experiments 4 Nuclear mass density Scattering experiments indicate the nucleus is roughly spherical with a radius given by 1 3 −15 R = RRooA ; =1.07 × 10meters= 1.07 fm = 1.07 fermis A=atomic mass number What is the nuclear mass density of the most common isotope of iron? 56 26 Fe⇒= A56; Z = 26, N = 30 m Am⋅⋅3 Am 33A ⋅ m m ρ = nuc p= p= pp = o 1 33 VR4 3 3 3 44ππA R nuc π R 4(π RAo ) o o 3 3×× 1.66 10−27 kg = 3.2× 1017kg / m 3 4×× 3.14 (1.07 × 10−15m ) 3 The mass density is constant, independent of A! 5 Nuclear mass density for 27Al, 97Mo, 238U (from scattering experiments) (kg/m3) ρo heavy mass nucleus light mass nucleus middle mass nucleus 6 Typical Densities Material Density Helium 0.18 kg/m3 Air (dry) 1.2 kg/m3 Styrofoam ~100 kg/m3 Water 1000 kg/m3 Iron 7870 kg/m3 Lead 11,340 kg/m3 17 3 Nuclear Matter ~10 kg/m 7 Isotopes - same chemical element but different mass (J.J. -
Units and Magnitudes (Lecture Notes)
physics 8.701 topic 2 Frank Wilczek Units and Magnitudes (lecture notes) This lecture has two parts. The first part is mainly a practical guide to the measurement units that dominate the particle physics literature, and culture. The second part is a quasi-philosophical discussion of deep issues around unit systems, including a comparison of atomic, particle ("strong") and Planck units. For a more extended, profound treatment of the second part issues, see arxiv.org/pdf/0708.4361v1.pdf . Because special relativity and quantum mechanics permeate modern particle physics, it is useful to employ units so that c = ħ = 1. In other words, we report velocities as multiples the speed of light c, and actions (or equivalently angular momenta) as multiples of the rationalized Planck's constant ħ, which is the original Planck constant h divided by 2π. 27 August 2013 physics 8.701 topic 2 Frank Wilczek In classical physics one usually keeps separate units for mass, length and time. I invite you to think about why! (I'll give you my take on it later.) To bring out the "dimensional" features of particle physics units without excess baggage, it is helpful to keep track of powers of mass M, length L, and time T without regard to magnitudes, in the form When these are both set equal to 1, the M, L, T system collapses to just one independent dimension. So we can - and usually do - consider everything as having the units of some power of mass. Thus for energy we have while for momentum 27 August 2013 physics 8.701 topic 2 Frank Wilczek and for length so that energy and momentum have the units of mass, while length has the units of inverse mass. -
The Avogadro Constant to Be Equal to Exactly 6.02214X×10 23 When It Is Expressed in the Unit Mol −1
[august, 2011] redefinition of the mole and the new system of units zoltan mester It is as easy to count atomies as to resolve the propositions of a lover.. As You Like It William Shakespeare 1564-1616 Argentina, Austria-Hungary, Belgium, Brazil, Denmark, France, German Empire, Italy, Peru, Portugal, Russia, Spain, Sweden and Norway, Switzerland, Ottoman Empire, United States and Venezuela 1875 -May 20 1875, BIPM, CGPM and the CIPM was established, and a three- dimensional mechanical unit system was setup with the base units metre, kilogram, and second. -1901 Giorgi showed that it is possible to combine the mechanical units of this metre–kilogram–second system with the practical electric units to form a single coherent four-dimensional system -In 1921 Consultative Committee for Electricity (CCE, now CCEM) -by the 7th CGPM in 1927. The CCE to proposed, in 1939, the adoption of a four-dimensional system based on the metre, kilogram, second, and ampere, the MKSA system, a proposal approved by the ClPM in 1946. -In 1954, the 10th CGPM, the introduction of the ampere, the kelvin and the candela as base units -in 1960, 11th CGPM gave the name International System of Units, with the abbreviation SI. -in 1970, the 14 th CGMP introduced mole as a unit of amount of substance to the SI 1960 Dalton publishes first set of atomic weights and symbols in 1805 . John Dalton(1766-1844) Dalton publishes first set of atomic weights and symbols in 1805 . John Dalton(1766-1844) Much improved atomic weight estimates, oxygen = 100 . Jöns Jacob Berzelius (1779–1848) Further improved atomic weight estimates . -
