IMA–CNMNC Approved Mineral Symbols
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An Application of Near-Infrared and Mid-Infrared Spectroscopy to the Study of 3 Selected Tellurite Minerals: Xocomecatlite, Tlapallite and Rodalquilarite 4 5 Ray L
QUT Digital Repository: http://eprints.qut.edu.au/ Frost, Ray L. and Keeffe, Eloise C. and Reddy, B. Jagannadha (2009) An application of near-infrared and mid- infrared spectroscopy to the study of selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite. Transition Metal Chemistry, 34(1). pp. 23-32. © Copyright 2009 Springer 1 2 An application of near-infrared and mid-infrared spectroscopy to the study of 3 selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite 4 5 Ray L. Frost, • B. Jagannadha Reddy, Eloise C. Keeffe 6 7 Inorganic Materials Research Program, School of Physical and Chemical Sciences, 8 Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, 9 Australia. 10 11 Abstract 12 Near-infrared and mid-infrared spectra of three tellurite minerals have been 13 investigated. The structure and spectral properties of two copper bearing 14 xocomecatlite and tlapallite are compared with an iron bearing rodalquilarite mineral. 15 Two prominent bands observed at 9855 and 9015 cm-1 are 16 2 2 2 2 2+ 17 assigned to B1g → B2g and B1g → A1g transitions of Cu ion in xocomecatlite. 18 19 The cause of spectral distortion is the result of many cations of Ca, Pb, Cu and Zn the 20 in tlapallite mineral structure. Rodalquilarite is characterised by ferric ion absorption 21 in the range 12300-8800 cm-1. 22 Three water vibrational overtones are observed in xocomecatlite at 7140, 7075 23 and 6935 cm-1 where as in tlapallite bands are shifted to low wavenumbers at 7135, 24 7080 and 6830 cm-1. The complexity of rodalquilarite spectrum increases with more 25 number of overlapping bands in the near-infrared. -
LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Dr. Öğr. Üyesi Fatma Tuğçe (Şenberber) Dumanli
DR. ÖĞR. ÜYESİ FATMA TUĞÇE (ŞENBERBER) DUMANLI ÖZGEÇMİŞ VE ESERLER LİSTESİ ÖZGEÇMİŞ 1. Adı Soyadı : FATMA TUĞÇE (ŞENBERBER) DUMANLI İletişim Bilgileri Adres : Cevizlik Mah. Kırmızı Şebboy Sok. Ebru Ap. A Blok 11/14 Bakırköy- İSTANBUL Telefon : 0554 3021265 Mail : [email protected] 2. Doğum Tarihi : 10/03/1988 3. Unvanı: DOKTOR ÖĞRETİM ÜYESİ 4. Öğrenim Durumu: Derece Alan Üniversite Yıl Lisans Kimya Mühendisliği ABD YTU, Fen Bilimleri Enstitüsü 2006-2010 Y. Lisans Kimya Mühendisliği ABD YTU, Fen Bilimleri Enstitüsü 2010-2012 Doktora Kimya Mühendisliği ABD YTU, Fen Bilimleri Enstitüsü 2012-2016 Yüksek Lisans Tez Başlığı ve Tez Danışmanı: “Magnezyum Oksit ve Borik Asit Kaynaklarından Magnezyum Boratların Üretimi, Karakterizasyonu ve Üretimi Etkileyen Faktörlerin İncelenmesi” YTÜ Fen Bilimleri Enstitüsü, Kimya Mühendisliği Anabilim Dalı, 2012. Tez Danışmanı: Yrd.Doç. Dr. Emek Möröydor Derun Doktora Tez Başlığı ve Tez Danışmanı: “Elektrik İletkenliğe Sahip Yeni Nesil Boyanın Isıl İletkenlik Özelliklerinin Belirlenmesi” YTÜ Fen Bilimleri Enstitüsü, Kimya Mühendisliği Anabilim Dalı, 2016. Tez Danışmanı: Prof. Dr. Sabriye Pişkin 1 5. Akademik Unvanlar Akademik Görev Görev Ünvanı Görev Yeri Yıl Dr.Öğr.