Optically Designed Anodised Aluminium Surfaces: Microstructural and Electrochemical Aspects

Total Page:16

File Type:pdf, Size:1020Kb

Optically Designed Anodised Aluminium Surfaces: Microstructural and Electrochemical Aspects Downloaded from orbit.dtu.dk on: Dec 18, 2017 Optically Designed Anodised Aluminium Surfaces: Microstructural and Electrochemical Aspects Gudla, Visweswara Chakravarthy; Ambat, Rajan Publication date: 2015 Document Version Publisher's PDF, also known as Version of record Link back to DTU Orbit Citation (APA): Gudla, V. C., & Ambat, R. (2015). Optically Designed Anodised Aluminium Surfaces: Microstructural and Electrochemical Aspects. Kgs. Lyngby: Technical University of Denmark (DTU). General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. Optically Designed Anodised Aluminium Surfaces Microstructural and Electrochemical Aspects PhD Thesis Visweswara Chakravarthy Gudla July 2015 Optically Designed Anodised Aluminium Surfaces: Microstructural and Electrochemical Aspects Visweswara Chakravarthy Gudla E-mail: [email protected] E-mail: [email protected], [email protected] Prof. Rajan Ambat E-mail: [email protected] Department of Mechanical Engineering, Materials and Surface Technology Technical University of Denmark Produktionstorvet, Building 425 2800 Kgs. Lyngby, Denmark Copyright: Reproduction of this publication in whole or in part must include the customary bibliographic citation, including author attribution, Optically Designed Anodised Aluminium Surfaces: Microstructural and Electrochemical Aspects, V. C. Gudla, 2015. Cover Image: Bright field transmission electron micrograph of anodised layer on Aluminium-TiO2 composite and the proposed light interaction mechanism with the anodic layer. Published by: Department of Mechanical Engineering, Section for Materials and Surface Engineering, Produktionstorvet, Building 425, 2800 Kgs. Lyngby, Denmark ii iii This thesis is submitted in partial fulfilment of the requirements for obtaining the degree of Ph.D. in Mechanical Engineering at Technical University of Denmark (DTU). The Ph.D. project was funded by the Danish National Advanced Technology Foundation (HTF, Højteknologi-fonden) through the project ‘Optically Designed Anodised Aluminium Surfaces (ODAAS)’. It was carried out at the Department of Mechanical Engineering, Section of Materials and Surface Engineering (MTU) in DTU during the period 1st April, 2012 – 14th July, 2015 under the supervision of Professor Dr. Rajan Ambat. Visweswara Chakravarthy Gudla Kongens Lyngby, 15th July 2015 iv This thesis presents the research work aimed at generating anodised aluminium surfaces with bright, white, and glossy decorative appearance. The aluminium surface finishing industry has been on the lookout for such surfaces due to their potential applications in aerospace, architecture, and design industry. Conventional colouring techniques applied to anodised aluminium surfaces cannot generate glossy white appearing surfaces due to the fundamental differences in the interaction with visible light that is required. Surfaces appearing as perfect white are due to the scattering of visible light providing high level of diffused reflection, which is similar to a mirror, but without the specular reflection component. Therefore the nature of the white surface should provide high scattering of light without significant absorption. Achieving white anodised surfaces using conventional dyeing techniques is not possible as the anodic pore sizes are an order of magnitude smaller than the traditional white pigments. The approaches presented in this thesis focus on different techniques like modification of the aluminium microstructure, engineering of the aluminium surface, and application on non-conventional anodising processes. The idea behind the mentioned approaches is to enhance the scattering of visible light from the anodised aluminium surface and aluminium substrate interface for achieving high reflectance. Magnetron sputtered coatings were