Italian Type Minerals / Marco E
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Thermal Behavior of Afghanite, an ABABACAC Member of the Cancrinite Group
American Mineralogist, Volume 97, pages 630–640, 2012 Thermal behavior of afghanite, an ABABACAC member of the cancrinite group PAOLO BALLIRANO1,2,* AND FERDINANDO BOSI1,3 1Dipartimento di Scienze della Terra, Sapienza Università di Roma, P.le Aldo Moro 5, I-00185, Roma, Italy 2CNR-IGAG, Istituto di Geologia Ambientale e Geoingegneria, Sede di Roma, Via Bolognola 7, I-00138 Roma, Italy 3CNR-IGG Istituto di Geoscienze e Georisorse, Sede di Roma, P.le A. Moro, 5, I-00185 Roma, Italy ABSTRACT Thermal behavior of afghanite, (Na15K5Ca11)Σ31[Si24Al24O96](SO4)6Cl6, P31c, a = 12.7961(7) Å, c = 21.4094(13) Å, an eight-layer member of the cancrinite group, has been investigated by combined electron microprobe analysis, X-ray single-crystal diffraction, and high-temperature X-ray powder diffraction. Non-ambient X-ray powder diffraction data were collected in the 323–1223 K thermal range on a specimen from Case Collina, Latium, Italy. Structural refinement and site assignment based on the bond-valence analysis, performed on room-temperature single-crystal X-ray diffraction data, provided more accurate site allocation of cations than the available model in the literature. The results show that the cancrinite cages alternating with the liottite cages are more compressed along the c-axis than the remaining ones. As a result the chlorine atom, located at the center of the cages, is driven off-axis to release the steric strain due to the cage compression. Thermal expansion shows a discontinuity at 448 K for both a and c unit-cell parameters, a feature previously reported for other cancrinite-like minerals. -
Beaverite- Ptumbojarosite Solid Solutions
Carudian Mineralogist Vol. 2l,pp. l0l-ll3 (1983) BEAVERITE- PTUMBOJAROSITE SOLID SOLUTIONS J. L. JAMBOR eNn J. E. DUTRIZAC CANMET, 555 Booth Steet, Ottawa, Ontario KIA OGl ABSTRACT pens6es par substitution d'hydronium. Bien qge les min6raux du groupe de la jgLrositeuent c -17 A, In synthetic plumbojarosite, incorporation of une raie de diffraction e I I A, observ6e dans plu- significant Cu or Zn (or both) increases with in- sieurs'6chantillons synthdtiques et naturels, mais creasing concentrations of Cu2+ or Zrf+ in solution sans relation avec Ia composition, indique que and, to a lesser extent, with increasing Pb/Fet+ certaines notions courantes sur la jarosite sont i ratio. Replacement of Fe3+ by Znz+ is minor, but r6viser' the replacement by Cu2+ is sufficient to indicate (Traduit par la R6daction) that a compositional series probably extends from plumbojarosite Pb[Fe"(SOJ:(OH)"1, to beaverite Mots-clls: plumbojarosite, beaverite, osarizawaite, PbCuFer(SOJr(OH)e. In the synthetic series, the syntldse de jarosite, substitution (Fe, Cu) et atomic ratio Pb:(C\ f Zn) deviates from the ex- (Fe, Zn), solution solide plumbojarosite-beaverite. pected value l:1, and vacancies in R sites (involving Fe"+, Cu2+, Zn2+) are sornmon. Variations in cell parameters calculated from X-ray powder patterns INrnonuctroN show that c is related mainly to tbe amount of Cu2* that has replaced Fe3+; a is controlled princi- Metallurgical interest in beaverite PbCuFez pally by the proportions of Cu, Zn and Fe and the (SO4)r(OH)sand copper-zinc-bearing synthetic vacant R sites. Apparently significant deficiencies in plumbojarosite Pb[Fes(SO,),(OH)o],has increased alkali-site occupancy in jarosite partly may be com- recently as a result of the recognition that pensated by hydronium substitution. -
Hydrothermal and Metamorphic Berthierine
