CURRICULUM VITAE WILLIAM E. GEIGER, JR.
Professor of Chemistry University of Vermont, Burlington VT 05405 802-656-0268; EMAIL [email protected] FAX 802-656-8705
Education
B.S. Canisius College 1965 Chemistry Ph.D. Cornell University 1969 Analytical Chemistry
Positions
Research Associate, Univ. of California at Riverside 1968-69 Postdoctoral Research Associate, Northwestern Univ. 1969-70 Assistant Professor, Southern Illinois Univ. 1970-74 Assistant Professor, Univ. of Vermont 1974-77 Associate Professor, Univ. of Vermont 1977-82 Professor, Univ. of Vermont 1982-Present Pomeroy Professor, Univ. of Vermont 1997-Present Chair, Department of Chemistry, University of Vermont 1998-2001
Honors
University of Vermont Scholar 1984 James Crowdle Award, Canisius College 1995 Dean’s Lecturer, UVM 2009 Vermont Academy of Science and Engineering 2009 William Geiger Research Laboratory (Free State University) 2011
Professional Organizations
Member, American Chemical Society (ACS) Division of Analytical Chemistry Division of Inorganic Chemistry Society for Electroanalytical Chemistry (SEAC) Vermont Academy of Science and Engineering
Selected Professional Activities
Professeur Associe, Univ. of Bordeaux 1986 Editor, Newsletter of SEAC 1985-88 Editorial Advisory Board, Organometallics 1989-91 Board of Directors, SEAC 1992-95 Graduiertenkolleg Lecturer, Univ. of Freiburg 1996 Editorial Board, Chemtracts 1997-98 Leverhulme Fellow, University of Bristol 1998 Erskine Fellow, University of Canterbury 2000 Advisory Board, Center for Molecular Electrocatalysis 2009-present
INVITED LECTURES AND COLLOQUIA
Canisius College 10/70 Univ. Maryland at Baltimore 9/71 Franklin and Marshall College 9/71 Univ. of Missouri at St. Louis 2/73 Brown University 10/75 Univ. of Massachusetts at Amherst 12/75 Univ. of Massachusetts at Boston 2/76 SUNY at Buffalo 11/76 SUNY at Plattsburgh 1/77 Providence College 2/78
Wesleyan University 2/78 St. Bonaventure Univ. 3/78 CUNY (Queen's College) 5/78 SUNY at New Paltz 5/78 SUNY at Oneonta 11/78 Union College 11/78 Trinity College(Hartford) 11/78 Univ. of Texas at Austin 3/79 Univ. of Houston 3/79 Canisius College 3/79
Brookhaven National Laboratory 9/79 MIT 9/79 Cambridge University 10/79 Univ. of Bristol 10/79 P.R. Mallory Co. (Burlington, MA) 12/79 Univ. of New Hampshire 12/79 Cal Tech 1/80 Univ. of Southern California 1/80 UCLA 1/80 Dartmouth College 4/80
Univ. of Delaware 10/80 SUNY at Stony Brook 10/80 SUNY at Albany 2/81 Univ. of Illinois 3/81 Southern Illinois Univ. 3/81 Univ. of Connecticut 9/81 CUNY (City College) 11/81 Bates College 11/81 Ohio State Univ. 1/82 Brown University 9/82
North Carolina State Univ. 11/82 Brandeis University 11/82 Electrochemistry Society, Boston Section 12/82 Merrimack College 3/83 Colgate University 11/83 SUNY at Buffalo 11/83 Univ. of West Virginia 3/84 Univ. of Pittsburgh 3/84 Kansas State University 4/84 Washington Univ. (St. Louis) 4/84
Univ. Sherbrooke 4/84 Concordia Univ. 10/84 Wellesley College 11/84 RPI 2/85 Boston University 3/85 Northeastern Univ. 3/85 Notre Dame Univ. 4/85 Indiana University 4/85 Univ. of Wisconsin 5/85 Mt. Holyoke College 11/85
Univ. of Zurich 3/86 Univ. of Heidelberg 3/86 Univ. of Marburg 3/86 Univ. of Aachen 3/86 Univ. of Bordeaux I 3/86 Univ. of Toulouse 3/86 Ecole Normale Superieure (Paris) 3/86 Univ. of Paris VII 3/86 Boston College 11/86 Univ. of Colorado 1/87
Wesleyan University 2/87 Univ. of California at Davis 3/87 Univ. of California at Berkeley 3/87 Chautauqua Short Course in Electrochemistry, White River 3/87 University of Louisville 9/87 SUNY at Potsdam 1/88 SUNY at Plattsburgh 4/88 Univ. of British Columbia 9/88 Univ. of Alberta 9/88 Georgetown University 10/88
Naval Research Lab, Washington 10/88 Texas A&M 11/88 Rutgers University at Newark 3/89 Holy Cross College 4/89 Rochester Institute of Technology 11/89 Hobart and William Smith Colleges 11/89 Merrimack College 4/90 University of Puerto Rico at Rio Pedras 8/90 Fordham University 12/90 McGill University 1/91
Univ. of New Hampshire 3/91 Univ. of Delaware 3/91 Univ. of Tennessee 3/91 Juniata College 4/91 CUNY (Queen's College) 4/91 Queen's University (Ont) 11/91 Purdue University 12/91 Indiana/Purdue at Indianapolis 12/91 Univ. of Minnesota 1/92 Fairfield University 2/92
Univ. of North Carolina at Chapel Hill 10/92 Rhode Island College 3/93 Univ. of Rhode Island 3/93 Connecticut College 4/93 Wesleyan University 4/93 Univ. of Pittsburgh 11/93 West Virginia Univ. 11/93 UVM Material Science 2/94 Northwestern Univ. 2/94 Canisius College 3/94
Virginia Commonwealth Univ. 4/94 Univ. of Virginia 4/94 Canisius College 9/95 St. Anselm's College 11/95 Boston University 12/95 New England Electrochemical Society 2/96 Univ. of Stuttgart 3/96 Univ. of Freiburg 3/96 Univ. of Marburg 3/96 Technical Univ. of Munich 3/96
SUNY Oneonta 11/96 SUNY Binghamton 11/96 Cal Tech 1/97 Univ. of California at Irvine 1/97 Univ. of California at San Diego 1/97 Australian National University 2/97 Univ. of New South Wales 2/97 University of Southampton 2/98 University of Heidelberg 4/98 University of Siena 4/98
University of Bristol 5/98 University of York 5/98 University of Edinborough 6/98 Boston College 9/98 University of Maine, Orono 4/99 University of New Hampshire 10/99 University of Canterbury 3/00 University of Otago 3/00 Northeastern University 10/00 University of Connecticut 4/01
University of Florida 3/02 University of Toronto 3/03 Brown University 7/03 MIT 5/04 Harvard University 5/04 Clemson University 11/04 DARPA, Washington DC 1/05 Fourth Potter Lodge Conference on Electrochemistry 9/05 Texas A&M University 11/05 University of New Mexico 11/05
University of Chicago 3/06 John Carroll University 4/06 Case Western Reserve University 4/06 University of Arizona 2/07 New Mexico State University 3/07 Colorado State University 4/07 University of Rochester 4/07 Sandia National Laboratory 3/08 Los Alamos National Laboratory 4/08 University of Miami 11/08
Indiana University 12/08 University of Quebec at Montreal 1/09 University of Texas 2/10 Cornell University 10/10 University of Delaware 10/10 University of the Free State 2/11
SYMPOSIA ORGANIZED
1982 12th Northeast Regional ACS Meeting Burlington Symposium on Electrochemistry
1982 12th Northeast Regional ACS Meeting Burlington Symposium on Analytical Chemistry
