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Mass Defect & Binding Energy
Sem-3 CC7 Nuclear Physics Mass Defect & Binding Energy According to nuclear particle experiments, the total mass of a nucleus (mnuc) is less than the sum of the masses of its constituent nucleons (protons and neutrons). For a nucleus with Z protons and mass number A, the mass difference or mass defect is given by Δm= Zmp + (A−Z)mn − mnuc where Zmp is the total mass of the protons, (A−Z)mn is the total mass of the neutrons, and mnuc is the mass of the nucleus. According to Einstein’s special theory of relativity, mass is a measure of the total energy of a system (E=mc2). The energy equivalent to mass defect is alled the binding energy B of the nucleus. Thus 2 B= [Zmp + (A−Z)mn − mnuc] c The binding energy is equal to the amount of energy released in forming the nucleus. Example 1. Calculate the mass defect and the binding energy of the deuteron. The mass of the −27 deuteron is mD=3.34359×10 kg or 2.014102u. Solution For the deuteron Z=1 and A=2. The mass defect for the deuteron is Δm=mp+mn−mD=1.008665 u+ 1.007825 u- 2.014102u = 0.002388u The binding energy of the deuteron is then B= Δm c2= Δm ×931.5 MeV/u=2.224MeV. Over two million electron volts are needed to break apart a deuteron into a proton and a neutron. This very large value indicates the great strength of the nuclear force. By comparison, the greatest amount of energy required to liberate an electron bound to a hydrogen atom by an attractive Coulomb force (an electromagnetic force) is about 10 eV. -
Iron-57 of Its Isotopes and Has an Sum of Protons + Neutrons 26 Fe Average Mass As Determined by a in the Nucleus
Elements - elements are pure homogeneous forms of matter Solid Liquid Gas Plamsa •constant volume & shape •constant volume but takes •varaible shape and volume •like a gas except it •very low compressibility on the shape of container that fills the container is composed of ions; •particles vibrate in place •low compressibility •high compressibility an ion is charged •highly ordered arrangement •random particle movement •complete freedom of motion atom or group of •do not flow or diffuse •moderate disorder •extreme disorder atoms. •strongest attractive forces •can flow and diffuse •flow and diffuse easily •examples: between particles •weaker attractive forces •weakest attractive forces - flames •generally more dense than •more dense than gases •least dense state - atmosphere of stars liquids •exert a pressure easily - a comet's tail Matter NO YES Pure Substance Can it be separated Mixture by physical means? Can it be decomposed by Is the mixture composition ordinary chemical means? identical throughout; uniform? NO YES YES NO element compound homogeneous heterogenous mixture mixture Co,Fe,S,H,O,C FeS, H2O, H2SO4 steel, air, blood, steam, wet iron, solution of sulfuric acid Cannot be separated Can be decomposed and rust on steel chemcially into simple chemcially separated Uniform appearance, Appearance, composition, substances into simple substances. composition and and properties are variable properties throughout in different parts of the sample Isotopes Is a mass number attached to the element? NO YES All atoms of the same element are not exactly alike mass number attached mass number equals the 57 The element is as a mixture also can be written as iron-57 of its isotopes and has an sum of protons + neutrons 26 Fe average mass as determined by a in the nucleus. -
The Nucleus and Nuclear Instability
