5/20/2020 dioxide - Wikipedia

Carbon dioxide

Carbon dioxide ( CO2) is a colorless gas with Carbon dioxide a density about 60% higher than that of dry air. Carbon dioxide consists of a carbon covalently double bonded to two . It occurs naturally in Earth's atmosphere as a trace gas. The current concentration is about 0.04% (412 ppm) by volume, having risen from pre-industrial levels of 280 ppm.[8] Natural sources include volcanoes, hot springs and geysers, and it is freed from rocks by dissolution in water and acids. Because carbon dioxide is soluble in water, it occurs naturally in groundwater, rivers and lakes, ice caps, glaciers and seawater. It is present in deposits of petroleum and natural gas. Carbon dioxide is odorless at normally encountered concentrations, but at high concentrations, it has a sharp and acidic odor.[1] At such Names concentrations it generates the taste of soda water in the Other names [9] mouth. gas

As the source of available carbon in the carbon cycle, atmospheric Carbonic anhydride carbon dioxide is the primary carbon source for life on Earth and Carbonic its concentration in Earth's pre-industrial atmosphere since late Carbon oxide in the Precambrian has been regulated by photosynthetic organisms and geological phenomena. Plants, algae and Carbon(IV) oxide cyanobacteria use light energy to photosynthesize carbohydrate (solid phase) from carbon dioxide and water, with oxygen produced as a waste Identifiers product.[10] CAS Number 124-38-9 (http://ww w.commonchemistr CO2 is produced by all aerobic organisms when they metabolize carbohydrates and lipids to produce energy by respiration.[11] It is y.org/ChemicalDeta returned to water via the gills of fish and to the air via the lungs of il.aspx?ref=124-38- air-breathing land animals, including humans. Carbon dioxide is 9) produced during the processes of decay of organic materials and the fermentation of sugars in bread, beer and wine making. It is 3D model (JSmol) Interactive image (h produced by combustion of wood and other organic materials ttps://chemapps.sto and fossil fuels such as coal, peat, petroleum and natural gas. It is laf.edu/jmol/jmol.ph an unwanted byproduct in many large scale oxidation processes, p?model=O%3D for example, in the production of (over 5 million C%3DO) tons/year).[12][13][14] Interactive image (h It is a versatile industrial material, used, for example, as an inert ttps://chemapps.sto gas in welding and fire extinguishers, as a pressurizing gas in air laf.edu/jmol/jmol.ph guns and oil recovery, as a chemical feedstock and as a p?model=C%28%3 supercritical fluid in decaffeination of coffee and DO%29%3DO) supercritical drying.[15] It is added to drinking water and 3DMet B01131 (http://www. carbonated beverages including beer and sparkling wine to add 3dmet.dna.affrc.go.j https://en.wikipedia.org/wiki/Carbon_dioxide 1/32 5/20/2020 Carbon dioxide - Wikipedia p/cgi/show_data.ph effervescence. The frozen solid form of CO2, known as dry ice is used as a refrigerant and as an abrasive in dry-ice blasting. It is a p?acc=B01131) [16][17][18][19] feedstock for the synthesis of fuels and chemicals. Beilstein 1900390 Reference Carbon dioxide is the most significant long-lived greenhouse gas in Earth's atmosphere. Since the Industrial Revolution ChEBI CHEBI:16526 (http anthropogenic emissions – primarily from use of fossil fuels and s://www.ebi.ac.uk/c deforestation – have rapidly increased its concentration in the hebi/searchId.do?c atmosphere, leading to global warming. Carbon dioxide also hebiId=16526) causes ocean acidification because it dissolves in water to form ChEMBL ChEMBL1231871 carbonic acid.[20] (https://www.ebi.ac. uk/chembldb/index. php/compound/insp Contents ect/ChEMBL12318

Background 71) Chemical and physical properties ChemSpider 274 (http://www.che Structure and bonding mspider.com/Chemi In aqueous solution cal-Structure.274.ht ml) Chemical reactions of CO2 Physical properties ECHA InfoCard 100.004.271 (http Isolation and production s://echa.europa.eu/ substance-informati Applications on/-/substanceinfo/ Precursor to chemicals 100.004.271) Foods Beverages EC Number 204-696-9 Winemaking E number E290 Stunning animals (preservatives) Inert gas Gmelin Reference 989 Fire extinguisher KEGG D00004 (https://ww Supercritical CO as solvent 2 w.kegg.jp/entry/D00 Agriculture 004) Medical and pharmacological uses MeSH Carbon+dioxide (htt Energy ps://www.nlm.nih.g Fossil fuel recovery ov/cgi/mesh/2014/ Bio transformation into fuel MB_cgi?mode=&ter Refrigerant m=Carbon+dioxide) Minor uses PubChem CID 280 (https://pubche In Earth's atmosphere m.ncbi.nlm.nih.gov/ In the oceans compound/280)

Biological role RTECS number FF6400000 Photosynthesis and carbon fixation Toxicity UNII 142M471B3J (http Below 1% s://fdasis.nlm.nih.go Ventilation v/srs/srsdirect.jsp?r https://en.wikipedia.org/wiki/Carbon_dioxide 2/32 5/20/2020 Carbon dioxide - Wikipedia Human physiology egno=142M471B3 Content J) Transport in the blood UN number 1013 (gas), 1845 Regulation of respiration (solid) See also CompTox DTXSID4027028 (h Dashboard (EPA) References ttps://comptox.epa. Further reading gov/dashboard/DT XSID4027028) External links InChI SMILES Background Properties

