U.S. Scrap Tire Markets 2003 Edition Ii
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Reinforcement of Styrene Butadiene Rubber Employing Poly(Isobornyl Methacrylate) (PIBOMA) As High Tg Thermoplastic Polymer
polymers Article Reinforcement of Styrene Butadiene Rubber Employing Poly(isobornyl methacrylate) (PIBOMA) as High Tg Thermoplastic Polymer Abdullah Gunaydin 1,2, Clément Mugemana 1 , Patrick Grysan 1, Carlos Eloy Federico 1 , Reiner Dieden 1 , Daniel F. Schmidt 1, Stephan Westermann 1, Marc Weydert 3 and Alexander S. Shaplov 1,* 1 Luxembourg Institute of Science and Technology (LIST), 5 Avenue des Hauts-Fourneaux, L-4362 Esch-sur-Alzette, Luxembourg; [email protected] (A.G.); [email protected] (C.M.); [email protected] (P.G.); [email protected] (C.E.F.); [email protected] (R.D.); [email protected] (D.F.S.); [email protected] (S.W.) 2 Department of Physics and Materials Science, University of Luxembourg, 2 Avenue de l’Université, L-4365 Esch-sur-Alzette, Luxembourg 3 Goodyear Innovation Center Luxembourg, L-7750 Colmar-Berg, Luxembourg; [email protected] * Correspondence: [email protected]; Tel.: +352-2758884579 Abstract: A set of poly(isobornyl methacrylate)s (PIBOMA) having molar mass in the range of 26,000–283,000 g mol−1 was prepared either via RAFT process or using free radical polymerization. ◦ These linear polymers demonstrated high glass transition temperatures (Tg up to 201 C) and thermal Citation: Gunaydin, A.; stability (T up to 230 ◦C). They were further applied as reinforcing agents in the preparation of the Mugemana, C.; Grysan, P.; onset Eloy Federico, C.; Dieden, R.; vulcanized rubber compositions based on poly(styrene butadiene rubber) (SBR). The influence of the Schmidt, D.F.; Westermann, S.; PIBOMA content and molar mass on the cure characteristics, rheological and mechanical properties of Weydert, M.; Shaplov, A.S. -
Long Term Performance of Rubber in Seismic and Non-Seismic Bearings: a Literature Review
Long Term Performance of Rubber in Seismic and Non-Seismic Bearings: A Literature Review J. W. Martin us. DEPARTMENT OF COMMERCE National Institute of Standards and Technology Building and Fire Research Laboratory Gaithersburg, MD 20899 US. DEPARTMENT OF COMMERCE Robert A. Mosbacher, Secretary NATIONAL INSmUTE OF STANDARDS AND TECHNOLOGY UL John W. Lyons, Director 100 U56 NBT //4615 1991 NATIONAL INSTITUTE OF STANDARDS & TECHNOLOGY Research Information Center Gaithersburg, MD 20899 NISTIR 4613 / Long Term Performance of Rubber in Seismic and Non-Seismic Bearings: A Literature Review J. W. Martin U^. DEPARIMENT OF COMMERCE Nation^ Institute of Standards and Technoiogy Buiiding and Fire Research Laboratory Gaithersburg, MD 20899 June 1991 U.S. DEPARTMENT OF COMMERCE Robert A. Mosbacher, ScK:retary NATIONAL INSrmJTE OF STANDARDS AND TECHNOLOGY John W. Lyons, Director ABSTRACT The use of seismic isolation bearings to decouple buildings and lifeline structures from strong ground motion has received an increased amount of attention in recent years. While several types of seismic isolation bearings have been developed and proposed for use, the most common type is the laminated rubber (elastomeric) bearing. Because the design lifetime of these bearings is expected to be on the order of 50 to 100 years, the long-term performance of the rubber must be addressed. Therefore, a literature review was conducted to identify potential limits on the long-term performance of rubbers used in bearings. Several issues, including the need for consensus performance standards and for additional research on the effects of creep, aging, temperature, and high-energy radiation on the properties of rubber, were identified. -
Exxon™ Butyl Rubber Innertube Technology Manual
Exxon™ butyl rubber Exxon™ butyl rubber innertube technology manual Country name(s) 2 - Exxon™ butyl rubber innertube technology manual Exxon™ butyl rubber innertube technology manual - 3 Abstract Many bias and radial tires have innertubes. Radial truck tube-type tires are particularly common, and in many instances, such as in severe service, off-road applications, are preferred over tubeless radial tire constructions. The technology requirements for tubes for such tires is, in many respects, equally demanding when compared to that for the tire and wheel in the assembly. This manual has been prepared to describe how butyl rubber is important in meeting the demanding performance requirements of tire innertubes. Representative innertube compound formulations and compound properties are