Chemistry and Biochemistry Stanislaw F

Total Page:16

File Type:pdf, Size:1020Kb

Chemistry and Biochemistry Stanislaw F 170 College of Arts Sciences and Education Graduate Catalog 2020-2021 Chemistry and Biochemistry Stanislaw F. Wnuk, Professor and Associate Dean for Graduate Education, Robert Stempel School of Public Yong Cai, Professor and Chairperson Health Research Irina Agoulnik, Associate Professor, College of Medicine Yi Xiao, Associate Professor Jose R. Almirall, Professor David A. Becker, Associate Professor Graduate Admission Requirements John Berry, Associate Professor 1. A minimum undergraduate grade point average Konstantin Bukhryakov, Assistant Professor (GPA) of 3.0/4.0 in chemistry and cognate science Justin Carmel, Assistant Professor courses and submission of official GRE scores are Sara Casado Zapico, Instructor, Graduate Program required. International graduate student applicants Director, Professional Science Master's in Forensic whose native language is not English are required to Science submit a score for the Test of English as a Foreign Language (TOEFL) or for the International English Mrinal Chakraborty, Instructor Language Testing System (IELTS). A total score of 80 David C. Chatfield, Professor on the iBT TOEFL or 6.5 overall on the IELTS is Christopher J. Dares, Assistant Professor required. Anthony P. DeCaprio, Associate Professor and Director 2. Applicants must send a statement of purpose and of Forensic Science Certificate Program arrange to have sent transcripts and three letters of Milagros Delgado, University Lecturer and Coordinator of recommendation evaluating the applicant’s potential Laboratories at BBC and Chemistry Undergraduate for graduate work. Originals of these items must be Program Director sent to the FIU Admissions office as specified at Francisco Fernandez-Lima, Associate Professor and https://admissions.fiu.edu/how-to-apply/graduate- Director of the Advanced Mass Spectrometry Facility applicant/index.html. Prospective candidates should Kenneth G. Furton, Professor and Provost and Executive refer to both the above website and Vice President and Chief Operating Officer http://casgroup.fiu.edu/chemistry/ for details Piero R. Gardinali, Professor and Director of SERC regarding the application procedure, Which must be Megan Gillespie, Instructor completed on-line. Palmer Graves, University Lecturer and Coordinator of 3. Formal admission to the M.S. and Ph.D. programs is General Chemistry Laboratories granted by the Admissions Office. Awards of teaching Arthur W. Herriott, Professor Emeritus assistantships are granted by the Graduate Program Rudolf Jaffe, Professor Emeritus Director. Entrance is possible at the beginning of each Jeffrey A. Joens, Professor semester (fall, spring, summer). For consideration for Konstantinos Kavallieratos, Associate Professor a graduate assistantship applicants need to apply for John T. Landrum, Professor Emeritus the Fall semester and all application materials should Watson J. Lees, Associate Professor and Biochemistry be received at least five months prior to the desired Undergraduate Program Director starting date. Fenfei Leng, Professor 4. Students whose undergraduate degree is not Chenzhong Li, Professor, Department of Biomedical equivalent to the American Chemical Society certified Engineering Bachelor of Science degree in chemistry may be Joseph Lichter, Senior Lecturer and Director of required to make up deficiencies. For example, Pre-Health Professional Advising depending on his or her area of specialization, a Yuan Liu, Associate Professor and Biochemistry student may be required to make up deficiencies in Graduate Program Director quantum mechanics, instrumental analysis, or Ramon Lopez de la Vega, Associate Professor and biochemistry by successfully completing Graduate Associate Chair Physical Chemistry II (CHM 5426), Graduate Bruce R. McCord, Professor Analytical Methods (CHM 5150), or Graduate Alexander M. Mebel, Professor Biological Chemistry (CHM 5305) respectively. Jaroslava Miksovska, Associate Professor 5. Entering graduate students must pass two proficiency Joong-ho Moon, Associate Professor exams. Proficiencies are offered in organic, physical, Zaida Morales-Martinez, Professor Emerita inorganic, analytical, and biochemistry. One pass Kevin E. O’Shea, Professor