employed to modify the Aluminium surface and tailor the microstructure in order to impart light scattering ability to the anodised layer. Coatings based on Al-Zr and Al- Ti binary system were studied for their anodising behaviour with and without heat treatment. The structure evolution of the Al-Zr sputtered coatings and the effect of Si during heat treatment was studied in-situ in a transmission electron microscope and also ex-situ using grazing incidence X-ray diffraction. The Al-Metal oxide surface composites based on TiO2, Y2O3, and CeO2 prepared by friction stir processing were employed to generate light scattering anodised surfaces by embedding oxide particles. Theoretical modelling and physical modelling of the anodised layer with TiO2 particles were simulated using Polyurthenane-TiO2 coatings and investigating the optical appearance. The conventional DC anodising and high frequency pulse and pulse reverse pulse anodising were employed to generate bright-anodised surfaces. Effect of pulse frequency, anodic and cathodic cycle potential values was systematically investigated. Characterization of surfaces and substrates was performed using Scanning and Transmission Electron Microscopy, Grazing-Incidence X-ray Diffraction, Glow Discharge Optical Emission Spectroscopy, and Scanning Kelvin Probe Force Microscopy. Optical characterization was performed using integrating sphere measurements. Combining the results and understanding obtained from anodising of magnetron sputtered coatings, Al-TiO2 surface composites and their electrochemical behaviour under high frequency anodising, highly reflecting, bright and glossy white anodised aluminium surfaces were generated for the first time. Further, these white anodised surfaces were conventionally dyed to generate new appearances based on pastel colours. The work presented in this thesis is mainly divided into two parts. The first part is based on magnetron sputter deposition, their heat treatment, characterization, and anodising behaviour (Chapter 5-8, 14). The second part of the thesis is based on Al-TiO2 composites, their preparation characterization, and anodising behaviour (Chapter 9-13). The outcome of the work is presented in the last chapter (Chapter 15). The results from white anodising of the Al surfaces, which is the primary goal of this thesis and also the generation of a new set of pastel coloured anodised surfaces is presented. The optical characterization of these white anodised surfaces along with other reference white surfaces is presented and discussed. v Denne ph.d. afhandling beskriver resultater og overvejelser fra et forskningsarbejde, der har haft til formål at udvikle anodiserede aluminiumsoverflader, der fremstår med en blank og dekorativ hvid farve. Sådanne overflader har store potentielle anvendelser inden for f.eks. transport-, fly- og rumfarts-, bygnings- og designindustrierne og har i lang tid været efterspurgt i brancherne. Konventionelle teknikker til at farve anodiseret aluminium kan ikke fremstille skinnende hvide overflader, idet den fysiske størrelse af porerne i det anodiserede lag ikke er store nok til at rumme pigment med hvid farve. En overflade fremstår perfekt hvid, hvis den spreder alt indkommende lys i det synlige spektrum, uden at der absorberes noget lys i materialet. Derfor er det et krav til overfladens optiske egenskaber, at al synligt lys spredes uden signifikant absorption. I dette projekt er anvendt forskellige teknikker til at skræddersy aluminiumsoverfladen, f.eks. ved at ændre mikrostrukturen af og ved anvendelse af alternative anodiserings processer. Formålet med dette var at øge spredningen af synligt lys i det anodiserede lag og i grænselaget mellem basismaterialet og det anodiserede lag. Belægninger fremstillet ved magnetronforstøvning blev optimeret, så lys vil spredes effektivt ved en efterfølgende anodisering. Egenskaberne ved anodisering af belægninger baseret på Al-Zr og Al-Ti binære systemer blev undersøgt, både med og uden efterfølgende