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Vanadium Pentoxide and Other Inorganic Vanadium Compounds
This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organization, or the World Health Organization. Concise International Chemical Assessment Document 29 VANADIUM PENTOXIDE AND OTHER INORGANIC VANADIUM COMPOUNDS Note that the layout and pagination of this pdf file are not identical to the printed CICAD First draft prepared by Dr M. Costigan and Mr R. Cary, Health and Safety Executive, Liverpool, United Kingdom, and Dr S. Dobson, Centre for Ecology and Hydrology, Huntingdon, United Kingdom Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization, and the World Health Organization, and produced within the framework of the Inter-Organization Programme for the Sound Management of Chemicals. World Health Organization Geneva, 2001 The International Programme on Chemical Safety (IPCS), established in 1980, is a joint venture of the United Nations Environment Programme (UNEP), the International Labour Organization (ILO), and the World Health Organization (WHO). The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management -
JAN Iia 20U T6T1/V
IN REPLY REFER TO: UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY WASHINGTON 25. D.C. November 19, 1956 AEC-193/7 Mr. Robert D. Nininger Assistant Director for Exploration Division of Bav Materials U* S. Atomic Energy Commission Washington 25, D. C, Dear Bobs Transmitted herewith are three copies of TEI-622, "The crystal chemistry and mineralogy of vanadium," by Ho-ward T. Evans, Jr. Me are asking Mr. Hosted to approve our plan to publish this report as a chapter of a Geological Survey professional paper on miner alogy and geochemistry of the ores of the Colorado Plateau. Aelrnovledg- ment of AEC sponsorship will be made in the introductory chapter* Sincerely yours, r ^ O U—— TV , Z^*i—w«__ ™~ W. H. Bradley Chief Geoldigist .JAN iia 20U T6T1/V Geology and 8$i:aeralQgy This document consists of k-2 pages* Series A» Howard T. Erans, Jr, Trace Elements Investigations Report 622 This preliminary report is distributed without editorial and technical review for conformity with official standards and nomenclature. It is not for public inspection or quotation* *This report concerns work done on behalf of the Division of Raw Materials of the U. S« Atomic Energy Commission* - TEI-622 AHD MIHERALQ6T Distribution (Series A) Ro. of copies Atomic Energy Commission, Washington .»**«»..*»..«*»..««..*... 2 Division of Rs¥ Materials, Albuquerque ,...****.*.«.»*.....*.. 1 Division of Raw Materials, Austin »«,..«.»...»*.»...*«..*...«» 1 Diylsion of Raw Materials, Butte *«*,.»».*..,*...».»......*.*. 1 Division of Raw Materials, Casper ............a............... 1 Division of Raw Ifeterials, Denver ,........»...».....«.,.*..... 1 Division of Raw Materials, Ishpeming .................a....... 1 Division of Raw Materials, Pnoenix ...a.....,....*........*... 1 Division of Eaw Materials, Rapid City ....................... -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Mercury Sulfide Dimorphism in Thioarsenate Glasses Mohammad Kassem, Anton Sokolov, Arnaud Cuisset, Takeshi Usuki, Sohayb Khaoulani, Pascal Masselin, David Le Coq, M
