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Wo 2009/082437 A9
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) CORRECTED VERSION (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date 2 July 2009 (02.07.2009) WO 2009/082437 A9 (51) International Patent Classification: KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, C07D 207/08 (2006.01) A61K 31/402 (2006.01) MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, C07D 207/09 (2006.01) A61P 5/26 (2006.01) NZ, OM, PG, PH, PL, PT, RO, RS, RU, SC, SD, SE, SG, C07D 498/04 (2006.01) SK, SL, SM, ST, SV, SY, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (21) International Application Number: PCT/US2008/013657 (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (22) International Filing Date: G M M N S D S L s z τ z U G Z M 12 December 2008 (12.12.2008) z w Eurasian (A M B γ KG> M D RU> τ (25) Filing Language: English TM), European (AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, (26) Publication Language: English M C M T N L N O P L P T R O S E S I s T R OAPI (30) Priority Data: B F ' B J ' C F ' C G ' C I' C M ' G A ' G N ' 0 G W ' M L ' M R ' 61/008,731 2 1 December 2007 (21 .12.2007) US N E ' S N ' T D ' T G ) - (71) Applicant (for all designated States except US): LIG- Declarations under Rule 4.17: AND PHARMACEUTICALS INCORPORATED [US/ — as to applicant's entitlement to apply for and be granted US]; 11085 N. -
Retention Indices for Frequently Reported Compounds of Plant Essential Oils
Retention Indices for Frequently Reported Compounds of Plant Essential Oils V. I. Babushok,a) P. J. Linstrom, and I. G. Zenkevichb) National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA (Received 1 August 2011; accepted 27 September 2011; published online 29 November 2011) Gas chromatographic retention indices were evaluated for 505 frequently reported plant essential oil components using a large retention index database. Retention data are presented for three types of commonly used stationary phases: dimethyl silicone (nonpolar), dimethyl sili- cone with 5% phenyl groups (slightly polar), and polyethylene glycol (polar) stationary phases. The evaluations are based on the treatment of multiple measurements with the number of data records ranging from about 5 to 800 per compound. Data analysis was limited to temperature programmed conditions. The data reported include the average and median values of retention index with standard deviations and confidence intervals. VC 2011 by the U.S. Secretary of Commerce on behalf of the United States. All rights reserved. [doi:10.1063/1.3653552] Key words: essential oils; gas chromatography; Kova´ts indices; linear indices; retention indices; identification; flavor; olfaction. CONTENTS 1. Introduction The practical applications of plant essential oils are very 1. Introduction................................ 1 diverse. They are used for the production of food, drugs, per- fumes, aromatherapy, and many other applications.1–4 The 2. Retention Indices ........................... 2 need for identification of essential oil components ranges 3. Retention Data Presentation and Discussion . 2 from product quality control to basic research. The identifi- 4. Summary.................................. 45 cation of unknown compounds remains a complex problem, in spite of great progress made in analytical techniques over 5. -
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
United States Patent (19) 11) Patent Number: 5,072,065 Sun Et Al