1983 National ACS Meeting Washington DC Symposium on Inorganic and Organometallic Electrochemistry
1983 National ACS Meeting Washington DC Tutorial on Electrochemistry
1990 Electrochemical Society Meeting Montreal Symposium on Mechanistic Aspects of Inorganic and Organometallic Electrochemistry Co-organizer: C.M. Elliott
1990 National ACS Meeting Washington DC Symposium on Organometallic Electrochemistry Co-organizer: K.D. Kadish
1990 National ACS Meeting Washington DC Tutorial on Inorganic Electrochemistry Co-organizer: K.D. Kadish
1994 24th Northeast Regional ACS Meeting Burlington Symposium on Analytical Characterization of Surfaces Co-organizers: J.M. Goldberg and K.B. Sentell
1997 National ACS Meeting Las Vegas Symposium on Inorganic Electrochemistry
INVITED GORDON CONFERENCE LECTURES
1977 INORGANIC CHEMISTRY "Electrochemistry as a Probe to Unusual Oxidation States"
1980 ELECTROCHEMISTRY "Electrochemically-Induced Structure Changes in Organometallics"
1986 RADICAL IONS "One-Electron versus Two-Electron Redox Processes"
1986 PHYSICAL ELECTROCHEMISTRY "Structural Rearrangements in Organometallic Redox Reactions"
1988 ORGANOMETALLIC CHEMISTRY "Two-Electron Reactions"
1990 ELECTROCHEMISTRY "Mechanisms of Two-Electron Transfers" 1994 ELECTROCHEMISTRY "Electron Transfer Involving Rigid Molecules and Monolayers
1998 ORGANOMETALLIC CHEMISTRY "Structures of Organometallic Radicals"
2002 ELECTROCHEMISTRY "Big Changes in Electrolyte Anions"
2005 INORGANIC CHEMISTRY “Surprising Reactions of Organometallic Radical Cations, or What a Difference an Anion Makes”
2006 ORGANOMETALLIC CHEMISTRY “Ferrocene-free Organometallic Electrochemistry”
KEYNOTE AND OTHER INVITED LECTURES
1980 Northeast Regional ACS, Potsdam "Electrochemical Investigation of Oxidation State/Structure Relationships for Gold and Copper Complexes"
1981 Electrochemical Society, Minneapolis "Influence of Metal Oxidation State on the Structure of Pi-Complexed Polyolefins"
1982 Northeast Regional ACS, Burlington "Redox Effects in Metal Polyolefin Compounds"
1983 National ACS, Washington "Electrochemically-Induced Structural Changes in Cobalt and Nickel-Group Polyolefin Complexes"
1983 National ACS, Washington "Cyclic Voltammetry- Pros and Cons"
1984 Rocky Mountain Conference, Denver "Electrochemical Guide to Preparation of Metal Pi-Complexes and Their Radicals"
1984 International Conf. on Coordination Chemistry, Boulder "Control of Structures Through Multi-Electron Transfer Reactions"
1985 National ACS, Chicago "Changes in Ligand Hapticity During Multi-Electron Transfer Reactions"
1985 National ACS, Chicago "Electrochemistry of Metal-C8H8 Complexes"
1987 Eastern Analytical Symposium, New York "Multi-Electron Processes"
1990 Electrochemical Society, Montreal "Electrochemistry of Cobaltocenium Oligomers"
1990 National ACS, Washington "Cyclic Voltammetry: a Quantitative Technique"
1990 National ACS, Washington "Mixed Valency in Rigid Radical Cations of Binuclear Complexes Containing (Arene)Cr(CO)2(PR3) Groups"
1992 NATO Research Workshop, Sintra, Portugal "One- and Two-Electron Oxidations of Fulvalene Complexes"
1993 Reilly Award Symposium (PittCon), Atlanta "A New Twist on an Old Square Scheme: An Effective Homogeneous Cross-Reaction"
1996 Platinum Metals Conference, York "Electron-transfer Reactions of Rhodium Complexes"
1997 10th Australasian Electrochemistry Conference "Spectroelectrochemistry of Organometallic Compounds"
1997 214th ACS National Meeting "Infrared Spectroelectrochemistry"
1998 2nd International Symposium on Intra-and Inter-molecular Electron Transfer, Staffelstein, Germany "Infrared Spectroelectrochemistry as a Probe of Organometallic Redox Reactions"
2000 Pacifichem 2000 International Chemical Congress (Hawaii) "New Solvents and Electrolytes in Inorganic Electrochemistry" and "New Studies in Electron Transfer/Structure Relationships"
2002 2nd Chianti Meeting on Molecular Electrochemistry (Siena) "New Directions in Electrochemistry'
2003 New Trends in Molecular Electrochemistry and XII Meeting of the Portugese Electrochemical Society (Lisbon) “Electrochemical Advances Using Fluoroborate Anion Supporting Electrolytes”
2010 61st Annual Meeting of the International Society of Electrochemistry, Nice, Sept. 2010 “New Directions in Anodic Reactions Based on Third-Generation Electrolyte Anions”
OTHER SYMPOSIUM PAPERS
1972 Great Lakes Regional ACS, Houghton "Electrochemical Reduction of Cobaltocene"
1972 Internat. Conf. on Coordination Chemistry (XIV), Toronto "Electrochemical Characterization of Trianions of Bis (Dithiolato) Nickelates"
1973 Great Lakes Regional ACS, Kalamazoo "Molecular Complexes of Nickel Dithietene with Metalloporphyrins"
1973 Internat. Conf. on Organometallic Chemistry (VI), Amherst "Kinetics and Mechanism of the Electroreduction of Cobaltocene in Nonaqueous Solvents"
1973 Midwest Regional ACS, Lawrence "Electroreduction of Diaminomaleonitrile Complexes of Nickel,Palladium, and Platinum"
1974 Northeast Regional ACS, Burlington "Electrochemical Study of the Reduction Pathways of Nickel Dithiolenes Involving Ni(I) Intermediates"
1974 Northeast Regional ACS, Burlington "Electrochemical and EPR Studies of Nickel, Palladium, and Platinum Complexes of Diaminomaleonitrile"
1975 National ACS, Chicago "Stabilization of the Plus One Oxidation State of the Nickel Group: Electrochemical and EPR Studies"
1976 Mid-Atlantic Regional ACS, Philadelphia "Electron-Transfer Properties of Metal 1,3-Dithiolates"
1977 Electrochemical Society, Philadelphia "Redox Properties of Metallocenes"
1978 National ACS and Canadian Institute of Chemistry, Montreal "Nonaqueous Electrochemical Behavior of Gold and Copper Dithiolate Complexes at Solid Electrodes"
1981 New England Analytical Chemists Conference, Kingston "Directions in Organometallic Electrochemistry"
1981 Internat. Conf. on Organometallic Chemistry (X), Toronto "Redox Properties of Methylene-Bridged Dimetallics"
1982 Northeast Regional ACS, Burlington "Electrochemistry of Methylene-Bridged Dimers of Mn, Co, and Rh"
1982 NSF Organometallic Workshop, State College (Pa) "Electron-transfer Reactions of Organometallics"
1985 Electrochemical Society. Toronto "Isomeric Interconversions of Dimetallic Complexes Initiated by Two-Electron Transfer Reactions"
1985 Electrochemical Society, Toronto "Mechanism and Kinetics of Multi-Electron Transfer Reactions of Organometallic Sandwich Complexes"
