Appendix 3-E
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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
Common and Chemical Names of Herbicides Approved by the WSSA
Weed Science 2010 58:511–518 Common and Chemical Names of Herbicides Approved by the Weed Science Society of America Below is the complete list of all common and chemical of herbicides as approved by the International Organization names of herbicides approved by the Weed Science Society of for Standardization (ISO). A sponsor may submit a proposal America (WSSA) and updated as of September 1, 2010. for a common name directly to the WSSA Terminology Beginning in 1996, it has been published yearly in the last Committee. issue of Weed Science with Directions for Contributors to A herbicide common name is not synonymous with Weed Science. This list is published in lieu of the selections a commercial formulation of the same herbicide, and in printed previously on the back cover of Weed Science. Only many instances, is not synonymous with the active ingredient common and chemical names included in this complete of a commercial formulation as identified on the product list should be used in WSSA publications. In the absence of label. If the herbicide is a salt or simple ester of a parent a WSSA-approved common name, the industry code number compound, the WSSA common name applies to the parent as compiled by the Chemical Abstracts Service (CAS) with compound only. CAS systematic chemical name or the systematic chemical The chemical name used in this list is that preferred by the name alone may be used. The current approved list is also Chemical Abstracts Service (CAS) according to their system of available at our web site (www.wssa.net). -
Special Report 354 April 1972 Agricultural Experiment Station
ORTMAL DO ;10T REMOVE 7.9 m FILE Special Report 354 April 1972 Agricultural Experiment Station Oregon State University, Corvallis I FIELD APPLICATION OF HERBICIDES--AVOIDING DANGER TO FISH Erland T. Juntunen Department of Fisheries and Wildlife Oregon State University Corvallis, Oregon and Logan A. Norris Pacific Northwest Forestry Sciences Laboratory and Range Experiment Station Forest Service, U. S. Department of Agriculture Corvallis, Oregon April, 1972 Trade names are used in this publication solely to provide specific information. No endorsement of products is intended nor is criticism implieLl to products mentioned or omitted. Recommendations are not made concerning safe use of products nor is any guarantee or warranty of results or effects of the products intended or implied. ii Chemical weed and brush control with herbicides is an important land management practice in modern agriculture and forestry. In some cases, herbicides are applied directly to bodies of water for aquatic weed control. More commonly, herbicides are applied to lands adjacent to waterways for general weed and brush control. The responsible applicator will avoid damage to fishery resources by being fully aware of a particular herbicides potential hazard to fish. Herbicide applications should be considered hazardous to fish when there is the probability fish will be exposed to herbicide concen- trations which are harmful. This bulletin offers information that will aid in selecting the particular herbicides and formulations of least hazard to fish considering the toxicity of the herbicide and the poten- tial for its entry into streams, lakes, or ponds. Entry of Herbicides into the Aquatic Environment In aquatic weed control, the effective concentration of herbicide in the water depends on the rate of application, the rate of the spread of the chemical, the size and chemical composition of the body of water, the rate of degradation or adsorption of the chemical on sediments, and the rate of mixing of treated water with untreated water. -
Multi-Residue Method I for Agricultural Chemicals by LC-MS (Agricultural Products)
Multi-residue Method I for Agricultural Chemicals by LC-MS (Agricultural Products) 1. Analytes See Table 2 or 3. 2. Instruments Liquid chromatograph-mass spectrometer (LC-MS) Liquid chromatograph-tandem mass spectrometer (LC-MS/MS) 3. Reagents Use the reagents listed in Section 3 of the General Rules except for the following. 0.5 mol/L Phosphate buffer (pH 7.0): Weigh 52.7 g of dipotassium hydrogenphosphate (K2HPO4) and 30.2 g of potassium dihydrogenphosphate (KH2PO4), dissolve in about 500 mL of water, adjust the pH to 7.0 with 1 mol/L sodium hydroxide or 1 mol/L hydrochloric acid, and add water to make a 1 L solution. Reference standards of agricultural chemicals: Reference standards of known purities for each agricultural chemical. 