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Mottramite Pbcu(VO4)(OH) C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Orthorhombic
Mottramite PbCu(VO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As crystals, equant or dipyramidal {111}, prismatic [001] or [100], with {101}, {201}, many others, to 3 mm, in drusy crusts, botryoidal, usually granular to compact, massive. Physical Properties: Fracture: Small conchoidal to uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = ∼5.9 D(calc.) = 6.187 Optical Properties: Transparent to nearly opaque. Color: Grass-green, olive-green, yellow- green, siskin-green, blackish brown, nearly black. Streak: Yellowish green. Luster: Greasy. Optical Class: Biaxial (–), rarely biaxial (+). Pleochroism: Weak to strong; X = Y = canary-yellow to greenish yellow; Z = brownish yellow. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,strong; rarely r< v.α= 2.17(2) β = 2.26(2) γ = 2.32(2) 2V(meas.) = ∼73◦ Cell Data: Space Group: P nma. a = 7.667–7.730 b = 6.034–6.067 c = 9.278–9.332 Z=4 X-ray Powder Pattern: Mottram St. Andrew, England; close to descloizite. 3.24 (vvs), 5.07 (vs), 2.87 (vs), 2.68 (vs), 2.66 (vs), 2.59 (vs), 1.648 (vs) Chemistry: (1) (2) (1) (2) CrO3 0.50 ZnO 0.31 10.08 P2O5 0.24 PbO 55.64 55.30 As2O5 1.33 H2O 3.57 2.23 V2O5 21.21 22.53 insol. 0.17 CuO 17.05 9.86 Total 100.02 100.00 (1) Bisbee, Arizona, USA; average of three analyses. (2) Pb(Cu, Zn)(VO4)(OH) with Zn:Cu = 1:1. -
Descloizite Pbzn(VO4)(OH) C 2001-2005 Mineral Data Publishing, Version 1
Descloizite PbZn(VO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As crystals, equant or pyramidal {111}, prismatic [001] or [100], or tabular {100}, with {101}, {201}, many others, rarely skeletal, to 5 cm, commonly in drusy crusts, stalactitic or botryoidal, coarsely fibrous, granular to compact, massive. Physical Properties: Fracture: Small conchoidal to uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = ∼6.2 D(calc.) = 6.202 Optical Properties: Transparent to nearly opaque. Color: Brownish red, red-orange, reddish brown to blackish brown, nearly black. Streak: Orange to brownish red. Luster: Greasy. Optical Class: Biaxial (–), rarely biaxial (+). Pleochroism: Weak to strong; X = Y = canary-yellow to greenish yellow; Z = brownish yellow. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,strong; rarely r< v.α= 2.185(10) β = 2.265(10) γ = 2.35(10) 2V(meas.) = ∼90◦ Cell Data: Space Group: P nma. a = 7.593 b = 6.057 c = 9.416 Z = 4 X-ray Powder Pattern: Venus mine, [El Guaico district, C´ordobaProvince,] Argentina; close to mottramite. 3.23 (vvs), 5.12 (vs), 2.90 (vs), 2.69 (vsb), 2.62 (vsb), 1.652 (vs), 4.25 (s) Chemistry: (1) (2) (1) (2) SiO2 0.02 ZnO 19.21 10.08 As2O5 0.00 PbO 55.47 55.30 +350◦ V2O5 22.76 22.53 H2O 2.17 −350◦ FeO trace H2O 0.02 MnO trace H2O 2.23 CuO 0.56 9.86 Total 100.21 100.00 (1) Abenab, Namibia. -
Heyite, Pbsfez(VO )Zo , a New Mineral from Nevada
MINERALOGICAL MAGAZINE, MARCH ~973, VOL. 39, PP. 65--68 Heyite, PbsFez(VO )zO , a new mineral from Nevada SIDNEY A. WILLIAMS Phelps Dodge Corporation, Douglas, Arizona SUMMARY. Heyite occurs in silicified limestone with other oxidation-zone minerals derived from galena, chalcopyrite, aod pyrite. The occurrence is near Ely, Nevada. Most common are pyro- morphite, cerussite, and chrysocolla. Heyite occurs on and replaces corroded tungstenian wulfenite. Crystals are small (up to o'4 mm), simple in habit, and monoclinic. Only {oo I }, {t oo}, {t I o}, and {io I } have been observed. Twinning on {I Io} is relatively common. The colour is yellow-orange with a yellow streak, H = 4. Electron probe analyses (average of three) gave PbO 75"4 %, ZnO o'8I %, FeO 8"4I %, V~O5 I2"65 %. This leads to Pbs(Fe,Zn)2(VO4)204, with Z = L The space group is P21/m. Cell constants, refined from powder data, are a 8-9IO/~, b 6'oi7, c 7"734 (all !o'oo4/~);/3 I I I ~ 53'-4-4'. The strongest powder lines (Cr-K~) are: 3"248, 11 ~, (i oo); 2"97o, 3oi, 21~, (69); 2"767, 2Ii (6I); 4"873, iio, (46); 3"674, ~I~, (35); 2"306 (33); 3"oio, o2o, (29); 3"4~2, 2o~, II~, (25); 8"281, Ioo, (25); and 2"II3 (2o). Geale 6'284, Gmeas 6"3• Optically biaxial with 2Ve 82~10, 89~e~ ; c~9 2-I85,/39 2'219, ~9 2.266; all values zko-oI and determined in S-Se melts. Dispersion is weak with p > v. -
