Condensation Heat Transfer of R22, R410A and R32 Inside a Multiport Mini-Channel Tube
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Chapter 8 and 9 – Energy Balances
CBE2124, Levicky Chapter 8 and 9 – Energy Balances Reference States . Recall that enthalpy and internal energy are always defined relative to a reference state (Chapter 7). When solving energy balance problems, it is therefore necessary to define a reference state for each chemical species in the energy balance (the reference state may be predefined if a tabulated set of data is used such as the steam tables). Example . Suppose water vapor at 300 oC and 5 bar is chosen as a reference state at which Hˆ is defined to be zero. Relative to this state, what is the specific enthalpy of liquid water at 75 oC and 1 bar? What is the specific internal energy of liquid water at 75 oC and 1 bar? (Use Table B. 7). Calculating changes in enthalpy and internal energy. Hˆ and Uˆ are state functions , meaning that their values only depend on the state of the system, and not on the path taken to arrive at that state. IMPORTANT : Given a state A (as characterized by a set of variables such as pressure, temperature, composition) and a state B, the change in enthalpy of the system as it passes from A to B can be calculated along any path that leads from A to B, whether or not the path is the one actually followed. Example . 18 g of liquid water freezes to 18 g of ice while the temperature is held constant at 0 oC and the pressure is held constant at 1 atm. The enthalpy change for the process is measured to be ∆ Hˆ = - 6.01 kJ. -
Ammonia As a Refrigerant
1791 Tullie Circle, NE. Atlanta, Georgia 30329-2305, USA www.ashrae.org ASHRAE Position Document on Ammonia as a Refrigerant Approved by ASHRAE Board of Directors February 1, 2017 Expires February 1, 2020 ASHRAE S H A P I N G T O M O R R O W ’ S B U I L T E N V I R O N M E N T T O D A Y © 2017 ASHRAE (www.ashrae.org). For personal use only. Additional reproduction, distribution, or transmission in either print or digital form is not permitted without ASHRAE’s prior written permission. COMMITTEE ROSTER The ASHRAE Position Document on “Ammonia as a Refrigerant” was developed by the Society’s Refrigeration Committee. Position Document Committee formed on January 8, 2016 with Dave Rule as its chair. Dave Rule, Chair Georgi Kazachki IIAR Dayton Phoenix Group Alexandria, VA, USA Dayton, OH, USA Ray Cole Richard Royal Axiom Engineers, Inc. Walmart Monterey, CA, USA Bentonville, Arkansas, USA Dan Dettmers Greg Scrivener IRC, University of Wisconsin Cold Dynamics Madison, WI, USA Meadow Lake, SK, Canada Derek Hamilton Azane Inc. San Francisco, CA, USA Other contributors: M. Kent Anderson Caleb Nelson Consultant Azane, Inc. Bethesda, MD, USA Missoula, MT, USA Cognizant Committees The chairperson of Refrigerant Committee also served as ex-officio members: Karim Amrane REF Committee AHRI Bethesda, MD, USA i © 2017 ASHRAE (www.ashrae.org). For personal use only. Additional reproduction, distribution, or transmission in either print or digital form is not permitted without ASHRAE’s prior written permission. HISTORY of REVISION / REAFFIRMATION / WITHDRAWAL -
A Comprehensive Review of Thermal Energy Storage
sustainability Review A Comprehensive Review of Thermal Energy Storage Ioan Sarbu * ID and Calin Sebarchievici Department of Building Services Engineering, Polytechnic University of Timisoara, Piata Victoriei, No. 2A, 300006 Timisoara, Romania; [email protected] * Correspondence: [email protected]; Tel.: +40-256-403-991; Fax: +40-256-403-987 Received: 7 December 2017; Accepted: 10 January 2018; Published: 14 January 2018 Abstract: Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included. Keywords: storage system; phase-change materials; chemical storage; cold storage; performance 1. Introduction Recent projections predict that the primary energy consumption will rise by 48% in 2040 [1]. On the other hand, the depletion of fossil resources in addition to their negative impact on the environment has accelerated the shift toward sustainable energy sources. -
(Vocs) in Asian and North American Pollution Plumes During INTEX-B: Identification of Specific Chinese Air Mass Tracers
