New Mineral Names*
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American Mineralogist, Volume 62, pages 593400, 1977 NEW MINERAL NAMES* Mrcnerl FLnrscHrR,Louls J. Cttnr, ERNssrH. Nrcxtl ANDADoLF pABsr Argentocuproaurite Bracewellite,* grimaldiite,* guyanaite,+ mcconnellite* (1975) L V. Razin Minerals-natural alloys of gold and copper in Charles Milton, D. E. Appleman, M. H Appleman, E. C. T. ores of copper-nickel deposits of Noril's. Trudy Mineral. Mu- Chao, Frank Cuttitta, J. I. Dinnin, E. J. Dwornik, B. L. Ingram zeya Akad. Naak SSSR, 24, 93-106 (in Russian) and H. J Rose,Jr. (1976) Merumite, a complex assemblageof chromium minerals from Guyana. U. S. Geol. Suns. Prof. Pap., Microprobe analysesof two grains from Noril'sk and Talnakh. 887. l-29. respectivefy,gave Au 67.7,66.5:Cu 9.2, t 1.2;Ag 12 8, 19.4;pd4.2" 22:Rh4.3, -; Pb I 6, -; Pt 0.9,-; Sn -,0.5; totals100.7,99.8, with Merumite, supposedly CrrOr. HrO [Am. Mineral., 34, 339 idealizedformulae of AuuoCu'Agr?Rh6pd6and AurrAgr"Curnpd.. (19a9)]is shown to consistoffine-grained intergrowths ofeskolaite The X-ray powder pattern (8 lines)was indexedas primitive cubic (Cr,O.) (predominant) with 4 new minerals. It occurs as black with a : 4.073(2)A. The mineral is light reddish-rose in reflecred rounded grains in alluvial gravelsof the drainage basin of the light, isotropic, with no observed birefringence Reflectanceat 5g0 Merume River, Guyana. mm : 64.3 percent. VHNuo = 214(2ll-216). Negative to standard Guyanaite, CrO(OH) is orthorhombic, space group Pnnm, a etch agents, except for KCN and aqua regia. 4.857,b 4.295,c 2.958,4,Z = 2,G calc4.53; synthetic material has closelyagreeing unit-cell dimensions. Analysis on 37 mg by B.L.L Discussion gaveCr2O, 7 |.7, Al,Os4.0, Fe.O, 4.4, Mn,O3 0.98,Tiros 0.86,HrO Compositionally, the mineral is argentoanCuAu or cuproan ar- * 8 7, sum 90.7 percent.The strongestX-ray lines (21 given) are gentoan gold. The mineral can be indexedas face-centeredcubic 3.224(vvs) (t t0),2.432 (SX200), 1.719 (MSX2l I ), 1.636(SXl 2 I ), (hence cuproan argentoan gold), except for the weakest reflection 1.609(MSX220), 1.516 (MSX3l0). Color reddish-brown, golden- in the pattern reported at 1.6734 Confirmation by single-crystal brown, greenish-brown,green (synthetic). methods of this single weak extra reflection in the powder pattern Bracewellite, also CrO(OH), is orthorhombic, space group is necessaryto justify characterization as a new mineral species. Pbnm, a 4.492 + 0.003, b 9.860 + 0.005, c 2.974 + 0.002A., Z = 4, The name is unnecessary.L.J.C. G 4.45-4.48.It is isostructuralwith goethiteand diaspore.Analysis of a mixture containing 70 percent bracewellite * 30 percent eskolaitegave Cr2O.70.6, FeO, 15.1,AlrO3 6.2,V2Oe 0.64, TirO, Aurocuproite 0.17, H,O 6.9, sum 996 percent The strongestX-ray lines (14 L V. Razin (1975) Minerals-natural alloys of gold and copper in given) are 4.065(VVS) (ll0),2.648 (VSXl30),2.404 (VSXlll). ores of copper-nickel deposits of Noril'sk. Trudy Mineral. Mu- Color deep red to black, streak dark brown. The mineral has not zeya Akad. Nauk SSSR, 24,93-106 (in Russian). been