Mottramite, Descloizite, and Vanadinite) in the Caldbeck Area of Cumberland
289 New occurrences of vanadium minerals (mottramite, descloizite, and vanadinite) in the Caldbeck area of Cumberland. By ART~VR W. G. KINGSBURu F.G.S., Dept. of Geology and Mineralogy, University Museum, Oxford, and J. HARTLnY, B.Sc., F.G.S., Dept. of Geology, University of Leeds. [Taken as read 10 June 1954.] Summary.--Four new occurrences of vanadium minerals are described. New X-ray powder data are given for descloizite and mottramite, and show appreciable differences. Evidence is brought that the original occurrence of mottramite was not at Mottram St. Andrew, Cheshire, but Pim Hill, Shropshire, and that most if not all specimens labelled Mottram St. Andrew or Cheshire really came from Pim Hill. ANADIUM minerals are rare in the British Isles, and only two V species, mottramite (Cu, Zn)PbV0tOH and vanadinite Pbs(VO4)aC1, have so far been recorded from a limited number of localities. We do not include the vanadiferous nodules from Budleigh Salterton in Devon, as the vanadiferous mineral has not been identified. Mottramite, supposedly from Mottram St. Andrew in Cheshire, was first described in 1876,1 but we have evidence (below, p. 293) that the locality was in fact Pim Hill in Shropshire. ~ Vanadinite has so far only been found at Leadhills and Wanlockhead in Scotland. Vauquelinite has been de- scribed from Leadhills and Wanlockhead,a but the specimens have since been shown to be mottramite. 4 As a result of our investigations in the Lake District, we have found several new localities in the Caldbeck area for raottramite, deseloizite, and vanadinite. Higher part of Brandy Gill, Carroek Fell. -
The Crystal Chemistry of Duftite, Pbcuaso4(OH)
Mineralogical Magazine, February 1998, Vol. 62(1), pp. 121–130 The crystalchemistry of duftite, PbCuAsO4(OH) and the b-duftiteproblem KHARISUN*, MAX R. TAYLOR, D. J. M BEVAN Department of Chemistry, The Flinders University of South Australia, GPOBox 2100 Adelaide, S.A.5001, Australia AND ALLAN PRING Department of Mineralogy, South Australian Museum, North Terrace, S.A.5000, Australia ABSTRACT Duftite,PbCu(AsO 4)(OH)is orthorhombic, space group P212121 with a = 7.768(1), b = 9. 211(1), c = 5.999(1) AÊ ,Z=4;the structure has been refined to R =4.6 % and Rw = 6.5% using640 observed reflections[F> 2 s(F)].The structure consists of chainsof edge-sharingCuO 6 ‘octahedra’,parallelto c; whichare linked via AsO 4 tetrahedraand Pb atoms in distorted square antiprismatic co-ordination to forma threedimensional network. The CuO 6 ‘octahedra’ showJahn-Teller distortion with the elongationrunning approximately along <627>. The hydrogen bonding network in the structure was characterizedusing bond valence calculations. ‘b-duftite’ isan intermediate in the duftite– conichalcite series,which has a modulatedstructure based on the intergrowth of the two structures in domains of approximately50 A Ê .Theorigin of the modulation is thought to beassociatedwith displacements in the oxygenlattice and is related to the orientation of the Jahn-Teller distortion of CuO 6 ‘octahedra’. Approximatelyhalf of the strips show an elongation parallel to <627> while the other strips are elongatedparallel to [010 ].This ordering results in an increase in the b cellrepeat compared to duftite andconichalcite. KEY WORDS: duftite,conichalcite, crystal structure, crystal chemistry, modulated structure. hadearlier tentatively proposed the point group Introduction 222,on the basis of morphological observations. -
Bulletin 65, the Minerals of Franklin and Sterling Hill, New Jersey, 1962