United States Patent (19) 11) Patent Number: 5,072,065 Sun et al. 45 Date of Patent: Dec. 10, 1991 54 NHIBITING POPCORN POLYMER FORMATION WITH ALKYL HALDES FOREIGN PATENT DOCUMENTS 63-223003 9/1988 Japan. (75) inventors: Hsiang-ning Sun, Houston, Tex.; Steven J. Potlock, Baton Rouge, La. OTHER PUBLICATIONS Liu, Plugging-Up of Equipment by Self-Polymeriza (73) Assignee: Exxon Chemical Patents Inc., tion Butadiene Production and its Prevention, China Linden, N.J. Synthetic Rubber Industry, 11(5) 356-360 (1988) & English abstract. 21 Appl. No.: 647,358 Liu et al., Determination of Traces of Diethylhydrox ylamine Inhibitor in c5 Fraction by Gas Chromatogra 22 Fied: Jan. 29, 1991 phy, China Synthetic Rubber Industry, 12(6), 408-410 (1989) & English abstract. (51 Int, C. ........................... C07C 7/20; B08B 9/00 (52) U.S. C. ..................................... 585/2; 134/22.19; Primary Examiner-Curtis R. Davis 585/3,585/950 Attorney, Agent, or Firm-Linda K. Russell (58 Field of Search ............................... 585/3, 2,950; 57 ABSTRACT 34/22.19 Inhibition of popcorn polymer growth by treatment with an alkyl halide. This compound can be admixed (56) References Cited with organic material from which popcorn polymer is U.S. PATENT DOCUMENTS formed, or added to a system for the recovery, use or 4,404,413 9/1983 Heskell ................................ 585/950 storage of such organic material. 4,941,926 7/1990 Nakajima ................................ 585/5 4,956,020 9/1990 Nakajima ................................ 585/5 16 Claims, No Drawings 5,072,065 1. 2 once present in a system. Some of the seeds become NHIBITING POPCORN POLYMER FORMATION attached to the processing and handling equipment, and WITH ALKYL HALDES cannot be readily removed by mechanical means; more over, being insoluble in most common solvents, they are CONCURRENTLY FILED APPLICATIONS virtually impossible to wash out by use of such solvents. -
(12) United States Patent (10) Patent No.: US 9,536,730 B2 Lee Et Al
USO0953673OB2 (12) United States Patent (10) Patent No.: US 9,536,730 B2 Lee et al. (45) Date of Patent: Jan. 3, 2017 (54) CLEANING FORMULATIONS 7/3209 (2013.01): CIID 7/3218 (2013.01); CIID 7/3281 (2013.01); CIID 7/5013 (71) Applicant: AIR PRODUCTS AND CHEMICALS (2013.01); CIID 7/5022 (2013.01); G03F INC. Allentown, PA (US) 7/425 (2013.01); G03F 7/426 (2013.01) (58) Field of Classification Search (72) Inventors: Yi Chia Lee, Dansheui (TW); CPC ............................... C11D 11/0047; C11D 7/50 Madhukar Bhaskara Rao, Fogelsville, See application file for complete search history. PA (US); Gautam Banerjee, Latham, NY (US); Wen Dar Liu, Chupei (TW); Aiping Wu, Macungie, PA (US); Seiji (56) References Cited Inaoka, Midland, MI (US) U.S. PATENT DOCUMENTS Assignee: AIR PRODUCTS AND (73) 5,279,771 A 1/1994 Lee CHEMICALS, INC., Allentown, PA 5,417,877 A 5, 1995 Ward (US) 5,746,837 A 5/1998 Becket al. 6,117,783 A 9, 2000 Small et al. (*) Notice: Subject to any disclaimer, the term of this 6,248,704 B1 6/2001 Small et al. patent is extended or adjusted under 35 (Continued) U.S.C. 154(b) by 392 days. FOREIGN PATENT DOCUMENTS (21) Appl. No.: 14/010,748 EP O 647 884 A1 4f1995 (22) Filed: Aug. 27, 2013 EP 1736534 A1 12/2006 (Continued) (65) Prior Publication Data Primary Examiner — Gregory Webb US 2014/O109931 A1 Apr. 24, 2014 (74) Attorney, Agent, or Firm — Anne B. Kiernan; Joseph Related U.S. Application Data D. -
Aldrich Raman
