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Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Hidalgoite from the Tsumeb Mine, Namibia, and Hydrogen 2+ 3+ 5+ Bonding in the D G3 (T O4)(TO3OH)(OH)6 Alunite Structures
Mineralogical Magazine, August 2012, Vol. 76(4), pp. 839–849 Refinement of the crystal structure of zoned philipsbornite– hidalgoite from the Tsumeb mine, Namibia, and hydrogen 2+ 3+ 5+ bonding in the D G3 (T O4)(TO3OH)(OH)6 alunite structures M. A. COOPER AND F. C. HAWTHORNE* Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada [Received 19 January 2012; Accepted 19 March 2012; Associate Editor: G. Diego Gatta] ABSTRACT The crystal structure of zoned philipsborniteÀhidalgoite, hexagonal (rhombohedral), R3¯m, Z =3:a= ˚ ˚ 3 7.1142(4), c=17.0973(9) A, V=749.4(1) A , from the Tsumeb mine, Namibia, has been refined to R1 = 1.68% for 301 unique reflections collected on a Bruker D8 three-circle diffractometer equipped with a rotating-anode generator, multilayer optics and an APEX-II CCD detector. Chemical analysis by electron microprobe showed zoned crystals with a rim enriched in S and Fe relative to the core. The core composition is SO3 3.31, As2O5 30.57, Al2O3 23.05, FeO 1.44, PbO 33.94, H2Ocalc 9.58, total 2+ 2+ 101.79 wt.%, corresponding to Pb0.98(Al2.92Fe0.13)(AsO4)[(As0.72S0.27)O3.14(OH)0.85](OH)6; and the rim composition is SO3 8.88, As2O5 22.63, Al2O3 22.90, FeO 2.57, PbO 34.91, H2Ocalc 9.27, total 2+ 2+ 101.16 wt.%, corresponding to Pb0.99(Al2.85Fe0.23)(AsO4)[(As0.25S0.70)O3.30(OH)0.50](OH)6. PhilipsborniteÀhidalgoite has the alunite-type structure, sheets of corner-sharing octahedra, decorated on top and bottom by [(As,S)O4]and(AsO3OH) tetrahedra, that are linked into a three-dimensional structure by [12]-coordinated Pb2+ cations and hydrogen bonds. -
Annual Report 2010
Annual Report 2010 THE MACAULAY LAND USE RESEARCH INSTITUTE Annual Report 2010 The Macaulay Land Use Research Institute Annual Report 2010 ISBN: 978-0-902701-09-0 © The Macaulay Land Use Research Institue, September 2010 Craigiebuckler Aberdeen AB15 8QH Tel +44 (0) 1224 395000 Fax +44 (0) 1224 395010 macaulay.ac.uk A SCOTTISH CHARITABLE COMPANY LIMITED BY GUARANTEE - REGISTERED IN EDINBURGH – No SCO16190 REGISTERED OFFICE: MACAULAY LAND USE RESEARCH INSTITUTE, CRAIGIEBUCKLER, ABERDEEN, AB15 8QH SCOTLAND, CHARITY No: 11922, VAT REGISTRATION No: GB 266 8932 11 THE MACAULAY LAND USE RESEARCH INSTITUTE Executive Editor Professor Richard Aspinall Associate Editor Clare Neely Scientific Editors Dr Dick Birnie, Professor Colin Campbell, Dr Tony Craig, Dr Bob Ferrier, Dr Pete Goddard, Professor David Miller, Dr Robin Matthews, Professor Bill Slee Technical Editors Carol Bisset, Dr Andy Midwood Graphics and Production John Brown, Pat Carnegie Photography David Riley 3 4 THE MACAULAY LAND USE RESEARCH INSTITUTE The Macaulay Land Use Research Institute The Macaulay Land Use Research Institute is an international centre for scientific research and consultancy on the: l Economic, social and environmental consequences of rural land uses l Impacts of potential changes in policy, management, climate and pollution for the management of natural resources, and sustainable rural development Our research provides new and impartial knowledge that contributes to environmental and rural development policy, both in Scotland and internationally and we are committed to ensuring that this knowledge is shared and effectively communicated to all interested parties. We are internationally recognised as a leader in land use research and we transfer our skills and experience through collaborations within over 40 countries worldwide. -