must be in either organic or physical chemistry; the Natalia Soares Quinete, Assistant Professor other is open. The proficiency exams will be J. Martin E. Quirke, Professor administered to incoming graduate students in the Raphael G. Raptis, Professor week before the fall and spring semesters. If a Kathleen S. Rein, Professor and Chemistry student fails to receive a pass in a proficiency exam, Graduate Program Director he or she must show proficiency by completing the Barry P. Rosen, Professor, College of Medicine appropriate course with a grade of “B” (3.0/4.0) or Sandra Stojanovic, Senior Lecturer and Coordinator of better. These courses are Graduate Organic Organic Chemistry Laboratories Chemistry (CHM 5225), Graduate Physical Chemistry Uma Swamy, University Lecturer and Coordinator of (CHM 5425), Graduate Analytical Methods (CHM General Chemistry Laboratories 5150), and Graduate Biological Chemistry (CHM Yuk-Ching Tse-Dinh, Professor and Director of 5305). Students are expected to complete proficiency Biomolecular Sciences Institute requirements by the end of their first semester. Sonia M. Underwood, Assistant Professor 6. Graduate students must maintain a GPA of 3.0/4.0. Xiaotang Wang, Associate Professor Only courses applicable to the graduate program, Stephen Winkle, Associate Professor Graduate Catalog 2020-2021 College of Arts Sciences and Education 171 excluding those for making up deficiencies or CHM 6281 Environmental Organic Chemistry satisfying proficiencies, are counted in the GPA. If the CHM 6340 Organic Geochemistry cumulative GPA drops below 3.0 for one semester, OCC 5050 Chemical Oceanography the student will be placed on academic probation. A CHM 6088 Environmental Chemistry of Trace student who fails to raise his or her GPA to 3.0 or Elements higher within one semester will be dismissed from the Inorganic program. CHM 5251 Organometallic Chemistry 7. Full-time graduate students generally serve as CHM 5440 Kinetics and Catalysis Teaching Assistants (TA’s) in the Department of CHM 5540 Group Theory in Chemistry Chemistry and Biochemistry for their first semester. CHM 5650 Physical Inorganic Chemistry Ph.D. candidates must serve as TA’s for at least one Organic year except in unusual circumstances. TA’s are CHM 5236 Spectroscopic Techniques and awarded on a competitive basis, require a minimum Structure Elucidation cumulative GPA of 3.0, and can be continued for up CHM 5250 Organic Synthesis to four years for Ph.D. students who maintain CHM 5263 Physical Organic Chemistry acceptable academic performance. A limited number of Graduate Research Assistantships (RA’s) may be Physical available. CHM 5423 Atmospheric Chemistry CHM 5490 Physical Spectroscopy Transfer of Credits and Financial Support CHM 5540 Group Theory in Chemistry Transfer of credits. Students having an M.S. in chemistry CHM 5586 Computational Chemistry may transfer as many as 36 credits towards their Ph.D. CHM 6461 Statistical Thermodynamics degree. However, no more than six of those credits will CHM 6480 Quantum Mechanics count toward fulfillment of the formal course work Courses not listed above may be counted as core course requirement. More than six credits for formal course work with prior departmental approval. can be transferred only with special permission of the Graduate Committee, in which case the number of b) At least six credits of additional graduate-level additional course work credits required will depend on the courses approved by the thesis committee in student’s performance in courses, the date courses were consultation with the Graduate Program Director completed, and the area of Ph.D. concentration. with the following guidelines: Financial Support. Full-time graduate students in good 1. The courses must be 5000 or 6000 level academic standing are eligible for financial support. chemistry courses (CHM prefix) or approved Teaching and research assistantships are available on a cognates (up to a maximum of six credits). competitive basis. Inquiries concerning application to the 2. The following do not count toward satisfaction of program and availability of financial support should be this requirement: proficiency courses and directed to the Chemistry Graduate Program Director. courses taken to make up for undergraduate- level deficiencies in chemistry (including