Mercury Sulfide Dimorphism in Thioarsenate Glasses Mohammad Kassem, Anton Sokolov, Arnaud Cuisset, Takeshi Usuki, Sohayb Khaoulani, Pascal Masselin, David Le Coq, M. Feygenson, C. J. Benmore, Alex Hannon, et al. To cite this version: Mohammad Kassem, Anton Sokolov, Arnaud Cuisset, Takeshi Usuki, Sohayb Khaoulani, et al.. Mer- cury Sulfide Dimorphism in Thioarsenate Glasses. Journal of Physical Chemistry B, American Chem- ical Society, 2016, 120 (23), pp.5278 - 5290. 10.1021/acs.jpcb.6b03382. hal-01426924 HAL Id: hal-01426924 https://hal.archives-ouvertes.fr/hal-01426924 Submitted on 5 Jan 2017 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Article Mercury Sulfide Dimorphism in Thioarsenate Glasses Mohammad Kassem, Anton Sokolov, Arnaud Cuisset, Takeshi Usuki, Sohayb Khaoulani, Pascal Masselin, David Le Coq, Joerg C. Neuefeind, Mikhail Feygenson, Alex C Hannon, Chris J. Benmore, and Eugene Bychkov J. Phys. Chem. B, Just Accepted Manuscript • Publication Date (Web): 23 May 2016 Downloaded from http://pubs.acs.org on May 23, 2016 Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. -
Metacinnabar Hgs C 2001-2005 Mineral Data Publishing, Version 1
Metacinnabar HgS c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Cubic. Point Group: 43m. Commonly massive; rarely as small (to 1 mm) tetrahedral crystals having rough faces. Twinning: Common on {111}, forming lamellae in polished section. Physical Properties: Fracture: Subconchoidal. Tenacity: Brittle. Hardness = 3 VHN = n.d. D(meas.) = 7.65 D(calc.) = 7.63 Optical Properties: Opaque. Color: Grayish black; in polished section, grayish white. Streak: Black. Luster: Metallic. Pleochroism: Weak, rarely. Anisotropism: Very weak, rarely. R: (400) 28.4, (420) 27.6, (440) 26.8, (460) 26.3, (480) 25.9, (500) 25.6, (520) 25.4, (540) 25.2, (560) 25.1, (580) 25.0, (600) 24.9, (620) 24.9, (640) 24.8, (660) 24.7, (680) 24.7, (700) 24.7 Cell Data: Space Group: F 43m. a = 5.8717(5) Z = 4 X-ray Powder Pattern: Synthetic. 3.378 (100), 2.068 (55), 1.7644 (45), 2.926 (35), 1.3424 (12), 1.6891 (10), 1.3085 (10) Chemistry: (1) (2) (3) (4) Hg 79.73 67.45 81.33 86.22 Zn 4.23 3.10 Cd 11.72 Fe trace 0.2 Se 1.08 6.49 S 14.58 15.63 10.30 13.78 Total 99.62 98.10 98.12 100.00 (1) Guadalc´azar,Mexico; corresponds to (Hg0.85Zn0.14)Σ=0.99(S0.97Se0.03)Σ=1.00. (2) Uland area, Russia; corresponds to (Hg0.69Cd0.21Zn0.10Fe0.01)Σ=1.01S1.00. (3) San Onofre, Mexico; corresponds to Hg1.00(S0.80Se0.20)Σ=1.00. -
Chemistry of Formation of Lanarkite, Pb2oso 4
SHORT COMMUNICATIONS MINERALOGICAL MAGAZINE, DECEMBER 1982, VOL. 46, PP. 499-501 Chemistry of formation of lanarkite, Pb2OSO 4 W E have recently reported (Humphreys et al., 1980; sion which is at odds with the widespread occur- Abdul-Samad et al., 1982) the free energies of rence of the simple sulphate and the extreme rarity formation of a variety of chloride-bearing minerals of the basic salt, and with aqueous synthetic of Pb(II) and Cu(II) together with carbonate procedures for the preparation of the compound and sulphate species of the same metals includ- (Bode and Voss, 1959), which involve reaction of ing leadhillite, Pb,SO4(COa)2(OH)2, caledonite, angtesite in basic solution. PbsCu2CO3(SO4)3(OH)6, and linarite, (Pb,Cu)2 Kellog and Basu (1960) also determined AG~ for SO4(OH)2. By using suitable phase diagrams it has Pb2OSOa(s) at 298.16 K using the method of proved possible to reconstruct, in part, the chemical univariant equilibria in the system Pb-S-O. They history of the development of some complex obtained a value of -1016.4 kJ mol-1 based on secondary mineral assemblages such as those at literature values for PbO(s), PbS(s), PbSO4(s), and the Mammoth-St. Anthony mine, Tiger, Arizona, SO2(g) and another of - 1019.8 kJ mol- 1 based on and the halide and carbonate suite of the Mendip adjusted values for the above compounds. These Hills, Somerset. two results, for which the error was estimated to A celebrated locality for the three sulphate- be about 4.5 kJ mol-1, seem to be considerably bearing minerals above is the Leadhills-Wanlock- more compatible with observed associations than head district of Scotland (Wilson, 1921; Heddle, the earlier values. -