4. Procedure 1) Extraction i) Grains, beans, nuts and seeds Add 20 mL of water to 10.0 g of sample and let stand for 15 minutes. Add 50 mL of acetonitrile, homogenize, and filter with suction. Add 20 mL of acetonitrile to the residue on the filter paper, homogenize, and filter with suction. Combine the resulting filtrates, and add acetonitrile to make exactly 100 mL. Take a 20 mL aliquot of the extract, add 10 g of sodium chloride and 20 mL of 0.5 mol/L phosphate buffer (pH 7.0), and shake for 10 minutes. Let stand, and discard the separated aqueous layer. Add 10 mL of acetonitrile to an octadecylsilanized silica gel cartridge (1,000 mg) and discard the effluent. Transfer the acetonitrile layer to the cartridge, elute with 2 mL of acetonitrile, collect the total eluates, dehydrate with anhydrous sodium sulfate, and filter out the anhydrous sodium sulfate. -
Risks of Linuron Use to Federally Threatened California Red-Legged Frog (Rana Aurora Draytonii)
Risks of Linuron Use to Federally Threatened California Red-legged Frog (Rana aurora draytonii) Pesticide Effects Determination Environmental Fate and Effects Division Office of Pesticide Programs Washington, D.C. 20460 June 19, 2008 Primary Authors: Michael Davy, Agronomist Wm. J. Shaughnessy, Ph.D, Environmental Scientist Environmental Risk Branch II Environmental Fate and Effects Division (7507C) Secondary Review: Donna Randall, Senior Effects Scientist Nelson Thurman, Senior Fate Scientist Environmental Risk Branch II Environmental Fate and Effects Division (7507P) Branch Chief, Environmental Risk Assessment Branch #: Arthur-Jean B. Williams, Acting Branch Chief Environmental Risk Branch II Environmental Fate and Effects Division (7507P) 2 Table of Contents 1. Executive Summary.................................................................................................8 2. Problem Formulation .............................................................................................14 2.1 Purpose...........................................................................................................................14 2.2 Scope..............................................................................................................................16 2.3 Previous Assessments ....................................................................................................18 2.4 Stressor Source and Distribution ...................................................................................19 2.4.1 Environmental Fate -
Diurnal Leaf Movement Effects on Spray Interception and Glyphosate Efficacy Author(S): Jason K
Diurnal Leaf Movement Effects on Spray Interception and Glyphosate Efficacy Author(s): Jason K. Norsworthy, Lawrence R. Oliver and Larry C. Purcell Source: Weed Technology, Vol. 13, No. 3 (Jul. - Sep., 1999), pp. 466-470 Published by: Cambridge University Press on behalf of the Weed Science Society of America Stable URL: http://www.jstor.org/stable/3989032 Accessed: 09-02-2018 21:24 UTC JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new forms of scholarship. For more information about JSTOR, please contact [email protected]. Your use of the JSTOR archive indicates your acceptance of the Terms & Conditions of Use, available at http://about.jstor.org/terms Cambridge University Press, Weed Science Society of America are collaborating with JSTOR to digitize, preserve and extend access to Weed Technology This content downloaded from 160.36.239.64 on Fri, 09 Feb 2018 21:24:07 UTC All use subject to http://about.jstor.org/terms Weed Technology. 1999. Volume 13:466-470 Diurnal Leaf Movement Effects on Spray Interception and Glyphosate Efficacy' JASON K. NORSWORTHY, LAWRENCE R. OLIVER, and LARRY C. PURCELL2 Abstract: Time of day at which a herbicide is applied can affect efficacy, and variability may be attributed to leaf angles at application. Spray interception by hemp sesbania (Sesbania exaltata), sicklepod (Senna obtusifolia), and prickly sida (Sida spinosa) under day and night conditions was quantified by measuring interception of a 2-M potassium nitrate solution. -
(12) United States Patent (10) Patent No.: US 7,943,644 B2 Uhr Et Al