Coulomb's Force
COULOMB’S FORCE LAW Two point charges Multiple point charges Attractive Repulsive - - + + + The force exerted by one point charge on another acts along the line joining the charges. It varies inversely as the square of the distance separating the charges and is proportional to the product of the charges. The force is repulsive if the charges have the same sign and attractive if the charges have opposite signs. q1 Two point charges q1 and q2 q2 [F]-force; Newtons {N} [q]-charge; Coulomb {C} origin [r]-distance; meters {m} [ε]-permittivity; Farad/meter {F/m} Property of the medium COULOMB FORCE UNIT VECTOR Permittivity is a property of the medium. Also known as the dielectric constant. Permittivity of free space Coulomb’s constant Permittivity of a medium Relative permittivity For air FORCE IN MEDIUM SMALLER THAN FORCE IN VACUUM Insert oil drop Viewing microscope Eye Metal plates Millikan oil drop experiment Charging by contact Example (Question): A negative point charge of 1µC is situated in air at the origin of a rectangular coordinate system. A second negative point charge of 100µC is situated on the positive x axis at the distance of 500 mm from the origin. What is the force on the second charge? Example (Solution): A negative point charge of 1µC is situated in air at the origin of a rectangular coordinate system. A second negative point charge of 100µC is situated on the positive x axis at the distance of 500 mm from the origin. What is the force on the second charge? Y q1 = -1 µC origin X q2= -100 µC Example (Solution): Y q1 = -1 µC origin X q2= -100 µC END Multiple point charges It has been confirmed experimentally that when several charges are present, each exerts a force given by on every other charge. -
Page 1 of 29 Dalton Transactions
Dalton Transactions Accepted Manuscript This is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are published online shortly after acceptance, before technical editing, formatting and proof reading. Using this free service, authors can make their results available to the community, in citable form, before we publish the edited article. We will replace this Accepted Manuscript with the edited and formatted Advance Article as soon as it is available. You can find more information about Accepted Manuscripts in the Information for Authors. Please note that technical editing may introduce minor changes to the text and/or graphics, which may alter content. The journal’s standard Terms & Conditions and the Ethical guidelines still apply. In no event shall the Royal Society of Chemistry be held responsible for any errors or omissions in this Accepted Manuscript or any consequences arising from the use of any information it contains. www.rsc.org/dalton Page 1 of 29 Dalton Transactions Core-level photoemission spectra of Mo 0.3 Cu 0.7 Sr 2ErCu 2Oy, a superconducting perovskite derivative. Unconventional structure/property relations a, b b b a Sourav Marik , Christine Labrugere , O.Toulemonde , Emilio Morán , M. A. Alario- Manuscript Franco a,* aDpto. Química Inorgánica, Facultad de CC.Químicas, Universidad Complutense de Madrid, 28040- Madrid (Spain) bCNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, Pessac, F-33608, France -
Irilll SDI: 0378-4371(92)00312-H