CHM Master of Science in Chemistry 5150, CHM 5225, CHM 5305, CHM 5425, and CHM 5426); and courses corresponding to Degree Requirements research, seminar, colloquium, supervised teaching, and thesis completion (CHM 6910L, 1. A minimum of 32 credits of course work. A grade of CHM 6935, CHM 6936, CHM 6940, CHM 6970, “C or higher must be obtained in all courses, and a and CHM 6971). cumulative grade point average of 3.0 or higher which c) Full-time graduate students are required to must be maintained. The course work must include: register for one credit of CHM 6940 (Supervised a) At least nine credits of chemistry in at least two of Teaching) each semester they serve as teaching the six major areas of chemistry (Analytical, assistants. Biochemistry, Environmental, Inorganic, Organic, d) Full-time graduate students are required to and Physical) from the core listed below: register for one credit of CHM 6935 (Graduate Core Courses (three credits each) Seminar) or one credit of CHM 6936 (Chemistry Analytical Colloquium) each fall
Recommended publications
  • The Radiochemistry of Tungsten
    National Academy of Sciences !National Research Council NUCLEAR SCIENCE SERIES The Radiochemistry of Tungsten — ...—- L. F. C URTISS,Chairman ROBLEY D. EVANS, Vice Chairman NationalBureau ofStandards MassachusettsInstituteofTechnology J.A. DeJUREN, Secretary WestinghouseElectricCorporation C. J.BORKOWSKI J.W. IRVINE,JR. Oak RidgeNationalLaboratory MassachusettsI&tituteofTechnology ROBERT G. COCHRAN E. D. KLEMA Texas Agriculturaland Mechanical NorthwesternUniversity College W. WAYNE MEINKE SAMUEL EPSTEIN UniversityofMichigan CaliforniaInstituteofTechnology J.J.NICKSON Memorial Hospital,New York U. FANO NationalBureau ofStandards ROBERT L. PLATZMAN Laboratoirede Chimie Physique HERBERT GOLDSTEIN NuclearDevelopmentCorporationof D. M. VAN PATTER America BartolResearch Foundation LIAISON MEMBERS PAUL C. AEBERSOLD CHARLES K. REED Atomic Energy Commission U. S.Air Force J.HOWARD McMILLEN WILLIAM E. WRIGHT NationalScienceFoundation OfficeofNavalResearch SUBCOMMITTEE ON RADIOCHEMISTRY W. WAYNE MEINKE, Chai~man HAROLD KIRBY UniversityofMichigan Mound Laboratory GREGORY R. CHOPPIN GEORGE LEDDICOTTE FloridaStateUniversity Oak RidgeNationalLaboratory GEORGE A. COWAN JULIAN NIELSEN Los Alamos ScientificLaboratory HanfordLaboratories ARTHUR W. FAIRHALL ELLIS P. STEINBERG UniversityofWashington Argonne NationalLaboratory JEROME HUDIS PETER C. STEVENSON BrookhavenNationalLaboratory UniversityofCalifornia(Livermore) EARL HYDE LEO YAFFE UniversityofC slifornia(Berkeley) McGillUniversity CONSULTANTS NATHAN BALLOU JAMES DeVOE NavalRadiologicalDefenseLaboratory
    [Show full text]
  • Radiochemistry and Uranium Laboratories
    HAZEN RESEARCH, INC. Analytical Department Superfun4Recoi er SITE: J 4601 Indiana St., Golden, CO 80403 303-279-4501 BREAK: OTHER: QUALITY MANUAL Radiochemistry and Uranium Laboratories Policies and Procedures Established to meet NELAC Quality Systems Standards Reviewed, Acknowledged, and Approved by: Signature Date Bill Youngclaus Bench Chemist Richard Oberto Senior Chemist Ann Strapac Lab Technician Eve DelaFuente Group Supervisor s* 'A*/ Robert Rostad Laboratory Manager John C. Jarvis Laboratory Director QA Officer Eleventh Revision, 3/8/2000 Quality Manual Page 1 Radiochemistry Laboratory Revision 11 Hazen Research Inc. 3/8/2000 TABLE of CONTENTS 1.0 Laboratory Description and Quality Statement 1.1 Laboratory Profile 4 1.2 Management Quality Statement 4 1.3 Laboratory Organization 5 2.0 Personnel 2.1 Job Descriptions and Responsibilities 5 2.2 Training 5 2.3 Resumes 6 2.4 Director's Certifications 6 2.5 Employee Signatures and Initials 6 3.0 Facilities 3.1 General Description 6 3.2 Hazen Campus Map 7 3.3 Analytical Department Floor Plan 7 4.0 Licenses and Laboratory Certifications 7 5.0 Methodology 5.1 Standard Operating Procedures 8 5.2 Radium-226 (ZnS scintillation counting) 8 5.3 Radium-226 (alpha spectrometry) 8 5.4 Radium-228 8 5.5 Thorium-230 9 5.6 Polonium-210. 9 5.7 Lead-210 10 5.8 Gross Alpha, Beta 10 5.9 Uranium 10 5.10 Radiocesium 11 5.11 Radiostrontium. 11 5.12 Tritium 12 5.13 Radon 12 5.14 Method Exceptions and Departures 12 5.15 Employee SOP Certification 13 continued next page Quality Manual Page 2 Radiochemistry Laboratory Revision 11 Hazen Research Inc.