USOO794364.4B2 (12) United States Patent (10) Patent No.: US 7,943,644 B2 Uhr et al. (45) Date of Patent: May 17, 2011 (54) STABILIZATION OF IODINE-CONTAINING (56) References Cited BOCDES BY MEANS OF SPECIAL AZOLE COMPOUNDS U.S. PATENT DOCUMENTS 2,739,922 A * 3/1956 Shelanski ..................... 524,548 (75) Inventors: Hermann Uhr, Leverkusen (DE); 4,276,211 A 6/1981 Singer et al. ... 260/29.6 MN Johannes Kaulen, Odenthal (DE); 4.297.258 A 10/1981 Long, Jr. .............. 260f29.6 MN Thomas Jaetsch, Köln (DE); Peter 4,552,885. A 1 1/1985 Gabriele et al. .............. 514/316 Spetmann, Leverkusen (DE) 5,051,256 A * 9/1991 Barnes ........... ... 424/402 6,143,204. A 1 1/2000 Lutz et al. ...... ... 252/384 rsr rr 6.353,021 B1 3/2002 Gaglani et al. ... 514,478 (73) Assignee: NNESS putschland GmbH, 6,472,424 B1 10/2002 Gaglani et al. ... 514,478 everkusen (DE) 6,946,427 B2* 9/2005 Lutz et al. ...... ... 504,140 c - 2006/00 13833 A1 1/2006 Bartko ........... ... 424/400 (*) Notice: Subject to any disclaimer, the term of this 2007/0128246 A1* 6/2007 Hossainy et al. ............. 424/423 patent is extended or adjusted under 35 U.S.C. 154(b) by 18 days. FOREIGN PATENT DOCUMENTS WO 98.22543 5, 1998 (21) Appl. No.: 12/281,163 WO 99.291.76 6, 1999 WO OOf 16628 3, 2000 (22) PCT Filed: Feb. 21, 2007 WO 2007 O28527 3, 2007 (86). PCT No.: PCT/EP2007/001480 OTHER PUBLICATIONS S371 (c)(1), Nomiya, Kenji, et al. -
AP-42, CH 9.2.2: Pesticide Application
9.2.2PesticideApplication 9.2.2.1General1-2 Pesticidesaresubstancesormixturesusedtocontrolplantandanimallifeforthepurposesof increasingandimprovingagriculturalproduction,protectingpublichealthfrompest-bornediseaseand discomfort,reducingpropertydamagecausedbypests,andimprovingtheaestheticqualityofoutdoor orindoorsurroundings.Pesticidesareusedwidelyinagriculture,byhomeowners,byindustry,andby governmentagencies.Thelargestusageofchemicalswithpesticidalactivity,byweightof"active ingredient"(AI),isinagriculture.Agriculturalpesticidesareusedforcost-effectivecontrolofweeds, insects,mites,fungi,nematodes,andotherthreatstotheyield,quality,orsafetyoffood.Theannual U.S.usageofpesticideAIs(i.e.,insecticides,herbicides,andfungicides)isover800millionpounds. AiremissionsfrompesticideusearisebecauseofthevolatilenatureofmanyAIs,solvents, andotheradditivesusedinformulations,andofthedustynatureofsomeformulations.Mostmodern pesticidesareorganiccompounds.EmissionscanresultdirectlyduringapplicationorastheAIor solventvolatilizesovertimefromsoilandvegetation.Thisdiscussionwillfocusonemissionfactors forvolatilization.Thereareinsufficientdataavailableonparticulateemissionstopermitemission factordevelopment. 9.2.2.2ProcessDescription3-6 ApplicationMethods- Pesticideapplicationmethodsvaryaccordingtothetargetpestandtothecroporothervalue tobeprotected.Insomecases,thepesticideisapplieddirectlytothepest,andinotherstothehost plant.Instillothers,itisusedonthesoilorinanenclosedairspace.Pesticidemanufacturershave developedvariousformulationsofAIstomeetboththepestcontrolneedsandthepreferred -
Redox Imbalance Caused by Pesticides: a Review of OPENTOX-Related Research
Marjanović Čermak AM, et al. Redox imbalance caused by pesticides Arh Hig Rada Toksikol 2018;69:126-134 126 Review DOI: 10.2478/aiht-2018-69-3105 Redox imbalance caused by pesticides: a review of OPENTOX-related research Ana Marija Marjanović Čermak, Ivan Pavičić, and Davor Želježić Institute for Medical Research and Occupational Health, Zagreb, Croatia [Received in February 2018; Similarity Check in February 2018; Accepted in May 2018] Pesticides are a highly diverse group of compounds and the most important chemical stressors in the environment. Mechanisms that could explain pesticide toxicity are constantly being studied and their interactions at the cellular level are often observed in well-controlled in vitro studies. Several pesticide groups have been found to impair the redox balance in the cell, but the mechanisms leading to oxidative stress for certain pesticides are only partly understood. As our scientific project “Organic pollutants in environment – markers and biomarkers of toxicity (OPENTOX)” is dedicated to studying toxic effects of selected insecticides and herbicides, this review is focused on reporting the knowledge regarding oxidative stress-related phenomena at the cellular level. We wanted to single out the most important facts relevant to the evaluation of our own findings from studies conducted onin vitro cell models. KEY WORDS: antioxidants; apoptosis; glyphosate; in vitro; neonicotinoids; organophosphates; oxidative stress; pyrethroids; reactive oxygen species Over the years, population growth and changes in food (HrZZ), is dedicated to studying the toxic effects of two consumption patterns have challenged agricultural major pesticide classes with three subgroups each: (A) production to meet the demand for food and quality insecticides (organophosphates, neonicotinoids, and standards. -
Literature Review of Controlling Aquatic Invasive Vegetation With