Physica A 195 (1993) 387-397 North-Holland IRIlll SDI: 0378-4371(92)00312-H On the spinodal instability of highly asymmetric hard sphere suspensions H.N.W. Lekkerkerker and A. Stroobants Van't Hoff Laboratory for Physical and Colloid Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands Received 21 December 1992 A new treatment of the binodal instability of suspensions containing a highly asymmetric mixture of hard spheres is presented. The origin of the instability is the attractive depletion interaction between the larger spheres, which is caused by the presence of the smaller spheres. 1. Introduction Until recently it was generally believed that hard sphere mixtures are stable with respect to phase separation into two fluid phases. Indeed, at least within the Percus-Yevick closure of the Ornstein-Zernike equation and using the compressibility theorem to calculate the thermodynamic quantities this is true [1,2]. However, recently Biben and Hansen [3] have shown that starting from the Rogers-Young closure [4], which is known to be more accurate for hard spheres than the Percus-Yevick closure, such mixtures do seem to become unstable for diameter ratios larger than 5 at sufficiently high volume fractions. A direct experimental test of the prediction of Biben and Hansen is obviously not any easy task as hard sphere atoms do not exist in reality. However, recently strong experimental evidence for phase separation in bimodal disper- sions of sterically stabilized silica particles was obtained in our laboratory [5]. The short-ranged harshly repulsive interactions between these sterically stabil- ized colloidal particles closely approximate that of hard spheres [6] and therefore the thermodynamic properties of such bimodal suspensions are closely related to those of hard sphere mixtures [7]. -
Guide for the Use of the International System of Units (SI)
Guide for the Use of the International System of Units (SI) m kg s cd SI mol K A NIST Special Publication 811 2008 Edition Ambler Thompson and Barry N. Taylor NIST Special Publication 811 2008 Edition Guide for the Use of the International System of Units (SI) Ambler Thompson Technology Services and Barry N. Taylor Physics Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899 (Supersedes NIST Special Publication 811, 1995 Edition, April 1995) March 2008 U.S. Department of Commerce Carlos M. Gutierrez, Secretary National Institute of Standards and Technology James M. Turner, Acting Director National Institute of Standards and Technology Special Publication 811, 2008 Edition (Supersedes NIST Special Publication 811, April 1995 Edition) Natl. Inst. Stand. Technol. Spec. Publ. 811, 2008 Ed., 85 pages (March 2008; 2nd printing November 2008) CODEN: NSPUE3 Note on 2nd printing: This 2nd printing dated November 2008 of NIST SP811 corrects a number of minor typographical errors present in the 1st printing dated March 2008. Guide for the Use of the International System of Units (SI) Preface The International System of Units, universally abbreviated SI (from the French Le Système International d’Unités), is the modern metric system of measurement. Long the dominant measurement system used in science, the SI is becoming the dominant measurement system used in international commerce. The Omnibus Trade and Competitiveness Act of August 1988 [Public Law (PL) 100-418] changed the name of the National Bureau of Standards (NBS) to the National Institute of Standards and Technology (NIST) and gave to NIST the added task of helping U.S. -
Physical Chemistry LD
Physical Chemistry LD Electrochemistry Chemistry Electrolysis Leaflets C4.4.5.2 Determining the Faraday constant Aims of the experiment To perform an electrolysis. To understand redox reactions in practice. To work with a Hoffman electrolysis apparatus. To understand Faraday’s laws. To understand the ideal gas equation. The second law is somewhat more complex. It states that the Principles mass m of an element that is precipitated by a specific When a voltage is applied to a salt or acid solution, material amount of charge Q is proportional to the atomic mass, and is migration occurs at the electrodes. Thus, a chemical reaction inversely proportional to its valence. Stated more simply, the is forced to occur through the flow of electric current. This same amount of charge Q from different electrolytes always process is called electrolysis. precipitates the same equivalent mass Me. The equivalent mass Me is equal to the molecular mass of an