Carbon dioxide was the first gas to Chemical formula CO2 be described as a discrete substance. 44.009 g·mol−1 In about 1640,[21] the Flemish Appearance Colorless gas chemist Jan Baptist van Helmont observed that when he burned Odor Low charcoal in a closed vessel, the mass concentrations: of the resulting ash was much less none than that of the original charcoal. High His interpretation was that the rest concentrations: Crystal structure of dry ice of the charcoal had been transmuted [1] into an invisible substance he sharp; acidic termed a "gas" or "wild spirit" Density 1562 kg/m3 (solid at [22] (spiritus sylvestris). 1 atm and −78.5 °C) The properties of carbon dioxide were further studied in the 1101 kg/m3 (liquid at 1750s by the Scottish physician Joseph Black. He found that saturation −37 °C) limestone ( carbonate) could be heated or treated with 1.977 kg/m3 (gas at acids to yield a gas he called "fixed air." He observed that the fixed air was denser than air and supported neither flame nor 1 atm and 0 °C) animal life. Black also found that when bubbled through −56.6 °C; −69.8 °F; limewater (a saturated aqueous solution of calcium hydroxide), it 216.6 K ( would precipitate . He used this phenomenon at 5.1 atm) to illustrate that carbon dioxide is produced by animal respiration and microbial fermentation. In 1772, English chemist Critical point (T, 31.1 °C (304.2 K), Joseph Priestley published a paper entitled Impregnating Water P) 7.38 megapascals with Fixed Air in which he described a process of dripping (73.8 bar) (or oil of vitriol as Priestley knew it) on chalk in Sublimation −78.5 °C; order to produce carbon dioxide, and forcing the gas to dissolve conditions −109.2 °F; 194.7 K [23] by agitating a bowl of water in contact with the gas. (1 atm) Carbon dioxide was first liquefied (at elevated pressures) in 1823 in water 1.45 g/L at 25 °C by Humphry Davy and Michael Faraday.[24] The earliest (77 °F), 100 kPa description of solid carbon dioxide (dry ice) was given by the Vapor pressure 5.73 MPa (20 °C) French inventor Adrien-Jean-Pierre Thilorier, who in 1835 opened a pressurized container of , only to Acidity (pKa) 6.35, 10.33 find that the cooling produced by the rapid evaporation of the Magnetic −20.5·10−6 cm3/mol [25][26] susceptibility (χ) liquid yielded a "snow" of solid CO2. https://en.wikipedia.org/wiki/Carbon_dioxide 3/32 5/20/2020 Carbon dioxide - Wikipedia Chemical and physical properties Thermal 0.01662 W·m-1·K-1 conductivity (300 K)[2] Refractive index 1.00045 Structure and bonding (nD) Viscosity 14.90 μPa·s at The carbon dioxide 25 °C[3] is linear and Stretching and bending oscillations centrosymmetric. The 70 μPa·s at of the CO carbon dioxide molecule. 2 carbon–oxygen bond length −78.5 °C Upper left: symmetric stretching. Upper right: antisymmetric is 116.3 pm, noticeably Dipole moment 0 D shorter than the bond length stretching. Lower line: degenerate Structure pair of bending modes. of a C–O single bond and even shorter than most other Crystal structure Trigonal C–O multiply-bonded Molecular shape Linear functional groups.[27] Since it is centrosymmetric, the molecule has no electrical dipole. Consequently, only two vibrational bands Thermochemistry are observed in the IR spectrum – an antisymmetric stretching Heat capacity (C) 37.135 J/K·mol −1 mode at wavenumber 2349 cm and a degenerate pair of Std molar 214 J·mol−1·K−1 bending modes at 667 cm−1 (wavelength 15 μm). There is also a o entropy (S 298) symmetric stretching mode at 1388 cm−1 which is only observed −1 [28] Std enthalpy of −393.5 kJ·mol in the Raman spectrum. formation ⦵ (ΔfH 298) In aqueous solution Pharmacology ATC code V03AN02 (WHO (ht Carbon dioxide is soluble in water, in which it reversibly forms tps://www.whocc.n H CO (carbonic acid), which is a weak acid since its ionization in 2 3 o/atc_ddd_index/?c water is incomplete. ode=V03AN02))

CO2 + H2O ⇌ H2CO3 Hazards Safety data sheet See: data page The hydration equilibrium constant of carbonic acid is Sigma-Aldrich (htt (at 25 °C). Hence, the p://www.sigmaaldric h.com/MSDS/MSD majority of the carbon dioxide is not converted into carbonic S/DisplayMSDSPa acid, but remains as CO2 , not affecting the pH. ge.do?country=PL& language=EN-gene The relative concentrations of CO , H CO , and the deprotonated 2 2 3 ric&productNumber forms HCO− () and CO2−(carbonate) depend on the 3 3 =295108&brand=A pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) LDRICH&PageToG becoming the most prevalent (>95%) at the pH of seawater. In oToURL=http%3A% very alkaline water (pH > 10.4), the predominant (>50%) form is 2F%2Fwww.sigmaa carbonate. The oceans, being mildly alkaline with typical pH = ldrich.com%2Fcatal 8.2–8.5, contain about 120 mg of bicarbonate per liter. og%2Fproduct%2F aldrich%2F29510 Being diprotic, carbonic acid has two acid dissociation constants, 8%3Flang%3Dpl) the first one for the dissociation into the bicarbonate (also called − NFPA 704 [6][7] carbonate) (HCO3 ): (fire diamond) 0 https://en.wikipedia.org/wiki/Carbon_dioxide 4/32 5/20/2020 Carbon dioxide - Wikipedia − + H2CO3 ⇌ HCO3 + H 2 SA 0 −4 [27] Ka1 = 2.5 × 10 mol/L; pKa1 = 3.6 at 25 °C. Lethal dose or concentration (LD, LC): This is the true first acid dissociation constant, defined as LCLo (lowest 90,000 ppm published) (human, 5 min)[5] , where the denominator includes only NIOSH (US health exposure limits): covalently bound H2CO3 and does not include hydrated CO2(aq). PEL TWA 5000 ppm −7 The much smaller and often-quoted value near 4.16 × 10 is an (Permissible) (9000 mg/m3)[4] apparent value calculated on the (incorrect) assumption that all REL TWA 5000 ppm dissolved CO2 is present as carbonic acid, so that (Recommended) (9000 mg/m3), ST . Since most of the 30,000 ppm (54,000 mg/m3)[4] [4] dissolved CO2 remains as CO2 molecules, Ka1(apparent) has a IDLH 40,000 ppm much larger denominator and a much smaller value than the true (Immediate [29] danger) Ka1. Related compounds The bicarbonate ion is an amphoteric species that can act as an Other anions acid or as a base, depending on pH of the solution. At high pH, it 2− Carbon diselenide dissociates significantly into the carbonate ion (CO3 ): Carbon ditelluride HCO − ⇌ CO 2− + H+ 3 3 Other cations dioxide −11 Ka2 = 4.69 × 10 mol/L; pKa2 = 10.329 dioxide In organisms carbonic acid production is catalysed by the dioxide enzyme, carbonic anhydrase. dioxide