A New Layered Silicate with an Original Type of Siliconðoxygen Networks O
ISSN 1063-7745, Crystallography Reports, 2008, Vol. 53, No. 2, pp. 206–215. © Pleiades Publishing, Inc., 2008. Original Russian Text © O.V. Yakubovich, W. Massa, N.V. Chukanov, 2008, published in Kristallografiya, 2008, Vol. 53, No. 2, pp. 233–242. STRUCTURE OF INORGANIC COMPOUNDS Crystal Structure of Britvinite [Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)]: A New Layered Silicate with an Original Type of Silicon–Oxygen Networks O. V. Yakubovicha, W. Massab, and N. V. Chukanovc a Lomonosov Moscow State University, Leninskie gory, Moscow, 119992 Russia e-mail: [email protected] b Philipps-Universität Marburg, Biegenstrasse 10, Marburg, D-35032 Germany c Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432 Russia Received January 25, 2007 Abstract—The crystal structure of a new mineral britvinite Pb7.1Mg4.5(Si4.8Al0.2O14)(BO3)(CO3)[(BO3)0.7(SiO4)0.3](OH, F)6.7 from the Lángban iron–manganese skarn deposit (Värmland, Sweden) is determined at T = 173 K using X-ray diffraction (Stoe IPDS diffractometer, λ α θ MoK , graphite monochromator, 2 max = 58.43°, R = 0.052 for 6262 reflections). The main crystal data are as follows: a = 9.3409(8) Å, b = 9.3579(7) Å, c = 18.8333(14) Å, α = 80.365(6)°, β = 75.816 + (6)°, γ = 3 ρ 3 59.870(5)°, V = 1378.7(2) Å , space group P1 , Z = 2, and calc = 5.42 g/cm . The idealized structural formula of the mineral is represented as [Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)]. -
Thirty-Fourth List of New Mineral Names
MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given. -
Yuksporite (K; Ba)(Na; Sr)Ca2(Si; Ti)4O11(F; OH) ² H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Orthorhombic
Yuksporite (K; Ba)(Na; Sr)Ca2(Si; Ti)4O11(F; OH) ² H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Orthorhombic. Point Group: n.d. Fibrous, scaly, or lamellar; in irregular aggregates, to 10 cm. Physical Properties: Hardness = 5 D(meas.) = 3.05(3) D(calc.) = [2.98] Optical Properties: Semitransparent. Color: Rose-red to straw-yellow. Optical Class: Biaxial (+). Pleochroism: Marked; X = pale rose-yellow; Y = Z = rose-yellow. ® = 1.644(2) ¯ = n.d. ° = 1.660(2) 2V(meas.) = 46±{76± Cell Data: Space Group: n.d. a = 24.869(8) b = 16.756(6) c = 7.057(3) Z = 10 X-ray Powder Pattern: Khibiny massif, Russia. 2.778 (10), 3.00 (9), 1.786 (9), 3.10 (8), 3.05 (8), 1.888 (7), 2.92 (6) Chemistry: (1) (2) (1) (2) SiO2 40.92 38.40 BaO 8.60 TiO2 11.00 Na2O 7.94 3.84 Al2O3 0.07 K2O 12.57 6.15 Fe2O3 9.10 0.75 F 3.05 MnO 0.91 0.29 Cl 0.80 + MgO 0.42 H2O 2.20 CaO 20.56 18.90 H2O 8.52 SrO 5.87 O = (F; Cl) 1.46 ¡ 2 Total 100.94 [98.46] (1) Khibiny massif, Russia. (2) Murun massif, Russia; original total given as 99.07%, 3+ corresponds to (K0:70Ba0:30)§=1:00(Na0:66Sr0:30)§=0:96(Ca1:80Ti0:19Fe0:06Mn0:02)§=2:07 (Si3:42Ti0:57Al0:01)§=4:00O11[F0:86Cl0:12(OH)0:02]§=1:00 ² 0:6H2O: Occurrence: In veins in nepheline syenite in a di®erentiated alkalic massif (Khibiny massif, Russia). -
