Acutely Hazardous Wastes
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12.18 Carbofuran Carbofuran (CAS No
12. CHEMICAL FACT SHEETS WHO (2003) Cadmium in drinking-water. Background document for preparation of WHO Guidelines for drinking-water quality. Geneva, World Health Organization (WHO/SDE/WSH/03.04/80). 12.18 Carbofuran Carbofuran (CAS No. 1563-66-2) is used worldwide as a pesticide for many crops. Residues in treated crops are generally very low or not detectable. The physical and chemical properties of carbofuran and the few data on occurrence indicate that drink- ing-water from both groundwater and surface water sources is potentially the major route of exposure. Guideline value 0.007 mg/litre Occurrence Has been detected in surface water, groundwater and drinking-water, generally at levels of a few micrograms per litre or lower; highest concentration (30 mg/litre) measured in groundwater ADI 0.002 mg/kg of body weight based on a NOAEL of 0.22 mg/kg of body weight per day for acute (reversible) effects in dogs in a short-term (4- week) study conducted as an adjunct to a 13-week study in which inhibition of erythrocyte acetylcholinesterase activity was observed, and using an uncertainty factor of 100 Limit of detection 0.1 mg/litre by GC with a nitrogen–phosphorus detector; 0.9 mg/litre by reverse-phase HPLC with a fluorescence detector Treatment achievability 1 mg/litre should be achievable using GAC Guideline derivation • allocation to water 10% of ADI • weight 60-kg adult • consumption 2 litres/day Additional comments Use of a 4-week study was considered appropriate because the NOAEL is based on a reversible acute effect; the NOAEL will also be protective for chronic effects. -
Carbamate Pesticides Aldicarb Aldicarb Sulfoxide Aldicarb Sulfone
Connecticut General Statutes Sec 19a-29a requires the Commissioner of Public Health to annually publish a list setting forth all analytes and matrices for which certification for testing is required. Connecticut ELCP Drinking Water Analytes Revised 05/31/2018 Microbiology Total Coliforms Fecal Coliforms/ E. Coli Carbamate Pesticides Legionella Aldicarb Cryptosporidium Aldicarb Sulfoxide Giardia Aldicarb Sulfone Carbaryl Physicals Carbofuran Turbidity 3-Hydroxycarbofuran pH Methomyl Conductivity Oxamyl (Vydate) Minerals Chlorinated Herbicides Alkalinity, as CaCO3 2,4-D Bromide Dalapon Chloride Dicamba Chlorine, free residual Dinoseb Chlorine, total residual Endothall Fluoride Picloram Hardness, Calcium as Pentachlorophenol CaCO3 Hardness, Total as CaCO3 Silica Chlorinated Pesticides/PCB's Sulfate Aldrin Chlordane (Technical) Nutrients Dieldrin Endrin Ammonia Heptachlor Nitrate Heptachlor Epoxide Nitrite Lindane (gamma-BHC) o-Phosphate Metolachlor Total Phosphorus Methoxychlor PCB's (individual aroclors) Note 1 PCB's (as decachlorobiphenyl) Note 1 Demands Toxaphene TOC Nitrogen-Phosphorus Compounds Alachlor Metals Atrazine Aluminum Butachlor Antimony Diquat Arsenic Glyphosate Barium Metribuzin Beryllium Paraquat Boron Propachlor Cadmium Simazine Calcium Chromium Copper SVOC's Iron Benzo(a)pyrene Lead bis-(2-ethylhexyl)phthalate Magnesium bis-(ethylhexyl)adipate Manganese Hexachlorobenzene Mercury Hexachlorocyclopentadiene Molybdenum Nickel Potassium Miscellaneous Organics Selenium Dibromochloropropane (DBCP) Silver Ethylene Dibromide (EDB) -
Florida State Emergency Response Commission
