The American Mineralogist
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
TRAVERTINE-MARL DEPOSITS of the VALLEY and RIDGE PROVINCE of VIRGINIA - a PRELIMINARY REPORT David A
- Vol. 31 February 1985 No. 1 TRAVERTINE-MARL DEPOSITS OF THE VALLEY AND RIDGE PROVINCE OF VIRGINIA - A PRELIMINARY REPORT David A. Hubbard, Jr.1, William F. Gianninil and Michelle M. Lorah2 The travertine and marl deposits of Virginia's Valley and Ridge province are the result of precipitation of calcium carbonate from fresh water streams and springs. Travertine is white to light yellowish brown and has a massive or concretionary structure. Buildups of this material tend to form cascades or waterfalls along streams (Figure 1). Marl refers to white to dark yellowish brown, loose, earthy deposits of calcium carbonate (Figure 2). Deposits of these carbonate materials are related and have formed during the Quaternary period. This preliminary report is a compilation of some litei-ature and observations of these materials. A depositional model is proposed. These deposits have long been visited by man. Projectile points, pottery fragments, and firepits record the visitation of American Indians to Frederick and Augusta county sites. Thomas Jefferson (1825) wrote an account of the Falling Spring Falls from a visit prior to 1781. Aesthetic and economic considerations eontinue to attract interest in these deposits. 'Virginia Division of Mineral Resources, Charlot- Figure 1. Travertine waterfall and cascade series tesville, VA on Falling Springs Creek, Alleghany County, 2Department of Environmental Sciences, Univer- Virginia. Note man standing in center of left sity of Virginia, Charlottesville, VA margin. 2 VIRGINIA DIVISION OF MINERAL RESOURCES Vol. 31 Figure 2. An extensive marl deposit located in Figure 3. Rimstone dam form resulting from Frederick County, Virginia. Stream, in fore- precipitation of calcium carbonate in Mill Creek, ground, has incised and drained the deposit. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Cafetite, Ca[Ti2o5](H2O): Crystal Structure and Revision of Chemical Formula
American Mineralogist, Volume 88, pages 424–429, 2003 Cafetite, Ca[Ti2O5](H2O): Crystal structure and revision of chemical formula SERGEY V. K RIVOVICHEV,1,* VICTOR N. YAKOVENCHUK,2 PETER C. BURNS,3 YAKOV A. PAKHOMOVSKY,2 AND YURY P. MENSHIKOV2 1Department of Crystallography, St. Petersburg State University, University Embankment 7/9, St. Petersburg 199034, Russia 2Geological Institute, Kola Science Centre, Russian Academy of Sciences, Fersmana 14, 184200-RU Apatity, Russia 3Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, Indiana 46556-0767, U.S.A. ABSTRACT The crystal structure of cafetite, ideally Ca[Ti2O5](H2O), (monoclinic, P21/n, a = 4.9436(15), b = 12.109(4), c = 15.911(5) Å, b = 98.937(5)∞, V = 940.9(5) Å3, Z = 8) has been solved by direct methods and refined to R1 = 0.057 using X-ray diffraction data collected from a crystal pseudo-merohedrally twinned on (001). There are four symmetrically independent Ti cations; each is octahedrally coordi- nated by six O atoms. The coordination polyhedra around the Ti cations are strongly distorted with individual Ti-O bond lengths ranging from 1.743 to 2.223 Å (the average <Ti-O> bond length is 1.98 Å). Two symmetrically independent Ca cations are coordinated by six and eight anions for Ca1 and Ca2, respectively. The structure is based on [Ti2O5] sheets of TiO6 octahedra parallel to (001). The Ca atoms and H2O groups are located between the sheets and link them into a three-dimensional struc- ture. The structural formula of cafetite confirmed by electron microprobe analysis is Ca[Ti2O5](H2O), . -
The Picking Table Volume 27, No. 1 – Spring 1986
