Dats Correction Pen, Correction Fluid

Dats Pty Ltd Chemwatch Hazard Alert Code: 3

Chemwatch: 5202-68 Issue Date: 15/04/2016 Version No: 2.1.1.1 Print Date: 15/04/2016 Safety Data Sheet according to WHS and ADG requirements Initial Date: Not Available S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Dats Correction Pen, Correction Fluid Synonyms 51773, 51793, 51795, 52166, Item No: 1013

Proper shipping name FLAMMABLE LIQUID, N.O.S. (contains methylcyclohexane) Other means of Not Available identification

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified Stationery, office product. uses

Details of the supplier of the safety data sheet

Registered company Dats Pty Ltd name Address 1/51 Eastern Creek Drive NSW Eastern Creek 2766 Australia Telephone +61 2 9830 3100 Fax +61 2 9830 3111 Website Not Available Email Not Available

Emergency telephone number

Association / Glenn Duncan (Logistics Manager) Organisation Emergency telephone 0438 111 007 (24hrs) numbers Other emergency Not Available telephone numbers

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

Poisons Schedule Not Applicable Flammable Liquid Category 2, Skin Corrosion/Irritation Category 2, Specific target organ toxicity - single exposure Category Classification [1] 3 (narcotic effects), Aspiration Hazard Category 1, Acute Aquatic Hazard Category 2, Chronic Aquatic Hazard Category 2 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex Legend: VI

Label elements

GHS label elements

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SIGNAL WORD DANGER

Hazard statement(s)

H225 Highly flammable liquid and vapour.

H315 Causes skin irritation. H336 May cause drowsiness or dizziness.

H304 May be fatal if swallowed and enters airways. H411 Toxic to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.

P103 Read label before use. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P271 Use only outdoors or in a well-ventilated area. P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ventilating/lighting/intrinsically safe equipment. P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge. P261 Avoid breathing mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P362 Take off contaminated clothing and wash before reuse. P370+P378 In case of fire: Use alcohol resistant foam or normal protein foam for extinction. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P391 Collect spillage. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P332+P313 If skin irritation occurs: Get medical advice/attention.

Precautionary statement(s) Storage

P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name 108-87-2 51 methylcyclohexane 13463-67-7 40 titanium dioxide 24969-06-0 9 epichlorohydrin homopolymer

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SECTION 4 FIRST AID MEASURES

Description of first aid measures

If this product comes in contact with eyes: Wash out immediately with water. Eye Contact If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid Inhalation procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Ingestion Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice. Avoid giving milk or oils. Avoid giving alcohol.

Indication of any immediate medical attention and special treatment needed

Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanical means should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may be delayed up to 48 hours.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Special hazards arising from the substrate or mixture

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may Fire Incompatibility result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Fire Fighting Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water course. Liquid and vapour are highly flammable. Severe fire hazard when exposed to heat, flame and/or oxidisers. Vapour may travel a considerable distance to source of ignition. Fire/Explosion Hazard Heating may cause expansion or decomposition leading to violent rupture of containers. Combustion products include:, carbon dioxide (CO2), other pyrolysis products typical of burning organic material Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions. WARNING: Long standing in contact with air and light may result in the formationof potentially explosive peroxides.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

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Remove all ignition sources. Clean up all spills immediately. Minor Spills Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Major Spills May be violently or explosively reactive. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Safe handling Use in a well-ventilated area. Prevent concentration in hollows and sumps.

Store in original containers in approved flame-proof area. No smoking, naked lights, heat or ignition sources. Other information DO NOT store in pits, depressions, basements or areas where vapours may be trapped. Keep containers securely sealed.

Conditions for safe storage, including any incompatibilities

Packing as supplied by manufacturer. Plastic containers may only be used if approved for flammable liquid. Check that containers are clearly labelled and free from leaks. Suitable container For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an inner package, the can must have a screwed enclosure. For materials with a viscosity of at least 2680 cSt. (23 deg. C) For manufactured product having a viscosity of at least 250 cSt.

Storage Avoid reaction with oxidising agents incompatibility

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes Australia Exposure methylcyclohexane Methylcyclohexane 1610 mg/m3 / 400 ppm Not Available Not Available Not Available Standards Australia Exposure titanium dioxide Titanium dioxide 10 mg/m3 Not Available Not Available Not Available Standards

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3 methylcyclohexane Methylcyclohexane 400 ppm 400 ppm 10000 ppm titanium dioxide Titanium oxide; (Titanium dioxide) 10 mg/m3 10 mg/m3 10 mg/m3

Ingredient Original IDLH Revised IDLH methylcyclohexane 10,000 ppm 1,200 [LEL] ppm titanium dioxide N.E. mg/m3 / N.E. ppm 5,000 mg/m3 epichlorohydrin Not Available Not Available homopolymer

Exposure controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed Appropriate engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to engineering controls provide this high level of protection.