2012 Bmc Auction Specimens
A SAMPLER OF SELECTED 2017 BMC AUCTION SPECIMENS (2017 Auction Date is Saturday, 21 January) Volume 3 3+ Hematite [Fe 2O3] & Quartz [SiO2] Locality Cleator Moor Iron Mines Cleator Moor West Cumberland Iron Field Cumbria, England, UK Size 13.5 x 9.5 x 7.0 cm 1498 g Donated by Stonetrust Hematite Crystal System: Trigonal Photograph by Mike Haritos Physical Properties Transparency: Subtranslucent to opaque Mohs hardness: 6.5 Density: approx 5.3 gm/cm3 Streak: Red Luster: Metalic Vanadinite [Pb5(VO4)3Cl] var. Endlichite Locality Erupción Mine (Ahumada Mine) Los Lamentos Mountains (Sierra de Los Lamentos) Mun. de Ahumada Chihuahua, Mexico Size 12.0 x 9.5 x 7.0 cm 1134 g Donated by Stonetrust Crystal System: Hexagonal Physical Properties Transparency: Subtranslucent to opaque Mohs hardness: 3.5-4 Photograph by Mike Haritos Density: 6.8 to 7.1 gm/cm3 Streak: Brownish yellow Endlichite, Pb5([V, As]O4)3Cl, is the arsenic rich Luster: Adamantine variety of vanadinite with arsenic atoms (As) substituting for some of the vanadium (V) 2+ Dolomite [CaMg(CO3)2] & Chalcopyrite [CuFe S2] Locality Picher Field Tri-State District Ottawa Co. Oklahoma, USA Size 19.0 x 14.5 x 6.0 cm 1892 g Consigned with Reserve by Stonetrust Dolomite Crystal System: Trigonal Physical Properties Photograph by Mike Haritos Transparency: Transparent, Translucent, Opaque Mohs hardness: 3.5 to 4 Density: 2.8 to 2.9 gm/cm3 Streak: White Luster: Vitreous Calcite [CaCO3] Locality Mexico Size 15.5 x 12.8 x 6.2 cm 1074 g Donated by Stonetrust Calcite Crystal System: Trigonal Physical Properties Transparency: Transparent, Translucent Mohs hardness: 3 Density: 2.71 gm/cm3 Streak: White Luster: Vitreous, Sub-Vitreous, Photograph by Mike Haritos Resinous, Waxy, Pearly Quartz [SiO2], var. -
Adsorption of RNA on Mineral Surfaces and Mineral Precipitates
Adsorption of RNA on mineral surfaces and mineral precipitates Elisa Biondi1,2, Yoshihiro Furukawa3, Jun Kawai4 and Steven A. Benner*1,2,5 Full Research Paper Open Access Address: Beilstein J. Org. Chem. 2017, 13, 393–404. 1Foundation for Applied Molecular Evolution, 13709 Progress doi:10.3762/bjoc.13.42 Boulevard, Alachua, FL, 32615, USA, 2Firebird Biomolecular Sciences LLC, 13709 Progress Boulevard, Alachua, FL, 32615, USA, Received: 23 November 2016 3Department of Earth Science, Tohoku University, 2 Chome-1-1 Accepted: 15 February 2017 Katahira, Aoba Ward, Sendai, Miyagi Prefecture 980-8577, Japan, Published: 01 March 2017 4Department of Material Science and Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama This article is part of the Thematic Series "From prebiotic chemistry to 240-8501, Japan and 5The Westheimer Institute for Science and molecular evolution". Technology, 13709 Progress Boulevard, Alachua, FL, 32615, USA Guest Editor: L. Cronin Email: Steven A. Benner* - [email protected] © 2017 Biondi et al.; licensee Beilstein-Institut. License and terms: see end of document. * Corresponding author Keywords: carbonates; natural minerals; origins of life; RNA