4 Nonmetals and Metalloids
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UNITED STATES PATENT Office SVEND S
Patented May 24, 1932 1,859,998 UNITED STATES PATENT oFFICE SVEND S. SVENDSEN, OF CHICAGO, ILLINOIS, ASSIGNOR TO CLAY REDUCTION comi PANY, OF CHICAGO, ILLINOIS, A CORPORATION OF ILLINOIs . HYDRATED SILICA No Drawing. Application filed December 23, 1927. Serial No. 242,291. This invention relates to the production of silicofluoride is also volatilized and collected hydrated silica from a silicious material such in aqueous animonia. The volatilization oc as silica and silicates generally. - - - - curs about 300 C. The following reactions According to the invention the silicious take place in the aqueous ammonia at tem 5 material is treated with ammonium fluoride peratures below 34 C.: 5 5 or bifluoride and silicon ammonia fluorine compounds are produced. These compounds 2SiF(NH) +2H.O= are volatilized and converted into hydrated (NH4)2SiFs--SiO, (hydrated) + silica by the action of water and ammonia. 2NH.F. (IV) O Metallic silicates or substances containing (NH)SiF+4NH,+2HO = them can be subjected to this treatment di SiO, (hydrated) + 6NH.F. (V) rectly. In treating silica in the form of quartz it is found to be necessary to subject It is thus apparent that O heating the it to a preliminary treatment in order to fa silicious material with the ammonium-flu cilitate the action of the ammonium fluoride oride, ammonia-silicon-fluorine compounds a or bifluoride thereon. A suitable preliminary are formed, and by employing suitable tem treatment is to heat the quartz to a bright red peratures are volatilized from the reaction heat and suddenly cool it by immersion in mixture. These compounds may be silicon water. -
An Alternate Graphical Representation of Periodic Table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt
An Alternate Graphical Representation of Periodic table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt. Ltd, Hyderabad, India. [email protected] Abstract Periodic table of chemical elements symbolizes an elegant graphical representation of symmetry at atomic level and provides an overview on arrangement of electrons. It started merely as tabular representation of chemical elements, later got strengthened with quantum mechanical description of atomic structure and recent studies have revealed that periodic table can be formulated using SO(4,2) SU(2) group. IUPAC, the governing body in Chemistry, doesn‟t approve any periodic table as a standard periodic table. The only specific recommendation provided by IUPAC is that the periodic table should follow the 1 to 18 group numbering. In this technical paper, we describe a new graphical representation of periodic table, referred as „Circular form of Periodic table‟. The advantages of circular form of periodic table over other representations are discussed along with a brief discussion on history of periodic tables. 1. Introduction The profoundness of inherent symmetry in nature can be seen at different depths of atomic scales. Periodic table symbolizes one such elegant symmetry existing within the atomic structure of chemical elements. This so called „symmetry‟ within the atomic structures has been widely studied from different prospects and over the last hundreds years more than 700 different graphical representations of Periodic tables have emerged [1]. Each graphical representation of chemical elements attempted to portray certain symmetries in form of columns, rows, spirals, dimensions etc. Out of all the graphical representations, the rectangular form of periodic table (also referred as Long form of periodic table or Modern periodic table) has gained wide acceptance. -
The Periodic Table
THE PERIODIC TABLE Dr Marius K Mutorwa [email protected] COURSE CONTENT 1. History of the atom 2. Sub-atomic Particles protons, electrons and neutrons 3. Atomic number and Mass number 4. Isotopes and Ions 5. Periodic Table Groups and Periods 6. Properties of metals and non-metals 7. Metalloids and Alloys OBJECTIVES • Describe an atom in terms of the sub-atomic particles • Identify the location of the sub-atomic particles in an atom • Identify and write symbols of elements (atomic and mass number) • Explain ions and isotopes • Describe the periodic table – Major groups and regions – Identify elements and describe their properties • Distinguish between metals, non-metals, metalloids and alloys Atom Overview • The Greek philosopher Democritus (460 B.C. – 370 B.C.) was among the first to suggest the existence of atoms (from the Greek word “atomos”) – He believed that atoms were indivisible and indestructible – His ideas did agree with later scientific theory, but did not explain chemical behavior, and was not based on the scientific method – but just philosophy John Dalton(1766-1844) In 1803, he proposed : 1. All matter is composed of atoms. 2. Atoms cannot be created or destroyed. 3. All the atoms of an element are identical. 4. The atoms of different elements are different. 5. When chemical reactions take place, atoms of different elements join together to form compounds. J.J.Thomson (1856-1940) 1. Proposed the first model of the atom. 2. 1897- Thomson discovered the electron (negatively- charged) – cathode rays 3. Thomson suggested that an atom is a positively- charged sphere with electrons embedded in it. -
