Incandescence and Luminescence
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Article Soot Photometer Using Supervised Machine Learning
Atmos. Meas. Tech., 12, 3885–3906, 2019 https://doi.org/10.5194/amt-12-3885-2019 © Author(s) 2019. This work is distributed under the Creative Commons Attribution 4.0 License. Classification of iron oxide aerosols by a single particle soot photometer using supervised machine learning Kara D. Lamb1,2 1Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA 2NOAA Earth System Research Laboratory Chemical Sciences Division, Boulder, CO, USA Correspondence: Kara D. Lamb ([email protected]) Received: 15 March 2019 – Discussion started: 22 March 2019 Revised: 20 June 2019 – Accepted: 21 June 2019 – Published: 15 July 2019 Abstract. Single particle soot photometers (SP2) use laser- each class are compared with the true class for those particles induced incandescence to detect aerosols on a single particle to estimate generalization performance. While the specific basis. SP2s that have been modified to provide greater spec- class approach performed well for rBC and Fe3O4 (≥ 99 % tral contrast between their narrow and broad-band incandes- of these aerosols are correctly identified), its classification of cent detectors have previously been used to characterize both other aerosol types is significantly worse (only 47 %–66 % refractory black carbon (rBC) and light-absorbing metallic of other particles are correctly identified). Using the broader aerosols, including iron oxides (FeOx). However, single par- class approach, we find a classification accuracy of 99 % for ticles cannot be unambiguously identified from their incan- FeOx samples measured in the laboratory. The method al- descent peak height (a function of particle mass) and color lows for classification of FeOx as anthropogenic or dust-like ratio (a measure of blackbody temperature) alone. -
LED Retrofit Headlamp Light Sources Ensure Legal Access to the German Automotive Market
LED Retrofit Headlamp Light Sources Ensure legal access to the German automotive market Your challenges Before September 2020, the Kraftfahrt-Bundesamt hazards. Other advantages include: (Federal Motor Transport Authority) did not permit the ■ Near-daylight luminescence for improved visibility replacement of vehicle headlamps with LED retrofit ■ Quicker response time to 100% light light sources for driving beams and passing beams in ■ Highly resistant to vibration and shock Germany, as the appropriate homologation guidelines did ■ Longer lifetime not exist. Consequently, vehicle owners could not modify ■ Higher efficiency (lm/W), fewer CO2 emissions and their old halogen lamps with LEDs and manufacturers more environmentally friendly were unable to sell LED retrofits for vehicles registered on German public roads. Why is retrofitted LED headlamp light source testing and compliance important? The advantages of headlamps equipped with All external light sources on a vehicle, such as headlights or LED retrofit brake lights, are considered “technical lighting equipment” According to a study by the Allgemeiner Deutscher and must be type approved. Any subsequent modifications Automobil-Club (ADAC), retrofitting car headlights with to the type-approved lighting equipment will have an impact LEDs offers a road traffic safety gain. This is because on the type approval of the entire vehicle, and result in the retrofitted LED headlights are more durable, have a longer loss of the operating licence for public roads. beam range and their white light improves contrast. It is therefore essential that any LED updates made to Overall, LEDs have been proven to increase driver safety headlamps are installed correctly, do not disadvantage through improved visibility and earlier detection of road other road users and meet current safety requirements. -
Introduction 1
