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Rhodochrosite Gems Unstable Colouration of Padparadscha-Like
Volume 36 / No. 4 / 2018 Effect of Blue Fluorescence on the Colour Appearance of Diamonds Rhodochrosite Gems The Hope Diamond Unstable Colouration of in London Padparadscha-like Sapphires Volume 36 / No. 4 / 2018 Cover photo: Rhodochrosite is prized as both mineral specimens and faceted stones, which are represented here by ‘The Snail’ (5.5 × 8.6 cm, COLUMNS from N’Chwaning, South Africa) and a 40.14 ct square-cut gemstone from the Sweet Home mine, Colorado, USA. For more on rhodochrosite, see What’s New 275 the article on pp. 332–345 of this issue. Specimens courtesy of Bill Larson J-Smart | SciAps Handheld (Pala International/The Collector, Fallbrook, California, USA); photo by LIBS Unit | SYNTHdetect XL | Ben DeCamp. Bursztynisko, The Amber Magazine | CIBJO 2018 Special Reports | De Beers Diamond ARTICLES Insight Report 2018 | Diamonds — Source to Use 2018 The Effect of Blue Fluorescence on the Colour 298 Proceedings | Gem Testing Appearance of Round-Brilliant-Cut Diamonds Laboratory (Jaipur, India) By Marleen Bouman, Ans Anthonis, John Chapman, Newsletter | IMA List of Gem Stefan Smans and Katrien De Corte Materials Updated | Journal of Jewellery Research | ‘The Curse Out of the Blue: The Hope Diamond in London 316 of the Hope Diamond’ Podcast | By Jack M. Ogden New Diamond Museum in Antwerp Rhodochrosite Gems: Properties and Provenance 332 278 By J. C. (Hanco) Zwaan, Regina Mertz-Kraus, Nathan D. Renfro, Shane F. McClure and Brendan M. Laurs Unstable Colouration of Padparadscha-like Sapphires 346 By Michael S. Krzemnicki, Alexander Klumb and Judith Braun 323 333 © DIVA, Antwerp Home of Diamonds Gem Notes 280 W. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
List of New Mineral Names: with an Index of Authors
415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis. -
An Improved Approach to Crystal Symmetry and the Derivation And
71-22,530 SHANKLIN, Robert Elstone, 1915- AN IMPROVED APPROACH TO CRYSTAL SYMMETRY AND THE DERIVATION AND DESCRIPTION OF THE THIRTY- TWO CRYSTAL CLASSES BY MEANS OF THE STEREOGRAPHIC PROJECTION AND GROUP THEORY. The Ohio State University, Ph.D., 1971 Mineralogy University Microfilms, A XEROX Company , Ann Arbor, Michigan ©Copyright by Robert Elstone Shanklin 1971 AN IMPROVED APPROACH TO CRYSTAL SYMMETRY AND THE DERIVATION AND DESCRIPTION OF THE THIRTY-TNO CRYSTAL CLASSES BY MEANS OF THE STEREOGRA.PHIC PROJECTION AND GROUP THEORY DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of The Ohio State University By Robert Elstone Shanklin, A. B., M.S ★ * * * * Approved By Department of Mineralogy PLEASE NOTE: Some pages have indistinct print. Filmed as received. UNIVERSITY MICROFILMS. PREFACE The subject of order in the natural world is a favorite topic of scientists and philosophers alike. If there is any order in the universe, the crystalline state seems to be an excellent place to find it. That which is orderly should be comprehensible. There is no reason why a subject as rich in educational value, as reward ing in intellectual content, and as full of aesthetic satisfaction as crystallography should remain behind a veil of obscurity, the property of a few specialists. As a teacher of crystallography and mineralogy for many years, it has become apparent to me that existing textbooks often do not serve the needs of either students or instructors. The material generally available on elementary crystallography seems to vary between excessively abstruse and involved on the one hand, or too brief on the other. -
