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Aeolian Inputs As Parent Materials for Podzols and Terra-Rossa Soils in A

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Aeolian Inputs As Parent Materials for Podzols and Terra-Rossa Soils in A Aeolian inputs as parent materials for Podzols and terra-rossa soils in a dolomitic landscape in the Italian Alps (Salmezza, BG, Italy) M D’Amico E Casati M Barcella F Previtali Università di Torino, DISAFA Università di Milano Bicocca, DISAT Introduction Aeolian dust is an important source of elements and minerals in karst soils, although often neglected during soil surveys and studies. Extremely high pedo-diversity in a karst area in an unglaciated sector of the Lombard Prealps (Salmezza, Nembro municipality, Bergamo), on pure or quartz-rich dolostone. Where do soil-forming materials come from? Podzols, Cambisols, Rendzic Leptosols/Phaeozems, buried Terra Rossa (Rhodic Luvisol)/brown “Haplic Luvisol”, Haplic Umbrisol Site properties Elevation: 1100-1200 m a.s.l. MAP: 1600 mm/y MAT: 7°C Natural vegetation: beech dolostone: <1% impurities Main element composition Areno-dolostone: 17% sand-sized, SiO2 % Al2O3 % Fe2O3 % MgO % CaO % Dolostone 0.30 0.06 0.04 20.24 29.47 well crystallized quartz (after Areno-dolostone 29.76 0.02 0.02 15.12 21.42 dissolution); dolomite 83% Podzols On Si-dolostone P2 pH TXT E 4.7 S Bhs1 5.7 S Bhs2 6.5 S R Buried Terra-rossa in sinkholes P3 pH TXT AE 5.7 LS Bw(s) 6.2 S 2Bt 6.1 SC R Sinkhole on a slope on Si-dolostone Flat doline on pure dolostone P8 pH TXT A 6.3 CL Bw 6.8 SC 2Bt2 6.7 C R Luvisols in karst valleys P7 pH TXT Silt % Pleistocene loess inputs in karst BA 6.3 L 42.9 valleys and solines (highest silt); 2Bt1 6.8 LC 25.9 3C 6.9 LS 10.5 No loess on slopes Rendzic Leptosols/Phaeozems On both dolostone and Si-dolostone cos2 pH TXT P5 pH TXT Silt % A 8.4 SL A 8.4 LS 22.1 R R 120 Clay mineralogy 100 Feldspar Clorite Smectite 80 Kaolinite 14-14 60 gibbsite 10-14 Vermiculite 40 illite talc 20 quartz 0 P1EA P1Bh P1Bh2 P3Bw P3-2Bt P3-2Cr P5A P6Bw1 P6Bw3 P7BA P7Bt P7-2Bt P7-2C P8 Bw P8-2Bt1 P8-2Bt2 Podzol Terra-rossa Haplic Luvisol Terra-rossa Rendzic Leptosol Eutric Cambisol Chlorite abundant in Bw horizons and in surface soils; scarce in buried soils. Kaolinite common, particularly in surface soils (Podzols and Bw horizons). Vermiculite common in surface soils (Podzols and Bw horizons) but not in Rendzic Leptosols Gibbsite particularly common in buried terra-rossa soils (in agreement with Al2O3 content) HIS and HIV common in some profiles, not different between surface and buried soils Mineralogical discontinuites between surface soil horizons and buried ones: different ages 19,000 Mass balance (tau) Based on immobile element TiO2: 14,000 Al2O3 Fe2O3 Huge enrichment in Al (up to MgO 9,000 1900%) and Fe; CaO almost complete loss of Ca and Mg; SiO2 SiO2 greatly lost as well. 4,000 Trends were related to soil age (assuming Rendzinc Leptosols the -1,000 youngest, Cambisols and Podzols of P1E P1Bhs2 P3-2Bt P5A P7BA P7-3C P8-2Bt2 P1Bhs P3Bw P6 Bw cos2A P7-2Bt1 P8Bw Holocene age, buried soils older), except in P8 (terra-rossa soil on Podzol Rendzic Leptosol Terra-rossa pure dolostone); small losses and Terra-rossa Haplic Luvisol gains in Rendzic Leptosols, a bit Eutric Cambisol higher in Bw horizons, much higher in Bt and Bhs horizons. Based on immobile sand-sized quartz in Podzols: The silica loss is not compatible with Greater enrichment in Al and Fe; primary sand-sized, well crystallized almost complete loss of Ca and Mg; quartz in Podzols and in P3: Tau – Al2O3 Tau – Fe2O3 P1 E 8.59 2.05 Post-glacial aeolian inputs in Podzols P1 Bhs 38.22 17.13 can explain element enrichment P1 Bhs2 53.34 11.78 NormalizedNormalized «stable» element elements ratios ratios 1 0,9 0,8 0,7 0,6 0,5 0,4 0,3 0,2 0,1 0 SiO2/TiO2 (Fe+Al)/Ti (Fe+Al)/Si Fe/Al SiO2/R2O3 Zr/Ti Na/K Ca/Mg Si/Al Podzol Terra-rossa Rendzic Leptosol Haplic Luvisol Eutric Cambisol The variability of the «stable» elements ratios commonly found in the literature is broad between different soil types and even horizons No univocal aeolian input (loess vs saharan dust vs local dust) is immediately visible. Discussions and Conclusions The dissolution of dolostone/areno-dolostone releases few elements to the soils. Shallow layers of LGM loess can be observed in dolines and karst valleys, mixed with slope materials but quite well characterized mineralogically even if strongly weathered; On slopes, no loess can be detected, both in surface soils and in buried soils in sinkholes, likely removed by solifluction and erosion, particularly during cold Pleistocene periods Strong aeolian (Saharan?) inputs are necessary, well visible on arenodolostone. On arenodolostone, the fast dissolution of dolomite in this temperate-suboceanic climate releases pure quartz sand, in which podzolization takes place. Aeolian inputs (Saharan dust?) slowly deposits on the soil surface, where the minerals are quickly weathered in the aggressive podzol soil environment; bases are leached, while Fe, Al, Ti etc are concentrated, particularly in spodic horizons. Different element ratios in different soil types evidences the strong effect of pedogenic processes, also during quite short periods. Thank you! .
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