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Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Campro Catalog Stable Isotope
Introduction & Welcome Dear Valued Customer, We are pleased to present to you our Stable Isotopes Catalog which contains more than three thousand (3000) high quality labeled compounds. You will find new additions that are beneficial for your research. Campro Scientific is proud to work together with Isotec, Inc. for the distribution and marketing of their stable isotopes. We have been working with Isotec for more than twenty years and know that their products meet the highest standard. Campro Scientific was founded in 1981 and we provide services to some of the most prestigious universities, research institutes and laboratories throughout Europe. We are a research-oriented company specialized in supporting the requirements of the scientific community. We are the exclusive distributor of some of the world’s leading producers of research chemicals, radioisotopes, stable isotopes and environmental standards. We understand the requirements of our customers, and work every day to fulfill them. In working with us you are guaranteed to receive: - Excellent customer service - High quality products - Dependable service - Efficient distribution The highly educated staff at Campro’s headquarters and sales office is ready to assist you with your questions and product requirements. Feel free to call us at any time. Sincerely, Dr. Ahmad Rajabi General Manager 180/280 = unlabeled 185/285 = 15N labeled 181/281 = double labeled (13C+15N, 13C+D, 15N+18O etc.) 186/286 = 12C labeled 182/282 = d labeled 187/287 = 17O labeled 183/283 = 13C labeleld 188/288 = 18O labeled 184/284 = 16O labeled, 14N labeled 189/289 = Noble Gases Table of Contents Ordering Information.................................................................................................. page 4 - 5 Packaging Information .............................................................................................. -
Aldrich Vapor
Aldrich Vapor Library Listing – 6,611 spectra This library is an ideal tool for investigator using FT-IR to analyze gas phase materials. It contains gas phase spectra collected by Aldrich using a GC-IR interface to ensure chromatographically pure samples. The Aldrich FT-IR Vapor Phase Library contains 6,611 gas phase FT-IR spectra collected by Aldrich Chemical Company using a GC interface. The library includes compound name, molecular formula, CAS (Chemical Abstract Service) registry number, Aldrich catalog number, and page number in the Aldrich Library of FT-IR Spectra, Edition 1, Volume 3, Vapor-Phase. Aldrich Vapor Index Compound Name Index Compound Name 6417 ((1- 3495 (1,2-Dibromoethyl)benzene; Styrene Ethoxycyclopropyl)oxy)trimethylsilane dibromide 2081 (+)-3-(Heptafluorobutyryl)camphor 3494 (1-Bromoethyl)benzene; 1-Phenylethyl 2080 (+)-3-(Trifluoroacetyl)camphor bromide 262 (+)-Camphene; 2,2-Dimethyl-3- 6410 (1-Hydroxyallyl)trimethylsilane methylenebicyclo[2.2.1]heptane 6605 (1-Methyl-2,4-cyclopentadien-1- 2828 (+)-Diisopropyl L-tartrate yl)manganese tricarbonyl 947 (+)-Isomenthol; [1S-(1a,2b,5b)]-2- 6250 (1-Propynyl)benzene; 1-Phenylpropyne Isopropyl-5-methylcyclohexano 2079 (1R)-(+)-3-Bromocamphor, endo- 1230 (+)-Limonene oxide, cis + trans; (+)-1,2- 2077 (1R)-(+)-Camphor; (1R)-(+)-1,7,7- Epoxy-4-isopropenyl-1- Trimethylbicyclo[2.2.1]heptan- 317 (+)-Longifolene; (1S)-8-Methylene- 976 (1R)-(+)-Fenchyl alcohol, endo- 3,3,7-trimethyltricyclo[5.4.0 2074 (1R)-(+)-Nopinone; (1R)-(+)-6,6- 949 (+)-Menthol; [1S-(1a,2b,5a)]-(+)-2- Dimethylbicyclo[3.1.1]heptan-2- -
European Journal of Chemistry 5 (4) (2014) 681‐694