Strontium Borate) Mineral
STUDIES ON TUNELLITE (STRONTIUM BORATE) MINERAL Hüseyin GÜLENSOY and T. TEBERDAR İstanbul University, Faculty of Chemistry SUMMARY. — In these studies, the physical, chemical and mineralogical properties of the tunellite found associated with the boron mines in Turkey, which have long been known, have been investigated and the chemical compositon determined. The thermal decomposition of tunellite mineral has been studied both by dynamic and static methods. The results obtained with the methods above were checked with those obtained by Röntgenographic analysis and with the DTA studies. As a result of these studies, it has been observed that the tunellite mineral was transformed into veatchite mineral, after losing 4 molecules of its crystal water. INTRODUCTION AND HISTORY Boron minerals which are gaining ever-increasing importance in the world industry occur widespread in the northwest part of Turkey. Boron occurrences of the country are generally located in the vicinity of Bigadiç, Balıkesir, Mustafakemalpaşa, Emet and Eskişehir. Borate ores encountered in these mines are generally, ulexite and colemanite. The reserves and the grade of the ore are con- sidered favorable for economic production. Associated with the colemanite and ulexite produced from these mines, some other boron minerals are also found and the most important of these are inyoite, meyerhofferite, tertschite and howlite. These secondary minerals are locally found interbedded in the clay seams, as thin beds or nodules. In some mines, a new mineral, showing the composition of strontium borate, is found in association with colemanite and ulexite; this new mineral, which sometimes shows a prismatic struc- ture, is also found to occur closely mixed with clay having bentonite texture. -
108. the Crystal Structure O F Axinite Revised
490 Proc. Japan Acad., 45 (1969) [Vol. 45, 108. The Crystal Structure o f Axinite Revised By Tei-ichi ITO, M.J.A., Yoshio TAKEUCHI,*' Toru OzAWA,*' Takaharu ARAKI,**',fi' Tibor ZOLTAI,**' and J. J. FINNNEY***' (Comm. June 10, 1969) The crystal structure of axinite, H (Fe, Mn) Ca2A12BSi4016, was investigated by Ito and Takeuchi (1952) on the assumption that boron atoms in the structure form separate B03 groups like tourma- line (Ito, 1950; Ito and Sadanaga, 1951; vide Buerger et al., 1962). The structure then deduced by taking account of Patterson projec- tions consists of separate Si4012 and B03 groups bound together by Fe, Al and Ca atoms. Although the structure was crystallo-chemically reasonable, the residual R could not be reduced to less than 0.35 for all the reflections observed. Since axinite is one of those common silicate minerals whose crystal structure has not been refined, it has been thoroughly reinvestigated using modern techniques. The specimens used are from Woodlake, California (Type collec- tion #9620, Colorado School of Mines). Chemical analysis by an electron microprobe gives the Fe to Mn ratio of the specimen to be approximately unity. The lattice constants of the triclinic crystal are a=7.1566+0.0015, a=91.75°+0.83 b=9.1995±0.0020, 9=98.14° + 0.02 c=8.9585±0.0022, T=77.30° + 0.02 and the unit cell contains two formula units. Three dimensional intensities were collected by a scintillation counter using an equi- inclination single-crystal diffractometer, MoKa radiation and a pair of balanced Zr-Y filters. -