Atmos. Chem. Phys., 9, 5371–5388, 2009 www.atmos-chem-phys.net/9/5371/2009/ Atmospheric © Author(s) 2009. This work is distributed under Chemistry the Creative Commons Attribution 3.0 License. and Physics Characterization of volatile organic compounds (VOCs) in Asian and north American pollution plumes during INTEX-B: identification of specific Chinese air mass tracers B. Barletta1, S. Meinardi1, I. J. Simpson1, E. L. Atlas2, A. J. Beyersdorf3, A. K. Baker4, N. J. Blake1, M. Yang1, J. R. Midyett1, B. J. Novak1, R. J. McKeachie1, H. E. Fuelberg5, G. W. Sachse3, M. A. Avery3, T. Campos6, A. J. Weinheimer6, F. S. Rowland1, and D. R. Blake1 1University of California, Irvine, 531 Rowland Hall, Irvine 92697 CA, USA 2University of Miami, RSMAS/MAC, 4600 Rickenbacker Causeway, Miami, 33149 FL, USA 3NASA Langley Research Center, Hampton, 23681 VA, USA 4Max Plank Institute, Atmospheric Chemistry Dept., Johannes-Joachim-Becherweg 27, 55128 Mainz, Germany 5Florida State University, Department of Meteorology, Tallahassee Florida 32306-4520, USA 6NCAR, 1850 Table Mesa Drive, Boulder, 80305 CO, USA Received: 9 March 2009 – Published in Atmos. Chem. Phys. Discuss.: 24 March 2009 Revised: 16 June 2009 – Accepted: 17 June 2009 – Published: 30 July 2009 Abstract. We present results from the Intercontinental 1 Introduction Chemical Transport Experiment – Phase B (INTEX-B) air- craft mission conducted in spring 2006. By analyzing the The Intercontinental Chemical Transport Experiment – mixing ratios of volatile organic compounds (VOCs) mea- Phase B (INTEX-B) aircraft experiment was conducted in sured during the second part of the field campaign, to- the spring of 2006. Its broad objective was to understand gether with kinematic back trajectories, we were able to the behavior of trace gases and aerosols on transcontinental identify five plumes originating from China, four plumes and intercontinental scales, and their impact on air quality from other Asian regions, and three plumes from the United and climate (an overview of the INTEX-B campaign can be States. -
Cryogenicscryogenics Forfor Particleparticle Acceleratorsaccelerators Ph
CryogenicsCryogenics forfor particleparticle acceleratorsaccelerators Ph. Lebrun CAS Course in General Accelerator Physics Divonne-les-Bains, 23-27 February 2009 Contents • Low temperatures and liquefied gases • Cryogenics in accelerators • Properties of fluids • Heat transfer & thermal insulation • Cryogenic distribution & cooling schemes • Refrigeration & liquefaction Contents • Low temperatures and liquefied gases ••• CryogenicsCryogenicsCryogenics ininin acceleratorsacceleratorsaccelerators ••• PropertiesPropertiesProperties ofofof fluidsfluidsfluids ••• HeatHeatHeat transfertransfertransfer &&& thermalthermalthermal insulationinsulationinsulation ••• CryogenicCryogenicCryogenic distributiondistributiondistribution &&& coolingcoolingcooling schemesschemesschemes ••• RefrigerationRefrigerationRefrigeration &&& liquefactionliquefactionliquefaction • cryogenics, that branch of physics which deals with the production of very low temperatures and their effects on matter Oxford English Dictionary 2nd edition, Oxford University Press (1989) • cryogenics, the science and technology of temperatures below 120 K New International Dictionary of Refrigeration 3rd edition, IIF-IIR Paris (1975) Characteristic temperatures of cryogens Triple point Normal boiling Critical Cryogen [K] point [K] point [K] Methane 90.7 111.6 190.5 Oxygen 54.4 90.2 154.6 Argon 83.8 87.3 150.9 Nitrogen 63.1 77.3 126.2 Neon 24.6 27.1 44.4 Hydrogen 13.8 20.4 33.2 Helium 2.2 (*) 4.2 5.2 (*): λ Point Densification, liquefaction & separation of gases LNG Rocket fuels LIN & LOX 130 000 m3 LNG carrier with double hull Ariane 5 25 t LHY, 130 t LOX Air separation by cryogenic distillation Up to 4500 t/day LOX What is a low temperature? • The entropy of a thermodynamical system in a macrostate corresponding to a multiplicity W of microstates is S = kB ln W • Adding reversibly heat dQ to the system results in a change of its entropy dS with a proportionality factor T T = dQ/dS ⇒ high temperature: heating produces small entropy change ⇒ low temperature: heating produces large entropy change L. -
Refrigerant Selection and Cycle Development for a High Temperature Vapor Compression Heat Pump