European Journal of Chemistry 5 (4) (2014) 681‐694 European Journal of Chemistry Journal homepage: www.eurjchem.com Synthesis, reactions and applications of pyranotriazolopyrimidines Ashraf Hassan Fekry Abd El‐Wahab a,b,*, Ibrahim Ali Radini a and Hany Mostafa Mohamed a,b a Chemistry Department, Faculty of Science, Jazan University, 2097, Jazan, Saudi Arabia b Chemistry Department, Faculty of Science, Al‐Azhar University, 11884, Nasr City, Cairo, Egypt *Corresponding author at: Chemistry Department, Faculty of Science, Jazan University, 2097, Jazan, Saudi Arabia. Tel.: +966.054.0963753. Fax: +966.017.3230028. E‐mail address: [email protected] (A.H.F.A. El‐Wahab). REVIEW INFORMATION ABSTRACT This review deals with synthesis, reactions and their applications of pyranotriazolo‐ pyrimidines. The main purpose of this review is present a survey of literatures on the reactivity of amino imino derivatives and carboxylic acid derivatives. Some of these reactions have been applied successfully to the synthesis of biological important compounds. DOI: 10.5155/eurjchem.5.4.681‐694.1087 Received: 30 April 2014 Received in revised form: 27 May 2014 Accepted: 27 May 2014 Online: 31 December 2014 KEYWORDS Naphthols Pyrimidine Biological activity Pyranopyrimidines α‐Cyanocinnamonitriles Carboxylic acid derivatives 1. Introduction chemical and biological view points, due to their diverse pharmacological activities, such as antitumor potency [19,20], Pyran derivatives have attracted a great deal of interest inhibition of KDR kinase [21], antifungal effect [22] and owing to their antimicrobial activity [1‐7], inhibition of influ‐ macrophage activation [23]. enza, virus sialidase [8], mutagenic activity [9], activity as antiviral [10], anti‐proliferaction agents [11], sex pheromones [12], antitumor [13] and anti‐inflammatory agents [14]. -
(VI) and Chromium (V) Oxide Fluorides
Portland State University PDXScholar Dissertations and Theses Dissertations and Theses 1976 The chemistry of chromium (VI) and chromium (V) oxide fluorides Patrick Jay Green Portland State University Follow this and additional works at: https://pdxscholar.library.pdx.edu/open_access_etds Part of the Chemistry Commons Let us know how access to this document benefits ou.y Recommended Citation Green, Patrick Jay, "The chemistry of chromium (VI) and chromium (V) oxide fluorides" (1976). Dissertations and Theses. Paper 4039. https://doi.org/10.15760/etd.5923 This Thesis is brought to you for free and open access. It has been accepted for inclusion in Dissertations and Theses by an authorized administrator of PDXScholar. Please contact us if we can make this document more accessible: [email protected]. All ABSTRACT OF THE TllESIS OF Patrick Jay Green for the Master of Science in Chemistry presented April 16, 1976. Title: Chemistry of Chromium(VI) and Chromium(V) Oxide Fluorides. APPROVEO BY MEMBERS OF THE THESIS CO'"o\l TIEE: y . • Ii . ' I : • • • • • New preparative routes to chromyl fluoride were sought. It was found that chlorine ironofluoride reacts with chromium trioxide and chromyl chlo ride to produce chromyl fluoride. Attempts were ~ade to define a mechan ism for the reaction of ClF and Cr0 in light of by-products observed 3 and previous investigations. Carbonyl fluoride and chromium trioxide react to fom chro·yl fluoride and carbo:i dioxide. A mechanism was also proposed for this react10n. Chromium trioxide 11itl\ l~F6 or WF5 reacts to produce chromyl fluoride and the respective oxide tetrafluoride. 2 Sulfur hexafluoride did not react with Cr03. -
Iodomethane Safety Data Sheet 1100H01 According to Federal Register / Vol