adsorption; synthetic minerals Abstract The prebiotic significance of laboratory experiments that study the interactions between oligomeric RNA and mineral species is difficult to know. Natural exemplars of specific minerals can differ widely depending on their provenance. While laboratory-gener- ated samples of synthetic minerals can have controlled compositions, they are often viewed as "unnatural". Here, we show how trends in the interaction of RNA with natural mineral specimens, synthetic mineral specimens, and co-precipitated pairs of synthe- tic minerals, can make a persuasive case that the observed interactions reflect the composition of the minerals themselves, rather than their being simply examples of large molecules associating nonspecifically with large surfaces. -
Mottramite Pbcu(VO4)(OH) C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Orthorhombic
Mottramite PbCu(VO4)(OH) c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As crystals, equant or dipyramidal {111}, prismatic [001] or [100], with {101}, {201}, many others, to 3 mm, in drusy crusts, botryoidal, usually granular to compact, massive. Physical Properties: Fracture: Small conchoidal to uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = ∼5.9 D(calc.) = 6.187 Optical Properties: Transparent to nearly opaque. Color: Grass-green, olive-green, yellow- green, siskin-green, blackish brown, nearly black. Streak: Yellowish green. Luster: Greasy. Optical Class: Biaxial (–), rarely biaxial (+). Pleochroism: Weak to strong; X = Y = canary-yellow to greenish yellow; Z = brownish yellow. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,strong; rarely r< v.α= 2.17(2) β = 2.26(2) γ = 2.32(2) 2V(meas.) = ∼73◦ Cell Data: Space Group: P nma. a = 7.667–7.730 b = 6.034–6.067 c = 9.278–9.332 Z=4 X-ray Powder Pattern: Mottram St. Andrew, England; close to descloizite. 3.24 (vvs), 5.07 (vs), 2.87 (vs), 2.68 (vs), 2.66 (vs), 2.59 (vs), 1.648 (vs) Chemistry: (1) (2) (1) (2) CrO3 0.50 ZnO 0.31 10.08 P2O5 0.24 PbO 55.64 55.30 As2O5 1.33 H2O 3.57 2.23 V2O5 21.21 22.53 insol. 0.17 CuO 17.05 9.86 Total 100.02 100.00 (1) Bisbee, Arizona, USA; average of three analyses. (2) Pb(Cu, Zn)(VO4)(OH) with Zn:Cu = 1:1. -
Zincite (Zn, Mn2+)O
Zincite (Zn, Mn2+)O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal. Point Group: 6mm. Crystals rare, typically pyramidal, hemimorphic, with large {0001}, to 2.5 cm, rarely curved; in broad cleavages, foliated, granular, compact, massive. Twinning: On {0001}, with composition plane {0001}. Physical Properties: Cleavage: {1010}, perfect; parting on {0001}, commonly distinct. Fracture: Conchoidal. Tenacity: Brittle. Hardness = 4 VHN = 205–221 (100 g load). D(meas.) = 5.66(2) D(calc.) = 5.6730 Rare pale yellow fluorescence under LW UV. Optical Properties: Translucent, transparent in thin fragments. Color: Yellow-orange to deep red, rarely yellow, green, colorless; deep red to yellow in transmitted light; light rose-brown in reflected light, with strong red to yellow internal reflections. Streak: Yellow-orange. Luster: Subadamantine to resinous. Optical Class: Uniaxial (+). ω = 2.013 = 2.029 R1–R2: (400) 13.0–13.6, (420) 12.8–13.2, (440) 12.6–12.8, (460) 12.3–12.6, (480) 12.1–12.4, (500) 12.0–12.2, (520) 11.8–12.1, (540) 11.8–12.0, (560) 11.7–11.9, (580) 11.6–11.8, (600) 11.4–11.7, (620) 11.3–11.6, (640) 11.2–11.5, (660) 11.1–11.4, (680) 11.0–11.2, (700) 11.0–11.2 Cell Data: Space Group: P 63mc (synthetic). a = 3.24992(5) c = 5.20658(8) Z = 2 X-ray Powder Pattern: Synthetic. 2.476 (100), 2.816 (71), 2.602 (56), 1.626 (40), 1.477 (35), 1.911 (29), 1.379 (28) Chemistry: (1) (2) SiO2 0.08 FeO 0.01 0.23 MnO 0.27 0.29 ZnO 99.63 98.88 Total 99.99 [99.40] (1) Sterling Hill, New Jersey, USA. -
