Title 農薬の名称 Author(S) 大野, 稔 Citation 防虫科学 (1956), 21(2
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UNIVERSIDAD COMPLUTENSE DE MADRID FACULTAD DE CIENCIAS QUíMICAS DEPARTAMENTO DE QUíMICA ANALITICA UNIVERSIDAD COMPLUTENSE DETERMINACION DE HERBICIDAS N1TROFENOLES Y S-TRIAZINAS POR VOLTAMPEROMETRIA DE ADSORCION-REDISOLUCION Directores: Fi. Manuel de Villena Rueda J.M. Pingarrón Carrazón MARíA PEDRERO MUÑOZ MADRID, 1993 Ciudad Universitaria 28040 Madrid (España) TeIéf. 394 43 31 Fax: 394 43 29 UNIVERSIDAD COMPLUTENSE FACULTAD DE CIENCIAS QUíMICAS DEPARTAMENTO DE QUíMICA ANALíTICA LUIS MARIA POLO DIEZ, CATEDRATICO Y DIRECTOR DE ESTE DEPARTAMENTO CERTIFICO: Que el presente trabajo, titulado “Determinación de herbicidas nitrofenoles y s-triazinas por valtamperometría de adsorción- redisolución”, ha sido realizado en este departamento por Dfia. MaríaPedrero Muflo;bajo la dirección del Dr. D. FranciscoJavier Manuel de Villena Rueda y del Dr. D. Jase Manuel Pingarrón Carrazón,ProfesoresTitulares de estedepartamento, constituyendo la Tesis Doctoral de su autora. Madrid, Junio 1993 A mis padres El presente trabajo ha sido realizado en el Departamento de Química Analítica de la Universidad Complutense de Madrid con la ayuda y colaboración de muchas personas. A todas ellas quiero expresar mi agradecimiento, en especial: Al Prof. Dr. Don Francisco Javier Manuel de Villena Rueda y al Prof. Dr. Don Jose Manuel Pm garrón Carrazón, sus directores, por su inestimable ayuda, dedicación y paciencia. Al Prof. Dr. Don Luis María Polo Diez, catedrático y director de este departamento, por haber puesto a mi disposición todos los medios necesarios para llevarlo a cabo. A las Lcdas. Dha. Victoria Calvo Baza, Dha. Paloma Soriano Gil-Albare- líos, Dha. Belén Casado Perdices y Dha. Rosa Alonso Velasco, por su generosa colaboración. Y a todas aquellas personas que de una manera u otra han contribuido a su realización, en especial a Dha. -
Ortho-Cresyl-Phosphate Poisoning
J Neurol Neurosurg Psychiatry: first published as 10.1136/jnnp.25.3.234 on 1 August 1962. Downloaded from J. Neurol. Neurosurg. Psychiat., 1962, 25, 234 Toxic polyneuritis in Bombay due to ortho-cresyl-phosphate poisoning D. D. VORA, DARAB K. DASTUR, BEATRIZ M. BRAGANCA, L. M. PARIHAR, C. G. S. IYER, R. B. FONDEKAR, AND K. PRABHAKARAN From Lokmanya Tilak Municipal General Hospital, Sion, Neurology Unit, Indian Council of Medical Research, and Department of Enzyme Chemistry, Indian Cancer Research Centre, Bombay Since 1930 poisoning with ortho-cresyl-phosphate purchased food from the same grocer in their neigh- has been recognized as a cause of peripheral poly- bourhood. He also mentioned that others staying in neuritis (Smith, Elvove, and Frazier, 1930). Ortho- the same locality and consuming mustard oil, but cresyl-phosphate (O.C.P.) is widely used as a purchasing their food from other grocers, were not plasticiser and in the production of heat-stable affected. The examination of the other affected per- lubricating oils. Many cases of industrial poisoning sons revealed identical histories and clinical pictures. with O.C.P. have been reported since then but as a In this group there was no history of gastro-enteritis result of strict precautionary measures it has now or of febrile illness preceding the paralysis. These become a rarity. However, the occasional contamina- patients also asserted that all those who were buying is not uncommon. their food from the same grocer but who were not tion of food with O.C.P. Protected by copyright. Poisoning with O.C.P. -
Title <綜説>Insecticide-Resistance and Darwinism Author(S) BROWN
