How Clean Are Hydrogen Fuel Cell Electric Vehicles?
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An Alternate Graphical Representation of Periodic Table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt
An Alternate Graphical Representation of Periodic table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt. Ltd, Hyderabad, India. [email protected] Abstract Periodic table of chemical elements symbolizes an elegant graphical representation of symmetry at atomic level and provides an overview on arrangement of electrons. It started merely as tabular representation of chemical elements, later got strengthened with quantum mechanical description of atomic structure and recent studies have revealed that periodic table can be formulated using SO(4,2) SU(2) group. IUPAC, the governing body in Chemistry, doesn‟t approve any periodic table as a standard periodic table. The only specific recommendation provided by IUPAC is that the periodic table should follow the 1 to 18 group numbering. In this technical paper, we describe a new graphical representation of periodic table, referred as „Circular form of Periodic table‟. The advantages of circular form of periodic table over other representations are discussed along with a brief discussion on history of periodic tables. 1. Introduction The profoundness of inherent symmetry in nature can be seen at different depths of atomic scales. Periodic table symbolizes one such elegant symmetry existing within the atomic structure of chemical elements. This so called „symmetry‟ within the atomic structures has been widely studied from different prospects and over the last hundreds years more than 700 different graphical representations of Periodic tables have emerged [1]. Each graphical representation of chemical elements attempted to portray certain symmetries in form of columns, rows, spirals, dimensions etc. Out of all the graphical representations, the rectangular form of periodic table (also referred as Long form of periodic table or Modern periodic table) has gained wide acceptance. -
The Piedmont Service: Hydrogen Fuel Cell Locomotive Feasibility
The Piedmont Service: Hydrogen Fuel Cell Locomotive Feasibility Andreas Hoffrichter, PhD Nick Little Shanelle Foster, PhD Raphael Isaac, PhD Orwell Madovi Darren Tascillo Center for Railway Research and Education Michigan State University Henry Center for Executive Development 3535 Forest Road, Lansing, MI 48910 NCDOT Project 2019-43 FHWA/NC/2019-43 October 2020 -i- FEASIBILITY REPORT The Piedmont Service: Hydrogen Fuel Cell Locomotive Feasibility October 2020 Prepared by Center for Railway Research and Education Eli Broad College of Business Michigan State University 3535 Forest Road Lansing, MI 48910 USA Prepared for North Carolina Department of Transportation – Rail Division 860 Capital Boulevard Raleigh, NC 27603 -ii- Technical Report Documentation Page 1. Report No. 2. Government Accession No. 3. Recipient’s Catalog No. FHWA/NC/2019-43 4. Title and Subtitle 5. Report Date The Piedmont Service: Hydrogen Fuel Cell Locomotive Feasibility October 2020 6. Performing Organization Code 7. Author(s) 8. Performing Organization Report No. Andreas Hoffrichter, PhD, https://orcid.org/0000-0002-2384-4463 Nick Little Shanelle N. Foster, PhD, https://orcid.org/0000-0001-9630-5500 Raphael Isaac, PhD Orwell Madovi Darren M. Tascillo 9. Performing Organization Name and Address 10. Work Unit No. (TRAIS) Center for Railway Research and Education 11. Contract or Grant No. Michigan State University Henry Center for Executive Development 3535 Forest Road Lansing, MI 48910 12. Sponsoring Agency Name and Address 13. Type of Report and Period Covered Final Report Research and Development Unit 104 Fayetteville Street December 2018 – October 2020 Raleigh, North Carolina 27601 14. Sponsoring Agency Code RP2019-43 Supplementary Notes: 16. -
Power Sources Challenge