THEMINERALSOF FRANKLINAND STERLINGHILL NEWJERSEY BULLETIN 65 NEW JERSEYGEOLOGICALSURVEY DEPARTMENTOF CONSERVATIONAND ECONOMICDEVELOPMENT NEW JERSEY GEOLOGICAL SURVEY BULLETIN 65 THE MINERALS OF FRANKLIN AND STERLING HILL, NEW JERSEY bY ALBERT S. WILKERSON Professor of Geology Rutgers, The State University of New Jersey STATE OF NEw JERSEY Department of Conservation and Economic Development H. MAT ADAMS, Commissioner Division of Resource Development KE_rr_ H. CR_V_LINCDirector, Bureau of Geology and Topography KEMBLEWIDX_, State Geologist TRENTON, NEW JERSEY --1962-- NEW JERSEY GEOLOGICAL SURVEY NEW JERSEY GEOLOGICAL SURVEY CONTENTS PAGE Introduction ......................................... 5 History of Area ................................... 7 General Geology ................................... 9 Origin of the Ore Deposits .......................... 10 The Rowe Collection ................................ 11 List of 42 Mineral Species and Varieties First Found at Franklin or Sterling Hill .......................... 13 Other Mineral Species and Varieties at Franklin or Sterling Hill ............................................ 14 Tabular Summary of Mineral Discoveries ................. 17 The Luminescent Minerals ............................ 22 Corrections to Franklln-Sterling Hill Mineral List of Dis- credited Species, Incorrect Names, Usages, Spelling and Identification .................................... 23 Description of Minerals: Bementite ......................................... 25 Cahnite .......................................... -
Introduction to Apatites
Chapter 1 Introduction to Apatites Petr Ptáček Additional information is available at the end of the chapter http://dx.doi.org/10.5772/62208 Abstract Apatite is the generic name, which was first introduced by German geologist A.G. Werner. These minerals and their synthetic analogs represent a major class of ionic compounds and the most common crystalline form of calcium phosphates, which are of interest of many industrial branches and scientific disciplines. Since, apatite (fluora‐ patite) is the most abundant phosphate mineral, apatite bearing phosphate rocks represents an important source of inorganic phosphorus. First chapter of this book introduces the basic concepts of nomenclature, composition, classification, crystal structure, mineralogy and properties of minerals from the supergroup of apatite. Furthermore, the minerals from the group of apatite and polysomatic apatites are described. Since, the most of the topics mentioned in this chapter will be developed in the following chapters, the key concepts provided in this chapter are important to understood before proceeding further. Keywords: Apatite, Group of Apatite, Polysomatic Apatites, Fluorapatite, Hydroxyla‐ patite, Chlorapatite, Vanadinite The minerals1 [1],[2],[3],[4],[5] from the apatite group2 [6] are classified as hexagonal or pseudo‐ hexagonal monoclinic anhydrous phosphates containing hydroxyl or halogen of the generic formula3: 1Minerals are individual components comprising rocks formed by geological processes classified according to their crystal structure and chemical composition. The total number of minerals accepted by mineralogical community is about 4000. Mineraloids are mineral-like phases including synthetic materials, human-treated substances, and some biological materials, which do not fulfill the criteria for the definition of mineral species [2]. -
MINERALS with a FRENCH CONNECTION François Fontan and Robert F
MINERALS with a FRENCH CONNECTION François Fontan and Robert F. Martin The Canadian Mineralogist Special Publication 13 TABLE OF CONTENTS Préface vii Preface viii Introduction 1 The scope and contents of this book 1 Early discoveries 1 The three museums in Paris 2 Previous surveys of minerals discovered in France 5 The profile of mineralogy in France today 6 The information to be reported in each entry 6 Bibliography 7 Acknowledgements: special mentions 8 Acknowledgements prepared by François Fontan (2005–2007) 9 Acknowledgements prepared by Robert F. Martin (2007–2017) 9 Hold the presses: new arrivals! 