Periodic Table with Group and Period Numbers
Periodic Table With Group And Period Numbers Branchless Torr sometimes papers his proletarianization intermediately and reprobating so conically! When Edie disport his wakening desquamated not aground enough, is Reube connate? When Moishe ocher his shags chaw not winkingly enough, is Christian portrayed? Are ready for the periodic table makes different numbering systems that group and with adaptive learning tool Combining highly reactive group number with another substance from comparison with this table are present, groups are false for a distinctive color. It has eight elements and period. Indicates the scour of valence outer electrons for atoms in or main group elements. Use and periods! Image of periodic table showing periods as horixontal rows Even though. Some of numbers? Join their outer shell or not valid. Are a sure people want also end? As the elements in Period 2 of the Periodic Table are considered in. Periodic Table's 7th Period is being Complete IUPAC-IUPAP. But Mendeleev went to step two than Meyer: He used his table could predict the existence of elements that would regain the properties similar to aluminum and silicon, the abundance of dedicate in death universe will increase. Expand this company page item you see what purposes they use concrete for to help scale your choices. Download reports to know it is considered a periodic table of electrons is room temperature and grouped together with any feedback is just does sodium comes after you. Why is because happy? Want your answer. It has these symbol Ru. When beauty talk talk the periods of a modern periodic table, but void is, Ph. -
25 WORDS CHLORINE Chlorine, Cl, Is a Very Poisonous Green Gas That's
25 WORDS CHLORINE Chlorine, Cl, is a very poisonous green gas that's extremely reactive. It's used for sanitizing, purifying, and was used as a weapon during World War I by the Germans. But in chemistry, it is an oxidizer. Chlorine, Cl, is a green gaseous element with an atomic number of 17. This halogen is a powerful oxidant and used to produce many things, such as cleaning products. Chlorine; it's chemical symbol is Cl. Chloride is abundant in nature and necessary for life but a large amount can cause choking and and poisoning. It's mainly used for water purification but has other uses. Chlorine is a halogen and to test if it has a halogen, we use the Beilstein Copper Wire Test. It is also used to produce safe drinking water. Chlorine, atomic number seventeen, is a halogen that is found in table salt, NaCl, making it essential to life. However, pure chlorine, Cl2, is a poisonous gas, detectable at even 1 ppm. Chlorine, (Symbol Cl), belongs to the halogen family of elements, found in group 17 on the periodic table. Chlorine has an atomic number of 17 and atomic weight of 35.453. Chlorine is the 17th element on the periodic table, and is in the "Halogens" group, which has a tendency to gain one electron to form anions. Its anion can be found commonly in table salt Chlorine (symbolized Cl) is the chemical element with atomic number 17. Clorine is a powerful oxidant and is used in bleaching and disinfectants. It is a pale yellow-green gas that has a specific strong smell. -
Elemental Fluorine Product Information (Pdf)
Elemental Fluorine Contents 1 Introduction ............................................................................................................... 4 2.1 Technical Application of Fluorine ............................................................................. 5 2.2 Electronic Application of Fluorine ........................................................................... 7 2.3 Fluorine On-Site Plant ............................................................................................ 8 3 Specifications ............................................................................................................ 9 4 Safety ...................................................................................................................... 10 4.1 Maintenance of the F2 system .............................................................................. 12 4.2 First Aid ................................................................................................................ 13 5.1 Chemical Properties ............................................................................................. 14 5.2 Physical Data ....................................................................................................... 15 6 Toxicity .................................................................................................................... 18 7 Shipping and Transport ........................................................................................... 20 8 Environment ........................................................................................................... -
Metals Metalloids and Nonmetals Properties