L'leve~Th List of New Mineral Na~Es. ~
556 L'leve~th list of new mineral na~es. ~ By L. J. SPENCER, M.A., Sc.D., F.R.S. Keeper of Minerals ia the British Museum (Natural History). [Communicated June 12~ 1928.] Ajkaite. (L. Zeehmeister, Math. Termdszettud. ~:rtesitS, Badapest, 1926, vol. 43, p. 332 (ajkait); L. Zechmeister and V. Vrab~ly, Per. Deutsch. Chem. Gesell., 1926, vol. 59, Abt. B, p. 1426). The same as ajkite (Bull. Soc. Min. France, 1878, vol. 1, p. 126 ; abstract from... ?). A fossil resin containing 1-5 ~ sulphur and no succinic acid, from Ajka, com. Veszpr~m, Hungary. [M.A. 3-362.] Albiclase. A. N. Winchell, 1925. Journ. Geol. Chicago, vol. 83, p. 726 ; Elements of optical mineralogy, 2nd edit., 1927, pt. 2, p. 319. P. Niggli, Lehrbuch Min., 1926, vol. 2, p. 536 (Albiklas). A contrac- tion of albite-oligoclase for felspars of the plagioclase series ranging in composition from Ab~Anlo to AbsoAn~o. Allite. tL Harrassowitz, 1926. Laterit, Material und Versuch erdgesehichtlicher Auswertung, Berlin 1926, p. 255 (Allit, plur. Allite). A rock-name to include both bauxite and laterite. Later (Metall und Erz, Halle, ]927, vol. 24, p. 589) bauxite with A1208. H~O is distinguished as monohydrallite (Monohydrallit) and laterite with Al~0s.3H20 as trihydrallite (Trihydrallit). These, although suggestive of mineral- names (and given so i~ error in Chem. Zentr., 1926, vol. 1, p. 671), are proposed as rock-names ; from aluminium and M~o~. Similarly, siallites (1926, p. 252, Siallit, from Si, A1, M0o~), to include kaolinite and allo- phanite, are rocks composed of the aluminium silicates kaolin and allophane. -
Design Rules for Discovering 2D Materials from 3D Crystals
Design Rules for Discovering 2D Materials from 3D Crystals by Eleanor Lyons Brightbill Collaborators: Tyler W. Farnsworth, Adam H. Woomer, Patrick C. O'Brien, Kaci L. Kuntz Senior Honors Thesis Chemistry University of North Carolina at Chapel Hill April 7th, 2016 Approved: ___________________________ Dr Scott Warren, Thesis Advisor Dr Wei You, Reader Dr. Todd Austell, Reader Abstract Two-dimensional (2D) materials are championed as potential components for novel technologies due to the extreme change in properties that often accompanies a transition from the bulk to a quantum-confined state. While the incredible properties of existing 2D materials have been investigated for numerous applications, the current library of stable 2D materials is limited to a relatively small number of material systems, and attempts to identify novel 2D materials have found only a small subset of potential 2D material precursors. Here I present a rigorous, yet simple, set of criteria to identify 3D crystals that may be exfoliated into stable 2D sheets and apply these criteria to a database of naturally occurring layered minerals. These design rules harness two fundamental properties of crystals—Mohs hardness and melting point—to enable a rapid and effective approach to identify candidates for exfoliation. It is shown that, in layered systems, Mohs hardness is a predictor of inter-layer (out-of-plane) bond strength while melting point is a measure of intra-layer (in-plane) bond strength. This concept is demonstrated by using liquid exfoliation to produce novel 2D materials from layered minerals that have a Mohs hardness less than 3, with relative success of exfoliation (such as yield and flake size) dependent on melting point. -