1990 National ACS, Boston "Mixed-Valent Triple-Decker Complexes: Organometallic Analogues of the Creutz-Taube Ion"
1990 NSF Organometallic Workshop, Lexington (Ky) "Does Ligand Geometry Determine M-M Delocalization?"
1994 Northeast Regional ACS, Burlington "Electrode Surfaces Modified with Naphthalene Anchored Through Rigid Spacers"
1995 Northeast Regional ACS, Rochester "Fiber-optic IR Spectroscopy Applied to Organometallic Electrochemistry"
RESEARCH FUNDING
Major Grants
1974-77 National Science Foundation 75,000 "Electrochemical and EPR Studies of Metal Complexes in Unusual Oxidation States"
1977-80 National Science Foundation 125,000 "Electrochemical and Spectroscopic Studies of Organometallic Complexes"
1979-81 Petroleum Research Fund 30,000 "Redox Properties of Molecular Clusters"
1980-83 National Science Foundation 260,000 "Electrochemical Studies of Structural Consequences of Electron-Transfer Reactions"
1982-85 Petroleum Research Fund 30,000 "Reduction and Oxidation Pathways in Small Metal Cluster Compunds and Dimetallacycles"
1983-86 National Science Foundation 375,000 "Electrochemical Studies of Structure/Reactivity/ Redox Relationships in Organometallic Pi-Complexes"
1986-89 National Science Foundation 340,000 "Electrochemical Investigations of Multiple Electron-Transfer Reactions of Organometallics"
1989-91 National Science Foundation 240,000 "Extension of 1986-89 Grant for Special Creativity"
1989-91 Petroleum Research Fund 40,000 "Electrochemical Activation of Metal Complexes"
1992-95 National Science Foundation 437,000 "Homogeneous and Heterogeneous Electron- Transfer Reactions"
1994-96 Petroleum Research Fund 50,000 "Redox Properties of Unusual Polynuclear Complexes"
1995-98 National Science Foundation 482,000 "Electrochemistry and Spectroelectrochemistry of Organometallic Compounds"
1998-2000 National Science Foundation 532,000 AElectron-Transfer Induced Changes in Ligand Hapticity and Reactivity@
2001-2004 National Science Foundation 537,000 "Electrochemical Studies of Important Organometallic Compounds in New Types of Electrolytes" 2004-2008 National Science Foundation 599,000 “Molecular Electroanalytical Chemistry: New Directions in Structures and Reactions of Organometallic Radicals”
2008-2011 National Science Foundation 524,500 “New Organometallic Radical Cation-Based Homogeneous and Heterogeneous Ractions and Materials”
Other Grants
1970 Research Corporation 8,000 "Ionic Donor-Acceptor Complexes of Biologically Significant Donors"
1981 NATO Research Grant 4,000 Joint with N.G. Connelly, Univ. of Bristol
1983 NATO Research Grant 4,000 Joint with N.G. Connelly, Univ. of Bristol
1983 PRF Educational Grant 3,000 Symposium on Organometallic Electrochemistry
1989 PRF Educational Grant 3,400 Symposium on Inorganic and Organometallic Electrochemistry, ACS Meeting, Washington
1997 PRF Educational Grant Symposium on Inorganic Electrochemistry, 2,000 ACS Meeting, Las Vegas
THESIS SUPERVISION
Ph.D. Degrees
Fred C. Senftleber 7/77 SIU "Electrochemical Investigation of Transition Metal Complexes of Diaminomaleonitrile"
John D. L. Holloway 5/78 UVM "An Investigation of the Redox Properties of Vanadocene, Chromocene, and Nickelocene"
Jerry Moraczewski 7/80 UVM "An Investigation of the Redox Behavior of Metal-Polyolefin Compounds"
David E. Brennan 10/80 UVM "An Investigation of the Redox Properties of Transition Metal Borane Complexes"
Bunchai Tulyathan 10/81 UVM "Electrochemistry of Organo- metallic Compounds"
Thomas Gennett 9/83 UVM "Electrochemical Investigations of Bridged Bimetallics and Cyclopentadienyl Cobalt Cyclo- Polyolefin Complexes"
Richard S. Kelly 10/84 UVM "Electrochemical Investigations of Cobalt-Containing Metallacycles and Polyolefin Complexes"
Gregg A. Lane 3/85 UVM "Stabilization of Paramagnetic Palladium Complexes and Studies of Their Reaction Mechanisms"
Walter J. Bowyer 4/85 UVM "Electroanalytical Investigation of the Reduction of Cyclopentadienyl Metal Arene Complexes"
Jeanne S. Bickford 3/86 UVM "HPLC Separation of Organometallic Carbonyl Compounds"
Norman E. Van Order, Jr. 5/87 UVM "Electrochemical and Spectroscopic Investigations of Mixed-Valent Organochromium Compounds"
Judith M. Mevs 5/88 UVM "Electrochemical and Spectroscopic Investigations of (arene) Co(polyolefin) Cationic Compounds and [CpRh(CO)]3 Clusters"
Joseph J. Orsini, Jr. 5/89 UVM "Electrochemical Studies of Pre- and + Post-Electron Transfer Reactions of Rh(COD)2 "
Bernadette T. Donovan 5/89 UVM "Electrochemically-Induced Reactions of Some Cobalt Metallacycle Complexes"
David T. Pierce 10/90 UVM "Investigations of the Electrode and Solution Kinetics of Bis(m6-hexamethylbenzene) Ru (II, I, 0) and the Intramolecular Mixed-Valence Interactions of Bimetallic - (6 , 6 -diarene) dicarbonylphosphine Cr(0, I, II) Complexes"
Thomas C. Richards 8/92 UVM "Contributions from the Cross-Reaction in the CpCo(COT) Square Scheme and Dimerization Rates for CpCr(CO)3"
Jon W. Merkert 3/93 UVM "Electrochemical Studies of Rh Arene Complexes and Studies of Mixed Valency of Some Bimetallic Complexes"
Andre Morneau 3/93 UVM "Mechanistic Invesitgation of the Electrochemically-Induced CO-insertion Process and Investigations of the Redox Sites in Arachno Mixed- Metal Clusters"
Teen T. Chin 11/93 UVM "Redox Properties of (Fulvalene) Dicobalt and (Fulvalene) Dirhodium Complexes"
Christopher G. Atwood 3/94 UVM "Investigations of the Intra-Molecular Mixed-Valence Interactions of Dimetallic Dimanganese (O,I,II) Complexes"
Matthew P. Robben 9/94 UVM "Redox Properties of Several Cobalt Helicene Complexes and Study of Tricobalt Clusters in Several Oxidation States"
Michael E. Stoll 10/00 UVM "Electron-Transfer Studies of Bent Metallocenes and Cobalt-Superphane Complexes"
Sabrina M. Trupia 3/02 UVM "Electrochemical Studies of Selected Rhodium, Cobalt, and Ruthenium Organometallic Complexes"
Robert J. LeSuer 3/03 UVM "An Electron-Transfer Study of Bis(Maleonitriledithiolato)gold"
Ayman Nafady 4/04 South Valley University, Sohag, Egypt “Novel Electrochemistry of Organometalllic Cobalt Compounds in Low-Polarity Media Containing Fluoroarylborate Anions”
Derek Laws 5/08 UVM “Organometallic Electrochemistry: A Study of Diazonium-Based Surface Attachments and the Anodic Chemistry of Piano-Stool Complexes”
Michael Stewart 5/10 UVM “Anodic Electrochemistry: Organorhenium Catalyzed Electron Transfer Reactions of Unactivated Olefins and Anodically Induced Haptotropic Metal Migration of Chromium Naphthohydroquinoids”
M.S. Theses
Gerald M. Shkolnik 2/73 SIU "Molecular Complexes of Metallo-porphines with Nickel Dithietene"
Thomas E. Mines 7/73 SIU "Electrochemical Investigations of Nickel Dithiolate Complexes"
Richard K. Elton 5/77 UVM AThe Electrochemical Study of Cacodylic Acid and Methanearsonic Acid"
Marc D. Andrews 10/80 UVM "Electrochemical Investigations of Significant Organoarsenicals"
Deborah Pufahl 5/85 UVM "Consequence of the Reduction of the Cation + [(C5H5)Mo(2-butyne)2(NCMe) ] "
Esteban Fonseca 10/87 UVM "Oxidation of the Complexes (C5H5)RhCO(PR3)"
Paul R. Gamm 3/95 UVM "Electrochemistry of Disulfides on Gold and Platinum"
David M. Nemer 12/96 UVM "Electrochemical Investigations of (triolefin)Cr(CO)3 Complexes"
Anupam Garg 5/01 UVM "Electrochemical Investigation and Spectral Analysis of the Reduction of Chronium Triolefin Complexes"
William M. Volcheck 3/02 UVM "Electrochemistry and Mechanistic Studies of Tris(pyrazolylmethane) Ruthenium Arene Dication"
Nicole Camire Ohrenberg 8/03 UVM “The Importance of Supporting Electrolyte in Electrochemical Media: New Developments Utilizing a Fluoroaryl Borate Anion”
Lacey Marina Paradee (Rees) 10/09 UVM “An Electrochemical Switching Approach to Cr(Arene)(CO)3 Substitution Reactions”
SELECTED COMMITTEE WORK
Department Committees
1974-80 Graduate Affairs Equipment 1977-78 (Chair) 1978-80 Curriculum 1981-89 1980-pres Graduate Admissions (Chair) 1977, 79, 81, 84, 85 (Chair), 88 (Chair), 89, 95, 96 Search Committees
University and College Committees
1976-77 Search, Chemistry Chairperson 1977 Search, Vice President for Research and Dean of Graduate School 1977 Search, Sociology Chairperson (Chair) 1976-77 Graduate College, Institutuional Grants 1979-82 Graduate College, Research and Scholarship, Physical Sciences Section (Chair) 1981 Search, Director of School of Allied Health (Chair) 1982 Arts and Sciences, By-laws 1984-86 Graduate College, Minority Recruitment 1985-94 Arts and Sciences, Kidder Scholarship 1989-91 Graduate College, Research Advisory Council (Chair) 1990 Presidential Task Force on Graduate Education 1992 EPSCoR Research Cluster Review Panel 1994 Graduate Teaching Fellowship Committee 1996 GTF Allocation Panel (Chair)
PUBLICATIONS WILLIAM E. GEIGER, JR.
