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Fuel Cell Energy Generators PLATINUM CATALYSTS USED in ALTERNATIVE ENERGY SOURCE
Fuel Cell Energy Generators PLATINUM CATALYSTS USED IN ALTERNATIVE ENERGY SOURCE By D. S. Cameron Group Research Centre, Johnson Matthey and Co Limited The steam, in turn, is produced by burning Improvements in the preparation and fossil fuels (coal or hydrocarbons), or by utilisation of platinum metal catalysts nuclear fission. Unfortunately, the processes have now made megawatt scale fuel cell of converting fuel into heat, heat into steam, systems economically viable. The high and steam into electricity involve efficiency thermal efficiency and low pollution losses at every stage. The Carnot cycle characteristics of this novel power source shows that the thermal efficiency of any heat are likely to result in it forming an engine is limited to E where: increasing proportion of the generating capacity utilised for both peaking and intermediate applications. This paper T, and TI being the temperatures, in degrees briejly reviews the development of fuel kelvin, at which heat is supplied to, and cells; it also describes how they work, rejected by, the system. In practice, upper including the function of the catalyst, temperatures are limited to about 500'C and indicates the more important of the (773 K), lower temperatures are at least 30°C many factors which have to be considered (303 K), and efficiencies are limited to a when selecting a commercial system. maximum of 60 per cent. Indeed most modern large power stations are able to achieve only 38 to 40 per cent efficiency. Fuel cells have already achieved acceptance Fuel cells convert fuel directly into elec- as reliable, lightweight power sources for trical energy by an electrochemical route space applications, for example in the Apollo which is not limited by the Carnot cycle. -
Philosophical Transactions, »
INDEX TO THE PHILOSOPHICAL TRANSACTIONS, » S e r ie s A, FOR THE YEAR 1898 (VOL. 191). A. Absorption, Change of, produced by Fluorescence (B urke), 87. Aneroid Barometers, Experiments on.—Elastic After-effect; Secular Change; Influence of Temperature (Chree), 441. B. Bolometer, Surface, Construction of (Petavel), 501. Brilliancy, Intrinsic, Law of Variation of, with Temperature (Petavel), 501. Burke (John). On the Change of Absorption produced by Fluorescence, 87. C. Chree (C.). Experiments on Aneroid Barometers at Kew Observatory, and their Discussion, 441. Correlation and Variation, Influence of Random Selection on (Pearson and Filon), 229. Crystals, Thermal Expansion Coefficients, by an Interference Method (Tutton), 313. D. Differential Equations of the Second Order, &c., Memoir on the Integration of; Characteristic Invariant of (Forsyth), 1. 526 INDEX. E. Electric Filters, Testing Efficiency of; Dielectrifying Power of (Kelvin, Maclean, and Galt), 187. Electricity, Diffusion of, from Carbonic Acid Gas to Air; Communication of, from Electrified Steam to Air (Kelvin, Maclean, and Galt), 187. Electrification of Air by Water Jet, Electrified Needle Points, Electrified Flame, &c., at Different Air-pressures; at Different Electrifying Potentials; Loss of Electrification (Kelvin, Maclean, and Galt), 187. Electrolytic Cells, Construction and Calibration of (Veley and Manley), 365. Emissivity of Platinum in Air and other Gases (Petavel), 501. Equations, Laplace's and other, Some New Solutions of, in Mathematical Physics (Forsyth), 1. Evolution, Mathematical Contributions to Theory o f; Influence of Random Selection on the Differentiation of Local Races (Pearson and Filon), 229. F. Filon (L. N. G.) and Pearson (Karl). Mathematical Contributions to the Theory of Evolution.—IV. On the Probable Errors of Frequency Constants and on the Influence of Random Selection on Variation and Correlation, 229. -
The Electric Telegraph
