Staples - Correction Fluid 20ml and 25g
Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue: 12/03/2015 Revision date: 12/03/2015 : Version: 1.1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier Product form : Mixture Name : Staples - Correction Fluid 20ml and 25g Product code : CorrFluid
1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category : Consumer use,Professional use Use of the substance/mixture : Correction fluid
1.2.2. Uses advised against No additional information available
1.3. Details of the supplier of the safety data sheet Kores CE GmbH Muthgasse 36 1190 Vienna - Austria T +43 / 1 / 378 07 55 - F +43 / 1/ 318 55 77 [email protected] - www.kores.com
1.4. Emergency telephone number Emergency number : 112 (EU)
Country Organisation/Company Address Emergency number IRELAND (REPUBLIC National Poisons Information Centre Beaumont Hospital Beaumont Road : +353 1 8379964 OF) Beaumont Hospital 9 Dublin UNITED KINGDOM National Poisons Information Service (NHS http://www.npis.org 111 (England & Wales only) Direct) or 112 (EU) or 08454 24 24 24 (Scotland) SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Aquatic Chronic 2 H411
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F+; R12 R52/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects No additional information available
2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) :
GHS02 GHS09 Signal word (CLP) : Danger Hazard statements (CLP) : H225 - Highly flammable liquid and vapour H411 - Toxic to aquatic life with long lasting effects Precautionary statements (CLP) : P102 - Keep out of reach of children P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed
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P273 - Avoid release to the environment
2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients
3.1. Substance Not applicable
3.2. Mixture
Name Product identifier % Classification according to Directive 67/548/EEC cyclopentane (CAS No) 287-92-3 10-50 F; R11 (EC no) 206-016-6 R52/53 (EC index no) 601-030-00-2 Chalk (CAS No) 1317-65-3 20-50 Not classified substance with national workplace exposure limit(s) (BE, BG, ET, FR, (EC no) 215-279-6 GB, HU) titanium(IV) oxide (CAS No) 13463-67-7 15-40 Not classified substance with national workplace exposure limit(s) (AT, BE, BG, DK, (EC no) 236-675-5 ET, FR, GB, GR, IT, LT, LV, PT, SE) acetone (CAS No) 67-64-1 <10 F; R11 (EC no) 200-662-2 Xi; R36 (EC index no) 606-001-00-8 R66 R67
Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics (EC no) 920-750-0 <10 F; R11 (REACH-no) 01-2119473851-33 Xn; R65 R66 R67 N; R51/53
isobutyl methacrylate (CAS No) 97-86-9 <10 R10 substance with national workplace exposure limit(s) (AT, DK, ET, LT, SE) (EC no) 202-613-0 Xi; R36/37/38 (EC index no) 607-113-00-X R43 N; R50
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] cyclopentane (CAS No) 287-92-3 10-50 Flam. Liq. 2, H225 (EC no) 206-016-6 Aquatic Chronic 3, H412 (EC index no) 601-030-00-2 Chalk (CAS No) 1317-65-3 20-50 Not classified substance with national workplace exposure limit(s) (BE, BG, ET, FR, (EC no) 215-279-6 GB, HU) titanium(IV) oxide (CAS No) 13463-67-7 15-40 Not classified substance with national workplace exposure limit(s) (AT, BE, BG, DK, (EC no) 236-675-5 ET, FR, GB, GR, IT, LT, LV, PT, SE) acetone (CAS No) 67-64-1 <10 Flam. Liq. 2, H225 (EC no) 200-662-2 Eye Irrit. 2, H319 (EC index no) 606-001-00-8 STOT SE 3, H336 Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics (EC no) 920-750-0 <10 Flam. Liq. 2, H225 (REACH-no) 01-2119473851-33 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 isobutyl methacrylate (CAS No) 97-86-9 <10 Flam. Liq. 3, H226 substance with national workplace exposure limit(s) (AT, DK, ET, LT, SE) (EC no) 202-613-0 Skin Irrit. 2, H315 (EC index no) 607-113-00-X Eye Irrit. 2, H319 Skin Sens. 1, H317 STOT SE 3, H335 Aquatic Acute 1, H400
Full text of R- and H-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
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First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.