Related carbon Chemical reactions of CO2 Carbon Dicarbon monoxide CO2 is a potent electrophile having an electrophilic reactivity that is comparable to benzaldehyde or strong α,β-unsaturated carbonyl compounds. However, unlike electrophiles of similar Related Carbonic acid reactivity, the reactions of nucleophiles with CO2 are compounds thermodynamically less favored and are often found to be highly Carbonyl reversible.[30] Only very strong nucleophiles, like the carbanions Supplementary data page provided by Grignard reagents and organolithium compounds Structure and Refractive index react with CO2 to give carboxylates: properties (n), Dielectric constant MR + CO → RCO M 2 2 (ε ), etc. where M = Li or Mg Br and R = alkyl or aryl. r Thermodynamic Phase behaviour data In metal carbon dioxide complexes, CO2 serves as a ligand, which solid–liquid–gas [31] can facilitate the conversion of CO2 to other chemicals. Spectral data UV, IR, NMR, MS Except where otherwise noted, data are The reduction of CO2 to CO is ordinarily a difficult and slow given for materials in their standard reaction: state (at 25 °C [77 °F], 100 kPa).

− + verify (what is ?) CO2 + 2 e + 2H → CO + H2O https://en.wikipedia.org/wiki/Carbon_dioxide 5/32 5/20/2020 Carbon dioxide - Wikipedia Photoautotrophs (i.e. plants and cyanobacteria) use the energy Infobox references contained in sunlight to photosynthesize simple sugars from CO2 absorbed from the air and water:

n CO2 + n H2O → (CH2O)n + n O2 The potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode. The -containing enzyme carbon monoxide dehydrogenase catalyses this process.[32]

Physical properties

Carbon dioxide is colorless. At low concentrations the gas is odorless; however, at sufficiently-high concentrations, it has a sharp, acidic odor.[1] At standard temperature and pressure, the density of carbon dioxide is around 1.98 kg/m3, about 1.67 times that of air.

Carbon dioxide has no liquid state at pressures below 5.1 standard atmospheres (520 kPa). At 1 atmosphere (near mean sea level pressure), the gas deposits directly to a solid at temperatures below −78.5 °C (−109.3 °F; 194.7 K) and the solid sublimes directly to a gas above −78.5 °C. In its solid state, carbon dioxide is commonly called dry ice. Pellets of "dry ice", a common form of solid carbon dioxide Liquid carbon dioxide forms only at pressures above 5.1 atm; the triple point of carbon dioxide is about 5.1 bar (517 kPa) at 217 K (see phase diagram). The critical point is 7.38 MPa at 31.1 °C.[33][34] Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid.[35] This form of glass, called carbonia, is produced by supercooling heated CO2 at extreme pressure (40–48 GPa or about 400,000 atmospheres) in a diamond anvil. This discovery confirmed the theory that carbon dioxide could exist in a glass state similar to other members of its elemental family, like silicon (silica glass) and . Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released.

At temperatures and pressures above the critical point, carbon Pressure–temperature phase dioxide behaves as a supercritical fluid known as supercritical diagram of carbon dioxide carbon dioxide. In this state it is starting (as of 2018) to be used for power generation.[36]

Isolation and production

Carbon dioxide can be obtained by distillation from air, but the method is inefficient. Industrially, carbon dioxide is predominantly an unrecovered waste product, produced by several methods which may be practiced at various scales.[37]

The combustion of all carbon-based fuels, such as (natural gas), petroleum distillates (gasoline, diesel, kerosene, propane), coal, wood and generic organic matter produces carbon dioxide and, except in the case of pure carbon, water. As an example, the chemical reaction between methane and oxygen: https://en.wikipedia.org/wiki/Carbon_dioxide 6/32 5/20/2020 Carbon dioxide - Wikipedia

CH4 + 2 O2 → CO2 + 2 H2O

It is produced by thermal decomposition of limestone, CaCO3 by heating (calcining) at about 850 °C (1,560 °F), in the manufacture of quicklime (, CaO), a compound that has many industrial uses:

CaCO3 → CaO + CO2 is reduced from its oxides with coke in a blast furnace, producing pig iron and carbon dioxide:[38]

Carbon dioxide is a byproduct of the industrial production of hydrogen by steam reforming and the water gas shift reaction in production. These processes begin with the reaction of water and natural gas (mainly methane).[39] This is a major source of food-grade carbon dioxide for use in carbonation of beer and soft drinks, and is also used for stunning animals such as poultry. In the summer of 2018 a shortage of carbon dioxide for these purposes arose in Europe due to the temporary shut-down of several ammonia plants for maintenance.[40]

Acids liberate CO2 from most metal . Consequently, it may be obtained directly from natural carbon dioxide springs, where it is produced by the action of acidified water on limestone or dolomite. The reaction between hydrochloric acid and calcium carbonate (limestone or chalk) is shown below:

CaCO3 + 2 HCl → CaCl2 + H2CO3

The carbonic acid (H2CO3) then decomposes to water and CO2:

H2CO3 → CO2 + H2O Such reactions are accompanied by foaming or bubbling, or both, as the gas is released. They have widespread uses in industry because they can be used to neutralize waste acid streams.

