New Mineral Names*
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American Mineralogist, Volume 90, pages 768–773, 2005 New Mineral Names* PAULA C. PIILONEN,1,† T. SCOTT ERCIT,1,‡ AND ANDREW C. ROBERTS2 1Research Division, Canadian Museum of Nature, P.O. Box 3443, Stn. D, Ottawa, Ontario K1P 6P4, Canada 2Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario K1A 0E8, Canada ANKINOVICHITE 17.8098(8), b = 5.1228(2), c = 8.8665(4) Å, β = 92.141(1)°, V 3 3 3 Karpenko, V.Yu., Pautov, L.A., Sokolova, E.V., Hawthorne, F.G., = 808.4(2) Å , Z = 2, Dobs = 2.48(2) g/cm , Dcalc = 2.476 g/cm . Agakhanov, A.A., Dikaya, T.V., Bekenova, G.K. (2004) Anki- The strongest lines on the powder X-ray diffraction pattern (FeKα radiation, 34 lines) are 8.89(100,200), 7.83(100,101), novichite, the nickel analogue of alvanite, a new mineral from – 5.01(30,301), 4.91(20,110), 3.354(40,012), 3.266(50,501), Kurumsak (Kazakhstan) and Kara-Chagyr (Krygyzstan). Za- – – 2.944(30, 312), 2.631(20,412), 2.463(20,701,220), 2.378(30, piski Vseross. Mineral. Obshch. 133(2), 59–70 (in Russian, – – – 313,221), 2.323(30,313), 1.970(80,613,422), 1.935(20,023), English abstract). – 1.904(70,621), 1.680(40,820), 1.605(50,623), 1.539(30,804,332). Ankinovichite is described from two localities—Kurumsak, The mineral is isostructural with alvanite and is its Ni analogue. Chminken Oblysy, Kazakhstan, and Mount Kara-Chagyr, Osh The high R1 value is thought to be due to twinning, although Oblast, Krygyzstan). The material from Kurumsak occurs as the reÞ ned site occupancies match well with those obtained by crusts of prismatic, pale green, elongate crystals up to 0.5 electron microprobe analyses. Ankinovichite is only the second mm. The material from Mount Kara-Chagyr occurs as green mineral known to have chains of V tetrahedra. to light blue, tabular, commonly elongate crystals 0.05 to 0.2 Ankinovichite was found in the vanadium-bearing schists mm in length. The crystals often occur in aggregates, and are of the Kara-Tau range, south Kazakhstan. It is a low-tempera- commonly twinned. Ankinovichite is brittle, with perfect (010) ture hydrothermal or supergene mineral, forming after earlier cleavage, Mohs hardness 2.5 to 3, microindentation hardness sphalerite, tetrahedrite, sulvanite, patronite, and breithauptite. VHN 68 kg/mm2. The mineral is transparent and vitreous. At Kurumsak, ankinovichite was found in a dump at a bore pit Electron microprobe analyses (Kara-Chagyr/Kurumsak) gave within a middle Cambrian schist rich in carbonaceous material and clay and interbedded with dolomites. It is associated with Al2O3 33.82/33.79, SiO2 0.59/0.67, V2O5 28.41/27.98, FeO volborthite, carnotite, goethite and an unknown dark orange V 0.14/0.35, NiO 8.43/7.19, CuO 0.27/0.20, ZnO 2.24/4.20, H2O 23.30 (PenÞ eld method)/25.65(by difference), sum 97.20/100.00 oxide. Ankinovichite at Kara-Chagyra (Isfayramsay River, Osh Oblastʼ) occurs in fractures and as a cement in schist fragments wt%, corresponding to (Ni0.68Zn0.17Cu0.02Fe0.01)Σ0.88Al4(VO3)1.88Si0.06 (early Paleozoic) found within a serpentinite matrix, part of (OH)12.12(H2O)2.67 for material from Kara-Chagyr and (Ni0.58Zn0.31 the early Carboniferous Fergana complex. It is associated with Cu0.02Fe0.03)Σ0.94Al4(VO3)1.85Si0.06(OH)12.27(H2O)2.46 for material allophone, kolovratite, volborthite, nickelalumite, metatyuy- from Kurumsak. The simpliÞ ed general formula is (Ni,Zn)Al4 amunite, roscoelite and tangeite. Ankinovichite was named for (VO3)2(OH)12·2H2O based on 4 Al atoms pfu. The IR spectrum of ankinovichite contains bands at 3570, 3460, and 3175, 1735, Ekaterina Aleksandrovna Ankinovich (1911–1991) and Stepane and 1620 cm–1, as well as less intense bands in the range from Gerasimoviche Ankinovich (1912–1985), a well-known miner- 1025 to 465 cm–1. Neither a discussion of the IR spectrum nor alogist and geologist, respectively. The type material has been identiÞ cation of the absorption bands is given. It is biaxial nega- deposited at the A.E. Fersman Mineralogical Museum, Russian Academy of Science, Moscow, Russia (catalogue no. 6798). tive, α = 1.653(2) β = 1.677(2), γ = 1.706(3), 2Vobs-86(2)°, 2Vcalc- 86°. Ankinovichite has parallel extinction, positive elongation, is P.C.P./T.S.E. non-pleochroic and non-ß uorescent under UV radiation. Discussion. The authors state that they succeeded in locat- The crystal structure of ankinovichite was reÞ ned on a 0.06 ing two hydrogen atoms of the H2O group although this seems × 0.004 × 0.006 mm crystal by single-crystal X-ray diffraction unlikely given the poor quality of the Þ nal reÞ nement. methods, R1 = 0.128 for 1143 reß ections with I > 4σ(I). Start- ing parameters were taken from alvanite (Dunn et al. 1990; BARI-OLGITE* Mineral. Mag. 54, 609–611; Pertlik et al. 1990; Neues Jahrb. Mineral. Mh. 385–392). The mineral is monoclinic, P21/n, a = Pekov, I.V., Chukanov, N.V., Kulikova, I.M., Zubkova, N.V., Krotova, O.D., Sorokina, N.I., Pushcharovsky, D.S. (2004) A new mineral, bari-olgite Ba(Na,Sr,REE)2Na[PO4]2, and its crystal structure. Zapiski Vseross. Mineral. Obshch. 