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Geology, Land-use, and Water Quality: Lessons from Big Spring

Bob Libra – State Geologist of Iowa Geological & Water Survey Iowa D.N.R.

The rock sequence in the Turkey River Watershed:

All units are aquifers except the Maquoketa Shales.

The Cedar Valley, , and Galena rocks are particularly karst-prone.

Karst Aquifers move LOTS of water!

Geography and Geology of Big Spring

? BTLUW BTLUE VD24 BTLD BOOGD ?

L23S L22T Dc05

T17

F08

F47

GL01 ?

RC02

JSW TR01 N

USA

BIG SPRING BASIN 0 6 miles 0 10 km CLAYTON COUNTY

GEOLOGIC MAP UNITS EXPLANATION SILURIAN Silurian dolomites (Blanding, Tete des Morts, Mosalem Fms.) Private well Surface-water site ( Member) Gaged tile-line site Maquoketa Formation Big Spring (Ft. Atkinson, Clermont, Elgin Members) Groundwater-basin divide Galena Carbonates (Dubuque, Wise Lake, Dunleith Fms.) Cross section A B C

Elevation Groundwater Groundwater in Divide Divide meters feet 400 1200 Q 1150 SU Sinkhole Area Sinkhole Area Q 1100 k

k e Q

e

k e

r Omf

e e

Q r

C e

r

C

350 1050 s t C Omf

d

r

r

Q r e

a

e

b v

w

l Q

o i

1000 Omf o

R S

H

w Omf na Og 950 o l le alluvium f Ga r Og e f t o G c a a tri 300 900 Top len iome w a tent d po n u 850 o r cks G te ro arbona Og shaly c 800 shale a p en Od 750 al one 250 f G eter Sandst e o St. P as p B Os 700 Osh 650

1 1/2 0 1 mile GEOLOGIC UNITS 1 1/2 0 1 kilometer

Holocene alluvium Omb Maquoketa Formation Odp Decorah, Platteville, (stream deposits) Brainard Shale Member and Glenwood Fms.

Q deposits Omf Maquoketa Formation Osp St. Peter Sandstone undiferentiated loess, till, etc. Ft. Atkinson, Clermont, and Elgin Members SU Silurian dolomites Og Galena carbonate rocks Osh Shakopee Formation NO3 in water and N-Inputs to Big Spring Basin

mg/L 3000 60 Payment-in-Kind 3000 set-aside program 2500 Fertilizer-N 50 2500 10 Big Spring 2000 40 Groundwater NO3 2000 3 -N 1500 30 3 NO Metric Tons-N Metric 1500 NO Tons-N 5 1000 20 1000

500 10 500 Manure-N (and Soil-N) 0 0 0 0 1960 1965 1970 1975 1980 1985 1990 1995 2000

Graph with event at different watershed scales Big Spring Water 1982-2000

cm inches

50 NO3-N load 120 Annual Basin mg/L kg Precipitation 45 14 900,000 110 Annual FW Mean NO -N 40 3 100 12 750,000 Annual NO3-N Load 90 35 600,000 10 80 30 450,000 70 8 25 300,000 60 6 150,000 50 20 '82 '83 '84 '85 '86 '87 '88 '89 '90 '91 '92 '93 '94 '95 '96 '97 '98 '99 '00 '01 4 0 '82 '83 '84 '85 '86 '87 '88 '89 '90 '91 '92 '93 '94 '95 '96 '97 '98 '99 '00 '01

mcm ac-ft Atrazine load 60,000 µg/L kg 70 Annual Groundwater 10.0 70 Annual FW Mean Atrazine Discharge 60 50,000 5.0 60 Annual Atrazine Load 50 50 40,000 40 40 1.0 30,000 30 30 0.5 20 20,000 20 10

10 10,000 0.1 0 '82 '83 '84 '85 '86 '87 '88 '89 '90 '91 '92 '93 '94 '95 '96 '97 '98 '99 '00 '01 '82 '83 '84 '85 '86 '87 '88 '89 '90 '91 '92 '93 '94 '95 '96 '97 '98 '99 '00 '01 Nitrogen Input Reductions

Basin average fertilizer-nitrogen rates Average Yield Rotation All corn 1st- corn 2nd-year corn Continuous Continuous after alfalfa after alfalfa corn corn yields Year ...... lbs N/Acre...... Bushels/Acre

1981 174 123 160 178 128 1982 174 123 ... 178 138 1984 158 115 155 169 130 1986 147 96 ... 153 149 1987 149 84 121 157 141 1988 141 84 124 151 79* 1989 138 82 125 148 147 1990 123 66 121 145 145 1991 117 59 112 131 138 1992 117 ...... 128 165 1993 115 55 117 124 110**

* drought lowered yields in the basin and across Iowa ** frequent rains lowered yields in the basin and across Iowa Nitrate – Big Spring Groundwater

Row – Crop: 45% 57% 64% 71% (1982) (1992) (2002) (2009)