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An Application of Near-Infrared and Mid-Infrared Spectroscopy to the Study of 3 Selected Tellurite Minerals: Xocomecatlite, Tlapallite and Rodalquilarite 4 5 Ray L
QUT Digital Repository: http://eprints.qut.edu.au/ Frost, Ray L. and Keeffe, Eloise C. and Reddy, B. Jagannadha (2009) An application of near-infrared and mid- infrared spectroscopy to the study of selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite. Transition Metal Chemistry, 34(1). pp. 23-32. © Copyright 2009 Springer 1 2 An application of near-infrared and mid-infrared spectroscopy to the study of 3 selected tellurite minerals: xocomecatlite, tlapallite and rodalquilarite 4 5 Ray L. Frost, • B. Jagannadha Reddy, Eloise C. Keeffe 6 7 Inorganic Materials Research Program, School of Physical and Chemical Sciences, 8 Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, 9 Australia. 10 11 Abstract 12 Near-infrared and mid-infrared spectra of three tellurite minerals have been 13 investigated. The structure and spectral properties of two copper bearing 14 xocomecatlite and tlapallite are compared with an iron bearing rodalquilarite mineral. 15 Two prominent bands observed at 9855 and 9015 cm-1 are 16 2 2 2 2 2+ 17 assigned to B1g → B2g and B1g → A1g transitions of Cu ion in xocomecatlite. 18 19 The cause of spectral distortion is the result of many cations of Ca, Pb, Cu and Zn the 20 in tlapallite mineral structure. Rodalquilarite is characterised by ferric ion absorption 21 in the range 12300-8800 cm-1. 22 Three water vibrational overtones are observed in xocomecatlite at 7140, 7075 23 and 6935 cm-1 where as in tlapallite bands are shifted to low wavenumbers at 7135, 24 7080 and 6830 cm-1. The complexity of rodalquilarite spectrum increases with more 25 number of overlapping bands in the near-infrared. -
New Mineral Names*,†
American Mineralogist, Volume 104, pages 625–629, 2019 New Mineral Names*,† DMITRIY I. BELAKOVSKIY1 AND FERNANDO CÁMARA2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2Dipartimento di Scienze della Terra “Ardito Desio”, Universitá di degli Studi di Milano, Via Mangiagalli, 34, 20133 Milano, Italy IN THIS ISSUE This New Mineral Names has entries for 8 new minerals, including fengchengite, ferriperbøeite-(Ce), genplesite, heyerdahlite, millsite, saranchinaite, siudaite, vymazalováite and new data on lavinskyite-1M. FENGCHENGITE* X-ray diffraction pattern [d Å (I%; hkl)] are: 7.186 (55; 110), 5.761 (44; 113), 4.187 (53; 123), 3.201 (47; 028), 2.978 (61; 135). 2.857 (100; 044), G. Shen, J. Xu, P. Yao, and G. Li (2017) Fengchengite: A new species with 2.146 (30; 336), 1.771 (36; 24.11). Single-crystal X-ray diffraction data the Na-poor but vacancy-dominante N(5) site in the eudialyte group. shows the mineral is trigonal, space group R3m, a = 14.2467 (6), c = Acta Mineralogica Sinica, 37 (1/2), 140–151. 30.033(2) Å, V = 5279.08 Å3, Z = 3. The structure was solved by direct methods and refined to R = 0.043 for all unique I > 2σ(I) reflections. Fengchengite (IMA 2007-018a), Na Ca (Fe3+,) Zr Si (Si O ) 12 3 6 3 3 25 73 Fenchengite is the Fe3+ analog of eudialyte with a structural difference (H O) (OH) , trigonal, is a new eudialyte-group mineral discovered in 2 3 2 in vacancy dominant N5 site and splitting its Na site N1 into N1a and the agpaitic nepheline syenites and its pegmatite facies near the Saima N1b sites. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Sonoraite Fe3+Te4+O3(OH)•