POWER SOURCES CHALLENGE FUSION PHYSICS! A CLEAN ENERGY Summary: What if we could harness the power of the Sun for energy here on Fusion reactions occur when two nuclei come together to form one Earth? What would it take to accomplish this feat? Is it possible? atom. The reaction that happens in the sun fuses two Hydrogen atoms together to produce Helium. It looks like this in a very simplified way: Many researchers including our Department of Energy scientists and H + H He + ENERGY. This energy can be calculated by the famous engineers are taking on this challenge! In fact, there is one DOE Laboratory Einstein equation, E = mc2. devoted to fusion physics and is committed to being at the forefront of the science of magnetic fusion energy. Each of the colliding hydrogen atoms is a different isotope of In order to understand a little more about fusion energy, you will learn about hydrogen, one deuterium and one the atom and how reactions at the atomic level produce energy. tritium. The difference in these isotopes is simply one neutron. Background: It all starts with plasma! If you need to learn more about plasma Deuterium has one proton and one physics, visit the Power Sources Challenge plasma activities. neutron, tritium has one proton and two neutrons. Look at the The Fusion Reaction that happens in the SUN looks like this: illustration—do you see how the mass of the products is less than the mass of the reactants? That is called a mass deficit and that difference in mass is converted into energy. -
Fuel Cells on Bio-Gas
Fuel Cells on Bio-Gas 2009 Michigan Water Environment Association's (MWEA) Biosolids and Energy Conference Robert J. Remick, PhD March 4, 2009 NREL/PR-560-45292 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Wastewater Treatment Plants • WWTP operators are looking for opportunities to utilize biogas as a renewable energy source. • Majority use biogas through boilers for reheating • Interest is growing in distributed generation, especially where both electricity and fuel costs are high. • Drivers for the decision to purchase fuel cells – Reliability – Capital and O&M costs – Availability of Government Incentives National Renewable Energy Laboratory Innovation for Our Energy Future Anaerobic Digestion and Biogas • Anaerobic digestion is a process used to stabilize Range of Biogas Compositions wastewater sludge before final disposal. Methane 50% – 75% Carbon Dioxide 25% – 50% • The process uses Nitrogen 0% – 10% microorganisms in the Hydrogen 0% – 1% absence of oxygen to Sulfur Species 0% – 3% convert organic Oxygen 0% – 2% materials to biogas. National Renewable Energy Laboratory Innovation for Our Energy Future WWTP Co-Gen Market • There are over 16,800 WWTP in the U.S. • 615 facilities with flows > 3 mgd that use anaerobic digestion • 215 do not use their biogas but flare it instead. • California has the highest number of municipal facilities using anaerobic digestion, about 102, of which 25 do not use their biogas. -
Fuel Properties Comparison
Alternative Fuels Data Center Fuel Properties Comparison Compressed Liquefied Low Sulfur Gasoline/E10 Biodiesel Propane (LPG) Natural Gas Natural Gas Ethanol/E100 Methanol Hydrogen Electricity Diesel (CNG) (LNG) Chemical C4 to C12 and C8 to C25 Methyl esters of C3H8 (majority) CH4 (majority), CH4 same as CNG CH3CH2OH CH3OH H2 N/A Structure [1] Ethanol ≤ to C12 to C22 fatty acids and C4H10 C2H6 and inert with inert gasses 10% (minority) gases <0.5% (a) Fuel Material Crude Oil Crude Oil Fats and oils from A by-product of Underground Underground Corn, grains, or Natural gas, coal, Natural gas, Natural gas, coal, (feedstocks) sources such as petroleum reserves and reserves and agricultural waste or woody biomass methanol, and nuclear, wind, soybeans, waste refining or renewable renewable (cellulose) electrolysis of hydro, solar, and cooking oil, animal natural gas biogas biogas water small percentages fats, and rapeseed processing of geothermal and biomass Gasoline or 1 gal = 1.00 1 gal = 1.12 B100 1 gal = 0.74 GGE 1 lb. = 0.18 GGE 1 lb. = 0.19 GGE 1 gal = 0.67 GGE 1 gal = 0.50 GGE 1 lb. = 0.45 1 kWh = 0.030 Diesel Gallon GGE GGE 1 gal = 1.05 GGE 1 gal = 0.66 DGE 1 lb. = 0.16 DGE 1 lb. = 0.17 DGE 1 gal = 0.59 DGE 1 gal = 0.45 DGE GGE GGE Equivalent 1 gal = 0.88 1 gal = 1.00 1 gal = 0.93 DGE 1 lb. = 0.40 1 kWh = 0.027 (GGE or DGE) DGE DGE B20 DGE DGE 1 gal = 1.11 GGE 1 kg = 1 GGE 1 gal = 0.99 DGE 1 kg = 0.9 DGE Energy 1 gallon of 1 gallon of 1 gallon of B100 1 gallon of 5.66 lb., or 5.37 lb. -