varmebehandling. Udviklingen af mikrostrukturen af Al-Zr belagte overflader samt effekten af Si i grundmaterialet blev undersøgt in-situ ved transmission elektron mikroskopi og ex-situ ved røntgen spektroskopi. Overflader af Al-metaloxid kompositter, baseret på TiO2, Y2O3, og CeO2, blev fremstillet ved friction stir processer og er anvendt til at skabe anodiserede overflader med integrerede partikler af metaloxider, der effektivt spreder synligt lys. De optiske egenskaber af anodiseret Al med inkorporerede TiO2 partikler er modelleret ud fra teoretiske beregninger, og eftervist med fysiske modeller med Polyuretan-TiO2. Konventionel DC anodisering samt anodisering med højfrekvente puls mønstre er anvendt til at fremstille lyse, anodiserede overflader. Effekten af puls frekvensen og potentialerne af de anodiske og katodiske pulser, er undersøgt systematisk. De frembragte overflader og substrater er karakteriseret med scanningselektronmikroskopi (SEM), transmissionselektronmikroskopi (TEM), røntgendiffraktion (XRD), optisk emission spektroskopi (GDOES),
Recommended publications
  • The Processing and Characterisation of Recycled Ndfeb Based Magnets
    The Processing and Characterisation of Recycled NdFeB based Magnets By Salahadin Muhammed Ali Adrwish A thesis submitted to the University of Birmingham for the degree of Doctor of Philosphy Supervisors Prof. I.R. Harris Dr. A.J. Williams School of Metallurgy and materials University of Birmingham B15 2TT University of Birmingham Research Archive e-theses repository This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder. CONTENTS Acknowledgement List of abbreviations Synopsis Chapter One 1.0 Aims of the Project 1 Chapter Two 2.0 Commercial use of NdFeB magnets 5 2.1 Development of NdFeB-type magnets 5 2. 2 Global NdFeB market 6 2.3 Major NdFeB producers 8 2.4 Applications 12 2.5 Factors affecting NdFeB supply and demand 14 2.5.1 IT sector 14 2.5.2 Global price of Dy and Nd 16 2.5.3 Environmental considerations 18 Chapter Three 3.0 Detailed aspects of NdFeB-type magnets recycling 22 3.1 Introduction 22 3.2 Introduction 22 3.3 Processing of recycled NdFeB over the years 25 3.3.1 Recycling of NdFeB magnets 26 3.3.2 Recycling of machine (internal) waste (sludge) 27
    [Show full text]
  • Aluminium Level 2 2019 CES Edupack
    Level 2 Age-hardening wrought Al-alloys The 2000 and 7000 series age -hardening aluminum alloys are the backbone of the aerospace industry. The 6000 series has lower strength but is more easily extruded: it is used for marine and ground transport systems. THE MATERIAL The high -strength aluminum alloys rely on age -hardening: a sequence of heat treatment steps that causes the precipitation of a nano-scale dispersion of intermetallics that impede dislocation motion and impart strength. This can be as high as 700 MPa giving them a strength-to-weight ratio exceeding even that of the strongest steels. This record describes for the series of wrought Al alloys that rely on age-hardening requiring a solution heat treatment followed by quenching and ageing. This is recorded by adding TX to the series number, where X is a number between 0 and 8 that records the state of heat treatment. They are listed below using the IADS designations (see Technical notes for details).2000 series: Al with 2 to 6% Cu -- the oldest and most widely used aerospace series.6000 series: Al with up to 1.2% Mg and 1.3% Si -- medium strength extrusions and forgings.7000 series: Al with up to 8% Zn and 3% Mg -- the Hercules of aluminum alloys, used for high strength aircraft structures, forgings and sheet. Certain special alloys also contain silver. So this record, like that for the non-age hardening alloys, is broad, encompassing all of these. COMPOSITION 2000 series: Al + 2 to 6% Cu + Fe, Mn, Zn and sometimes Zr 6000 series: Al + up to 1.2%Mg + 0.25% Zn + Si, Fe a nd Mn 7000 series: Al + 4 to 9 % Zn + 1 to 3% Mg + Si, Fe, Cu and occasionally Zr and Ag GENERAL PROPERTIES Density 2500 - 2900 kg/m^3 Price *1.