3+ 4+ Sonoraite Fe Te O3(OH) • H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Bladelike crystals, to 2 mm, flattened on {100}, in subparallel sheaves and rosettes. Physical Properties: Hardness = ∼3 D(meas.) = 3.95(1) D(calc.) = 4.18 Optical Properties: Transparent. Color: Dark yellowish green. Luster: Vitreous. Optical Class: Biaxial (–). α = 2.018(3) β = 2.023(3) γ = 2.025(3) 2V(meas.) = 20◦–25◦ Cell Data: Space Group: P 21/c. a = 10.984(2) b = 10.268(1) c = 7.917(2) β = 108.49(2)◦ Z=8 X-ray Powder Pattern: Moctezuma mine, Mexico. 10.4 (10), 4.66 (8), 3.110 (8), 3.290 (7), 3.66 (6), 5.18 (5), 3.035 (5) Chemistry: (1) (2) TeO2 52.5 59.90 Fe2O3 27.9 29.96 H2O 18.2 10.14 Total 98.6 100.00 • (1) Moctezuma mine, Mexico; H2O taken as loss on ignition. (2) FeTeO3(OH) H2O. Occurrence: A very rare mineral in the oxide zone of a hydrothermal Au–Te ore deposit (Moctezuma mine, Mexico). Association: Emmonsite, anglesite, “limonite”, quartz (Moctezuma mine, Mexico); emmonsite (Mohawk mine, Nevada, USA); rodalquilarite, emmonsite, jarosite, limonite (Tombstone, Arizona, USA). Distribution: From the Moctezuma (Bambolla) mine, 12 km south of Moctezuma, Sonora, Mexico. In the USA, in the Mohawk mine, Goldfield, Esmeralda Co., Nevada; from the Joe shaft, near Tombstone, Cochise Co., Arizona; in the Wilcox district, Catron Co., New Mexico; in Colorado, at the Good Hope mine, Vulcan district, Gunnison Co., and the Hoosier mine, Cripple Creek district, Teller Co. -
Uraninite Alteration in an Oxidizing Environment and Its Relevance to the Disposal of Spent Nuclear Fuel
TECHNICAL REPORT 91-15 Uraninite alteration in an oxidizing environment and its relevance to the disposal of spent nuclear fuel Robert Finch, Rodney Ewing Department of Geology, University of New Mexico December 1990 SVENSK KÄRNBRÄNSLEHANTERING AB SWEDISH NUCLEAR FUEL AND WASTE MANAGEMENT CO BOX 5864 S-102 48 STOCKHOLM TEL 08-665 28 00 TELEX 13108 SKB S TELEFAX 08-661 57 19 original contains color illustrations URANINITE ALTERATION IN AN OXIDIZING ENVIRONMENT AND ITS RELEVANCE TO THE DISPOSAL OF SPENT NUCLEAR FUEL Robert Finch, Rodney Ewing Department of Geology, University of New Mexico December 1990 This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author (s) and do not necessarily coincide with those of the client. Information on SKB technical reports from 1977-1978 (TR 121), 1979 (TR 79-28), 1980 (TR 80-26), 1981 (TR 81-17), 1982 (TR 82-28), 1983 (TR 83-77), 1984 (TR 85-01), 1985 (TR 85-20), 1986 (TR 86-31), 1987 (TR 87-33), 1988 (TR 88-32) and 1989 (TR 89-40) is available through SKB. URANINITE ALTERATION IN AN OXIDIZING ENVIRONMENT AND ITS RELEVANCE TO THE DISPOSAL OF SPENT NUCLEAR FUEL Robert Finch Rodney Ewing Department of Geology University of New Mexico Submitted to Svensk Kämbränslehantering AB (SKB) December 21,1990 ABSTRACT Uraninite is a natural analogue for spent nuclear fuel because of similarities in structure (both are fluorite structure types) and chemistry (both are nominally UOJ. Effective assessment of the long-term behavior of spent fuel in a geologic repository requires a knowledge of the corrosion products produced in that environment. -
Pdf/14/3/387/3420048/387.Pdf by Guest on 30 September 2021 388 TTIE CANADIAN MINERALOGIST
Canadian Mineraloslst Vol. 14, pp. 387-390 (197Q ZEMANNITE,A ZINGTETLURITE FROM MOCTEZUMA, SONORA, MEXICO J. A. MANDARINO Department of Mineralogy and Geology, Royal Ontario Museum, L00 Qaeeds Park, Toronto, Ontario, Canada E. MATZAT Mineraloglsch-krlstallographisches Institut, University of Gdttingen, Gdttlngen, Gennany S. J. WILLIAMS Pera State College, Pera, Nebraska, U,S-4. ABSIRAG"I fesseurJosef Zemann,de I'Universit6 de Vienne, qui a contribu6 tellement i nos connaissancesdes struc- Zemannite occurs as minute hexagonal prisms tures des compos6sde tellure. terminated by a bipyramid. The mineral is light Clraduit par le journal) to dark brown, has an adamantine lustre, and is brittle. It is uniaxial positive: <o-1.85, e:1.93. The density is greater than 4.05 g/cm3, probably about