    [Show full text]
  • Chemistry (CHEM) 1
    Chemistry (CHEM) 1 CHEM 6A. Introduction to General Chemistry. 5 Units CHEMISTRY (CHEM) Prerequisite(s): One year high school algebra; high school chemistry recommended. CHEM 1A. General Chemistry I. 5 Units General Education Area/Graduation Requirement: Laboratory (B3), Prerequisite(s): High school chemistry and college algebra; sufficient Physical Science (B1) performance on the college algebra diagnostic test, or equivalent; Term Typically Offered: Fall, Spring passing score on a standardized Chemistry diagnostic exam given prior to each semester, or a minimum grade of "C" in CHEM 4. Structure of atoms, molecules and ions; their interactions including General Education Area/Graduation Requirement: Physical Science (B1), stoichiometry, equilibria, and oxidation-reduction. Does not fulfill the Laboratory (B3) requirements for more advanced study in chemistry and cannot be Term Typically Offered: Fall, Spring counted toward a major or minor in chemistry. Lecture three hours, discussion one hour, laboratory three hours. Fundamental principles and concepts of chemistry, including CHEM 6B. Introduction to Organic and Biological Chemistry. 5 Units stoichiometry; thermochemistry; atomic and molecular structure; Prerequisite(s): CHEM 1A or CHEM 6A, or a high school chemistry course solution chemistry, including acid-base chemistry; quantum theory; and passing a qualifying exam given in the first laboratory period. bonding and intermolecular forces; and chemical kinetics. Lecture three General Education Area/Graduation Requirement: Further Studies in Area hours, laboratory three hours, discussion one hour. B (B5) Note: Not open to enrollment by engineering majors, who should take Term Typically Offered: Fall, Spring CHEM 1E, General Chemistry for Engineering. Introduction to structure and properties of the major classes of organic CHEM 1B.
    [Show full text]
  • Chemistry (CHEM) 1
    Chemistry (CHEM) 1 CHEMISTRY (CHEM) GenEd Learning Objective: Key Literacies CHEM 5: Kitchen Chemistry CHEM 1: Molecular Science 3 Credits 3 Credits CHEM 5 Kitchen Chemistry (3) (GN)(BA) CHEM 5 focuses on an Selected concepts and topics designed to give non-science majors an elementary discussion of the chemistry associated with foods and appreciation for how chemistry impacts everyday life. Students who cooking. It incorporates lectures and videos, reading, problem-solving, have received credit for CHEM 3, 101, 130, or 110 may not schedule and "edible"; home experiments to facilitate students' understanding of this course. CHEM 1 is designed for students who want to gain a better chemical concepts and scientific inquiry within the context of food and appreciation of chemistry and how it applies to everyone's everyday cooking. Please note that this is a chemistry class presented in a real life. You are expected to have an interest in understanding the nature of world interactive way, not a cooking class! The course will start from a science, but not necessarily to have any formal training in the sciences. primer on food groups and cooking, proceed to the structures of foods, During the course, you will explore important societal issues that can be and end with studies of the physical and chemical changes observed in better understood knowing some concepts in chemistry. The course is foods. Students will develop an enhanced understanding of the chemical largely descriptive, though occasionally a few simple calculations will principles involved in food products and common cooking techniques. be done to illuminate specific information.