Aldrich Raman Library Listing – 14,033 spectra This library represents the most comprehensive collection of FT-Raman spectral references available. It contains many common chemicals found in the Aldrich Handbook of Fine Chemicals. To create the Aldrich Raman Condensed Phase Library, 14,033 compounds found in the Aldrich Collection of FT-IR Spectra Edition II Library were excited with an Nd:YVO4 laser (1064 nm) using laser powers between 400 - 600 mW, measured at the sample. A Thermo FT-Raman spectrometer (with a Ge detector) was used to collect the Raman spectra. The spectra were saved in Raman Shift format. Aldrich Raman Index Compound Name Index Compound Name 4803 ((1R)-(ENDO,ANTI))-(+)-3- 4246 (+)-3-ISOPROPYL-7A- BROMOCAMPHOR-8- SULFONIC METHYLTETRAHYDRO- ACID, AMMONIUM SALT PYRROLO(2,1-B)OXAZOL-5(6H)- 2207 ((1R)-ENDO)-(+)-3- ONE, BROMOCAMPHOR, 98% 12568 (+)-4-CHOLESTEN-3-ONE, 98% 4804 ((1S)-(ENDO,ANTI))-(-)-3- 3774 (+)-5,6-O-CYCLOHEXYLIDENE-L- BROMOCAMPHOR-8- SULFONIC ASCORBIC ACID, 98% ACID, AMMONIUM SALT 11632 (+)-5-BROMO-2'-DEOXYURIDINE, 2208 ((1S)-ENDO)-(-)-3- 97% BROMOCAMPHOR, 98% 11634 (+)-5-FLUORODEOXYURIDINE, 769 ((1S)-ENDO)-(-)-BORNEOL, 99% 98+% 13454 ((2S,3S)-(+)- 11633 (+)-5-IODO-2'-DEOXYURIDINE, 98% BIS(DIPHENYLPHOSPHINO)- 4228 (+)-6-AMINOPENICILLANIC ACID, BUTANE)(N3-ALLYL)PD(II) CL04, 96% 97 8167 (+)-6-METHOXY-ALPHA-METHYL- 10297 ((3- 2- NAPHTHALENEACETIC ACID, DIMETHYLAMINO)PROPYL)TRIPH 98% ENYL- PHOSPHONIUM BROMIDE, 12586 (+)-ANDROSTA-1,4-DIENE-3,17- 99% DIONE, 98% 13458 ((R)-(+)-2,2'- 963 (+)-ARABINOGALACTAN BIS(DIPHENYLPHOSPHINO)-1,1'- -
The Synthesis of 1,2-Azaphospholes, 1,2-Azaphosphorines and 1,2-Azaphosphepines
The Free Internet Journal Review for Organic Chemistry Archive for Arkivoc 2020, i, 472-498 Organic Chemistry The synthesis of 1,2-azaphospholes, 1,2-azaphosphorines and 1,2-azaphosphepines Noha M. Hassanin,a Tarik E. Ali,b,a* Mohammed A. Assiri,b Hafez M. Elshaaer,a and Somaia M. Abdel-Kariema a Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, Egypt b Department of Chemistry, Faculty of Science, King Khalid University, Abha, Saudi Arabia Email: [email protected], [email protected] Received 06-28-2020 Accepted 08-26-2020 Published online 10-22-2020 Abstract 1,2-Azaphospholes, 1,2-azaphosphorines and 1,2-azaphosphepines are prominent phosphorus heterocycles and are of interest due to their potent pharmacological activities. In this review, we provide the available literature data on the synthesis of 1,2-azaphospholes, 1,2-azaphosphorines and 1,2-azaphosphepines. Keywords: 1,2-azaphospholes, 1,2-azaphosphorines, 1,2-azaphosphepines, phosphorus heterocycles DOI: https://doi.org/10.24820/ark.5550190.p011.280 Page 472 ©AUTHOR(S) Arkivoc 2020, i, 472-498 Hassanin, N. M. et al. Table of Contents 1. Introduction 2. Synthetic Methods for Functionalized 1,2-Azaphosphole Derivatives 2.1 Cyclization of ethyl N-methyl-3-bromopropylphosphonamidate with NaH 2.2 Cyclization of -aminophosphorus compounds with bases 2.3 Reaction of methyleneaminophosphanes with activated alkenes and alkynes 2.4 Cyclization of 2-[2-(t-butylimino)cyclohexyl]acetonitrile with PCl3 2.5 Cyclization of 2-imino-2H-chromene-3-carboxamide -
From Ultrathin Coatings to Laser Lithography