INtnopucficyt* gave 4.36 g/cma. Crystal structure study the fol- Zemannite was first recognized as a possible group P6s/m, a 9.4t!0,42, c 7.64! lowing: space new species by Mandarino & Williams (1961) tellurite 0.024, Z:2. Zemannite is a zeolite-like who referred to it as a zinc tellurite or tellurate. with a negatively charged framework of lZtu Problems involving the determination of the GeOrLl having large (diam. : 8.28A) open chan- nels parallel to [0001]. These channels are statis- chemical formula delayed submission of the tically occupied by Na and H ions and possibly by description to the Commission on New Minerals H:O. Some Fe substitutes f.or 7m, Partial analyses Names, I.M.A. After the structural determina- and the crystal structure analysis indicate the for- tion by Matzat (1967), the description of zeman- mula (Zn,Fe)2(feOs)sNafir-']HzO. -
Utahite, a New Mineral and Associated Copper Tellurates from the Centennial Eureka Mine, Tintic District, Juab County, Utah
UTAHITE, A NEW MINERAL AND ASSOCIATED COPPER TELLURATES FROM THE CENTENNIAL EUREKA MINE, TINTIC DISTRICT, JUAB COUNTY, UTAH Andrew C. Roberts and John A. R. Stirling Geological Survey of Canada 601 Booth Street Ottawa, Ontario, Canada K IA OE8 Alan J. Criddle Martin C. Jensen Elizabeth A. Moffatt Department of Mineralogy 121-2855 Idlewild Drive Canadian Conservation Institute The Natural History Museum Reno, Nevada 89509 1030 Innes Road Cromwell Road Ottawa, Ontario, Canada K IA OM5 London, England SW7 5BD Wendell E. Wilson Mineralogical Record 4631 Paseo Tubutama Tucson, Arizona 85750 ABSTRACT Utahite, idealized as CusZn;(Te6+04JiOH)8·7Hp, is triclinic, fracture. Utahite is vitreous, brittle and nonfluorescent; hardness space-group choices P 1 or P 1, with refined unit-cell parameters (Mohs) 4-5; calculated density 5.33 gtcm' (for empirical formula), from powder data: a = 8.794(4), b = 9996(2), c = 5.660(2);\, a = 5.34 glcm' (for idealized formula). In polished section, utahite is 104.10(2)°, f3 = 90.07(5)°, y= 96.34(3YO, V = 479.4(3) ;\3, a:b:c = slightly bireflectant and nonpleochroic. 1n reflected plane-polar- 0.8798:1 :0.5662, Z = 1. The strongest five reflections in the X-ray ized light in air it is very pale brown, with ubiquitous pale emerald- powder pattern are (dA(f)(hkl)]: 9.638(100)(010); 8.736(50)(100); green internal reflections. The anisotropy is unknown because it is 4.841(100)(020); 2.747(60)(002); 2.600(45)(301, 311). The min- masked by the internal reflections. Averaged electron-microprobe eral is an extremely rare constituent on the dumps of the Centen- analyses yielded CuO = 25.76, ZnO = 15.81, Te03 = 45.47, H20 nial Eureka mine, Tintic district, Juab County, Utah, where it (by difference) {12.96], total = {100.00] weight %, corresponding occurs both as isolated 0.6-mm clusters of tightly bound aggre- to CU49;Zn29lTe6+04)39l0H)79s' 7.1H20, based on 0 = 31. -
Inis: Terminology Charts
IAEA-INIS-13A(Rev.0) XA0400071 INIS: TERMINOLOGY CHARTS agree INTERNATIONAL ATOMIC ENERGY AGENCY, VIENNA, AUGUST 1970 INISs TERMINOLOGY CHARTS TABLE OF CONTENTS FOREWORD ... ......... *.* 1 PREFACE 2 INTRODUCTION ... .... *a ... oo 3 LIST OF SUBJECT FIELDS REPRESENTED BY THE CHARTS ........ 5 GENERAL DESCRIPTOR INDEX ................ 9*999.9o.ooo .... 