Iodomethane Safety Data Sheet 1100H01 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 08/18/2016 Version: 1.0 SECTION 1: Identification 1.1. Identification Product form : Substance Substance name : Iodomethane CAS No : 74-88-4 Product code : 1100-H-01 Formula : CH3I Synonyms : Methyl iodide Other means of identification : MFCD00001073 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Laboratory chemicals Manufacture of substances Scientific research and development 1.3. Details of the supplier of the safety data sheet SynQuest Laboratories, Inc. P.O. Box 309 Alachua, FL 32615 - United States of America T (386) 462-0788 - F (386) 462-7097 [email protected] - www.synquestlabs.com 1.4. Emergency telephone number Emergency number : (844) 523-4086 (3E Company - Account 10069) SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute Tox. 3 (Oral) H301 - Toxic if swallowed Acute Tox. 3 (Dermal) H311 - Toxic in contact with skin Acute Tox. 2 (Inhalation) H330 - Fatal if inhaled Acute Tox. 3 (Inhalation:vapour) H331 - Toxic if inhaled Skin Irrit. 2 H315 - Causes skin irritation Eye Dam. 1 H318 - Causes serious eye damage Resp. Sens. 1 H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin Sens. 1 H317 - May cause an allergic skin reaction Carc. 2 H351 - Suspected of causing cancer STOT SE 3 H335 - May cause respiratory irritation -
METHYL IODIDE 1. Exposure Data
METHYL IODIDE Data were last reviewed in IARC (1986) and the compound was classified in IARC Monographs Supplement 7 (1987). 1. Exposure Data 1.1 Chemical and physical data 1.1.1 Nomenclature Chem. Abstr. Serv. Reg. No.: 74-88-4 Chem. Abstr. Name: Iodomethane IUPAC Systematic Name: Iodomethane 1.1.2 Structural and molecular formulae and relative molecular mass H H C I H CH3I Relative molecular mass: 141.94 1.1.3 Chemical and physical properties of the pure substance (a) Description: Colourless transparent liquid, with a sweet ethereal odour (American Conference of Governmental Industrial Hygienists, 1992; Budavari, 1996) (b) Boiling-point: 42.5°C (Lide, 1997) (c) Melting-point: –66.4°C (Lide, 1997) (d) Solubility: Slightly soluble in water (14 g/L at 20°C); soluble in acetone; miscible with diethyl ether and ethanol (Budavari, 1996; Verschueren, 1996; Lide, 1997) (e) Vapour pressure: 53 kPa at 25.3°C; relative vapour density (air = 1), 4.9 (Ver- schueren, 1996) ( f ) Octanol/water partition coefficient (P): log P, 1.51 (Hansch et al., 1995) (g) Conversion factor: mg/m3 = 5.81 × ppm –1503– 1504 IARC MONOGRAPHS VOLUME 71 1.2 Production and use No information on the global production of methyl iodide was available to the Working Group. Production in the United States in 1983 was about 50 tonnes (IARC, 1986). Because of its high refractive index, methyl iodide is used in microscopy. It is also used as an embedding material for examining diatoms, in testing for pyridine, as a methy- lating agent in pharmaceutical (e.g., quaternary ammonium compounds) and chemical synthesis, as a light-sensitive etching agent for electronic circuits, and as a component in fire extinguishers (IARC, 1986; American Conference of Governmental Industrial Hygienists, 1992; Budavari, 1996). -
(12) United States Patent (10) Patent No.: US 9,536,730 B2 Lee Et Al
USO0953673OB2 (12) United States Patent (10) Patent No.: US 9,536,730 B2 Lee et al. (45) Date of Patent: Jan. 3, 2017 (54) CLEANING FORMULATIONS 7/3209 (2013.01): CIID 7/3218 (2013.01); CIID 7/3281 (2013.01); CIID 7/5013 (71) Applicant: AIR PRODUCTS AND CHEMICALS (2013.01); CIID 7/5022 (2013.01); G03F INC. Allentown, PA (US) 7/425 (2013.01); G03F 7/426 (2013.01) (58) Field of Classification Search (72) Inventors: Yi Chia Lee, Dansheui (TW); CPC ............................... C11D 11/0047; C11D 7/50 Madhukar Bhaskara Rao, Fogelsville, See application file for complete search history. PA (US); Gautam Banerjee, Latham, NY (US); Wen Dar Liu, Chupei (TW); Aiping Wu, Macungie, PA (US); Seiji (56) References Cited Inaoka, Midland, MI (US) U.S. PATENT DOCUMENTS Assignee: AIR PRODUCTS AND (73) 5,279,771 A 1/1994 Lee CHEMICALS, INC., Allentown, PA 5,417,877 A 5, 1995 Ward (US) 5,746,837 A 5/1998 Becket al. 6,117,783 A 9, 2000 Small et al. (*) Notice: Subject to any disclaimer, the term of this 6,248,704 B1 6/2001 Small et al. patent is extended or adjusted under 35 (Continued) U.S.C. 154(b) by 392 days. FOREIGN PATENT DOCUMENTS (21) Appl. No.: 14/010,748 EP O 647 884 A1 4f1995 (22) Filed: Aug. 27, 2013 EP 1736534 A1 12/2006 (Continued) (65) Prior Publication Data Primary Examiner — Gregory Webb US 2014/O109931 A1 Apr. 24, 2014 (74) Attorney, Agent, or Firm — Anne B. Kiernan; Joseph Related U.S. Application Data D. -
Safety Data Sheet
SAFETY DATA SHEET Preparation Date: 05/19/2015 Revision Date: 05/08/2017 Revision Number: G2 1. IDENTIFICATION Product identifier Product code: B1100 Product Name: BISMUTH METAL, GRANULAR, REAGENT Other means of identification Synonyms: Bismuth-209 Bismuth, elemental CAS #: 7440-69-9 RTECS # EB2600000 CI#: Not available Recommended use of the chemical and restrictions on use Recommended use: In safety devices in fire detection and extinguishing systems; Catalyst for making acrylic fibers; In production of malleable irons; carrier for radioactive uranium fuel in atomic reactor; In printing industry; alloying agent; chemical intermediate for pharmaceuticals and other chemicals; In cosmetics. Uses advised against No information available Supplier: Spectrum Chemical Mfg. Corp 14422 South San Pedro St. Gardena, CA 90248 (310) 516-8000. Order Online At: https://www.spectrumchemical.com Emergency telephone number Chemtrec 1-800-424-9300 Contact Person: Martin LaBenz (West Coast) Contact Person: Ibad Tirmiz (East Coast) 2. HAZARDS IDENTIFICATION Classification This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Not a dangerous substance or mixture according to the Globally Harmonized System (GHS) Label elements Not classified Hazards not otherwise classified (HNOC) Not Applicable Other hazards May be harmful if swallowed Product code: B1100 Product name: BISMUTH METAL, 1 / 11 GRANULAR, REAGENT 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No. Weight % Bismuth Metal 7440-69-9 100 4. FIRST AID MEASURES First aid measures General Advice: National Capital Poison Center in the United States can provide assistance if you have a poison emergency and need to talk to a poison specialist. -
Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds
Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Library Listing – 1,523 spectra Subset of Aldrich FT-IR Library related to organometallic, inorganic, boron and deueterium compounds. The Aldrich Material-Specific FT-IR Library collection represents a wide variety of the Aldrich Handbook of Fine Chemicals' most common chemicals divided by similar functional groups. These spectra were assembled from the Aldrich Collections of FT-IR Spectra Editions I or II, and the data has been carefully examined and processed by Thermo Fisher Scientific. Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 1066 ((R)-(+)-2,2'- 1193 (1,2- BIS(DIPHENYLPHOSPHINO)-1,1'- BIS(DIPHENYLPHOSPHINO)ETHAN BINAPH)(1,5-CYCLOOCTADIENE) E)TUNGSTEN TETRACARBONYL, 1068 ((R)-(+)-2,2'- 97% BIS(DIPHENYLPHOSPHINO)-1,1'- 1062 (1,3- BINAPHTHYL)PALLADIUM(II) CH BIS(DIPHENYLPHOSPHINO)PROPA 1067 ((S)-(-)-2,2'- NE)DICHLORONICKEL(II) BIS(DIPHENYLPHOSPHINO)-1,1'- 598 (1,3-DIOXAN-2- BINAPH)(1,5-CYCLOOCTADIENE) YLETHYNYL)TRIMETHYLSILANE, 1140 (+)-(S)-1-((R)-2- 96% (DIPHENYLPHOSPHINO)FERROCE 1063 (1,4- NYL)ETHYL METHYL ETHER, 98 BIS(DIPHENYLPHOSPHINO)BUTAN 1146 (+)-(S)-N,N-DIMETHYL-1-((R)-1',2- E)(1,5- BIS(DI- CYCLOOCTADIENE)RHODIUM(I) PHENYLPHOSPHINO)FERROCENY TET L)E 951 (1,5-CYCLOOCTADIENE)(2,4- 1142 (+)-(S)-N,N-DIMETHYL-1-((R)-2- PENTANEDIONATO)RHODIUM(I), (DIPHENYLPHOSPHINO)FERROCE 99% NYL)ETHYLAMIN 1033 (1,5- 407 (+)-3',5'-O-(1,1,3,3- CYCLOOCTADIENE)BIS(METHYLD TETRAISOPROPYL-1,3- IPHENYLPHOSPHINE)IRIDIUM(I) -