133(1), * Before publication, minerals marked with an asterisk were approved by the Commission on New Minerals and Mineral 41–49 (in Russian, English abstract). Names, International Mineralogical Association. † E-mail: [email protected] Bari-olgite occurs as irregular, isometric or ß attened crys- ‡ English translations of the articles are available upon request tals, sometimes with a hexagonal outline, up to 1.5 × 1.0 cm. (E-mail: [email protected]) The crystals are transparent, light green, with a white streak 0003-004X/05/0004–768$05.00/DOI: 10.2138/am.2005.432 768 PIILONEN ET AL.: NEW MINERAL NAMES 769 and a vitreous luster. The dominat forms are trigonal prisms accurate than the WDS results, based on similar results for bast- – – – [{100}, {100}] and trigonal pyramids [{101}, {101}, {101}, nåsite analyzed under the same conditions. A proposed general – – 3+ 4+ and {101}]. They often resemble quartz crystals. It ß uoresces formula for the natural mineral is La(1-y)[Ce (y-x)Ce x]O(1+x)F(1-x). bright pink-orange in short-wave and weak pink-red in long-wave The density could not be determined but was calculated to be 6.5 2 UV radiation. Bari-olgite is brittle, has uneven fracture, a Mohs g/cm . The mineral is expected to be isotropic, ncalc ≈ 1.9. A single hardness of 4 to 4.5, and imperfect (00l) and (hk0) cleavage. crystal structure determination was not possible and therefore Electron microprobe analyses gave Na2O 14.78, K2O 0.87, CaO the Rietveld method was employed. The strongest lines on the 0.32, SrO 16.57, BaO 31.17, MnO 0.39, La2O3 2.41, Ce2O3 1.90, X-ray diffraction pattern [Guinier-Hägg camera, (40.16 mm, d- Pr2O3 0.10, Nd2O3 0.16, SiO2 0.08, P2O5 31.77, sum 100.52 wt%, spacings), diffractometer (intensities), CuKα, 17 lines given] are corresponding to (Na2.14K0.08Ca0.03Mn0.02Sr0.72Ba0.91La0.07Ce0.05)Σ4.02 3.252(100,111), 2.815(31,200), 1.991(61,220), 1.6969(46,311), P2.01O8 based on 8 oxygen atoms pfu. The simpliÞ ed general 1.2916(331), 1.1486(12,422). A Rietveld reÞ nement of the pow- 2 formula is Ba(Na,Sr,REE)2Na[PO4]2. The IR spectrum of bari- der X-ray diffraction data was performed (RF = 0.051, χ = 0.86, olgite is simple, containing only three absorption bands in the 12 reÞ ned parameters). Results indicate håleniusite-(La) to be region 400–1200 cm–1: 1035, 946, and 563 cm–1. The mineral cubic, Fm3m, a = 5.6282(5) Å, V = 178.28(5) Å3, and Z = 4. The is uniaxial negative, ε = 1.623(3), ω = 1.628(2). It is colorless mineral is isostructural with ß uorite. and non-pleochroic. Håleniusite-(La) was found on the dumps of the Bastnäs The crystal structure of the mineral was reÞ ned by single-crystal Cu-REE mines in Våstmanland, Sweden. It is associated with X-ray diffraction methods, R1 = 0.038 for 601 reß ections with I bastnåsite-(Ce), brochanite, ferriallanite-(Ce), and quartz. Ad- > 4σ(I). The mineral is trigonal, P3, a = 5.541(2), c = 7.020(3) ditional minerals in the dumps include cerite-(Ce), molybdenite, 3 3 3 Å, V = 186.6 Å , Z = 1, Dobs = 3.986 g/cm , Dcalc = 4.000 g/cm , µ and an amphibole. The mineral is a secondary alteration product = 9.995 mm–1. Starting parameters for the reÞ nement were taken of bastnåsite-(La) via a decarbonation reaction. The name of the from those of olgite (Sokolova et al. 1990; Vestnik MGU Ser.4, mineral is for Ulf Hålenius, Professor of Mineralogy, Swedish Geologiya, 1, 87–91). The strongest lines of the powder X-ray dif- Museum of Natural History. The type material has been deposited fraction pattern (diffractometer, CoKα, 25 lines) are 7.044(22,001), at the Swedish Museum of Natural History, Stockholm, Sweden 3.964(60,101,011), 2.839(100,012), 2.774(100,110), 2.344(20,003), (catalogue no. 20030025). – 2.272(19,021), 1.984(40,202), 1.611(26,212,122), 1.387(19,220).