4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures
5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area.
6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if substance enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage
7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapours are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Take precautionary measures against static discharge. Use only non-sparking tools.
7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof Flame proof, lighting, electrical equipment and ventilation equipment. Storage conditions : Keep container tightly closed. Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, Heat and ignition sources. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s) No additional information available 13/03/2015 EN (English) 3/17
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SECTION 8: Exposure controls/personal protection
8.1. Control parameters
titanium(IV) oxide (13463-67-7) Austria Local name Titandioxid (Alveolarstaub) Austria MAK (mg/m³) 5 mg/m³ Austria MAK Short time value (mg/m³) 10 mg/m³ Belgium Local name Titane (dioxyde de) Belgium Limit value (mg/m³) 10 mg/m³ Bulgaria Local name Титанов диоксид, респирабилен прах Bulgaria OEL TWA (mg/m³) 10 mg/m³ Croatia Local name Titanov dioksid Croatia GVI (granična vrijednost izloženosti) (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust Denmark Local name Titandioxid, beregnet som Ti Denmark Grænseværdie (langvarig) (mg/m³) 6 mg/m³ Estonia Local name Titaanoksiid Estonia OEL TWA (mg/m³) 5 mg/m³ France Local name Titane (dioxyde de),en Ti France VME (mg/m³) 10 mg/m³ Greece OEL TWA (mg/m³) 10 mg/m³ Latvia Local name Titānadioksīds Latvia OEL TWA (mg/m³) 10 mg/m³ Lithuania Local name Titano dioksidas Lithuania IPRV (mg/m³) 5 mg/m³ Portugal Local name Dióxido de titânio Portugal OEL TWA (mg/m³) 10 mg/m³ Sweden Local name Titanium dioxide total dust Sweden nivågränsvärde (NVG) (ppm) 5 ppm United Kingdom WEL TWA (mg/m³) 10 mg/m³ Iceland Local name Títandíoxíð, sem Ti Iceland OEL (8 hours ref) (mg/m³) 6 mg/m³ Norway Local name Titandioksid Norway Gjennomsnittsverdier (AN) (mg/m³) 5 mg/m³ Switzerland Local name Dioxyde de titane Switzerland VME (mg/m³) 3 mg/m³ Australia Local name Titanium dioxide Australia TWA (mg/m³) 10 mg/m³ Australia Remark (AU) (a) USA - ACGIH Local name Titanium dioxide USA - ACGIH ACGIH TWA (mg/m³) 1 mg/m³ USA - ACGIH Remark (ACGIH) LRT irr; A3 USA - OSHA Local name Titanium dioxide (Total dust) USA - OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³
cyclopentane (287-92-3) Belgium Local name Cyclopentane Belgium Limit value (mg/m³) 1800 mg/m³ Belgium Limit value (ppm) 600 ppm Denmark Local name Cyclopentan Denmark Grænseværdie (langvarig) (mg/m³) 850 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 300 ppm France Local name Cyclopentane France VME (mg/m³) 1720 mg/m³