    [Show full text]
  • The Radiochemistry of Gold COMMITTEE on NUCLEAR SCIENCE
    National Academy v of Sciences National Research Council I NUCLEAR SCIENCE SERIES The Radiochemistry of Gold COMMITTEE ON NUCLEAR SCIENCE L. F. CURTISS,Chairman ROBLEY D. EVANS, Vice Chairman NationalBureauofStandards MassachusettsInstituteofTechnology J.A. DeJUREN, Secretary WestinghouseElectricCorporation C. J.BORKOWSKI J.W. IRVINE,JR. Oak RidgeNationalLaboratory MassachusettsInstituteofTechnology ROBERT G. COCHRAN E. D. KLEMA Texas Agriculturaland Mechanical NorthwesternUniversity College W. WAYNE MEINKE SAMUEL EPSTEIN UniversityofMichigan CaliforniaInstituteofTechnology J.J.NICKSON U. FANO MemorialHospital,New York NationalBureauofStandards ROBERT L. PLATZMAN Laboratoirede ChimiePhysique HERBERT GOLDSTEIN NuclearDevelopmentCorporationof D. M. VAN PATTER America BartolResearchFoundation LIAISON MEMBERS PAUL C. AEBERSOLD CHARLES K. REED AtomicEnergyCommission U. S.Air Force J.HOWARD McMILLEN WILLIAM E. WRIGHT NationalScienceFoundation OfficeofNavalResearch SUBCOMMITTEE ON RADIOCHEMISTRY W. WAYNE ME INKE, Chairman HAROLD KIRBY UniversityofMichigan Mound Laboratory GREGORY R. CHOPPIN GEORGE LEDDICOTTE FloridaStateUniversity Oak RidgeNationalLaboratory GEORGE A. COWAN JULfAN NIELSEN Los Alamos ScientificLaboratory HanfordLaboratories ARTHUR W. FAIRHALL ELLIS P. STEINBERG lJniversityofWashington ArgonneNationalLaboratory JEROME HUDIS PETER C. STEVENSON BrookhavenNationalLaboratory UniversityofCalifornia(Livermore) EARL HYDE LEO YAFFE UniversityofCalifornia(Berkeley) McGillUniversity CONSULTANTS NATHAN BALLOU JAMES DeVOE NavalRadiologicalDefenseLaboratory
    [Show full text]
  • Quality, Isotopes, and Radiochemistry of Water Sampled from the Upper Moenkopi Village Water-Supply Wells, Coconino County, Arizona
    Prepared in cooperation with the Hopi Tribe Quality, Isotopes, and Radiochemistry of Water Sampled from the Upper Moenkopi Village Water-Supply Wells, Coconino County, Arizona Open-File Report 2013–1162 U.S. Department of the Interior U.S. Geological Survey FRONT COVER Overview of Upper and Lower Moenkopi Villages from the south looking north across Moenkopi Wash. Photograph taken by D.J. Bills, Fall 2008. Quality, Isotopes, and Radiochemistry of Water Sampled from the Upper Moenkopi Village Water-Supply Wells, Coconino County, Arizona By Robert L. Carruth, Kimberly Beisner, and Greg Smith Prepared in cooperation with the Hopi Tribe Open-File Report 2013–1162 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior SALLY JEWELL, Secretary U.S. Geological Survey Suzette M. Kimball, Acting Director U.S. Geological Survey, Reston, Virginia: 2013 For product and ordering information: World Wide Web: http://www.usgs.gov/pubprod Telephone: 1-888-ASK-USGS For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment: World Wide Web: http://www.usgs.gov Telephone: 1-888-ASK-USGS Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this information product, for the most part, is in the public domain, it also may contain copyrighted materials as noted in the text. Permission to reproduce copyrighted items must be secured from the copyright owner. Suggested citation: Carruth, R.L., Beisner, Kimberly, and Smith, Greg, 2013, Qualilty, isotopes, and radiochemistry of water sampled from the Upper Moenkopi Village water-supply wells, Coconino County, Arizona: U.S.