1 1 Introduction . ex arte calcinati, et illuminato aeri [ . properly calcinated, and illuminated seu solis radiis, seu fl ammae either by sunlight or fl ames, they conceive fulgoribus expositi, lucem inde sine light from themselves without heat; . ] calore concipiunt in sese; . Licetus, 1640 (about the Bologna stone) 1.1 What Is Luminescence? The word luminescence, which comes from the Latin (lumen = light) was fi rst introduced as luminescenz by the physicist and science historian Eilhardt Wiede- mann in 1888, to describe “ all those phenomena of light which are not solely conditioned by the rise in temperature,” as opposed to incandescence. Lumines- cence is often considered as cold light whereas incandescence is hot light. Luminescence is more precisely defi ned as follows: spontaneous emission of radia- tion from an electronically excited species or from a vibrationally excited species not in thermal equilibrium with its environment. 1) The various types of lumines- cence are classifi ed according to the mode of excitation (see Table 1.1 ). Luminescent compounds can be of very different kinds: • Organic compounds : aromatic hydrocarbons (naphthalene, anthracene, phenan- threne, pyrene, perylene, porphyrins, phtalocyanins, etc.) and derivatives, dyes (fl uorescein, rhodamines, coumarins, oxazines), polyenes, diphenylpolyenes, some amino acids (tryptophan, tyrosine, phenylalanine), etc. + 3 + 3 + • Inorganic compounds : uranyl ion (UO 2 ), lanthanide ions (e.g., Eu , Tb ), doped glasses (e.g., with Nd, Mn, Ce, Sn, Cu, Ag), crystals (ZnS, CdS, ZnSe, CdSe, 3 + GaS, GaP, Al 2 O3 /Cr (ruby)), semiconductor nanocrystals (e.g., CdSe), metal clusters, carbon nanotubes and some fullerenes, etc. 1) Braslavsky , S. et al . ( 2007 ) Glossary of terms used in photochemistry , Pure Appl. -
2. Making Fires Burn Or Go out 1: Introduction to the Fire Triangle
2. Making Fires Burn or Go Out 1: Introduction to the Fire Triangle Lesson Overview: In this activity, students describe and organize what they already know Subjects: Science, Mathematics, Writing, about fire so it fits into the conceptual model of Speaking and Listening, Health and the Fire Triangle. They examine the geometric Safety stability of a triangle and how that property Duration: one half-hour session applies to fire. Group size: Whole class. Students work in groups of 2-3. Lesson Goal: Increase students’ understanding of Setting: Indoors how fires burn and why they go out. Vocabulary: Fire Triangle, fuel, heat, ignition, oxygen, model Objectives: • Students can construct a triangle out of toothpicks and gumdrops, and can label its legs with the three components of the Fire Triangle. • Students can demonstrate that removing one side of the triangle makes it collapse. • Students can identify the component(s) of the Fire Triangle that are removed in various scenarios, and explain how this makes the fire go out. Standards: 1st 2nd 3rd 4th 5th CCSS Writing 2, 7, 8 2, 7, 8 2, 7, 10 2,7, 9, 10 2,7, 9, 10 Speaking/Listening 1, 2, 4, 6 1, 2, 4, 6 1, 2, 4, 6 1, 2, 4, 6 1, 2, 4, 6 1, 2, 3, 4, Language 1, 2, 4, 6 1, 2, 4, 6 6 1, 2, 3, 4, 6 1, 2, 3, 4, 6 MP.4, MP.4, MP.4, MP.4, Math MP.5 MP.5, MP.5 MP.5 MP.4, MP.5 Matter and Its PS1.A, NGSS Interactions PS1.B PS1.B From Molecules to Organisms: Structure/Processes LS1.C Engineering Design ETS1.B ETS1.B EEEGL Strand 1 A, B, C, E, F, G A, B, C, E, F, G Teacher Background: This activity explores the chemistry of combustion as described by a conceptual model called the Fire Triangle. -
Energy Efficiency Lighting Hearing Committee On
S. HRG. 110–195 ENERGY EFFICIENCY LIGHTING HEARING BEFORE THE COMMITTEE ON ENERGY AND NATURAL RESOURCES UNITED STATES SENATE ONE HUNDRED TENTH CONGRESS FIRST SESSION TO RECEIVE TESTIMONY ON THE STATUS OF ENERGY EFFICIENT LIGHT- ING TECHNOLOGIES AND ON S. 2017, THE ENERGY EFFICIENT LIGHT- ING FOR A BRIGHTER TOMORROW ACT SEPTEMBER 12, 2007 ( Printed for the use of the Committee on Energy and Natural Resources U.S. GOVERNMENT PRINTING OFFICE 39–385 PDF WASHINGTON : 2007 For sale by the Superintendent of Documents, U.S. Government Printing Office Internet: bookstore.gpo.gov Phone: toll free (866) 512–1800; DC area (202) 512–1800 Fax: (202) 512–2104 Mail: Stop IDCC, Washington, DC 20402–0001 VerDate 0ct 09 2002 11:58 Feb 20, 2008 Jkt 040443 PO 00000 Frm 00001 Fmt 5011 Sfmt 5011 G:\DOCS\39385.XXX SENERGY2 PsN: MONICA COMMITTEE ON ENERGY AND NATURAL RESOURCES JEFF BINGAMAN, New Mexico, Chairman DANIEL K. AKAKA, Hawaii PETE V. DOMENICI, New Mexico BYRON L. DORGAN, North Dakota LARRY E. CRAIG, Idaho RON WYDEN, Oregon LISA MURKOWSKI, Alaska TIM JOHNSON, South Dakota RICHARD BURR, North Carolina MARY L. LANDRIEU, Louisiana JIM DEMINT, South Carolina MARIA CANTWELL, Washington BOB CORKER, Tennessee KEN SALAZAR, Colorado JOHN BARRASSO, Wyoming ROBERT MENENDEZ, New Jersey JEFF SESSIONS, Alabama BLANCHE L. LINCOLN, Arkansas GORDON H. SMITH, Oregon BERNARD SANDERS, Vermont JIM BUNNING, Kentucky JON TESTER, Montana MEL MARTINEZ, Florida ROBERT M. SIMON, Staff Director SAM E. FOWLER, Chief Counsel FRANK MACCHIAROLA, Republican Staff Director JUDITH K. PENSABENE, Republican Chief Counsel (II) VerDate 0ct 09 2002 11:58 Feb 20, 2008 Jkt 040443 PO 00000 Frm 00002 Fmt 5904 Sfmt 5904 G:\DOCS\39385.XXX SENERGY2 PsN: MONICA C O N T E N T S STATEMENTS Page Bingaman, Hon. -