discussed along with typical processing guidelines of the compound in the manufacture of innertubes. Chlorobutyl rubber based compound formulations are also used in innertubes. Such innertubes show good heat resistance, durability, allow greater flexibility in compounding, and process equally well as regular butyl rubber tube compounds. An extensive discussion of bicycle tire innertubes has been included. Service conditions can range from simple commuting and recreation to high speed competitive sporting applications. Like automobile and truck tire innertubes, tubes for bicycle tires can thus have demanding performance requirements. Guidelines on troubleshooting provide a checklist for the factory process engineer to enhance manufacturing efficiency, high -
Use of Waste-Tire Materials in Architectural Application in Egypt International Journal of Chemtech Research
International Journal of ChemTech Research CODEN (USA): IJCRGG, ISSN: 0974-4290, ISSN(Online):2455-9555 Vol.9, No.12 pp 14-27, 2016 Use of Waste-Tire Materials in Architectural Application in Egypt Farrag, Nermin Mokhtar* Civil and Architectural Engineering Department, National Research Center, Egypt Abstract : With the increase in the production of the automobile, a lot of waste tire need to be disposed. Due to the reduction of available sites for waste disposal, a lot of countries forbid the disposal of waste tire rubber in landfills. Researches seek for a long time to find alternatives to the waste tire. Reusing and recycled waste tire rubber is the promising material in the Architectural Applications due to its light weight, flexibility, insulating properties, and energy absorption. There are many studies show that Egypt capable of competing within the global tires Reusing sector, the paper aims to how to improve this Sector to face its future challenges and attract Foreign Investment, many points should be considered such as improving the legislative framework, rising of awareness, developing business development service and, role of external institutionalization and financing. Keywords: tires wastes, Tires bales, sound barrier, landscaping mulch, Architectural Applications, reuse management. Introduction Recycling waste materials is not a new phenomenon, Fig.1. The reuse of solid waste can improve of environmental quality, contribute to solutions of urban issues, energy shortage, and waste disposal. Recycling provide job opportunities to the needy people, conserve finite resources and save the environment. Recycling of rubber receives less attention than other waste materials such as Paper, glass, steel cans due to its final product, quality and public acceptance, financial value, marketability, and margin of the earning. -
Model Vulcanization Systems for Butyl Rubber and Halobutyl Rubber Manual
Exxon™ butyl and halobutyl rubber Model vulcanization systems for butyl rubber and halobutyl rubber manual Country name(s) 2 - Model vulcanization systems for butyl rubber and halobutyl rubber manual Model vulcanization systems for butyl rubber and halobutyl rubber manual - 3 Abstract The vulcanization of isobutylene-co-isoprene rubber (IIR), brominated isobutylene-co-isoprene rubber (BIIR), chlorinated isobutylene-co-isoprene rubber (CIIR), and brominated isobutylene-co-para-methylstyrene elastomer (BIMSM) differs from that of general-purpose rubbers (GPR). Butyl rubber has approximately 2% unsaturation in the backbone. Halobutyl rubber (BIIR and CIIR) incorporates the butyl backbone with either bromine or chlorine, which significantly increases the chemical reactivity of the isoprenyl units located in the butyl backbone. Similarly, in BIMSM the bromine atom is bonded to the para-methylstyrene (PMS) group, thus affording the completely saturated polymer backbone a site of chemical reactivity. Utilization of the unique attributes of butyl rubber and halobutyl rubbers with their minimal backbone unsaturation and of BIMSM elastomers with no backbone unsaturation is found in many areas of industry. These properties are excellent vapor impermeation, resistance to heat degradation, and improved chemical resistance as compared to general-purpose rubbers. However, this low amount of reactivity requires special consideration to vulcanize these isobutylene-based polymers. The type of vulcanization system selected is a function of the composite structure in which it is used, and the cured product performance requirements. Therefore, vulcanization systems vary and may include an accelerator package along with resins, zinc oxide, zinc oxide and sulfur, and quinoid systems. This review will discuss the types and selection of appropriate vulcanization systems for isobutylene-based elastomers. -