Refrigerant Selection and Cycle Development for a High Temperature Vapor Compression Heat Pump Heinz Moisia*, Renè Riebererb aResearch Assistant, Institute of Thermal Engineering, Graz University of Technology, Inffeldgasse 25/B, 8010 Graz, Austria bAssociate Professor, Institute of Thermal Engineering, Graz University of Technology, Inffeldgasse 25/B, 8010 Graz, Austria Abstract Different technological challenges have to be met in the course of the development of a high temperature vapor compression heat pump. In certain points of operation, high temperature refrigerants can show condensation during the compression which may lead to compressor damage. As a consequence, high suction gas superheat up to 20 K can be necessary. Furthermore high compressor outlet temperatures caused by high heat sink outlet temperatures (approx. 110 °C) and high pressure ratios can lead to problems with the compressor lubricant. In order to meet these challenges different refrigerant and cycle configurations have been investigated by means of simulation. Thermodynamic properties as well as legal and availability aspects have been considered for the refrigerant selection. The focus of the cycle configurations has been set on the realization of the required suction gas superheat. Therefore the possibility of an internal heat exchanger and a suction gas cooled compressor has been investigated. The simulation results showed a COP increase of up to +11 % due to the fact that the main part of the suction gas superheat has not been provided in the evaporator. Furthermore, the effect of increased subcooling has been investigated for a single stage cycle with internal heat exchanger. The results showed a COP of 3.4 with a subcooling of 25 K at a temperature lift of approximately 60 K for the refrigerant R600 (n-butane). -
Factors Affecting Indoor Air Quality
Factors Affecting Indoor Air Quality The indoor environment in any building the categories that follow. The examples is a result of the interaction between the given for each category are not intended to site, climate, building system (original be a complete list. 2 design and later modifications in the Sources Outside Building structure and mechanical systems), con- struction techniques, contaminant sources Contaminated outdoor air (building materials and furnishings, n pollen, dust, fungal spores moisture, processes and activities within the n industrial pollutants building, and outdoor sources), and n general vehicle exhaust building occupants. Emissions from nearby sources The following four elements are involved n exhaust from vehicles on nearby roads Four elements— in the development of indoor air quality or in parking lots, or garages sources, the HVAC n loading docks problems: system, pollutant n odors from dumpsters Source: there is a source of contamination pathways, and or discomfort indoors, outdoors, or within n re-entrained (drawn back into the occupants—are the mechanical systems of the building. building) exhaust from the building itself or from neighboring buildings involved in the HVAC: the HVAC system is not able to n unsanitary debris near the outdoor air development of IAQ control existing air contaminants and ensure intake thermal comfort (temperature and humidity problems. conditions that are comfortable for most Soil gas occupants). n radon n leakage from underground fuel tanks Pathways: one or more pollutant pathways n contaminants from previous uses of the connect the pollutant source to the occu- site (e.g., landfills) pants and a driving force exists to move n pesticides pollutants along the pathway(s). -
A Critical Review on Thermal Energy Storage Materials and Systems for Solar Applications
AIMS Energy, 7(4): 507–526. DOI: 10.3934/energy.2019.4.507 Received: 05 July 2019 Accepted: 14 August 2019 Published: 23 August 2019 http://www.aimspress.com/journal/energy Review A critical review on thermal energy storage materials and systems for solar applications D.M. Reddy Prasad1,*, R. Senthilkumar2, Govindarajan Lakshmanarao2, Saravanakumar Krishnan2 and B.S. Naveen Prasad3 1 Petroleum and Chemical Engineering Programme area, Faculty of Engineering, Universiti Teknologi Brunei, Gadong, Brunei Darussalam 2 Department of Engineering, College of Applied Sciences, Sohar, Sultanate of Oman 3 Sathyabama Institute of Science and Technology, Chennai, India * Correspondence: Email: [email protected]; [email protected]. Abstract: Due to advances in its effectiveness and efficiency, solar thermal energy is becoming increasingly attractive as a renewal energy source. Efficient energy storage, however, is a key limiting factor on its further development and adoption. Storage is essential to smooth out energy fluctuations throughout the day and has a major influence on the cost-effectiveness of solar energy systems. This review paper will present the most recent advances in these storage systems. The manuscript aims to review and discuss the various types of storage that have been developed, specifically thermochemical storage (TCS), latent heat storage (LHS), and sensible heat storage (SHS). Among these storage types, SHS is the most developed and commercialized, whereas TCS is still in development stages. The merits and demerits of each storage types are discussed in this review. Some of the important organic and inorganic phase change materials focused in recent years have been summarized. The key contributions of this review article include summarizing the inherent benefits and weaknesses, properties, and design criteria of materials used for storing solar thermal energy, as well as discussion of recent investigations into the dynamic performance of solar energy storage systems. -
Refrigerants and the Refrigeration System
M25_STAN0893_00_SE_C25.QXD 9/4/08 9:54 PM Page 1 SECTION FOUR Refrigerants and the Refrigeration System UNIT 25 Accessing Sealed Refrigeration Systems OBJECTIVES determine the pressures. Knowing the temperature differ- ence across the coils, the amperage, and the airflow all give After completing this unit you will be able to: the technician vital information; but sometimes without the system operating pressures a final determination of a prob- ■ describe the different types of refrigeration service lem cannot be accurately made. valves. It is important to attach and remove a gauge manifold ■ explain the operation of gauge manifold valves. ■ explain how to properly install and remove a gauge set properly. Understanding how to properly manipulate sys- manifold set on manual service valves. tem access valves and install gauge manifolds is vital to the ■ explain the operation of split system installation personal safety of the service technician. Improper technique valves. can damage the system or injure the technician. Proper tech- ■ explain how to properly install and remove a gauge niques should always be practiced so that they become a manifold set on Schrader valves. habit performed the same way each time. ■ describe how to gain access to systems without service valves. SAFETY TIP 25.1 INTRODUCTION One of the last things a service technician should do when The proper personal protective equipment, PPE, for in- troubleshooting a system is attach a set of gauges to the sys- stalling refrigeration gauges and manipulating valves includes safety glasses and gloves. When liquid refrig- tem. Each time a sealed system is accessed there is a chance erant escapes into the atmosphere it boils at ex- that some contaminants can be introduced to the system, or tremely cold temperatures. -
Lecture 11. Surface Evaporation and Soil Moisture (Garratt 5.3) in This
Atm S 547 Boundary Layer Meteorology Bretherton Lecture 11. Surface evaporation and soil moisture (Garratt 5.3) In this lecture… • Partitioning between sensible and latent heat fluxes over moist and vegetated surfaces • Vertical movement of soil moisture • Land surface models Evaporation from moist surfaces The partitioning of the surface turbulent energy flux into sensible vs. latent heat flux is very important to the boundary layer development. Over ocean, SST varies relatively slowly and bulk formulas are useful, but over land, the surface temperature and humidity depend on interactions of the BL and the surface. How, then, can the partitioning be predicted? For saturated ideal surfaces (such as saturated soil or wet vegetation), this is relatively straight- forward. Suppose that the surface temperature is T0. Then the surface mixing ratio is its saturation value q*(T0). Let z1 denote a measurement height within the surface layer (e. g. 2 m or 10 m), at which the temperature and humidity are T1 and q1. The stability is characterized by an Obhukov length L. The roughness length and thermal roughness lengths are z0 and zT. Then Monin-Obuhkov theory implies that the sensible and latent heat fluxes are HS = ρLvCHV1 (T0 - T1), HL = ρLvCHV1 (q0 - q1), where CH = fn(V1, z1, z0, zT, L)" We can eliminate T0 using a linearized version of the Clausius-Clapeyron equations: q0 - q*(T1) = (dq*/dT)R(T0 - T1), (R indicates a reference temp. near (T0 + T1)/2) HL = s*HS +!LCHV1(q*(T1) - q1), (11.1) s* = (L/cp)(dq*/dT)R (= 0.7 at 273 K, 3.3 at 300 K) This equation expresses latent heat flux in terms of sensible heat flux and the saturation deficit at the measurement level. -