Ferroaxinite Ca2fe2+Al2bsi4o15(OH)
2+ Ferroaxinite Ca2Fe Al2BSi4O15(OH) c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Triclinic. Point Group: 1: Crystals typically °attened, axe-head-shaped, to 20 cm; granular, massive. Physical Properties: Cleavage: Good on 100 , poor on 001 , 110 , and 011 . Fracture: Uneven to conchoidal. Tenacity: Brfittleg. Hardnessf = 6g.5{f7 Dg (measf.) =g3.25{3.28 D(calc.) = [3.33] Optical Properties: Transparent to translucent. Color: Clove-brown, brown, plum-blue, pearl-gray; colorless to pale brown or blue in thin section. Luster: Vitreous. Optical Class: Biaxial ({). ® = 1.674{1.682 ¯ = 1.682{1.690 ° = 1.685{1.693 2V(meas.) = 65±{75± Cell Data: Space Group: P 1: a = 7.1437(4) b = 9.1898(6) c = 8.9529(4) ® = 91:857(6)± ¯ = 98:188(5)± ° = 77:359(4)± Z = 2 X-ray Powder Pattern: Isµere, France. 2.812 (100), 3.16 (90), 3.46 (80), 6.30 (70), 3.68 (60), 3.28 (60), 2.998 (60) Chemistry: (1) (2) (3) (1) (2) (3) SiO2 43.14 41.97 42.16 ZnO 0.04 TiO2 0.10 MgO 1.34 0.66 B2O3 6.12 [6.14] 6.11 CaO 19.76 19.18 19.67 Al2O3 16.70 17.24 17.88 Na2O 0.36 Fe2O3 1.28 K2O 0.23 + FeO 7.12 10.41 12.60 H2O 1.56 [1.57] 1.58 MnO 1.66 2.61 Total 99.41 [99.78] 100.00 (1) Durango, Mexico. (2) Rosebery district, Tasmania, Australia; by electron microprobe, B2O3 interpolated from end members, H2O calculated from stoichiometry. -
Minerals of the Axinite Group from Norwegian Localities
Minerals of the axinite group from Norwegian localities Fred Steinar Nordrum, Alf Olav Larsen og Muriel Erambert Introduction The mineral known today as axinite was first described by Schreiber in 1781, but thought to be a variety of schorl. During the next two decades the mineral was referred to under different names: violet schorl, yanolite, thumerstein, thumite and glasschorl. The name axinite was first applied by Hauy in 1799, in reference to the common axe-like shape of the crystals. The axinite group minerals are complex cyclosilicates. The three Ca-dominant end-members are ferroaxinite, manganaxinite and magnesia-axinite, named after the second most abundant cations, and with the general formula Ca4(Fe,Mn,Mg),AI4B2Sia030(OH),. Tinzenite has a Ca deficiency, compensated by an excess of Mn, and with the formula Ca2Mn.A14B2Sia030(OH),. The definition of ferroaxinite, manganaxinite and tinzenite was established by Sanero & Gollardi (1968), while magnesio-axinite was described by Jobbins et al. (1975). Axinite from Norway was first described by Schumacher (1801) who reported the mineral both from the silver deposits at Kongsberg and from Torbjlilrnsbo iron mine at Arendal. Keilhau (1838) mentioned axinite from Nikkerud iron mine near Drammen. Goldschmidt (1911) thoroughly described axinite from Arvoll near Oslo, and his chemical analysis showed that the mineral was close to the manganaxinite end member. He also mentioned another axinite locality at Arvoll, as well as Nikkerud (Aserud) near Drammen. Munster (1883) mentioned axinite from the Kongsberg silver deposits, while Neumann (1944) described axinite from several localities within the Kongsberg silver deposits, and published the chemical composition of an axinite from Golles Hulfe in der Noth mine (358 m level). -
