OCTOBER-DECEMBER 2020 Vol.26, Number 4, 321-425
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ISSN 1451 - 9372(Print) ISSN 2217 - 7434(Online) OCTOBER-DECEMBER 2020 Vol.26, Number 4, 321-425 www.ache.org.rs/ciceq Journal of the Association of Chemical Engineers of Serbia, Belgrade, Serbia EDITOR-In-Chief Vlada B. Veljković Faculty of Technology, University of Niš, Leskovac, Serbia E-mail: [email protected] ASSOCIATE EDITORS Jonjaua Ranogajec Srđan Pejanović Milan Jakšić Faculty of Technology, University of Department of Chemical Engineering, ICEHT/FORTH, University of Patras, Novi Sad, Novi Sad, Serbia Faculty of Technology and Metallurgy, Patras, Greece University of Belgrade, Belgrade, Serbia EDITORIAL BOARD (Serbia) Đorđe Janaćković, Sanja Podunavac-Kuzmanović, Viktor Nedović, Sandra Konstantinović, Ivanka Popović Siniša Dodić, Zoran Todorović, Olivera Stamenković, Marija Tasić, Jelena Avramović, Goran Nikolić, Dunja Sokolović ADVISORY BOARD (International) Dragomir Bukur Ljubisa Radovic Texas A&M University, Pen State University, College Station, TX, USA PA, USA Milorad Dudukovic Peter Raspor Washington University, University of Ljubljana, St. Luis, MO, USA Ljubljana, Slovenia Jiri Hanika Constantinos Vayenas Institute of Chemical Process Fundamentals, Academy of Sciences University of Patras, of the Czech Republic, Prague, Czech Republic Patras, Greece Maria Jose Cocero Xenophon Verykios University of Valladolid, University of Patras, Valladolid, Spain Patras, Greece Tajalli Keshavarz Ronnie Willaert University of Westminster, Vrije Universiteit, London, UK Brussel, Belgium Zeljko Knez Gordana Vunjak Novakovic University of Maribor, Columbia University, Maribor, Slovenia New York, USA Igor Lacik Dimitrios P. Tassios Polymer Institute of the Slovak Academy of Sciences, National Technical University of Athens, Bratislava, Slovakia Athens, Greece Denis Poncelet Hui Liu ENITIAA, Nantes, France China University of Geosciences, Wuhan, China FORMER EDITOR (2005-2007) Professor Dejan Skala University of Belgrade, Faculty of Technology and Metallurgy, Belgrade, Serbia Journal of the Association of Chemical Engineers of Serbia, Belgrade, Serbia Vol. 26 Belgrade, October-December 2020 No. 4 Chemical Industry & Chemical Engineering CONTENTS Quarterly (ISSN 1451-9372) is published quarterly by the Association of Chemical Pongayi Ponnusamy Selvi, Rajoo Baskar, CO2 absorption in Engineers of Serbia, Kneza Miloša 9/I, nanofluid with magnetic field .............................................. 321 11000 Belgrade, Serbia D. Revathi, Dr.K. Saravanan, Experimental studies on Editor: hydrodynamic aspects for mixing of non-Newtonian Vlada B. Veljković fluids in a Komax static mixer ............................................. 329 [email protected] Sanja Radonjić, Helena Prosen, Vesna Maraš, Lea Demšar, Tatjana Košmerl, Incidence of volatile phenols in Editorial Office: Montenegrin red wines: Vranac, Kratošija and Kneza Miloša 9/I, 11000 Belgrade, Serbia Cabernet Sauvignon ........................................................... 337 Phone/Fax: +381 (0)11 3240 018 E-mail: [email protected] P.C. Nnaji, B.I. Okolo, O.D. Onukwuli, Luffa cylindrica seed: www.ache.org.rs Biomass for wastewater treament, sludge generation study at optimum conditions ............................................... 349 For publisher: Kristina Jančaitienė, Rasa Šlinkšienė, Influence of cellulose Ivana T. Drvenica additive on the granulation process of potassium dihydrogen phosphate ........................................................ 359 Secretary of the Editorial Office: Slavica Desnica Bruna Muriel F. Costa, Carolina Monteiro Coelho, Cássia Ribeiro Souza, Gabriela Drumond A. Duarte, Maria Marketing and advertising: Bernadete Pinto, Vítor J. O. Silva, Marcelo S. Batista, AChE Marketing Office Study of the drying kinetics of the malt bagasse in a Kneza Miloša 9/I, 11000 Belgrade, Serbia pneumatic transporter ........................................................ 369 Phone/Fax: +381 (0)11 3240 018 Marija Bodroža-Solarov, Nevenka Rajić, Lato Pezo, Jovana Publication of this Journal is supported by the Kojić, Jelena Krulj, Bojana Filipčev, Rada Jevtić Muči- Ministry of Education, Science and babić, The rheological properties of wheat dough Technological Development of the Republic of containing zeolite residue ................................................... 377 Serbia Rim Jouraiphy, Islaam Anouar, Hamid Mazouz, Badr El Kor- Subscription and advertisements make payable tobi, Rachid Boulif, Ahmed Mahrou, Amina Ibnlfassi, to the account of the Association of Chemical Solid-liquid separation techniques for efficient recovery Engineers of Serbia, Belgrade, No. 205-2172- of P2O5 from phosphoric sludge ......................................... 