    [Show full text]
  • Machining of Aluminum and Aluminum Alloys / 763
    ASM Handbook, Volume 16: Machining Copyright © 1989 ASM International® ASM Handbook Committee, p 761-804 All rights reserved. DOI: 10.1361/asmhba0002184 www.asminternational.org MachJning of Aluminum and AlumJnum Alloys ALUMINUM ALLOYS can be ma- -r.. _ . lul Tools with small rake angles can normally chined rapidly and economically. Because be used with little danger of burring the part ," ,' ,,'7.,','_ ' , '~: £,~ " ~ ! f / "' " of their complex metallurgical structure, or of developing buildup on the cutting their machining characteristics are superior ,, A edges of tools. Alloys having silicon as the to those of pure aluminum. major alloying element require tools with The microconstituents present in alumi- larger rake angles, and they are more eco- num alloys have important effects on ma- nomically machined at lower speeds and chining characteristics. Nonabrasive con- feeds. stituents have a beneficial effect, and ,o IIR Wrought Alloys. Most wrought alumi- insoluble abrasive constituents exert a det- num alloys have excellent machining char- rimental effect on tool life and surface qual- acteristics; several are well suited to multi- ity. Constituents that are insoluble but soft B pie-operation machining. A thorough and nonabrasive are beneficial because they e,,{' , understanding of tool designs and machin- assist in chip breakage; such constituents s,~ ,.t ing practices is essential for full utilization are purposely added in formulating high- of the free-machining qualities of aluminum strength free-cutting alloys for processing in alloys. high-speed automatic bar and chucking ma- Strain-hardenable alloys (including chines. " ~ ~p /"~ commercially pure aluminum) contain no In general, the softer ailoys~and, to a alloying elements that would render them lesser extent, some of the harder al- c • o c hardenable by solution heat treatment and ,p loys--are likely to form a built-up edge on precipitation, but they can be strengthened the cutting lip of the tool.
    [Show full text]
  • Aluminum Alloy Weldability: Identification of Weld Solidification Cracking Mechanisms Through Novel Experimental Technique and Model Development
    Dipl.-Ing. Nicolas Coniglio Aluminum Alloy Weldability: Identifi cation of Weld Solidifi cation Cracking Mechanisms through Novel Experimental Technique and Model Development BAM-Dissertationsreihe • Band 40 Berlin 2008 Die vorliegende Arbeit entstand an der BAM Bundesanstalt für Materialforschung und -prüfung. Impressum Aluminum Alloy Weldability: Identifi cation of Weld Solidifi cation Cracking Mechanisms through Novel Experimental Technique and Model Development 2008 Herausgeber: BAM Bundesanstalt für Materialforschung und -prüfung Unter den Eichen 87 12205 Berlin Telefon: +49 30 8104-0 Telefax: +49 30 8112029 E-Mail: [email protected] Internet: www.bam.de Copyright © 2008 by BAM Bundesanstalt für Materialforschung und -prüfung Layout: BAM-Arbeitsgruppe Z.64 ISSN 1613-4249 ISBN 978-3-9812354-3-2 Aluminum Alloy Weldability: Identification of Weld Solidification Cracking Mechanisms through Novel Experimental Technique and Model Development Dissertation zur Erlangung des akademischen Grades Doktor-Ingenieur (Dr.-Ing.) genehmigt durch die Fakultät für Maschinenbau der Otto-von-Guericke-Universität Madgeburg am 02.06.08 vorgelegte Dissertation von Dipl.-Ing. Nicolas Coniglio Thesis Committee: Prof. Dr.-Ing. A. Bertram Prof. Dr.-Ing. T. Böllinghaus Prof. C.E. Cross Prof. S. Marya Date of Examination: 23 October 2008 Abstract Abstract The objective of the present thesis is to make advancements in understanding solidification crack formation in aluminum welds, by investigating in particular the aluminum 6060/4043 system. Alloy 6060 is typical of a family of Al-Mg-Si extrusion alloys, which are considered weldable only when using an appropriate filler alloy such as 4043 (Al-5Si). The effect of 4043 filler dilution (i.e. weld metal silicon content) on cracking sensitivity and solidification path of Alloy 6060 welds are investigated.