    [Show full text]
  • Γ Spectroscopy System for Teaching and Research
    γ Spectroscopy System for Teaching and Research PI: Nathalie Wall- Washington State Collaborators: NA University Program: General Scientific Infrastructure ABSTRACT: The project objective is to improve the technical capability of the Washington State University (WSU) Department of Chemistry in the field of radiochemistry, allowing for enhancement of WSU’s capacity to attract and teach high quality students interested in nuclear energy-related studies. The specific aim of this project is to purchase and setup the equipment pieces necessary for a new up-to-date γ spectroscopy system. One of the flagship academic programs at WSU is radiochemistry, administratively located in the Chemistry Department. Six (6) faculty members of the Department of Chemistry are involved in different aspects of nuclear sciences, including environmental radiochemistry, separation, nuclear forensics, radiopharmacology, and computational chemistry. In addition to academic radiochemistry program, WSU is home to the Nuclear Radiation Center (WSU-NRC), which includes a 1 MW TRIGA-fueled research reactor and associated radiochemistry laboratory space. WSU nuclear science program at the Department of Chemistry has shown a considerable growth in the last decade. Out of the 48 students currently integrated in the program (only 5 graduate students were enrolled in this program in 2000), 36 are currently conducting experimental work requiring radioanalytical equipment. Although the program currently features adequate counting systems and α spectroscopy, there is a lack of an up-to- date γ spectroscopy system that is readily available for both R&D work and laboratory instruction. The only γ spectroscopy system owned by the radiochemistry faculty in the chemistry department is a 17 years-old HPGe detector currently used for low-level and long term (months) measurements, rendering its application to other projects nearly impossible.
    [Show full text]
  • RADIOCHEMISTRY and NUCLEAR CHEMISTRY – Vol
    RADIOCHEMISTRY AND NUCLEAR CHEMISTRY – Vol. I - Radiochemistry and Nuclear Chemistry - Sándor Nagy RADIOCHEMISTRY AND NUCLEAR CHEMISTRY Sándor Nagy Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd University, Budapest, Hungary Keywords: activation, activity, aftereffects, annihilation, attenuation, binding energy, bremsstrahlung, charts of nuclides, cross section, decay chains, decay schemes, equilibrium, exponential law, half-life, half-thickness, isobar, isotone, isotope, lethargy, mass excess, moderator, nuclear isomer, nuclear reactions, nuclide, nuclidic mass, radiation–matter interactions, range, recoil, separation energy, X-rays Contents 1. Introduction 2. The beginnings of RC&NC and the timeline of nuclear science 3. Nuclides and nuclei – isotopes, isobars, isotones, and isomers 4. Nuclear starter – concepts, quantities and units 5. Kinetics of radioactive decay and activation 6. Aftereffects of radioactive decay and nuclear reactions 7. Interaction of nuclear radiations with matter 8. Conclusions Acknowledgements Appendices Glossary Bibliography Biographical Sketch Summary This chapter outlines the field of radiochemistry and nuclear chemistry (RC&NC). It gives a short summary of the early history of RC&NC as well as a detailed timeline of the development of subatomic concepts, nuclear science and technology. The basic nuclear concepts, units and relationships are also introduced here. The chapter explains in some detailUNESCO radioactive decay, nuclear reac –tions, EOLSS and radiation–matter interactions to serve with necessary background to related chapters on a selection of the applications of RC&NC written by specialists of their fields. 1. IntroductionSAMPLE CHAPTERS The “official” definitions of radiochemistry (RC) and nuclear chemistry (NC) in the “IUPAC Gold Book” (http://goldbook.iupac.org/index-alpha.html) read as follows: Radiochemistry: “That part of chemistry which deals with radioactive materials.