Designing Functional 2D and 3D Structures: From Ultrathin Coatings to Laser Lithography Zur Erlangung des akademischen Grades eines DOKTORS DER NATURWISSENSCHAFTEN (Dr. rer. nat.) von der KIT-Fakultät für Chemie und Biowissenschaften des Karlsruher Instituts für Technologie (KIT) genehmigte DISSERTATION von M. Sc. Markus Michael Zieger aus Pforzheim, Deutschland 1. Referent: Prof. Dr. Christopher Barner-Kowollik 2. Referent: Prof. Dr. Hans-Achim Wagenknecht Tag der mündlichen Prüfung: 18.07.2018 Die vorliegende Arbeit wurde vom Februar 2015 bis Juni 2018 unter der Anleitung von Prof. Dr. Christopher Barner-Kowollik und Prof. Dr. Martin Wegener am Karlsruher Institut für Technologie (Universitätsbereich) angefertigt. iii Introduction In tiefer Dankbarkeit meiner Familie gewidmet. iv Hiermit erkläre ich wahrheitsgemäß, dass die vorliegende Doktorarbeit im Rahmen der Betreuung durch Prof. Dr. Christopher Barner-Kowollik von mir verfasst wurde und keine anderen als die angegebenen Quellen und Hilfsmittel verwendet wurden. Wörtlich oder inhaltlich übernommene Passagen sind mit dem entsprechenden Zitat kenntlich gemacht. Darüber hinaus wurde die Satzung des Karlsruher Instituts für Technologie (KIT) zur Sicherung guter wissenschaftlicher Praxis beachtet, insbesondere die Abgabe und Archivierung der Primärdaten gemäß Abs. A (6). Ebenfalls bestätige ich, dass die elektronische Version der Arbeit mit der schriftlich abgegebenen übereinstimmt. Des Weiteren erkläre ich, dass ich mich derzeit in keinem weiteren laufenden Promotionsverfahren befinde -
Everything Added to Food in the United States (EAFUS)
Everything Added to Food in the United States (EAFUS) A to Z Index Follow FDA FDA Voice Blog Most Popular Searches Home Food Drugs Medical Devices Radiation-Emitting Products Vaccines, Blood & Biologics Animal & Veterinary Cosmetics Tobacco Products Everything Added to Food in the United States (EAFUS) FDA Home Everything Added to Food in the United States (EAFUS) Everything Added to Food in the United States (EAFUS) - The list below is an alphabetical inventory representing only five of 196 fields in FDA/CFSAN's PAFA database. Definitions of the labels that are found in the inventory are: Label Definition DOCTYPE An indicator of the status of the toxicology information available for the substance in PAFA (administrative and chemical information is available on all substances): A Fully up-to-date toxicology information has been sought. S P E There is reported use of the substance, but it has not yet been assigned for toxicology literature search. A F N There is reported use of the substance, and an initial toxicology literature search is in progress. E W NI Although listed as a added to food, there is no current reported use of the substance, and, therefore, L although toxicology information may be available in PAFA, it is not being updated. N There is no reported use of the substance and there is no toxicology information available in PAFA. U L B The substance was formerly approved as a food additive but is now banned; there may be some toxicology A data available. N DOCNUM PAFA database number of the Food Additive Safety Profile volume containing the printed source information concerning the substance. -
WO 2016/147132 Al 22 September 2016 (22.09.2016) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/147132 Al 22 September 2016 (22.09.2016) P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C07C 227/32 (2006.01) C07D 405/04 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/IB20 16/05 14 1 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 17 March 2016 (17.03.2016) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: 895/MUM/2015 18 March 2015 (18.03.2015) (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (71) Applicant: PIRAMAL ENTERPRISES LIMITED GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, [IN/IN]; Piramal Tower, Ganpatrao Kadam Marg, Lower TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, Parel, Mumbai 400 013 (IN). -