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cyclopentane (287-92-3) France VME (ppm) 600 ppm Greece OEL TWA (mg/m³) 1720 mg/m³ Greece OEL TWA (ppm) 600 ppm Ireland Local name Cyclopentane Ireland OEL (8 hours ref) (mg/m³) 1720 mg/m³ Ireland OEL (8 hours ref) (ppm) 600 ppm Portugal Local name Ciclopentano Portugal OEL TWA (ppm) 600 ppm Iceland Local name Sýklópentan Iceland OEL (8 hours ref) (mg/m³) 850 mg/m³ Iceland OEL (8 hours ref) (ppm) 300 ppm Switzerland Local name Cyclopentane Switzerland VME (mg/m³) 1720 mg/m³ Switzerland VME (ppm) 600 ppm Australia Local name Cyclopentane Australia TWA (mg/m³) 1720 mg/m³ Australia TWA (ppm) 600 ppm USA - ACGIH Local name Cyclopentane USA - ACGIH ACGIH TWA (ppm) 600 ppm USA - ACGIH ACGIH STEL (ppm) 600 ppm USA - ACGIH Remark (ACGIH) URT, eye, & skin irr; CNS impair
Chalk (1317-65-3) Belgium Local name Calcium (carbonate de) Belgium Limit value (mg/m³) 10 mg/m³ Bulgaria Local name Калциев карбонат Bulgaria OEL TWA (mg/m³) 10 mg/m³ Croatia Local name Limeston (sedimentna stijena) Croatia GVI (granična vrijednost izloženosti) (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust Estonia Local name Kaltsiumkarbonaat peentolm Estonia OEL TWA (mg/m³) 105 mg/m³ France VME (mg/m³) Calcium (carbonate de),10 mg/m³; France; Time- weighted average exposure limit 8 h; VL: Valeur non réglementaire indicative Hungary Local name KALCIUM-KARBONÁT Hungary AK-érték 10 mg/m³ United Kingdom WEL TWA (mg/m³) 10 mg/m³ Switzerland Local name Carbonate de calcium Switzerland VME (mg/m³) 3 mg/m³
isobutyl methacrylate (97-86-9) Austria Local name Isobutylmethacrylat Austria MAK (mg/m³) 300 mg/m³ Austria MAK (ppm) 50 ppm Austria MAK Short time value (mg/m³) 450 mg/m³ Austria MAK Short time value (ppm) 75 ppm Austria Remark (AT) Sh Denmark Local name Isobutylmethacrylat (2000) Denmark Grænseværdie (langvarig) (mg/m³) 145 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 25 ppm Estonia Local name Isobutüülmetakrülaat Estonia OEL TWA (mg/m³) 300 mg/m³ Estonia OEL TWA (ppm) 50 ppm
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isobutyl methacrylate (97-86-9) Estonia OEL STEL (mg/m³) 450 mg/m³ Estonia OEL STEL (ppm) 75 ppm Lithuania Local name Izobutilmetakrilatas Lithuania IPRV (mg/m³) 300 mg/m³ Lithuania IPRV (ppm) 50 ppm Lithuania TPRV (mg/m³) 450 mg/m³ Lithuania TPRV (ppm) 75 ppm Lithuania Remark (LT) J Slovenia Local name 2-metilpropilmetakrilat Slovenia OEL TWA (mg/m³) 300 mg/m³ Sweden Local name Isobutyl methacrylate Sweden nivågränsvärde (NVG) (mg/m³) 300 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 50 ppm Sweden kortidsvärde (KTV) (mg/m³) 450 mg/m³ Sweden kortidsvärde (KTV) (ppm) 75 ppm Iceland Local name Ísóbútýlmetakrýlat Iceland OEL (8 hours ref) (mg/m³) 290 mg/m³ Iceland OEL (8 hours ref) (ppm) 50 ppm Iceland Notes (IS) O Norway Local name Isobutylmetakrylat Norway Gjennomsnittsverdier (AN) (mg/m³) 300 mg/m³ Norway Gjennomsnittsverdier (AN) (ppm) 50 ppm Norway Merknader (NO) A