Carbon dioxide is a by-product of the fermentation of sugar in the brewing of beer, whisky and other alcoholic beverages and in the production of bioethanol. Yeast metabolizes sugar to produce CO2 and , also known as , as follows:

C6H12O6 → 2 CO2 + 2 C2H5OH

All aerobic organisms produce CO2 when they oxidize carbohydrates, fatty acids, and . The large number of reactions involved are exceedingly complex and not described easily. Refer to (cellular respiration, anaerobic respiration and photosynthesis). The equation for the respiration of and other monosaccharides is:

C6H12O6 + 6 O2 → 6 CO2 + 6 H2O Anaerobic organisms decompose organic material producing methane and carbon dioxide together with traces of other compounds.[41] Regardless of the type of organic material, the production of gases follows well defined kinetic pattern. Carbon dioxide comprises about 40–45% of the gas that emanates from decomposition in landfills (termed "landfill gas"). Most of the remaining 50–55% is methane.[42]

Applications

https://en.wikipedia.org/wiki/Carbon_dioxide 7/32 5/20/2020 Carbon dioxide - Wikipedia Carbon dioxide is used by the food industry, the oil industry, and the chemical industry.[37] The compound has varied commercial uses but one of its greatest uses as a chemical is in the production of carbonated beverages; it provides the sparkle in carbonated beverages such as soda water, beer and sparkling wine.

Precursor to chemicals

In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of , with a smaller fraction being used to produce and a range of other products.[43] Some carboxylic acid derivatives such as salicylate are prepared using CO2 by the Kolbe-Schmitt reaction.[44]

In addition to conventional processes using CO2 for chemical production, electrochemical methods are also being explored at a research level. In particular, the use of renewable energy for production of fuels from CO2 (such as methanol) is attractive as this could result in fuels that could be easily transported [45] and used within conventional combustion technologies but have no net CO2 emissions.

Foods

Carbon dioxide is a food additive used as a propellant and acidity regulator in the food industry. It is approved for usage in the EU[46] (listed as E number E290), US[47] and Australia and New Zealand[48] (listed by its INS number 290).

A candy called Pop Rocks is pressurized with carbon dioxide gas[49] at about 4 × 106 Pa (40 bar, 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles Carbon dioxide bubbles in a soft with an audible pop. drink. Leavening agents cause dough to rise by producing carbon dioxide.[50] Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids.

Beverages

Carbon dioxide is used to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British real ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with .

The taste of soda water (and related taste sensations in other carbonated beverages) is an effect of the dissolved carbon dioxide rather than the bursting bubbles of the gas. Carbonic anhydrase 4 converts to carbonic acid leading to a sour taste, and also the dissolved carbon dioxide induces a somatosensory response.[51]

https://en.wikipedia.org/wiki/Carbon_dioxide 8/32 5/20/2020 Carbon dioxide - Wikipedia Winemaking

Carbon dioxide in the form of dry ice is often used during the cold soak phase in winemaking to cool clusters of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over water ice is that it cools the grapes without adding any additional water that might decrease the sugar concentration in the grape must, and thus the alcohol concentration in the finished wine. Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine. Dry ice used to preserve grapes Carbon dioxide is sometimes used to top up wine bottles or other after harvest. storage vessels such as barrels to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers.

Stunning animals

Carbon dioxide is often used to "stun" animals before slaughter.[52] "Stunning" may be a misnomer, as the animals are not knocked out immediately and may suffer distress.[53][54]

Inert gas

It is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are more brittle than those made in more inert atmospheres. It is used as a welding gas primarily because it is much less expensive than more inert gases such as argon or helium. When used for MIG welding, CO2 use is sometimes referred to as MAG welding, for Metal Active Gas, as CO2 can react at these high temperatures. It tends to produce a hotter puddle than truly inert atmospheres, improving the flow characteristics. Although, this may be due to atmospheric reactions occurring at the puddle site. This is usually the opposite of the desired effect when welding, as it tends to embrittle the site, but may not be a problem for general mild steel welding, where ultimate ductility is not a major concern.

It is used in many consumer products that require pressurized gas because it is inexpensive and nonflammable, and because it undergoes a phase transition from gas to liquid at room temperature at an attainable pressure of approximately 60 bar (870 psi, 59 atm), allowing far more carbon dioxide to fit in a given container than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. capsules of CO2 are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water. Rapid vaporization of liquid carbon dioxide is used for blasting in coal mines. High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy[55] and in the decaffeination of coffee beans.

https://en.wikipedia.org/wiki/Carbon_dioxide 9/32 5/20/2020 Carbon dioxide - Wikipedia Fire extinguisher

Carbon dioxide can be used to extinguish flames by flooding the environment around the flame with the gas. It does not itself react to extinguish the flame, but starves the flame of oxygen by displacing it. Some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because although it excludes oxygen, it does not cool the burning substances Use of a CO fire extinguisher. significantly and when the carbon dioxide disperses they are free to 2 catch fire upon exposure to atmospheric oxygen. Their desirability in electrical fire stems from the fact that, unlike water or other chemical based methods, Carbon dioxide will not cause short circuits, leading to even more damage to equipment. Because it is a gas, it is also easy to dispense large amounts of the gas automatically in IT infrastructure rooms, where the fire itself might be hard to reach with more immediate methods because it is behind rack doors and inside of cases. Carbon dioxide has also been widely used as an extinguishing agent in fixed fire protection systems for local application of specific hazards and total flooding of a protected space.[56] International Maritime Organization standards also recognize carbon dioxide systems for fire protection of ship holds and engine rooms. Carbon dioxide based fire protection systems have been linked to several deaths, because it can cause suffocation in sufficiently high concentrations. A review of CO2 systems identified 51 incidents between 1975 and the date of the report (2000), causing 72 deaths and 145 injuries.[57]

Supercritical CO2 as solvent

Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to remove from coffee.[15] Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional such as organochlorides. It is also used by some dry cleaners for this reason (see green chemistry). It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide.