Review of the Human Health & Ecological Safety of Exposure to Recycled Tire Rubber Found at Playgrounds and Synthetic Turf F
Review of the Human Health & Ecological Safety of Exposure to Recycled Tire Rubber found at Playgrounds and Synthetic Turf Fields Prepared for: Rubber Manufacturers Association Washington, DC Prepared by: Cardno ChemRisk Pittsburgh, PA August 1, 2013 Executive Summary Increasingly, tires that reach the end of their serviceable life are processed for beneficial reuse in novel applications. Some of these include soil and surface amendments at athletic fields, playground and garden mulch, and bound surfaces at playgrounds and athletic facilities. These modern artificial surfaces reduce the likelihood of personal injury, provide uniform recreational playing surfaces, promote energy conservation, eliminate pesticide and fertilizer usage, and support waste recycling. Tires are manufactured with a variety of materials and additives to ensure optimum product safety, reliability and performance. Some tire ingredients are considered to be human health hazards at exposure levels several orders of magnitude greater than possible from contact with finished consumer products. Accordingly, athletes, parents and other stakeholders have expressed questions and concerns about the potential for adverse human health or ecological effects from the use of recycled tires in sport surface or playground materials. The purpose of this report is to evaluate the health and ecological risks associated with the use of recycled tire rubber in consumer applications, particularly playgrounds and athletic fields. In doing so, a thorough review of available literature was conducted including studies from both advocates and opponents to the use of recycled tire materials. An examination of the weight of evidence across all of the available studies was conducted to enable a comprehensive assessment of potential risk. -
Evaluation of Health Effects of Recycled Waste Tires in Playground and Track Products
Contractor’s Report to the Board Evaluation of Health Effects of Recycled Waste Tires in Playground and Track Products Produced under contract by: January 2007 S TATE OF C ALIFORNIA Arnold Schwarzenegger Governor Linda S. Adams Secretary, California Environmental Protection Agency INTEGRATED WASTE MANAGEMENT BOARD Margo Reid Brown Wesley Chesbro Jeffrey Danzinger Board Chair Board Member Board Member Rosalie Mulé Gary Petersen Vacant Position Board Member Board Member Board Member Mark Leary Executive Director For additional copies of this publication, contact: Integrated Waste Management Board Public Affairs Office, Publications Clearinghouse (MS–6) 1001 I Street P.O. Box 4025 Sacramento, CA 95812-4025 www.ciwmb.ca.gov/Publications/ 1-800-CA-WASTE (California only) or (916) 341-6306 Publication #622-06-013 Copies of this document originally provided by CIWMB were printed on recycled paper containing 100 percent postconsumer fiber. Copyright © 2007 by the California Integrated Waste Management Board. All rights reserved. This publication, or parts thereof, may not be reproduced in any form without permission. Prepared as part of contract number IWM-C2070, $420,000 The California Integrated Waste Management Board (CIWMB) does not discriminate on the basis of disability in access to its programs. CIWMB publications are available in accessible formats upon request by calling the Public Affairs Office at (916) 341-6300. Persons with hearing impairments can reach the CIWMB through the California Relay Service, 1-800-735-2929. Disclaimer: This report to the Board was produced under contract by the Office of Environmental Health Hazard Assessment of California Environmental Protection Agency. The statements and conclusions contained in this report are those of the contractor and not necessarily those of the California Integrated Waste Management Board, its employees, or the State of California and should not be cited or quoted as official Board policy or direction. -
Relevance and Development of New Rubber Technology Competences for a Sustainable Automotive Industry