acetone (67-64-1) EU Local name Acetone EU IOELV TWA (mg/m³) 1210 mg/m³ EU IOELV TWA (ppm) 500 ppm Austria Local name Aceton Austria MAK (mg/m³) 1200 mg/m³ Austria MAK (ppm) 500 ppm Austria MAK Short time value (mg/m³) 4800 mg/m³ Austria MAK Short time value (ppm) 2000 ppm Belgium Local name Acétone Belgium Limit value (mg/m³) 1210 mg/m³ Belgium Limit value (ppm) 500 ppm Belgium Short time value (mg/m³) 2420 mg/m³ Belgium Short time value (ppm) 1000 ppm Bulgaria Local name Ацетон• Bulgaria OEL TWA (mg/m³) 600 mg/m³ Bulgaria OEL STEL (mg/m³) 1400 mg/m³ Croatia Local name Aceton Croatia GVI (granična vrijednost izloženosti) (mg/m³) 1210 mg/m³ Croatia GVI (granična vrijednost izloženosti) (ppm) 500 ppm Croatia KGVI (kratkotrajna granična vrijednost izloženosti) 3620 mg/m³ (mg/m³) Croatia KGVI (kratkotrajna granična vrijednost izloženosti) 1500 ppm (ppm) Croatia Naznake (HR) F, Xi EU* Czech Republic Local name Aceton Czech Republic Expoziční limity (PEL) (mg/m³) 800 mg/m³
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acetone (67-64-1) Czech Republic Expoziční limity (PEL) (ppm) 337 ppm Czech Republic Expoziční limity (NPK-P) (mg/m³) 1500 mg/m³ Czech Republic Expoziční limity (NPK-P) (ppm) 632 ppm Denmark Local name Acetone Denmark Grænseværdie (langvarig) (mg/m³) 600 mg/m³ Denmark Grænseværdie (langvarig) (ppm) 250 ppm Denmark Anmærkninger (DK) E Estonia Local name Atsetoon (2-propanoon) Estonia OEL TWA (mg/m³) 1210 mg/m³ Estonia OEL TWA (ppm) 500 ppm France Local name Acétone France VME (mg/m³) 1210 mg/m³ France VME (ppm) 500 ppm France VLE (mg/m³) 2420 mg/m³ France VLE (ppm) 1000 ppm Germany Local name Aceton Germany TRGS 900 Occupational exposure limit value (mg/m³) 1200 mg/m³ Germany TRGS 900 Occupational exposure limit value (ppm) 500 ppm Germany Remark (TRGS 900) DFG,EU Greece OEL TWA (mg/m³) 1780 mg/m³ Greece OEL STEL (mg/m³) 3560 mg/m³ Hungary Local name ACETON Hungary AK-érték 1210 mg/m³ Hungary CK-érték 2420 mg/m³ Hungary Megjegyzések (HU) i; EU1 Ireland Local name Acetone Ireland OEL (8 hours ref) (mg/m³) 1210 mg/m³ Ireland OEL (8 hours ref) (ppm) 500 ppm Ireland Notes (IE) IOELV Italy Local name Acetone Italy OEL TWA (mg/m³) 1210 mg/m³ Italy OEL TWA (ppm) 500 ppm Latvia Local name Acetons (2-propanons, dimetilketons) Latvia OEL TWA (mg/m³) 1210 mg/m³ Latvia OEL TWA (ppm) 500 ppm Lithuania Local name Acetonas Lithuania IPRV (mg/m³) 1210 mg/m³ Lithuania IPRV (ppm) 500 ppm Lithuania TPRV (mg/m³) 2420 mg/m³ Lithuania TPRV (ppm) 1000 ppm Luxembourg Local name Acétone Luxembourg OEL TWA (mg/m³) 1210 mg/m³ Luxembourg OEL TWA (ppm) 500 ppm Malta Local name Acetone Malta OEL TWA (mg/m³) 1210 mg/m³ Malta OEL TWA (ppm) 500 ppm Netherlands Local name Aceton Netherlands Grenswaarde TGG 8H (mg/m³) 1210 mg/m³