Comparison of Hydrogen Powertrains with the Battery Powered Electric Vehicle and Investigation of Small-Scale Local Hydrogen Production Using Renewable Energy
Review Comparison of Hydrogen Powertrains with the Battery Powered Electric Vehicle and Investigation of Small-Scale Local Hydrogen Production Using Renewable Energy Michael Handwerker 1,2,*, Jörg Wellnitz 1,2 and Hormoz Marzbani 2 1 Faculty of Mechanical Engineering, University of Applied Sciences Ingolstadt, Esplanade 10, 85049 Ingolstadt, Germany; [email protected] 2 Royal Melbourne Institute of Technology, School of Engineering, Plenty Road, Bundoora, VIC 3083, Australia; [email protected] * Correspondence: [email protected] Abstract: Climate change is one of the major problems that people face in this century, with fossil fuel combustion engines being huge contributors. Currently, the battery powered electric vehicle is considered the predecessor, while hydrogen vehicles only have an insignificant market share. To evaluate if this is justified, different hydrogen power train technologies are analyzed and compared to the battery powered electric vehicle. Even though most research focuses on the hydrogen fuel cells, it is shown that, despite the lower efficiency, the often-neglected hydrogen combustion engine could be the right solution for transitioning away from fossil fuels. This is mainly due to the lower costs and possibility of the use of existing manufacturing infrastructure. To achieve a similar level of refueling comfort as with the battery powered electric vehicle, the economic and technological aspects of the local small-scale hydrogen production are being investigated. Due to the low efficiency Citation: Handwerker, M.; Wellnitz, and high prices for the required components, this domestically produced hydrogen cannot compete J.; Marzbani, H. Comparison of with hydrogen produced from fossil fuels on a larger scale. -
EPRI Journal--Driving the Solution: the Plug-In Hybrid Vehicle
DRIVING THE SOLUTION THE PLUG-IN HYBRID VEHICLE by Lucy Sanna The Story in Brief As automakers gear up to satisfy a growing market for fuel-efficient hybrid electric vehicles, the next- generation hybrid is already cruis- ing city streets, and it can literally run on empty. The plug-in hybrid charges directly from the electricity grid, but unlike its electric vehicle brethren, it sports a liquid fuel tank for unlimited driving range. The technology is here, the electricity infrastructure is in place, and the plug-in hybrid offers a key to replacing foreign oil with domestic resources for energy indepen- dence, reduced CO2 emissions, and lower fuel costs. DRIVING THE SOLUTION THE PLUG-IN HYBRID VEHICLE by Lucy Sanna n November 2005, the first few proto vide a variety of battery options tailored 2004, more than half of which came from Itype plugin hybrid electric vehicles to specific applications—vehicles that can imports. (PHEVs) will roll onto the streets of New run 20, 30, or even more electric miles.” With growing global demand, particu York City, Kansas City, and Los Angeles Until recently, however, even those larly from China and India, the price of a to demonstrate plugin hybrid technology automakers engaged in conventional barrel of oil is climbing at an unprece in varied environments. Like hybrid vehi hybrid technology have been reluctant to dented rate. The added cost and vulnera cles on the market today, the plugin embrace the PHEV, despite growing rec bility of relying on a strategic energy hybrid uses battery power to supplement ognition of the vehicle’s potential. -
Unique Properties of Water!