Eurasian watermilfoil in Christmas Lake, 2011 Literature Review on Controlling Aquatic Invasive Vegetation with Aquatic Herbicides Compared to Other Control Methods: Effectiveness, Impacts, and Costs Prepared for: Prepared by: Minnehaha Creek Watershed District Steve McComas Blue Water Science St. Paul, MN 55116 September 2011 1 Literature Review on Controlling Aquatic Invasive Vegetation with Aquatic Herbicides Compared to Other Control Methods: Effectiveness, Impacts, and Costs Steve McComas, Blue Water Science Table of Contents page number Introduction .................................................................................................................................................................. 1 Use of Herbicides as an Aquatic Plant Control Technique ...................................................................................... 2 How Herbicides Work and Their Mode of Action ....................................................................................................... 3 Aquatic Herbicide Impacts on Humans and the Ecosystem ....................................................................................... 8 Where to Find Sources of Specific Information on herbicide Products and Their Active Ingredients ....................... 16 Harvesting, Drawdown, and Biocontrol as Aquatic Plant Control Techniques ................................................... 17 Summary of Control Techniques for Non-Native Curlyleaf Pondweed and Eurasian Watermilfoil ................... 25 Control Techniques for Other -
US Environmental Protection Agency Office of Pesticide Programs
US Environmental Protection Agency Office of Pesticide Programs Reregistration Eligibility Decision for Prometon March 25, 2008 United States Prevention, Pesticides EPA 738-R-08-004 Environmental Protection and Toxic Substances Agency (7508P) Reregistration Eligibility Decision for Prometon TABLE OF CONTENTS GLOSSARY OF TERMS AND ABBREVIATIONS............................................................................... 4 I. INTRODUCTION.............................................................................................................................. 5 II. CHEMICAL OVERVIEW................................................................................................................ 6 A. REGULATORY HISTORY ................................................................................................................... 6 B. CHEMICAL IDENTIFICATION............................................................................................................. 6 C. USE PROFILE .................................................................................................................................... 7 D. ESTIMATED USAGE OF PESTICIDE.................................................................................................... 8 III. SUMMARY OF PROMETON RISK ASSESSMENTS............................................................. 9 A. HUMAN HEALTH RISK ASSESSMENT ............................................................................................... 9 1. Toxicity of Prometon.................................................................................................................. -
Pesticide Contamination Prevention Program Report A.R.S
Pesticide Contamination Prevention Program Report A.R.S. 49-303.C § The Arizona Pesticide Contamination Prevention Program was established by the Environmental Quality Act of 1986. The major objective of the program is to prevent or mitigate groundwater pollution by agricultural pesticides. The program is composed of the following four major components: 1) Product chemistry and environmental fate review – Prior to registering an agricultural-use pesticide with the Arizona Department of Agriculture (ADA), applicants must submit product chemistry and environmental fate data of the associated active ingredient to ADEQ for review and approval. The information is used to determine the potential of the active ingredient to leach to groundwater, and generate the Arizona Groundwater Protection List (GWPL). 2) Groundwater Protection List – The GWPL is a list of agricultural pesticides in use in Arizona and their active ingredients that have the potential to pollute groundwater, based on product chemistry and environmental fate data and groundwater monitoring of the active ingredient(s). 3) Environmental monitoring – ADEQ, in cooperation with the ADA, monitors groundwater and soils in agricultural areas throughout the state for the presence of agricultural-use pesticide active ingredients on the GWPL. 4) Compilation of data – ADEQ collects and reports product use information for agricultural pesticides applied to the soil on the GWPL. Results of pesticide monitoring for ground-water wells are evaluated and stored in the Water Quality Division’s groundwater database. This report which covers calendar year 2011 is in fulfillment of a requirement pursuant to A.R.S. § 49- 303.C that requires ADEQ to report the following information to the Legislature annually: 1) A list of agricultural-use pesticide active ingredient for which there is a groundwater protection data gap (A.R.S.