MASTER THESIS Relevance and development of new rubber technology competences for a sustainable automotive industry Marnick Olthuis Faculty of Engineering Technology (ET) Department of Mechanics of Solids, Surfaces and Systems (MS3) Elastomer Technology and Engineering (ETE) EXAMINATION COMMITTEE Prof. Dr. Anke Blume Asst. Prof. Dr. Fabian Grunert Asst. Prof. Dr. Laurent Warnet March 2020 Master graduation thesis Faculty of Engineering Technology Department of Mechanics of Solids, Surfaces and Systems (MS3) Elastomer Technology and Engineering (ETE) Title Relevance and development of new rubber technology competences for a sustainable automotive industry Student Marnick Olthuis (M.J.A.) 1380605 Supervisors Prof. Dr. Anke Blume Asst. Prof. Dr. Fabian Grunert Graduation committee Prof. Dr. Anke Blume Asst. Prof. Dr. Fabian Grunert Asst. Prof. Dr. Laurent Warnet ii Acknowledgement It has been a great learning experience to work for the DRIVES project in co-operation with Fabian Grunert and Anke Blume. I would like to express my gratitude towards them for facilitating this type of master graduation assignment. I would like to thank the staff and members of the Elastomer Technology and Engineering group. The working environment in the group is stimulating and the members are always available for helping you out. This open-minded mentality has been fruitful for thoroughly understanding the content and relevance of this graduation research project. Special thanks to Jungmin, who has been my personal rubber consultant for the past years. I want -
(Pp)/ Ground Tire Rubber
MANUFACTURING OF POLYPROPYLENE (PP)/ GROUND TIRE RUBBER (GTR) THERMOPLASTIC ELASTOMERS USING ULTRASONICALLY AIDED EXTRUSION A Thesis Presented to The Graduate Faculty of The University of Akron In Partial Fulfillment of the Requirements for the Degree Master of Science Jieruo Liu August, 2013 MANUFACTURING OF POLYPROPYLENE (PP)/ GROUND TIRE RUBBER (GTR) THERMOPLASTIC ELASTOMERS USING ULTRASONICALLY AIDED EXTRUSION Jieruo Liu Thesis Approved: Accepted ______________________ _______________________ Advisor Department Chair Dr. Avraam I. Isayev Dr. Robert Weiss _______________________ _______________________ Committee Member Dean of the College Dr. Thein Kyu Dr. Steven Cheng _______________________ ________________________ Committee Member Dean of the Graduate School Dr. Younjin Min Dr. George Newkome ________________________ Date ii ABSTRACT Compounding ground tire rubber (GTR) from whole waste tires with thermoplastic polyolefins, such as polypropylene (PP), is a possible way to manufacture thermoplastic elastomers and also to recycle waste tires to solve a major environmental problem. The present study looks at the effect of PP/GTR mixing ratio, rubber particle size, type of extruder, maleic anhydride grafted polypropylene (PP-g-MA) compatibilizer and ultrasound on the mechanical and rheological properties of PP and PP/GTR blends. PP and GTR were compounded at ratios of 30/70, 50/50 and 70/30. Whole tire GTR particles of 40 and 140 mesh sizes were used. Both the single screw extruder (SSE) and twin screw extruder (TSE) without and with ultrasonic treatment were applied. PP-g-MA compatibilizer was added to PP/GTR 50/50 blends at concentration of 10 wt %. Rheological, tensile and impact properties of uncompatibilized and compatibilized PP/GTR 50/50 blends were compared. -
Rubber Division ACS Best Paper Awards
Rubber Division ACS Best Paper Awards The Best Paper Committee of Rubber Division, ACS seeks to improve the quality of technical presentations by evaluating and publicly recognizing the authors of outstanding papers presented our technical meetings. Each year Committee Judges and peer attendees, rate each presentation on quality of content, originality, and clarity. Winning papers are selected from the top-rated presentations after further review by the Best Paper Committee. The Best Symposium is awarded to the symposium with the highest average paper ratings and best average attendance of presentations. Meeting Year Award Authors/Moderators Affiliation Title 196th, Fall 2019 Best Paper Steven K. Henning & Fabien Total Cray Valley Silane-Terminated Liquid Poly(butadienes) in Tread Formulations: A Mechanistic Study 196th, Fall 2019 Best Symposium Ed Terrill & Crittenden ARDL, Inc. & University of Testing and Predicting Behavior of Rubber and Tires Ohlemacher Akron 194th, Fall 2018 Best Paper Nuthathai Warasitthinon and Cooper Tire & Rubber Co. The Payne Effect: Primarily Polymer-Related or Filler-Related Phenomenon? Chris Robertson 194th, Fall 2018 Pest Symposum Cal Moreland & Sy Mowdood Michelin USA & Pirelli Advances in Material and Processes of Car and Truck Tires (Retired 192nd, 2017 Best Paper Anke Blume*, Katarzyna S. University of Twente, Influence of Network Structure on Elastomer Properties Fall Bandzierz, Louis A.E.M. Netherlands Reuvekamp, Jerzy Dryzek, Wilma K. Dierkes, Dariusz M. Bielinski 192nd, 2017 Best Symposium Crittenden Ohlemacher & University of Akron & Characterization Tools for Elastomers Fall Michael Warner CCSI, Inc. 190th, Fall 2016 Best Paper Peter Mott U.S. Naval Research The Thermomechanical Response of Polyurea Laboratory, Chemistry Division 190th, Fall 2016 Honorable Mention Steven K Henning and Taejun Yoo Total Cray Valley The Synthesis and Characterization of Farnesene-Based Oligomers 190th 2016 Best Symposium Sy Mowdood and J. -
