Common Landscape Herbicides and Their Effects on Trees
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(12) United States Patent (10) Patent No.: US 8,586,504 B2 Wright Et Al
USOO85865.04B2 (12) United States Patent (10) Patent No.: US 8,586,504 B2 Wright et al. (45) Date of Patent: Nov. 19, 2013 (54) HERBICIDAL COMPOSITIONS CONTAINING FOREIGN PATENT DOCUMENTS GLYPHOSATE AND A PYRONE ANALOG AU 100.73/92 B 10, 1992 CA 2340240 A1 2, 2000 (75) Inventors: Daniel R. Wright, St. Louis, MO (US); EP O 808 569 A1 11, 1997 Joseph J. Sandbrink, Chesterfield, MO GB 2267 825 A 12/1993 (US); Paul G. Ratliff, Olivette, MO WO 99/00013 1, 1999 WO OO,30452 6, 2000 (US) WO OO,642.57 11, 2000 WO OO/67571 11, 2000 (73) Assignee: Monsanto Technology LLC, St. Louis, WO O1/35740 A2 5, 2001 MO (US) WO 02/21924 A2 3, 2002 (*) Notice: Subject to any disclaimer, the term of this OTHER PUBLICATIONS patent is extended or adjusted under 35 Exhibit PMH-17 Supplemental Labeling regarding Roundup Pro U.S.C. 154(b) by 0 days. Herbicide by Monsanto, EPA Reg. No. 524-475 (Nov. 1995), 11 pageS. (21) Appl. No.: 13/404,861 Exhibit PMH-18 Notice of Pesticide Registration issued on Oct. 5, 2000, 35 pages. Exhibit PMH-19 EPA Application for Pesticide, ID No. 200405 (22) Filed: Feb. 24, 2012 (Sep. 1995), 33 pages. Exhibit PMH-20-Documentation regarding Starmas Racun/ (65) Prior Publication Data Rumpai Herbicide (bears the year 2003), 10 pages. Exhibit PMH-21—Documentation regarding Starmix Racun/ US 2012/O157309 A1 Jun. 21, 2012 Rumpai Herbicide (Date Unknown), 3 pages. Exhibit PMH-22—article entitled Control of Eucalyptus grandis cut stumps by Keith Little et al., ICFR Bulletin Series, No. -
2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
July 6, 2020 OPP Docket Environmental Protection Agency Docket Center (EPA/DC), (28221T) 1200 Pennsylvania Ave. NW Washington
July 6, 2020 OPP Docket Environmental Protection Agency Docket Center (EPA/DC), (28221T) 1200 Pennsylvania Ave. NW Washington, DC 20460-000 Docket ID # EPA-HQ-OPP-2014-0167 Re. Clopyralid, Case Number 7212 Dear Madam/Sir: These comments are submitted on behalf of Beyond Pesticides, Beyond Toxics, Center for Food Safety, Hawai’i Alliance for Progressive Action, Hawai'i SEED, LEAD for Pollinators, Maine Organic Farmers and Gardeners Association, Maryland Pesticide Education Network, Northeast Organic Farming Association—Massachusetts Chapter, Northwest Center for Alternatives to Pesticides, People and Pollinators Action Network, Real Organic Project, Sierra Club, Toxic Free NC, Women’s Voices for the Earth. Founded in 1981 as a national, grassroots, membership organization that represents community-based organizations and a range of people seeking to bridge the interests of consumers, farmers and farmworkers, Beyond Pesticides advances improved protections from pesticides and alternative pest management strategies that reduce or eliminate a reliance on pesticides. Our membership and network span the 50 states and the world. EPA’s proposed interim decision (PID) on the weed killer clopyralid is inadequate to protect property, nontarget plants, and pollinators from exposure to the chemical. Clopyralid poses unreasonable adverse effects that cannot be remedied by EPA’s proposed fixes. It should not be reregistered. Clopyralid has a long history of causing environmental and property damage through drift, runoff, use of treated plant material (such as straw or grass clippings) for mulch or compost, contaminated irrigation water, and urine or manure from animals consuming treated vegetation. Clopyralid (3,6-dichloro-2-pyridinecarboxylic acid) is an herbicide used to control broadleaf weeds on nonresidential lawns and turf, range, pastures, right-of ways and on several crops. -
