Near-Infrared Tm3+:ZBLAN Fiber Lasers
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Eliminating Crystals in Non-Oxide Optical Fiber Preforms and Optical
Eliminating Crystals in Non‐Oxide Optical Fiber Preforms and Optical Fibers Short Running Title Gravity and Magnetic Effects on Glass Author’s Names and Affiliations Dennis S. Tucker Michael R. LaPointe NASA NASA/ZP10 EM20 National Space Science and Technology Center MSFC, Alabama, USA, 35812 320 Sparkman Drive Telephone: 256‐544‐7022 Huntsville, Alabama 35805 FAX: 256‐961‐9604 Telephone: 256‐961‐7555 [email protected] [email protected] Abstract Non‐oxide fiber optics such as heavy metal fluoride and chalcogenide glasses are extensively used in infrared transmitting applications such as communication systems, chemical sensors, and laser fiber guides for cutting, welding and medical surgery. The addition of rare earths such as erbium, enable these materials to be used as fiber laser and amplifiers. Some of these glasses however are very susceptible to crystallization. Even small crystals can lead to light scatter and a high attenuation coefficient, limiting their usefulness. Previously two research teams found that microgravity suppressed crystallization in heavy metal fluoride glasses. Looking for a less expensive method to suppress crystallization, ground based research was performed utilizing an axial magnetic field. The experiments revealed identical results to those obtained via microgravity processing. This research then led to a patented process for eliminating crystals in optical fiber preforms and the resulting optical fibers. In this paper, the microgravity results will be reviewed as well as patents and papers relating to the use of magnetic fields in various material and glass processing applications. Finally our patent to eliminate crystals in non‐oxide glasses utilizing a magnetic field will be detailed. -
The American Ceramic Society 25Th International Congress On
The American Ceramic Society 25th International Congress on Glass (ICG 2019) ABSTRACT BOOK June 9–14, 2019 Boston, Massachusetts USA Introduction This volume contains abstracts for over 900 presentations during the 2019 Conference on International Commission on Glass Meeting (ICG 2019) in Boston, Massachusetts. The abstracts are reproduced as submitted by authors, a format that provides for longer, more detailed descriptions of papers. The American Ceramic Society accepts no responsibility for the content or quality of the abstract content. Abstracts are arranged by day, then by symposium and session title. An Author Index appears at the back of this book. The Meeting Guide contains locations of sessions with times, titles and authors of papers, but not presentation abstracts. How to Use the Abstract Book Refer to the Table of Contents to determine page numbers on which specific session abstracts begin. At the beginning of each session are headings that list session title, location and session chair. Starting times for presentations and paper numbers precede each paper title. The Author Index lists each author and the page number on which their abstract can be found. Copyright © 2019 The American Ceramic Society (www.ceramics.org). All rights reserved. MEETING REGULATIONS The American Ceramic Society is a nonprofit scientific organization that facilitates whether in print, electronic or other media, including The American Ceramic Society’s the exchange of knowledge meetings and publication of papers for future reference. website. By participating in the conference, you grant The American Ceramic Society The Society owns and retains full right to control its publications and its meetings. -
Chapter 22 Reflection and Refraction of Light
Chapter 22 Reflection and Refraction of Light Problem Solutions 22.1 The total distance the light travels is d2 Dcenter to R Earth R Moon center 2 3.84 108 6.38 10 6 1.76 10 6 m 7.52 10 8 m d 7.52 108 m Therefore, v 3.00 108 m s t 2.51 s 22.2 (a) The energy of a photon is sinc nair n prism 1.00 n prism , where Planck’ s constant is 1.00 8 sinc sin 45 and the speed of light in vacuum is c 3.00 10 m s . If nprism 1.00 1010 m , 6.63 1034 J s 3.00 10 8 m s E 1.99 1015 J 1.00 10-10 m 1 eV (b) E 1.99 1015 J 1.24 10 4 eV 1.602 10-19 J (c) and (d) For the X-rays to be more penetrating, the photons should be more energetic. Since the energy of a photon is directly proportional to the frequency and inversely proportional to the wavelength, the wavelength should decrease , which is the same as saying the frequency should increase . 1 eV 22.3 (a) E hf 6.63 1034 J s 5.00 10 17 Hz 2.07 10 3 eV 1.60 1019 J 355 356 CHAPTER 22 34 8 hc 6.63 10 J s 3.00 10 m s 1 nm (b) E hf 6.63 1019 J 3.00 1029 nm 10 m 1 eV E 6.63 1019 J 4.14 eV 1.60 1019 J c 3.00 108 m s 22.4 (a) 5.50 107 m 0 f 5.45 1014 Hz (b) From Table 22.1 the index of refraction for benzene is n 1.501. -
Teng-Cheong Ong Thesis