1. "Electron Spin Resonance of Oxygen-17 Enriched Pentamethylnitrobenzene and p-Dinitrobenzene Anion Radicals", with Gulick, W.M. Jr.; Geske, D.H. J. Am. Chem. Soc. 1968, 90, 4218
2. "Oxygen-17 Semiquinones. The Effect of Fluorine Substitution" with Gulick, W.M., Jr. J. Am. Chem. Soc. 1969, 91, 4657
3. "Oxygen-17 and Carbon-13 Hyperfine Interactions in the Electron Paramagnetic Resonance Spectrum of the Hydroquinone Cation Radical" with Bolton, J.R.; Sullivan, P.D. J. Am. Chem. Soc. 1970, 92, 4176
4. "Electrochemical Indications of New Oxidation States in Transition Metal Dicarbollide Complexes", with Smith, D.E. J. Chem. Soc. Chem. Commun. 1971, 8
5. "Donor-Acceptor Complexes of Phenothiazine and Phenoxazine with Nickel Thiete" with Maki, A.H. J. Phys. Chem. 1971, 75, 2387
6. "Stereochemistry of Electrode Reductions. III. Dichloromaleic, Chloromaleic, Dichlorofumaric, and Chlorofumaric Acids" with Annino, R.; Boczkowski, R.J.; Bolton, D.J.; Jackson, D.T. Jr. Mahler, J. Electroanal. Chem. 1972, 38, 403
7. "The Electrochemical Characterization of Trianions of Bis(Dithiolato) Nickelates" with Mines, T.E. XIV Internat. Conf. Coord. Chem. Proceedings 1972, 480.
8. "Electrochemical Generation and Spectral Characterization of the Bis(maleonitriledithiolato) nickel Trianion" with Mines, T. E. Inorg. Chem. 1973,12, 1189
9. "The Tetrathiotetracene Cation Radical", J. Phys. Chem. 1973, 77, 1862
100 "Kinetics and Mechanism of the Electroreduction of Cobaltocene in Nonaqueous Solutions" VI Internat. Conf. Organometal. Chem. Proceedings 1973, 250
11. "Heterogeneous Electron-Transfer Kinetics at the Mercury- Acetonitrile Interface for Some Metal Dicarbollide Complexes and Their Metallocene Analogs" with Smith, D.E. J. Electroanal. Chem. 1974, 50, 31
12. "The Electroreduction of Cobaltocene. Evidence for a Metallocene Anion" J. Am. Chem. Soc. 1974, 96, 2632
13. "Molecular Charge-Transfer Complexes of Metalloporphryins with Bis(1,2- trifluoromethylethylene-1, 2-dithiolato) nickel" with Shkolnik, G. Inorg. Chem. 1975, 14, 313.
14. "Crystal and Molecular Structures of Ion Radical Molecular Complexes of Bis(1,2- trifluoromethylethylene-1, 2-dithiolato)-nickel with Phenothiazine and Phenoxazine. Effects of Donor-Acceptor Separation on the Molecular Properties" with Singh-abhandu, A.; Robinson, P.; Fang, J. Inorg. Chem. 1975, 14, 318.
15. "Stabilization of Paramagnetic Metal (I) Complexes of the Nickel Subgroup. Electrochemical and ESR Studies of Metal Dithiolene Complexes and Their Amino Analoges" with Senftleber F. J. Am. Chem. Soc. 1975, 97 , 5019.
16. "Vacuum Electrochemical Studies of Ni(I) Products and Intermediates Produced in the Reduction of Nickel Dithiolenes" with Mines, T.; Senftleber F. Inorg. Chem, 1975, 14, 2141.
17. "Electroactivity of Cacodylic Acid in Aqueous and Nonaqueous Media" with Elton R. Anal. Lett. 1976, 9, 665.
18. "Electrochemistry of the Nitroprusside Ion in Nonaqueous Media" with Bowden, W.L.; Bonnar, P.; Brown, D.B. Inorg. Chem. 1977, 16, 41.
19. Paramagentic Complexes Produced in the Electrochemical and Chemical Reduction of Cyclopentadienyl Cobalt - and Rhodium-Cyclopentadieneone Complexes" with van Willigen, H.; Rausch, M.D. Inorg. Chem. 1977, 16, 581.
20. "Paramagnetic M(I) Complexes Generated by the Electrochemical Reduction of M(II) Nickel-, Palladium-, and Platinum-1,2- Dithiolates" with Allen, C.S.; Mines, T.E.; Senftleber, F. Inorg. Chem. 1977, 16, 2003.
21. "Unusual Electron-Transfer Processes Involving Electron-Rich and Electron-Deficient Metallocenes" with Holloway, J.D.L.; Bowden, W. L. J. Am. Chem. Soc. 1977, 99, 7089.
22. "Electrochemical Study of the Reduction Pathways of Metal 1,3 Dithioketonate Complexes" with Bowden, W.L.; Holloway, J.D.L. Inorg. Chem. 1978, 17, 256
23. "Analytical and Mechanistic Studies of the Electrochemical Reduction of Biologically Significant Organoarsenic Acids" with Elton, R.K. Anal. Chem. 1978, 50, 712.
24. "Vacuum Electrochemical Cell Applied to the Oxidation of Bis (Cyclopentadienyl) Chromium" with Holloway, J.D.L.; Senftleber, F.C. Anal. Chem. 1978, 50, 1010.
25. "Gas Chromatographic Separation of Monothio- and Dithio-Acetylacetonates of Nickel" with Uden, P.C.; Nonnemaker, K.A. Inorg. Nucl. Chem. Lett. 1978, 14, 161.
26. "Electrochemical Properties of Bis(cyclopentadienylcobalt) cyclooctatetraene: Formation of a 34-Electron Triple-Decker Compound" with Moraczewski, J. J. Am. Chem. Soc. 1978, 100, 7429.
27. "Comparison of the Electrochemical Properties and ESR Spectra of Thio- and Imino- chelates" with Senftleber, F.C. Inorg. Chem. 1978, 17, 3615.
28. "Electron-Transfer Reactions of Metallocenes. Influence of Metal Oxidation State on Structure and Reactivity" with Holloway, J.D.L. J. Am. Chem. Soc. 1979, 101, 2038.
29. "Redox Properties of Small Metallocarborane Clusters: Electrochemistry of Cobalt Triple-Decker Sandwich Compounds" with Brennan, D.E. J. Am. Chem. Soc. 1979, 101, 3399.
30. "Structural Consequences of Electron-Transfer Reactions. 3. Electrochemical Isomerization of a Metal-Hydrocarbon Bond in the Reduction of Cyclopentadienyl- cobalt Cyclooctatetraene" with Moraczewski J. J. Am. Chem. Soc. 1979, 101, 3407.
31. "Electrochemical Reduction Pathways of the Rhodocenium Ion. Dimerization and Reduction of Rhodocene" with El Murr, N.; Sheats, J.E.; Holloway, J.D.L. Inorg. Chem. 1979, 18, 1443.
32. "An Electrochemical Study of the Protonation Site of the Cobaltocene Anion and of Cyclopentadienylcobalt(I) Dicarbollides" with Bowden, W.L.: El Murr, N. Inorg. Chem, 1979, 18, 2358.
33. "Structural Consequences of Electron-Transfer Reactions. 4. Kinetics of the Reduction of Cyclooctatetraene Iron Tricarbonyl" with Tulyathan, B. J. Electroanal. Chem. 1980, 109, 325.
34. "Structural Consequences of Electron-Transfer Reactions. 5. Electrochemically- Induced Isomerizations of (Cyclooctadiene-) and (Cyclooctatetraene-) Cobalt Compounds" with Moraczewski, J. J. Am. Chem. Soc. 1981, 103, 4779.
35. "Structural Consequences of Electron-Transfer Reactions. 6. Electronic Structures and Structural Preferences of Cyclooctatetraene and Cyclooctadiene Iron and Cobalt Compounds and Their Radical Ions" with Albright, T.A.; Moraczewski J.; Tulyathan, B. J. Am. Chem. Soc. 1981, 103, 4787.