    [Show full text]
  • Mechanical Milling of Co-Rich Melt-Spun Sm-Co Alloys
    University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln Mechanical & Materials Engineering, Engineering Mechanics Dissertations & Theses Department of Spring 5-2010 MECHANICAL MILLING OF CO-RICH MELT-SPUN SM-CO ALLOYS Farhad Reza Golkar-Fard University of Nebraska - Lincoln, [email protected] Follow this and additional works at: https://digitalcommons.unl.edu/engmechdiss Part of the Engineering Mechanics Commons, and the Mechanical Engineering Commons Golkar-Fard, Farhad Reza, "MECHANICAL MILLING OF CO-RICH MELT-SPUN SM-CO ALLOYS" (2010). Engineering Mechanics Dissertations & Theses. 6. https://digitalcommons.unl.edu/engmechdiss/6 This Article is brought to you for free and open access by the Mechanical & Materials Engineering, Department of at DigitalCommons@University of Nebraska - Lincoln. It has been accepted for inclusion in Engineering Mechanics Dissertations & Theses by an authorized administrator of DigitalCommons@University of Nebraska - Lincoln. MECHANICAL MILLING OF CO-RICH MELT-SPUN SM-CO ALLOYS by FARHAD REZA GOLKAR-FARD A THESIS Presented to the Faculty of The Graduate College at the University of Nebraska In Partial Fulfillment of Requirements For the Degree of Master Science Major: Engineering Mechanics Under the Supervision of Professor Jeffrey E. Shield Lincoln, Nebraska May, 2010 MECHANICAL MILLING OF CO-RICH MELT-SPUN SM-CO ALLOYS Farhad Reza Golkar-Fard, M.S UNIVERSITY OF NEBRASKA, 2010 Advisor: Jeffrey E. Shield Rare-earth, high-energy permanent magnets are currently the best performing permanent magnets used today. The discovery of single domain magnetism in 1950’s ultimately led to the development of nanocomposite magnets which had superior magnetic properties. Previous work has shown that mechanical milling (MM) effectively generates nanoscale structures in Sm-Co-based alloys.
    [Show full text]
  • Conversion Coatings for Aluminium Alloys: a Surface Investigation for Corrosion Mechanisms
    Conversion coatings for aluminium alloys: a surface investigation for corrosion mechanisms. by Rossana Grilli Submitted for the Degree of Doctor of Philosophy March 2010 The Surface Analysis Laboratory Surrey Materials Institute and Faculty of Engineering & Physical Sciences University of Surrey Guildford Surrey GU2 7XH UK Abstract Abstract Cr(VI) based conversion coatings are currently the treatments of choice for aluminium alloys to prevent corrosion, and are widely used in the aerospace industry also because of their good electrical conductivity and because they are good primers for paints and adhesives. Hexavalent chromium though is harmful for humans and for the environment, thus it needs to be replaced with more environmentally friendly materials. In this work three alternative pre-treatments for aluminium alloys were proposed and their properties were investigated and compared with the performance of a Cr(VI) based treatment. The selected “green” alternatives are based on titanium and zirconium compounds and they were applied to three different aluminium alloys relevant for spacecraft applications: Al2219, Al7075 and Al5083. After the characterization of the chosen materials by means of SEM, AES, XPS, EDX and SAM, some of their surface properties were explored: the adsorption of an epoxy acrylate resin used for UV-cured coatings, and the stability under UV and thermal exposure. The outcome of this preliminary investigation provided the basis for a further selection of materials to use in a corrosion study, and Al2219 was chosen as a substrate, together with an hybrid (organic/inorganic) coating, Nabutan STI/310. Alodine 1200S was proposed as chromate treatment and used as reference. A comparison of the behaviour during the exposure to a corrosive environment, as a NaCl solution, was made between the untreated Al2219 alloy, and the alloy treated with Nabutan STI/310 and Alodine 1200S.