Florida State Emergency Response Commission Sub-Committee on Training (SOT) HAZARDOUS MATERIALS MEDICAL TREATMENT PROTOCOLS Version 3.3 TOXIDROMES Toxidromes are clinical syndromes that the patient presents with. These patterns of signs and symptoms are essential for the successful recognition of chemical exposure. The toxidromes identified in this protocol are chemical exposure based while others such as the opioids are found within general medical protocol. These chemical toxidromes are identified clinically into five syndromes: Irritant Gas Toxidrome Asphyxiant Toxidrome Corrosive Toxidrome Hydrocarbon and Halogenated Hydrocarbons Toxidrome Cholinergic Toxidrome Each can present as a clinical manifestation of the chemical/poisoning involved with some cross-over between toxidromes. This list combines the toxic syndromes found within NFPA 473 (A.5.4.1(2) and traditional syndromes. Toxidrome Correlation to NFPA Standard 473 and Traditional Syndromes Toxidrome NFPA 473 A.5.4.1(2) Hazardous Materials Protocol Correlation Irritant Gas (j) Irritants Bronchospasm OC Pepper spray & lacrimants Asphyxiant (c) Chemical asphyxiants Carbon Monoxide (d) Simple asphyxiants Aniline dyes, Nitriles, Nitrares (h) Blood Agents Cyanide & Hydrogen Sulfide (n) Nitrogen Compounds Closed Space Fires Simple Asphyxants Corrosive (a) Corrosives Hydrofluroic Acid (g) Vesicants Chemical burns to the eye Choramine and Chlorine Hydrocarbon (e) Organic solvents Phenol and (q) Phenolic Compounds Halogenated Hydrocarbons Halogenated Hydrocarbons Cholinergic (b) Pesticides -
Rapid HPLC Determination of Carbofuran and Carbaryl in Tap and Environmental Waters Using On-Line SPE
Application Update: 186 Rapid HPLC Determination of Carbofuran and Carbaryl in Tap and Environmental Waters Using On-Line SPE Xu Qun1 and Jeff Rohrer2 1Shanghai, Peoples Republic of China; 2Sunnyvale, CA, USA Introduction Method detection limits (MDLs) of the two Key Words N-methylcarbamates are widely used agricultural compounds were both ≤ 0.062 μg/L, which is lower than pesticides. Reversed-phase high-performance liquid the MDLs reported in EPA Method 8318 (2.0 μg/L for • Carbamates chromatography (RP-HPLC) with fluorescence detection carbofuran and 1.7 μg/L for carbaryl), and in the standard • U.S. EPA following postcolumn derivatization, per EPA Methods method enacted by the Chinese government (7 μg/L 531.2 and 8318,1,2 is the method typically used for the for carbofuran).5 The MDLs were also similar to those • Pesticides sensitive determination of carbamates. Thermo Scientific reported in EPA Method 531.2 (0.058 μg/L for carbofuran • Drinking Water has published a detailed method3,4 that is consistent with and 0.068 μg/L for carbaryl). The MDL for carbofuran is the EPA methods. When an HPLC with UV absorbance well under the 40 μg/L maximum allowable concentration • SolEx HRP detection method is used, a sample preparation in U.S. drinking water,6 and meets the general rule for • RSLC procedure—either liquid-liquid extraction or off-line pesticides in drinking water (98/83/EC) published by the solid-phase extraction (SPE)—is required to increase the European Union (the maximum admissible concentration detection sensitivity. However, these procedures are time- of each individual pesticide component is 0.1 μg/L).7 consuming, require large volumes of organic solvents, and Therefore this method would be universally appropriate are deficient in terms of process control. -
Argonne Report.Pdf
CONTENTS NOTATION ........................................................................................................................... xi ABSTRACT ........................................................................................................................... 1 1 INTRODUCTION ........................................................................................................... 5 1.1 Overview of the Emergency Response Guidebook ................................................ 5 1.2 Organization of this Report ..................................................................................... 7 2 GENERAL METHODOLOGY ....................................................................................... 9 2.1 TIH List ................................................................................................................... 