TABLE JOURNAL of the FRANKLIN-OGDENSBURG MINERALOGICAL SOCIETY, INC. SPRING. 1986 VOLUME 27, NO.l The contents of The Picking Table are licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. F.QM.S. Notes prise a spectacular fluorescent display. For PRESIDENT'S MESSAGE years the Gerstmann Mineral Museum has displayed the collection for the delight and With the melting of the snow, the rocks of education of amateur and professional mineralo- the Buckwheat Dump emerge from their white gists alike. The Franklin Mineral Museum mantle, and the seismic tremors rumble through is most grateful to Arthur and Harriet Mitteldorf the souls of the collector community. Whatever for this most generous donation and to Ewald Spring may mean to the average mortal, to Gerstmann for its accumulation and for his FOMS members it brings a special appeal to sponsorship of the Franklin Mineral Museum dig in the dirt, not to plant, but to explore as the recipient. Transfer of the collection again the crystalline mysteries of Nature. will be effected as soon as suitable space is available to house it. Let us not lose sight of the fact that we are a community, however widespread, dedicated JLB to a great common interest and purpose: the expansion and preservation of knowledge about the world's most remarkable mineral location. ABOUT THE COVER SKETCH Like all great enterprises, this demands the efforts and participation of many. To the Located Sphalerite Occurrences—Franklin Mine extent that we share our knowledge, our time, and our interest with each other and the world, It is suggested that you refer to this hand Franklin lives. -
MINERALS and MINERAL VARIETIES from METAMORPHOSED Mn DEPOSITS of BISTRITA MOUNTAINS, ROMANIA
Acta Mineralogica-Petrographica, Abstract Series 1, Szeged, 2003 MINERALS AND MINERAL VARIETIES FROM METAMORPHOSED Mn DEPOSITS OF BISTRITA MOUNTAINS, ROMANIA HÎRTOPANU, P.1 & SCOTT, P.2 1 Geological Institute of Romania, Caransebeş 1, RO-78344 Bucharest, Romania. E-mail: [email protected] 2 Camborne School of Mines, Redruth, Cornwall, United Kingdom. The Bistrita Mountains belong to the Crystalline Meso- mation of some amphiboles and some pyroxenes into other zoic Zone of the East Carpathians, which consists of super- phases, there are drastical transformations of pyroxenes into posed Variscan and Alpine Nappes, overthrusted eastwards pyroxenoids (johannsenite into rhodonite), pyroxenoids into over the Flysch Zone. The manganese ore is contained by pyroxenoids (pyroxmangite into rhodonite), pyroxmangite Tulghes Group (Tg2 level) of the Variscan Putna Nappe, into manganogrunerite, garnets into garnets (spessartine- situated over the Pietrosu Bistritei Nappe and supporting the calderite into spessartine, spessartine into anisotropic spes- thrusting of the Rebra Nappe. All these Variscan nappes sartine-andradite-grossular), calderite into pyroxmangite- constitute the Alpine Sub-Bucovinian Nappe localised be- magnetite, etc. are the best evidences of continuous variation tween Alpine Infrabucovinian Nappe in the East and the of formation conditions. Alpine Bucovinian Nappe in the West. The Mn ore have a predominant carbonate rather than The mineralogy of Mn metamorphosed deposits from silicate mineralogical composition, which means a great CO2 Bistrita Mts. includes 328 minerals and mineral varieties. fluid control in the carbonation and dehydration processes They may count among the mineralogically the most com- along the many stages of the whole history of the ore and the plex deposits of the world. -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
Download the Scanned
American Mineralogist, Volume 70, pages 379-387, 1985 Ma_nganesehumites and leucophoenicitesfrom Franklin and Sterling- Hill' NewJersev: 'i"? andimplications ;ifi':il1,;;lfiil11"r's' Perr J. Dullx Department of Mineral Sciences Smithsonian lnstitution, Washington, D. C. 20560 Abstract The manganesehumites, (alleghanyite, manganhumite, and sonolite),together with some Mn-bearing samplesof the Mg-humites,and the related phasesleucophoenicite and jerry- gibbsite,from the orebodiesat Franklin and SterlingHill, New Jersey,are describedtogether with analytical data. Solid solution betweenhumite and manganhumiteis at least partially continuous. Expected Mn/Mg solid solutions between alleghanyiteand chondrodite, and betweensonolite and clinohumite, are discontinuous; they are interrupted by apparently orderedphases. In all cases,the possibleorderings involve Zn as well as Mn and Mg. There are no Mn end-membersof the manganesehumites at this locality. Manganeseis apparently restricted in leucophoenicite(5.42-6.63 Mn per 7 octahedral cations) and in jerrygibbsite (7.79-8.02Mn per 9 octahedralcations). Calcium is common to both leucophoeniciteand jerrygibbsite,but among the Mn-humites,only sonoliteaccepts appreciable Ca (0.65Ca per 9 octahedralcations). There is a "threshold" level ofzinc in all studiedsamples; this "threshold" levelis a constantfor leucophoenicite1-9.3 Znper 3 Si)and alleghanyite(-O.2Zn per 2 Si). No samplesof leucophoeniciteor jerrygibbsite were found to be Zn-ftee,suggesting either that Zn is required for their stability, or that these two phasesmight not be stable as end-members.Fluorine is present in all the Mn-humites and is proportional to the Mg- content,but is absentin leucophoeniciteand jerrygibbsite. Introduction humite speciesoccur there; the Mg-humites occur in the The magnesiumhumite species(norbergite, chondrodite, host Franklin Marble for the most part, and the Mn- humite, and clinohumite) have been well-studiedand re- humites in the orebodiesthemselves. -