7 FOREWORD This document is one in a series of publications known as the INIS Reference Series. It is to be used in conjunction with the indexing manual 1) and the thesaurus 2) for the preparation of INIS input by national and regional centrea. The thesaurus and terminology charts in their first edition (Rev.0) were produced as the result of an agreement between the International Atomic Energy Agency (IAEA) and the European Atomic Energy Community (Euratom). Except for minor changesq the terminology and the interrela- tionships btween rms are those of the December 1969 edition of the Euratom Thesaurus 3) In all matters of subject indexing and ontrol, the IAEA followed the recommendations of Euratom for these charts. Credit and responsibility for the present version of these charts must go to Euratom. Suggestions for improvement from all interested parties. particularly those that are contributing to or utilizing the INIS magnetic-tape services are welcomed. These should be addressed to: The Thesaurus Speoialist/INIS Section Division of Scientific and Tohnioal Information International Atomic Energy Agency P.O. Box 590 A-1011 Vienna, Austria International Atomic Energy Agency Division of Sientific and Technical Information INIS Section June 1970 1) IAEA-INIS-12 (INIS: Manual for Indexing) 2) IAEA-INIS-13 (INIS: Thesaurus) 3) EURATOM Thesaurusq, Euratom Nuclear Documentation System. -
An Overview of Minerals Toxicity, by RDG, 2014-2020
AN OVERVIEW OF MINERALS TOXICITY Written by RDG, 2014 Copyright © 2014 - 2020, RDG. All rights reserved. First published electronically November 2014. Last updated December 19, 2020. Disclaimer: This article is not intended as an authoritative text. The author cannot be held responsible for your safety. TABLE OF CONTENTS 1.INTRODUCTION …................................................................................................................. 3 1.1.Why discuss the toxicity of minerals …....................................................................................3 1.2.A few basic notions of toxicology …........................................................................................ 3 1.2.1.Dose …...................................................................................................................................3 1.2.2.Bioavailability …................................................................................................................... 3 1.2.3.Toxicity class, Acute toxicity, and Median lethal dose …......................................................3 1.2.4.Chronic toxicity …................................................................................................................. 4 1.2.5.Carcinogenic, Mutagenic, Reprotoxic …...............................................................................4 1.3.Risk assessment ….................................................................................................................... 4 2.TOXICITY OF MINERALS …............................................................................................... -
New Mineral Names*
AmericanMineralogM, Volume66, pages 1099-l103,IgEI NEW MINERAL NAMES* LouIs J. Cetnt, MrcHeer FtnrscHnn AND ADoLF Pnssr Aldermanlter Choloallte. I. R. Harrowficl4 E. R. Segnitand J. A. Watts (1981)Alderman- S. A. Williams (1981)Choloalite, CuPb(TeO3)z .HrO, a ncw min- ite, a ncw magnesiumalrrminum phosphate.Mineral. Mag.44, eral. Miaeral. Mag. 44, 55-51. 59-62. Choloalite was probably first found in Arabia, then at the Mina Aldermanite o@urs as minute, very thin" talc-likc crystallitcs La Oriental, Moctczuma, Sonora (the typc locality), and finally at with iuellite and other secondaryphosphates in the Moculta rock Tombstone, Arizona. Only thc Tombstone material provides para- phosphatc deposit near thc basc of Lower Cambrisn limestone genetic information. In this material choloalite occurs with cerus- close to Angaston, ca. 60 km NE of Adelaide. Microprobc analy- site, emmonsite and rodalquilarite in severcly brecciated shale that si.q supplcmented by gravimetric water determination gave MgO has been replaced by opal and granular jarosite. Wet chcmical E.4,CaO 1.2, AJ2O328.4, P2O5 25.9, H2O 36.1%,(totat 100),lead- analysisofcholoalitc from the type locality gave CuO 11.0,PbO ing to the formula Mg5Als2(POa)s(OH)zz.zH2O,where n = 32. 33.0,TeO2 50.7, H2O 3.4,total 98.1%,correspolding closcly to thc Thc powder diffraction pattern, taken with a Guinier camera, can formula in the titlc. Powder pattems of thc mineral from thc three be indexed on an orthorhombic. ccll with a = 15.000(7), D = localities can bc indexcd on the basis of a cubic ccll with a : 8.330(6),c - 26.60(l)A, Z = 2,D alc.2.15 from assumedcell con- l2.5l9A for the material from Mina La Oriental, Z: l2,D c,alc. -