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acetone (67-64-1) Netherlands Grenswaarde TGG 8H (ppm) Aceton,501 ppm; Netherlands; Time-weighted average exposure limit 8 h; Public occupational exposure limit value Netherlands Grenswaarde TGG 15MIN (mg/m³) 2420 mg/m³ Netherlands Grenswaarde TGG 15MIN (ppm) Aceton,1002 ppm; Netherlands; Short time value; Public occupational exposure limit value Poland Local name Aceton Poland NDS (mg/m³) 600 mg/m³ Poland NDSCh (mg/m³) 1800 mg/m³ Portugal Local name Acetona Portugal OEL TWA (ppm) 500 ppm Portugal OEL STEL (ppm) 750 ppm Romania Local name Acetona Romania OEL TWA (mg/m³) 1210 mg/m³ Romania OEL TWA (ppm) 500 ppm Slovenia Local name aceton Slovenia OEL TWA (mg/m³) 1210 mg/m³ Slovenia OEL TWA (ppm) 500 ppm Sweden Local name Acetone Sweden nivågränsvärde (NVG) (mg/m³) 600 mg/m³ Sweden nivågränsvärde (NVG) (ppm) 250 ppm Sweden kortidsvärde (KTV) (mg/m³) 1200 mg/m³ Sweden kortidsvärde (KTV) (ppm) 500 ppm United Kingdom Local name Acetone United Kingdom WEL TWA (mg/m³) 1210 mg/m³ United Kingdom WEL TWA (ppm) 500 ppm United Kingdom WEL STEL (mg/m³) 3620 mg/m³ United Kingdom WEL STEL (ppm) 1500 ppm Iceland Local name Aseton (2-própanón) Iceland OEL (8 hours ref) (mg/m³) 600 mg/m³ Iceland OEL (8 hours ref) (ppm) 250 ppm Norway Local name Aceton Norway Gjennomsnittsverdier (AN) (mg/m³) 295 mg/m³ Norway Gjennomsnittsverdier (AN) (ppm) 125 ppm Switzerland Local name Acétone Switzerland VME (mg/m³) 1200 mg/m³ Switzerland VME (ppm) 500 ppm Switzerland VLE (mg/m³) 2400 mg/m³ Switzerland VLE (ppm) 1000 ppm Switzerland Remark (CH) 4x15 Australia Local name Acetone Australia TWA (mg/m³) 1185 mg/m³ Australia TWA (ppm) 500 ppm Australia STEL (mg/m³) 2375 mg/m³ Australia STEL (ppm) 1000 ppm USA - ACGIH Local name Acetone USA - ACGIH ACGIH TWA (ppm) 200 ppm USA - ACGIH ACGIH STEL (ppm) 500 ppm USA - ACGIH Remark (ACGIH) eye irr; CNS impair; BEI USA - OSHA Local name Acetone USA - OSHA OSHA PEL (TWA) (mg/m³) 2400 mg/m³ USA - OSHA OSHA PEL (TWA) (ppm) 1000 ppm
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8.2. Exposure controls Appropriate engineering controls : Provide adequate general and local exhaust ventilation. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : In case of repeated or prolonged contact wear gloves. Not required for normal conditions of use Eye protection : Not required for normal conditions of use Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state : Liquid
Colour : white.
Odour : characteristic.
Odour threshold : No data available pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 55 - 60 °C
Flash point : -42 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour
Vapour pressure : 40 hPa 20°C
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1,3 - 1,5 g/cm³ Solubility : insoluble in water.
Log Pow : No data available
Viscosity, kinematic : > 340 mm²/s 25°C
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 1 - 6,5 vol %
9.2. Other information No additional information available SECTION 10: Stability and reactivity
10.1. Reactivity No additional information available
10.2. Chemical stability Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions Not established.
10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials Strong acids. Strong bases.