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NEW MINERAL NAN,{ES Gallite H. SrnuNz, B. H. Grran, exo E. Snnr,rcrn. Gallit, cuGaS:, das erste selbstandige Galli- ummineral, und seine verbreitung in den Erzen der Tsumeb- uncl Kipushi-Mine. NeuesJahrb. Mineral , Monotslt- 1958, No. 1l-1'2,241-264. Galium has long been known to be present in amounts up to 1,.85/6in germanite from Tsumeb and various unidentified minerals have been thought to be gallium minerals. This is now proved to be the case. Analyses by W. Reiner gave Cu 23'52, 35 52; Pb 14.25,3.00; Zn 3'36' 2'76; Fe 3'41, 4.93; Ge 0 66, 0 45; Ga 23.O6,17.11; As 1.00,0 90; S 24.16,27.90;SiOr 4'05, 4 92, sum 97.+7, 97.4g7o. Recalculation, deducting (based on microscopic counts) quartz 4'0, 49; renierite 13.4, 8.0; tennantite 1 0, 0.4; galena 14.0, 1'7; bornite 5 6; chalcocite -,0.5; 2.0 give for , 5.3; digenite pyrite 0.8; and "arsenate" thegallite Cr-26.9,30.8;Pb 3.0,2.3;2n4.6,4.4;Fe2.7,4 9; Ga35.4,29.2;527.4,284/6' corresponclingto CuGaSr, with some substitution of Cu or Ga by Fe and Zn The mineral was also synthesized by passing HuS over an equimolar mixture of Ga:Or and CuzO at 400'; the product gave an r-ray pattern identical with that of the mineral' X-ray study by single crystal and powcler photographs shorvedgallite to be tetragonal, structure like that of chalcopyrite, space group probably Dzal2-142d. -
Glossary of Obsolete Mineral Names
Uaranpecherz = uraninite, László 282 (1995). überbasisches Cuprinitrat = gerhardtite, Hintze I.3, 2741 (1916). überbrannter Amethyst = heated 560ºC red-brown Fe-rich quartz, László 11 (1995). Überschwefelblei = galena + anglesite + sulphur-α, Chudoba RI, 67 (1939); [I.3,3980]. uchucchacuaïte = uchucchacuaite, MR 39, 134 (2008). uddervallite = pseudorutile, Hey 88 (1963). uddevallite = pseudorutile, Dana 6th, 218 (1892). uddewallite = pseudorutile, Des Cloizeaux II, 224 (1893). udokanite = antlerite, AM 56, 2156 (1971); MM 43, 1055 (1980). uduminelite (questionable) = Ca-Al-P-O-H, AM 58, 806 (1973). Ueberschwefelblei = galena + anglesite + sulphur-α, Egleston 132 (1892). Uekfildit = wakefieldite-(Y), Chudoba EIV, 100 (1974). ufalit = upalite, László 280 (1995). uferite = davidite-(La), AM 42, 307 (1957). ufertite = davidite-(La), AM 49, 447 (1964); 50, 1142 (1965). U-free thorite = huttonite, Clark 303 (1993). U-galena = U-rich galena, AM 20, 443 (1935). ugandite = bismutotantalite, MM 22, 187 (1929). ughvarite = nontronite ± opal-C, MAC catalog 10 (1998). ugol = coal, Thrush 1179 (1968). ugrandite subgroup = uvarovite + grossular + andradite ± goldmanite ± katoite ± kimzeyite ± schorlomite, MM 21, 579 (1928). uhel = coal, Thrush 1179 (1968). Uhligit (Cornu) = colloidal variscite or wavellite, MM 18, 388 (1919). Uhligit (Hauser) = perovskite or zirkelite, CM 44, 1560 (2006). U-hyalite = U-rich opal, MA 15, 460 (1962). Uickenbergit = wickenburgite, Chudoba EIV, 100 (1974). uigite = thomsonite-Ca + gyrolite, MM 32, 340 (1959); AM 49, 223 (1964). Uillemseit = willemseite, Chudoba EIV, 100 (1974). uingvárite = green Ni-rich opal-CT, Bukanov 151 (2006). uintahite = hard bitumen, Dana 6th, 1020 (1892). uintaite = hard bitumen, Dana 6th, 1132 (1892). újjade = antigorite, László 117 (1995). újkrizotil = chrysotile-2Mcl + lizardite, Papp 37 (2004). új-zéalandijade = actinolite, László 117 (1995). -