Üyesi Nişantaşı Üniversitesi, Mühendislik ve Mimarlık Fakültesi, 2018-… İnşaat Mühendisliği Bölümü Öğr. Gör. Dr. Ataşehir Adıgüzel Meslek Yüksekokulu, İş Sağlığı ve 2016-2018 Güvenliği Programı 6. Yayınlar 6.1. Uluslararası hakemli dergilerde yayımlanan makaleler: 6.1.1. SCI/SCI-exp 1. Senberber, F.T., Kipcak, A.S., Vardar, D.S., Tugrul, N. (2020). Ultrasonic-Assisted Synthesis of Zinc Borates: Effect of Boron Sources, Journal of Chemical Society of Pakistan, Volume 42, Issue 6, pp. 839 – 845. 2. Senberber, F.T., Dere Ozdemir, O. (2020). Effect of Synthesis Parameters on the Color Performance of Blue CoAl2O4 Ceramic Pigment, Russian Journal of Inorganic Chemistry, Volume 65, Issue 14, pp. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Molecular Biogeochemistry, Lecture 8
12.158 Lecture Pigment-derived Biomarkers (1) Colour, structure, distribution and function (2) Biosynthesis (3) Nomenclature (4) Aromatic carotenoids ● Biomarkers for phototrophic sulfur bacteria ● Alternative biological sources (5) Porphyrins and maleimides Many of the figures in this lecture were kindly provided by Jochen Brocks, RSES ANU 1 Carotenoid pigments ● Carotenoids are usually yellow, orange or red coloured pigments lutein β-carotene 17 18 19 2' 2 4 6 8 3 7 9 16 1 5 lycopenelycopene 2 Structural diversity ● More than 600 different natural structures are known, ● They are derived from the C40 carotenoid lycopene by varied hydrogenation, dehydrogenation, cyclization and oxidation reaction 17 18 19 2' 2 4 6 8 3 7 9 16 1 5 lycopene neurosporene α-carotene γ -carotene spirilloxanthin siphonaxanthin canthaxanthin spheroidenone 3 Structural diversity Purple non-sulfur bacteria peridinin 7,8-didehydroastaxanthin okenone fucoxanthin Biological distribution ● Carotenoids are biosynthesized de novo by all phototrophic bacteria, eukaryotes and halophilic archaea ● They are additionally synthesized by a large variety of non-phototrophs ● Vertebrates and invertebrates have to incorporate carotenoids through the diet, but have often the capacity to structurally modifiy them 4 Carotenoid function (1) Accessory pigments in Light Harvesting Complex (LHC) (annual production by marine phytoplancton alone: 4 million tons) e.g. LH-II Red and blue: protein complex Green: chlorophyll Yellow: lycopene (2) Photoprotection (3) photoreceptors for phototropism -
Alamosite Pbsio3 C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Monoclinic
Alamosite PbSiO3 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals ¯brous [010]; as radiating aggregates and balls, to 7.5 cm. k Physical Properties: Cleavage: Perfect on 010 . Hardness = 4.5 D(meas.) = 6.488(3) D(calc.) = [6.30] f g Optical Properties: Transparent to translucent. Color: Colorless to white, cream, or light gray. Luster: Adamantine. Optical Class: Biaxial ({). Orientation: Y = b. Dispersion: r < v; strong, weak inclined. ® = 1.945{1.947 ¯ = 1.955{1.961 ° = 1.959{1.968 2V(meas.) = 65± Cell Data: Space Group: P 2=n: a = 12.247 b = 7.059 c = 11.236 ¯ = 113:12± Z = 12 X-ray Powder Pattern: Tsumeb, Namibia. 3.34 (100), 3.56 (95), 3.53 (75), 2.300 (75), 3.23 (70), 2.987 (70), 3.25 (60) Chemistry: (1) (2) (3) SiO2 21.11 20.01 21.21 Al2O3 0.09 FeO 0.09 0.18 MnO 0.02 PbO 78.13 78.95 78.79 CaO trace 0.09 insol: 0.61 Total 99.94 99.34 100.00 (1) Alamos, Mexico. (2) Tsumeb, Namibia; by electron microprobe. (3) PbSiO3: Occurrence: As a rare secondary mineral in the oxidized zone of lead-bearing base metal deposits. Association: Wulfenite, leadhillite, cerussite (Alamos, Mexico); leadhillite, anglesite, melanotekite, °eischerite, kegelite, hematite (Tsumeb, Namibia); diaboleite, phosgenite, cerussite, wulfenite, willemite (Tiger, Arizona, USA); melanotekite, shattuckite, wickenburgite (Rawhide mine, Arizona, USA). Distribution: From Mexico, in Sonora, at Alamos, and the San Pascual mine, near Zimap¶an, Hidalgo. In the USA, from Arizona, in the Mammoth-St. -