10 2.1.1 Background ................................................................................................. 10 2.1.2 Changes in the TIH List for the ERG2012 ................................................. 11 2.2 Shipment and Release Scenarios ............................................................................ 11 2.2.1 Shipment Profiles ........................................................................................ 12 2.2.2 Treatment of Chemical Agents ................................................................... 14 2.3 Generics, Mixtures, and Solutions .......................................................................... 17 2.4 Analysis of Water-Reactive -
Chemical Name Federal P Code CAS Registry Number Acutely
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
Measurement Technique for the Determination of Photolyzable
JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 102, NO. D13, PAGES 15,999-16,004,JULY 20, 1997 Measurement techniquefor the determination of photolyzable chlorine and bromine in the atmosphere G. A. Impey,P. B. Shepson,• D. R. Hastie,L. A. Bartie• Departmentof Chemistryand Centre for AtmosphericChemistry, York University,Toronto, Ontario, Canada Abstract. A techniquehas been developed to enablemeasurement of photolyzablechlorine and bromineat tracelevels in the troposphere.In thismethod, ambient air is drawnt•ough a cylindricalflow cell, whichis irradiatedwith a Xe arc lamp. In the reactionvessel of the photoactivehalogen detector (PHD), photolyrically active molecules Clp (including C12, HOC1, C1NO,C1NO2, and C1ONO2) and Brp (including Br2, HOBr, BrNO, BrNO2, and BrONO2) are photolyzed,and the halogenatoms produced react with properieto form stablehalogenated products.These products are thensampled and subsequently separated and detected by gas chromatography.The systemis calibratedusing low concentrationmixtures of C12and Br2 in air from commerciallyavailable permeation sources. We obtaineddetection limits of 4 pptv and 9 pptv as Br2 andC12, respectively, for 36 L samples. 1. Introduction (or C12)in the Arctic, largely as a result of the lack of suitable analyticalmethodologies. This paperreports the developmentof The episodicdestruction of groundlevel ozonein the Arctic at a measurementtechnique for the determinationof rapidly sunriseis a phenomenonthat hasbeen observed for many years. photolyzingchlorine (referred to hereas Clp) and bromine (Brp) With the onsetof polar sunrise,ozone levels are often observed speciesat pansper trillion by volume(pptv) mixingratios in the to drop from a backgroundconcentration of •40 ppbv to almost atmosphere.Impey et al. [this issue]discuss the resultsobserved zero on a timescaleof a day or less [Barrie et al., 1988] for from a field studyconducted in the Canadianhigh Arctic at Alert, periodsof 1-10 days. -
The List of Extremely Hazardous Substances)
APPENDIX A (THE LIST OF EXTREMELY HAZARDOUS SUBSTANCES) THRESHOLD REPORTABLE INVENTORY RELEASE QUANTITY QUANTITY CAS NUMBER CHEMICAL NAME (POUNDS) (POUNDS) 75-86-5 ACETONE CYANOHYDRIN 500 10 1752-30-3 ACETONE THIOSEMICARBAZIDE 500/500 1,000 107-02-8 ACROLEIN 500 1 79-06-1 ACRYLAMIDE 500/500 5,000 107-13-1 ACRYLONITRILE 500 100 814-68-6 ACRYLYL CHLORIDE 100 100 111-69-3 ADIPONITRILE 500 1,000 116-06-3 ALDICARB 100/500 1 309-00-2 ALDRIN 500/500 1 107-18-6 ALLYL ALCOHOL 500 100 107-11-9 ALLYLAMINE 500 500 20859-73-8 ALUMINUM PHOSPHIDE 500 100 54-62-6 AMINOPTERIN 500/500 500 78-53-5 AMITON 500 500 3734-97-2 AMITON OXALATE 100/500 100 7664-41-7 AMMONIA 500 100 300-62-9 AMPHETAMINE 500 1,000 62-53-3 ANILINE 500 5,000 88-05-1 ANILINE,2,4,6-TRIMETHYL- 500 500 7783-70-2 ANTIMONY PENTAFLUORIDE 500 500 1397-94-0 ANTIMYCIN A 500/500 1,000 86-88-4 ANTU 500/500 100 1303-28-2 ARSENIC PENTOXIDE 100/500 1 THRESHOLD