Elastomeric Materials
ELASTOMERIC MATERIALS TAMPERE UNIVERSITY OF TECHNOLOGY THE LABORATORY OF PLASTICS AND ELASTOMER TECHNOLOGY Kalle Hanhi, Minna Poikelispää, Hanna-Mari Tirilä Summary On this course the students will get the basic information on different grades of rubber and thermoelasts. The chapters focus on the following subjects: - Introduction - Rubber types - Rubber blends - Thermoplastic elastomers - Processing - Design of elastomeric products - Recycling and reuse of elastomeric materials The first chapter introduces shortly the history of rubbers. In addition, it cover definitions, manufacturing of rubbers and general properties of elastomers. In this chapter students get grounds to continue the studying. The second chapter focus on different grades of elastomers. It describes the structure, properties and application of the most common used rubbers. Some special rubbers are also covered. The most important rubber type is natural rubber; other generally used rubbers are polyisoprene rubber, which is synthetic version of NR, and styrene-butadiene rubber, which is the most important sort of synthetic rubber. Rubbers always contain some additives. The following chapter introduces the additives used in rubbers and some common receipts of rubber. The important chapter is Thermoplastic elastomers. Thermoplastic elastomers are a polymer group whose main properties are elasticity and easy processability. This chapter introduces the groups of thermoplastic elastomers and their properties. It also compares the properties of different thermoplastic elastomers. The chapter Processing give a short survey to a processing of rubbers and thermoplastic elastomers. The following chapter covers design of elastomeric products. It gives the most important criteria in choosing an elastomer. In addition, dimensioning and shaping of elastomeric product are discussed The last chapter Recycling and reuse of elastomeric materials introduces recycling methods. -
Dry Rubber Technology (3 Days)
LEMBAGA GETAH MALAYSIA DRY RUBBER TECHNOLOGY (3 DAYS) INTRODUCTION METHODOLOGY Lectures, Discussions and Demonstrations Rubber Technology is a combination of art and science of processing, fabricating and converting rubbers into COURSE FEES useful products. Hence, it covers science/chemistry of 1. Local participant RM 200.00/person /day 2. Foreign participant RM 200.00/person / day materials, machines/equipments and quality assurance Meals ‐ RM 50.00 person / day in the rubber product manufacturing industry. Lodging ‐ RM 80.00 room / day This course is designed to give a basic understanding of VENUE dry rubber technology and its product manufacturing Akademi Hevea Malaysia processes to all personnel at the production and Lembaga Getah Malaysia supervisory levels who are directly and indirectly 47000 Sungai Buloh involved in the manufacture of rubber products. Selangor Darul Ehsan OBJECTIVES LECTURERS To acquire knowledge about various rubber Dr. Md Aris Ahmad. Rubber compounding and formulation designs, moulding and extrusion types, grades, characteristics and applications. studies. Involved in the Common Fund for Commodities (CFC) Project on Rubber‐rubber blends, particularly for NR / EPDM blends for Automotive To be familiar with compounding ingredients, applications. Also involved in the development of NR‐based their specifications and standards including their Thermoplastic materials. Chairman for MRB’s Malaysian Standard Technical Committee on General Rubber Goods and MRB MS ISO 9001 storage/shelf life, hazardous nature and safe Quality Audit Committee. He was the Head of the Advanced Rubber handling. Technology Unit, MRB and now a Research Fellow in MRB. Published more than 50 scientific papers presented at International To enhance the knowledge and skills of Rubber Conference , Refereed Journals , seminars , workshops, etc.