Agriculture

Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of [58][59] large size, must) be enriched with additional CO2 to sustain and increase the rate of plant growth. At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as whiteflies and spider mites in a greenhouse.[60]

Medical and pharmacological uses

In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O2/CO2 balance in blood. Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as Carbogen and has a variety of medical and research uses.

https://en.wikipedia.org/wiki/Carbon_dioxide 10/32 5/20/2020 Carbon dioxide - Wikipedia Energy

Fossil fuel recovery

Carbon dioxide is used in enhanced oil recovery where it is injected into or adjacent to producing oil wells, usually under supercritical conditions, when it becomes miscible with the oil. This approach can increase original oil recovery by reducing residual oil saturation by between 7% to 23% additional to primary extraction.[61] It acts as both a pressurizing agent and, when dissolved into the underground crude oil, significantly reduces its viscosity, and changing surface chemistry enabling the oil to flow more rapidly through the reservoir to the removal well.[62] In mature oil fields, extensive pipe networks are used to carry the carbon dioxide to the injection points.

In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.[63]

Bio transformation into fuel

It has been proposed that CO2 from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel.[64] A strain of the cyanobacterium Synechococcus elongatus has been genetically engineered to produce the fuels isobutyraldehyde and from [65] CO2 using photosynthesis.

Refrigerant

Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C (−109.3 °F) at regular Comparison of phase diagrams of carbon dioxide (red) and water (blue) atmospheric pressure, regardless of as a log-lin chart with phase transitions points at 1 atmosphere the air temperature.

Liquid carbon dioxide (industry nomenclature R744 or R-744) was used as a refrigerant prior to the discovery of R-12 and may enjoy a renaissance due to the fact that R134a contributes to climate change more than CO2 does. Its physical properties are highly favorable for cooling, refrigeration, and heating purposes, having a high volumetric cooling capacity. Due to the need to operate at pressures of up to 130 bar (1880 psi), CO2 systems require highly resistant components that have already been developed for mass production in many sectors. In automobile air conditioning, in more than 90% of all driving conditions for latitudes higher than 50°, R744 operates more efficiently than systems using R134a. Its environmental advantages (GWP of 1, non- depleting, non-toxic, non-flammable) could make it the future working fluid to replace current https://en.wikipedia.org/wiki/Carbon_dioxide 11/32 5/20/2020 Carbon dioxide - Wikipedia

HFCs in cars, supermarkets, and heat pump water heaters, among others. Coca-Cola has fielded CO2- based beverage coolers and the U.S. Army is interested in CO2 refrigeration and heating technology.[66][67]

The global automobile industry is expected to decide on the next-generation refrigerant in car air conditioning. CO2 is one discussed option.(see Sustainable automotive air conditioning)

Minor uses

Carbon dioxide is the lasing medium in a carbon dioxide laser, which is one of the earliest type of lasers.

Carbon dioxide can be used as a means of controlling the pH of swimming pools,[68] by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this is the avoidance of handling (more hazardous) acids. Similarly, it is also used in the maintaining reef aquaria, where it is commonly used in calcium reactors to temporarily A carbon dioxide laser. lower the pH of water being passed over calcium carbonate in order to allow the calcium carbonate to dissolve into the water more freely where it is used by some corals to build their skeleton.

Used as the primary coolant in the British advanced gas-cooled reactor for nuclear power generation.

Carbon dioxide induction is commonly used for the euthanasia of laboratory research animals. Methods to administer CO2 include placing animals directly into a closed, prefilled chamber containing CO2, or exposure to a gradually increasing concentration of CO2. In 2013, the American Veterinary Medical Association issued new guidelines for carbon dioxide induction, stating that a displacement rate of 10% to 30% of the gas chamber volume per minute is optimal for the humane euthanization of small rodents.[69] However, there is opposition to the practice of using carbon dioxide for this, on the grounds that it is cruel.[54]

Carbon dioxide is also used in several related cleaning and surface preparation techniques.

In Earth's atmosphere

Carbon dioxide in Earth's atmosphere is a trace gas, currently (start of 2020) having a global average concentration of 412 parts per million by volume[70][71][72] (or 622 parts per million by mass). Atmospheric concentrations of carbon dioxide fluctuate slightly with the seasons, falling during the Northern Hemisphere spring and summer as plants consume the gas and rising during northern autumn and winter as plants go dormant or die and decay. Concentrations also vary on a regional basis, most strongly near the ground with much smaller variations aloft. In urban areas concentrations are generally higher[73] and indoors they can reach 10 times background levels.

The concentration of carbon dioxide has risen due to human activities.[75] Combustion of fossil fuels and deforestation have caused the atmospheric concentration of carbon dioxide to increase by about 43% since the beginning of the age of industrialization.[76] Most carbon dioxide from human activities is https://en.wikipedia.org/wiki/Carbon_dioxide 12/32 5/20/2020 Carbon dioxide - Wikipedia released from burning coal and other fossil fuels. Other human activities, including deforestation, biomass burning, and cement production also produce carbon dioxide. Human activities emit about 29 billion tons of carbon dioxide per year, while volcanoes emit between 0.2 and 0.3 billion tons.[77][78] Yearly increase of atmospheric CO2: In the 1960s, the average annual Human activities have caused increase was 35% of the 2009-2018 CO2 to increase above levels not [74] average. seen in hundreds of thousands The Keeling Curve of atmospheric

of years. Currently, about half of CO2 concentrations measured at the carbon dioxide released Mauna Loa Observatory from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans.[79][80][81][82]

While transparent to visible light, carbon dioxide is a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see the section "Structure and bonding" above). Light emission from the earth's surface is most intense in the infrared region between 200 and 2500 cm−1,[83] as opposed to light emission from the much hotter sun which is most intense in the visible region. Absorption of infrared light at the vibrational frequencies of atmospheric carbon dioxide traps energy near the surface, warming the surface and the lower atmosphere. Less energy reaches the upper atmosphere, which is therefore cooler because of this absorption.[84] Increases in atmospheric concentrations of CO2 and other long-lived greenhouse gases such as methane, and ozone have correspondingly strengthened their absorption and emission of infrared radiation, causing the rise in average global temperature since the mid-20th century. Carbon dioxide is of greatest concern because it exerts a larger overall warming influence than all of these other gases combined and because it has a long atmospheric lifetime (hundreds to thousands of years).