This is the author’s version of a work that was submitted/accepted for pub- lication in the following source: Ong, Teng-Cheong (2018) Research of the suppression effects of cooling rate on crystallization in ZBLAN glass. PhD thesis, Queensland University of Technology. This file was downloaded from: https://eprints.qut.edu.au/116614/ Notice: Changes introduced as a result of publishing processes such as copy-editing and formatting may not be reflected in this document. For a definitive version of this work, please refer to the published source: https://doi.org/10.5204/thesis.eprints.116614 Research of the suppression effects of cooling rate on crystallization in ZBLAN glass Teng-Cheong Ong Bachelor of Engineering (Mechanical) (Hons) Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy School of Chemistry, Physics and Mechanical Engineering Science & Engineering Faculty Queensland University of Technology 2018 Abstract ZBLAN glass is a heavy metal fluoride glass that has great potential in the application of long- haul telecommunication cables. However, during processing in the fibre-drawing temperature region, the material tends to undergo heavy devitrification, resulting in a crystalline fibre that is not usable for such purposes. There are many papers exploring various processing techniques in the aims of creating a test sample that can transmit with the theoretical minimum attenuation loss predicted for ZBLAN. As ZBLAN glass is cooled from its melt, crystallites form throughout the medium, their size and structure dependent on the rate of cooling and degree of undercooling. These crystallites act as scattering centres that degrade a signal that is propagated through the glass. -
Design and Fabrication of Nonconventional Optical Components by Precision Glass Molding
Design and Fabrication of Nonconventional Optical Components by Precision Glass Molding DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of the Ohio State University By Peng He Graduate Program in Industrial and Systems Engineering The Ohio State University 2014 Dissertation Committee: Dr. Allen Y. Yi, Advisor Dr. Jose M. Castro Dr. L. James Lee Copyright by Peng He 2014 Abstract Precision glass molding is a net-shaping process to fabricate glass optics by replicating optical features from precision molds to glass at elevated temperature. The advantages of precision glass molding over traditional glass lens fabrication methods make it especially suitable for the production of optical components with complicated geometries, such as aspherical lenses, diffractive hybrid lenses, microlens arrays, etc. Despite of these advantages, a number of problems must be solved before this process can be used in industrial applications. The primary goal of this research is to determine the feasibility and performance of nonconventional optical components formed by precision glass molding. This research aimed to investigate glass molding by combing experiments and finite element method (FEM) based numerical simulations. The first step was to develop an integrated compensation solution for both surface deviation and refractive index drop of glass optics. An FEM simulation based on Tool-Narayanaswamy-Moynihan (TNM) model was applied to predict index drop of the molded optical glass. The predicted index value was then used to compensate for the optical design of the lens. Using commercially available general purpose software, ABAQUS, the entire process of glass molding was simulated to calculate the surface deviation from the adjusted lens geometry, which was applied to final mold shape modification. -
High-Precision Micro-Machining of Glass for Mass-Personalization and Submitted in Partial Fulfillment of the Requirements for the Degree Of
High-precision micro-machining of glass for mass-personalization Lucas Abia Hof A Thesis In the Department of Mechanical, Industrial and Aerospace Engineering Presented in Partial Fulfillment of the Requirements For the Degree of Doctor of Philosophy (Mechanical Engineering) at Concordia University Montreal, Québec, Canada June 2018 © Lucas Abia Hof, 2018 CONCORDIA UNIVERSITY School of Graduate Studies This is to certify that the thesis prepared By: Lucas Abia Hof Entitled: High-precision micro-machining of glass for mass-personalization and submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy (Mechanical Engineering) complies with the regulations of the University and meets the accepted standards with respect to originality and quality. Signed by the final examining committee: ______________________________________ Chair Dr. K. Schmitt ______________________________________ External Examiner Dr. P. Koshy ______________________________________ External to Program Dr. M. Nokken ______________________________________ Examiner Dr. C. Moreau ______________________________________ Examiner Dr. R. Sedaghati ______________________________________ Thesis Supervisor Dr. R. Wüthrich Approved by: ___________________________________________________ Dr. A. Dolatabadi, Graduate Program Director August 14, 2018 __________________________________________________ Dr. A. Asif, Dean Faculty of Engineering and Computer Science Abstract High-precision micro-machining of glass for mass- personalization Lucas Abia Hof, -
Appendix a Definitions and Symbols