U.S. EPA, Pesticide Product Label, CLOPYRALID MEA+2,4-D, 07/07/2008
'f-;) 7 S-O - 'ta- \ ENVIRONMENTAL PROTECTION u.s. EPA Reg, Nwnber: Date of Issuance: AGENCY Office of Pesticide Programs 42750-92 Registration Division (7505P) -- 7 JtJL 2DOB Ariel Rios, Building 1200 Pennsylvania Ave., NW Washington, D.C, 20460 NOTICE OF PESTICIDE: Term of Issuance: _ Registration -X Reregistration Name of Pesticide Product: (under FIFRA, as amended) Clopyralid MEA+ 2,4- D Name and Address of Registrant (include ZIP Code): Albaugh, Inc. 121 NE 18th Street Ankeny, IA 50021 N o~e: C.h~nge,~itiIflb~ljllgl,~i:t1~1i~~J9~~~1?~!iUiC~,fJqnf.th~i.:~G~~t~4j#'qqHriet£i~riw,ii4;tl}is, :' ',' ,,',: " registratio"n ~4stl>e ,s~Drriittedto,aPQjl,~9:~pt~qby 'theRe,gi~ttatipn pivisi()i1 prior t9 ':tI~.~"Qn~~)*~eI , ,~:~~~~r:::~.~:;~~:1~~jJ:r~,2t.edf.~,~.&.~~lt;'~I~\~i,~tfl%~~~i;m)~t~~:;'~~/~~·?~~:,)~·¥'t·.'~~~i,~j~:~:i)~.:,;" ,.".;,' "' On the basis of information furnished by the registrant, the above named pesticide is hereby registered/reregistered under the Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no way to be construed as an endorsement or recommendation of this product by the Agency. In order to protect health and the environment, the Administrator, on his motion, may at any time suspend or cancel the registration of a pesticide in accordance with the Act. The acceptance of any name in connection with the registration of a product under this Act is not to be construed as giving the registrant a right to exclusive use of the name or to its use ifit has been covered by others. This product is reregistered in accordance with FIFRA sec. -
Environmental Fate of Imidazolinone Herbicides and Their Enantiomers
Title Environmental Fate of Imidazolinone Herbicides and Their Enantiomers in Soil and Water Mohammadkazem Ramezani B.Sc. Agronomy, M.Sc. Weed Science This thesis is presented for the degree of Doctorate of Philosophy of the University of Adelaide School of Agriculture, Food & Wine The University of Adelaide Waite Campus, South Australia 2007 Declaration This work contains no material which has been accepted for the award of any other degree or diploma in any university or other tertiary institution and, to the best of my knowledge and belief, contains no material previously published or written by another person, except where due reference has been made in the text. I give consent to this copy of my thesis, when deposited in the University Library, being made available for loan and photocopying. Mohammadkazem Ramezani ii Abstract Imidazolinones represent a new class of herbicides with low mammalian toxicity that can be used at low application rates, either pre- or post-emergence for the control of a wide range of weeds in broadleaf and cereal crops, and non-crop situations. All imidazolinone herbicides are chiral, containing two enantiomers that derive from the chiral centre of the imidazolinone ring. The inhibitory activity of the R(+) enantiomer is nearly eight times greater than that of the S(-) enantiomer. The use of imidazolinone herbicides has increased in recent years in Australia owing to increased popularity of pulses and the introduction of imidazolinone-tolerant canola and wheat. Concerns have been raised about the potential carry over damage to the subsequent crops grown in rotation with legumes and herbicide tolerant crops. -
Corn and Soybean Mode of Action Herbicide Chart
