Power Modulation of Aluminium Reduction Cells – Operational Constraints and Process Limits

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Power Modulation of Aluminium Reduction Cells – Operational Constraints and Process Limits Power Modulation of Aluminium Reduction Cells – Operational Constraints and Process Limits Till Carsten Reek A thesis submitted in fulfillment of the requirements for the degree of Doctor of Philosophy School of Chemical Engineering Faculty of Engineering The University of New South Wales Sydney, Australia February 2015 Abstract iv Abstract Aluminium reduction cells are operated traditionally with an energy input as constant as possible. This is to reduce the variability of the process and simplify process monitoring and detection of abnormal situations. Recent advances in control systems have decreased the number and magnitude of process excursions keeping a vast majority of reduction cells within optimum performance. Reorientation in energy generation towards volatile renewable sources and changes in marketing mechanisms in Germany have led to an elevated and volatile electricity price resulting in an incentive to overcome the concept of constant energy input. This thesis postulates theoretical aspects and boundaries of both possibility and magnitude of power modulation. With this objective material and thermal balances are built including side reactions and material introduced at ambient temperature and heated to process temperature which is otherwise not affected by the process, but nevertheless inevitable for continued operation. These theories are compared with results found in experiments simulating aspects of power modulation undertaken on industrial reduction cells as well as during practical operation of a whole smelter with continuous power modulation. Key results of these investigations are: 1. Theoretical amount of extra energy that can be stored in the cell was determined to be 0.7 MWh for TRIMET Hamburg’s modified P19 cell.. This amount was experimentally verified. 2. Side ledge shows a distinctly different behaviour if in contact with molten bath or molten metal. Previous considerations always assumed equilibrium when discussing side ledge. Experimental results show that there are significant dynamics influencing the shape of side ledge. Abstract v 3. Cells show a significant capability of shedding additional heat in less than a day, stabilizing operation shortly after increased energy inputs. 4. Top cell cover contributes up to 50% to physical changes in the cell induced by energy imbalances. 5. For prolonged, severe energy reductions a shifting of work practices, especially anode change, is advisable to avoid superimposing effects reducing available energy in the cell needed for good operation. Basic approaches for modelling and incorporating effects of power modulation into process control algorithms are derived from experimental results. Changes in process efficiency found during continuous modulation are evaluated with regards to the economical impact on smelter operation showing that power modulation is a valid approach for reducing production costs. Other scenarios for generating revenue based on flexible smelter operation are highlighted. To extend the capabilities for power modulation, engineering solutions available today, such as shell heat exchangers and dampers to control off-gas volume, are discussed with respects to their ability to vary and control heat loss from a cell. It is shown that shell heat exchangers are the only applicable system to actively vary heat loss. The findings of this thesis can be used to optimize future designs and retrofits of cells by taking the variability of heat loss and the limits for energy storage into account to optimize the design to extend the possibilities for power modulation. Two areas of future work are identified in this thesis. On the one hand, new process control strategies have to be developed if cells are to be operated with Abstract vi the ability to vary heat loss. These strategies have to incorporate decision points when to increase and decrease heat loss intentionally. Also it has to be defined which continuous measurements to base this decision on and if new continuous measurements are needed. The second are of interest is the extension of existing FEM models to reflect the dynamics detailed in this thesis to help predict changes in the cell. Existing MHD models could be extended to study the ledge dynamics at various heat inputs to also help optimizing cell relining for ledge stability at variable heat input. Acknowledgement vii Acknowledgement “Remember that the most difficult tasks are consummated, not by a single explosive burst of energy or effort, but by the constant daily application of the best you have within you.” Og Mandino Such a work is not easily completed, especially if the work is done part time. For that reason there are many people to thank for their help, input and understanding. First and foremost I’d like to thank Martin Iffert at Trimet Aluminium SE who paved the way for this thesis with regards to the university as well as with regards to the subject. Also many thanks for showing me the wisdom of writing a thesis while commuting between two plants, Martin! My thanks to Jörg Prepeneit for the continuous support during my time working for him at Trimet Hamburg. Andreas Lützerath, Richard Meier and Helge Friedrich along with all the employees in the reduction department in Hamburg and especially in the process control department for bearing with me during all the experiments and trials necessary for this thesis. As they supported most of the practical work, this thesis would not have been possible without them. At UNSW I’d like to thank Barry Welch, Maria Skyllas-Kazacos and Jie Bao for the supervision of my work and their continuous input on the content of the thesis. If they wouldn’t have pushed for a lot of the additional content this work would have been considerably shorter. Also at UNSW I’d like to thank Winnie Cheung for helping me around campus and having a good time as well as for the continuous confirmation that actually writing a thesis seems to be an impossible task for everybody. My thanks to our post graduate coordinator, Ik Ling Lau, for all thankful reminders when I was approaching another deadline and helping with all the administrative issues that are hard to manage if not on-site. Last but not least I’d like thank my wife Monika. Without her support not only this thesis would have been an even more difficult task than it was already. Table of Contents viii Table of Contents 1 Introduction .................................................................................................. 1 2 Background .................................................................................................. 5 2.1 Overview of the Process ........................................................................ 5 2.1.1 Temperature and Electrolyte Composition ....................................... 8 2.1.2 Smelting, Energy Use and Metal Production. ................................ 10 2.1.3 Cell Voltage.................................................................................... 14 2.1.4 Basics of Control ............................................................................ 18 2.2 Evolution of cell designs ...................................................................... 22 2.2.1 Alumina Feeding Mechanisms ....................................................... 24 2.2.2 End to End vs. Side by Side .......................................................... 25 2.2.3 Development in Relining Materials and Cathode Grades .............. 27 2.2.4 Typical Modern Cell ....................................................................... 30 2.2.5 The P19 cell used at Trimet Hamburg ........................................... 30 2.3 Global Development of the Primary Aluminium Industry ...................... 34 2.3.1 Critical Resources of the Process .................................................. 35 2.3.2 Trends in Cost Structure ................................................................ 43 2.3.3 Environmental Influence ................................................................ 44 2.4 Changing Trends in Energy Generation............................................... 46 2.4.1 Hydro Power .................................................................................. 46 2.4.2 Nuclear, Coal and Oil Power .......................................................... 46 2.4.3 Geothermal Power ......................................................................... 47 2.4.4 Wind Power.................................................................................... 47 2.4.5 Solar Power ................................................................................... 48 Table of Contents ix 2.4.6 Summary on Renewable Energy Sources ..................................... 49 2.5 “Energiewende”, Energy Reorientation ................................................ 50 2.5.1 Change from Demand to Supply Driven Market............................. 50 2.5.2 Change from Centralized to Decentralized Power Generation ...... 52 2.5.3 Impact on Use Pattern ................................................................... 52 3 Material and Thermal Balances ................................................................. 54 3.1 Process Fundamentals ........................................................................ 54 3.1.1 Operational Constraints ................................................................. 54 3.1.2 The Challenge of Power Modulation .............................................. 62 3.2 Material and Thermal Balances ........................................................... 63 3.2.1
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