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The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment.

Personal protection

Safety glasses with side shields. Eye and face Chemical goggles. protection Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove Hands/feet protection material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final choice. Suitability and durability of glove type is dependent on usage.

Body protection See Other protection below Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Eyewash unit. · Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may Other protection produce static electricity. · For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets). · Non sparking safety or conductive footwear should be considered. Conductive footwear describes a boot or shoe with a sole made from a conductive compound chemically bound to the bottom components, for permanent control to electrically ground the foot an shall dissipate static electricity from the body to reduce the possibility of ignition of volatile compounds.

Thermal hazards Not Available

Respiratory protection Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Highly flammable white liquid with a slightly irritant odour.

Relative density Physical state Liquid Not Available (Water = 1) Partition coefficient Odour Not Available Not Available n-octanol / water Auto-ignition Odour threshold Not Available Not Available temperature (°C) Decomposition pH (as supplied) Not Available Not Available temperature Melting point / Not Available Viscosity (cSt) Not Available freezing point (°C) Initial boiling point Molecular weight Not Available Not Applicable and boiling range (°C) (g/mol) Flash point (°C) *-3 (methylcyclohexane) Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability HIGHLY FLAMMABLE. Oxidising properties Not Available Upper Explosive Limit Surface Tension Not Available Not Available (%) (dyn/cm or mN/m) Lower Explosive Limit Volatile Component Not Available Not Available (%) (%vol)

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Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Not Available pH as a solution (1%) Not Available (g/L) Vapour density (Air = Not Available VOC g/L Not Available 1)

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7 Unstable in the presence of incompatible materials. Chemical stability Product is considered stable. Hazardous polymerisation will not occur.

Possibility of See section 7 hazardous reactions

Conditions to avoid See section 7 Incompatible materials See section 7

Hazardous decomposition See section 5 products

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo. Inhaled Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervous depression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination. Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequences Ingestion may result. (ICSC13733) Considered an unlikely route of entry in commercial/industrial environments This material can cause inflammation of the skin on contact in some persons. Skin Contact The material may accentuate any pre-existing dermatitis condition Open cuts, abraded or irritated skin should not be exposed to this material Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce Eye transient discomfort characterised by tearing or conjunctival redness (as with windburn). Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Chronic Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of course. Due to almost complete elimination of methylcyclohexane from the body, the danger of chronic poisoning is relatively slight

Dats Correction Pen, TOXICITY IRRITATION Correction Fluid Not Available Not Available

TOXICITY IRRITATION

dermal (rat) LD50: >=3080 mg/kg[1] Nil reported

Inhalation (mouse) LC50: 36.9 mg/L/2H[2] methylcyclohexane Inhalation (mouse) LC50: 41.5 mg/L/2h[2]

Inhalation (rat) LC50: 33-42 mg/l4 h[1]

Oral (rat) LD50: >6160 mg/kg[1]

TOXICITY IRRITATION

Inhalation (rat) LC50: >2.28 mg/l4 h[1] Skin (human): 0.3 mg /3D (int)-mild *

Inhalation (rat) LC50: >3.56 mg/l4 h[1]

[1] titanium dioxide Inhalation (rat) LC50: >6.82 mg/l4 h

Inhalation (rat) LC50: 3.43 mg/l4 h[1]

Inhalation (rat) LC50: 5.09 mg/l4 h[1]

Oral (rat) LD50: >2000 mg/kg[1]

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epichlorohydrin TOXICITY IRRITATION homopolymer Not Available Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin. Exposure to titanium dioxide is via inhalation, swallowing or skin contact. When inhaled, it may deposit in lung tissue and TITANIUM DIOXIDE lymph nodes causing dysfunction of the lungs and immune system. Absorption by the stomach and intestines depends on the size of the particle. It penetrated only the outermost layer of the skin, suggesting that healthy skin may be an effective barrier.

WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans. * IUCLID

EPICHLOROHYDRIN No significant acute toxicological data identified in literature search. HOMOPOLYMER

Acute Toxicity Carcinogenicity Skin Reproductivity Irritation/Corrosion Serious Eye STOT - Single Damage/Irritation Exposure Respiratory or Skin STOT - Repeated sensitisation Exposure Mutagenicity Aspiration Hazard

Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source methylcyclohexane LC50 96 Fish 1.152mg/L 3 methylcyclohexane EC50 3 Algae or other aquatic plants 0.01050847mg/L 4 methylcyclohexane EC50 48 Crustacea 0.00147315mg/L 4 methylcyclohexane EC50 72 Algae or other aquatic plants 0.134mg/L 2 methylcyclohexane NOEC 72 Algae or other aquatic plants 0.0221mg/L 2 titanium dioxide LC50 96 Fish 9.214mg/L 3 titanium dioxide EC50 72 Algae or other aquatic plants 5.83mg/L 4 titanium dioxide NOEC 336 Fish 0.089mg/L 4 titanium dioxide EC50 48 Crustacea 1.23mg/L 2 titanium dioxide EC50 504 Crustacea 0.46mg/L 2 epichlorohydrin EC50 96 Algae or other aquatic plants 132.133mg/L 3 homopolymer epichlorohydrin LC50 96 Fish 0.450mg/L 3 homopolymer Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Legend: Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites.