Name: _______ANSWER KEY_______________ Class: _____ Date: _______________ Unique Properties of Water! Word Bank: Adhesion Evaporation Polar Surface tension Cohesion Freezing Positive Universal solvent Condensation Melting Sublimation Dissolve Negative 1. The electrons are not shared equally between the hydrogen and oxygen atoms of water creating a Polar molecule. 2. The polarity of water allows it to dissolve most substances. Because of this it is referred to as the universal solvent 3. Water molecules stick to other water molecules. This property is called cohesion. 4. Hydrogen bonds form between adjacent water molecules because the positive charged hydrogen end of one water molecule attracts the negative charged oxygen end of another water molecule. 5. Water molecules stick to other materials due to its polar nature. This property is called adhesion. 6. Hydrogen bonds hold water molecules closely together which causes water to have high surface tension. This is why water tends to clump together to form drops rather than spread out into a thin film. 7. Condensation is when water changes from a gas to a liquid. 8. Sublimation is when water changes from a solid directly to a gas. 9. Freezing is when water changes from a liquid to a solid. 10. Melting is when water changes from a solid to a liquid. 11. Evaporation is when water changes from a liquid to a gas. 12. Why does ice float? Water expands as it freezes, so it is LESS DENSE AS A SOLID. 13. What property refers to water molecules resembling magnets? How are these alike? Polar bonds create positive and negative ends of the molecule. -
Waste-To-Energy and Fuel Cell Technologies Overview
Innovation for Our Energy Future Waste-to-Energy and Fuel Cell ThTechnol ogi es O vervi ew Presented to: DOD-DOE Waste-to- Energy Workshop Dr. Robert J. Remick January 13, 2011 Capital Hilton Hotel Washington, DC NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Global Approach for Using Biogas Innovation for Our Energy Future Anaerobic Digestion of Organic Wastes is a Good Source of Methane. Organic waste + methanogenic bacteria → methane (CH4) Issues: High levels of contamination Time varying output of gas quantity and quality Photo courtesy of Dos Rios Water Recycling Center, San Antonio, TX Innovation for Our Energy Future Opportunities for Methane Production via Anaerobic Digestion • Breweries (~73 Watts per barrel of beer) • Municipal Waste Water Treatment Plants (~4 W/person) • Industrial-scale Food Processing • Landfills • Dairy and Pig Farms (~200 W/Cow) • Pulp and Paper Mills Innovation for Our Energy Future Stationary Fuel Cell Products Currently on the Maaetrket aaere Confi gured to Oper ate on Natura l Gas UTC Power, Inc. PureCell 400 FlCllFuelCell EIEnergy Inc. DFC 300, 1500, an d 3000 Bloom Energy, Inc. ES-5000 Energy Server Waste processes that produce methane, like anaerobic digestion of organic matter, are most easily mated to these fuel cell systems. Innovation for Our Energy Future Comparison by Generator Type (based on 40-million SCF* of bioggpyas per year** ) Generator Type Megawatt‐hours/year PAFC 2,900 MCFC 3,300 Micro‐tbiturbine 1, 800 Reciprocating Engine 1,500 * ~830 Btu/SCF (HHV) ** WWTP serving a community of about 110,000 people This comparison ignores the fact that generators do not come in an infinite range of sizes. -
Making Markets for Hydrogen Vehicles: Lessons from LPG
Making Markets for Hydrogen Vehicles: Lessons from LPG Helen Hu and Richard Green Department of Economics and Institute for Energy Research and Policy University of Birmingham Birmingham B15 2TT United Kingdom Hu: [email protected] Green: [email protected] +44 121 415 8216 (corresponding author) Abstract The adoption of liquefied petroleum gas vehicles is strongly linked to the break-even distance at which they have the same costs as conventional cars, with very limited market penetration at break-even distances above 40,000 km. Hydrogen vehicles are predicted to have costs by 2030 that should give them a break-even distance of less than this critical level. It will be necessary to ensure that there are sufficient refuelling stations for hydrogen to be a convenient choice for drivers. While additional LPG stations have led to increases in vehicle numbers, and increases in vehicles have been followed by greater numbers of refuelling stations, these effects are too small to give self-sustaining growth. Supportive policies for both vehicles and refuelling stations will be required. 