New Mineral Names*
American Mineralogist, Volume 62, pages 173-176, 1977 NEW MINERAL NAMES* MrcHlrI- Fr-BlscHrnAND J. A. MeNnn'ntNo and Institute Agrellite* Museum of Canada, Geological Survey of Canada, for the Mineralogy, Geochemistryand Crystal Chemistry of the J. GrrrrNs, M. G. BowN .qNoB. D. Srunlt.ltt (1976)Agrellite, a Rare Elements(Moscow). J. A. M. new rock-forming mineral in regionally metamorphosed agpaitic alkafic rocks Can. Mineral. 14, 120-126. Fedorovskite+ The mineral occurs as lensesand pods in mafic gneissescom- posed of albite, microcline, alkalic amphibole, aegirine-augite, S. V. MeltNro, D P SsrsurlN and K V. YunrtN'l (1976) eudialyte,and nepheline.Other mineralspresent are: hiortdahlite, Fedorovskite,a new boron mineral,and the isomorphousseries other members of the w<ihleritegroup, mosandrite, miserite, brith- roweite-fedorovskite olite, vlasovite, calcite, fluorite, clinohumite, norbergite, zircon, Zap. Vses Mineral- O'uo 105,71-85 (in Russian)' biotite, phlogopite, galena, and a new unnamed mineral, CaZr- SirO, [seeabstract in Am. Mineral 61, 178-179 (1976)]. The local- ity is on the Kipawa River, Villedieu Township, T6miscamingue County, Quebei, Canada, at about Lat.46" 4'7' 49" N, and Long 78" 29'3l" W (Note by J.A.M.: The Lat. and Long. figuresare interchangedin the paper,and the figurefor the latitudeshould be 46" not 45" ) Agrellite occurs as crystals up to 100 mm in length. They are HCI elongatedparallel to [001] and are flattened on either {010} or X-ray powder data are given for the first 3 samplesanalyzed For { I l0} The color is white to greyishor greenishwhite The lusteron sample(Mg*Mn.u), the strongestlines (41 given) are 3'92 cleavagesis pearly. -
Ramsbeckite (Cu, Zn)15(SO4)4(OH)22 • 6H2O C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Monoclinic, Pseudohexagonal
Ramsbeckite (Cu, Zn)15(SO4)4(OH)22 • 6H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic, pseudohexagonal. Point Group: 2/m. Crystals are tabular with large {001}, also {210}, {110}, {100}, giving a slightly rounded rhombic outline, to 3 mm. Twinning: Observed, repeated, forming cylindrical aggregates. Physical Properties: Cleavage: On {001}, perfect. Fracture: Conchoidal. Tenacity: Brittle. Hardness = 3.5 D(meas.) = 3.39–3.41 D(calc.) = 3.37 Optical Properties: Transparent to translucent. Color: Green, blue-green. Streak: Pale green. Luster: Vitreous. Optical Class: Biaxial (–). Pleochroism: Weak; X = pale blue-green, emerald-green; Y = Z = blue-green, yellow-green. Orientation: Y = b; X ∧ c =5◦; Z ∧ a =5◦. Absorption: X > Y = Z. α = 1.624–1.669 β = 1.674–1.703 γ = 1.678–1.707 2V(meas.) = 36◦–38◦ 2V(calc.) = 38.0◦ Cell Data: Space Group: P 21/a. a = 16.088–16.110 b = 15.576–15.602 c = 7.102–7.112 β =90.0◦−90.27◦ Z=2 X-ray Powder Pattern: Bastenberg mine, Ramsbeck, Germany. 7.090 (100), 3.549 (25), 1.776 (20), 3.254 (13), 4.400 (12), 3.232 (12), 3.244 (11) Chemistry: (1) (2) (3) SO3 17.4 17.6 17.51 CuO 44.5 43.8 43.49 ZnO 15.8 18.1 22.25 H2O 19.3 [20.5] 16.75 Total 97.0 [100.0] 100.00 (1) Bastenberg mine, Ramsbeck, Germany; SO4 by photometry, CuO, ZnO by AA, H2O by gas 1− chromatography, (OH) computed for charge balance; corresponds to (Cu10.30Zn3.58)Σ=13.88 • (SO4)4.00(OH)19.76 9.84H2O.