11 Minerals with a type locality in France 13 Minerals discovered elsewhere and named after French citizens 267 Six irregular cases 525 Appendices and indexes 539 The appendices 540 Appendix 1. Minerals with a type locality in France, including New Caledonia: alphabetical listing 541 Appendix 2. Minerals (n = 127) with a type locality in France, including New Caledonia: chronological listing 544 Figure A1. Geographic distribution of mineral discoveries in France 545 Figure A2. Geographic distribution of mineral discoveries in New Caledonia 546 Figure A3. The number of type localities of minerals, grouped by decade 546 Appendix 3. Minerals with a type locality in France, including New Caledonia: geographic distribution 547 Appendix 4. Minerals discovered elsewhere than in France and named after French citizens: alphabetical list 549 Appendix 5. Minerals (n = 128) discovered elsewhere than in France and named after French citizens: chronological listing 552 Appendix 6. Minerals discovered elsewhere than in France and named after French citizens: geographic distribution 553 Appendix 7. The top 21 countries ranked according to the number of new mineral species discovered 556 Appendix 8. -
The Descloizite-Mottramite Series of Vanadates from Minas Do Lueca, Angola
THE AMERICAN MINERALOGIST, VOL. 45, ]ULY_AUGUST, 1960 THE DESCLOIZITE-MOTTRAMITE SERIES OF VANADATES FROM MINAS DO LUECA, ANGOLA ANrnoNv P. Mrr.rMlr.r, Royal SchooloJ Mines, Imperial College of Scienceand, Technology, London. Assrnlcr The results are given of a chemical, microchemical and x-ray investigation of vanadium minerals from a new locality in west Africa-Minas do Lueca in Angola, together with comparative data for similar minerals from other localities. A rapid and simple technique of microchemical analysis has been devised which enables accurate discrimination to be made between different members of the descloizite (Zn)pb(VO)OH-mottramite (Cu)Pb(VO)OH isomorphous series. A description is given of the mode of occurrence and origin of the vanadium minerals at the Lueca Mine, and of the associated tarbuttite ZnTPO4OHand volborthite Cu:(VOJz.3HrO. INrnooucrrow In the courseof a study of a new vanadium depositat Minas do Lueca in Angola, PortugueseWest Africa, it was found that there was a wide variation in color and physical propertiesof the ,,descloizite,'-typemin- eralsoccurring in the deposit.Reference to Iiterature showedthat there is still some confusionin the nomenclatureof these minerals and that the x-ray powder diffraction data have not been fully established for a representativenumber of members of the isomorphousseries to which thesevanadates belong. For paragenesisstudies of the vanadium min- eralizationat Lueca, it was found necessaryto make preciseidentifica- tion of membersof the seriespresent in the ore. For this purpose,com- plete chemicalanalysis was found to be too tediousin view of the large number of specimensinvolved, and *-ray powder photography too in- definite;consequently a rapid microchemicaltechnique has beendevised which enablesprecise discrimination to be made between members of the descloizite-mottramiteseries. -
Major, Minor and Trace Element Composition of Pyromorphite-Group Minerals As Recorder of Supergene Weathering Processes From
1 Major, minor and trace element composition of pyromorphite-group minerals as 2 recorder of supergene weathering processes from the Schwarzwald mining 3 district, SW Germany 4 5 6 REVISION 1 7 8 9 10 Gregor Markl*, Michael A. W. Marks, Johannes Holzäpfel, Thomas Wenzel 11 12 13 14 15 16 17 Mathematisch-Naturwissenschaftliche Fakultät, Fachbereich Geowissenschaften, 18 Universität Tübingen, Wilhelmstraße 56, D-72074 Tübingen, Germany. 