1. Introduction While hydrogen offers many advantages as an energy vector within a low-carbon energy system [1, 2, 3], developing markets for hydrogen vehicles is likely to be a challenge. Put bluntly, there is no point in buying a vehicle powered by hydrogen, unless there are sufficient convenient places to re-fuel it. Nor is there any point in providing a hydrogen refuelling station unless there are vehicles that will use the facility. What is the most effective way to get round this “chicken and egg” problem? Data from trials of hydrogen vehicles can provide information on driver behaviour and charging patterns, but extrapolating this to the development of a mass market may be difficult. -
Prospects for Bi-Fuel and Flex-Fuel Light Duty Vehicles
Prospects for Bi-Fuel and Flex-Fuel Light-Duty Vehicles An MIT Energy Initiative Symposium April 19, 2012 MIT Energy Initiative Symposium on Prospects for Bi-Fuel and Flex-Fuel Light-Duty Vehicles | April 19, 2012 C Prospects for Bi-Fuel and Flex-Fuel Light-Duty Vehicles An MIT Energy Initiative Symposium April 19, 2012 ABOUT THE REPORT Summary for Policy Makers The April 19, 2012, MIT Energy Initiative Symposium addressed Prospects for Bi-Fuel and Flex-Fuel Light-Duty Vehicles. The symposium focused on natural gas, biofuels, and motor gasoline as fuels for light-duty vehicles (LDVs) with a time horizon of the next two to three decades. The important transportation alternatives of electric and hybrid vehicles (this was the subject of the 2010 MITEi Symposium1) and hydrogen/fuel-cell vehicles, a longer-term alternative, were not considered. There are three motivations for examining alternative transportation fuels for LDVs: (1) lower life cycle cost of transportation for the consumer, (2) reduction in the greenhouse gas (GHG) footprint of the transportation sector (an important contributor to total US GHG emissions), and (3) improved energy security resulting from greater use of domestic fuels and reduced liquid fuel imports. An underlying question is whether a flex-fuel/bi-fuel mandate for new LDVs would drive development of a robust alternative fuels market and infrastructure versus alternative fuel use requirements. Symposium participants agreed on these motivations. However, in this symposium in contrast to past symposiums, there was a striking lack of agreement about the direction to which the market might evolve, about the most promising technologies, and about desirable government action. -
Lithium Hydride Powered PEM Fuel Cells for Long-Duration Small Mobile Robotic Missions
Lithium Hydride Powered PEM Fuel Cells for Long-Duration Small Mobile Robotic Missions Jekanthan Thangavelautham, Daniel Strawser, Mei Yi Cheung Steven Dubowsky Abstract— This paper reports on a study to develop power supplies for small mobile robots performing long duration missions. It investigates the use of fuel cells to achieve this objective, and in particular Proton Exchange Membrane (PEM) fuel cells. It is shown through a representative case study that, in theory, fuel cell based power supplies will provide much longer range than the best current rechargeable battery technology. It also briefly discusses an important limitation that prevents fuel cells from achieving their ideal performance, namely a practical method to store their fuel (hydrogen) in a form that is compatible with small mobile field robots. A very efficient Fig. 1. Example of small robots (Left) A ball shaped hopping robot concept fuel storage concept based on water activated lithium hydride for exploration of extreme terrains and caves developed for NASA. (Right) (LiH) is proposed that releases hydrogen on demand. This iRobot 110 Firstlook used for observation, security and search and rescue. concept is very attractive because water vapor from the air is passively extracted or waste water from the fuel cell is recycled and transferred to the lithium hydride where the hydrogen is the near future. Hence, new means for powering field robots “stripped” from water and is returned to the fuel cell to form more water. This results in higher hydrogen storage efficiencies need to be considered. than conventional storage methods. Experimental results are This paper explores the use of fuel cells, and in particular presented that demonstrate the effectiveness of the approach.