Heat and Thermodynamics Course
Heat and Thermodynamics Introduction Definitions ! Internal energy ! Kinetic and potential energy ! Joules ! Enthalpy and specific enthalpy ! H= U + p x V ! Reference to the triple point ! Engineering unit ! ∆H is the work done in a process ! J, J/kg More Definitions ! Work ! Standard definition W = f x d ! In a gas W = p x ∆V ! Heat ! At one time considered a unique form of energy ! Changes in heat are the same as changes in enthalpy Yet more definitions ! Temperature ! Measure of the heat in a body ! Heat flows from high to low temperature ! SI unit Kelvin ! Entropy and Specific Entropy ! Perhaps the strangest physics concept ! Notes define it as energy loss ! Symbol S ! Units kJ/K, kJ/(kg•k) ! Entropy increases mean less work can be done by the system Sensible and Latent Heat ! Heat transfers change kinetic or potential energy or both ! Temperature is a measure of kinetic energy ! Sensible heat changes kinetic (and maybe potential energy) ! Latent heat changes only the potential energy. Sensible Heat Q = m⋅c ⋅(t f − ti ) ! Q is positive for transfers in ! c is the specific heat capacity ! c has units kJ/(kg•C) Latent Heat Q = m⋅lv Q = m⋅lm ! Heat to cause a change of state (melting or vaporization) ! Temperature is constant Enthalpy Changes Q = m⋅∆h ! Enthalpy changes take into account both latent and sensible heat changes Thermodynamic Properties of H2O Temperature °C Sensible heat Latent heat Saturation temp 100°C Saturated Saturated liquid steam Superheated Steam Wet steam Subcooled liquid Specific enthalpy Pressure Effects Laws of Thermodynamics ! First Law ! Energy is conserved ! Second Law ! It is impossible to convert all of the heat supplied to a heat engine into work ! Heat will not naturally flow from cold to hot ! Disorder increases Heat Transfer Radiation Conduction • • A 4 Q = k ⋅ ⋅∆T QαA⋅T l A T2 T1 l More Heat Transfer Convection Condensation Latent heat transfer Mass Flow • from vapor Q = h⋅ A⋅∆T Dalton’s Law If we have more than one gas in a container the pressure is the sum of the pressures associated with an individual gas. -
Module P7.4 Specific Heat, Latent Heat and Entropy
FLEXIBLE LEARNING APPROACH TO PHYSICS Module P7.4 Specific heat, latent heat and entropy 1 Opening items 4 PVT-surfaces and changes of phase 1.1 Module introduction 4.1 The critical point 1.2 Fast track questions 4.2 The triple point 1.3 Ready to study? 4.3 The Clausius–Clapeyron equation 2 Heating solids and liquids 5 Entropy and the second law of thermodynamics 2.1 Heat, work and internal energy 5.1 The second law of thermodynamics 2.2 Changes of temperature: specific heat 5.2 Entropy: a function of state 2.3 Changes of phase: latent heat 5.3 The principle of entropy increase 2.4 Measuring specific heats and latent heats 5.4 The irreversibility of nature 3 Heating gases 6 Closing items 3.1 Ideal gases 6.1 Module summary 3.2 Principal specific heats: monatomic ideal gases 6.2 Achievements 3.3 Principal specific heats: other gases 6.3 Exit test 3.4 Isothermal and adiabatic processes Exit module FLAP P7.4 Specific heat, latent heat and entropy COPYRIGHT © 1998 THE OPEN UNIVERSITY S570 V1.1 1 Opening items 1.1 Module introduction What happens when a substance is heated? Its temperature may rise; it may melt or evaporate; it may expand and do work1—1the net effect of the heating depends on the conditions under which the heating takes place. In this module we discuss the heating of solids, liquids and gases under a variety of conditions. We also look more generally at the problem of converting heat into useful work, and the related issue of the irreversibility of many natural processes.