10.6. Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
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SECTION 11: Toxicological information
11.1. Information on toxicological effects Acute toxicity : Not classified
titanium(IV) oxide (13463-67-7) LD50 oral rat > 10000 mg/kg (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure; Experimental value; > 5000 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 10000 mg/kg (Rabbit; Experimental value) LC50 inhalation rat (mg/l) > 6,8 mg/l/4h (Rat; Experimental value)
cyclopentane (287-92-3) LD50 oral rat 11400 mg/kg (Rat) LC50 inhalation rat (mg/l) 106 mg/l/4h (Rat)
Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2800 mg/kg LC50 inhalation rat (Vapours - mg/l/4h) > 23,3 mg/l/4h
Chalk (1317-65-3) LD50 oral rat 6450 mg/kg (Rat; Literature study)
isobutyl methacrylate (97-86-9) LD50 oral rat > 5000 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value; 9590 mg/kg bodyweight; Rat)
acetone (67-64-1) LD50 oral rat 5800 mg/kg (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rabbit 20000 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402) LC50 inhalation rat (mg/l) 71 mg/l/4h (Rat; Experimental value; 76 mg/l/4h; Rat; Experimental value) LC50 inhalation rat (ppm) 30000 ppm/4h (Rat; Experimental value)
Skin corrosion/irritation : Not classified Based on available data, the classification criteria are not met Serious eye damage/irritation : Not classified Based on available data, the classification criteria are not met Respiratory or skin sensitisation : Not classified Based on available data, the classification criteria are not met Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified Based on available data, the classification criteria are not met
Reproductive toxicity : Not classified Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : Not classified Based on available data, the classification criteria are not met
Specific target organ toxicity (repeated : Not classified exposure) Based on available data, the classification criteria are not met
Aspiration hazard : Not classified Based on available data, the classification criteria are not met
Kores - Correction Fluid Viscosity, kinematic > 340 mm²/s 25°C
Potential adverse human health effects and : Based on available data, the classification criteria are not met. symptoms
SECTION 12: Ecological information
12.1. Toxicity Ecology - water : Toxic to aquatic life with long lasting effects.
titanium(IV) oxide (13463-67-7) LC50 fish 1 > 1000 mg/l (96 h; Pimephales promelas)
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titanium(IV) oxide (13463-67-7) EC50 Daphnia 1 < 1000 mg/l (432 h; Daphnia magna; Static system) LC50 fish 2 > 1 g/l (96 h; Leuciscus idus) EC50 Daphnia 2 < 500 mg/l (720 h; Daphnia magna; Static system) Threshold limit algae 1 61 mg/l (72 h; Pseudokirchneriella subcapitata)
cyclopentane (287-92-3) LC50 fish 1 100 mg/l (96 h; Pisces) EC50 Daphnia 1 10,5 mg/l (48 h; Daphnia magna) Threshold limit algae 1 262 mg/l (72 h; Algae)
isobutyl methacrylate (97-86-9) LC50 fish 1 100 - 1000 mg/l (96 h; Pisces; GLP) LC50 other aquatic organisms 1 100 - 1000 mg/l (96 h) EC50 Daphnia 1 > 130 mg/l (48 h; Daphnia magna) LC50 fish 2 92 mg/l (48 h; Leuciscus idus) Threshold limit other aquatic organisms 1 100 - 1000,96 h Threshold limit algae 1 16 mg/l (72 h; Pseudokirchneriella subcapitata; GLP)
acetone (67-64-1) LC50 fish 1 6210 mg/l (96 h; Pimephales promelas; Nominal concentration) EC50 Daphnia 1 8800 mg/l (48 h; Daphnia pulex) LC50 fish 2 5540 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) TLM fish 1 13000 ppm (96 h; Gambusia affinis; Turbulent water) TLM fish 2 > 1000 ppm (96 h; Pisces) Threshold limit other aquatic organisms 1 3000 mg/l (Plankton) Threshold limit other aquatic organisms 2 28 mg/l (Protozoa) Threshold limit algae 1 7500 mg/l (Scenedesmus quadricauda; pH = 7) Threshold limit algae 2 3400 mg/l (48 h; Chlorella sp.)
12.2. Persistence and degradability Kores - Correction Fluid Persistence and degradability May cause long-term adverse effects in the environment.
titanium(IV) oxide (13463-67-7) Persistence and degradability Biodegradability: Not applicable. Low potential for Mobility in soil. Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable BOD (% of ThOD) Not applicable
cyclopentane (287-92-3) Persistence and degradability Not readily biodegradable in water. Biochemical oxygen demand (BOD) 0,56 g O₂/g substance
ThOD 3,42 g O₂/g substance BOD (% of ThOD) < % ThOD (5 day(s)) < 0.5
Chalk (1317-65-3) Persistence and degradability Biodegradability: Not applicable. Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable BOD (% of ThOD) Not applicable
isobutyl methacrylate (97-86-9) Persistence and degradability Readily biodegradable in water. Low potential for Mobility in soil. Photolysis in the air.