To Mark, Karen and Paul CONTENTS page ORIGINS AND DEVELOPMENTS TO 1837 13 Early experiments—Francis Ronalds—Cooke and Wheatstone—successful experiment on the London & Birmingham Railway 2 `THE CORDS THAT HUNG TAWELL' 29 Use on the Great Western and Blackwall railways—the Tawell murder—incorporation of the Electric Tele- graph Company—end of the pioneering stage 3 DEVELOPMENT UNDER THE COMPANIES 46 Early difficulties—rivalry between the Electric and the Magnetic—the telegraph in London—the overhouse system—private telegraphs and the press 4 AN ANALYSIS OF THE TELEGRAPH INDUSTRY TO 1868 73 The inland network—sources of capital—the railway interest—analysis of shareholdings—instruments- working expenses—employment of women—risks of submarine telegraphy—investment rating 5 ACHIEVEMENT IN SUBMARINE TELEGRAPHY I o The first cross-Channel links—the Atlantic cable— links with India—submarine cable maintenance com- panies 6 THE CASE FOR PUBLIC ENTERPRISE 119 Background to the nationalisation debate—public attitudes—the Edinburgh Chamber of Commerce— Frank Ives. Scudamore reports—comparison with continental telegraph systems 7 NATIONALISATION 1868 138 Background to the Telegraph Bill 1868—tactics of the 7 8 CONTENTS Page companies—attitudes of the press—the political situa- tion—the Select Committee of 1868—agreement with the companies 8 THE TELEGRAPH ACTS 154 Terms granted to the telegraph and railway companies under the 1868 Act—implications of the 1869 telegraph monopoly 9 THE POST OFFICE TELEGRAPH 176 The period 87o-1914—reorganisation of the -
History of Electric Light
SMITHSONIAN MISCELLANEOUS COLLECTIONS VOLUME 76. NUMBER 2 HISTORY OF ELECTRIC LIGHT BY HENRY SGHROEDER Harrison, New Jersey PER\ ^"^^3^ /ORB (Publication 2717) CITY OF WASHINGTON PUBLISHED BY THE SMITHSONIAN INSTITUTION AUGUST 15, 1923 Zrtie Boxb QSaftitnore (prcee BALTIMORE, MD., U. S. A. CONTENTS PAGE List of Illustrations v Foreword ix Chronology of Electric Light xi Early Records of Electricity and Magnetism i Machines Generating Electricity by Friction 2 The Leyden Jar 3 Electricity Generated by Chemical Means 3 Improvement of Volta's Battery 5 Davy's Discoveries 5 Researches of Oersted, Ampere, Schweigger and Sturgeon 6 Ohm's Law 7 Invention of the Dynamo 7 Daniell's Battery 10 Grove's Battery 11 Grove's Demonstration of Incandescent Lighting 12 Grenet Battery 13 De Moleyns' Incandescent Lamp 13 Early Developments of the Arc Lamp 14 Joule's Law 16 Starr's Incandescent Lamp 17 Other Early Incandescent Lamps 19 Further Arc Lamp Developments 20 Development of the Dynamo, 1840-1860 24 The First Commercial Installation of an Electric Light 25 Further Dynamo Developments 27 Russian Incandescent Lamp Inventors 30 The Jablochkofif " Candle " 31 Commercial Introduction of the Differentially Controlled Arc Lamp ^3 Arc Lighting in the United States 3;^ Other American Arc Light Systems 40 " Sub-Dividing the Electric Light " 42 Edison's Invention of a Practical Incandescent Lamp 43 Edison's Three-Wire System 53 Development of the Alternating Current Constant Potential System 54 Incandescent Lamp Developments, 1884-1894 56 The Edison " Municipal -
High School - Round 1A
HIGH SCHOOL - ROUND 1A TOSS-UP 1) Earth and Space – Short Answer What is a tornado called when it moves or develops over water? ANSWER: WATERSPOUT BONUS 1) Earth and Space – Multiple Choice As the Atlantic Ocean began to open around 200 million years ago, which of the following regions was most directly adjacent to the crust that now underlies the eastern margin of the United States? W) The British Isles X) The southwest margin of Scandinavia Y) The northwest margin of Africa Z) The Walvis Ridge ANSWER: Y) THE NORTHWEST MARGIN OF AFRICA ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ TOSS-UP 2) Biology – Multiple Choice In which of the following organelles does transcription NOT occur? W) Nucleus X) Peroxisome [purr-OX-ih-zohm] Y) Chloroplast [KLOR-oh-plast] Z) Mitochondrion [my-tow-KON-dree-on] ANSWER: X) PEROXISOME BONUS 2) Biology – Short Answer A commonly-used method of classifying animals is to find a shared ancestral characteristic and use it to group organisms as either within the group or outside the group. Identify all of the following three animals that are inside the group for the hinged jaw characteristic: 1) Lamprey; 2) Turtle; 3) Bass. ANSWER: 2 AND 3 High School - Round 1A Page 1 TOSS-UP 3) Math – Short Answer Solve the following equation for x: 4 divided by open parenthesis x – 6 close parenthesis equals 5 divided by open parenthesis x – 1 close parenthesis. ANSWER: 26 BONUS 3) Math – Short Answer Identify all of the following four expressions that are odd functions: 1) Cube root of x; 2) Cosine of x; 3) Tangent of x; 4) e to the x power. -