By Premix Corn and Soybean This chart lists premix herbicides alphabetically by their trade names so you can identify the premix’s component herbicides and their respective site of action groups. Refer Herbicide Chart to the Mode of Action chart for more information. Component Repeated use of herbicides with the same Site of Premix Trade Active Action site of action can result in the development of Trade Name ® Name ® Ingredient Group* herbicide-resistant weed populations. Authority First ............... Spartan sulfentrazone 14 FirstRate cloransulam 2 Axiom ........................... Define flufenacet 15 This publication was designed for commercial printing, color shifts may occur on other printers and on-screeen. Sencor metribuzin 5 Basis . ........................... Resolve rimsulfuron 2 Harmony GT thifensulfuron 2 By Mode of Action (effect on plant growth) Bicep II Magnum .......... Dual II Magnum s-metolachlor 15 AAtrex atrazine 5 This chart groups herbicides by their modes of action to assist Bicep Lite II Magnum .... Dual II Magnum s-metolachlor 15 AAtrex atrazine 5 you in selecting herbicides 1) to maintain greater diversity in Boundary ...................... Dual Magnum s-metolachlor 15 herbicide use and 2) to rotate among herbicides with different Sencor metribuzin 5 Breakfree ATZ ............... Breakfree acetochlor 15 sites of action to delay the development of herbicide resistance. atrazine atrazine 5 Breakfree ATZ Lite ........ Breakfree acetochlor 15 Number of atrazine atrazine 5 resistant weed Buctril + Atrazine ......... Buctril bromoxynil 6 atrazine atrazine 5 species in U.S. Bullet ............................ Micro-Tech alachlor 15 Site of Chemical Active atrazine atrazine 5 Action Product Examples Camix ........................... Callisto mesotrione 28 Group* Site of Action Family Ingredient (Trade Name ®) Dual II Magnum s-metolachlor 15 Lipid Canopy DF .................. -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
Efficacy of Imazapic/Imazapyr and Other Herbicides in Mixtures for The
Efficacy of imazapic/imazapyr and other herbicides in mixtures for the control of Digitaria insularis prior to soybean sowing Efectividad de imazapic/imazapyr y otros herbicidas en mezclas para el control de Digitaria insularis en pre-siembra de soya Alfredo Junior Paiola Albrecht1, Leandro Paiola Albrecht1, André Felipe Moreira Silva²*, Romulo Augusto Ramos³, Everson Pedro Zeny³, Juliano Bortoluzzi Lorenzetti4, Maikon Tiago Yamada Danilussi4, and Arthur Arrobas Martins Barroso4 ABSTRACT RESUMEN Herbicide mixtures, use of multiple sites of action, and other Las mezclas entre herbicidas, el uso de múltiples sitios de acción weed management practices are necessary to avoid cases of y otras prácticas de manejo de malezas son necesarias para biotype resistance. The aim of this study was to evaluate the evitar otros casos de resistencia de biotipos. El objetivo de este efficiency of imazapic/imazapyr and other herbicides in mix- estudio fue evaluar la eficiencia de imazapic/imazapyr y otros tures to control Digitaria insularis at burndown before soybean herbicidas en mezclas para controlar Digitaria insularis en la sowing. This field research was conducted in Umuarama, State desecación antes de la siembra de soya. Esta investigación de of Parana (PR), Brazil, in the 2018/19 soybean season. The ex- campo se realizó en Umuarama, Estado de Paraná (PR), Brasil, periment was conducted in a randomized block experimental en la cosecha de soya de 2018/19. El experimento se realizó en design with four replicates and 11 treatments composed of the un diseño experimental de bloques al azar, con cuatro repe- application of glyphosate, clethodim, haloxyfop, imazapic/ ticiones y 11 tratamientos, compuestos por la aplicación de imazapyr, glufosinate, 2,4-dichlorophenoxyacetic acid (2,4-D), glifosato, cletodim, haloxifop, imazapic/imazapir, glufosinato, dicamba, triclopyr, and saflufenacil, in mixtures. -
Safety and Efficacy of Postemergence Herbicides for Container-Grown Landscape Groundcovers