    [Show full text]
  • Fundamental Research on Radiochemistry of Geological Nuclear Waste Disposal
    1000 CHIMIA 2020, 74, No. 12 RadiochemistRy in switzeRland doi:10.2533/chimia.2020.1000 Chimia 74 (2020) 1000–1009 © S. V. Churakov, W. Hummel, M. Marques Fernandes Fundamental Research on Radiochemistry of Geological Nuclear Waste Disposal Sergey V. Churakovab*, Wolfgang Hummela, and Maria Marques Fernandesa Abstract: Currently, 5⋅1019 Bq of radioactive waste originating from the use of nuclear power for energy produc- tion, and medicine, industry and research, is maintained in Switzerland at intermediate storage facilities.[1] Deep geological disposal of nuclear waste is considered as the most reliable and sustainable long-term solution world- wide. Alike the other European countries, the Swiss waste disposal concept embarks on the combination of en- gineered and geological barriers. The disposal cell is a complex geochemical system. The radionuclide mobility and consequently radiological impact depend not only on their chemical speciation but also on the background concentration of other stable nuclides and their behaviour in the natural environment. The safety assessment of the repository is thus a complex multidisciplinary problem requiring knowledge in chemical thermodynamics, structural chemistry, fluid dynamics, geo- and radiochemistry. Broad aspects of radionuclide thermodynamics and geochemistry are investigated in state-of-the-art radiochemical laboratories at the Paul Scherrer Institute. The research conducted over the last 30 years has resulted in a fundamental understanding of the radionuclides release, retention and transport mechanism in the repository system. Keywords: Nuclear waste disposal · Radionuclide geochemistry · Radionuclide retention and transport Sergey V. Churakov is Head of Laboratory Maria Marques Fernandes is head of the of Waste Management in the Department Clay Sorption group in the Laboratory for of Nuclear Energy and Safety at the Paul Waste Management in the Department Scherrer Institute (PSI) and Full Professor of Nuclear Energy and Safety at the in the Institute of Geological Sciences at Paul Scherrer Institute (PSI).
    [Show full text]
  • Chemistry (CHE) 1
    Chemistry (CHE) 1 CHE 122 Intro to Chemical Systems 3 Credits CHEMISTRY (CHE) A continuation of CHE 120. For students majoring in the sciences but may be taken by others. Chemical systems in which the study of kinetics, CHE 100 Intro to College Chemistry 3 Credits thermodynamics, equilibrium, and radiochemistry are emphasized. Three Open to all students, but designed primarily for those who wish to major hours of lecture per week. Prerequisite(s): CHE 120, MTH 105 or higher. in a science which requires chemistry but whose chemistry background Corequisite(s): CHE 123. is not sufficient to allow entrance into Chemistry 120. It focuses on the nomenclature used in chemistry including the symbols used to designate CHE 123 Quantitative Methods Lab 1 Credits the chemical elements, the construction of chemical formulas, and the Usually taken concurrently with CHE 122. Primarily for students majoring writing and balancing of chemical equations. Other topics will include in the sciences. A number of quantitative classical and instrumental interpreting the Periodic Table, the valences of the elements, the mole methods of analysis are used to determine thermodynamic properties concept, and simple stoichiometry. In addition, chemical calculations and reaction mechanisms. One three-hour lab per week. Prerequisite(s): involving units, scientific notation, significant figures, and the algebraic CHE 121. manipulations of simple equations will be included. Three hours of Corequisite(s): CHE 122. lecture per week. This course does not satisfy the requirements for the biochemistry or chemistry degree, but does satisfy the core requirements CHE 211 Organic Chemistry I 4 Credits for liberal arts, education and business majors.
