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Safety Data Sheet SAFETY DATA SHEET Creation Date 24-Nov-2010 Revision Date 14-Feb-2020 Revision Number 2 1. Identification Product Name Selenium (IV) oxide Cat No. : 12358 CAS-No 7446-08-4 Synonyms Selenium dioxide Recommended Use Laboratory chemicals. Uses advised against Food, drug, pesticide or biocidal product use. Details of the supplier of the safety data sheet Company Alfa Aesar Thermo Fisher Scientific Chemicals, Inc. 30 Bond Street Ward Hill, MA 01835-8099 Tel: 800-343-0660 Fax: 800-322-4757 Email: [email protected] www.alfa.com Emergency Telephone Number During normal business hours (Monday-Friday, 8am-7pm EST), call (800) 343-0660. After normal business hours, call Carechem 24 at (866) 928-0789. 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute oral toxicity Category 2 Acute dermal toxicity Category 1 Acute Inhalation Toxicity - Dusts and Mists Category 2 Skin Corrosion/Irritation Category 1 Serious Eye Damage/Eye Irritation Category 1 Germ Cell Mutagenicity Category 2 Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Liver. Label Elements Signal Word Danger Hazard Statements Toxic if swallowed ______________________________________________________________________________________________ Page 1 / 8 Selenium (IV) oxide Revision Date 14-Feb-2020 ______________________________________________________________________________________________ Causes severe skin burns and eye damage Suspected of causing genetic defects May cause damage to organs through prolonged or repeated exposure Fatal in contact with skin or if inhaled Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves/protective clothing/eye protection/face protection In case of inadequate ventilation wear respiratory protection Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Do not get in eyes, on skin, or on clothing Response IF exposed or concerned: Get medical attention/advice Inhalation Immediately call a POISON CENTER or doctor/physician IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Skin Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse Eyes Immediately call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Very toxic to aquatic life with long lasting effects Other hazards Hygroscopic. 3. Composition/Information on Ingredients Component CAS-No Weight % Selenium dioxide 7446-08-4 >95 4. First-aid measures Eye Contact Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. ______________________________________________________________________________________________ Page 2 / 8 Selenium (IV) oxide Revision Date 14-Feb-2020 ______________________________________________________________________________________________ Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Inhalation Remove to fresh air. Immediate medical attention is required. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If not breathing, give artificial respiration. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Most important symptoms and No information available. effects Notes to Physician Treat symptomatically 5. Fire-fighting measures Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media No information available Flash Point No information available Method - No information available Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Do not allow run-off from fire-fighting to enter drains or water courses. Hazardous Combustion Products Carbon dioxide (CO2). Carbon monoxide (CO). Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Flammability Instability Physical hazards 4 0 1 N/A 6. Accidental release measures Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. Do not touch damaged packages or spilled material. Environmental Precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Methods for Containment and Clean Avoid dust formation. Wear self-contained breathing apparatus and protective suit. Sweep Up up and shovel into suitable containers for disposal. Do not let this chemical enter the environment. 7. Handling and storage ______________________________________________________________________________________________ Page 3 / 8 Selenium (IV) oxide Revision Date 14-Feb-2020 ______________________________________________________________________________________________ Handling Handle product only in closed system or provide appropriate exhaust ventilation. Ensure adequate ventilation. Wear personal protective equipment/face protection. Avoid contact with skin, eyes or clothing. Avoid dust formation. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid ingestion and inhalation. Storage Keep in a dry, cool and well-ventilated place. Refer product specification and/or product label for specific storage temperature requirement. Keep container tightly closed. Corrosives area. 8. Exposure controls / personal protection Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Selenium dioxide TWA: 0.2 mg/m3 (Vacated) TWA: 0.2 mg/m3 IDLH: 1 mg/m3 TWA: 0.2 mg/m3 TWA: 0.2 mg/m3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: NIOSH - National Institute for Occupational Safety and Health Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Powder Solid Appearance Light cream Odor No information available Odor Threshold No information available pH 2 10 g/L aq.sol Melting Point/Range 315 °C / 599 °F Boiling Point/Range No information available Flash Point No information available Evaporation Rate Not applicable Flammability (solid,gas) No information available Flammability or explosive limits Upper No data available Lower No data available Vapor Pressure 12.5 mmHg @ 70 °C Vapor Density Not applicable Specific Gravity No information available Solubility No information available ______________________________________________________________________________________________ Page 4 / 8 Selenium (IV) oxide Revision Date 14-Feb-2020 ______________________________________________________________________________________________ Partition coefficient; n-octanol/water No data available Autoignition Temperature Decomposition Temperature No information available Viscosity Not applicable Molecular Formula O2 Se Molecular Weight 110.96 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Hygroscopic. Conditions to Avoid Avoid dust formation. Incompatible products. Exposure to moist air or water. Incompatible Materials Strong oxidizing agents, Strong acids, Ammonia, Reducing Agent Hazardous Decomposition Products Carbon dioxide (CO2), Carbon monoxide
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