36. "Voltammetric Quantitation of Agriculturally-Significant Benzenearsonic Acids" with Andrews, M. Anal. Chim. Acta 1981, 132, 35.
37. "Cyclopentadienyl Nickel Cyclooctadiene: A Stable Organometallic Pi Radical Containing a Non-Conjugated Polyolefin" with Lane, G.A. Organometallics 1982, 1, 401.
38. "Comparison of the Redox Properties of Small Metallocarboranes with Metallocenes and Large Metallocarborane Clusters" with Brennan, D.E. Inorg. Chem. 1982, 21, 1963.
39. "Electrochemical Study of High and Low Cobalt Oxidation States in Group V- substituted Borane Clusters" with Brennan, D.E.; Little, J.L. Inorg. Chem. 1982, 21, 2529.
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72. "Electrochemically Induced Reversible Insertion of Ruthenium Atoms Into an Eight- Carbon Chain" with Edwin, J.; Salzer, A.; Ruppli, U.; Rheingold, A.L. J. Am. Chem. Soc 1987, 109, 7893.
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75. "The One-Electron Oxidation of (cot)RhCp: Rearrangements of the Radical Cation and of the Resulting Dimerization Product" with Brammer, L.; Connelly, N.G.; Edwin, J.;Orpen, A.G.; Sheridan, J.B. Organometallics 1988, 7, 1259.
76. "A Model for the Unsaturated Intermediate in Dissociative Electron-Transfer Catalyzed Substitution Reactions of Organometallic Compounds" with Donovan, B.T. J. Am. Chem. Soc. 1988, 110, 2335.
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79. "Confirmation of a Radical Mechanism in the Alkyne-Linkage Reaction of the + [CpMo(C2Me2)2(NCMe)] Cation" with Pufahl, D.; Connelly, N.G. Organometallics 1989, 8, 412.
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86. "Electrochemically Induced Insertion of Ru Atoms into a C-C Bond: Reversible Slicing of a Cyclooctatetraene Ligand" with Salzer, A.; Edwin, J.; von Philipsborn, W.; Piantini, U.; Rheingold, A. J. Am. Chem. Soc. 1990, 112, 7113.
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89. "Cp3M3(CO)3 Clusters: Electrocatalytic Isomerization and Effect of Changes in Metal and CO Bonding Mode on Electron-Transfer Properties" with Mevs, J.M.; Gennett, T.; Organometallics 1991, 10, 1229.
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92. "Class II Mixed-Valent Complexes from Oxidation of Doubly-Linked (Arene) Chromium Compounds" with Van Order, Jr., N.; Pierce, D.T.; Bitterwolf, T.E.; Rheingold, A.L.; Chasteen, N.D. Organometallics 1991, 10, 2403.
6 II 5 93. "Electrochemical Properties of ( -arene) M ( -Et2C2B4H4) Complexes: Formation of Persistent d5 (M = Fe, Ru) and d7 (M = Fe) Redox Products" with Merkert, J.W.; Attwood, M.D.; Grimes, R.N. Organometallics 1991, 10, 3545.
94. "The Synthesis of Asymmetric Alkyne-bridged Dipalladium Complexes from the + Paramagnetic Cation [Pd2(-PhC2Ph)-(-C5Ph5)2] " with Connelly, N.G.; Orpen, A.G.; Orsini, Jr., J.J.; Richardson, K.E. J. Chem. Soc. Dalton Trans 1991, 2967.
5 95 "Cyclic Voltammetric Study of the Metal-Centered Radicals [ -C5H5Cr(CO)2L] [L = CO, PMe3, PMe2Ph, PMePh2, PPh3] and [5-C5Me5Cr(CO)3]" with O'Calloghan, K.A.E.; Brown S.J.; Page, J.A.; Baird, M.C.; Richards, T.C. Organometallics 1991, 10, 3119
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99. "Complexes with Two Arene Chromium Tricarbonyl Moieties Separated by Rigid Spacers: Preparation, X-Ray Structures, and Oxidative Voltammetry" with Merkert, J.W.; Paddon- Row, M.N.; Oliver, A.M.; Rheingold, A.L. Organometallics 1992, 11, 4109
100. "Delocalization in Bimetallic Triple-Decker Complexes: Electrochemistry, ESR Spectroscopy, and Spectroelectrochemistry of (MeC6H4CHMe2)2Ru2(Et2C2B3H3) and CpCo(Et2C2B3H3) Ru(MeC6H4CHMe2) and Derived Ions" with Merkert, J.W.; Davis, Jr., J.H.; Grimes, R.N. J. Am. Chem. Soc. 1992, 114, 9846
101. "Synthesis, Characterization, and Crystal Structure of the (C5Ph5)Cr(CO)3 Radical " with Hoobler, R.J.; Hutton, M.A.; Dillard, M.M.; Castellani, M.P.; Rheingold, A.L.; Rieger, A.L.; Rieger, P.H.; Richards, T.C. Organometallics 1993, 12, 116
102. "Electron-Transfer Induced Isomerizations of Co, Ni, and Pd Cyclooctatetraene Complexes: The Role Played by the Ligand vs Metal Composition of the Redox Orbital" with Rieger, P.H. Corbato, C.; Edwin, J.; Fonseca, E.; Lane, G..; Mevs; J.M. J. Am. Chem. Soc., 1993, 115,, 2314
103. "The Synthesis and Properties of an Optically Active Helical Bis-Cobaltocenium Ion" with Gilbert, A.,M.; Katz, T.J.; Robben, M.P.; Rheingold, A.L. J. Am. Chem. Soc., 1993, 115, 3199
104. "The Synthesis and Properties of Optically Active Helical Metallocene Oligomers" with Katz, T.J.; Sudhakar, A.; Teasley, M.F.; Gilbert, A.M.; Robben M.P.; Wuensch, M.; Ward, M.D. J. Am. Chem. Soc., 1993, 115, 3182
105. "Gas-Phase and Solution Studies of the Oxidation of the First Perfluorocyclopentadienyl 5 5 Complex, [Ru( -C5Me5) ( -C5F5)]" with Richardson, D.E.; Ryan M.F.; Chin, T.T.; Hughes, R.P.; Curnow, O.J. Organometallics 1993, 12, 613
106. "One- and Two-Electron Oxidations of Bimetallic Fulvalene Complexes Studied by Voltammetry and IR Spectroelectrochemistry" with Atwood, C.G.; Chin, T.T. in Pombiero, A.J.L.; McCleverty, J. (eds) Molecular Electrochemistry of Inorganic, Bioinorganic, and Organometallic Compounds, NATO ASI Series C, 1993, 385, 519
107. "Evidence for Time-Dependent Valence Detrapping in a Mixed-Valent Dimanganese Fulvalenyl Cation" with Atwood, C.G. J. Am. Chem. soc., 1993, 115, 5310
108. "Synthesis of a Rigid Dimethoxynaphthalene-Spacer-Dithiol Which Spontaneously Attaches to Au and Pt Electrodes: Properties of Monolayer Films in Nonaqueous Solvents" with Black, A.J.; Wooster,, T.T.; Paddon-Row, M.N. J. Am. Chem. Soc. 1993, 115, 7924
109. "Mixed-Valent Interactions in Rigid Dinuclear Sytems: Electrochemical and Spectroscopic Studies of Cr(I)Cr(O) Ions with Controlled Torsion of the Biphenyl Bridge" with Pierce D.T. Inorg. Chem. 1994, 33, 373
110. "Competition Between Homogeneous and Heterogeneous Electron Transfer Pathways in an Electrochemical Square Scheme" with Richards, T.C. J. Am. Chem. Soc. 1994, 116, 2028
111. "Stepwise Oxidation of Three Communicating Metal Centers: Electrochemistry of Trinuclear Trindenyl Complexes of Manganese and Rhodium" with Winter, R.; Pierce, D.T.; Lynch, T.J. J. Chem. Soc., Chem. Commun. 1994, 1949
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113. "Infrared Spectroelectrochemistry of Boron-Hydrogen Stretches: A Tool for Diagnosis of Delocalization in Mixed-Valent Metallocarborane Complexes" with Chin, T.T.; Lovelace, S.R.; Davis, C.M.; Grimes, R.N. J. Am. Chem. Soc. 1994, 116, 9359