Thermodynamics and Electrochemistry of Low Temperature Fuel Cells
Thermodynamics and Electrochemistry Of Low Temperature Fuel Cells Frano Barbir Professor, FESB, Split, Croatia Joint European Summer School for Fuel Cell and Hydrogen Technology Prof. Dr. Frano Barbir energy partners What is fuel cell? Fuel cell is an electrochemical energy converter. It converts chemical energy of fuel (H 2) directly into electricity. Fuel cell is like a battery but with constant fuel and oxidant supply. heat _ hydrogen FUELBATTERY CELL DC electricity oxygen + water Fuel cell history Christian Schönbein Invention of fuel cell (1799-1868): Prof. of Phys. and Chem. in Basel, first observation of fuel cell effect (Dec. 1838, Phil. Mag.) William Robert Grove (1811 –1896): Welsh lawyer turned scientist, demonstration of fuel cell (Jan. 1839, Phil. Mag.) 1839 Fuel cell history Invention of fuel cell Scientific curiosity Friedrich Wilhelm Ostwald (1853-1932, Nobel prize 1909): founder of “Physical Chemistry”, provided much of the theoretical understanding of how fuel cells operate 1839 Friedrich Wilhelm Ostwald – visionary ideas: “I do not know whether all of us realise fully what an imperfect thing is the most essential source of power which we are using in our highly developed engineering – the steam engine” Energy conversion in combustion engines limited by Carnot efficiency unacceptable levels of atmospheric pollution vs. Energy conversion in fuel cells direct generation of electricity highly efficient, silent, no pollution Transition would be technical revolution Prediction: practical realization could take a long -
Philosophical Transactions (A)
INDEX TO THE PHILOSOPHICAL TRANSACTIONS (A) FOR THE YEAR 1889. A. A bney (W. de W.). Total Eclipse of the San observed at Caroline Island, on 6th May, 1883, 119. A bney (W. de W.) and T horpe (T. E.). On the Determination of the Photometric Intensity of the Coronal Light during the Solar Eclipse of August 28-29, 1886, 363. Alcohol, a study of the thermal properties of propyl, 137 (see R amsay and Y oung). Archer (R. H.). Observations made by Newcomb’s Method on the Visibility of Extension of the Coronal Streamers at Hog Island, Grenada, Eclipse of August 28-29, 1886, 382. Atomic weight of gold, revision of the, 395 (see Mallet). B. B oys (C. V.). The Radio-Micrometer, 159. B ryan (G. H.). The Waves on a Rotating Liquid Spheroid of Finite Ellipticity, 187. C. Conroy (Sir J.). Some Observations on the Amount of Light Reflected and Transmitted by Certain 'Kinds of Glass, 245. Corona, on the photographs of the, obtained at Prickly Point and Carriacou Island, total solar eclipse, August 29, 1886, 347 (see W esley). Coronal light, on the determination of the, during the solar eclipse of August 28-29, 1886, 363 (see Abney and Thorpe). Coronal streamers, observations made by Newcomb’s Method on the Visibility of, Eclipse of August 28-29, 1886, 382 (see A rcher). Cosmogony, on the mechanical conditions of a swarm of meteorites, and on theories of, 1 (see Darwin). Currents induced in a spherical conductor by variation of an external magnetic potential, 513 (see Lamb). 520 INDEX. -
Complete List of CHRISTMAS LECTURES