1 17B-Student-Conner-IPPS-2018.doc Safety and Efficacy of Postemergence Herbicides for Container-Grown Landscape Groundcovers© Crystal J. Connera, Chris Marble, and Annette Chandler Mid-Florida Research and Education Center, University of Florida, 2725 S. Binion Road, Apopka, Florida 32703, USA aEmail: [email protected] KeyWords: Landscape nursery, weed management, asiatic jasmine, Trachelospermum asiaticum ‘Minima’, perennial peanut, Arachis glabrata ‘Ecoturf’ SUMMARY Research was conducted to determine crop tolerance of asiatic jasmine (Trachelospermum asiaticum ‘Minima’) and perennial peanut (Arachis glabrata ‘Ecoturf’) to postemergence herbicides including bentazon, sulfentrazone, iron HEDTA, indaziflam (a preemergence herbicide), sulfosulfuron, and clopyralid. Efficacy of these herbicides was evaluated on flowering eclipta (Eclipta prostrata) and hairy beggarticks (Bidens pilosa). All herbicides with the exception of bentazon caused no significant damage to asiatic jasmine; injury resulting from bentazon was minimal. In perennial peanut, the highest injury was noted in plants treated with indaziflam, sulfosulfuron, or clopyralid, but injury was less than 30% and considered acceptable. All herbicides evaluated provided poor control of either weed species with the exception of clopyralid, which provided over 90% control of hairy beggarticks. Results indicate that several postemergence herbicides labeled for use in either nurseries or landscapes could be used to manage weeds in asiatic jasmine or perennial peanut groundcovers but further testing is needed. 1 2 INTRODUCTION Turfgrass is the most widely planted irrigated crop in the United States and occupies the vast majority of most residential and commercial landscapes in Florida (NTRI, 2003). However, the common mantra of landscape design is “right plant right place”. In many neighborhoods, parks, and other areas containing significant tree canopy, turfgrass is not suitable due to limited sunlight. -
Aminopyralid Ecological Risk Assessment Final
Aminopyralid Ecological Risk Assessment Final U.S. Department of the Interior Bureau of Land Management Washington, D.C. December 2015 EXECUTIVE SUMMARY EXECUTIVE SUMMARY The United States Department of the Interior (USDOI) Bureau of Land Management (BLM) administers about 247.9 million acres in 17 western states in the continental United States (U.S.) and Alaska. One of the BLM’s highest priorities is to promote ecosystem health, and one of the greatest obstacles to achieving this goal is the rapid expansion of invasive plants (including noxious weeds and other plants not native to an area) across public lands. These invasive plants can dominate and often cause permanent damage to natural plant communities. If not eradicated or controlled, invasive plants will jeopardize the health of public lands and the activities that occur on them. Herbicides are one method employed by the BLM to control these plants. In 2007, the BLM published the Vegetation Treatments Using Herbicides on Bureau of Land Management Lands in 17 Western States Programmatic Environmental Impact Statement (17-States PEIS). The Record of Decision (ROD) for the 17-States PEIS allowed the BLM to use 18 herbicide active ingredients available for a full range of vegetation treatments in 17 western states. In the ROD, the BLM also identified a protocol for identifying, evaluating, and using new herbicide active ingredients. Under the protocol, the BLM would not be allowed to use a new herbicide active ingredient until the agency 1) assessed the hazards and risks from using the new herbicide active ingredient, and 2) prepared an Environmental Impact Statement (EIS) under the National Environmental Policy Act to assess the impacts of using new herbicide active ingredient on the natural, cultural, and social environment. -
INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401