JOURNAL the Russell Society
JOURNAL OF The Russell Society Volume 20, 2017 www.russellsoc.org JOURNAL OF THE RUSSELL SOCIETY The journal of British Isles topographical mineralogy EDITOR Dr Malcolm Southwood 7 Campbell Court, Warrandyte, Victoria 3113, Australia. ([email protected]) JOURNAL MANAGER Frank Ince 78 Leconfield Road, Loughborough, Leicestershire, LE11 3SQ. EDITORIAL BOARD R.E. Bevins, Cardiff, U.K. M.T. Price, OUMNH, Oxford, U.K. R.S.W. Braithwaite, Manchester, U.K. M.S. Rumsey, NHM, London, U.K. A. Dyer, Hoddlesden, Darwen, U.K. R.E. Starkey, Bromsgrove, U.K. N.J. Elton, St Austell, U.K. P.A. Williams, Kingswood, Australia. I.R. Plimer, Kensington Gardens, S. Australia. Aims and Scope: The Journal publishes refereed articles by both amateur and professional mineralogists dealing with all aspects of mineralogy relating to the British Isles. Contributions are welcome from both members and non-members of the Russell Society. Notes for contributors can be found at the back of this issue, on the Society website (www.russellsoc.org) or obtained from the Editor or Journal Manager. Subscription rates: The Journal is free to members of the Russell Society. The non-member subscription rates for this volume are: UK £13 (including P&P) and Overseas £15 (including P&P). Enquiries should be made to the Journal Manager at the above address. Back numbers of the Journal may also be ordered through the Journal Manager. The Russell Society: named after the eminent amateur mineralogist Sir Arthur Russell (1878–1964), is a society of amateur and professional mineralogists which encourages the study, recording and conservation of mineralogical sites and material. -
A Review of the Structural Architecture of Tellurium Oxycompounds
Mineralogical Magazine, May 2016, Vol. 80(3), pp. 415–545 REVIEW OPEN ACCESS A review of the structural architecture of tellurium oxycompounds 1 2,* 3 A. G. CHRISTY ,S.J.MILLS AND A. R. KAMPF 1 Research School of Earth Sciences and Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, ACT 2601, Australia 2 Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia 3 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA [Received 24 November 2015; Accepted 23 February 2016; Associate Editor: Mark Welch] ABSTRACT Relative to its extremely low abundance in the Earth’s crust, tellurium is the most mineralogically diverse chemical element, with over 160 mineral species known that contain essential Te, many of them with unique crystal structures. We review the crystal structures of 703 tellurium oxysalts for which good refinements exist, including 55 that are known to occur as minerals. The dataset is restricted to compounds where oxygen is the only ligand that is strongly bound to Te, but most of the Periodic Table is represented in the compounds that are reviewed. The dataset contains 375 structures that contain only Te4+ cations and 302 with only Te6+, with 26 of the compounds containing Te in both valence states. Te6+ was almost exclusively in rather regular octahedral coordination by oxygen ligands, with only two instances each of 4- and 5-coordination. Conversely, the lone-pair cation Te4+ displayed irregular coordination, with a broad range of coordination numbers and bond distances.