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Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air methylcyclohexane LOW LOW

titanium dioxide HIGH HIGH epichlorohydrin LOW LOW homopolymer

Bioaccumulative potential

Ingredient Bioaccumulation methylcyclohexane LOW (BCF = 321)

titanium dioxide LOW (BCF = 10) epichlorohydrin LOW (LogKOW = 0.912) homopolymer

Mobility in soil

Ingredient Mobility methylcyclohexane LOW (KOC = 268)

titanium dioxide LOW (KOC = 23.74) epichlorohydrin MEDIUM (KOC = 2.443) homopolymer

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. A Hierarchy of Controls seems to be common - the user should investigate: Reduction Reuse Recycling Disposal (if all else fails) This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. Product / Packaging DO NOT allow wash water from cleaning or process equipment to enter drains. disposal It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material). Decontaminate empty containers.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM •3YE

Land transport (ADG)

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UN number 1993

Packing group II UN proper shipping FLAMMABLE LIQUID, N.O.S. (contains methylcyclohexane) name

Environmental hazard Not Applicable

Transport hazard Class 3 class(es) Subrisk Not Applicable

Special precautions Special provisions 274 for user Limited quantity 1 L

Air transport (ICAO-IATA / DGR)

UN number 1993 Packing group II

UN proper shipping Flammable liquid, n.o.s. * (contains methylcyclohexane) name Environmental hazard Not Applicable

ICAO/IATA Class 3 Transport hazard ICAO / IATA Subrisk Not Applicable class(es) ERG Code 3H

Special provisions A3 Cargo Only Packing Instructions 364 Cargo Only Maximum Qty / Pack 60 L Special precautions Passenger and Cargo Packing Instructions 353 for user Passenger and Cargo Maximum Qty / Pack 5 L Passenger and Cargo Limited Quantity Packing Instructions Y341 Passenger and Cargo Limited Maximum Qty / Pack 1 L

Sea transport (IMDG-Code / GGVSee)

UN number 1993 Packing group II UN proper shipping FLAMMABLE LIQUID, N.O.S. (contains methylcyclohexane) name Environmental hazard Marine Pollutant

Transport hazard IMDG Class 3 class(es) IMDG Subrisk Not Applicable

EMS Number F-E, S-E Special precautions Special provisions 274 for user Limited Quantities 1 L

Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

METHYLCYCLOHEXANE(108-87-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Exposure Standards Australia Inventory of Chemical Substances (AICS) Australia Hazardous Substances Information System - Consolidated Lists

TITANIUM DIOXIDE(13463-67-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS

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Australia Exposure Standards International Agency for Research on Cancer (IARC) - Agents Classified Australia Inventory of Chemical Substances (AICS) by the IARC Monographs

EPICHLOROHYDRIN HOMOPOLYMER(24969-06-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS)

National Inventory Status Australia - AICS Y Canada - DSL Y

Canada - NDSL N (epichlorohydrin homopolymer; methylcyclohexane) China - IECSC Y

Europe - EINEC / N (epichlorohydrin homopolymer) ELINCS / NLP Japan - ENCS Y

Korea - KECI Y New Zealand - NZIoC N (epichlorohydrin homopolymer)

Philippines - PICCS Y USA - TSCA Y

Y = All ingredients are on the inventory Legend: N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers

Name CAS No 100292-32-8, 101239-53-6, 116788-85-3, 12000-59-8, 12188-41-9, 12701-76-7, 12767-65-6, 12789-63-8, 1309-63-3, 1317-70-0, 1317-80-2, 1344-29-2, 13463-67-7, 185323-71-1, 185828-91-5, 188357-76-8, 188357-79-1, 195740-11-5, 221548-98-7, titanium dioxide 224963-00-2, 246178-32-5, 252962-41-7, 37230-92-5, 37230-94-7, 37230-95-8, 37230-96-9, 39320-58-6, 39360-64-0, 39379-02-7, 416845-43-7, 494848-07-6, 494848-23-6, 494851-77-3, 494851-98-8, 55068-84-3, 55068-85-4, 552316-51-5, 62338-64-1, 767341-00-4, 97929-50-5, 98084-96-9

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.

end of SDS