Lecture 2: The nucleus and nuclear instability Nuclei are described using the following nomenclature: A Z Element N Z is the atomic number, the number of protons: this defines the element. A is called the “mass number” A = N + Z. N is the number of neutrons (N = A - Z) Nuclide: A species of nucleus of a given Z and A. Isotope: Nuclides of an element (i.e. same Z) with different N. Isotone: Nuclides having the same N. Isobar: Nuclides having the same A. [A handy way to keep these straight is to note that isotope includes the letter “p” (same proton number), isotone the letter “n” (same neutron number), and isobar the letter “a” (same A).] Example: 206 82 Pb124 is an isotope of 208 82 Pb126 is an isotone of 207 83 Bi124 and an isobar of 206 84 Po122 1 Chart of the Nuclides Image removed. 90 natural elements 109 total elements All elements with Z > 42 are man-made Except for technicium Z=43 Promethium Z = 61 More than 800 nuclides are known (274 are stable) “stable” unable to transform into another configuration without the addition of outside energy. “unstable” = radioactive Images removed. [www2.bnl.gov/ton] 2 Nuclear Structure: Forces in the nucleus Coulomb Force Force between two point charges, q, separated by distance, r (Coulomb’s Law) k0 q1q2 F(N) = 9 2 -2 r 2 k0 = 8.98755 x 10 N m C (Boltzman constant) Potential energy (MeV) of one particle relative to the other k q q PE(MeV)= 0 1 2 r Strong Nuclear Force • Acts over short distances • ~ 10-15 m • can overcome Coulomb repulsion • acts on protons and neutrons Image removed. -
Atomic Weights and Isotopic Abundances*
Pure&App/. Chem., Vol. 64, No. 10, pp. 1535-1543, 1992. Printed in Great Britain. @ 1992 IUPAC INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY INORGANIC CHEMISTRY DIVISION COMMISSION ON ATOMIC WEIGHTS AND ISOTOPIC ABUNDANCES* 'ATOMIC WEIGHT' -THE NAME, ITS HISTORY, DEFINITION, AND UNITS Prepared for publication by P. DE BIEVRE' and H. S. PEISER2 'Central Bureau for Nuclear Measurements (CBNM), Commission of the European Communities-JRC, B-2440 Geel, Belgium 2638 Blossom Drive, Rockville, MD 20850, USA *Membership of the Commission for the period 1989-1991 was as follows: J. R. De Laeter (Australia, Chairman); K. G. Heumann (FRG, Secretary); R. C. Barber (Canada, Associate); J. CCsario (France, Titular); T. B. Coplen (USA, Titular); H. J. Dietze (FRG, Associate); J. W. Gramlich (USA, Associate); H. S. Hertz (USA, Associate); H. R. Krouse (Canada, Titular); A. Lamberty (Belgium, Associate); T. J. Murphy (USA, Associate); K. J. R. Rosman (Australia, Titular); M. P. Seyfried (FRG, Associate); M. Shima (Japan, Titular); K. Wade (UK, Associate); P. De Bi&vre(Belgium, National Representative); N. N. Greenwood (UK, National Representative); H. S. Peiser (USA, National Representative); N. K. Rao (India, National Representative). Republication of this report is permitted without the need for formal IUPAC permission on condition that an acknowledgement, with full reference together with IUPAC copyright symbol (01992 IUPAC), is printed. Publication of a translation into another language is subject to the additional condition of prior approval from the relevant IUPAC National Adhering Organization. ’Atomic weight‘: The name, its history, definition, and units Abstract-The widely used term “atomic weight” and its acceptance within the international system for measurements has been the subject of debate. -
The Delimiting/Frontier Lines of the Constituents of Matter∗
The delimiting/frontier lines of the constituents of matter∗ Diógenes Galetti1 and Salomon S. Mizrahi2 1Instituto de Física Teórica, Universidade Estadual Paulista (UNESP), São Paulo, SP, Brasily 2Departamento de Física, CCET, Universidade Federal de São Carlos, São Carlos, SP, Brasilz (Dated: October 23, 2019) Abstract Looking at the chart of nuclides displayed at the URL of the International Atomic Energy Agency (IAEA) [1] – that contains all the known nuclides, the natural and those produced artificially in labs – one verifies the existence of two, not quite regular, delimiting lines between which dwell all the nuclides constituting matter. These lines are established by the highly unstable radionuclides located the most far away from those in the central locus, the valley of stability. Here, making use of the “old” semi-empirical mass formula for stable nuclides together with the energy-time uncertainty relation of quantum mechanics, by a simple