Kumtyubeite Ca5(Sio4)2F2—A New Calcium Mineral of the Humite Group from Northern Caucasus, Kabardino-Balkaria, Russia
American Mineralogist, Volume 94, pages 1361–1370, 2009 Kumtyubeite Ca5(SiO4)2F2—A new calcium mineral of the humite group from Northern Caucasus, Kabardino-Balkaria, Russia Ir I n a О. Ga l u s k I n a ,1,* BI l j a n a la z I c ,2 Th o m a s ar m B r u s T e r,2 ev G e n y v. Ga l u s k I n ,1 vI k T o r m. Ga z e e v,3 al e k s a n d e r e. za d o v,4 nI k o l a I n. Pe r T s e v,3 lIdIa je ż a k ,5 ro m a n Wr z a l I k ,6 a n d an a T o l y G. Gu r B a n o v 3 1Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland 2Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland 3Institute of Geology of Ore Deposits, Geochemistry, Mineralogy and Petrography (IGEM) RAS, Staromonetny 35, 119017 Moscow, Russia 4OOO NPP TEPLOCHIM, Dmitrovskoye av. 71, 127238 Moscow, Russia 5Institute of Geochemistry, Mineralogy and Petrology, University of Warsaw, al. Żwirki i Wigury 93, 02-089 Warszawa, Poland 6Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland aB s T r a c T Kumtyubeite, Ca5(SiO4)2F2—the fluorine analog of reinhardbraunsite with a chondrodite-type structure—is a rock-forming mineral found in skarn carbonate-xenoliths in ignimbrites of the Upper Chegem volcanic structure, Kabardino-Balkaria, Northern Caucasus, Russia. -
Leucophoenicite Mn (Sio4)3(OH)2
2+ Leucophoenicite Mn7 (SiO4)3(OH)2 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals rare, typically slender, prismatic, elongated and striated [010], to 8 mm; in isolated grains or granular massive. Twinning: On k 001 , common, contact or interpenetrant twins, lamellar. f g Physical Properties: Cleavage: 001 , imperfect. Tenacity: Brittle. Hardness = 5.5{6 f g D(meas.) = 3.848 D(calc.) = [4.01] Optical Properties: Transparent to translucent. Color: Brown to light purple-red, raspberry-red, deep pink to light pink; rose-red to colorless in thin section. Luster: Vitreous. Optical Class: Biaxial ({). Pleochroism: Faint; rose-red 001 ; colorless 001 . Orientation: k f g ? f g X 001 cleavage. Dispersion: r > v; slight. ® = 1.751(3) ¯ = 1.771(3) ° = 1.782(3) ? f g 2V(meas.) = 74(5)± Cell Data: Space Group: P 21=a: a = 10.842(19) b = 4.826(6) c = 11.324(9) ¯ = 103:93(9)± Z = [2] X-ray Powder Pattern: Franklin, New Jersey, USA. 1.8063 (10), 2.877 (9), 2.684 (8), 4.36 (5), 3.612 (5), 2.365 (5), 2.620 (4) Chemistry: (1) (2) (3) (1) (2) (3) SiO2 26.36 26.7 26.7 CaO 5.67 2.4 2.8 FeO trace 0.3 0.3 Na2O 0.39 MnO 60.63 62.8 64.7 K2O 0.24 ZnO 3.87 0.0 0.0 H2O 2.64 [2.3] [2.8] MgO 0.21 5.5 2.7 Total 100.01 [100.0] [100.0] (1) Franklin, New Jersey, USA; composite of two analyses, corresponding to (Mn5:89Ca0:70Zn0:32 Na0:04Mg0:03K0:01)§=6:99(Si1:01O4)3(OH)2: (2) Kombat mine, Namibia; by electron microprobe, H2O by di®erence; corresponding to (Mn5:98Mg0:92Ca0:29Fe0:02)§=7:21(SiO4)3(OH)1:72: (3) Valsesia-Valtournanche area, Italy; by electron microprobe, H2O by di®erence; corresponding to (Mn6:16Mg0:45Ca0:34Fe0:03)§=6:98(SiO4)3(OH)2:10: Mineral Group: Leucophoenicite group. -
Jerrygibbsite Mn (Sio4)