Comparison of Colorimetric, Fluorescence and Luminescence Analysis
www.aladdin-e.com Comparison of colorimetric, fluorescence and luminescence analysis Introduction 25°C, and 37°C, Over the years, the enzyme immunoassay that greater than six months shelf life when stored Engvall and Perlmann first described has taken at 4°C, many different forms. Today there are commercially available, heterogeneous, homogeneous, cell-based, capable of being conjugated to an antigen or colorimetric, fluorescent and luminescent, to antibody, name just a few, versions of the original ELISA. inexpensive, They all have antibody-antigen complexes and easily measurable activity, enzyme reactions in common. In this technical high substrate turnover number, bulletin, we here will focus on the enzyme linked unaffected by biological components of the immunosorbent assay and discuss three types of assay. detection systems — colorimetric, fluorescent, and luminescent. By far, the two most popular enzymes are All ELISA, regardless of the detection system peroxidase and alkaline phosphatase. Each has employed, require the immobilization of an their advantages and disadvantages. Both are antigen or antibody to a surface. They also quite stable when handled and stored properly, require the use of an appropriate enzyme label and both can be stored at 4°C for greater than 6 and a matching substrate that is suitable for the months. Both are also commercially available as detection system being used. Associated with the free enzymes and as enzyme conjugates (enzyme enzyme-substrate reaction are several labeled antibodies, etc.) and are relatively requirements, such as timing and development inexpensive. However, there are some differences conditions, that need to be optimized to result in between these two enzymes that should be a precise, accurate and reproducible assay. -
Biofluorescence
Things That Glow In The Dark Classroom Activities That Explore Spectra and Fluorescence Linda Shore [email protected] “Hot Topics: Research Revelations from the Biotech Revolution” Saturday, April 19, 2008 Caltech-Exploratorium Learning Lab (CELL) Workshop Special Guest: Dr. Rusty Lansford, Senior Scientist and Instructor, Caltech Contents Exploring Spectra – Using a spectrascope to examine many different kinds of common continuous, emission, and absorption spectra. Luminescence – A complete description of many different examples of luminescence in the natural and engineered world. Exploratorium Teacher Institute Page 1 © 2008 Exploratorium, all rights reserved Exploring Spectra (by Paul Doherty and Linda Shore) Using a spectrometer The project Star spectrometer can be used to look at the spectra of many different sources. It is available from Learning Technologies, for under $20. Learning Technologies, Inc., 59 Walden St., Cambridge, MA 02140 You can also build your own spectroscope. http://www.exo.net/~pauld/activities/CDspectrometer/cdspectrometer.html Incandescent light An incandescent light has a continuous spectrum with all visible colors present. There are no bright lines and no dark lines in the spectrum. This is one of the most important spectra, a blackbody spectrum emitted by a hot object. The blackbody spectrum is a function of temperature, cooler objects emit redder light, hotter objects white or even bluish light. Fluorescent light The spectrum of a fluorescent light has bright lines and a continuous spectrum. The bright lines come from mercury gas inside the tube while the continuous spectrum comes from the phosphor coating lining the interior of the tube. Exploratorium Teacher Institute Page 2 © 2008 Exploratorium, all rights reserved CLF Light There is a new kind of fluorescent called a CFL (compact fluorescent lamp). -