Title <綜説>Insecticide-resistance and Darwinism Author(s) BROWN, A.W.A. Citation 防虫科学 (1957), 22(2): 277-282 Issue Date 1957-05-31 URL http://hdl.handle.net/2433/157282 Right Type Departmental Bulletin Paper Textversion publisher Kyoto University Insecticide-resistance and Darwinism. * A. W. A; BROWN (Professor and Head of the Department of Zoology, University of Western Ontario, London, Canada. Temporarily, Scientist (Biologist) of W. H. 0., Division of Environmental Sanita- tion). Received May 8, 1957. Botyu-Kagaku 22,277,1957. ' ' 48. *1m~lmmt±c9"?-! ='AA (!'J;m: rJJmWF 22, 282, 1957) Next summer, the International Congress of including Hikone in 1954. Zoology will 'meet in London to celebrate the The housefly has also developed resistance to centenary of"The Origin of Species," and to other insecticides, which like DDT are in the class honour its author Charles Robert Darwin. Darwin known as chlorinated' hydrocarbons, In 1949, stated, 100 years ago, that it was natural selection, BHC-and dieldrin-resistance was reported in Cali operating on the normal variation of animals and fornia. Finally resistance has appeared to those plants which Over the course' of time separated insecticides which we at first thought never in the subspecies which,' he said, were the origin duce it, namely the organophosphorus compounds; of species. 'Vith that book he made his out it was reported from Denmark in 1955 that para standing contribution to the progress of science thion, diazinon and Resitox can no longer control and radically changed the thought of man. For houseflies there. proof, Darwin pointed not only to 'what could This resistance is not only confined to the be seen in different parts of the world, but also housefly. -
The Effects of Occupational Exposure to Chlorpyrifos on the Peripheral
201 Occup Environ Med: first published as 10.1136/oem.2003.008847 on 25 February 2004. Downloaded from ORIGINAL ARTICLE The effects of occupational exposure to chlorpyrifos on the peripheral nervous system: a prospective cohort study J W Albers, D H Garabrant, S J Schweitzer, R P Garrison, R J Richardson, S Berent ............................................................................................................................... Occup Environ Med 2004;61:201–211. doi: 10.1136/oem.2003.008847 Aims: To determine whether chronic occupational exposure to chlorpyrifos at levels associated with various aspects of manufacturing produced a clinically evident or subclinical peripheral neuropathy. Methods: Clinical and quantitative nerve conduction study (NCS) examinations were performed on two occasions on chlorpyrifos manufacturing workers who had measurable chlorpyrifos exposure and a referent group. Baseline evaluations were performed on 53 of 66 eligible chlorpyrifos subjects and on 60 of 74 eligible referent subjects; one-year evaluations were completed on 111 of the 113 subjects evaluated at baseline. Results: Chlorpyrifos and referent groups differed significantly in measures of 3,5,6 trichloro-2-pyridinol excretion and plasma butyrylcholinesterase (BuChE) activity, indicating substantially higher exposures See end of article for authors’ affiliations among chlorpyrifos subjects. Few subjects had clinically important neurological symptoms or signs. NCS ....................... results were comparable to control values, and there were no significant group differences in NCS results at baseline, one year, or change over one year. No chlorpyrifos subject fulfilled conventional criteria for Correspondence to: Dr J W Albers, Department confirmed peripheral neuropathy at baseline or one-year examinations. The odds ratios for developing of Neurology, 1C325/ any diagnosable level of peripheral neuropathy among the chlorpyrifos subjects was not increased at 0032 University Hospital, baseline or at one year compared to referents at baseline. -
Newly Developed Insecticides for Pest Control