n27 CanadianMineralogist Vol. 30,pp. 1127-1142 (1992) HYDROTHERMALAND METAMORPHICBERTHIERINE FROM THE KIDD CREEK VOLCANOGENICMASSTVE SULFIDE DEPOSIT. TIMMINS, ONTARIO JOHNF.SLACK U.S.Geological Survey, Nationnl Center, Mail Stop954, Reston, Virginia 22092, U.S.A. WEI-TEH JIANG ANDDONALD R. PEACOR Depamnent of Geological Sciences, University of Michigan, Ann Arbor, Michigan 48109, U.S.A. PATRICKM. OKITA* U.S.Geological Survey, National Center,Mail Stop954, Reston,Virginia 22092,U.S.A. ABSTRACT Berthierine,a 7 A pe-Al memberof the serpentinegroup, occursin the footwall stringerzone of the ArcheanKidd Creek massivesulfide deposit, Ontario, associated with quartz,muscovite, chlorite, pyrite, sphalerite,chalcopyrite, and local tourmaline' cassiterite,and halloysite. Berthierine has been identified by the lack of 14A basalreflections on X-ray powderdiffractionpattems, by its composition (electron-microprobedata), and by transmissionelectron microscopy (TEM). Peoogaphic and scanning eiectronmicroscopic (SEM) studiesreveal different types of berthierineocculrences, including interlayerswithin and rims on deformedchlorite, intergrowthswith muscoviteand halloysite,and discretecoarse grains. TEM imagesshow thick packetsof berthierineand chlorite that are parallel or relatedby low-angle boundaries,and layer terminationsof chlorite by berthierine; mixedJayer chlorite-berthierinealso is observed,intergrown with Fe-rich chlorite and berthierine.End-member (Mg-free) berthierineis presentin small domainsin two samples.The Kidd Creekberthierine is chemicallysimilar -
Calcium Orthophosphates (Capo4): Occurrence and Properties
Prog Biomater DOI 10.1007/s40204-015-0045-z REVIEW PAPER Calcium orthophosphates (CaPO4): occurrence and properties Sergey V. Dorozhkin1 Received: 6 October 2015 / Accepted: 5 November 2015 Ó The Author(s) 2015. This article is published with open access at Springerlink.com Abstract The present overview is intended to point the Introduction readers’ attention to the important subject of calcium orthophosphates (CaPO4). This type of materials is of the Due to the abundance in nature (as phosphate ores) and special significance for the human beings because they presence in living organisms (as bones, teeth, deer antlers represent the inorganic part of major normal (bones, teeth and the majority of various pathological calcifications), and antlers) and pathological (i.e., those appearing due to calcium phosphates are the inorganic compounds of a special various diseases) calcified tissues of mammals. For exam- interest for human being. They were discovered in 1769 and ple, atherosclerosis results in blood vessel blockage caused have been investigated since then (Dorozhkin 2012a, 2013a). by a solid composite of cholesterol with CaPO4, while According to the databases of scientific literature (Web of dental caries and osteoporosis mean a partial decalcifica- knowledge, Scopus, Medline, etc.), the total amount of tion of teeth and bones, respectively, that results in currently available publications on the subject exceeds replacement of a less soluble and harder biological apatite 40,000 with the annual increase for, at least, 2000 papers. by more soluble and softer calcium hydrogenorthophos- This is a clear confirmation of the importance. phates. Therefore, the processes of both normal and Briefly, by definition, all known calcium phosphates pathological calcifications are just an in vivo crystallization consist of three major chemical elements: calcium (oxi- of CaPO4. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Chromite Crystal Structure and Chemistry Applied As an Exploration Tool
Western University Scholarship@Western Electronic Thesis and Dissertation Repository February 2015 Chromite Crystal Structure and Chemistry applied as an Exploration Tool Patrick H.M. Shepherd The University of Western Ontario Supervisor Dr. Roberta L. Flemming The University of Western Ontario Graduate Program in Geology A thesis submitted in partial fulfillment of the equirr ements for the degree in Master of Science © Patrick H.M. Shepherd 2015 Follow this and additional works at: https://ir.lib.uwo.ca/etd Part of the Geology Commons Recommended Citation Shepherd, Patrick H.M., "Chromite Crystal Structure and Chemistry applied as an Exploration Tool" (2015). Electronic Thesis and Dissertation Repository. 