Request to Renew Exemption 1(A)
Request to renew Exemption 1(a) under the RoHS Directive 2011/65/EU Mercury in single-capped (compact) fluorescent lamps below 30 W Date: January 15, 2015 LIGHTINGEUROPE Contents Contents ................................................................................................................... 2 1 Name and contact details ................................................................................. 4 2 Reason for application ...................................................................................... 4 3 Summary of the exemption request .................................................................. 4 4 Technical description of the exemption request ................................................ 7 4.1 Description of the lamps and their applications .................................................. 7 4.1.1 Lamps covered by this exemption .................................................................. 7 4.1.2 Applications covered by this exemption .......................................................... 8 4.1.3 Annex I category covered by this exemption ................................................ 10 4.2 Description of the substance ............................................................................ 11 4.2.1 Substance covered by this exemption .......................................................... 11 4.2.2 Function of mercury in lamps ....................................................................... 11 4.2.3 Location of mercury in lamps....................................................................... -
Exterior Lighting Guide for Federal Agencies
EXTERIOR LIGHTING GUIDE FOR FederAL AgenCieS SPONSORS TABLE OF CONTENTS The U.S. Department of Energy, the Federal Energy Management Program, page 02 INTRODUctiON page 44 EMERGING TECHNOLOGIES Lawrence Berkeley National Laboratory (LBNL), and the California Lighting Plasma Lighting page 04 REASONS FOR OUTDOOR Technology Center (CLTC) at the University of California, Davis helped fund and Networked Lighting LiGHtiNG RETROFitS create the Exterior Lighting Guide for Federal Agencies. Photovoltaic (PV) Lighting & Systems Energy Savings LBNL conducts extensive scientific research that impacts the national economy at Lowered Maintenance Costs page 48 EXTERIOR LiGHtiNG RETROFit & $1.6 billion a year. The Lab has created 12,000 jobs nationally and saved billions of Improved Visual Environment DESIGN BEST PRActicES dollars with its energy-efficient technologies. Appropriate Safety Measures New Lighting System Design Reduced Lighting Pollution & Light Trespass Lighting System Retrofit CLTC is a research, development, and demonstration facility whose mission is Lighting Design & Retrofit Elements page 14 EVALUAtiNG THE CURRENT to stimulate, facilitate, and accelerate the development and commercialization of Structure Lighting LIGHtiNG SYSTEM energy-efficient lighting and daylighting technologies. This is accomplished through Softscape Lighting Lighting Evaluation Basics technology development and demonstrations, as well as offering outreach and Hardscape Lighting Conducting a Lighting Audit education activities in partnership with utilities, lighting -
Basic Physics of the Incandescent Lamp (Lightbulb) Dan Macisaac, Gary Kanner,Andgraydon Anderson
Basic Physics of the Incandescent Lamp (Lightbulb) Dan MacIsaac, Gary Kanner,andGraydon Anderson ntil a little over a century ago, artifi- transferred to electronic excitations within the Ucial lighting was based on the emis- solid. The excited states are relieved by pho- sion of radiation brought about by burning tonic emission. When enough of the radiation fossil fuels—vegetable and animal oils, emitted is in the visible spectrum so that we waxes, and fats, with a wick to control the rate can see an object by its own visible light, we of burning. Light from coal gas and natural say it is incandescing. In a solid, there is a gas was a major development, along with the near-continuum of electron energy levels, realization that the higher the temperature of resulting in a continuous non-discrete spec- the material being burned, the whiter the color trum of radiation. and the greater the light output. But the inven- To emit visible light, a solid must be heat- tion of the incandescent electric lamp in the ed red hot to over 850 K. Compare this with Dan MacIsaac is an 1870s was quite unlike anything that had hap- the 6600 K average temperature of the Sun’s Assistant Professor of pened before. Modern lighting comes almost photosphere, which defines the color mixture Physics and Astronomy at entirely from electric light sources. In the of sunlight and the visible spectrum for our Northern Arizona University. United States, about a quarter of electrical eyes. It is currently impossible to match the He received B.Sc. -