REPORTABLE INVENTORY RELEASE QUANTITY QUANTITY CAS NUMBER CHEMICAL NAME (POUNDS) (POUNDS) 1327-53-3 ARSENOUS OXIDE 100/500 1 7784-34-1 ARSENOUS TRICHLORIDE 500 1 7784-42-1 ARSINE 100 100 2642-71-9 AZINPHOS-ETHYL 100/500 100 86-50-0 AZINPHOS-METHYL 10/500 1 98-87-3 BENZAL CHLORIDE 500 5,000 98-16-8 BENZENAMINE, 3-(TRIFLUOROMETHYL)- 500 500 100-14-1 BENZENE, 1-(CHLOROMETHYL)-4-NITRO- 500/500 500 98-05-5 BENZENEARSONIC ACID 10/500 10 3615-21-2 BENZIMIDAZOLE, 4,5-DICHLORO-2-(TRI- 500/500 500 FLUOROMETHYL)- 98-07-7 BENZOTRICHLORIDE 100 10 100-44-7 BENZYL CHLORIDE 500 100 140-29-4 BENZYL CYANIDE 500 500 15271-41-7 BICYCLO[2.2.1]HEPTANE-2-CARBONITRILE,5- -
Malathion Human Health and Ecological Risk Assessment Final Report
SERA TR-052-02-02c Malathion Human Health and Ecological Risk Assessment Final Report Submitted to: Paul Mistretta, COR USDA/Forest Service, Southern Region 1720 Peachtree RD, NW Atlanta, Georgia 30309 USDA Forest Service Contract: AG-3187-C-06-0010 USDA Forest Order Number: AG-43ZP-D-06-0012 SERA Internal Task No. 52-02 Submitted by: Patrick R. Durkin Syracuse Environmental Research Associates, Inc. 5100 Highbridge St., 42C Fayetteville, New York 13066-0950 Fax: (315) 637-0445 E-Mail: [email protected] Home Page: www.sera-inc.com May 12, 2008 Table of Contents Table of Contents............................................................................................................................ ii List of Figures................................................................................................................................. v List of Tables ................................................................................................................................. vi List of Appendices ......................................................................................................................... vi List of Attachments........................................................................................................................ vi ACRONYMS, ABBREVIATIONS, AND SYMBOLS ............................................................... vii COMMON UNIT CONVERSIONS AND ABBREVIATIONS.................................................... x CONVERSION OF SCIENTIFIC NOTATION .......................................................................... -
Table II. EPCRA Section 313 Chemical List for Reporting Year 2017 (Including Toxic Chemical Categories)
Table II. EPCRA Section 313 Chemical List For Reporting Year 2017 (including Toxic Chemical Categories) Individually listed EPCRA Section 313 chemicals with CAS numbers are arranged alphabetically starting on page II-3. Following the alphabetical list, the EPCRA Section 313 chemicals are arranged in CAS number order. Covered chemical categories follow. Note: Chemicals may be added to or deleted from the list. The Emergency Planning and Community Right-to-Know Call Center or the TRI-Listed Chemicals website will provide up-to-date information on the status of these changes. See section B.3.c of the instructions for more information on the de minimis % limits listed below. There are no de minimis levels for PBT chemicals since the de minimis exemption is not available for these chemicals (an asterisk appears where a de minimis limit would otherwise appear in Table II). However, for purposes of the supplier notification requirement only, such limits are provided in Appendix C. Chemical Qualifiers Certain EPCRA Section 313 chemicals listed in Table II have parenthetic “qualifiers.” These qualifiers indicate that these EPCRA Section 313 chemicals are subject to the section 313 reporting requirements if manufactured, processed, or otherwise used in a specific form or when a certain activity is performed. An EPCRA Section 313 chemical that is listed without a qualifier is subject to reporting in all forms in which it is manufactured, processed, and otherwise used. The following chemicals are reportable only if they are manufactured, processed, or otherwise used in the specific form(s) listed below: Chemical/ Chemical Category CAS Number Qualifier Aluminum (fume or dust) 7429-90-5 Only if it is a fume or dust form. -