2685. https://ir.lib.uwo.ca/etd/2685 This Dissertation/Thesis is brought to you for free and open access by Scholarship@Western. It has been accepted for inclusion in Electronic Thesis and Dissertation Repository by an authorized administrator of Scholarship@Western. For more information, please contact [email protected]. Western University Scholarship@Western University of Western Ontario - Electronic Thesis and Dissertation Repository Chromite Crystal Structure and Chemistry Applied as an Exploration Tool Patrick H.M. Shepherd Supervisor Roberta Flemming The University of Western Ontario Follow this and additional works at: http://ir.lib.uwo.ca/etd Part of the Geology Commons This Thesis is brought to you for free and open access by Scholarship@Western. It has been accepted for inclusion in University of Western Ontario - Electronic Thesis and Dissertation Repository by an authorized administrator of Scholarship@Western. For more information, please contact [email protected]. Chromite Crystal Structure and Chemistry Applied as an Exploration Tool (Thesis format: Integrated Article) by Patrick H.M. -
Mirabilite Na2so4 • 10H2O C 2001-2005 Mineral Data Publishing, Version 1
Mirabilite Na2SO4 • 10H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals short to long prismatic, with complex form development, also crude, to 10 cm, in interlocking masses; crystalline, granular to compact massive, commonly as efflorescences. Twinning: Rare on {001} or {100}. Physical Properties: Cleavage: On {100}, perfect; on {010} and {001}, good to fair. Fracture: Conchoidal. Hardness = 1.5–2.5 D(meas.) = 1.464 D(calc.) = 1.467 Quickly dehydrates to th´enarditein dry air; very soluble in H2O, taste cool, then saline and bitter. Optical Properties: Transparent to opaque. Color: Colorless to white; colorless in transmitted light. Streak: White. Luster: Vitreous. Optical Class: Biaxial (–). Orientation: X = b; Z ∧ c =31◦. Dispersion: r< v,strong, crossed. α = 1.391–1.394 β = 1.394–1.396 γ = 1.396–1.398 2V(meas.) = 75◦560 Cell Data: Space Group: P 21/c (synthetic). a = 11.512(3) b = 10.370(3) c = 12.847(2) β = 107.789(10)◦ Z=4 X-ray Powder Pattern: Synthetic. (ICDD 11-647). 5.49 (100), 3.21 (75), 3.26 (60), 3.11 (60), 4.77 (45), 3.83 (40), 2.516 (35) Chemistry: (1) (2) SO3 25.16 24.85 Na2O 18.67 19.24 H2O 55.28 55.91 Total 99.11 100.00 • (1) Kirkby Thore, Westmoreland, England. (2) Na2SO4 10H2O. Occurrence: Typically in salt pans, playas, and saline lakes, where deposition may be seasonal, and bedded deposits formed therefrom; rarely in caves and lava tubes; in volcanic fumaroles; a product of hydrothermal sericitic alteration; a post-mining precipitate. -
Marinellite, a New Feldspathoid of the Cancrinite-Sodalite Group
Eur. J. Mineral. 2003, 15, 1019–1027 Marinellite, a new feldspathoid of the cancrinite-sodalite group ELENA BONACCORSI* and PAOLO ORLANDI Dipartimento di Scienze della Terra, Universita` di Pisa, Via S. Maria 53, I-56126 Pisa, Italy * Corresponding author, e-mail: [email protected] Abstract: Marinellite, [(Na,K)42Ca6](Si36Al36O144)(SO4)8Cl2·6H2O, cell parameters a = 12.880(2) Å, c = 31.761(6) Å, is a new feldspathoid belonging to the cancrinite-sodalite group. The crystal structure of a twinned crystal was preliminary refined in space group P31c, but space group P62c could also be possible. It was found near Sacrofano, Latium, Italy, associated with giuseppettite, sanidine, nepheline, haüyne, biotite, and kalsilite. It is anhedral, transparent, colourless with vitreous lustre, white streak and Mohs’ hardness of 5.5. The mineral does not fluoresce, is brittle, has conchoidal fracture, and presents poor cleavage on {001}. Dmeas is 3 3 2.405(5) g/cm , Dcalc is 2.40 g/cm . Optically, marinellite is uniaxial positive, non-pleochroic, = 1.495(1), = 1.497(1). The strongest five reflections in the X-ray powder diffraction pattern are [d in Å (I) (hkl)]: 3.725 (100) (214), 3.513 (80) (215), 4.20 (42) (210), 3.089 (40) (217), 2.150 (40) (330). The electron microprobe analysis gives K2O 7.94, Na2O 14.95, CaO 5.14, Al2O3 27.80, SiO2 32.73, SO3 9.84, Cl 0.87, (H2O 0.93), sum 100.20 wt %, less O = Cl 0.20, (total 100.00 wt %); H2O calculated by difference. The corresponding empirical formula, based on 72 (Si + Al), is (Na31.86K11.13Ca6.06) =49.05(Si35.98Al36.02)S=72O144.60(SO4)8.12Cl1.62·3.41H2O. -