Tips for Improved Luminescence Performance Getting the Most of out of Your Biotek Reader
Tips for Improved Luminescence Performance Getting the Most of Out of Your BioTek Reader In order to achieve the best possible luminescence results from your BioTek microplate reader, several different parameters must be addressed. While there are an infinite number of possible combinations, addressing just a few key issues will greatly increase the likelihood of experimental success. In this technical note, we describe some of those issues and parameters. Introduction BioTek offers two reader series capable of measuring fluorescence: the Synergy HT and the FLx800. Depending on the model and type the end user will be able to perform various luminescent reactions. For example, only those readers configured with injectors have the capability to perform flash luminescence assays, while virtually all the luminescent capable readers can perform glow assays. Listed below are several different parameters, which may or may not apply to any one specific reader. Getting Started Plate Type: The type of plate used does matter. Opaque white plates have been shown to provide the best performance for luminescence assays, as they maximize the signal. Other plates can be used, such as white sided with clear bottom if necessary. Solid black plates will also work, but the signal will be significantly reduced. Quality plates should not allow any light leakage through the walls of the microplate. Filter Wheel Settings: In order to prevent any stray light from entering the optical path, an opaque plug is located in the excitation wheel in lieu of an excitation filter. Generally an open aperture on the emission filter wheel is used when performing luminescence measurements. -
Electroluminescence Vs. Photoluminescence
Electroluminescence vs. Photoluminescence This application note presents a brief comparison in characterization of light-emitting material such as GaN using electroluminescence and photoluminescence. In photoluminescence (PL), excess carriers (electrons and holes) are photo-excited by exposure to a sufficiently intense light source, and the luminescence emitted from the radiative recombination of these photo-excited carriers. PL mapping combines conventional PL with a scanning stage. Both the intensity and the peak wavelength uniformity across the whole wafer can thus be acquired and used for evaluation. Electroluminescence (EL) is similar to photoluminescence, except that in electroluminescence the excess carriers are produced by current injection and it is usually measured on finished device. The photoluminescence is mainly determined by the optical properties of the material, while the electroluminescence is determined by a number of factors such as the optical properties and physical structures of the optically active layers, the electrical properties of two conductive regions which are used for cathode and anode contacts, and the properties of the electrical contacts through which the electrical current injected. It is well known that photoluminescence is not equivalent to electroluminescence. High photo-luminescence efficiency is necessary but not sufficient for good light-emitting materials or wafers. A wafer with high photoluminescence efficiency may or may not exhibit high electroluminescence efficiency and hence good light emitting diodes (LEDs). The different emission mechanism between PL and EL could also result in huge emission wavelength/intensity change. It has been reported that, at least in green LED, top contact layer could change the MQW PL emissions dramatically, and EL spectra from the fabricated devices were very different from the MQW PL measurements.