19 20 *corresponding author: [email protected] 21 22 23 24 25 26 27 Keywords: pyromorphite, mimetite, vanadinite, fluorophosphohedyphane, hedyphane, 28 trace elements, solid solution, “hydroxylmimetite” 29 30 31 Abstract 32 33 More than 150 samples of pyromorphite, mimetite, vanadinite and minerals of the 34 hedyphane-group (which collectively are summarized here under the term PyGM for 35 pyromorphite-group minerals) from the Schwarzwald mining district, SW Germany, 36 have been analyzed by electron microprobe and LA-ICP-MS. In this largest study of its 37 kind, the relations of PyGM composition to host rock and fluid compositions and the 38 amount of solid solution between the various endmembers were investigated. In 39 addition, we report the colors of the many analyzed mineral compositions. The most 40 important results are: 41 - pyromorphite and mimetite are completely miscible; 42 - at conditions of the oxidation zone in ore deposits, the solvus between pyromorphite 43 and vanadinite appears to asymmetrical with up to about 3 mol% of vanadinite 44 component in pyromorphite and up to about 39 mol% -
The Mineralogical Magazine
THE MINERALOGICAL MAGAZINE AND JOUR1VAL OF THE MINERALOGICAL SOCIETY. No. 68. April, 1908. Vol. XV. On Hopeite and other zinc phosphates and associated minerals from the Broken Hill mines, North-Western .Rhodesia. By L. J. SrENC~R, M.A., F.G.S. Assistant in the Mineral Department of the :British Museum. [Read November 12, 1907.] HE new and remarkable mineral locality known as Rhodesia T Broken Hill is situated in NorLh-Western Rhodesla, at a distance of about 800 miles to tile north-east of tile Victoria Falls, and at tlw present terminus of the Cape to Cairo ]{ailway. The outcrop of lead and zinc ore which occurs here was accidentally discovered in January, 1902, by Mr. T. G. Davey, while he was prospecti,g the country for copper, l~ising out of the flat surrounding country is a series of low hills or kopjes, the largest of them being about 90 feet in height ; and these consist almost entirely of oxidized ore. The surrounding rocks are mainly crystalline limestones with some beds of sandstone, conglomerate, and phyllite. The ordinary type of ore of which the kopjes consist is compact and of a light yellowish colour. It is composed of an intimate intermixture of zinc silicate (hemimorphite) and lead carbonate (eerussitc) with variable amounts of interspersed iron hydroxide (llmonite). Crystal-lined cavities are of frequent occurrence in this ore. In the work of explora- tion, one of the tunnels driven through Kopje No. 1 broke into a large cavern, measuring about 24 x 80 feet. In this cave were found bones of recent animals, together with stone implements and other evidences of B 2 L, J. -
Oxidized Zinc Deposits of the United States
Oxidized Zinc Deposits of the United States GEOLOGICAL SURVEY BULLETIN 1135 This bulletin was published as separate chapters A-C UNITED STATES DEPARTMENT--OF THE INTERIOR STEWART· L.' ·UDALL,. Secretary - GEOLOGICAL SURVEY Thomas B. Nolan, Director CONTENTS [The letters in parentheses preceding the titles designate separately published chapters] Oxidized zinc deposits of the United States: (A) Part 1. General geology. (B) Part 2. Utah. ( 0) Part 3. Colorado. 0 Oxidized Zinc Deposits of the United States Part 1. General Geology By ALLEN V. HEYL and C. N. BOZION GEOLOGICAL SURVEY BULLETIN 1135-A Descriptions of the many varieties of ox idized zinc deposits of supergeneland hypogene origin UNITED STATES GOVERNMENT PRINTING OFFICE1 WASHINGTON a 1962 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY Thomas B. Nolan, Director For sale by the Superintendent of Documents, U.S. Government Printing Office Washington 25, D.C. CONTENTS Page Abstract---------------------------------------------------------- A-1 Introduction------------------------------------------------------ 1 Distribution_ _ _ _ __ _ _ _ _ _ __ __ _ __ _ _ _ _ _ _ _ __ __ __ __ __ _ _ _ __ _ __ _ _ _ _ _ __ __ _ _ 3 Mliner&ogY------------------------------------------------------- 5 Commercial ores___________________________________________________ 7 Varieties----------------------------------------------------- 7 Grades------------------------------------------------------- 9 Generalgeology___________________________________________________