114. "Isolation of the All-Bridging CO Isomer of Cp3Co3(CO)3 and Observations Concerning a Highly Deformable Small Metal Cluster" with Robben, M.P.; Rheingold, A.L. Inorg. Chem. 1994, 33, 5615
115. "Low Energy Electronic Absorptions in 17-Electron Organometallic Piano Stool Radicals" with Atwood C.G. J. Am. Chem. Soc. 1994, 116, 10849
116. "Synthesis and Properties of Copper and Nickel Complexes of the General Formula n+ (B11H11)2M " with Kester, J.G.; Keller, D.; Huffman, J.C.; Benefiel, M.A.; Atwood, C.; Siedle, A.R.; Korba, G.A.; Todd, L.J. Inorg. Chem. 1994, 33, 5438
117. "Electrochemical Reduction of the bis(Cyclooctadiene)rhodium Monocation: Generation and Fate of the 17-Electron Radical" with Orsini, J. J. Electroanal. Chem. 1995, 380, 83
118. "Organometallic Mixed-Valent Ions with d7d8 and d8d9 Electronic Configurations Derived From (Fulvalenediyl) Co2(COD)2" with Chin, T.T. Organometallics 1995, 14, 1316
119. "Characterization of the 17-Electron Radical Cation [CpCo(1,5-COD)]+ by ESR Spectroscopy" with Chin, T.T.; Sharp, L.I.; Rieger, P.H. Organometallics 1995, 14, 1322
120. "Synthesis, Characterization, and Molecular Structure of Bis(tetraphenylcyclopentadienyl)rhodium (II)" with Collins, J.E.; Castellani, M.P.; Rheingold, A.L.; Miller, E.J.; Rieger, A.L.; Rieger, P.H. Organometallics 1995, 14, 1232
121. "Quantitative Study of the Interconversion of S- and U- Isomers of Cp(pentadienyl)Cr(CO) in 18e and 17e Complexes: Cyclic Voltammetry Study of an Organometallic Square Scheme" with Wooster, T.W.; Ernst, R.D. Organometallics 1995, 14, 3455
122. "Deducing Structures of 19-Electron Complexes From Studies of Metal Polyolefin Radicals" Accounts Chem. Research 1995, 28, 351
123. "Anodic Infrared Spectroelectrochemistry of Mono- and Di-Nuclear Complexes Containing the (C5H4R)Mn(CO)2L Moiety (L = CO or PR3)" with Atwood, C.G.; Bitterwolf, T.E. J. Electroanal. Chem. 1995, 397, 279
124. "Electron-Transfer Induced Interconversion of Alkyne and Vinylidene Chromium Complexes: A Quantitative Study" with Connelly, N.G.; Lagunas, C.; Metz, B.; Rieger, A.L.; Rieger, P.H.; Shaw, M.J. J. Am. Chem. Soc. 1995, 107, 12202
125. "Ligand-Mediated Metal-Metal Interactions In (Fulvalene) Bis(Dicarbonylcobalt) and Rhodium Complexes" with Lichtenberger, D.L.; Gruhn, N.E.; Rempe, M.E.; Chin, T.T. Inorg. Chim. Acta 1995, 240, 623.
126. "A New Approach to Infrared Spectroelectrochemistry Using a Fiber-optic Probe: Application to Organometallic Redox Chemistry" with Shaw, M.J. Organometallics, 1996, 15, 13
127. "Chemical Redox Agents for Organometallic Chemistry" with Connelly, N.G. Chemical Reviews, 1996, 96, 877.
128. "Instructional Examples of Electrode Mechanisms of Transition Metal Complexes" in Kissinger, P.T.; Heinemann, W.R. (eds.) Laboratory Techniques in Electroanalytical Chemistry, 2nd ed., Marcel Dekker, New York, 1996, p. 683.
6 4 129. "Nineteen-Electron Radicals of the Type ( -C6Me6)Co( -diolefin): Electrochemistry and ESR Results" with Mevs, J.M. Organometallics, 1996, 15, 2350.
130. "Relation of Structural Changes to Electron-Transfer Parameters in Fulvalendiyl Dirhodium Complexes Demonstrating Quasi-Reversible Two-Electron Voltammetry" with Chin, T.T.; Rheingold, A.L., J. Am. Chem. Soc. 1996, 108, 5002.
131. "Synthesis and Properties of the 17-Electron Tantalum-Centered Radical Ta(CO)4(Ph2PCH2CH2PPh2)" with Koeslag, M.A.; Baird, M.C.; Lovelace, S. Organometallics 1996, 15, 3289.
132. "Linear Oligo(ferrocenyldimethylsilanes) with between Two and Nine Ferrocene Units: Electrochemical and Structural Models for Poly (ferrocenylsilane) High Polymers" with Rulkens, R.; Lough, A.J.; Manners, I.; Lovelace, S.R.; Grant, C. J. Am. Chem. Soc. 1996, 118, 12683.
133. "Synthesis and Surface - Confined Electrochemistry of Dimethoxynaphthalene Fused Through Rigid Norbornylogous Spacers to Thiolate, Dithiolate, and Disulfide Groups" with Wooster, T.T.; Gamm, P.R.; Oliver, A.M.; Black, A.J.; Craig, D.C.; Paddon-Row, M.N., Langmuir, 1996, 12, 6616
134. "Comparison of Isomerization Rates of the Metal Carbonyl Cluster Cp*IrCp2Co2(CO)3 in Three Oxidation States (47e, 48e, 49e): Dramatic Rate Enhancements in the Odd- Electron Species" with Shaw, M.J.; Weunsch, M.; Barnes, C.E.; Foersterling, F.H. J. Am. Chem. Soc. 1997, 119, 2804.
135. "Electrochemical and Structural Characterization of cis -and- trans- [Cp(CO)Ru(AsPh2)]2. Isomers that Undergo Two-Electron Oxidations" with DiMaio, A-J.; Rheingold, A.L.; Chin, T.T.; Pierce, D.T. Organometallics, 1998, 17, 1169.
136. "Synthesis, Structures, and Properties of Strained Spirocyclic Sila - and Germaferrocenophanes and Tetraferrocenylsilane" with MacLachlan, M.J.; Lough, A.J.; Manners, I. Organometallics, 1998, 17, 1873.
137. "16-Electron Through 19-Electron Complexes of the 1,5-COD and 1,3-COD Isomers of (C5Ph5)Rh(C8H12): Electrochemical Evidence for an Oxidatively-Induced Agostic Interaction" with Shaw, M.J.; Hyde, J.; White, C. Organometallics, 1998, 17, 5486.
138. "A Delocalized Analogue of the Bicobaltocene Cation Derived From Reduction of a d6 d6 (fulvalenediyl) bis (cobaltacarborane) Complex: Electrochemistry, ESR, Optical Spectroscopy and IR Spectroscopy of the Carborane Group", with Chin, T.T.; Grimes, R.N. Inorg. Chem. 1999, 38, 93.
139. "Geometric Preferences of Tricobalt Clusters Having 47 to 49-Electron Counts: Deceptively Simple Cyclic Voltammetric responses and EPR Evidence for Exchange- Coupled Dimers in Frozen Solutions" with Robben, M.P.; Rieger, P.H. J. Am. Chem. Soc. 1999, 121, 367.
140. "Redox Properties of the 17-Electron Metallocene (C5H5)Mo(C6Ph6)): Electrochemical Characterization of the 16e- Lewis Acid Monocation and - Its PF6 Adduct" with Quarmby, I.C.; Hemond, R.C.; Feher, F.J.; Green, M. J. Organometal. Chem., 1999,577, 189.
141. "Ferrocenylsiloxane Chemistry: Synthesis and Characterization of Hexaferrocenylcyclotrisiloxane and Tetraferrocenyldisiloxanediol" with MacLachlan, M.J.; Zheng, J.; Lough, A.J.; Manners, I.; Mordas, C.; LeSuer, R.; Liablel-Sands, L.M.; Rheingold, A.L. Organometallics, 1999, 18,1337.
142. "Electrochemical Characterization of Equilibria Involving Catalyst Precursors: Cyclic Voltammetry of Labile Organorhodium Complexes in Coordinating Solvents" with Orsini, J. Organometallics, 1999, 18, 1854.
143. "Electron-Transfer Properties of CpFeP5: Evidence for Dimerization Reactions Following Both Oxidation and Reduction", with Winter, R.F. Organometallics, 1999, 18, 1827.