Complete list of CHRISTMAS LECTURES Year Lecturer Title of the lecture series 1825 John Millington ‘Natural philosophy’ 1826 J Wallis ‘Astronomy’ 1827 Michael Faraday ‘Chemistry’ 1828 J Wood ‘Architecture’ 1829 Michael Faraday ‘Electricity’ 1830 Thomas Webster ‘Geology’ 1831 James Rennie ‘Zoology’ 1832 Michael Faraday ‘Chemistry’ 1833 John Lindley ‘Botany’ 1834 William Thomas Brande ‘Chemistry’ 1835 Michael Faraday ‘Electricity’ 1836 William Thomas Brande ‘Chemistry of the gases’ 1837 Michael Faraday ‘Chemistry’ 1838 J Wallis ‘Astronomy’ 1839 William Thomas Brande ‘The Chemistry of the atmosphere and the ocean’ 1840 John Frederic Daniell ‘The first principles of franklinic electricity’ 1841 Michael Faraday ‘The rudiments of chemistry’ 1842 William Thomas Brande ‘The chemistry of the non–metallic elements’ 1843 Michael Faraday ‘First principles of electricity’ 1844 William Thomas Brande ‘The chemistry of the gases’ 1845 Michael Faraday ‘The rudiments of chemistry’ 1846 J Wallis ‘The rudiments of astronomy’ 1847 William Thomas Brande ‘The elements of organic chemistry’ 1848 Michael Faraday ‘The chemical history of a candle’ 1849 Robert Walker ‘The properties of matter and the laws of motion’ 1850 William Thomas Brande ‘The chemistry of coal’ 1851 Michael Faraday ‘Attractive forces’ 1852 Michael Faraday ‘Chemistry’ 1853 Michael Faraday ‘Voltaic electricity’ 1854 Michael Faraday ‘The chemistry of combustion’ 1855 Michael Faraday ‘The distinctive properties of the common metals’ 1856 Michael Faraday ‘Attractive forces’ 1857 Michael Faraday -
The Early History of Telegraphy
VOLUME 26 268 PHILIPS TECHNICAL REVIEW The early history of telegraphy G. R. M. Garratt 621.394(091) It has been said that the history of the art of commu- cian in The Hague tried to explain the causes of the .nication is the history of the human race. While such astonishing military successes of the French which had a statement is perhaps too sweeping, it is undoubtedly occurred in the meantime, he mentioned several factors: a fact that the development of communication is an in- " ... courage, aided by inventiveness which yielded the tegral part ofthe growth of civilization, Every improve- useful telegraph, the application of the balloon, an ample ment in the speed and facility with which thoughts production of saltpetre and ingenious strategic plans" [11. and ideas can be exchanged has had its social or econo- It is certainly not without significanee that it was the mic effect, and we can appreciate fully the significanee telegraph, the device which had permitted coordina- and trend of historical, social and political develop- tion of efforts on different fronts, which was given ments only if we view them against the background of priority of mention in this quotation. The telegraph the contemporary state of the art of communication. referred to was the visual telegraph or Semaphore Momentous changes in the art of communication devised by Claude Chappe. were initiated in the first half of the 19th century, and Claude Chappe - nephew of a well-known astron- in the context of this special issue of Philips Technical omer- had shown a keen interest in science when still Review it seems worth while to give some attention to a young man and had published several articles in the this most interesting period. -
Cambridge University Press 978-1-108-41966-6 — the Victorian Palace of Science Edward J
Cambridge University Press 978-1-108-41966-6 — The Victorian Palace of Science Edward J. Gillin Index More Information Index A Geological Manual,94 Albemarle Street, 68 A Preliminary Discourse on the Study of Albert, Prince, 160, 195 Natural philosophy,4 anti slavery, 158 A rudimentary treatise on clock and at the British Association, 68 watchmaking, 245 Michael Faraday, 184 Aberdeen, University of, 29 Alison, Archibald, 50–52 abolition of slavery, 3, 91, 158 on architecture, 51, 52 Acland, Thomas, 198 on Parliament, 51 acoustics, 30, 31, 56, 58, 59, 84, 140, 143 on utility, 52 Adams, Robert, 116, 117 political views, 51 Admiralty, 224 All Saint’s Church, Babbacombe, 120 Airy, George Biddell, 203, 216, 218, 220, All Souls College, Oxford, 95 232, 233, 238, 244, 252, 253, 256, An Introduction to the Study of Chemical 262, 263, 267, 268, 271 Philosophy,99 accuracy, 214, 224, 225, 237 Anderson, John Wilson, 131, 132 as Astronomer Royal, 221–23 Anglican, 6, 244 at Cambridge, 220 architecture, 109 at Greenwich, 216, 217, 221–23, 224, Broad Church, 6 225, 231 Cornwall, 188 authority over Edward John Dent, 250–51 geology, 107 career, 220 governance, 51 compass deviation, 221 High Church, 47, 106 dispute with Benjamin Vulliamy, 234–38 John Frederic Daniell, 99 Edmund Beckett Denison, 216 science, 5 Edward John Dent, 219, 225–26, 237 theology, 4 galvanic regulation, 217 universities, 125 galvanic time system, 227, 228–32, Anning, Mary, 91 238–44, 252, 253, 258 Ansted, David, 266 Greenwich time, 217 Anston stone, 102, 115, 117, 118, 265, Greenwich -