calculation we show that the obtained frontier lines, for proton and neutron excesses, present an appreciable agreement with the delimiting lines. For the sake of presenting a somewhat comprehensive panorama of the matter in our Universe and their relation with the frontier lines, we narrate, in brief, what is currently known about the astrophysical nucleogenesis processes. Keywords: chart of nuclides, nucleogenesis, nuclide mass formula, valley/line of stability, energy-time un- certainty relation, nuclide delimiting/frontier lines, drip lines arXiv:1909.07223v2 [nucl-th] 22 Oct 2019 ∗ This manuscript is based on an article that was published in Brazilian portuguese language in the journal Revista Brasileira de Ensino de Física, 2018, 41, e20180160. http://dx.doi.org/10.1590/ 1806-9126-rbef-2018-0160. -
CHAPTER 2 the Nucleus and Radioactive Decay
1 CHEMISTRY OF THE EARTH CHAPTER 2 The nucleus and radioactive decay 2.1 The atom and its nucleus An atom is characterized by the total positive charge in its nucleus and the atom’s mass. The positive charge in the nucleus is Ze , where Z is the total number of protons in the nucleus and e is the charge of one proton. The number of protons in an atom, Z, is known as the atomic number and dictates which element an atom represents. The nucleus is also made up of N number of neutrally charged particles of similar mass as the protons. These are called neutrons . The combined number of protons and neutrons, Z+N , is called the atomic mass number A. A specific nuclear species, or nuclide , is denoted by A Z Γ 2.1 where Γ represents the element’s symbol. The subscript Z is often dropped because it is redundant if the element’s symbol is also used. We will soon learn that a mole of protons and a mole of neutrons each have a mass of approximately 1 g, and therefore, the mass of a mole of Z+N should be very close to an integer 1. However, if we look at a periodic table, we will notice that an element’s atomic weight, which is the mass of one mole of its atoms, is rarely close to an integer. For example, Iridium’s atomic weight is 192.22 g/mole. The reason for this discrepancy is that an element’s neutron number N can vary. -
Nuclear Criticality Safety Engineer Training Module 1 1
Nuclear Criticality Safety Engineer Training Module 1 1 Introductory Nuclear Criticality Physics LESSON OBJECTIVES 1) to introduce some background concepts to engineers and scientists who do not have an educational background in nuclear engineering, including the basic ideas of moles, atom densities, cross sections and nuclear energy release; 2) to discuss the concepts and mechanics of nuclear fission and the definitions of fissile and fissionable nuclides. NUCLEAR CRITICALITY SAFETY The American National Standard for Nuclear Criticality Safety in Operations with Fissionable Materials Outside Reactors, ANSI/ANS-8.1 includes the following definition: Nuclear Criticality Safety: Protection against the consequences of an inadvertent nuclear chain reaction, preferably by prevention of the reaction. Note the words: nuclear - related to the atomic nucleus; criticality - can it be controlled, will it run by itself; safety - protection of life and property. DEFINITIONS AND NUMBERS What is energy? Energy is the ability to do work. What is nuclear energy? Energy produced by a nuclear reaction. What is work? Work is force times distance. 1 Developed for the U. S. Department of Energy Nuclear Criticality Safety Program by T. G. Williamson, Ph.D., Westinghouse Safety Management Solutions, Inc., in conjunction with the DOE Criticality Safety Support Group. NCSET Module 1 Introductory Nuclear Criticality Physics 1 of 18 Push a car (force) along a road (distance) and the car has energy of motion, or kinetic energy. Climb (force) a flight of steps (distance) and you have energy of position relative to the first step, or potential energy. Jump down the stairs or out of a window and the potential energy is changed to kinetic energy as you fall. -