element divid- Michael Faraday had already made these observations in the ed by its valence z. 1830s. He coined the terms electrolyte, electrode, anode and cathode, and formulated Faraday's laws in 1834. These count M M = as some of the foundational laws of electrochemistry and e z describe the relationships between material conversions In order to precipitate this equivalent mass, 96,500 Cou- during electrochemical reactions and electrical charge. The lombs/mole are always needed. This number is the Faraday first of Faraday’s laws states that the amount of moles n, that constant, which is a natural constant based on this invariabil- are precipitated at an electrode is proportional to the charge ity. -
Useful Constants
Appendix A Useful Constants A.1 Physical Constants Table A.1 Physical constants in SI units Symbol Constant Value c Speed of light 2.997925 × 108 m/s −19 e Elementary charge 1.602191 × 10 C −12 2 2 3 ε0 Permittivity 8.854 × 10 C s / kgm −7 2 μ0 Permeability 4π × 10 kgm/C −27 mH Atomic mass unit 1.660531 × 10 kg −31 me Electron mass 9.109558 × 10 kg −27 mp Proton mass 1.672614 × 10 kg −27 mn Neutron mass 1.674920 × 10 kg h Planck constant 6.626196 × 10−34 Js h¯ Planck constant 1.054591 × 10−34 Js R Gas constant 8.314510 × 103 J/(kgK) −23 k Boltzmann constant 1.380622 × 10 J/K −8 2 4 σ Stefan–Boltzmann constant 5.66961 × 10 W/ m K G Gravitational constant 6.6732 × 10−11 m3/ kgs2 M. Benacquista, An Introduction to the Evolution of Single and Binary Stars, 223 Undergraduate Lecture Notes in Physics, DOI 10.1007/978-1-4419-9991-7, © Springer Science+Business Media New York 2013 224 A Useful Constants Table A.2 Useful combinations and alternate units Symbol Constant Value 2 mHc Atomic mass unit 931.50MeV 2 mec Electron rest mass energy 511.00keV 2 mpc Proton rest mass energy 938.28MeV 2 mnc Neutron rest mass energy 939.57MeV h Planck constant 4.136 × 10−15 eVs h¯ Planck constant 6.582 × 10−16 eVs k Boltzmann constant 8.617 × 10−5 eV/K hc 1,240eVnm hc¯ 197.3eVnm 2 e /(4πε0) 1.440eVnm A.2 Astronomical Constants Table A.3 Astronomical units Symbol Constant Value AU Astronomical unit 1.4959787066 × 1011 m ly Light year 9.460730472 × 1015 m pc Parsec 2.0624806 × 105 AU 3.2615638ly 3.0856776 × 1016 m d Sidereal day 23h 56m 04.0905309s 8.61640905309 -
Arxiv:2012.01639V4 [Cond-Mat.Soft] 29 Jun 2021 T =Kbt/Ε, Where Kb and T Are the Boltzmann Constant and the Temperature of System, Respectively
Self-Assembly of Isostatic Self-Dual Colloidal Crystals Qun-Li Lei,1, 2, ∗ Wei Zheng,1, 2, ∗ Feng Tang,1 Xiangang Wan,1 Ran Ni,2, y and Yuqiang Ma1, z 1National Laboratory of Solid State Microstructures and School of Physics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210093, China 2School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, 637459, Singapore Self-dual structures whose dual counterparts are themselves possess unique hidden symmetry, beyond the description of classical spatial symmetry groups. Here we propose a strategy based on a nematic monolayer of attractive half-cylindrical colloids to self-assemble these exotic structures. This system can be seen as a 2D system of semi-disks. By using Monte Carlo simulations, we discover two isostatic self-dual crystals, i.e., an unreported crystal with pmg space-group symmetry and the twisted Kagome crystal. For the pmg crystal approaching the critical point, we find the double degeneracy of the full phononic spectrum at the self-dual point, and the merging of two tilted Weyl nodes into one critically-tilted Dirac node. The latter is `accidentally' located on the high-symmetry line. The formation of this unconventional Dirac node is due to the emergence of the critical flat bands at the self-dual point, which are linear combinations of finite-frequency floppy modes. These modes can be understood as mechanically-coupled self-dual rhomb chains vibrating in some unique uncoupled ways. Our work paves the way for designing and fabricating self-dual materials with exotic mechanical or phononic properties.