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acetone (67-64-1) Persistence and degradability Readily biodegradable in water. Biodegradable in soil. Biodegradable in soil in anaerobic condition. No (test)data available on mobility of the substance. Not established. Biochemical oxygen demand (BOD) 1,43 g O₂/g substance
Chemical oxygen demand (COD) 1,92 g O₂/g substance
ThOD 2,20 g O₂/g substance BOD (% of ThOD) (20 day(s)) 0.872
12.3. Bioaccumulative potential Kores - Correction Fluid Bioaccumulative potential Not established.
titanium(IV) oxide (13463-67-7) Bioaccumulative potential Not bioaccumulative.
cyclopentane (287-92-3) Log Pow 2,05 - 3 (Experimental value) Bioaccumulative potential Low bioaccumulation potential (Log Kow < 4).
Chalk (1317-65-3) Bioaccumulative potential Bioaccumulation: No data available.
isobutyl methacrylate (97-86-9) BCF fish 1 64 (Pisces) Log Pow 2,95 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method; 20 °C) Bioaccumulative potential Low bioaccumulation potential (Log Kow < 4).
acetone (67-64-1) BCF fish 1 0,69 (Pisces) BCF other aquatic organisms 1 3 Log Pow -0,24 (Test data) Bioaccumulative potential Not bioaccumulative. Not established.
12.4. Mobility in soil
cyclopentane (287-92-3) Surface tension 0,023 N/m
acetone (67-64-1) Surface tension 0,0237 N/m
12.5. Results of PBT and vPvB assessment No additional information available
12.6. Other adverse effects Additional information : Avoid release to the environment
SECTION 13: Disposal considerations
13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to a licensed waste centre in accordance with local/regional/national/international regulations. Additional information : Handle empty containers with care because residual vapours are flammable. Ecology - waste materials : Avoid release to the environment. European List of Waste (LoW) code : 20 01 27* - paint, inks, adhesives and resins containing dangerous substances
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H code : H3-A - ‘Highly flammable’ : — liquid substances and preparations having a flash point below 21 °C (including extremely flammable liquids), or — substances and preparations which may become hot and finally catch fire in contact with air at ambient temperature without any application of energy, or — solid substances and preparations which may readily catch fire after brief contact with a source of ignition and which continue to burn or to be consumed after removal of the source of ignition, or — gaseous substances and preparations which are flammable in air at normal pressure, or — substances and preparations which, in contact with water or damp air, evolve highly flammable gases in dangerous quantities.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number UN-No. (ADR) : 1993 UN-No. (IMDG) : 1993 UN-No.(IATA) : 1993 UN-No.(ADN) : 1993 UN-No. (RID) : 1993
14.2. UN proper shipping name Proper Shipping Name (ADR) : FLAMMABLE LIQUID, N.O.S. Proper Shipping Name (IMDG) : FLAMMABLE LIQUID, N.O.S. Proper Shipping Name (IATA) : Flammable liquid, n.o.s. Proper Shipping Name (ADN) : FLAMMABLE LIQUID, N.O.S. Proper Shipping Name (RID) : FLAMMABLE LIQUID, N.O.S. Transport document description (ADR) : UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS ; isobutyl methacrylate(97-86-9) ; cyclopentane(287-92-3) ; acetone(67-64-1)), 3, II, (D/E), ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 1993 FLAMMABLE LIQUID, N.O.S., 3, II, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 3 Danger labels (ADR) : 3
:
IMDG Transport hazard class(es) (IMDG) : 3 Danger labels (IMDG) : 3
:
IATA Transport hazard class(es) (IATA) : 3 Hazard labels (IATA) : 3
:
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ADN Transport hazard class(es) (ADN) : 3 Danger labels (ADN) : 3
:
RID Transport hazard class(es) (RID) : 3 Danger labels (RID) : 3
:
14.4. Packing group Packing group (ADR) : II Packing group (IMDG) : II Packing group (IATA) : II Packing group (ADN) : II Packing group (RID) : II
14.5. Environmental hazards Dangerous for the environment : Yes Marine pollutant : Yes Other information : No supplementary information available
14.6. Special precautions for user 14.6.1. Overland transport Classification code (ADR) : F1 Special provisions (ADR) : 274, 601, 640D Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions : T7 (ADR) Portable tank and bulk container special : TP1, TP8, TP28 provisions (ADR) Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation : S2, S20 (ADR) Hazard identification number (Kemler No.) : 33 Orange plates :
