SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name: DURAD® 220B-EP
Product Use Description: Additive Processing aid
Synonyms: DURAD 220B-EP
Company: LANXESS Solutions US Inc. 2 Armstrong Road Shelton, Ct 06484 United States of America (USA)
Telephone: (US) +1 866-430-2775
Emergency telephone CHEMTREC: (24 hours) 800-424-9300 number: : : US : 800-292-5898 (Technical inquiries)
For additional emergency telephone numbers see section 16 of the Safety Data Sheet.
Prepared by Product Safety Department (US) +1 866-430-2775
Recommended use of the chemical and restrictions on use
Recommended use : Additive, Processing aid
Restrictions on use : For R&D use only. Not for pharmaceutical, household or other uses.
SECTION 2. HAZARDS IDENTIFICATION
Form liquid Colour clear Odour none
GHS Classification Skin irritation : Category 2 Serious eye damage : Category 1 Long-term (chronic) aquatic : Category 2
SAP 6.0 SDS 2012-2 NA GHS 1 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
hazard
GHS label elements
Signal word : Danger
Hazard pictograms :
Hazard statements : H315 Causes skin irritation. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects.
Other hazards : None
Precautionary statements : Prevention: P264 Wash skin thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P391 Collect spillage. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
SAP 6.0 SDS 2012-2 NA GHS 2 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Chemical name CAS-No. Concentration (%) Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%] 68937-40-6 >= 90 - < 100 % Alcohols, C4-18, reaction products with phosphorus oxide (P2O5) 92257-02-8 >= 3 - < 5 % decan-1-ol 112-30-1 >= 0.1 - < 0.25 %
SECTION 4. FIRST AID MEASURES
If inhaled : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. Call a physician or poison control centre immediately. If breathing is difficult, give oxygen. Keep respiratory tract clear.
In case of skin contact : Wash off with soap and plenty of water. If symptoms persist, call a physician. Take off contaminated clothing and wash before reuse.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist.
If swallowed : Call a physician or poison control centre immediately. Rinse mouth with water. If victim is fully conscious, give a cupful of water. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Do not give milk or alcoholic beverages.
Most important symptoms : No information available. and effects, both acute and delayed No information available.
Notes to physician : No information available.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
SAP 6.0 SDS 2012-2 NA GHS 3 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water firefighting courses. Burning produces irritant fumes. Burning produces noxious and toxic fumes.
Specific extinguishing : Collect contaminated fire extinguishing water separately. This methods must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment : Wear full protective clothing and self-contained breathing for firefighters apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Use personal protective equipment. protective equipment and Ensure adequate ventilation. emergency procedures Evacuate personnel to safe areas. Material can create slippery conditions.
Environmental precautions : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Avoid release to the environment.
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel, containment and cleaning up acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : For personal protection see section 8. No special handling advice required. Dispose of rinse water in accordance with local and national regulations.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.
Materials to avoid : Strong oxidizing agents
SAP 6.0 SDS 2012-2 NA GHS 4 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Basis Components CAS-No. Form of Permissible exposure concentration
Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required.
Hand protection Remarks : Polyvinyl alcohol or nitrile- butyl-rubber gloves Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems.
Skin and body protection : Protective suit
Hygiene measures : General industrial hygiene practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : clear Odor : none pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : 230 °C Method: Cleveland open cup
Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available
SAP 6.0 SDS 2012-2 NA GHS 5 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
Density : No data available Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available
Partition coefficient: n- : No data available octanol/water Auto-ignition temperature : No data available Thermal decomposition : No data available
Viscosity Viscosity, kinematic : 45.1 mm2/s (40 °C)
Molecular weight : No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable under recommended storage conditions.
Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous : No hazards to be specially mentioned. reactions Conditions to avoid : Heat, flames and sparks. Contamination
Incompatible materials : Strong oxidizing agents
Hazardous decomposition : products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Oxides of phosphorus
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Components: decan-1-ol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
SAP 6.0 SDS 2012-2 NA GHS 6 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
Acute inhalation toxicity : LC50 (Rat): > 2.05 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity
Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Components: decan-1-ol: Species: Rabbit Result: No skin irritation
Serious eye damage/eye irritation
Components: decan-1-ol: Species: Rabbit Result: Irritating to eyes.
Respiratory or skin sensitisation
Components: decan-1-ol: Test Type: Buehler Test Species: Guinea pig Result: Does not cause skin sensitisation.