United States Patent Office Patented Dec
3,629,301 United States Patent Office Patented Dec. 21, 1971 3,629,301 3,3-DIFLUORO-2-SUBSTITUTED STEROIDS AND THER PREPARATION William C. Ripka, Wilmington, Del, assignor to E. I. du Pont de Nemours and Company, Wilmington, Del. 5 where R is hydrogen, methyl, or ethynyl, and R2 is hydro No Drawing. Filed Oct. 24, 1969, Ser. No. 869,352 gen or an alkanoyl having no more than 8 carbon atoms, Int, C. C07c 169/20 Such as formyl, acetyl, propionyl, butyryl, valleryl and U.S. C. 260-397.3 10 Claims caproyl. These compounds are prepared from 3-fluoro-A2-steroids 10 by a reaction with nitrosyl fluoride and subsequent conver ABSTRACT OF THE DISCLOSURE sion of the 3,3-difluoro-2-nitrimino steroid products to the New steroids of the formula corresponding 3,3-difluoro-2-keto steroids with alumina CE containing Water, as shown in the reaction scheme below X involving the steroid A-ring: R NO R R ? NOF N= A. AlO3.H2O Os R - A. l -3 F2 Fs! N Z-F 20 The 2-keto group can be converted to the 2-hydroxy F= group by conventional techniques, including, for example, wherein Z is oxygen or reduction with sodium borohydrides. DETALED DESCRIPTION OF THE INVENTION The first step of the reaction sequence, the reaction of a .O 3-fluoro-Asteroid with nitrosyl fluoride is carried out in R is hydrogen or methyl; and X is oxygen or an inert Solvent such as methylene chloride, chloroform, OR2 carbon tetrachloride, fluorodichloromethane, and ethylene 30 dichloride. -
Operation Permit Application
Un; iy^\ tea 0 9 o Operation Permit Application Located at: 2002 North Orient Road Tampa, Florida 33619 (813) 623-5302 o Training Program TRAINING PROGRAM for Universal Waste & Transit Orient Road Tampa, Florida m ^^^^ HAZARDOUS WAb 1 P.ER^AlTTlNG TRAINING PROGRAM MASTER INDEX CHAPTER 1: Introduction Tab A CHAPTER 2: General Safety Manual Tab B CHAPTER 3: Protective Clothing Guide Tab C CHAPTER 4: Respiratory Training Program Tab D APPENDIX 1: Respiratory Training Program II Tab E CHAPTER 5: Basic Emergency Training Guide Tab F CHAPTER 6: Facility Operations Manual Tab G CHAPTER 7: Land Ban Certificates Tab H CHAPTER 8: Employee Certification Statement Tab. I CHAPTER ONE INTRODUCTION prepared by Universal Waste & Transit Orient Road Tampa Florida Introducti on STORAGE/TREATMENT PERSONNEL TRAINING PROGRAM All personnel involved in any handling, transportation, storage or treatment of hazardous wastes are required to start the enclosed training program within one-week after the initiation of employment at Universal Waste & Transit. This training program includes the following: Safety Equipment Personnel Protective Equipment First Aid & CPR Waste Handling Procedures Release Prevention & Response Decontamination Procedures Facility Operations Facility Maintenance Transportation Requirements Recordkeeping We highly recommend that all personnel involved in the handling, transportation, storage or treatment of hazardous wastes actively pursue additional technical courses at either the University of South Florida, or Tampa Junior College. Recommended courses would include general chemistry; analytical chemistry; environmental chemistry; toxicology; and additional safety and health related topics. Universal Waste & Transit will pay all registration, tuition and book fees for any courses which are job related. The only requirement is the successful completion of that course.