American Journal of Science
1 'Ui J}-_) 3J/ e~,. ~r1Vlv~ J. HE AMERICAN JOURNAL OF SCIENCE. EDITOR: EDWARD S. DANA. ASSOCIATE EDITORS PROFESSORS GEO. L. GOODALE, JOHN TROWBRIDGE, H. P. BOWDITCH AND W. G. F ARLO'V, OF CAMBRIDGE, PROFESSORS O. C. MARSH, A. E. VERRILL AND H. S. WILLIAMS, OF NEW HAVEN, PROFESSOR GEORGE F. BARKER, OF PHILADELPHIA, PROFESSOR H. A. RO'VLAND, OF BALTIMORE, MR. J. S. DILLER, OF WASHINGTON. FOURTH SERIES. YOLo III-[WHOLE NUMBER, CLIIL] Nos. 13-18. JANUARY '1'0 JUNE, 1897. WITH SEVEN PLATES• • ># •.'" , • .' ,_'_._,9_._;~: ", ~ • oJ " ... • ... ~ ~ • NEW HAYEN, CONNECTICUT. 1897. ,Sf- Penfield and Jioote-Rmblhlgite, a new Silicate. 413 ART. XLII.-On Rmblingite, a new Silicate from Franklin Furnace, N. J., containing Sulphur Dio;:cide and Lead; by S, L. PENFIELD and H. W. FOOTE, MR. FRANK L. NASON, who has been especially interested in the geology and mineralogy of the zinc deposits of Frank lin, New Jersey, has recently brought to our attention a mineral from the Parker shaft of the New Jersey Zinc Com pany, which owing' to its unusual chemical composition is of especial interest. The mineral occurs in dense, white, compact masses, which consist of an aggregate of minute prismatic crystals. These when examined with the microscope show parallel extinction and a weak double refraction, but they are so minute that the system of crystallization could not be deter mined. The specific gravity is 3'433; hardness a trifle under 3. A chemical analysis of this material by Foote gave the following resnlts : 1. II. Average. Ratio, SiO. __ . -
STUDIES of BORATE MINERAI,S (ID: X-RAY CRYSTALLOG- RAPHY of INYOITE and MEYERHOFFERITE; X-RAY and MORPHOLOGICAL CRYSTALLOGRAPHY of 2Cao-3Bzo .9H2O*
STUDIES OF BORATE MINERAI,S (ID: X-RAY CRYSTALLOG- RAPHY OF INYOITE AND MEYERHOFFERITE; X-RAY AND MORPHOLOGICAL CRYSTALLOGRAPHY OF 2CaO-3Bzo .9H2O* C. L. Cunrsr, [/. S. GeologicalSuraey, Washington25, D. C. Ansrnacr fnyoite is monoclinic,P21/a, ao:10.63, bo:fi.A6, co:8.40rA, F:114.02,. 2CaO'3BrOa.9HzOistriclinic PT, ao: /.94, bo:9.452,co-7.412 A, a:101"21,,p-: l}l"7g,, t:99"49'. The findingsof Switzerin Palache(1938) for meyerhofferiteare confirmed. Powder patterns, partially indexed, are given for inyoite, meyerhofierite,and 2CaO.3BzOs.9HrO. INrnooucrroN ANDAcrwowr,ooGMENTS A systematic study of borate minerals has been continued in the pres- ent investigation with the determination of the r-ray crystallography of inyoite, 2CaO.3B2OB.13H2O, the *-ray crystallographyand morphology of the synthetic mineral 2CaO.38zOs.9HzO,and the redeterminationof the r-ray crystallography of meyerhofierite, 2CaO.3BzOt. jIJzO. Results obtained on meyerhofferite were in excellent agreementwith those previ- ously reported by Switzer in Palache (1933). Powder patterns of the three compounds have been measured and partially indexed. The work was undertaken primarily as a preliminary to the determina- tion of the structures. The writer is indebted to various colleaguesin the U. S. Geological Survey: Waldemar T. Schaller furnished the crystals studied; Mrs. Joan R. Clark made many of the calculations and film measurements; Howard T. Evans, Jr., made the goniometric measurementson and the drawing of 2CaO.3B2OB.9HsOand,also renderedmuch helpful advice; Fred A. Hildebrand prepared the powder patterns reported. ExpBnrlrpwrAr, WoRK All of the crystals used were synthetic. Schaller (personal communica- tion) has furnished the following description of the methods of prepara- tion: Inyoite (2:3:13). -