Infrared and Raman Spectroscopic Characterization of the Carbonate Bear- Ing Silicate Mineral Aerinite - Implications for the Molecular Structure
This may be the author’s version of a work that was submitted/accepted for publication in the following source: Frost, Ray, Scholz, Ricardo, & Lopez Toro, Andres (2015) Infrared and Raman spectroscopic characterization of the carbonate bear- ing silicate mineral aerinite - Implications for the molecular structure. Journal of Molecular Structure, 1097, pp. 1-5. This file was downloaded from: https://eprints.qut.edu.au/84503/ c Consult author(s) regarding copyright matters This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the docu- ment is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recog- nise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to [email protected] License: Creative Commons: Attribution-Noncommercial-No Derivative Works 2.5 Notice: Please note that this document may not be the Version of Record (i.e. published version) of the work. Author manuscript versions (as Sub- mitted for peer review or as Accepted for publication after peer review) can be identified by an absence of publisher branding and/or typeset appear- ance. If there is any doubt, please refer to the published source. https://doi.org/10.1016/j.molstruc.2015.05.008 Infrared and Raman spectroscopic characterization of the carbonate bearing silicate mineral aerinite – implications for the molecular structure Ray L. -
Thirty-Fourth List of New Mineral Names
MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given. -
Nabokoite Cu7(Te4+O4)
4+ Nabokoite Cu7(Te O4)(SO4)5 • KCl c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Tetragonal. Point Group: 4/m 2/m 2/m. Crystals are thin tabular on {001}, to 1 mm, showing {001}, {110}, {102}, {014}, in banded intergrowth with atlasovite. Physical Properties: Cleavage: Perfect on {001}. Hardness = 2–2.5 D(meas.) = 4.18(5) D(calc.) = 3.974 Optical Properties: Transparent. Color: Pale yellow-brown, yellow-brown. Streak: Yellow- brown. Luster: Vitreous. Optical Class: Uniaxial (–). ω = 1.778(3) = 1.773(3) Cell Data: Space Group: P 4/ncc. a = 9.833(1) c = 20.591(2) Z = 4 X-ray Powder Pattern: Tolbachik volcano, Russia. 10.35 (10), 2.439 (7), 3.421 (6), 2.881 (5), 4.57 (4), 3.56 (4), 1.972 (4) Chemistry: (1) (2) SO3 33.66 33.60 TeO2 13.78 13.40 V2O3 0.07 Bi2O3 0.49 Fe2O3 0.09 CuO 45.25 46.74 ZnO 1.26 PbO 0.28 K2O 3.94 3.95 Cs2O 0.11 Cl 2.92 2.98 −O=Cl2 0.66 0.67 Total 101.19 100.00 (1) Tolbachik volcano, Russia; by electron microprobe, corresponds to (Cu6.74Zn0.18)Σ=6.92 (Te1.02Bi0.02Pb0.01Fe0.01V0.01)Σ=1.07O4.10(SO4)4.98Cl0.98. (2) KCu7(TeO4)(SO4)5Cl. Polymorphism & Series: Forms a series with atlasovite. Occurrence: A rare sublimate formed in a volcanic fumarole. Association: Atlasovite, chalcocyanite, dolerophanite, chloroxiphite, euchlorine, piypite, atacamite, alarsite, fedotovite, lammerite, klyuchevskite, anglesite, langbeinite, hematite, tenorite. Distribution: From the Tolbachik fissure volcano, Kamchatka Peninsula, Russia. -
Paleomineralogy of the Hadean Eon: What Minerals Were Present at Life’S Origins?