Llllllillllllllllillllllllllllllllllllllllllllilllllllllllll
llllllIllllllllllIllllllllllllllllllllllllllllIlllllllllllllllllllllllllllSOO5223589A United States Patent -- [19] [11] Patent Number: 5,223,589 Kulprathipanja et al. [45] Date of Patent: Jun. 29, 1993 [54] PROCESS FOR SEPARATING DURENE 3.422.848 1/1969 Liebman et a]. ......... .. 137/625.l5 FROM SUBSTITUTED BENZENE 3.706.812 12/1972 De Rosset et a1. 260/674 SA v 3,864,416 2/1975 Campbell et al. .. 260/674 A HYDROCARBOI\S 4.642.397 2/1987 Zinnen et al. .. 568/934 [75] Inventors: Santi Kulprathipanja, Inverness; 4,743.708 5/1988 Rosenfeld et al. ................ .. 585/828 Kenneth K. Kuhnle, St. Charles; Marjorie s. Patton, Darien, all of 111. OTHER PUBLICATIONS , . Chartov et al. Chem. Abstract 92(7) 58328d [73] Asslgnee: UOP’ Des Flames’ 111‘ (l972)-—Abstract only, page unavailable. [21] APPL No-i 872,191 Primary Examiner-Helen M. S. Sneed [22] Filed. Apr. 22, 1992 Assistant Examiner-Nhat D. Phan Attorney, Agent, or Firm-Thomas K. McBride; John F. [51] Int. (31.5 ......................... .. C07C 7/12; C07C 7/00 Spears’ 1L; Jack H_ Hall - [52] US. Cl. .................................. .. 585/828; 585/825; 585/831; 585/853 [57] ABSTRACT [58] Field Of Search .... ........ .. 585/825. 828, 831, 853 The separation Ofdurene in purity from coal tar or . petroleum fractions by an adsorptive chromatographic [56] References cued process and liquid phase with lithium-exchanged X US- PATENT DOCUMENTS zeolite as the adsorbent and liquid aromatic desorbents. 2.985.589 5/1961 Broughton er al. ................ .. 210/34 3.040.777 6/1962 Carson et al. ................ .. l37/625.l5 4 Claims, No Drawings 5,223,589 1 2 scale (deRosset U.S. -
Reactive Chlorine Compounds in the Atmosphere
CHAPTER 1 Reactive Bromine Compounds O.N.Singh 1 · P.Fabian 2 1 Department of Applied Physics, Institute of Technology, Banaras Hindu University, Varanasi- 221 005, India. E-mail: [email protected] 2 University of Munich, Lehrstuhl für Bioklimatologie und Immissionsforschung, Am Hochanger 13, D-85354 Freising-Weihenstephan, Germany. E-mail: [email protected] Bromine, a minor constituent in the Earth’s atmosphere – with its 50-fold higher efficiency of ozone destruction compared to chlorine – contributes significantly to the ozone hole formation and wintertime stratospheric ozone depletion over northern mid and high latitudes.In addition ozone episodes observed in the Arctic during polar sunrise are solely due to atmospheric bromine.CH3Br, CH2Br2 and CHBr3 are the major brominated gases in the atmosphere, of which CH3Br being most abundant, contributes about 50% and CH2Br2 around 7 to 10% of the total organic stratospheric bromine.Bromocarbons with shorter lifetimes like CHBr3 ,CH2BrCl, CHBr2Cl, CHBrCl2 and CH2BrI decompose before reaching the stratosphere, and are responsible for the ozone episodes.But for 3CHBr, which has also significant anthropogenic sources, all the aforementioned bromocarbons are mostly of marine origin.Halons (H-1211, H-1301, H-2402, H-1202) are solely anthropogenic and are far more stable.They decompose only after reaching the stratosphere.It is estimated that 39% of the stratospheric organic bromine (ª 7 pptv) loading is due to these halons.Increa- ses are being still registered in the atmospheric abundance of halons in spite of production restrictions.Though extensively investigated,the existing knowledge with regard to the pro- duction and degradation of atmospheric bromine gases, is not commensurate with its importance.