BENJAMIN SILLIMAN JR.’S 1874 PAPERS: AMERICAN CONTRIBUTIONS to CHEMISTRY 22 Martin D
BULLETIN FOR THE HISTORY OF CHEMISTRY Division of the History of Chemistry of the American Chemical Society VOLUME 36 Number 1 2011 Celebrate the International Year of Chemistry with HIST and ACS BULLETIN FOR THE HISTORY OF CHEMISTRY VOLUME 36, CONTENTS NUMBER 1 CHAIRS’ LETTER 1 EDITOR’S LETTER 2 “NOTITIA CŒRULEI BEROLINENSIS NUPER INVENTI” ON THE 300th ANNIVERSARY OF THE FIRST PUBLICATION ON PRUSSIAN BLUE 3 Alexander Kraft, Gesimat GmbH, Berlin PHYSICAL CHEMISTRY BEFORE OSTWALD: THE TEXTBOOKS OF JOSIAH PARSONS COOKE 10 William B. Jensen, University of Cincinnati BENJAMIN SILLIMAN JR.’S 1874 PAPERS: AMERICAN CONTRIBUTIONS TO CHEMISTRY 22 Martin D. Saltzman, Providence College THE RISE AND FALL OF DOMESTIC CHEMISTRY IN HIGHER EDUCATION IN ENGLAND DURING THE EARLY 20TH CENTURY 35 Marelene Rayner-Canham and Geoff Rayner-Canham Grenfell Campus, Memorial University, Corner Brook, Newfoundland DENISON-HACKH STRUCTURE SYMBOLS: A FORGOTTEN EPISODE IN THE TEACHING OF ORGANIC CHEMISTRY 43 William B. Jensen, University of Cincinnati LETTER: Vedic Hinduism and the Four Elements 51 BOOK REVIEWS Pharmacy and Drug Lore in Antiquity: Greece, Rome, Byzantium 52 Materials and Expertise in Early Modern Europe 54 The Historiography of the Chemical Revolution: Patterns of Interpretatrion in the History of Science 56 Much Ado about (Practically) Nothing: A History of the Noble Gases 57 The Poisoner’s Handbook: Murder and the Birth of Forensic Medicine in Jazz Age New York 58 Bull. Hist. Chem., VOLUME 36, Number 1 (2011) 1 CHAIRS’ LETTER Dear Fellow HIST Members, Readers, and Friends of the Bulletin for the History of Chemistry, We, the undersigned Chairs, past and current, of the Division of History of Chemistry of the American Chemical Society, along with our Secretary-Treasurer for the last 16 years, join our entire community in acknowledging our gratitude to Paul R. -
Ccitt Itu-T 1956 2006 50Years
International Telecommunication Union 1956 0YEARS 2006 1 505 YEARS OF EXCELLENCE CCITT ITU-T 1956 2006 50YEARS 20 July 2006 www.itu.int/ITU-T/50/ CCITT / ITU-T 1956 - 2006 Etymology Telecommunication is the communication of information over a distance and the term is commonly used to refer to communication using some type of signalling or the transmission and reception of electromagnetic energy. The word comes from a combination of the Greek tele, meaning ‘far’, and the Latin communicatio- nem, meaning to impart, to share – literally: to make common. It is the discipline that studies the principles of transmitting information and the methods by which that information is delivered, such as print, radio or television, etc. Visual/optical telegraphs Early forms of telecommunication Telecommunications predate the tele- and stimulated Lord George Murray to Boston, and its purpose was to transmit phone. The first forms of telecommu- propose a system of visual telegraphy to news about shipping. nication were optical telegraphs using the British Admiralty. A chain of 15 tow- visual means of transmission, such as er stations was set up for the Admiralty In the late 19th century, the British Roy- smoke signals and beacons, and have between London and Deal at a cost of al Navy pioneered the use of the Aldis, existed since ancient times. nearly GBP 4 000; others followed to or signal lamp, which, using a focused Portsmouth, Yarmouth and Plymouth. lamp, produced pulses of light in Morse A significant telecommunication de- code. Invented by A.C.W Aldis, the velopment took place in the late eigh- In the United States, the first visual tele- lamps were used until the end of the 2 teenth century with the invention of graph based on the semaphore principle 20th century and were usually equipped semaphore.