Answer Key Chapter 6: Standard Review Worksheet 1
Answer Key Chapter 6: Standard Review Worksheet 1. 1 amu = 1.66 _ 10–24 g. For example, the average atomic mass of sodium is 22.99 amu, which represents the average mass of all the sodium atoms in the world (including all the various isotopes and their relative abundances). So that we will be able to use the mass of a sample of sodium to count the number of atoms of sodium present in the sample, we consider that every sodium atom in a sample has exactly the same mass (the average atomic mass). The average atomic mass of an element is typically not a whole number of amu’s because of the presence of the different isotopes of the element, each with its own relative abundance. Since the relative abundance of an element can be any number, when the weighted average atomic mass of the element is calculated, the average is unlikely to be a whole number. 2. On a microscopic basis, one mole of a substance represents Avogadro’s number (6.022 _ 1023) of individual units (atoms or molecules) of the substance. On a macroscopic basis, one mole of a substance represents the amount of substance present when the molar mass of the substance in grams is taken (for example, 12.01 g of carbon will be one mole of carbon). 3. The molar mass of a compound is the mass in grams of one mole of the compound (6.022 _ 1023 molecules of the compound) and is calculated by summing the average atomic masses of all the atoms present in a molecule of the compound. -
Nuclear Mass and Stability
CHAPTER 3 Nuclear Mass and Stability Contents 3.1. Patterns of nuclear stability 41 3.2. Neutron to proton ratio 43 3.3. Mass defect 45 3.4. Binding energy 47 3.5. Nuclear radius 48 3.6. Semiempirical mass equation 50 3.7. Valley of $-stability 51 3.8. The missing elements: 43Tc and 61Pm 53 3.8.1. Promethium 53 3.8.2. Technetium 54 3.9. Other modes of instability 56 3.10. Exercises 56 3.11. Literature 57 3.1. Patterns of nuclear stability There are approximately 275 different nuclei which have shown no evidence of radioactive decay and, hence, are said to be stable with respect to radioactive decay. When these nuclei are compared for their constituent nucleons, we find that approximately 60% of them have both an even number of protons and an even number of neutrons (even-even nuclei). The remaining 40% are about equally divided between those that have an even number of protons and an odd number of neutrons (even-odd nuclei) and those with an odd number of protons and an even number of neutrons (odd-even nuclei). There are only 5 stable nuclei known which have both 2 6 10 14 an odd number of protons and odd number of neutrons (odd-odd nuclei); 1H, 3Li, 5B, 7N, and 50 23V. It is significant that the first stable odd-odd nuclei are abundant in the very light elements 2 (the low abundance of 1H has a special explanation, see Ch. 17). The last nuclide is found in low isotopic abundance (0.25%) and we cannot be certain that this nuclide is not unstable to radioactive decay with extremely long half-life. -
5.1: Atomic Mass Unit 5.1: Atomic Mass
Topic 5: Stoichiometry - Chemical Arithmetic Masses of some atoms: 1 -24 16 -23 1H = 1.6736×10 g 8 O = 2.6788 ×10 g 238 -22 92U = 3.9851×10 g Introducing…….the Atomic Mass Unit (amu) 1 amu = 1.66054 x 10-24 g 1 5.1: Atomic Mass Unit Atomic Mass is defined relative to Carbon -12 isotope 12 12 amu is the mass of the 6 C isotope of carbon Carbon -12 atom = 12.000 amu Hydrogen -1 atom = 1.008 amu Oxygen -16 atom = 15.995 amu Chlorine -35 atom = 34.969 amu 2 5.1: Atomic Mass - Natural Abundance We deal with the naturally occurring mix of isotopes, rather than pure isotopes Carbon has three natural isotopes Isotope Mass (amu) Abundance (%) 12C 12.000 98.892 13C 13.00335 1.108 14C 14.00317 1 x 10-4 Any shovelful of Carbon from living material will have a Naturally Occurring Abundance of 98.892% 12C, 1.108% 13C and 0.0001% 14C 3 1 5.1: Atomic Mass - Relative