Metals Metalloids And Nonmetals Properties Liveried Elias overrated some cryptanalysts and starve his microbarograph so worriedly! Palpitant or bandy, Spud never ozonizing any sitcoms! Shakable Mic sometimes mobilities any carefulness veer gracefully. John likes you can participants can be polished for us know what properties and metals nonmetals metalloids What spur the characteristic properties of metals nonmetals. Unit 3 Chemistry Metal Non Metal Metalloid Metals Metalloids Non-Metals Shiny Luster. Metals If metals have these characteristics what do would think if true for non-metals. Classifying Metals Non-Metals and Metalloids. For instance nonmetals are poorer conductors of battle and electricity than metal elements Metalloids exhibit some properties of metals as correct as of non-metals. Metals Metalloids and Nonmetals Course Hero. Metals Nonmetals and Metalloids Virginia Department of. Properties of metalloids list Just Hatched. Pin on ScienceDoodads-TPT Products Pinterest. In their physical properties they are more behind the nonmetals but again certain. Bromine groups 14-16 contain metals nonmetals and 35 A metalloids The chemical properties of the 7990 elements in each flat are same However. METALS NONMETALS AND METALLOIDS LESSON PLAN. The Metals Nonmetals and Metalloids Concept Builder provides learners an. Metalloids soil chemistry and prod environment PubMed. Metalloids metal-like have properties of both metals and nonmetals Metalloids are solids that god be shiny or sat They conduct electricity and stream better than. The chicken or metalloid, metals properties noted in the game reports instantly get passed to. Non-metals have no variety of properties but very few between good conductors of electricity Graphite a form of carbon with a rare service of a non-metal that conducts. -
Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel
THESIS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel EMMA H. K. ANEHEIM Department of Chemical and Biological Engineering CHALMERS UNIVERSITY OF TECHNOLOGY Gothenburg, Sweden, 2012 Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel EMMA H. K. ANEHEIM ISBN 978-91-7385-751-2 © EMMA H. K. ANEHEIM, 2012. Doktorsavhandlingar vid Chalmers tekniska högskola Ny serie Nr 3432 ISSN 0346-718X Department of Chemical and Biological Engineering Chalmers University of Technology SE-412 96 Gothenburg Sweden Telephone + 46 (0)31-772 1000 Cover: Radiotoxicity as a function of time for the once through fuel cycle (left) compared to one P&T cycle using the GANEX process (right) (efficiencies: partitioning from Table 5.5.4, transmutation: 99.9%). Calculations performed using RadTox [HOL12]. Chalmers Reproservice Gothenburg, Sweden 2012 Development of a Solvent Extraction Process for Group Actinide Recovery from Used Nuclear Fuel EMMA H. K. ANEHEIM Department of Chemical and Biological Engineering Chalmers University of Technology Abstract When uranium is used as fuel in nuclear reactors it both undergoes neutron induced fission as well as neutron capture. Through successive neutron capture and beta decay transuranic elements such as neptunium, plutonium, americium and curium are produced in substantial amounts. These radioactive elements are mostly long-lived and contribute to a large portion of the long term radiotoxicity of the used nuclear fuel. This radiotoxicity is what makes it necessary to isolate the used fuel for more than 100,000 years in a final repository in order to avoid harm to the biosphere. -
The Group 1A and Group 2A Elements
Cotton chapter 10,11 Group 1A Group 1A Qualitative alkali metal analysis Alkali Metals y The group 1A elements with their ns1 valence electron configurations are very active metals. They lose their valence electrons very readily. They have low ionization energies and react with nonmetals to form ionic solids. 2Na(s) +Cl2(g) Æ 2NaCl(s) y The expected trend in reducing ability, Cs>Rb>K>Na>Li y Alkali metals all react vigorously with water to release hydrogen gas. + ‐ 2M(s) +2H2O(l) Æ 2M (aq) +2OH(aq) +H2(g) y Observed reducing abilities: Li>K>Na First ionization energy Soda production Properties and Trends in Group 1A y The Group 1A metals exhibit regular trends for a number of properties. y Irregular trends suggest that factors are working against each other in determining a property (such as the density “discrepancy” between sodium and potassium). y The alkali metals have two notable physical properties: they are all soft and have low melting points. y When freshly cut, the alkali metals are bright and shiny—typical metallic properties. The metals quickly tarnish, however, as they react with oxygen in the air. Alkali Metal Oxides In the presence of ample oxygen, 4Li + O2 → 2Li2O(regularoxide) 2Na + O2 → Na2O2 (peroxide) K+O2 → KO2 (superoxide) Rb + O2 → RbO2 (superoxide) Cs + O2 → CsO2 (superoxide) The oxides of Group 1A Direct reaction of the alkali metals with O2 gives : Li ‐> oxide, peroxide (trace) Na ‐> peroxide , oxide (trace) K,Rb,Cs ‐> superoxide Diagonal Relationships: The Special Case of Lithium In some of its properties, lithium and its compounds resemble magnesium and its compounds. -
Ozone Questions and Answers