Inyoite Cab3o3(OH)5 • 4H2O C 2001-2005 Mineral Data Publishing, Version 1
Inyoite CaB3O3(OH)5 • 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as crystals, short prismatic along [001], tabular on {001}, exhibiting prominent {110} and {001} and a dozen other minor forms, to 2.5 cm; in cockscomb aggregates of pseudorhombohedral crystals; also coarse spherulitic, granular. Physical Properties: Cleavage: {001}, good; {010}, distinct. Fracture: Irregular. Tenacity: Brittle. Hardness = 2 D(meas.) = 1.875 D(calc.) = 1.87 Soluble in H2O. Optical Properties: Transparent, translucent on dehydration. Color: Colorless, white on dehydration. Luster: Vitreous. Optical Class: Biaxial (–). Orientation: Y = b; X ∧ c =37◦; Z ∧ c = –53◦. Dispersion: r< v, slight. α = 1.490–1.495 β = 1.501–1.505 γ = 1.516–1.520 2V(meas.) = 70◦–86◦ Cell Data: Space Group: P 21/a. a = 10.621(1)) b = 12.066(1) c = 8.408(1) β = 114◦1.2◦ Z=4 X-ray Powder Pattern: Monte Azul mine, Argentina. 7.67 (100), 2.526 (25), 3.368 (22), 1.968 (22), 2.547 (21), 3.450 (20), 2.799 (19) Chemistry: (1) (2) B2O3 37.44 37.62 CaO 20.42 20.20 + H2O 9.46 − H2O 32.46 H2O 42.18 rem. 0.55 Total 100.33 100.00 • (1) Hillsborough, Canada; remnant is gypsum. (2) CaB3O3(OH)5 4H2O. Occurrence: Along fractures and nodular in sedimentary borate deposits; may be authigenic in playa sediments. Association: Meyerhofferite, colemanite, priceite, hydroboracite, ulexite, gypsum. Distribution: In the USA, in California, from an adit on Mount Blanco, Furnace Creek district, Death Valley, Inyo Co., and in the Kramer borate deposit, Boron, Kern Co. -
Meyerhofferite Cab3o3(OH)
Meyerhofferite CaB3O3(OH)5 • H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Triclinic. Point Group: 1. Rare as complex acicular to crude crystals, to ∼4 cm, in fibrous divergent, radiating aggregates, commonly reticulated; may be nodular. Physical Properties: Cleavage: On {010}, perfect; in traces on {100} and {110}. Hardness = 2 D(meas.) = 2.120 D(calc.) = 2.125 Optical Properties: Transparent to translucent. Color: Colorless to white, pale yellow. Luster: Vitreous to silky. Optical Class: Biaxial (–). Orientation: X (165◦,62◦); Y (45◦300,47◦); Z (-83◦,55◦) [with c (0◦,0◦) and b∗ (0◦,90◦) using (φ,ρ)]. Dispersion: r> v.α= 1.500 β = 1.535 γ = 1.560 2V(meas.) = 78◦ Cell Data: Space Group: P 1. a = 6.632(1) b = 8.337(1) c = 6.4748(6) α =90.81(1)◦ β = 101.97(1)◦ γ =86.76(1)◦ Z=2 X-ray Powder Pattern: Mt. Blanco, California, USA. (ICDD 12-411). 8.31 (100), 6.47 (100), 4.97 (25), 4.15 (20), 3.15 (20), 3.07 (20), 2.501 (20) Chemistry: (1) (2) B2O3 46.40 46.71 CaO 25.45 25.08 + H2O 27.75 − H2O 1.01 H2O 28.21 Total 100.61 100.00 • (1) Mt. Blanco, California, USA. (2) CaB3O3(OH)5 H2O. Occurrence: Typically a minor component of sedimentary or lake-bed borate deposits. Association: Inyoite, colemanite, hydroboracite, ulexite. Distribution: In the USA, from the Mt. Blanco deposit and along Gower Gulch, Furnace Creek district, Death Valley, Inyo Co., and in the Kramer borate deposit, Boron, Kern Co., California.