    [Show full text]
  • Microstructure and Mechanical Properties of the Annealed 6060 Aluminium Alloy Processed by ECAP Method
    Volume 80 International Scientific Journal Issue 1 published monthly by the July 2016 World Academy of Materials Pages 31-36 and Manufacturing Engineering Microstructure and mechanical properties of the annealed 6060 aluminium alloy processed by ECAP method M. Karoń *, A. Kopyść, M. Adamiak, J. Konieczny Faculty of Mechanical Engineering, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland * Corresponding e-mail address: [email protected] ABSTRACT Purpose: The main goal of this paper is to present the investigation results of microstructural evolution and mechanical properties changes in commercial EN AW 6060) aluminium alloy after intensive plastic deformation, obtained by equal channel angular pressing (ECAP) techniques in an annealed state. Design/methodology/approach: Annealing heat treatment was used to remove various types of internal stress in a commercially available alloy in order to increase workability of the material. The evolution of its properties and material behaviour was evaluated after 2,4,6,and 8 passes of the ECAP process. Findings: It was found that the mechanical properties and microstructure during intensive plastic deformation, such as that during the ECAP process, were changed. Plastic deformation refined grains in the aluminium alloy and increased its mechanical properties. Research limitations/implications: The presented study shows results of the investigated material in an annealed state. Practical implications: The applied processing route allows development of materials characterized by high strength and ultrafine grain microstructure compared to un-deformed annealed aluminium alloy. Originality/value: The work presents data about the influence of intensive plastic deformation on the microstructure and mechanical properties of 6060 aluminium alloy after annealing.
    [Show full text]
  • Long-Term Pitting Corrosion of 6060 Aluminium Alloy Immersed in Natural Seawater
    LONG-TERM PITTING CORROSION OF 6060 ALUMINIUM ALLOY IMMERSED IN NATURAL SEAWATER M. X. Liang, I. A. Chaves, R. E. Melchers Centre for Infrastructure Performance and Reliability, The University of Newcastle, NSW2308, Australia SUMMARY: Aluminium alloys are widely used in maritime industries because of their high strength to weight ratio, ease of fabrication and expected corrosion resistance. However, they are susceptible to localised corrosion under specific corrosive environment. Further, information on the long-term corrosion characteristics of aluminium alloys under natural seawater immersed condition is scarce. Hence, this study reports a field investigation on pitting corrosion data of 6060 aluminium alloy immersed for two years in natural seawater with average annual temperature of 20oC. An Optical Microscope was used to examine pit morphology and to measure pit depths. Cross-section microstructure and chemical composition of pits were investigated by means of Scanning Electron Microscopy and Energy Dispersive Spectrometry. Five deepest pits were measured on each face of a sextuplicate set of coupons. The pit depth data was analysed using extreme value statistics. Results show that the depth of the deepest pits progressed in a ‘step-wise’ manner. Pitting severity and the maximum pit depth increased with the depth of immersion. The results support previous findings indicating changes in corrosion mechanism with time. Similar to the corrosion of steels, this is considered to result from the build-up of corrosion products. The reason for this is discussed and further work is outlined. Keywords: Aluminium alloys; pitting corrosion; seawater immersion; microstructure. 1. INTRODUCTION Aluminium alloys are widely used in various fields such as marine infrastructures and aerospace due to their high strength to weight ratio and good corrosion resistance (Perryman 2007, Srinivasa Rao 2004).