Appendix A Definitions and Symbols A.1 Symbols and Conversion Factors A absorptivity a distance aperture b net increase in number of molecules per formula unit; b = μ − 1 C constant C Euler’s constant; C = 0.577 Cp heat capacity c speed of light; c = 2.998 ×1010 cm/s cp specific heat at constant pressure [J/gK, J/molK] cv specific heat at constant volume [J/gK, J/molK] D heat diffusivity [cm2/s] transmittivity 2 Di molecular diffusion coefficient of species i [cm /s] d lateral width of laser-processed features [μm, cm] diameter E electric field [V/cm] energy [J] −2 kBT (T = 273.15 K) = 2.354 ×10 eV 1 kcal/mol =# 0.043 eV =# 5.035 ×102 K 1eV=# 1.1604 ×104 K =# 1.602 ×10−19 J 1 kcal =# 4.187 ×103 J 1cm−1 =# 1.24 ×10−4 eV =# 1.439 K 1J=# 2.39 ×10−4 kcal EF Fermi energy E activation temperature [K]; E = E/kB E ∗ normalized activation temperature; E ∗ = E /T (∞) E activation energy [eV; kcal/mol] Em activation energy for melting Ev activation energy for vaporization at Tb D. Bäuerle, Laser Processing and Chemistry, 4th ed., 739 DOI 10.1007/978-3-642-17613-5, C Springer-Verlag Berlin Heidelberg 2011 740 Appendix A Eg bandgap energy = energy distance between (lowest) conduction and (highest) valence bands E laser-pulse energy [J] e elementary charge; e = 1.602 ×10−19 C ee≈ 2.718 eV electron Volt 1eV/particle = 23.04 kcal/mol F area Faraday constant; F = 96485 C/mol f focal length [cm] Gr Grashof number G Gibbs free energy g acceleration due to gravity gT temperature discontinuity coefficient H total enthalpy [J/cm3,J/g, J/mol] reaction enthalpy H a -
Engineering a Better Future Refraction of Light: a Forensic
Nanotechnology Education - Engineering a better future NNCI.net Teacher’s Guide Refraction of Light: A forensic analysis Grade Level: High school Summary: This lesson uses forensic science investigations to help students understand the refraction of light. Using The Subject area(s): Physics Marching Band Analogy, the students firsts “experience” how wavelengths of light can slow and bend. This activity provides Time required: (2 – 3) 50 an excellent analogy to understanding the cause of light minute class periods refraction. The forensic portion of the lesson has students solve (depending on which a crime scene by identifying glass using the index of refraction. activities are done) Students also learn that the refraction of light occurs at the nanoscale as the visible light range is 380 to 740 nm. Learning Objectives: Using two demonstrations and Pre-requisite Knowledge: Students should have some prior an inquiry-based activity, recognition of the refraction of light phenomenon such as a students will comprehend straw in a glass of water the principles of the refraction of light and its Lesson Background: Glass and its properties: Glass is a non- application in forensic crystalline amorphous solid material usually made of some science. percentage of silica. In science terms, the definition can go beyond this to include all solids that have a non-crystalline, amorphous, structure at the atomic scale (the nanoscale). These glasses also exhibits a glass- liquid transition when they heated near the liquid state. Nearly all commercial glasses fall into one of six basic categories based on chemical composition. Within each category (except for fused silica) there are numerous distinct compositions. -
Micro-Hole Drilling on Glass Substrates—A Review
micromachines Review Micro-Hole Drilling on Glass Substrates—A Review Lucas A. Hof 1 and Jana Abou Ziki 2,* 1 Department of Mechanical & Industrial Engineering, Concordia University, 1455 de Maisonneuve Blvd. West, Montreal, QC H3G 1M8, Canada; [email protected] 2 Bharti School of Engineering, Laurentian University, Sudbury, ON P3E 2C6, Canada * Correspondence: [email protected]; Tel.: +1-705-675-1151 (ext. 2296) Academic Editors: Hongrui Jiang and Nam-Trung Nguyen Received: 14 November 2016; Accepted: 3 February 2017; Published: 13 February 2017 Abstract: Glass micromachining is currently becoming essential for the fabrication of micro-devices, including micro- optical-electro-mechanical-systems (MOEMS), miniaturized total analysis systems (µTAS) and microfluidic devices for biosensing. Moreover, glass is radio frequency (RF) transparent, making it an excellent material for sensor and energy transmission devices. Advancements are constantly being made in this field, yet machining smooth through-glass vias (TGVs) with high aspect ratio remains challenging due to poor glass machinability. As TGVs are required for several micro-devices, intensive research is being carried out on numerous glass micromachining technologies. This paper reviews established and emerging technologies for glass micro-hole drilling, describing their principles of operation and characteristics, and their advantages and disadvantages. These technologies are sorted into four machining categories: mechanical, thermal, chemical, and hybrid machining (which combines several machining methods). Achieved features by these methods are summarized in a table and presented in two graphs. We believe that this paper will be a valuable resource for researchers working in the field of glass micromachining as it provides a comprehensive review of the different glass micromachining technologies. -
Ultrafast-Laser-Inscribed 3D Integrated Photonics: Challenges and Emerging Applications