Not only do increasing carbon dioxide concentrations lead to increases in global surface temperature, but increasing global temperatures also cause increasing concentrations of carbon dioxide. This produces a positive feedback for changes induced by other processes such as orbital cycles.[85] Five hundred million years ago the carbon dioxide concentration was 20 times greater than today, decreasing to 4–5 times during the Jurassic period and then CO in Earth's atmosphere if half of slowly declining with a particularly swift reduction occurring 49 2 [86][87] global-warming emissions are not million years ago. absorbed.[79][80][81][82] (NASA computer simulation). Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of

CO2 rise to above 75% overnight, sufficient to kill insects and small animals. After sunrise the gas is [88] dispersed by convection. High concentrations of CO2 produced by disturbance of deep lake water saturated with CO2 are thought to have caused 37 fatalities at , Cameroon in 1984 and 1700 casualties at , Cameroon in 1986.[89]

https://en.wikipedia.org/wiki/Carbon_dioxide 13/32 5/20/2020 Carbon dioxide - Wikipedia In the oceans

Carbon dioxide dissolves in the ocean to form carbonic acid (H2CO3), − bicarbonate (HCO3 ) and carbonate 2− (CO3 ). There is about fifty times as much carbon dioxide dissolved in the oceans as exists in the atmosphere. The oceans act as an enormous carbon sink, and have taken up about

a third of CO2 emitted by human [90] Pterapod shell dissolved in seawater adjusted to an ocean chemistry activity. projected for the year 2100. As the concentration of carbon dioxide increases in the atmosphere, the increased uptake of carbon dioxide into the oceans is causing a measurable decrease in the pH of the oceans, which is referred to as ocean acidification. This reduction in pH affects biological systems in the oceans, primarily oceanic calcifying organisms. These effects span the food chain from autotrophs to heterotrophs and include organisms such as coccolithophores, corals, foraminifera, echinoderms, crustaceans and mollusks. Under normal conditions, calcium carbonate is stable in surface waters since the carbonate ion is at supersaturating concentrations. However, as ocean pH falls, so does the concentration of this ion, and when carbonate becomes undersaturated, structures made of calcium carbonate are vulnerable to dissolution.[91] Corals,[92][93][94] coccolithophore algae,[95][96][97][98] coralline algae,[99] foraminifera,[100] shellfish[101] and pteropods[102] experience reduced calcification or enhanced dissolution when exposed to elevated CO2. Gas solubility decreases as the temperature of water increases (except when both pressure exceeds 300 bar and temperature exceeds 393 K, only found near deep geothermal vents)[103] and therefore the rate of uptake from the atmosphere decreases as ocean temperatures rise.

[104] Most of the CO2 taken up by the ocean, which is about 30% of the total released into the atmosphere, forms carbonic acid in equilibrium with bicarbonate. Some of these chemical species are consumed by photosynthetic organisms that remove carbon from the cycle. Increased CO2 in the atmosphere has led to decreasing alkalinity of seawater, and there is concern that this may adversely affect organisms living in the water. In particular, with decreasing alkalinity, the availability of carbonates for forming shells decreases,[105] although there's evidence of increased shell production by certain species under increased [106] CO2 content. NOAA states in their May 2008 "State of the science fact sheet for ocean acidification" that:

"The oceans have absorbed about 50% of the carbon dioxide (CO2) released from the burning of fossil fuels, resulting in chemical reactions that lower ocean pH. This has caused an increase in hydrogen ion (acidity) of about 30% since the start of the industrial age through a process known as "ocean acidification." A growing number of studies have demonstrated adverse impacts on marine organisms, including:

The rate at which reef-building corals produce their skeletons decreases, while production of numerous varieties of jellyfish increases. The ability of marine algae and free-swimming zooplankton to maintain protective shells is reduced. The survival of larval marine species, including commercial fish and shellfish, is reduced." https://en.wikipedia.org/wiki/Carbon_dioxide 14/32 5/20/2020 Carbon dioxide - Wikipedia Also, the Intergovernmental Panel on Climate Change (IPCC) writes in their Climate Change 2007: Synthesis Report:[107] "The uptake of anthropogenic carbon since 1750 has led to the ocean becoming more acidic with an average decrease in pH of 0.1 units. Increasing atmospheric CO2 concentrations lead to further acidification ... While the effects of observed ocean acidification on the marine biosphere are as yet undocumented, the progressive acidification of oceans is expected to have negative impacts on marine shell-forming organisms (e.g. corals) and their dependent species."

Some marine calcifying organisms (including coral reefs) have been singled out by major research agencies, including NOAA, OSPAR commission, NANOOS and the IPCC, because their most current research shows that ocean acidification should be expected to impact them negatively.[108]

Carbon dioxide is also introduced into the oceans through hydrothermal vents. The Champagne hydrothermal vent, found at the Northwest Eifuku volcano in the Marianas Trench, produces almost pure liquid carbon dioxide, one of only two known sites in the world as of 2004, the other being in the Okinawa Trough.[109] The finding of a submarine lake of liquid carbon dioxide in the Okinawa Trough was reported in 2006.[110]

Biological role

Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration.

Photosynthesis and carbon fixation

Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and (cyanobacteria) into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic Overview of the Calvin cycle and compounds can be constructed, carbon fixation and oxygen is produced as a by- product. Overview of photosynthesis and respiration. Carbon dioxide (at Ribulose-1,5-bisphosphate carboxylase oxygenase, commonly right), together with water, form abbreviated to RuBisCO, is the enzyme involved in the first major oxygen and organic compounds (at step of carbon fixation, the production of two molecules of 3- left) by photosynthesis, which can phosphoglycerate from CO and ribulose bisphosphate, as shown in 2 be respired to water and (CO2). the diagram at left. https://en.wikipedia.org/wiki/Carbon_dioxide 15/32 5/20/2020 Carbon dioxide - Wikipedia RuBisCO is thought to be the single most abundant on Earth.[111]

Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales.[112] A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.