    [Show full text]
  • 2000 TMS Annual Meeting Program
    TECHNICAL PROGRAM 12 9 thTMS ANNUAL MEETING & The 129th TMS Annual Meeting & Exhibition EXHIBITION Opryland Convention Center ❈ ❈ ❈ Nashville, Tennessee USA ❈ ❈ ❈ March 12 - March 16, 2000 MONDAY AM the cost of these increasingly complex materials. This paper will re- AIME/TMS KEYNOTE ADDRESS view some of the work currently being undertaken both at engine "FutureView...A Look Ahead" manufacturers, and at component suppliers in consortia such as the AM MONDAY Daniel Burrus Engine Supplier Base Initiatives and the Metals Affordability Initia- 11:30am-1:00pm tive. The creation of such consortia to reduce component cost has Convention Center, Presidential Ballroom made significant progress possible in focusing the entire supply chain ✦✦✦ and the customer on this critical issue of affordability Tutorial Luncheon Lecture 8:55 AM Invited "Advanced Rechargeable Batteries: A Materials Science Perspective" Application of Lean Concepts to the Aerospace Forging Value Donald R. Sadoway Stream: Dan Krueger1; Rod Boyer2; David Furrer3; Mary Lee 12:00noon-1:30pm Gambone4; Beth Lewis5; 1GE Aircraft Engines, One Neumann Way, Convention Center, Lincoln C MD H85, Cincinnati, OH 45215 USA; 2Boeing Company, Commercial ✦✦✦ Airplanes Grp., Seattle, WA 98124 USA; 3Ladish Company, Inc., 5481 AIME & TMS Banquet & Awards Presentation S. Packard Ave., Cudahy, WI 53110 USA; 4Rolls-Royce Allison, P.O. 6:00pm Reception Box 420, Indianapolis, IN 46206-0420 USA; 5Wyman Gordon Com- 7:00pm Dinner pany, 244 Worcester St., Grafton, MA 01563 USA Convention Center, Presidential Ballroom Forged components comprise approximately one-third the cost of a propulsion system, and are major cost drivers for airframe systems. +Indicates Student Traditionally, cost reduction efforts have focused on improving indi- vidual operations or steps in the value stream.
    [Show full text]
  • Properties of Solids
    PROPERTIES OF SOLIDS (Function values at 288 K. Note: there is little variation in the thermal capacity of metals, even when molten) Substance Note Melting Boiling Melting Boiling Density Thermal Sound Thermal Thermal Solar Emissivity temp. temp. enthalpy enthalpy (mass) expansion speed(**) capacity conductivity absorptance (hemispherical, (linear*) (normal) bolometric) α 6 c α ε Tf Tb hsl hlv ρ .10 c k 3 -1 K K kJ/kg kJ/kg kg/m K m/s J/(kg K) W/(m K) - - 1) Alumina 1 2300 3200 1070 3980 7 5600 840 33 0.1..0.25 0.3..0.5 2) Aluminium 2 933 2790 395 10 700 2710 24 5500 896 220 0.1..0.15 0.05 3) 2) Aluminium alloy A7075 3 750 2810 23.4 6300 960 134 0.1..0.15 0.05 Asbestos 4 1420 2400 1050 0.15 0.95 5) Asphalt 5 400 2000 200 920 0.7 0.9 0.9 Ash 6 640 800 0.07 7) Bakelite 7 430 1400 40 1000 1 0.9 0.94 Beryllium 8 1580 2740 900 33 000 1850 11 12800 1850 190 0.5..0.7 0.18 Brass 9 1200 8780 20 4600 400 150 0.03..0.25 Brick 10 1970 10 3600 800 0.7 0.6 0.9 Bronze 11 1300 8800 18 400 50..80 12) 12) Carbon fibre composite 12 400 1500 2 1100 20 0.85 0.85 Cement mortar 13 3000 20 670 0.3 0.6 0.9 Charcoal 14 240 840 0.05 0.95 0.95 Clay & pottery 15 1000 920 1.3 0.4 0.95 Coal 16 3910 1400 1000 0.17 0.95 0.80..0.95 Concrete 17 2100..3000 8..14 4300 653 1.5 0.6 0.8 Copper 18 1358 2830 205 4800 8910 17 3800 390 395 0.2..0.5 0.05 Cork 19 100 2000 0.05 0.7 20) 20) Diamond 20 4700 4100 3510 0.8 12000 500 2000 0.02 21) Elastomer (rubber) 21 400 1100 200..300 1600 2000 0.1 0.9 0.9 Glass (optical) 22 4000 6 500 1.4 Glass (pyrex) 23 2230 3 5600 840 1.1 0.9 Glass
    [Show full text]
  • Coniglio Thesis