Nanophotonics 2015; 4:332–352 Review Article Open Access S. Gross* and M. J. Withford Ultrafast-laser-inscribed 3D integrated photonics: challenges and emerging applications DOI 10.1515/nanoph-2015-0020 ing methods used to create photonic chips are relatively Received July 7, 2015; accepted July 30, 2015 immature, and the common approach is to adapt the pla- nar (2D) lithography methods originally developed for sil- Abstract: Since the discovery that tightly focused fem- icon microelectronics. Unfortunately, this is akin to push- tosecond laser pulses can induce a highly localised and ing a square peg into a round hole because photons, the permanent refractive index modification in a large num- elementary particle of light, have many degrees of free- ber of transparent dielectrics, the technique of ultrafast dom, in contrast to electrons which have few. For exam- laser inscription has received great attention from a wide ple, a stream of electrons can be characterised in terms range of applications. In particular, the capability to create of current and voltage. A stream of photons, on the other three-dimensional optical waveguide circuits has opened hand, can exhibit different traits based on velocity and up new opportunities for integrated photonics that would brightness, the optical equivalent to current and voltage as not have been possible with traditional planar fabrication well as wavelength, polarisation, spatial mode and orbital techniques because it enables full access to the many de- angular momentum. These additional features reflect the grees of freedom in a photon. This paper reviews the basic three dimensionality of light, features that cannot be fully techniques and technological challenges of 3D integrated exploited with planar circuitry. -
Bespoke Photonic Devices Using Ultrafast Laser Driven Ion Migration in Glasses ⇑ T.T
Progress in Materials Science 94 (2018) 68–113 Contents lists available at ScienceDirect Progress in Materials Science journal homepage: www.elsevier.com/locate/pmatsci Bespoke photonic devices using ultrafast laser driven ion migration in glasses ⇑ T.T. Fernandez a,1, M. Sakakura b,1, S.M. Eaton a, B. Sotillo a, , J. Siegel c, J. Solis c, Y. Shimotsuma d, K. Miura d a Istituto di Fotonica e Nanotecnologie-Consiglio Nazionale delle Ricerche (IFN-CNR), Milano, Italy b Optoelectronics Research Centre, University of Southampton, Southampton, United Kingdom c Laser Processing Group, Instituto de Optica, Consejo Superior de Investigaciones Científicas (IO,CSIC), Madrid, Spain d Department of Materials Chemistry, Kyoto University, Kyoto, Japan article info abstract Article history: This Review provides an exhaustive and detailed description of ion migration phenomena Received 16 August 2016 which occur inside transparent dielectric media due to the interaction with intense ultra- Accepted 20 December 2017 short pulses. The paper differentiates various processes underlying the ion migration influ- Available online 29 December 2017 enced by simultaneous heat accumulation and diffusion. The femtosecond laser induced temperature distribution, the major driving force of ions in dielectrics, is described in detail. Keywords: This discussion is based on three meticulous analysis methods including the thermal modi- Femtosecond laser micromachining fication of transparent dielectrics at various ambient temperatures, numerical simulations Ion-migration and comparison with direct observation of the light-matter interaction and micro-Raman Scanning electron microscope Glass spectroscopy. The ion migration phenomena studied have been triggered in four different Waveguides configurations: at low repetition and high repetition rates, and observations perpendicular Photonic devices and parallel to the laser irradiation direction. -
Index of Refraction: Glass Plates
Index of Refraction - T 1 of 11 Index of Refraction: Treasure at the Bottom of the Sea Artwork by Shelly Lynn Johnson When light moves from one material to another, the speed of the light changes. Refraction is the bending of a light ray when it moves from one medium (like air) to another (like glass or water). The amount of bending depends on the difference in speed of the light in the two different media. Snell’s Law describes this relationship. The refractive index of a material is an important optical property and is used to calculate the focusing power of lenses and the dispersive power of prisms. Refractive index is an important physical property of a substance that can be used for identification, purity determination or measurement of concentration. This activity is designed for the Nspire handheld and intends to help students understand the refraction of light as it moves from one medium to another. Students will discover Snell’s Law using an interactive diagram. Index of Refraction - T 2 of 11 Introduction 1.1.Open the IRefracT.tns file. Read the first three pages of the document. 1.2 Reflection and refraction describe the behavior of waves. Students answer questions on handout. Use a think, pair, share strategy to invite students to respond. Q1. How are they similar? Both are properties of waves. Both describe a change in direction of waves. Q2. How are they different? Reflection describes the response of a wave when it cannot pass into a new medium. Refraction describes the response of a wave when it enters a new medium.