Plants can grow as much as 50 percent faster in concentrations of 1,000 ppm CO2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients.[113]

Elevated CO2 levels cause increased growth reflected in the harvestable yield of crops, with wheat, rice [114][115] and soybean all showing increases in yield of 12–14% under elevated CO2 in FACE experiments.

[116] Increased atmospheric CO2 concentrations result in fewer stomata developing on plants which [117] to reduced water usage and increased water-use efficiency. Studies using FACE have shown that CO2 enrichment leads to decreased concentrations of micronutrients in crop plants.[118] This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain the same amount of protein.[119]

The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered [120][121] in plants exposed to high concentrations of CO2.

Plants also emit CO2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis, are only net absorbers during the day. Though a growing forest will absorb many tons of

CO2 each year, a mature forest will produce as much CO2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants.[122] Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon[123] and remain valuable carbon sinks, helping to maintain the carbon balance of Earth's atmosphere.

Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO2 in [124] the upper ocean and thereby promotes the absorption of CO2 from the atmosphere.

Toxicity

Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (412 ppm), depending on the location.[126]

CO2 is an and not classified as toxic or harmful in accordance with Globally Harmonized System of Classification and Labelling of Chemicals standards of United Nations Economic Commission for Europe by using the OECD Guidelines for the Testing of Chemicals. In concentrations up to 1% (10,000 ppm), it will make some people feel drowsy and give the lungs a stuffy feeling.[125] Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour.[127] The physiological effects of acute carbon dioxide exposure are grouped together under the term hypercapnia, a subset of asphyxiation.

https://en.wikipedia.org/wiki/Carbon_dioxide 16/32 5/20/2020 Carbon dioxide - Wikipedia Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without the dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of by [128] CO2 emissions from the nearby volcano Mt. Nyiragongo. The Swahili term for this phenomenon is ''.

Adaptation to increased concentrations of CO occurs in humans, 2 Main symptoms of carbon dioxide including modified breathing and kidney bicarbonate production, in toxicity, by increasing volume order to balance the effects of blood acidification (acidosis). Several percent in air.[125] studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days.[129][130] Yet, other studies show a decrease in cognitive function even at much lower levels.[131][132] Also, with ongoing respiratory acidosis, adaptation or compensatory mechanisms will be unable to reverse such condition.

Below 1%

There are few studies of the health effects of long-term continuous

CO2 exposure on humans and animals at levels below 1%. Occupational CO exposure limits have been set in the United States 2 Rising levels of CO threatened the [133] 2 at 0.5% (5000 ppm) for an eight-hour period. At this CO2 Apollo 13 astronauts who had to concentration, International Space Station crew experienced adapt cartridges from the command headaches, lethargy, mental slowness, emotional irritation, and module to supply the carbon dioxide [134] scrubber in the lunar module, which sleep disruption. Studies in animals at 0.5% CO2 have demonstrated kidney calcification and bone loss after eight weeks of they used as a lifeboat. exposure.[135] A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000 ppm) CO2 likely due to CO2 induced increases in cerebral blood flow.[131] Another study observed a decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm.[132]

Ventilation

Poor ventilation is one of the main causes of excessive CO2 concentrations in closed spaces. Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO concentration has stabilized) are sometimes used to estimate 2 CO2 concentration meter using a ventilation rates per person. Higher CO2 concentrations are nondispersive infrared sensor associated with occupant health, comfort and performance degradation.[136][137] ASHRAE Standard 62.1–2007 ventilation rates https://en.wikipedia.org/wiki/Carbon_dioxide 17/32 5/20/2020 Carbon dioxide - Wikipedia may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if the outdoor concentration is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000).

Miners, who are particularly vulnerable to gas exposure due to an insufficient ventilation, referred to mixtures of carbon dioxide and nitrogen as "blackdamp," "choke " or "stythe." Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked. The canary is more sensitive to asphyxiant gases than humans, and as it became unconscious would stop singing and fall off its perch. The could also detect high levels of blackdamp (which sinks, and collects near the floor) by burning less brightly, while methane, another suffocating gas and explosion risk, would make the lamp burn more brightly.

In February 2020, three people died from suffocation at a party in Moscow when dry ice (frozen CO2) was added to a swimming pool to cool it down.[138]

Human physiology

Content Reference ranges or averages for partial pressures of The body produces approximately 2.3 pounds (1.0 kg) carbon dioxide (abbreviated pCO2) of carbon dioxide per day per person,[140] containing 0.63 pounds (290 g) of carbon. In humans, this carbon kPa mmHg dioxide is carried through the venous system and is Venous blood carbon dioxide 5.5–6.8 41–51[139] breathed out through the lungs, resulting in lower Alveolar pulmonary 4.8 36 concentrations in the arteries. The carbon dioxide gas pressures content of the blood is often given as the partial [139] pressure, which is the pressure which carbon dioxide Arterial blood carbon dioxide 4.7–6.0 35–45 would have had if it alone occupied the volume.[141] In humans, the blood carbon dioxide contents is shown in the adjacent table:

Transport in the blood

CO2 is carried in blood in three different ways. (The exact percentages vary depending whether it is arterial or venous blood).

− Most of it (about 70% to 80%) is converted to bicarbonate HCO3 by the enzyme carbonic [142] + − anhydrase in the red blood cells, by the reaction CO2 + H2O → H2CO3 → H + HCO3. 5–10% is dissolved in the [142] 5–10% is bound to hemoglobin as carbamino compounds[142]

Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the CO2 bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of CO2 decreases the amount of oxygen that is bound for a given

https://en.wikipedia.org/wiki/Carbon_dioxide 18/32 5/20/2020 Carbon dioxide - Wikipedia partial pressure of oxygen. This is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of CO2 or a lower pH will cause offloading of oxygen from hemoglobin, which is known as the Bohr effect.

Regulation of respiration

Carbon dioxide is one of the mediators of local autoregulation of blood supply. If its concentration is high, the capillaries expand to allow a greater blood flow to that tissue.