Tunnel restriction code (ADR) : D/E EAC code : •3YE
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14.6.2. Transport by sea Special provisions (IMDG) : 274 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP8, TP28 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-E Stowage category (IMDG) : B
14.6.3. Air transport PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provisions (IATA) : A3 ERG code (IATA) : 3H
14.6.4. Inland waterway transport Classification code (ADN) : F1 Special provisions (ADN) : 274, 61, 64D Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1 Carriage prohibited (ADN) : No Not subject to ADN : No
14.6.5. Rail transport Classification code (RID) : F1 Special provisions (RID) : 274, 601, 640D Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions : T7 (RID) Portable tank and bulk container special : TP1, TP8, TP28 provisions (RID) Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 33 Carriage prohibited (RID) : No
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
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3. Liquid substances or mixtures which are regarded as dangerous in accordance with Kores - Correction Fluid - cyclopentane - Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or acetone - Hydrocarbons, C7-C9, n-alkanes, categories set out in Annex I to Regulation (EC) No 1272/2008 isoalkanes, cyclics - isobutyl methacrylate 3.a. Substances or mixtures fulfilling the criteria for any of the following hazard classes or Kores - Correction Fluid - cyclopentane - categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 2.1 to 2.4, acetone - Hydrocarbons, C7-C9, n-alkanes, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 isoalkanes, cyclics - isobutyl methacrylate and 2, 2.15 types A to F 3.b. Substances or mixtures fulfilling the criteria for any of the following hazard classes or acetone - Hydrocarbons, C7-C9, n-alkanes, categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, isoalkanes, cyclics - isobutyl methacrylate 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 3.c. Substances or mixtures fulfilling the criteria for any of the following hazard classes or Kores - Correction Fluid - cyclopentane - categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 Hydrocarbons, C7-C9, n-alkanes, isoalkanes, cyclics - isobutyl methacrylate 40. Substances classified as flammable gases category 1 or 2, flammable liquids categories Kores - Correction Fluid - cyclopentane - 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with acetone - Hydrocarbons, C7-C9, n-alkanes, water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric isoalkanes, cyclics - isobutyl methacrylate solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not.
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany Water hazard class (WGK) : 3 - severe hazard to waters WGK remark : Classification water polluting based on the components in compliance with Verwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 27 July 2005 (Anhang 4) Storage class (LGK) : LGK 3 - Flammable liquids VbF class : A I - Liquids with a flashpoint below 21°C
15.2. Chemical safety assessment No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None.
Full text of R-, H- and EUH-phrases: Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Asp. Tox. 1 Aspiration hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation — Skin, category 1 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H335 May cause respiratory irritation H336 May cause drowsiness or dizziness H400 Very toxic to aquatic life 13/03/2015 EN (English) 16/17
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H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects R10 Flammable R11 Highly flammable R12 Extremely flammable R36 Irritating to eyes R36/37/38 Irritating to eyes, respiratory system and skin R43 May cause sensitisation by skin contact R50 Very toxic to aquatic organisms R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking R67 Vapours may cause drowsiness and dizziness F Highly flammable F+ Extremely flammable N Dangerous for the environment Xi Irritant Xn Harmful
SDS EU Mod H F (REACH ANNEX II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
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