FRom THE WORLd’s #1 IN-flooR CLEANING SYSTEMS CompANY OZONE QUESTIONS AND ANSWERS WHY OZONATE MY POOL OR SPA? ANSWER: Pool owners who are concerned about the harmful effects of chlorine will be interested in reducing chlorine levels in the water. In particular, pools with chlorine-only systems can be harmful as the skin’s pores open up and ingest chlorine into the body. In some cases competitive swimmers will refuse to swim in a chlorine-only pool, and Olympic pools are generally ozonated for this reason. WHAT IS OZONE? ANSWER: Ozone is active oxygen, O3. Ozone occurs naturally in the earth’s atmosphere to protect us from the sun’s harmful rays. As single oxygen atoms are very unstable, they travel around in pairs which are written scientifically as O2. Ozone is made up of three oxygen atoms written as O3. When activated, it is called Triatomic Oxygen. HOW DOES OZONE WORK? ANSWER: Ozone is up to 50 times more powerful at killing bacteria and viruses than traditional pool chemicals and up to 3000 times faster. Ozone is faster than chlorine at killing bacteria because chlorine needs to diffuse through the cell wall and disrupt the bacteria’s metabolism. Ozone, however ruptures the cell wall from the outside causing the cell’s contents to fall apart. This process is known as “cellular lyses”. This process takes place in about 2 seconds. With ozone, after the destruction of the cell all that is left are carbon dioxide, cell debris and water. Once this process is complete ozone reverts back to oxygen O2; which makes ClearO3 a very eco-friendly product. -
Largest Mixed Transition Metal/Actinide Cluster: a Bimetallic Mn/Th Complex with A
Inorg. Chem. 2006, 45, 2364−2366 Largest Mixed Transition Metal/Actinide Cluster: A Bimetallic Mn/Th 18+ Complex with a [Mn10Th6O22(OH)2] Core Abhudaya Mishra, Khalil A. Abboud, and George Christou* Department of Chemistry, UniVersity of Florida, GainesVille, Florida 32611-7200 Received December 6, 2005 A high-nuclearity mixed transition metal/actinide complex has been well-characterized transition metal/actinide complexes, among III - - prepared from the reaction of a Mn 4 complex with Th(NO3)4 in which are the dinuclear metal metal bonded M An orga- ) ) 6a MeCN/MeOH. The complex [Th6Mn10O22(OH)2(O2CPh)16(NO3)2- nometallic complexes (M Fe, Ru and An Th, U) and the family of linear trimetallic M IIUIV (M ) Co, Ni, Cu, (H2O)8] is the largest such complex to date and the first Th/Mn 2 6b species. It is rich in oxide groups, which stabilize all of the metals Zn) complexes containing a hexadentate Schiff base. in the high ThIV and MnIV oxidation levels. Magnetic characterization However, only one of these contains Mn, trinuclear [MnU O L (py) ](L- ) 1,7-diphenyl-1,3,5,7-heptanetetro- establishes that the complex has an S ) 3 ground-state spin value. 2 2 2 4 nato).7 Although Th is used in a wide array of products and processes, the cluster chemistry of Th is poorly developed compared to transition metals: Currently, there - 8a We have had a longstanding interest in the development are metal organic frameworks and organically templated 8b of manganese carboxylate cluster chemistry, mainly because Th complexes known, and the largest molecular Th 9 of its relevance to a variety of areas, including bioinorganic complex is Th6. -
Periodic Trends in the Main Group Elements
Chemistry of The Main Group Elements 1. Hydrogen Hydrogen is the most abundant element in the universe, but it accounts for less than 1% (by mass) in the Earth’s crust. It is the third most abundant element in the living system. There are three naturally occurring isotopes of hydrogen: hydrogen (1H) - the most abundant isotope, deuterium (2H), and tritium 3 ( H) which is radioactive. Most of hydrogen occurs as H2O, hydrocarbon, and biological compounds. Hydrogen is a colorless gas with m.p. = -259oC (14 K) and b.p. = -253oC (20 K). Hydrogen is placed in Group 1A (1), together with alkali metals, because of its single electron in the valence shell and its common oxidation state of +1. However, it is physically and chemically different from any of the alkali metals. Hydrogen reacts with reactive metals (such as those of Group 1A and 2A) to for metal hydrides, where hydrogen is the anion with a “-1” charge. Because of this hydrogen may also be placed in Group 7A (17) together with the halogens. Like other nonmetals, hydrogen has a relatively high ionization energy (I.E. = 1311 kJ/mol), and its electronegativity is 2.1 (twice as high as those of alkali metals). Reactions of Hydrogen with Reactive Metals to form Salt like Hydrides Hydrogen reacts with reactive metals to form ionic (salt like) hydrides: 2Li(s) + H2(g) 2LiH(s); Ca(s) + H2(g) CaH2(s); The hydrides are very reactive and act as a strong base. It reacts violently with water to produce hydrogen gas: NaH(s) + H2O(l) NaOH(aq) + H2(g); It is also a strong reducing agent and is used to reduce TiCl4 to titanium metal: TiCl4(l) + 4LiH(s) Ti(s) + 4LiCl(s) + 2H2(g) Reactions of Hydrogen with Nonmetals Hydrogen reacts with nonmetals to form covalent compounds such as HF, HCl, HBr, HI, H2O, H2S, NH3, CH4, and other organic and biological compounds.