144. "Reactions of odd-Electron Cobaltacycles: Characterization of a Persistent 17- Electron Anionic Intermediate in Electron-Transfer catalyzed (ETC) Substitution Reactions" with Donovan-Merkert, B.T. and Rieger, P.H. Organometallics 1999, 18, 3194.
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146. "Transannular Effects in Dicobalta-Superphane Complexes on the Mixed-Valence Class II/Class III Interface: Distinguishing Between Spin and Charge Delocalization by Electrochemistry, Spectroscopy, and Ab Initio Calculations" with Stoll, M.E.; Lovelace, S.R.; Schimanke, H.; Hyla-Kryspin, I.; Gleiter, R. J. Am. Chem. Soc. 1999, 121,9343.
147. "Improved Electrochemistry in Low-Polarity Media Using Tetrakis (pentafluorophenyl)- borate Salts as Supporting Electrolytes" with LeSuer, R.J. Angew. Chem. Int. Ed., 2000, 39, 248.
148. "Synthesis, Characterization and Ring-Opening Polymerzation of a Novel [1]Silaferrocenophane with Two Ferrocenyl Substituents at Silicon" with MacLachlan, M.J.; Zheng, J.; Thieme, D; Lough, A.J.; Manners, I.; Mordas, C.; LeSuer, R.; Liable- Sands, L.M.; Rheingold, A.L. Polyhedron 2000, 19, 275.
149. "An Electron-Transfer Induced Migratory Insertion Reaction Originating From a 19- Electron Cobaltacyclic Anion" with Morneau, A.; Donovan-Merkert, B.T. Inorg. Chim. Acta, 2000, 300-302, 96.
150. "Investigations of Time-Dependent Delocalization and the Correlation of Carbonyl IR Shifts with E1/2 Values for Hydrocarbon-Linked Class II and Class III Mixed-Valent Complexes" with Atwood, C.G. J. Am. Chem. Soc. 2000, 122, 5477.
151. "Electrochemistry in Benzotrifluoride: Redox Studies in a "Non-coordinating" Solvent Capable of Bridging the Organic and Fluorous Phases" with Ohrenberg, C. Inorg. Chem. 2000, 39, 2948.
152. "Syntheses and Structural and Electrochemical Characterizations of Vanadatricarbadecaboranyl Analoges of Vanadocene and the Structural Characterization + of the [Li(CH2CN)2 ](6-CH3-nido-5,6,9-C3B7H9 ) Tricarbadecaboranyl Anion" with Wasczcak, M.D.; Wang, Y.; Garg, A.; Kang, S.O.; Carroll, P.J.; Sneddon, L.G. J. Am.Chem. Soc., 2001, 123, 2783.
153. "Redox-induced 6 isomerisation in hydrotri(pyrazolyl)boraterhodium complexes: synthesis, structure and ESR spectroscopy of stablised rhodium (II) species" with Connelly, N.G.; Emslie, D.J.H.; Hayward, O.D.; Linehan, E.B.; Orpen, A.G.; Quayle, M.J.; Rieger, P.H., J. Chem. Soc., Dalton Trans., 2001, 670.
154. "On the Electrochemical Preparation of the Neutral Complexes M[S4C4(CN)4], M(mnt)2 M=Ni, Pd, Pt with Barriere, F.; LeSuer, R.J.; Trupia, S. Inorg. Chem., 2001, 40, 2472.
+ 155. "Generation of the 15-Electron Rhodium (II) Complex [RhCl(PPh3)3] by 1-Electron Oxidation of Wilkinson's Catalyst" with Barriere, F., Organometallics, 2001, 20, 2133.
156. "Improved Electrochemistry of Multi-Ferrocenyl Compounds: Investigation of Biferrocene, Terferrocene, Bis(fulvalene)diiron and Diferrocenylethane in Dichloromethane Using [NBu4][B(C6F5)4] as Supporting Electrolyte" with Camire, N.; Mueller-Westerhoff, V.T. J. Organometal. Chem. 2001, 637-639, 823 (50th anniversary of ferrocene).
157. "Stepwise Hapticity Changes in Sequential One-Electron Redox Reactions of Indenyl-Mo Complexes: Combined Electrochemical, ESR, X-Ray and Theoretical Studies" with Stoll, M.E.; Beanzoni, P.; Calhorda, M.J.; Drew, M.G.; Felix, V.; Gamelas, C.A.; Goncalves, I.S.; Romao, C.C.; Veiros, L.F. J. Am.Chem. Soc., 2001, 123, 10595.
158. "Electrochemistry of Cycloaddition Products of Olefins with Nickel Dithiolenes: A Reinvestigation of the Reduction of the 1:1 Adduct Between Ni(S2C2(CF3)2)2 and Norbornadiene" Inorg. Chem., 2002, 41, 136.
159. "Reduction and Oxidation of the Arachno Clusters Fe2(CO)6(:-S)2PtL2: Characterization of Distinct One- and Two-Electron Transfer Sites in Heteropolynuclear Compounds" with Morneau, A.; Richmond, M.G.; Don, M-J.; Watson, W.H.; Nagl, A. Organometallics, 2002, 21, 1247.
160. "Organophosphazenes 25. Synthesis and Electrochemistry of the Dicobalt Hexacarbonyl Complexes of Phenylethynylcyclophosphazenes" with Bahadur, M.; Allen, C.W.; Bridges, A. Canadian J. Chem., 2002,80, 1393.
161. "Characterization and Reactions of Previously Elusive 17-Electron Cations: Electrochemical Oxidations of (C6H6)Cr(CO)3 and (C5H5)Co(CO)2 in the Presence of - [B(C6F5)4] with Camire, N.; Nafady, A. J. Am. Chem. Soc., 2002, 124, 7260.
162. "Use of Medium Effects to Tune the )E1/2 Values of Bimetallic and Oligometallic Compounds" with Barrier, F.; Camire, N.; Mueller-Westerhoff, U.T.; Sanders, R. J. Am. Chem. Soc., 2002, 124, 7262.
163. "Synthetic, Structural, Chemical and Electrochemical Studies of the Metallatricarbadacaboranyl Analogs of Ferrocene, Ruthenocene and Osmocene and the Observation of a Reversible 06-04 Tricarbadecaboranyl Coordination", with Ramachadran, B.M.; Trupia, S.M.; Carrol, P.J.; Sneddon, L.G., Organometallics, 2002, 21, 5078 . 164. "Structural, Spectroscopic, and Electrochemical Studies of Edge-Bridged Open Ferrocenes" with LeSuer, R.; Basta, R.; Arif, A.M.; Ernst, R.D. Organometallics, 2003, 22, 1487
165. “One-Electron Oxidation of Heterodinuclear Organometallic Compounds Having Polyphosphido Bridges” with Winter, R. Organometallics, 2003, 22, 1948
166. “Reversible Sequence of Intramolecular Associative and Dissociative Electron-Transfer Reactions in Hydrotris(pyrazolylborate) Complexes of Rhodium” with Ohrenberg, N.C.; Yeomans, B.; Connelly, N.G.; Emslie, D.J.H. J. Am. Chem. Soc., 2003, 125, 8680
167. “Electrochemical Preparation of the Bis(ruthenocenium) Dication” with Trupia, S.; Nafady, A. Inorg. Chem. 2003, 42, 5480
168. “Ligand-Based Reduction and Electron-Transfer Induced Tub-to-Chair Isomerization of the 5 4 Cyclooctatetraene Ligand in Rh(η -C5Ph5)( (η -C8H8)” with Shaw, M.J.; Hyde, J.; White, C. Organometallics 2004, 23, 2205
169. “Electrochemical Advances Using Fluoroarylborate Anion Supporting Electrolytes” with Barrière, F.; LeSuer, R.J. in Pombeiro, A.; Amatore, C. (Eds), Molecular Electrochemistry, Fontis Media, Portugal, 2004, pp 413-441
170. “Comparison of the Conductivity Properties of the Tetrabutylammonium Salt of Tetrakis(pentafluorophenyl)borate Anion with Those of Traditional Supporting Electrolyte Anions in Nonaqueous Solvents” with LeSuer, R.J.; Buttolph, C. Anal. Chem. 2004, 76, 6395
171. “In-situ IR Spectroelectrochemistry in Study of One-electron Oxidations of Bis(Cyclopentadienyl) Mo(II)-Alkyne or –Alkene Compounds” with Stoll, M.E. Organometallics 2004, 23, 5818
172. “Anodic Electrochemistry of Multiferrocenyl Phosphine and Phosphine Chalcogenide Complexes in Weakly Nucleophilic Electrolytes” with Barriere, F.; Kirss, R.U. Organometallics 2005, 24, 48
173. “A Robust Organometallic Electrode Based on Covalent Attachment of the Cobaltocenium Group to Carbon” with Swarts, J.C.; Laws, D. Organometallics 2005, 24, 341
2+ 174. “ Anodic Preparation of [Re2Cp2(CO)6] : a Dimeric Dication that Provides the Powerful One- + Electron Oxidant [ReCp(CO)3] ” with Chong, D.; Nafady, A.; Costa, P.J.; Calhorda, M.J. J. Am. Chem. Soc. 2005, 127, 15676
175. “On the Question of Redox-Induced Haptotropic Rearrangements in the Electrochemical Reduction of η6-Triolefin Chromium Complexes Having non-Aromatic Ligands” with Garg, A.; Nemer, D.N.; Choi, H.; Sheridan, J.B. Organometallics 2006, 25, 275
176. “ Manipulating the Electrolyte Medium to Favor Either One-Electron or Two-Electron Oxidation Pathways for (Fulvalendiyl)dirhodium Complexes” with Nafady, A.; Chin, T.T. Organometallics 2006, 25, 1654
177. “Use of Weakly-Coordinating Anions to Develop an Integrated Approach to the Tuning of
ΔE1/2 Values by Medium Effects” with Barriére, F. J. Am. Chem. Soc. 2006, 128, 3980
178. “ Approaches to Analytical and Synthetic Electrochemistry in Fluorous Solvent-Containing Media” with LeSuer, R.J. J. Electroanal. Chem. 2006, 594, 20
- - 179. “Electrochemical Oxidation of CoCp(CO)2: Radical-Substrate Reaction of a 17e /18e Pair and Production of a Unique Dimer Radical” with Nafady, A.; Costa, P.J.; Calhorda, M.J. J. Am. Chem. Soc. 2006, 128, 16587.