Calcium Orthophosphates: Occurrence, Properties and Major Applications Sergey V
lopmen e t an ev d D A s p c i p Dorozhkin, Bioceram Dev Appl 2014, 4:2 l i m c a a Bioceramics Development r t e i o DOI: 10.4172/2090-5025.1000081 c n o i s B ISSN: 2090-5025 and Applications Short communication Open Access Calcium Orthophosphates: Occurrence, Properties and Major Applications Sergey V. Dorozhkin* Kudrinskaja sq. 1-155, Moscow 123242, Russia Abstract The present overview is intended to point the readers’ attention to the important subject of calcium orthophosphates. They are of the special significance for the human beings because they represent the inorganic part of major normal (bones, teeth and antlers) and pathological (i.e., those appearing due to various diseases) calcified tissues of mammals. Therefore, the majority of the artificially prepared calcium orthophosphates of high purity appear to be well tolerated by human tissues in vivo and possess the excellent biocompatibility, osteoconductivity and bioresorbability. These biomedical properties of calcium orthophosphates are widely used to construct bone grafts. In addition, natural calcium orthophosphates are the major source of phosphorus, which are used to produce agricultural fertilizers, detergents and various phosphorus-containing chemicals. Thus, there is a great significance of calcium orthophosphates for the humankind and, here, an overview on the current knowledge on this subject is provided. Keywords: Calcium orthophosphates; Hydroxyapatite; Fluorapatite; In general, the atomic arrangement of all calcium orthophosphates Occurrence; Properties; Applications is built up around a network of orthophosphate (PO4) groups, which stabilize the entire structure. Therefore, the majority of calcium Introduction orthophosphates are sparingly soluble in water Table 1; however, all Due to the abundance in nature (as phosphate ores) and presence of them are easily soluble in acids but insoluble in alkaline solutions. -
Salt Crystallization in Porous Construction Materials I Estimation of Crystallization Pressure
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by EPrints Complutense Salt crystallization in porous construction materials I Estimation of crystallization pressure A. La Iglesiaa,*, V. Gonzalezb, V. L6pez-Acevedoc, C. Viedmac , Inslituto de Geologia Economica del CSIC, Facultad de Ciencias Ge% gicas, UCM, E·280411 Madrid. Spain b Deparlamento de Quimica, ETSI, Agronomos, UPM, E·28IJ40 Madrid, Spain , Deparlamenlo de Cristalografia y Mineralogia, Facultad de Ciencias Ge% gicas, UCM. E·28040 Madrid, Spain Abstract The crystallization process of soluble salts inside the natural and artificial porous materials partially immersed in different saline solutions has been studied, This procedure is used to simulate the conditions of exposure to salt weathering in which foundations and lower walls of building structures are within the zone of capillary rise of saline ground water. Crystallization pressures that can develop in the samples, which are a function of the pore size and salt-solution interfacial tension, have been calculated and are compared with experimental values of the materials tensile strength. since both these parameters allow the prediction of porous materials behaviour against salt weathering. Keywords: Salt weathering; Porous media; Salt crystallization; Crystallization pressure 1. Introduction The problem of crystallization pressure of salt was first studied by Correns [6J, who presented The crystallization process of soluble salts in a workable equation based on the Riecke principle porous materials can generate pressures inside the from which the pressure generated P versus salt pores sufficient to exceed the elastic limit of the supersaturation may be calculated: material, causing its breakage. -