synthesized. Grimaldiite, CrO(OH), and mcconnellite,CrOOCu, occur as M icroprobe analysesof two grains gave A u 6l .6, 64.5;Cu 28.4, intergrowths of tabular deep-red rhombohedral crystals up to I 28.0;Ag 0.9, -; Pd 7.1,69; pt 2.3,-; Rh 1.9,-; Bi 0.6,_; totals mm in size.Analysis of such an intergrowth (containing 80-86% 103.4,99.4, with idealized formulae of Cu,rAu,.pd, and grimaldiite) gave on 9.35 mg Cr"O"77.3, AlrOs 34.3, Fe,O,0.85, CurrAur"Pdr.The X-ray powder pattern (8 lines) was indexedas CuO 5.5, SiO,0.42, ignition loss 11.5,sum 999 percent.X-ray primitive cubic with a: 3.862(2)A.The mineral, foundin ores of study shows that both minerals are rhombohedral, spacegroup the Talnakh deposit,is light orange-yellowin reflectedlight, iso- R3m Grimaldiite has a 2.973 + 0.002,c 13 392 + 0.01A; mccon- tropic, with no birefringence observed. Reflectance at 580 nm : nellite has a2.983t 0.004,c 17.160+ 0.031A. The strongestlines 63 I percent. VHNuo = 199(189-206).Negative to standard etch ior grimaldiite (14 given) are 44'l (VVSX003), 2 401 (VSXOI2), reagents except for KCN and aqua regia 1.857(VSX0l5), 1.486(MSX009); for mcconnellite,the strongest Discussion Iines (14 given) are 2.860 (006), 24'14 (012),2.213 (104), 1.650 (018), 1.492(l l0). Theseboth agreewith data in the literatureon Compositionally the mineral is palladianAuCu or auroan palla- syntheticCrO(OH) and CrOOCu. dian copper. The powder pattern may be indexed as face centered Synthetic grimaldiite has been reported in the literature to have cubic (hence auroan palladian copper) except for the weakest a 2.155, e 1.975,G 4.11, 4.12. Optical propertieswere not mea- reflection at 1.0704. Confirmation by single-crystal methods of sured for mcconnellite;it has G meas(synthetic) 5.49, calc 5.61. this single extra weak reflection in the powder pattern is necessary Guyanaite is named for the locality, bracewellite for Smith to justify characterization as a new mineral species.The name is Bracewell,formerly director, British Guiana Geological Survey, unnecessary. L.J.C. who first describedmerumite, mcconnellitefor Dr. R. B. McCon- nell, former director, British Guiana Geological Survey, grimal- * Minerals marked with an asterisk after the name were ap- diite for Dr. Frank S. Grimaldi. former chief chemist.U.S. Geo- proved before publication by the Commission on New Minerals logical Survey. Type material is at the Smithsonian Institution, and Mineral Names, International Mineraloeical Association. Washington,D.C. M.F. 593 594 NEW MINERAL NAMES Kankitet Y : b, Z 1. a 2-4o, elong.pos., pleochroicwith X and Z colorless to pale purple, abs. X I Z { Y F. Cech,J Jansaand F Novak (1976)Kankite, FeAsO,'3112 The first sample forms the core of a zoned single crystal, the HrO, a new mineral. NeuesJahrb. Mineral Monatsh.,426-436. outer part being brown manganoanzinnwaldite, from a druse of Analysisby M. Mrazek gaveAs,Ou 43.92, SO3 0.44, FerO.3l.84, granite pegmatiteat Tanakamiyama,Japan, associated with topaz, CaO 0.02, H,O + 13.91,H,O - 9.91, insol.0.36, sum 100.40 black tourmaline, albite, and quartz. The secondis a pseudohexa- percent (given as 100.46), corresponding to 2FeAsO. 