Acutely Hazardous Waste List
ACUTELY HAZARDOUS WASTE P011 1303–28–2 Arsenic pentoxide P012 1327–53–3 Arsenic trioxide The following materials, when a waste, are specifically listed in P038 692–42–2 Arsine, diethyl- 40 CFR 261.33 as Acutely Hazardous Wastes, when they are the only active ingredient, and are unused/unaltered. Also, P036 696–28–6 Arsonous dichloride, phenyl- certain solvent mixtures (of at least 10%) containing dioxin are P054 151–56–4 Aziridine Acutely hazardous wastes. P067 75–55–8 Aziridine, 2-methyl- P013 542–62–1 Barium cyanide The primary hazardous property(ies) of these materials are P024 106–47–8 Benzenamine, 4-chloro- indicated by the letters T (Toxicity), R (Reactivity), I (Ignitability) and C (Corrosivity). Absence of a letter indicates that the P077 100–01–6 Benzenamine, 4-nitro- compound is only listed for toxicity. P028 100–44–7 Benzene, (chloromethyl)- 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51–43–4 The list was last updated on 10/30/08. (R)- P046 122–09–8 Benzeneethanamine, alpha,alpha-dimethyl- Haz P014 108–98–5 Benzenethiol waste CAS Material 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, No. P127 1563–66–2 methylcarbamate. P023 107–20–0 Acetaldehyde, chloro- Benzoic acid, 2-hydroxy-, compd. with (3aS-cis)- P002 591–08–2 Acetamide, N-(aminothioxomethyl)- P188 57–64–7 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo[2,3- P057 640–19–7 Acetamide, 2-fluoro- b]indol-5-yl methylcarbamate ester (1:1). P058 62–74–8 Acetic acid, fluoro-, sodium salt 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1- 1 P002 591–08–2 1-Acetyl-2-thiourea P001 81–81–2 phenylbutyl)-, & salts, when present at concentrations greater than 0.3% P003 107–02–8 Acrolein P028 100–44–7 Benzyl chloride P070 116–06–3 Aldicarb P015 7440–41–7 Beryllium powder P203 1646–88–4 Aldicarb sulfone. -
Code Chemical P026 1-(O-Chlorophenyl)Thiourea P081 1
Code Chemical P026 1-(o-Chlorophenyl)thiourea P081 1,2,3-Propanetriol, trinitrate (R) P042 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, (R)- P067 1,2-Propylenimine P185 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)- carbonyl]oxime 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa- chloro-1,4,4a,5,8,8a,-hexahydro-, P004 (1alpha,4alpha, 4abeta,5alpha,8alpha,8abeta)- 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa- chloro-1,4,4a,5,8,8a-hexahydro-, P060 (1alpha,4alpha, 4abeta,5beta,8beta,8abeta)- P002 1-Acetyl-2-thiourea P048 2,4-Dinitrophenol P051 2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3,4,5,6,9,9 -hexachloro-1a,2,2a,3,6,6a,7,7a- octahydro-, (1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7 beta, 7aalpha)-, & metabolites 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3,4,5,6,9,9- hexachloro-1a,2,2a,3,6,6a,7,7a- P037 octahydro-, (1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7 beta, 7aalpha)- P045 2-Butanone, 3,3-dimethyl-1-(methylthio)-, O-[methylamino)carbonyl] oxime P034 2-Cyclohexyl-4,6-dinitrophenol 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1- phenylbutyl)-, & salts, when present at P001 concentrations greater than 0.3% P069 2-Methyllactonitrile P017 2-Propanone, 1-bromo- P005 2-Propen-1-ol P003 2-Propenal P102 2-Propyn-1-ol P007 3(2H)-Isoxazolone, 5-(aminomethyl)- P027 3-Chloropropionitrile P047 4,6-Dinitro-o-cresol, & salts P059 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro- 3a,4,7,7a-tetrahydro- P008 4-Aminopyridine P008 4-Pyridinamine P007 5-(Aminomethyl)-3-isoxazolol 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-