A Specific Gravity Index for Minerats
A SPECIFICGRAVITY INDEX FOR MINERATS c. A. MURSKyI ern R. M. THOMPSON, Un'fuersityof Bri.ti,sh Col,umb,in,Voncouver, Canad,a This work was undertaken in order to provide a practical, and as far as possible,a complete list of specific gravities of minerals. An accurate speciflc cravity determination can usually be made quickly and this information when combined with other physical properties commonly leads to rapid mineral identification. Early complete but now outdated specific gravity lists are those of Miers given in his mineralogy textbook (1902),and Spencer(M,i,n. Mag.,2!, pp. 382-865,I}ZZ). A more recent list by Hurlbut (Dana's Manuatr of M,i,neral,ogy,LgE2) is incomplete and others are limited to rock forming minerals,Trdger (Tabel,l,enntr-optischen Best'i,mmungd,er geste,i,nsb.ildend,en M,ineral,e, 1952) and Morey (Encycto- ped,iaof Cherni,cal,Technol,ogy, Vol. 12, 19b4). In his mineral identification tables, smith (rd,entifi,cati,onand. qual,itatioe cherai,cal,anal,ys'i,s of mineral,s,second edition, New york, 19bB) groups minerals on the basis of specificgravity but in each of the twelve groups the minerals are listed in order of decreasinghardness. The present work should not be regarded as an index of all known minerals as the specificgravities of many minerals are unknown or known only approximately and are omitted from the current list. The list, in order of increasing specific gravity, includes all minerals without regard to other physical properties or to chemical composition. The designation I or II after the name indicates that the mineral falls in the classesof minerals describedin Dana Systemof M'ineralogyEdition 7, volume I (Native elements, sulphides, oxides, etc.) or II (Halides, carbonates, etc.) (L944 and 1951). -
New Mineral Names*
American Mineralogist, Volume 62, pages 1259-1262, 1977 NewMineral Names* MtcHe.rr-Flrlscsnn, Lours J. CesRrAND ADoLF Pe.ssr Franzinite* Six microprobe analyses gave (range and av.): AsrOu 44.96-45.68,45.36; CuO 16.84-20.22,18.81; ZnO 16.78-18.57, Stefano Merlino and Paolo Orlandi (1977)Franzinite, a new min- 17.90;CdO l3 58-14.93,14.08; CaO 0.41-l.ll' 0.80; PbO 0.14- eral phase from Pitigliano,ltaly. Neues Jahrb. Mineral. Mon- 1.42,0.63: MnO 0.'79-1.27,1.07; sum 97 8l-99 54' 98.65 percent, atsh., 163-167. corresponding to (Cu,Zn,Cd).(AsOa), with Cu:Zn:Cd : 1.19: Microchemical analysis gave SiO, 32.44, Al2Os 25.21, Fe"O" Lll:0.55. The mineral is readily dissolvedby concentratedacids 0.04,MgO 0.14,CaO 12.08,Na,O 11.50,K,O 4.24,SOa 10.65, CO, X-ray study showsthe mineral to be monoclinic,space group 12' 154, Cl 036,H,O 1.88,sum 100.08- (O:Cl,) 0.08 : 100.00 Im. or 12/m, a ll.65, b 12.68,c 6.87(all + 0.01A)' B 98 95 + 0.05'' percent. "SiO, and AlrO, were determined by X-ray fluorescence, Z = 6, G calc 4.95 The strongest X-ray lines (46 given) are 6.41 (vvs) account being taken of the proper correction factor for S and Cl (MS) (020, l0T), 3.29 (vSXll2), 2.876 (vSX400), 2.79s and assuming that the weight percentages sum up to 100 0." (222, 321, 240), 1.644(MS).