    [Show full text]
  • The Radiochemistry of Plutonium
    National v Academy of Sciences National1Research Council . E The Radiocheunistry of Plutonium ,“. m COMMlllEE ON NUCLEAR SCIENCE ~. A. Bromley, Chainmm R. D. Evans, Vice Cluri7man Yale University Massachusetts Institute of Technology Lewis Slack, Secrekq National Rese=ch COunCtl E. C. Anderson Jerry B. Marion Los Afamo6 Scientific Laboratory University of Maryland N. E. Baflou R. L. PLatman U. S. Naval Radiological Defense Argonne National Laboratory Labomto~ Ernest C. Pollard Martin J. Barger Pennsylvania State University , National Bureau of Standards Katharine Way C. J. Borkowski Oak Ridge National Laboratory Oak Ridge National Laboratory George W. Wetherill Herbert Goldstein University of California Columbia Uoivereity Marvin E. Wyman Bemd Kahn University of Illinois Taft Sanitary Engineering Center Harold Glsser William S. Rodney Office of Navsl Reeearch National Science Foundation George A. Kolstad Atomic Energy Commission SllWllMMITIEEON RADIOCNEMiSTSY Nathao E. Ballou, Chaivman Julian M. Nielsen U. S. Naval Radiolostcal Defense Battefle Pacific Northwest Lain-atow G. D. O’Ke!.ley G. R. Chq@n Oak Ridge National Laboratory Florida State University E. P. Steinberg Herbert M. Clark Argonne Nationaf Laboratory Rensselaer Polytechnic Institute D. N. Sunderman Richard M. Diamond Battelle Memoriel Institute IJmrence Radiation Laboratory John W. Winchester Jerome Hudla Massachusetts Institute of Technology Brookhaven National Laboratory R. P. Schuman, Consultant Jere D. Knight Sri Venkateswara University Los Alsmos Scientific Laboratow Tirupati, AndhI= Pradesh, India W. E. Nervik Lawrence Radiation Laborstory The Radiochemistry of Plutonium. George” H. Coleman September 1, 1965 UN17JERSITY OF CALIFORNIA Lawrence Radiation Laboratory Livermore, California AEC Contract No. W-7405 -eng-48 Subcommittee on Radiochemistry National Academy of Sciences—National Reaearcb Council Prfmtedin USA.
    [Show full text]
  • The Radiochemistry of Tellurium
    . (L22&QJv?k) National Academy ‘ v of Sciences 1“National Research Council m NUCLEAR SCIENCE SERIES The Radiochemistry of Tellurium i COMMITTEE ON NUCLEAR SCIENCE L. F. C URTISS,Chaiwzan ROBLEY D. EVANS, Vice Chairman NationalBureauofStandards MassachusettsInstituteofTechnology J.A. DeJUREN, Secrefa~y WestinghouseElectricCorporation C. J.BORKOWSKI J.W. IRVINE,JR. Oak RidgeNationalLaboratory MassachusettsInstituteofTechnology ROBERT G. COCHRAN E. D. KLEMA TexasAgriculturaland Mechanical NorthwesternUniversity College W. WAYNE MEINKE SAMUEL EPSTEIN UniversityofMichigan CaliforniaInstituteofTechnology J.J.NICKSON U. FANO MemorialHospital,New York NationalBureauofStandards ROBERT L. PLATZMAN Laboratoirede ChimiePhysique HERBERT GOLDSTEIN NuclearDevelopmentCorporationof D. M. VAN PATTER America BartolResearchFoundation LIAISON MEMBERS PAUL C. AEBERSOLD CHARLES K. REED Atomic EnergyCommission U. S.Air Force J.HOWARD McMILLEN WILLIAM E. WRIGHT NationalScienceFoundation OfficeofNavalResearch SUBCOMMITTEE ON RADIOCHEMISTRY W. WAYNE ME INKE, Chairman HAROLD KIRBY UniversityofMichigan Mound Laboratory GREGORY R. CHOPPIN GEORGE LEDDICOTTE FloridaStateUniversity Oak RidgeNationalLaboratory GEORGE A. COWAN JULIAN NIELSEN Los Alamos ScientificLaboratory HanfordLaboratories ARTHUR W. FAIRHALL ELLIS P. STEINBERG universityofWashington ArgonneNationalLaboratory JEROME HUDIS PETER C. STEVENSON BrookhavenNationalLaboratory UniversityofCalifornia(Livermore) EARL HYDE LEO YAFFE UniversityofCalifornia(Berkeley) McGillUniversity CONSLJLTANTS NATHAN BALLOU JAMES
    [Show full text]