    Dipl.-Ing. Nicolas Coniglio Aluminum Alloy Weldability: Identifi cation of Weld Solidifi cation Cracking Mechanisms through Novel Experimental Technique and Model Development BAM-Dissertationsreihe • Band 40 Berlin 2008 Die vorliegende Arbeit entstand an der BAM Bundesanstalt für Materialforschung und -prüfung. Impressum Aluminum Alloy Weldability: Identifi cation of Weld Solidifi cation Cracking Mechanisms through Novel Experimental Technique and Model Development 2008 Herausgeber: BAM Bundesanstalt für Materialforschung und -prüfung Unter den Eichen 87 12205 Berlin Telefon: +49 30 8104-0 Telefax: +49 30 8112029 E-Mail: [email protected] Internet: www.bam.de Copyright © 2008 by BAM Bundesanstalt für Materialforschung und -prüfung Layout: BAM-Arbeitsgruppe Z.64 ISSN 1613-4249 ISBN 978-3-9812354-3-2 Aluminum Alloy Weldability: Identification of Weld Solidification Cracking Mechanisms through Novel Experimental Technique and Model Development Dissertation zur Erlangung des akademischen Grades Doktor-Ingenieur (Dr.-Ing.) genehmigt durch die Fakultät für Maschinenbau der Otto-von-Guericke-Universität Madgeburg am 02.06.08 vorgelegte Dissertation von Dipl.-Ing. Nicolas Coniglio Thesis Committee: Prof. Dr.-Ing. A. Bertram Prof. Dr.-Ing. T. Böllinghaus Prof. C.E. Cross Prof. S. Marya Date of Examination: 23 October 2008 Abstract Abstract The objective of the present thesis is to make advancements in understanding solidification crack formation in aluminum welds, by investigating in particular the aluminum 6060/4043 system. Alloy 6060 is typical of a family of Al-Mg-Si extrusion alloys, which are considered weldable only when using an appropriate filler alloy such as 4043 (Al-5Si). The effect of 4043 filler dilution (i.e. weld metal silicon content) on cracking sensitivity and solidification path of Alloy 6060 welds are investigated.
    [Show full text]
  • Welding Journal {\SSH 0043-2296) Is Published R
    w •' VII PUBLISHED BY THE AMERICAN WELDING SOCIETY TO ADVANCE THE SCIENCE, TECHNOLOGY, AND APPLICATION OF WELDING AND ALLIED JOINING AND CUTTING PROCESSES, INCLUDING BRAZING, SOLDERING, AND THERMAL SPRAYING One Word Select-Arc's New (Line and Reputati U-Si Qii^lily.r. 1 fk % Select-Arc, Inc. has earned teristics, consistent deposit electrodes' higher deposi- Discover for yourself the an outstanding reputation chemistry and excellent tion rates improve produc- many benefits of specifying in the industry as a manu- overall performance you tivity and reduce welding Select-Arc's new premium facturer of premium quality have come to expect from costs. stainless steel electrodes. Call tubular welding electrodes Select-Arc. us today at 1-800-341-3213 for carbon and low alloy SelectAlloy's smooth bead or you can visit our website steel welding. The chart below shows contour, easy peeling slag, at www.select-arc.com for that SelectAUoy flux cored minimal spatter, closely more information. Now Select-Arc has controlled weld deposit expanded its range of Typical Deposition Rates for compositions and metal exceptional products Various Stainless Steel Consumables soundness deliver addi- with the introduction tional savings. SELECT of a complete line of .0 45" Fll xCor .045" vletal ( lored Elect rode E ectrod The Select 400-Series austenitic, martensitic // metal cored electrodes and ferritic stainless / V sS r offer the same advan- steel electrodes. Both f s 600 Enterprise Drive the new SelectAUoy So 45" So IdWir e tages as SelectAUoy and ^ * Elect ode P.O. Box 259 and Select stainless are ideally suited for Fort Loramie,OH 45845-0259 steel wires deliver the difficult-to-weld appli- .
    [Show full text]