2+ Jerrygibbsite Mn9 (SiO4)4(OH)2 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Orthorhombic. Point Group: mm2 (probable), or 2=m 2=m 2=m: As interlocking anhedral crystals, to 2 mm. Physical Properties: Cleavage: Imperfect on 001 . Hardness = 5.5 D(meas.) = 4.00(2) D(calc.) = 4.045 f g » Optical Properties: Transparent and translucent lamellae alternating 001 . Color: Violet-pink, with a brownish tinge; light pink in thin section. Strekakf: Light pink. Luster: Vitreous. Optical Class: Biaxial ({). Orientation: X = b; Y = c; Z = a. Dispersion: r > v; moderate. ® = 1.772(4) ¯ = 1.783(4) ° = 1.789(4) 2V(meas.) = 72± Cell Data: Space Group: P bn21 (probable), or P bnm: a = 4.875(2) b = 10.709(6) c = 28.18(2) Z = 4 X-ray Powder Pattern: Franklin, New Jersey, USA. 2.557 (100), 1.806 (100), 2.869 (78), 2.752 (49), 2.702 (46), 2.362 (39), 2.661 (34) Chemistry: (1) SiO2 27.1 FeO 0.3 MnO 64.1 ZnO 3.9 MgO 1.4 CaO 0.4 F 0.0 H2O 2.13 Total 99.3 (1) Franklin, New Jersey, USA; by electron microprobe, H2O by the Pen¯eld method; corresponds to (Mn7:86Zn0:59Mg0:24Ca0:16Fe0:14)§=8:99(SiO4)4(OH)2: Polymorphism & Series: Dimorphous with sonolite. Mineral Group: Leucophoenicite group. Occurrence: In a metamorphosed stratiform Zn-Mn deposit. Association: Franklinite, willemite, zincite, sonolite, leucophoenicite, tephroite. Distribution: From Franklin, Sussex Co., New Jersey, USA. Name: In honor of Professor Gerald V. Gibbs, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA. -
Delindeite and Lourenswalsite, Two New Titanosilicates from the Magnet Cove Region, Arkansas
Delindeite and lourenswalsite, two new titanosilicates from the Magnet Cove region, Arkansas DANIEL E. ApPLEMAN Department of Mineral Sciences, Smithsonian Institution, Washington, D.C. 20560, USA AND How ARD T. EVANS, JR., GORDON L. NORD, EDWARD J. DWORNIK AND CHARLES MIL TON U.S. Geological Survey, Reston, Virginia 22092, USA Abstract Delindeite and lourenswalsite are two new barium titanosilicate minerals found as microscopic crystals in miarolitic cavities in nepheline syenite in the Diamond Jo quarry, Hot Spring County, Arkansas. Delindeite is found as aggregates of flake-like crystallites in compact spherules, light pinkish grey in colour, with a resinous, pearly lustre. The flakes are biaxial positivewith average n ~ 1.813;the measured density is 3.3 g/cm3. Electron diffraction revealed a monoclinic unit cell in space group C2/m or subgroup, with a = 21.617(13), b = 6.816(5), c = 5.383(3) A, P = 94.03(5t(refined from X-ray powder data). The strongest X-ray lines are (hkl, dobs,!re'):(200,10.80,100); (311,3.54,24); (601,3.083,28); (601, 2.888, 31);(221, 2.806, 20); (910, 2.262,18). The crystals are submicroscopically twinned on (100) and also produce additional continuous diffraction streaks parallel to a*, which double the band c axes. The formula derived from electron and ion probe analyses (H20 by difference), as constrained by density and molar volume data, is approximately (Na,Kb.7(Ba,Ca)4(Ti,Fe,AI)6Sig026(OH)14' with Na> K, Ba »Ca, Ti» Fe,AI; Z = 1. Lourenswalsite occurs as very thin hexagonal plates in rosettes, silver grey to light brownish grey in colour. -
STRONG and WEAK INTERLAYER INTERACTIONS of TWO-DIMENSIONAL MATERIALS and THEIR ASSEMBLIES Tyler William Farnsworth a Dissertati
STRONG AND WEAK INTERLAYER INTERACTIONS OF TWO-DIMENSIONAL MATERIALS AND THEIR ASSEMBLIES Tyler William Farnsworth A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry. Chapel Hill 2018 Approved by: Scott C. Warren James F. Cahoon Wei You Joanna M. Atkin Matthew K. Brennaman © 2018 Tyler William Farnsworth ALL RIGHTS RESERVED ii ABSTRACT Tyler William Farnsworth: Strong and weak interlayer interactions of two-dimensional materials and their assemblies (Under the direction of Scott C. Warren) The ability to control the properties of a macroscopic material through systematic modification of its component parts is a central theme in materials science. This concept is exemplified by the assembly of quantum dots into 3D solids, but the application of similar design principles to other quantum-confined systems, namely 2D materials, remains largely unexplored. Here I demonstrate that solution-processed 2D semiconductors retain their quantum-confined properties even when assembled into electrically conductive, thick films. Structural investigations show how this behavior is caused by turbostratic disorder and interlayer adsorbates, which weaken interlayer interactions and allow access to a quantum- confined but electronically coupled state. I generalize these findings to use a variety of 2D building blocks to create electrically conductive 3D solids with virtually any band gap. I next introduce a strategy for discovering new 2D materials. Previous efforts to identify novel 2D materials were limited to van der Waals layered materials, but I demonstrate that layered crystals with strong interlayer interactions can be exfoliated into few-layer or monolayer materials.