6.74 H"O. gonal crystal, 3 cm across and I cm thick from Tawara, Gifu Spectographicanalysis showed traces of N, B, Cu, Mg, Mn, Ti, Prefecture, associated with cassiterite, top^z, black tourmaline, and Zn. The DTA curve shows 2 endothermicpeaks at 190 and albite, and quartz. 29O" and an exothermic peak at 605o. The loss in weight is 9.0 Unit-cell determinationsand opticson 8 lithium micasshow that percent at 200', 23.81 percent at 500'. The infrared absorption complete solid solutionsexist in the title ternary system. spectrumis given.The mineral is insolublein water, but dissolves The name is for Dr. Kazunosuke Masutomi, amateur miner- readily in l0 percentHCl. alogist and mineral collector.Type material is preservedat Kana- X-ray powder data (51 lines) are given; the strongestare 12.8 zawa Univ (anal. l) and at Tohoku University (anal.2). M'F. (l00xll0),7.56 (25)(001), 7.22 (2txi0l), 6.97 (l9x0ll), 4.764 (14x3r| ). 4.258 (2s)(r40). 3.697 (228)(42t. t4t). 2 630(29X631 ). 2553(22)(550,63t),2.520 (2lx0l3). These are indexed on a Nakauriite* monocliniccell with a 18.803,b 17 490, c7.633A, 0 92.7 1", Z ='16, Juiin Suzuki,Masahira lto and Tsutomu Sugiura(1976) A new C calc 2.732,meas 2.70 (pycnometer). .opp", sulfate-carbonate hydroxide hydrate mineral, The mineral forms yellowish-greenbotryoidal coatings and (Mn,Ni,Cu).(SO').(CO3)(OH)6.48H,O, from Nakauri, Achi crusts severaltenths mm to 7 mm thick. Luster dull. H 2-2 1/2, Prefecture, Japan. J. Japan Assoc Mineral Pettol' Econ. Geol., fracture uneven Mean n about 1.666,birefringence about d02, 71, t83-192 (in English). fi bers are length-fast The mineral was found in old dumps ( I 3th to Chemical analysiswas made of a mixture of the mineral with I sth century) near Kank, Kutna Hora district,Czechoslovakia It chrysotile,from which it could not be separated.Examination by is an alteration product of arsenopyriteand is associatedwith X-ray fluorescenceand electron microprobe analysis showed that quartz, scorodite,pitticite, gypsum, and a new mineral with for- the mineral did not contain Mg or Si; these were deducted as mula Fe3+(AsO.),(SO.XOH) I 5H,O. chrysotile,(about 607oof the sample), leaving FerO' 0.06, MnO The name is for the locality. The mineral was compared with 0.09,CuO 32.12,ZnO 0.03, NiO 0.88, SO, 16.23,CO,2.28,H2O+ ferrisymplesite(Dana's System,7th Ed., vol. 2, p. 753); type mate- 45 31, H,O 3 0l percent, corresponding to Cu(SOn).(COs) rial of the latter was amorohous to X-ravs. M.F. (OH)u.48HrO. DTA curves show strong endothermic breaks at 330o and 396' and weak ones at 78", 150', and 186' X-ray powder data (34 lines) are given for Type I and Type Masutomilite* * II crystals For Type I the strongestlines (those marked may Kazuo Harada, Mariko Honda, Kozo Nagashima and Satoshi be in part chrysotile):7.314*(100),(200); 7.081(la)(102); 4840 Kanisawa (1976) Masutomilite, manganeseanalogue of zinn- ( IaX300); 3.936(14)(222,023.312),3.652*(20X400); 3.ss2(I 3)(40 I )' waldite, with special reference to masutomilite-lepidolite- 2.3e7(t 0QaT: 2 367(|6)(s0a); 2.332 (14)(602) ; I 9I 5 ( I 6X7I 3); zinnwaldite seriesMineral J.