Paleomineralogy of the Hadean Eon: What Minerals Were Present at Life’s Origins? Robert M. Hazen—Geophysical Lab 1st ELSI International Symposium Tokyo Institute of Technology March 30, 2013 CONCLUSIONS As many as 90% of the 4700 known mineral species were not present on Earth prior to the origins of life before ~4.0 billion years ago. Origins-of-life models that rely on minerals for catalysis, selection, concentration, protection, or other processes must employ plausible prebiotic mineral species. List of 420 Mineral Species R. M. Hazen (2013) “Paleomineralogy of the Hadean Eon: A Preliminary List” American Journal of Science, in press. What Is Mineral Evolution? A change over time in: • The diversity of mineral species • The relative abundances of minerals • The compositional ranges of minerals • The grain sizes and morphologies of minerals “Ur”-Mineralogy Pre-solar grains contain about a dozen micro- and nano-mineral phases: • Diamond/Lonsdaleite • Graphite (C) • Moissanite (SiC) • Osbornite (TiN) • Nierite (Si3N4) • Rutile (TiO2) • Corundum (Al O ) 2 3 • Spinel (MgAl2O4) • Hibbonite (CaAl12O19) • Forsterite (Mg2SiO4) • Nano-particles of TiC, ZrC, MoC, FeC, Fe-Ni metal within graphite. • GEMS (silicate glass with embedded metal and sulfide). Mineral Evolution: How did we get from a dozen minerals to >4700 on Earth today? What minerals were not present at the origin of life (~4.0 Ga), and why? Mineral Evolution What Drives Mineral Evolution? Deterministic and stochastic processes that occur on any terrestrial body: 1. The progressive separation and concentration of chemical elements from their original uniform distribution. What Drives Mineral Evolution? Deterministic and stochastic processes that occur on any terrestrial body: 1. -
Articles Devoted to Silicate Minerals from Fumaroles of the Tol- Bachik Volcano (Kamchatka, Russia)
Eur. J. Mineral., 32, 101–119, 2020 https://doi.org/10.5194/ejm-32-101-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 1: Neso-, cyclo-, ino- and phyllosilicates Nadezhda V. Shchipalkina1, Igor V. Pekov1, Natalia N. Koshlyakova1, Sergey N. Britvin2,3, Natalia V. Zubkova1, Dmitry A. Varlamov4, and Eugeny G. Sidorov5 1Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia 2Department of Crystallography, St Petersburg State University, University Embankment 7/9, 199034 St. Petersburg, Russia 3Kola Science Center of Russian Academy of Sciences, Fersman Str. 14, 184200 Apatity, Russia 4Institute of Experimental Mineralogy, Russian Academy of Sciences, Academica Osypyana ul., 4, 142432 Chernogolovka, Russia 5Institute of Volcanology and Seismology, Far Eastern Branch of Russian Academy of Sciences, Piip Boulevard 9, 683006 Petropavlovsk-Kamchatsky, Russia Correspondence: Nadezhda V. Shchipalkina ([email protected]) Received: 19 June 2019 – Accepted: 1 November 2019 – Published: 29 January 2020 Abstract. This is the initial paper in a pair of articles devoted to silicate minerals from fumaroles of the Tol- bachik volcano (Kamchatka, Russia). These papers contain the first systematic data on silicate mineralization of fumarolic genesis. In this article nesosilicates (forsterite, andradite and titanite), cyclosilicate (a Cu,Zn- rich analogue of roedderite), inosilicates (enstatite, clinoenstatite, diopside, aegirine, aegirine-augite, esseneite, “Cu,Mg-pyroxene”, wollastonite, potassic-fluoro-magnesio-arfvedsonite, potassic-fluoro-richterite and litidion- ite) and phyllosilicates (fluorophlogopite, yanzhuminite, “fluoreastonite” and the Sn analogue of dalyite) are characterized with a focus on chemistry, crystal-chemical features and occurrence. -
New Mineral Names*
American Mineralogist, Volume 73, pages 1492-1499. 1988 NEW MINERAL NAMES* JOHN L. JAMBOR CANMET, 555 Booth Street, Ottawa, Ontario KIA OGI, Canada ERNST A. J. BURKE lnstituut voor Aardwetenschappen, Vrije Universitiete, De Boelelaan 1085, 1081 HV, Amsterdam, Netherlands T. SCOTT ERCIT, JOEL D. GRICE National Museum of Natural Sciences, Ottawa, Ontario KIA OM8, Canada Acuminite* prismatic to acicular crystals that are up to 10 mm long and 0.5 H. Pauly, O.Y. Petersen (1987) Acuminite, a new Sr-fluoride mm in diameter, elongate and striated [001], rhombic to hex- from Ivigtut, South Greenland. Neues Jahrb. Mineral. Mon., agonal in cross section, showing {l00} and {l10}. Perfect {100} 502-514. cleavage, conchoidal fracture, vitreous luster, H = 4, Dm'.. = 2.40(5) glcm3 (pycnometer), Dcale= 2.380 glcm3 for the ideal Wet-chemical analysis gave Li 0.0026, Ca 0.0185, Sr 37.04, formula, and Z = 4. Optically biaxial positive, a = 1.5328(4), (3 Al 11.86, F 33.52, OH (calc. from anion deficit) 6.82, H20 (calc. = 1.5340(4), 1.5378(4), 2 Vmoa,= 57(2)°, 2 Vcale= 59°; weak assuming 1 H20 in the formula) 7.80, sum 97.06 wt%, corre- 'Y = dispersion, r < v; Z = b, Y A c = -10°. X-ray structural study sponding to Sro98AIl.o2F.o7(OH)o.93H20. The mineral occurs as indicated monoclinic symmetry, space group C21c, a = 18.830(2), aggregates of crystals shaped like spear points and about I mm b= I 1.517(2), c= 5.190(I)A,{3 = 100.86(1)°. A Guinierpowder long.