Abundance How do we take into account the naturally occurring Abundances? Take the average mass of the various isotopes weighted according to their Relative Abundances Relative Isotope Mass (amu) Abundance (%) Abundance 12C 12.000 98.892 0.98892 13C 13.00335 1.108 0.0108 -6 14C 14.00317 1 x 10-4 1 x 10 N.B. The % Abundance adds up to 100 The Relative Abundance adds up to 1 4 5.1: Average Atomic Mass Relative Isotope Mass (amu) Abundance (%) Abundance 12C 12.000 98.892 0.98892 13C 13.00335 1.108 0.0108 -6 14C 14.00317 1 x 10-4 1 x 10 The Average Atomic Mass is given by: (0.98892 x 12.000 amu) + (0.01108 x 13.00335 amu) + (1 x 10-6 x 14.00317 amu) = 12.011 amu 5 5.1: Atomic and Molecular Mass You can calculate the mass of any compound from the sum of the atomic masses from the periodic table. -
Isotopes, Isobars, Isotones, Isodiaphers, Isoelectronic Species, Isosters and Nuclear Isomers
Isotopes, Isobars, Isotones, Isodiaphers, Isoelectronic species, Isosters and Nuclear isomers. (1) Isotopes:Atoms of a given element which have same atomic number (nuclear charge) but different mass number are called isotopes. In other words, isotopes are the atoms of the same element differing in mass number. Thus isotopes have same number of protons and electrons but different number of neutrons. They have same position in the periodic table, same chemical properties and same atomic charge. The term was first coined by Soddy. However, Aston using mass spectrometer first separated isotopes(Ne 20 and Ne 22 ) . 1 2 3 12 13 14 Examples:(i) 1 H , 1 H , 1 H (ii) 6 C , 6 C and 6 C Hydrogen (Protium) Deuterium Tritium (p 1, e 1, n 0) (p 1, e 1, n 0) (p 1, e 1, n 0) 16 17 18 35 37 (iii) 8 O , 8 O , 8 O (iv) 17 Cl and 17 Cl Of all the elements, tin has maximum number of stable isotopes (ten). The fractional atomic weight (35.5) of chlorine is due to the fact that in the ordinary chlorine atom, Cl 35 and Cl 37 are present in the ratio of 3: 1. 3 35 1 37 Average atomic weight of Cl 35.5 amu 4 The percentage of a given isotope in the naturally occurring sample of an element is called isotopic abundance. As the isotopic abundance of an element is constant irrespective of its source, atomic weight of an element is constant. (2) Isobars:Isobars are the atoms of different elements with the same mass number but different atomic numbers. -
Make an Atom Vocabulary Grade Levels
MAKE AN ATOM Fundamental to physical science is a basic understanding of the atom. Atoms are comprised of protons, neutrons, and electrons. Protons and neutrons are at the center of the atom while electrons live in lobe-shaped clouds outside the nucleus. The number of electrons usually matches the number of protons, yielding a net neutral charge for the atom. Sometimes an atom has less neutrons or more neutrons than protons. This is called an isotope. If an atom has different numbers of electrons than protons, then it is an ion. If an atom has different numbers of protons, it is a different element all together. Scientists at Idaho National Laboratory study, create, and use radioactive isotopes like Uranium 234. The 234 means this isotope has an atomic mass of 234 Atomic Mass Units (AMU). GRADE LEVELS: 3-8 VOCABULARY Atom – The basic unit of a chemical element. Proton – A stable subatomic particle occurring in all atomic nuclei, with a positive electric charge equal in magnitude to that of an electron, but of opposite sign. Neutron – A subatomic particle of about the same mass as a proton but without an electric charge, present in all atomic nuclei except those of ordinary hydrogen. Electron – A stable subatomic particle with a charge of negative electricity, found in all atoms and acting as the primary carrier of electricity in solids. Orbital – Each of the actual or potential patterns of electron density that may be formed on an atom or molecule by one or more electrons. Ion – An atom or molecule with a net electric charge due to the loss or gain of one or more electrons.