Page 2 CALIFORNIA AGRICULTURE September, I947 Oil Fractions And Their Toxic Vewly Developed Leasing Of Farm Lands In State Effect On Plants When Used As 'nsecticides For Thought To Be At Low Point Now Weed Killing Sprays Explained 'esf Control But Increase Is Anticipated Robert L. Metcalf (Continued from page 1) Scientific research by commercial ownership from one generation of Rental arrangements need to be nd governmental interests has re- farmers to the next. re-examined annually. ulted in an unprecedented devel- Young farmers find it a way to Trends pment of new materials showing expand their operations and earnings New procedures need to be devel- reat promise as insecticides. Intelli- more rapidly than through owner- oped to facilitate the gradual passage .ent evaluation of their potentiali- ship. of a farm from owner to son or po- ies will offer big dividends in im- Truck and crop specialists may In contrast to sprays in water solu- condense later. Thus each batch of tential purchaser with little capital. roving the efficiency of present shift their operations more readily New forms of profit sharing and tion, oils wet plant surfaces readily crude oil contains some gasoline ay pest control practices. where they lease a large part of the and tend to spread as thin films and some stove oil, and some Diesel fuel partnership contracts for farm op- DDD or TDE land they farm. eration will supplement traditional run down the stems. They penetrated etc., and each fraction may be re- Rental Arrangements moved within its own boiling range DDD or TDE is 2,2-bis-(p-chloro- leasing practices. -
Enzymatic Degradation of Organophosphorus Pesticides and Nerve Agents by EC: 3.1.8.2
catalysts Review Enzymatic Degradation of Organophosphorus Pesticides and Nerve Agents by EC: 3.1.8.2 Marek Matula 1, Tomas Kucera 1 , Ondrej Soukup 1,2 and Jaroslav Pejchal 1,* 1 Department of Toxicology and Military Pharmacy, Faculty of Military Health Sciences, University of Defence, Trebesska 1575, 500 01 Hradec Kralove, Czech Republic; [email protected] (M.M.); [email protected] (T.K.); [email protected] (O.S.) 2 Biomedical Research Center, University Hospital Hradec Kralove, Sokolovska 581, 500 05 Hradec Kralove, Czech Republic * Correspondence: [email protected] Received: 26 October 2020; Accepted: 20 November 2020; Published: 24 November 2020 Abstract: The organophosphorus substances, including pesticides and nerve agents (NAs), represent highly toxic compounds. Standard decontamination procedures place a heavy burden on the environment. Given their continued utilization or existence, considerable efforts are being made to develop environmentally friendly methods of decontamination and medical countermeasures against their intoxication. Enzymes can offer both environmental and medical applications. One of the most promising enzymes cleaving organophosphorus compounds is the enzyme with enzyme commission number (EC): 3.1.8.2, called diisopropyl fluorophosphatase (DFPase) or organophosphorus acid anhydrolase from Loligo Vulgaris or Alteromonas sp. JD6.5, respectively. Structure, mechanisms of action and substrate profiles are described for both enzymes. Wild-type (WT) enzymes have a catalytic activity against organophosphorus compounds, including G-type nerve agents. Their stereochemical preference aims their activity towards less toxic enantiomers of the chiral phosphorus center found in most chemical warfare agents. Site-direct mutagenesis has systematically improved the active site of the enzyme. These efforts have resulted in the improvement of catalytic activity and have led to the identification of variants that are more effective at detoxifying both G-type and V-type nerve agents. -
Environmental Health Criteria 63 ORGANOPHOSPHORUS
Environmental Health Criteria 63 ORGANOPHOSPHORUS INSECTICIDES: A GENERAL INTRODUCTION Please note that the layout and pagination of this web version are not identical with the printed version. Organophophorus insecticides: a general introduction (EHC 63, 1986) INTERNATIONAL PROGRAMME ON CHEMICAL SAFETY ENVIRONMENTAL HEALTH CRITERIA 63 ORGANOPHOSPHORUS INSECTICIDES: A GENERAL INTRODUCTION This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization World Health Orgnization Geneva, 1986 The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of manpower in the field of toxicology. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, coordination -
Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 Theinternational Programme on Chemical Safety (IPCS) Was Established in 1980
The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 cation Hazard of Pesticides by and Guidelines to Classi The WHO Recommended Classi The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 TheInternational Programme on Chemical Safety (IPCS) was established in 1980. The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management of chemicals. This publication was developed in the IOMC context. The contents do not necessarily reflect the views or stated policies of individual IOMC Participating Organizations. The Inter-Organization Programme for the Sound Management of Chemicals (IOMC) was established in 1995 following recommendations made by the 1992 UN Conference on Environment and Development to strengthen cooperation and increase international coordination in the field of chemical safety. The Participating Organizations are: FAO, ILO, UNDP, UNEP, UNIDO, UNITAR, WHO, World Bank and OECD. The purpose of the IOMC is to promote coordination of the policies and activities pursued by the Participating Organizations, jointly or separately, to achieve the sound management of chemicals in relation to human health and the environment. WHO recommended classification of pesticides by hazard and guidelines to classification, 2019 edition ISBN 978-92-4-000566-2 (electronic version) ISBN 978-92-4-000567-9 (print version) ISSN 1684-1042 © World Health Organization 2020 Some rights reserved. -
Opis Patentowy 130618 Rzeczpospolita Lodowa
POLSKA OPIS PATENTOWY 130618 RZECZPOSPOLITA LODOWA Patent dodatkowy do patentu nr — Zgłoszono: 82 06 25 (P. 237 107) Int. Cl8 A01N 57/10 Pierwszeństwof 81 06 27 Republika Federalna Niemiec URZĄD PATENTOWY Zgłoszenie ogłoszono: 83 02 28 PRL Opis patentowy opublikowano: .1987 10 15 Twórcy wynalazku: Miklos Ghyczy, Heinrich Osthoff, Eugen Etschen- berg Uprawniony z patentu: A. Nattermann und Cie GmbH, Kolonia (Republika Federalna Niemiec) Środek owadobójczy Przedmiotem wynalazku jest środek owadobój¬ kach o do 80%, gdy substancję owadobójczą lub czy. Na plantacjach roślin, liczne żyjące i ssące mieszaninę kilku substancji owadobójczych stosuje owady powodują poważne straty produkcyjne, się wespół z pewną substancją dodatkową będącą zwłaszcza w przypadku upraw bawełny, ryżu, zbóż, fosfolipidem. ziemniaków, owoców, warzyw i winorośli. Środek owadobójczy według wynalazku zawiera * Celem zwalczania owadów, podstawową sprawą jedną lub więcej substancji owadobójczych oraz jest obecnie stosowanie chemicznych środków owa¬ znane nośniki, rozcieńczalniki, rozpuszczalniki, pro- dobójczych. Niejednokrotnie konieczne jest stoso¬ pellenty yiub inne obojętne substancje pomocnicze, wanie chemicznych substancji owadobójczych w a cechą tego środka jest to, że zawiera jeden lub znacznych stężeniach, co w rezultacie staje się ło więcej fosfolipidów z grupy obejmującej fosfaty- źródłem toksycznych zanieczyszczeń otoczenia. Nie¬ dylocholinę, fosfatydyloetanoloaminę, N-acylofosfa- znaczna rozpuszczalność niektórych substancji owa¬ tydyloetanoloaminy, fosfatydyloinozyt, fosfatydylo- dobójczych, zwłaszcza w wodzie, powoduje ko¬ serynę, lizolecytynę, fosfatydyloglicerynę i uwodor¬ nieczność użycia toksycznych rozpuszczalników or¬ nione fosfatydylocholiny, przy czym stosunek wa¬ ganicznych. Ponadto większość chemicznych sub¬ 15 gowy substancji czynnej lub substancji czynnych stancji owadobójczych nie zawsze może wykazać do fosfolipidu lub fosfolipidów wynosi od 1 : 0,2 do swoją całkowitą aktywność, ponieważ nie wystar¬ 1 :20. -
Insecticide Resistance in the Sugarcane Borer, Diatraea Saccharalis (F.)
Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1964 Insecticide Resistance in the Sugarcane Borer, Diatraea Saccharalis (F.). Raghunath Prasad Yadav Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Yadav, Raghunath Prasad, "Insecticide Resistance in the Sugarcane Borer, Diatraea Saccharalis (F.)." (1964). LSU Historical Dissertations and Theses. 965. https://digitalcommons.lsu.edu/gradschool_disstheses/965 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. This dissertation has been 64—13,278 microfilmed exactly as received YADAV, Raghunath Prasad, 1935- INSECTICIDE RESISTANCE IN THE SUGARCANE SORER, DIATRAEA SACCHARALIS (F.). Louisiana State University, Ph.D., 1964 Zoology University Microfilms, Inc., Ann Arbor, Michigan INSECTICIDE RESISTANCE IN THE SUGARCANE BORER, DIATRAEA SACCHARALIS (F.) A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy in The Department of Entomology by Raghunath Prasad Yadav M.S., Govt. Agricultural College, Kanpur, 1958 May, 1964 ACKNOWLEDGMENT The writer is sincerely grateful to his major professor, Dr. W. H. Long, for many helpful suggestions and assistance in the preparation of this manuscript. Special thanks are due Dr. L. D. Newsom, Head of the Department of Entomology, for providing the opportunity to study at Louisiana State University. -
Identifying Potential POP and PBT Substances Development of a New Persistence/ Bioaccumulation Score
Identifying potential POP and PBT substances Development of a new Persistence/ Bioaccumulation score Report 601356001/2011 E. Rorije et al. National Insitute for Public Health and the Environment P.O. Box 1 | 3720 BA Bilthoven www.rivm.com Identifying potential POP and PBT substances Development of a new Persistence/Bioaccumulation-score RIVM Report 601356001/2011 Page 1 of 86 RIVM Report 601356001 Colophon © RIVM 2011 Parts of this publication may be reproduced, provided acknowledgement is given to the 'National Institute for Public Health and the Environment', along with the title and year of publication. E. Rorije (first author), SEC E.M.J. Verbruggen, SEC A. Hollander, LER T.P. Traas, SEC M.P.M. Janssen, SEC Contact: Martien Janssen RIVM/SEC [email protected] This investigation has been performed by order and for the account of I&M/RB, within the framework of Mondiaal Stoffenbeleid (M/601356) and REACH strategic support (M/601353) Page 2 of 86 RIVM Report 601356001 Abstract Identifying potential POP and PBT candidates Development of a new Persistence/Bioaccumulation score RIVM has screened the potential for long-term fate in the environment of a large number of substances. For this purpose a new methodology has been developed which indicates whether substances will persist in the environment and/or bioaccumulate in biological organisms. The results are a first step towards selection of substances which have inherent chemical properties that potentially make them a long-term hazard for the environment. Further research into the actual persistence and bioaccumulation of these substances in the environment will be needed. -
NMP-Free Formulations of Neonicotinoids
(19) & (11) EP 2 266 400 A1 (12) EUROPEAN PATENT APPLICATION (43) Date of publication: (51) Int Cl.: 29.12.2010 Bulletin 2010/52 A01N 43/40 (2006.01) A01N 43/86 (2006.01) A01N 47/40 (2006.01) A01N 51/00 (2006.01) (2006.01) (2006.01) (21) Application number: 09305544.0 A01P 7/00 A01N 25/02 (22) Date of filing: 15.06.2009 (84) Designated Contracting States: (72) Inventors: AT BE BG CH CY CZ DE DK EE ES FI FR GB GR • Gasse, Jean-Jacques HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL 27600 Saint-Aubin-Sur-Gaillon (FR) PT RO SE SI SK TR • Duchamp, Guillaume Designated Extension States: 92230 Gennevilliers (FR) AL BA RS • Cantero, Maria 92230 Gennevilliers (FR) (71) Applicant: NUFARM 92233 Gennevelliers (FR) (74) Representative: Cabinet Plasseraud 52, rue de la Victoire 75440 Paris Cedex 09 (FR) (54) NMP-free formulations of neonicotinoids (57) The invention relates to NMP-free liquid formulation comprising at least one nicotinoid and at least one aprotic polar component selected from the group comprising the compounds of formula I, II or III below, and mixtures thereof, wherein R1 and R2 independently represent H or an alkyl group having less than 5 carbons, preferably a methyl group, and n represents an integer ranging from 0 to 5, and to their applications. EP 2 266 400 A1 Printed by Jouve, 75001 PARIS (FR) EP 2 266 400 A1 Description Technical Field of the invention 5 [0001] The invention relates to novel liquid formulations of neonicotinoids and to their use for treating plants, for protecting plants from pests and/or for controlling pests infestation.