Bicarbonate ions are crucial for regulating blood pH. A person's breathing rate influences the level of

CO2 in their blood. Breathing that is too slow or shallow causes respiratory acidosis, while breathing that is too rapid leads to hyperventilation, which can cause respiratory alkalosis.

Although the body requires oxygen for metabolism, low oxygen levels normally do not stimulate breathing. Rather, breathing is stimulated by higher carbon dioxide levels. As a result, breathing low- pressure air or a gas mixture with no oxygen at all (such as pure nitrogen) can lead to loss of consciousness without ever experiencing air hunger. This is especially perilous for high-altitude fighter pilots. It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.[142]

The respiratory centers try to maintain an arterial CO2 pressure of 40 mm Hg. With intentional hyperventilation, the CO2 content of arterial blood may be lowered to 10–20 mm Hg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving.

See also Arterial blood gas Bosch reaction Bottled gas – Substances which are gaseous at standard temperature and pressure and have been compressed and stored in gas cylinders Carbon dioxide sensor Carbon sequestration – Methods of reducing net emissions by capturing and storing large volumes of carbon dioxide Cave of Dogs EcoCute – as refrigerants Emission standards Indoor air quality – Air quality within and around buildings and structures Kaya identity – Identity regarding anthropogenic carbon dioxide emissions – in the East African Rift valley List of least carbon efficient power stations – Wikipedia list article List of countries by carbon dioxide emissions – Wikimedia list article Meromictic lake – Lake with layers of water that do not intermix pCO2 – Partial pressure of carbon dioxide, often used in reference to blood

Gilbert Plass (early work on CO2 and climate change) https://en.wikipedia.org/wiki/Carbon_dioxide 19/32 5/20/2020 Carbon dioxide - Wikipedia Sabatier reaction – Methanation process of carbon dioxide with hydrogen NASA's Orbiting Carbon Observatory 2 Greenhouse Gases Observing Satellite

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Further reading

Seppänen, O.A.; Fisk, W.J.; Mendell, M.J. (December 1999). "Association of Ventilation Rates and

CO2 Concentrations with Health and Other Responses in Commercial and Institutional Buildings" (ht tps://web.archive.org/web/20161227032839/https://indoor.lbl.gov/sites/all/files/43334.pdf) (PDF). Indoor Air. 9 (4): 226–252. doi:10.1111/j.1600-0668.1999.00003.x (https://doi.org/10.1111%2Fj.1600- 0668.1999.00003.x). PMID 10649857 (https://pubmed.ncbi.nlm.nih.gov/10649857). Archived from the original (https://indoor.lbl.gov/sites/all/files/43334.pdf) (PDF) on 27 December 2016. Shendell, D.G.; Prill, R.; Fisk, W.J.; Apte, M.G.; Blake, D.; Faulkner, D. (October 2004). "Associations

between classroom CO2 concentrations and student attendance in Washington and Idaho" (https://w eb.archive.org/web/20161227030811/https://indoor.lbl.gov/sites/all/files/lbnl-54413.pdf) (PDF). Indoor Air. 14 (5): 333–341. doi:10.1111/j.1600-0668.2004.00251.x (https://doi.org/10.1111%2Fj.1600-0668. 2004.00251.x). hdl:2376/5954 (https://hdl.handle.net/2376%2F5954). PMID 15330793 (https://pubm ed.ncbi.nlm.nih.gov/15330793). Archived from the original (https://indoor.lbl.gov/sites/all/files/lbnl-544 13.pdf) (PDF) on 27 December 2016.

Soentgen, Jens (February 2014). "Hot air: The science and politics of CO2". Global Environment. 7 (1): 134–171. doi:10.3197/197337314X13927191904925 (https://doi.org/10.3197%2F197337314X13 927191904925). Good plant design and operation for onshore carbon capture installations and onshore pipelines: a recommended practice guidance document (https://web.archive.org/web/20181107001428/https://hu b.globalccsinstitute.com/publications/good-plant-design-and-operation-onshore-carbon-capture-instal lations-and-onshore-pipelines-recommended-practice-guidance-document). Global CCS Institute. Energy Institute and Global Carbon Capture and Storage Institute. 1 September 2010. Archived from the original (https://hub.globalccsinstitute.com/publications/good-plant-design-and-operation-onshore -carbon-capture-installations-and-onshore-pipelines-recommended-practice-guidance-document) on 7 November 2018. Retrieved 2 January 2018. "This new title is an essential guide for engineers, managers, procurement specialists and designers working on global carbon capture and storage projects."

External links

International Chemical Safety Card 0021 (http://www.inchem.org/documents/icsc/icsc/eics0021.htm) Carbon dioxide MSDS (http://sdsdata.org/68399) by Amerigas in the SDSdata.org database. CDC – NIOSH Pocket Guide to Chemical Hazards – Carbon Dioxide (https://www.cdc.gov/niosh/npg/ npgd0103.html)

CO2 Carbon Dioxide Properties, Uses, Applications (http://www.uigi.com/carbondioxide.html) https://en.wikipedia.org/wiki/Carbon_dioxide 31/32 5/20/2020 Carbon dioxide - Wikipedia Dry Ice information (http://www.dryiceinfo.com/science.htm) Trends in Atmospheric Carbon Dioxide (https://web.archive.org/web/20070225181531/http://www.cm dl.noaa.gov/ccgg/trends/) (NOAA) "A War Gas That Saves Lives" (https://books.google.com/books?id=RicDAAAAMBAJ&pg=PA53). Popular Science, June 1942, pp. 53–57. Reactions, Thermochemistry, Uses, and Function of Carbon Dioxide (http://www.chemistry-referenc e.com/q_compounds.asp?CAS=124-38-9) Carbon Dioxide – Part One (http://www.periodicvideos.com/videos/mv_carbon_dioxide_one.htm) and Carbon Dioxide – Part Two (http://www.periodicvideos.com/videos/mv_carbon_dioxide_two.htm) at The Periodic Table of Videos (University of Nottingham)

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