Germ cell mutagenicity
Components: decan-1-ol: Genotoxicity in vitro : Result: negative
Germ cell mutagenicity - : Animal testing did not show any mutagenic effects. Assessment
Carcinogenicity
Components: decan-1-ol: Carcinogenicity - : Not classifiable as a human carcinogen. Assessment
IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
SAP 6.0 SDS 2012-2 NA GHS 7 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Components: Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%]: Reproductive toxicity - : Based on available data, the classification criteria are not Assessment met., No effects on fertility and early embryonic development were detected.
decan-1-ol: Reproductive toxicity - : No toxicity to reproduction Assessment No toxicity to reproduction
Repeated dose toxicity
Components: decan-1-ol: Species: Rat NOAEL: 1,000 mg/kg Application Route: Oral Remarks: No adverse effect has been observed in chronic toxicity tests.
Species: Rat LOAEL: 100 mg/kg Application Route: Dermal Exposure time: 90 d
Species: Rat NOAEL: 0.057 mg/l Application Route: inhalation (dust/mist/fume) Exposure time: 20 d
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
decan-1-ol: Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 2.4 mg/l Exposure time: 96 h Test Type: flow-through test
SAP 6.0 SDS 2012-2 NA GHS 8 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.8 mg/l aquatic invertebrates Exposure time: 48 h Test Type: semi-static test
Toxicity to algae : ErC50 (Navicula pelliculosa): 1.4 mg/l Exposure time: 72 h Test Type: static test
Toxicity to fish (Chronic : NOEC: 0.0064 mg/l toxicity) Exposure time: 28 d
Toxicity to daphnia and other : NOEC: 0.51 mg/l aquatic invertebrates Exposure time: 21 d (Chronic toxicity)
Persistence and degradability
Product: Biodegradability : Remarks: No data available
Components:
Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%]: Biodegradability : GLP: yes Remarks: Readily biodegradable.
decan-1-ol: Biodegradability : Result: Not readily biodegradable.
Stability in water : Hydrolysis: 3.4 % at50 °C(5 d)
Hydrolysis: 4.0 % at50 °C(5 d)
Hydrolysis: 8.3 % at50 °C(5 d)
Bioaccumulative potential
Product: Bioaccumulation : Remarks: No data available
Components:
decan-1-ol: Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 4.11 - 4.23 octanol/water
SAP 6.0 SDS 2012-2 NA GHS 9 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
Mobility in soil
Components:
decan-1-ol: Mobility : Remarks: No data available
Stability in soil :
Other adverse effects
Components:
decan-1-ol: Results of PBT and vPvB : This substance is not considered to be persistent, assessment bioaccumulating and toxic (PBT).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Dispose of wastes in an approved waste disposal facility. The product should not be allowed to enter drains, water courses or the soil. In accordance with local and national regulations. Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR UN/ID No. : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%]) Class : 9 Packing group : III Labels : Miscellaneous IMDG-Code
SAP 6.0 SDS 2012-2 NA GHS 10 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
UN number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%]) Class : 9 Packing group : III Labels : 9 EmS Code : F-A, S-F Marine pollutant : yes Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations
49 CFR UN/ID/NA number : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%]) Class : 9 Packing group : III Labels : CLASS 9 ERG Code : 171 Marine pollutant : yes(Phenol, isobutylenated, phosphate [Triphenyl phosphate ≥ 2.5 < 25%]) Remarks : Shipment by ground under DOT is non-regulated; however it may be shipped per the applicable hazard classification to facilitate multi-modal transport involving ICAO (IATA) or IMO.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA304 Reportable Quantity This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Skin corrosion or irritation Serious eye damage or eye irritation
SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SAP 6.0 SDS 2012-2 NA GHS 11 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US State Regulations
California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Please note that Section 3 of this document lists only the hazardous components required by the specific country or region hazard communication regulations. The chemical identifiers listed in Section 3 are used globally for hazard communication purposes and may not reflect those used for chemical inventory coverage in a particular country or region. The chemical inventory information given in Section 15 of this document applies to the product as a whole and should be used when evaluating inventory compliance.
The components of this product are reported in the following inventories: DSL This product contains one or several components that are not on the Canadian DSL nor NDSL. AICS On the inventory, or in compliance with the inventory NZIoC Not in compliance with the inventory ENCS On the inventory, or in compliance with the inventory KECI Not in compliance with the inventory PICCS Not in compliance with the inventory IECSC On the inventory, or in compliance with the inventory TCSI On the inventory, or in compliance with the inventory US.TSCA On TSCA Inventory
SECTION 16. OTHER INFORMATION
Further information
Other Emergency Phone Number
Latin America: Brazil +55 113 711 9144 All other countries +44 (0) 1235 239 670 Mexico: +52 555 004 8763
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to
SAP 6.0 SDS 2012-2 NA GHS 12 / 13 SDS Number: 000000043659
SAFETY DATA SHEET
DURAD® 220B-EP
Version: 1.5 Revision Date: 09/04/2018 Print Date: 03/12/2019
the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
SAP 6.0 SDS 2012-2 NA GHS 13 / 13 SDS Number: 000000043659