A Single-Crystal Epr Study of Radiation-Induced Defects
A SINGLE-CRYSTAL EPR STUDY OF RADIATION-INDUCED DEFECTS IN SELECTED SILICATES A Thesis Submitted to the College of Graduate Studies and Research In Partial Fulfillment of the Requirements For the Degree of Doctor of Philosophy In the Department of Geological Sciences University of Saskatchewan Saskatoon By Mao Mao Copyright Mao Mao, October, 2012. All rights reserved. Permission to Use In presenting this thesis in partial fulfilment of the requirements for a Doctor of Philosophy degree from the University of Saskatchewan, I agree that the Libraries of this University may make it freely available for inspection. I further agree that permission for copying of this thesis in any manner, in whole or in part, for scholarly purposes may be granted by the professor or professors who supervised my thesis work or, in their absence, by the Head of the Department or the Dean of the College in which my thesis work was done. It is understood that any copying or publication or use of this thesis or parts thereof for financial gain shall not be allowed without my written permission. It is also understood that due recognition shall be given to me and to the University of Saskatchewan in any scholarly use which may be made of any material in my thesis. Requests for permission to copy or to make other use of material in this thesis in whole or part should be addressed to: Head of the Department of Geological Sciences 114 Science Place University of Saskatchewan Saskatoon, Saskatchewan S7N5E2, Canada i Abstract This thesis presents a series of single-crystal electron paramagnetic resonance (EPR) studies on radiation-induced defects in selected silicate minerals, including apophyllites, prehnite, and hemimorphite, not only providing new insights to mechanisms of radiation-induced damage in minerals but also having direct relevance to remediation of heavy metalloid contamination and nuclear waste disposal. -
Mineralogy of Low Grade Metamorphosed Manganese Sediments of the Urals: Petrological and Geological Applications
Ore Geology Reviews 85 (2017) 140–152 Contents lists available at ScienceDirect Ore Geology Reviews journal homepage: www.elsevier.com/locate/oregeorev Mineralogy of low grade metamorphosed manganese sediments of the Urals: Petrological and geological applications Aleksey I. Brusnitsyn a,⁎, Elena V. Starikova b,c,IgorG.Zhukovd,e a Department of Mineralogy, St. Petersburg State University, Universitetskaya Emb. 7/9, St. Petersburg 199034, Russia b JSC “PolarGeo”, 24 line, 3–7, St. Petersburg 199106, Russia c Department of Geology of Mineral Deposits, St. Petersburg State University, Universitetskaya Emb. 7/9, St. Petersburg 199034, Russia d Institute of Mineralogy, Urals Branch, Russian Academy of Sciences, Miass, Chelyabinsk District 456317, Russia e National Research South Urals State University, Miass Branch, 8 July str., 10a, Miass, Chelyabinsk District, 456304, Russia article info abstract Article history: The paper describes mineralogy of the low grade metamorphosed manganese sediments, which occur in sedi- Received 25 September 2015 mentary complexes of the Pai Khoi Ridge and the Polar Urals and volcanosedimentary complexes of the Central Received in revised form 5 July 2016 and South Urals. The degree of metamorphism of the rocks studied corresponds to PT conditions of the prehnite– Accepted 7 July 2016 pumpellyite (deposits of Pai Khoi and Polar and South Urals) and green schist (deposits of the Central Urals) fa- Available online 9 July 2016 cies. One hundred and nine minerals were identified in the manganese-bearing rocks on the basis of optical and electron microscopy, X-ray diffraction, and microprobe analysis. According to the variations in the amount of Keywords: – – Manganese major minerals of the manganese rocks of the Urals, they are subdivided on carbonate (I), oxide carbonate sil- 2+ Deposit icate (II), and oxide–silicate (III) types.