180. “Molecular and Electronic Structure of Square Planar Gold Complexes Containing Two 1,2- 1+/0/1-/2- di(4-tert-butylphenyl)ethylene-1,2-dithiolato Ligands: [Au(L)2] . A Combined Experimental and Computational Study” with Kokatam, S-L.; Ray, K.; Pap, J.; Bill, E.; LeSuer, R.J.; Rieger, P.H.; Weyhermüller, T.; Neese, F.; Wieghardt, K. Inorg. Chem. 2007, 46, 1100.
181. “Electrochemical Reduction of Ru(η6-arene)(κ3-tris(pyrazolyl)methane) Dicationic Complexes” with Volcheck, W.M.; Tocher, D.A. J. Organometal. Chem. 2007, 692, 3300.
182. “Hyper-electronic Metal-Carborane Analogues of Cymantrene Anions: Electronic and Structural Non-Innocence of the Tricarbdecaboranyl Ligand” with Nafady, A.; Butterick III, R.; Calhorda, M.J.; Carroll, P.J.; Chong, D.; Sneddon, L.G. Organometallics 2007, 26, 4471.
183. “Organometallic Electrochemistry: Origins, Development, and Future” Organometallics 2007, 26, 5738.
184. “Single Electron Oxidations of the Methyldiphenylphosphonium Cyclopentadienylide 5 Complexes (η - C5H4PMePh2)M(CO)3 (M = Cr, Mo, W); Formation and Dimerization of the 17- 5 + Electron, Metal-Centered Radicals [(η - C5H4PMePh2)M(CO)3] “ with Brownie, J.H.; Baird, M.C.; Laws, D.R. Organometallics, 2007, 26, 5890.
185. “Synthetic, Structural, and Electrochemical Studies of Edge-Bridged Open Ferrocenes” with Chong, D.; Davis, N.A.; Weisbrich, A.; Shi, Y.; Arif, A.M.; Ernst, R.D. Organometallics 2008, 27, 430.
5 + 186. “The [Re(η -C5H5)(CO)3] Family of 17-Electron Compounds: Monomer/Dimer Equilibria and Other Reactions”, with Chong, D.; Laws, D.R.; Nafady, A.; Costa, P.J.; Rheingold, A.L.; Calhorda, M.J. J. Am. Chem. Soc. 2008, 130, 2692.
187. “The Cymantrene Radical Cation Family: Spectral and Structural Characterization of the Half-Sandwich Analogues of Ferrocenium Ion” with Laws, D.R.; Chong, D.; Nash, K.; Rheingold, A.L. J. Am. Chem. Soc. 2008, 130, 9859.
188. “Characterization of the Successive One-Electron Oxidation Products of the Dicobalt Fulvalenediyl (Fv) Compound Co2Fv(CO)4 and its Phosphine-Substituted Product” with Nafady, A. Organometallics 2008, 27, 5624.
189. “Conjugated Organometallic Polymer Containing a Redox-Active Center” with Fortin, D.; Clement, S.; Gagnon, K.; Berube, J-F.; Stewart, M.P.; Harvey, P.D. Inorg. Chem. 2009, 48, 446.
190. “The One-Electron Oxidation of Ruthenocene: Reactions of the Ruthenocenium Ion in Gentle Electrolyte Media” with Swarts, J.C.; Nafady, A.; Roudebush, J.; Trupia, S. Inorg. Chem. 2009, 48, 2156.
191. “The Role of Solvent in the Stepwise Oxidation of Nickelocene to the Nickelocenium Dication” with Chong, D.; Slote, J. J. Electroanal. Chem. 2009, 630, 28.
192. “Cycloaddition Reactions of Unactivated Olefins Catalyzed by an Organorhenium Electron- transfer Mediator” with Chong, D.; Stewart, M. J. Am. Chem. Soc. 2009, 131, 7968.
5 - 193. “Consequences of the Protonation of the 19-Electron Anion [Co(η -C5H5)(1,5-C8H12)] “ with Shaw, M.J.; Eilers, J.E. Organometallics 2009, 28, 5349.
194. “Ligand-Solvent Interactions in a Highly-Reduced Metal Chelate Complex: Medium Effects of the One-Electron Reduction of the bis(Maleonitriledithiolato)Gold Dianion” with LeSuer, R.J. Inorg. Chem. 2009, 48, 10826.
- - 195. “Anodic Oxidation of Organometallic Sandwich Complexes using [Al(OC(CF3)4) or [AsF6] as the Supporting Electrolyte Anion” with Stewart, M.P.; Paradee, L.M.; Raabe, I.; Krossing, I. J. Fluorine Chem. 2010, 131, 1091 (Hughes issue).
196. “Organometallic Electrochemistry Based on Electrolytes Containing Weakly-Coordinating Fluoroarylborate Anions” with Barriére, F. Accounts Chem. Res. 2010, 43, 1030
6 5 197. “Voltammetry of Half-Sandwich Manganese Group Complexes of η - PhC3B7H9 and η - C60Bn2PhH2, Two Ligands that are Cyclopentadienyl Mimicks” with Stewart, M.P.; Butterick III, R.; Sneddon, L.G.; Matsuo, Y. Inorg. Chim. Acta 2010, 364, 251 (Rheingold issue)
198. “Spectra and Synthetic-Time-Scale Substitution Reactions of Electrochemically-Produced 6 + [Cr(CO)3(η -arene)] Complexes”, with Ohrenberg, N.C.; Paradee, L.M.; DeWitte III, R.J.; Chong, D. Organometallics 2010, 29, 3179.
199. “Organometallic Electrodes: Modification of Electrode Surfaces Through Cathodic Reduction of Cyclopentadienyldiazonium Complexes of Cobalt and Manganese” with Derek Laws, John Sheats, Arnold Rheingold Langmuir 2010, 26, 15010.
5 200. “The Anodic Reaction of Co(η -C5H5)(CO)(PPh3): An Oxidatively-Induced Ligand Exchange Involving a 17e-/18e- Redox Pair” with Ayman Nafady Organometallics 2010, 29, 4276.
201. “Reflections on Future Directions in Organometallic Electrochemistry” Organometallics 2011, 31, 28.
202. “Electrochemical Studies of the Oxidation and Reduction of Dicobalta-Superphane Complexes” with Sabrina Trupia, Jörg Classen, and Rolf Gleiter Inorg. Chim. Acta 2011, XXX, XXX (Kaim issue)