385 71, Komercijalna banka a.d., Beograd Jesús M. Casas, Josué Lagos, Drowning-out crystallization of sodium molybdate in aqueous–ethanol solutions ........... 395 Computer typeface and paging: Vladimir Panić Maja Čolnik, Maša Knez Hrnčič, Mojca Škerget, Željko Knez, Biodegradable polymers, current trends of research Printed by: and their applications, a review .......................................... 401 Faculty of Technology and Metallurgy, Corrigendum to Enhanced sorption of Cu(II) ions from Research and Development Centre of Printing aqueous ions from aqueous solution by ionic liquid Technology, Karnegijeva 4, P.O. Box 3503, impregnated nano-silic and nano-alumina particles 11120 Belgrade, Serbia (Chem. Ind. Chem. Eng. Q. 23(2) (2017) 207-216) ............ 419 Abstracting/Indexing: Contents: Vol. 26, Issues 1–4, 2020 .............................................. 421 Articles published in this Journal are indexed in Author Index, Vol. 25, 2019 .......................................................... 423 Thompson Reuters products: Science Citation Index - ExpandedTM - access via Web of Science®, part of ISI Web of KnowledgeSM Activities of the Association of Chemical Engineers of Serbia are supported by: - Ministry of Education, Science and Technological Development, Republic of Serbia - Hemofarm Koncern AD, Vršac, Serbia - Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia - Faculty of Technology, University of Novi Sad, Novi Sad, Serbia - Faculty of Technology, University of Niš, Leskovac, Serbia - Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Belgrade, Serbia Available on line at Association of the Chemical Engineers of Serbia AChE Chemical Industry & Chemical Engineering Quarterly www.ache.org.rs/CICEQ Chem. Ind. Chem. Eng. Q. 26 (4) 321−328 (2020) CI&CEQ PONGAYI PONNUSAMY CO2 ABSORPTION IN NANOFLUID WITH SELVI1 MAGNETIC FIELD RAJOO BASKAR2 1Department of Chemical Article Highlights Engineering, Kongu Engineering • Experiments carried with/without the magnetic field of the structured packed absorpt- College, Erode, India ion column 2 • Nanofluids were prepared by dispersing Al O nanofluids in water with/without mag- Department of Food Technology, 2 3 netic field Kongu Engineering College, Erode, • The mass transfer performance of the structured packed absorption column was India investigated SCIENTIFIC PAPER Abstract UDC 504.055:66.081:54 Acidic gases like CO2, SO2, NO2, H2S, etc., are to be removed as these are polluting the atmosphere in one way or another by inducing temperature rise which further results in undesirable climatic change. Among all these gases, CO2 is the most responsible for the environmental issues and its capture becomes one of prime importance. The objective of this work is the enhance- ment of the CO2 absorption by employing nanofluids in the presence of mag- netic field. The nanofluid used in this work is Al2O3/water in the concentration of 0.0015%. The maximum flux obtained is 0.014 mol/(m2s) (without magnetic 2 field) and 0.015 mol/(m s) (with magnetic field) for lower CO2 flow rate of 30 L/h. The nanofluids along with the magnetic field show a positive performance towards the absorption of CO2. Keywords: CO2, flux, flow rate, global warming. Due to human activities and since the industrial acid gas. Among all the chemical solvents [9], amine- th revolution from the 17 century, 289 ppm of CO2 -based solvents are used to capture CO2. But this increased to 406 ppm in 2017 resulting in a 2 °C raise method has several advantages and certain disad- in atmospheric temperature. To avoid dangerous eco- vantages like high power consumption, low gas load- logical and environmental issues, CO2 sequestration ing, high equipment corrosion, amine degradation etc. has to be carried out [1,2]. The major sources of Hence, a novel solvent with low cost, higher capacity greenhouse gases [3] come from the burning of fossil and efficiency with lesser decomposition and corros- fuels, fermentation, deforestation, chlorofluorocar- ion rate is the aqueous ammonia [10,11]. After the bons, agricultural activities [4,5], etc. CO2 is the major solvent selection, the next absorption is to be carried contributor to global warming which results in the loss out in the wetted wall column or packed column. in biodiversity and extreme changes in agricultural Among these two, the wetted wall column is most activities [6,7]. CO2 has been captured by various preferable with a film promoter. The film promoter technologies [8] like adsorption, membrane separ- improves the formation of a stable liquid film and ation, cryogenic method, biological fixation and wet liquid distribution inside the column. Apart from the scrubbing or absorption. Wet scrubbing is the cost conventional solvents, nanofluids [12–14] are used to effective and widely accepted method to